Conditions | Yield |
---|---|
Stage #1: sodium molybdate; ammonium dihydrogen phosphate With caesium carbonate In neat (no solvent, solid phase) at 850℃; for 24h; Stage #2: In neat (no solvent, solid phase) at 680℃; for 85h; Stage #3: In neat (no solvent, solid phase) at 20℃; for 66h; |
Conditions | Yield |
---|---|
Stage #1: ammonium dihydrogen phosphate; sodium carbonate In neat (no solvent, solid phase) at 350℃; for 24h; Stage #2: In neat (no solvent, solid phase) at 600℃; for 120h; Calcination; |
sodium pyrophosphate
Conditions | Yield |
---|---|
With silver cyanide In neat (no solvent) byproducts: NaCN, NaCNO, Ag; heating with AgCN in presence of (CN)2 to 270°C;; | 75% |
With sulfur In neat (no solvent) grinding phosphate with sulfur; heating to 1000°C in quartz crucible in a stream of air (10 K/min);; detn. by 31P-NMR; | |
With mercury(II) cyanide In neat (no solvent) molar ratio Na3PO4:Hg(CN)2=1:1 or 2:1, heating for 1.5h;; | 74-77 |
With oxygen; Nitrogen dioxide In neat (no solvent) Kinetics; byproducts: NaNO3; mixing with NO2 and O2 directly in the quartz reaction vessel contg. Na3PO4, heating on a platinum support at different temp. for different times; not isolated; Raman, NMR; |
sodium pyrophosphate
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: H2O; heating to 300°C for several days;; | |
byproducts: H2O; heating at 100-105°C to const. mass; | |
In solid byproducts: H2O; dehydrating the decahydrate at 130°C to constant weight; |
sodium pyrophosphate
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: H2O; dehydration at elevated temp., decompn. at red heat (Pt-vessel);; | |
In melt; neat (no solvent) byproducts: H2O; dehydration of melt in presence of 2-25% condensed phosphates; heating resulting dihydrate to 300-400°C;; | |
In melt; neat (no solvent) byproducts: H2O; dehydration of melt, heating resulting dihydrate to 300-400°C;; |
Conditions | Yield |
---|---|
With H2O In water formation of orthophosphate and pyrophosphate by hydratation of metaphosphate in alkaline solns.;; |
sodium pyrophosphate
Conditions | Yield |
---|---|
sodium nitrate In neat (no solvent) increase of react. rate by NaNO3 (decompn. of impurities);; | |
With sodium nitrate In neat (no solvent) oxidation of organic material in educt mixt. by NaNO3, light product;; | |
With thionyl chloride In neat (no solvent) byproducts: SO2, HCl; heating on a water bath;; |
sodium pyrophosphate
Conditions | Yield |
---|---|
In melt thermal decompn.;; | |
With water In water byproducts: HF; hydrolyzed at 883 K; | |
In neat (no solvent) on heating;; | |
In neat (no solvent) on heating;; |
sodium pyrophosphate
Conditions | Yield |
---|---|
With air In neat (no solvent) spraying Na posphates (Na2O:P2O5 >2:1) into a P flame, temp. up to 1000°C;; | |
With air In sodium hydroxide P flame, react. vessel coated with a layer of alk. orthophosphate-soln. (Na2O:P2O5=2:1), dehydration of resulting soln., calcination to Na4P2O7;; | |
With air In neat (no solvent) spraying sodium-phosphates-hydrate melts (Na2O:P2O5 >2:1) into a P flame, temp. up to 1000°C;; |
sodium pyrophosphate
Conditions | Yield |
---|---|
With oxygen In neat (no solvent) Kinetics; on heating;; | |
With sodium nitrite In neat (no solvent) 240-570°C, different molar ratios of Na2O and P2O5;; | |
With NaNO2 In neat (no solvent) 240-570°C, different molar ratios of Na2O and P2O5;; | |
With O2; Na-acetate or NaNO3 or Na2CO3 In neat (no solvent) Kinetics; on heating;; |
Conditions | Yield |
---|---|
In water at 80°C;; | |
In neat (no solvent) complete dehydration in a stream of dry NH3 within 8d;; | |
In neat (no solvent) isothermic dehydration at 23°C;; | |
In ammonia NH3 (liquid); dehydration with liquid NH3 at -78.5°C;; |
Conditions | Yield |
---|---|
With air In sodium hydroxide spraying NaCl into a P flame (introduction of excess air and H2O vapor), sepn. of volatile impurities, react. of generated metaphosphates with aq. NaOH; apparatus described;; | |
With oxygen In neat (no solvent) byproducts: metaphosphate; combustion of P in a vessel coated with NaCl, react. of P2O5 with molten NaCl;; | |
With air In sodium hydroxide spraying NaCl into a P flame (introduction of excess air and H2O vapor), sepn. of volatile impurities, react. of generated metaphosphates with aq. NaOH;; |
sodium pyrophosphate
Conditions | Yield |
---|---|
With zinc diacetate In water heating an aq. soln. with zinc acetate at 40 °C;; | |
With zinc acetate In water heating an aq. soln. with zinc acetate at 40 °C;; |
sodium pyrophosphate
Conditions | Yield |
---|---|
In neat (no solvent, solid phase) at 900℃; Heating; |
sodium pyrophosphate
Conditions | Yield |
---|---|
With ammonia In neat (no solvent) byproducts: (NH4)2H2P2O7, H2O; with NH3-gas at 100°C;; product-mixture;; | |
With NH3 In neat (no solvent) byproducts: (NH4)2H2P2O7, H2O; with NH3-gas at 100°C;; product-mixture;; |
sodium pyrophosphate
Conditions | Yield |
---|---|
With water In solid byproducts: NH3; moist air, at 200°C, for 0.5 and for 3 h; not isolated, detected by (31)P-NMR; |
Conditions | Yield |
---|---|
With air In neat (no solvent, solid phase) 315°C; |
A
sodium pyrophosphate
Conditions | Yield |
---|---|
With sodium hydroxide In water Electrolysis; 16 mM sodium phosphite was electrolyzed on B-doped diamond electrode at pH 12 (1 N NaOH) and 20°C for 500 min; ion chromy.; | |
With sulfuric acid In water Electrolysis; 9.7-29 mM sodium phosphite was electrolyzed on B-doped diamond electrodeat pH 2 or 7 (1 N H2SO4) and 10-40°C for 500 min; ion chromy.; |
sodium cyanide
sodium pyrophosphate
Conditions | Yield |
---|---|
With sodium hypophosphate; oxygen In neat (no solvent) byproducts: (CN)2; heating at 500°C, 1h;; | |
With NaPO3; O2 In neat (no solvent) byproducts: (CN)2; heating at 500°C, 1h;; |
sodium pyrophosphate
Conditions | Yield |
---|---|
With nitric acid In not given evapn. of Na2PO3 soln. in platinum crucible; oxidation (HNO3) and calcination;; | |
With HNO3 In not given evapn. of Na2PO3 soln. in platinum crucible; oxidation (HNO3) and calcination;; |
sodium pyrophosphate
Conditions | Yield |
---|---|
With nitric acid In not given evapn. of Na2PO3 soln. in platinum crucible; oxidation (HNO3) and calcination;; | |
With HNO3 In not given evapn. of Na2PO3 soln. in platinum crucible; oxidation (HNO3) and calcination;; |
sodium pyrophosphate
Conditions | Yield |
---|---|
With sodium hydroxide In not given pptn. of Na4P2O7 from a soln. satd. with NaOH;; | |
With NaOH In not given pptn. of Na4P2O7 from a soln. satd. with NaOH;; |
Conditions | Yield |
---|---|
With water In water Kinetics; 100°C; NMR monitoring; | |
With water; urea In water Kinetics; 100°C; NMR monitoring; |
sodium pyrophosphate
Conditions | Yield |
---|---|
With nitric acid In neat (no solvent) oxidation with HNO3 and then calcinated;; | >99 |
With HNO3 In neat (no solvent) oxidation with HNO3 and then calcinated;; | >99 |
A
sodium pyrophosphate
Conditions | Yield |
---|---|
With water In water hot H2O;; | |
With H2O In water hot H2O;; |
sodium pyrophosphate
Conditions | Yield |
---|---|
With silver cyanide In neat (no solvent) byproducts: NaCN, NaCNO, Ag; heating with AgCN in presence of (CN)2 to 270°C;; | 75% |
With sulfur In neat (no solvent) grinding phosphate with sulfur; heating to 1000°C in quartz crucible in a stream of air (10 K/min);; detn. by 31P-NMR; | |
With mercury(II) cyanide In neat (no solvent) molar ratio Na3PO4:Hg(CN)2=1:1 or 2:1, heating for 1.5h;; | 74-77 |
With oxygen; Nitrogen dioxide In neat (no solvent) Kinetics; byproducts: NaNO3; mixing with NO2 and O2 directly in the quartz reaction vessel contg. Na3PO4, heating on a platinum support at different temp. for different times; not isolated; Raman, NMR; |
aluminum oxide
phosphorus oxynitride
A
sodium pyrophosphate
Conditions | Yield |
---|---|
In neat (no solvent) heating in a sintered corund crucible at 800°C for 90 min, at 480°C for 120 min.;; extn. of byproducts (aq. HCl); elem. anal.;; | A n/a B 64.9% |
silver(I) cyanide
A
sodium cyanide
B
sodium pyrophosphate
C
sodium isocyanate
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: Ag; heating dry Na3PO4 with AgCN at 270°C;; | |
In neat (no solvent) byproducts: Ag; at 270°C;; | |
In neat (no solvent) byproducts: Ag; heating dry Na3PO4 with AgCN at 270°C;; |
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: H2; 400-900°C, small excess of Na2HPO4 needed to avoid formation of PH3;; |
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: ZnCl2; calcination;; | |
In neat (no solvent) byproducts: ZnCl2; calcination;; |
Conditions | Yield |
---|---|
In neat (no solvent) calcination of NaCl with Zn2P4O7;; evaporation of ZnCl2;; |
A
sodium pyrophosphate
Conditions | Yield |
---|---|
In further solvent(s) dissolution mechanism for 30 mole% NaCl + 70 mole% NaPO3 at 700°C; |
sodium dihydrogenphosphate
sodium pyrophosphate
Conditions | Yield |
---|---|
In water spraying method using NaH2PO4 soln. (from neutralization of H3PO4 with Na2CO3);; | |
In neat (no solvent) prepn. by calcination at 800°C; |
Conditions | Yield |
---|---|
With ammonia In neat (no solvent) byproducts: NH4Cl; heating in presence of NH3, sublimation of NH4Cl;; |
sodium dihydrogenphosphate
sodium pyrophosphate
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: Na4P2O6S; at 224°C;; | |
In neat (no solvent) byproducts: Na4P2O6S; at 224°C;; |
sodium dihydrogenphosphate
B
sodium pyrophosphate
Conditions | Yield |
---|---|
In neat (no solvent) on heating a stoichiometric mixture;; product mixture;; |
Conditions | Yield |
---|---|
With oxygen Kinetics; byproducts: Na2SO3, Na2SO4; at heating from 200°C up to 1000°C; raman spectroscopy; NMR; |
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: sulfur; heating of Na3PO4 in a SO2 atmosphere at 400-1000°C; not separated, detected by Raman-, (31)P-NMR-spectroscopy and X-ray diffraction;; |
mercury(II) cyanide
A
sodium cyanide
B
sodium pyrophosphate
C
sodium isocyanate
Conditions | Yield |
---|---|
In neat (no solvent) heating at 300°C;; | |
In neat (no solvent) heating at 300°C;; |
Conditions | Yield |
---|---|
With oxygen |
Conditions | Yield |
---|---|
With air In sodium hydroxide spraying NaCl into a P flame (introduction of excess air and H2O vapor), sepn. of volatile impurities, react. of generated metaphosphates with aq. NaOH; apparatus described;; | |
With oxygen In neat (no solvent) byproducts: metaphosphate; combustion of P in a vessel coated with NaCl, react. of P2O5 with molten NaCl;; | |
With air In sodium hydroxide spraying NaCl into a P flame (introduction of excess air and H2O vapor), sepn. of volatile impurities, react. of generated metaphosphates with aq. NaOH;; |
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: PbCl2; calcination;; | |
In neat (no solvent) byproducts: PbCl2; calcination;; |
Conditions | Yield |
---|---|
In neat (no solvent) calcination of NaCl with Pb2P4O7;; evaporating of PbCl2;; |
Conditions | Yield |
---|---|
In water byproducts: HCl; heating H3PO4 and NaCl until formation of HCl is finished, concg. of melt with H2O (150-250°C, 7-14 atm); addn. of Ca(OH)2 to the filtarte until a ratio of Na2P:P2O5=2;1 is reached, evapn. of filtrate, heating to ca. 550° for 45-60 min;; | |
In neat (no solvent) byproducts: HCl, H2O; calcination;; | |
In neat (no solvent) byproducts: HCl; heating to red heat in presence of SiO2;; | |
In neat (no solvent) byproducts: HCl, H2O; calcination;; |
Conditions | Yield |
---|---|
With oxygen In neat (no solvent) byproducts: Cl2; at about 1000°C, exclusion of H2O;; |
Conditions | Yield |
---|---|
With O2 |
Conditions | Yield |
---|---|
In neat (no solvent) 1123 K, 0.5 h; quenching, paper chromy.; |
Conditions | Yield |
---|---|
In water evapn. of a mixt. of H3PO4 with Na salts of volatile acids, molar ratio Na2O:P2O5=2:1;; | |
In water purifn. of H3PO4 by addn. of Ca(OH)2 or CaO, pptn. of impurities, addn. of Na(1+) to the filtrate until a ratio Na2O:P2O5=2:1 is reached;; |
sodium pyrophosphate
Conditions | Yield |
---|---|
With air In neat (no solvent) spraying Na posphates (Na2O:P2O5 >2:1) into a P flame, temp. up to 1000°C;; | |
With air In sodium hydroxide P flame, react. vessel coated with a layer of alk. orthophosphate-soln. (Na2O:P2O5=2:1), dehydration of resulting soln., calcination to Na4P2O7;; | |
With air In neat (no solvent) spraying sodium-phosphates-hydrate melts (Na2O:P2O5 >2:1) into a P flame, temp. up to 1000°C;; |
Conditions | Yield |
---|---|
With air In neat (no solvent) spraying solid NaOH into a P flame, temp. up to 1000°C;; |
Conditions | Yield |
---|---|
In neat (no solvent) Kinetics; evacuated quartz vessel, 700-1000°C, condensation in cold zone; yield depending on educt ratio, reaction time and temperature; product mixt. not sepd., detd. by powder X-ray diffraction and (31)P-NMRspectroscopy; |
sodium pyrophosphate
Conditions | Yield |
---|---|
In neat (no solvent) heating recrystd. educt to about 110°C, then for 1h to red heat;; recrystn., heating; very pure product;; | |
In neat (no solvent) heating recrystd. educt to about 110°C, then for 1h to red heat;; recrystn., heating; very pure product;; |
Conditions | Yield |
---|---|
In not given byproducts: SO2, HCl; heating Na2HPO4 with SOCl2 on a water bath;; | |
In not given byproducts: SO2, HCl; heating Na2HPO4 with SOCl2 on a water bath;; |
sodium cyanide
sodium pyrophosphate
Conditions | Yield |
---|---|
With sodium hypophosphate; oxygen In neat (no solvent) byproducts: (CN)2; heating at 500°C, 1h;; | |
With NaPO3; O2 In neat (no solvent) byproducts: (CN)2; heating at 500°C, 1h;; |
Conditions | Yield |
---|---|
In water at 60℃; for 0.5h; | 95% |
Conditions | Yield |
---|---|
In water Pd salt, bipyridine and Na salt were dissolved with stirring in H2O at 60°C; left for 2 h; slowly evapd. at room temp. for few d; dried in vac. overnight; elem. anal.; | 85% |
Conditions | Yield |
---|---|
In water aq. suspn. Cu(OH)2 was treated with 2,2'-bipyridine at room temp. and stirred for 15 min, Na4P2O7 was added and stirred for 4 h; soln. was allowed to stand over several days; elem. anal.; | 80% |
Conditions | Yield |
---|---|
In water 2,2'-bipyridine was added to aq. soln. VO(SO4)2*2H2O, aq. soln. Na4P2O7 was added; ppt. was filtered, washed with water and air dried; elem. anal.; | 80% |
Conditions | Yield |
---|---|
In methanol; acetone at 20℃; | 77% |
Conditions | Yield |
---|---|
With nitric acid; potassium hydroxide In ethanol; water at 60℃; for 15h; pH=8; | 74.6% |
The Urea hydrogen peroxide,with the CAS registry number 124-43-6, it is also named as carbamide peroxide. The Hydrogen peroxide with urea (1:1) is an organic compound with the formula CH6N2O3. The IUPAC name of this chemical is hydrogen peroxide; urea. The product's classification code is Anti-infective, topical [dental]. Besides, it is a white crystals or powder, which should be stored in a dry and well-ventilated place at temperature of 15 - 25 °C. In medicine and the pharmaceutical industry, it can be used as an efficient safe and convenient solid disinfectant.this chemical can be prepared by low concentrations of hydrogen peroxide and saturated or supersaturated urea solution.
Physical properties about Urea hydrogen peroxide with urea (1:1) are:
(1)ACD/LogP: -2.11; (2)ACD/LogD (pH 5.5): -2.11; (3)ACD/LogD (pH 7.4): -2.11; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 1; (6)ACD/KOC (pH 5.5): 1.69; (7)ACD/KOC (pH 7.4): 1.69; (8)#H bond acceptors: 3; (9)#H bond donors: 4; (10)Polar Surface Area: 23.55 Å2; (11)Flash Point: 72.7 °C; (12)Enthalpy of Vaporization: 43.28 kJ/mol; (13)Boiling Point: 196.6 °C at 760 mmHg; (14)Vapour Pressure: 0.395 mmHg at 25°C.
Safety of Urea hydrogen peroxide:
When you are using this chemical, please be cautious about it as the following: It contacts with combustible material may cause fire and can cause burns. Please keep away from combustible material. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable gloves and eye/face protection. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).
You can still convert the following datas into molecular structure:
(1)SMILES: O=C(N)N.OO
(2)InChI: InChI=1/CH4N2O.H2O2/c2-1(3)4;1-2/h(H4,2,3,4);1-2H
(3)InChIKey: AQLJVWUFPCUVLO-UHFFFAOYAW
(4)Std. InChI: InChI=1S/CH4N2O.H2O2/c2-1(3)4;1-2/h(H4,2,3,4);1-2H
(5)Std. InChIKey: AQLJVWUFPCUVLO-UHFFFAOYSA-N
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