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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

1,4-Cyclohexanedimethanol

Cas:105-08-8

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 1,4-Cyclohexanedimethanol supplier in China

Cas:105-08-8

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Assay (Ursolic acid) 98%min 98.22% ----------------------------------------------------------------

High purity 105-08-8 1,4-Cyclohexanedimethanol

Cas:105-08-8

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off white powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

1,4-Cyclohexanedimethanol

Cas:105-08-8

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Cyclohex-1,4-ylenedimethanol

Cas:105-08-8

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory price Cosmetic DIMETHYLOLCYCLOHEXANE 105-08-8 Manufacturer

Cas:105-08-8

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

1,4-Cyclohexanedimethanol

Cas:105-08-8

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

Our advantage: 1: High quality and Competitive price 2: Quality control, GC&HPLC&NMR or as your requested 3: Packing as your requested, and double check before shipment 4: Prompt shipment with professional documents 5: Excellent after-

1,4-Cyclohexanedimethanol CAS NO.105-08-8

Cas:105-08-8

Min.Order:1 Kilogram

FOB Price: $1.0 / 3.0

Type:Trading Company

inquiry

Chemwill Asia Co., Ltd.

CHemwill -- 1,4-Cyclohexanedimethanol (CHDM)

Cas:105-08-8

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

105-08-8 1,4-Cyclohexanedimethanol

Cas:105-08-8

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

1,4-Cyclohexanedimethanol CAS 105-08-8

Cas:105-08-8

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 105-08-8 with best quality

Cas:105-08-8

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

1,4-CyclohexanedimethanolCAS105-08-8

Cas:105-08-8

Min.Order:1 Kilogram

FOB Price: $80.0 / 90.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name 1,4-Cyclohexanedimethanol Synonyms 1,4-Bis(hydroxymethyl)cyclohexane; CHDM CAS No. 105-08-8 EINECS 203-268-9 Molecular Formula

1,4-Cyclohexanedimethanol

Cas:105-08-8

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

1,4-cyclohexanedimethano; 1,4-bis(hydroxymethyl)cyclohexane

Cas:105-08-8

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

1,4-Cyclohexanedimethanol 105-08-8

Cas:105-08-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

professionally supply Intermediate 1,4-Cyclohexanedimethanol CAS 105-08-8

Cas:105-08-8

Min.Order:1 Kilogram

FOB Price: $21.0 / 38.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

1,4-Cyclohexanedimethanol CAS:105-08-8 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic i

1,4-Cyclohexanedimethanol CAS:105-08-8

Cas:105-08-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1,4-Cyclohexanedimethanol

Cas:105-08-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Lonwin Chemical Group Limited

1,4-Cyclohexanedimethanol CAS: 105-08-8 Specification mp 31.5 °c bp 283 °c(lit.) density 1,04 g/cm3 vapor density 5 (vs air) fp 322 °f water solubility miscible

Factory supply 1,4-Cyclohexanedimethanol

Cas:105-08-8

Min.Order:1 Kilogram

Negotiable

Type:Other

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

1,4-Cyclohexanedimethanol

Cas:105-08-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

Best price 1,4-cyclohexanedimethanol CAS NO.105-08-8

Cas:105-08-8

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

1,4-Cyclohexanedimethanol

Cas:105-08-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

1,4-cyclohexanedimethano; 1,4-bis(hydroxymethyl)cyclohexane

Cas:105-08-8

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

1,4-Cyclohexanedimethanol

Cas:105-08-8

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,4-Cyclohexanedimethanol

Cas:105-08-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

our strengths: 1: Fast and guaranteed shipment (TNT;EMS;FEDEX;DHL;UPS;EUB, special line) 2: Various payment items accepted (Btc; MoneyGram; WU) 3: Valued package (Paraffin coating; Double aluminum foil bag; Vacuum packaging) 4: Efficient delivery

Best price/In stock 1,4-Cyclohexanedimethanol 105-08-8

Cas:105-08-8

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 1,4-Cyclohexanedimethanol

Cas:105-08-8

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

1,4-cyclohexanedimethano; 1,4-bis(hydroxymethyl)cyclohexane

Cas:105-08-8

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colourless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used in polyester section, polyest

1,4-Chidm

Cas:105-08-8

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Synthetic route

cyclohexane-1,4-dicarboxylic acid
619-81-8, 619-82-9, 1076-97-7

cyclohexane-1,4-dicarboxylic acid

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

Conditions
ConditionsYield
With tin; hydrogen at 220℃; under 90009 Torr; for 0.75h; Temperature; Pressure;100%
With hydrogen In water at 230℃; under 15001.5 - 75007.5 Torr; Catalytic behavior; Reagent/catalyst; Autoclave;98.3%
With hydrogen In water at 230℃; under 63756.4 Torr; for 3h; Reagent/catalyst; Autoclave;95.8%
1,4-benzenedicarboxylic acid dimethyl ester
120-61-6

1,4-benzenedicarboxylic acid dimethyl ester

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

Conditions
ConditionsYield
With hydrogen In methanol at 200 - 240℃; under 30003 - 60006 Torr; for 8h;92%
With Cat.7; hydrogen at 180 - 250℃; under 52505.3 - 67506.8 Torr; Reagent/catalyst; Temperature; Pressure;
p-xylylene glycol
589-29-7

p-xylylene glycol

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

Conditions
ConditionsYield
With Ru/Al2O3; hydrogen In tetrahydrofuran at 60℃; under 7.50075 Torr; for 3.5h; Pressure; Autoclave;92%
Bis(2-Hydroxyethyl)terephthalat
959-26-2

Bis(2-Hydroxyethyl)terephthalat

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

Conditions
ConditionsYield
Stage #1: Bis(2-Hydroxyethyl)terephthalat With tin(II) chloride dihdyrate; ruthenium(III) chloride trihydrate; alumina; Cl6H6Pt(2-)*2H(1+)*6H2O; hydrogen In water at 180 - 260℃; under 37503.8 Torr; for 10h; Autoclave;
Stage #2: With sodium tetrahydroborate; sodium hydroxide at 500℃; for 5.5h; pH=9; Reagent/catalyst; Concentration; Temperature;
87.1%
dimethyl 1,4-cyclohexane dicarboxylate
94-60-0

dimethyl 1,4-cyclohexane dicarboxylate

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

Conditions
ConditionsYield
With C33H29FeMnN2O3P(1+)*Br(1-); potassium tert-butylate; hydrogen In isopropyl alcohol at 75℃; under 37503.8 Torr; Autoclave;86%
Stage #1: dimethyl 1,4-cyclohexane dicarboxylate With lithium aluminium tetrahydride In tetrahydrofuran at 0 - 20℃; for 0.5h;
Stage #2: With water In tetrahydrofuran
With hydrogen In methanol at 220℃; under 45004.5 Torr; Catalytic behavior; Time; Temperature; Green chemistry;
Bis(2-Hydroxyethyl)terephthalat
959-26-2

Bis(2-Hydroxyethyl)terephthalat

A

4-methylbenzoic acid ethyl ester
94-08-6

4-methylbenzoic acid ethyl ester

B

para-xylene
106-42-3

para-xylene

C

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

Conditions
ConditionsYield
With hydrogen at 170 - 260℃; under 37503.8 Torr; for 8h; Autoclave;A n/a
B n/a
C 78.4%
bis(2-hydroxyethyl) cyclohexane-1,4-dicarboxylate

bis(2-hydroxyethyl) cyclohexane-1,4-dicarboxylate

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

Conditions
ConditionsYield
With hydrogen In neat (no solvent) at 269.84℃; under 78757.9 Torr; for 10h; Reagent/catalyst; Pressure; Temperature; Autoclave;78%
ethyl 4-formylcyclohex-3-enecarboxylate

ethyl 4-formylcyclohex-3-enecarboxylate

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

Conditions
ConditionsYield
With hydrogen In water at 160℃; under 45004.5 Torr; for 12h; Reagent/catalyst;56%
Bis(2-Hydroxyethyl)terephthalat
959-26-2

Bis(2-Hydroxyethyl)terephthalat

A

4-methylbenzoic acid ethyl ester
94-08-6

4-methylbenzoic acid ethyl ester

B

para-xylene
106-42-3

para-xylene

C

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

D

C10H18O3

C10H18O3

E

C10H18O4

C10H18O4

Conditions
ConditionsYield
With hydrogen at 230℃; under 37503.8 Torr; for 8h; Autoclave;A n/a
B n/a
C 47.2%
D n/a
E n/a
Bis(2-Hydroxyethyl)terephthalat
959-26-2

Bis(2-Hydroxyethyl)terephthalat

A

4-methylbenzoic acid ethyl ester
94-08-6

4-methylbenzoic acid ethyl ester

B

para-xylene
106-42-3

para-xylene

C

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

D

(4-methylcyclohexyl)methanol
34885-03-5

(4-methylcyclohexyl)methanol

E

1,4 dimethylcyclohexane
589-90-2

1,4 dimethylcyclohexane

Conditions
ConditionsYield
With hydrogen at 260℃; under 37503.8 Torr; for 8h; Autoclave;A n/a
B n/a
C 28.5%
D n/a
E n/a
Bis(2-Hydroxyethyl)terephthalat
959-26-2

Bis(2-Hydroxyethyl)terephthalat

A

4-methylbenzoic acid ethyl ester
94-08-6

4-methylbenzoic acid ethyl ester

B

para-xylene
106-42-3

para-xylene

C

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

D

C10H18O4

C10H18O4

E

(4-methylcyclohexyl)methanol
34885-03-5

(4-methylcyclohexyl)methanol

F

1,4 dimethylcyclohexane
589-90-2

1,4 dimethylcyclohexane

Conditions
ConditionsYield
With hydrogen at 170 - 260℃; under 37503.8 Torr; for 8h; Autoclave;A n/a
B n/a
C 14.7%
D n/a
E n/a
F n/a
Bis(2-Hydroxyethyl)terephthalat
959-26-2

Bis(2-Hydroxyethyl)terephthalat

A

4-methylbenzoic acid ethyl ester
94-08-6

4-methylbenzoic acid ethyl ester

B

para-xylene
106-42-3

para-xylene

C

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

D

C10H18O4

C10H18O4

Conditions
ConditionsYield
With hydrogen at 170 - 260℃; under 37503.8 Torr; for 8h; Autoclave;A n/a
B n/a
C 5.3%
D n/a
1,4-benzenedicarboxylic acid dimethyl ester
120-61-6

1,4-benzenedicarboxylic acid dimethyl ester

A

dimethyl 1,4-cyclohexane dicarboxylate
94-60-0

dimethyl 1,4-cyclohexane dicarboxylate

B

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

C

4-methyloxymethylhydroxymethylhydroxymethylcyclohexane
62172-89-8

4-methyloxymethylhydroxymethylhydroxymethylcyclohexane

D

bis(4-hydroxymethylcyclohexyl) ether

bis(4-hydroxymethylcyclohexyl) ether

Conditions
ConditionsYield
With hydrogen; Pt1Ru5; silica gel In ethanol at 99.85℃; under 15001.2 Torr; for 8h; Product distribution; Further Variations:; Catalysts; reaction times;
1,4-benzenedicarboxylic acid dimethyl ester
120-61-6

1,4-benzenedicarboxylic acid dimethyl ester

A

dimethyl 1,4-cyclohexane dicarboxylate
94-60-0

dimethyl 1,4-cyclohexane dicarboxylate

B

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

Conditions
ConditionsYield
With hydrogen; Ru5PtSn; silica gel In ethanol at 99.85℃; under 15001.2 Torr; for 24h;
1,4-benzenedicarboxylic acid dimethyl ester
120-61-6

1,4-benzenedicarboxylic acid dimethyl ester

A

dimethyl 1,4-cyclohexane dicarboxylate
94-60-0

dimethyl 1,4-cyclohexane dicarboxylate

B

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

C

methyl 4-methyl-1-cyclohexanecarboxylate
51181-40-9

methyl 4-methyl-1-cyclohexanecarboxylate

D

(4-methylcyclohexyl)methanol
34885-03-5

(4-methylcyclohexyl)methanol

Conditions
ConditionsYield
With hydrogen; Ru5PtSn; silica gel In ethanol at 119.85℃; under 30002.4 Torr; for 8h; Further byproducts given;
With hydrogen; Ru5PtSn; silica gel In ethanol at 119.85℃; under 15001.2 Torr; for 24h; Further byproducts given;
1,4-benzenedicarboxylic acid dimethyl ester
120-61-6

1,4-benzenedicarboxylic acid dimethyl ester

A

dimethyl 1,4-cyclohexane dicarboxylate
94-60-0

dimethyl 1,4-cyclohexane dicarboxylate

B

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

C

[4-(methoxymethyl)cyclohexyl]methanol
98955-27-2

[4-(methoxymethyl)cyclohexyl]methanol

D

bis(4-hydroxymethylcyclohexyl) ether

bis(4-hydroxymethylcyclohexyl) ether

Conditions
ConditionsYield
With hydrogen; Ru5PtSn; silica gel In ethanol at 99.85℃; under 15001.2 Torr; for 24h; Product distribution; Further Variations:; Catalysts; Temperatures; Pressures;
With hydrogen; Pt1Ru5; silica gel In ethanol at 99.85℃; under 15001.2 Torr; for 24h;
terephthalic acid
100-21-0

terephthalic acid

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 6 h / 260 - 280 °C / 4535.33 Torr
2: dimethyl 1,4-cyclohexane dicarboxylate; Pd/Al2O3; hydrogen / 1 h / 200 °C / 93849.2 Torr / Autoclave
3: (4-methylcyclohexyl)methanol; hydrogen / 5 h / 250 °C / 212036 Torr
View Scheme
Stage #1: terephthalic acid With palladium on activated charcoal; hydrogen In water at 230℃; under 60006 Torr;
Stage #2: at 230℃; Pressure; Temperature; Reagent/catalyst;
100 %Chromat.
With hydrogen In water at 20 - 230℃; under 60006 Torr; Catalytic behavior; Reagent/catalyst; Inert atmosphere;
terephthalic acid 1,4-bis(4-methylcyclohexyl)methyl ester
95623-88-4

terephthalic acid 1,4-bis(4-methylcyclohexyl)methyl ester

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: dimethyl 1,4-cyclohexane dicarboxylate; Pd/Al2O3; hydrogen / 1 h / 200 °C / 93849.2 Torr / Autoclave
2: (4-methylcyclohexyl)methanol; hydrogen / 5 h / 250 °C / 212036 Torr
View Scheme
With hydrogen at 150℃; under 22502.3 Torr; Temperature; Pressure;
bis((4-methylcyclohexyl)methyl) cyclohexane-1,4-dicarboxylate
1420954-46-6

bis((4-methylcyclohexyl)methyl) cyclohexane-1,4-dicarboxylate

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

Conditions
ConditionsYield
With (4-methylcyclohexyl)methanol; hydrogen at 250℃; under 212036 Torr; for 5h;
dimethyl 1,4-cyclohexane dicarboxylate
94-60-0

dimethyl 1,4-cyclohexane dicarboxylate

A

4-hydroxymethylcyclohexanecarboxylic acid methyl ester
13380-85-3

4-hydroxymethylcyclohexanecarboxylic acid methyl ester

B

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

Conditions
ConditionsYield
With hydrogen In methanol at 220℃; under 45004.5 Torr; Green chemistry;
With hydrogen In methanol at 219.84℃; under 37503.8 Torr; Reagent/catalyst; chemoselective reaction;
With hydrogen In isopropyl alcohol at 220℃; under 75007.5 Torr; for 10h; Reagent/catalyst; Autoclave;
dimethyl 1,4-cyclohexane dicarboxylate
94-60-0

dimethyl 1,4-cyclohexane dicarboxylate

A

4-hydroxymethylcyclohexanecarboxylic acid methyl ester
13380-85-3

4-hydroxymethylcyclohexanecarboxylic acid methyl ester

B

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

C

(4-methylcyclohexyl)methanol
34885-03-5

(4-methylcyclohexyl)methanol

D

4-(hydroxymethyl)-1-cyclohexanecarboxaldehyde
92385-32-5

4-(hydroxymethyl)-1-cyclohexanecarboxaldehyde

Conditions
ConditionsYield
With hydrogen at 220℃; under 45004.5 Torr; Catalytic behavior; Reagent/catalyst; Time; Overall yield = 98.7 %;
dimethyl 1,4-cyclohexane dicarboxylate
94-60-0

dimethyl 1,4-cyclohexane dicarboxylate

A

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

B

(4-methylcyclohexyl)methanol
34885-03-5

(4-methylcyclohexyl)methanol

C

4-(hydroxymethyl)-1-cyclohexanecarboxaldehyde
92385-32-5

4-(hydroxymethyl)-1-cyclohexanecarboxaldehyde

Conditions
ConditionsYield
With hydrogen at 220℃; under 45004.5 Torr; Catalytic behavior; Reagent/catalyst; Time; Overall yield = 67.4 %;
dimethyl 1,4-cyclohexane dicarboxylate
94-60-0

dimethyl 1,4-cyclohexane dicarboxylate

A

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

B

1,4-cyclohexanedicarboxaldehyde
33424-83-8

1,4-cyclohexanedicarboxaldehyde

Conditions
ConditionsYield
With hydrogen at 180℃; under 30003 Torr; Temperature; Pressure; Concentration;
dimethyl 1,4-cyclohexane dicarboxylate
94-60-0

dimethyl 1,4-cyclohexane dicarboxylate

A

4-hydroxymethylcyclohexanecarboxylic acid methyl ester
13380-85-3

4-hydroxymethylcyclohexanecarboxylic acid methyl ester

B

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

C

(4-methylcyclohexyl)methanol
34885-03-5

(4-methylcyclohexyl)methanol

Conditions
ConditionsYield
With hydrogen In isopropyl alcohol at 220℃; under 75007.5 Torr; for 10h; Reagent/catalyst; Pressure; Autoclave;
dimethyl 1,4-cyclohexane dicarboxylate
94-60-0

dimethyl 1,4-cyclohexane dicarboxylate

A

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

B

(4-methylcyclohexyl)methanol
34885-03-5

(4-methylcyclohexyl)methanol

Conditions
ConditionsYield
With hydrogen In isopropyl alcohol at 220℃; under 75007.5 Torr; for 10h; Reagent/catalyst; Pressure; Autoclave;
L-leucine
61-90-5

L-leucine

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

L,L-leucine 1,4-cyclohexanedimethanol diester
893447-84-2

L,L-leucine 1,4-cyclohexanedimethanol diester

Conditions
ConditionsYield
Stage #1: L-leucine; bis-1,4-(hydroxymethyl)cyclohexane With toluene-4-sulfonic acid In toluene at 150℃; for 30h; Heating / reflux;
Stage #2: With sodium hydrogencarbonate In water; toluene at 60℃;
100%
L-leucine
61-90-5

L-leucine

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

L,L-leucine 1,4-cyclohexanedimethanol diester
893447-84-2

L,L-leucine 1,4-cyclohexanedimethanol diester

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene at 20 - 150℃; for 30h; Heating / reflux;100%
bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

acetic anhydride
108-24-7

acetic anhydride

1,4-cyclohexanedimethylene diacetate
6308-18-5

1,4-cyclohexanedimethylene diacetate

Conditions
ConditionsYield
With pyridine at 125℃; for 3.5h; Reagent/catalyst; Large scale;99%
With pyridine at 125℃; for 3.5h; Large scale;99%
5-Norbornene-2-carboxaldehyde
5453-80-5, 19926-90-0

5-Norbornene-2-carboxaldehyde

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

5-norbornene-2-(4-hydroxymethyl)cyklohexylmethoxymethanol

5-norbornene-2-(4-hydroxymethyl)cyklohexylmethoxymethanol

Conditions
ConditionsYield
sodium hydride at 20℃; for 10h;93%
bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

7-oxa-bicyclo[2.2.1]hept-5-ene-2-carbaldehyde
59274-95-2

7-oxa-bicyclo[2.2.1]hept-5-ene-2-carbaldehyde

oxabicyclo[2.2.1]-hept-5-ene-2-(4-hydroxymethyl)cyclohexylmethoxy methanol

oxabicyclo[2.2.1]-hept-5-ene-2-(4-hydroxymethyl)cyclohexylmethoxy methanol

Conditions
ConditionsYield
sodium hydride at 20℃; for 10h;93%
bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

aniline
62-53-3

aniline

C20H26N2
1352050-49-7

C20H26N2

Conditions
ConditionsYield
With Pt-Sn/γ-Al2O3 In o-xylene at 145℃; for 24h; Inert atmosphere;93%
bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

cyclohexane-1,4-dimethyl chloride
824-93-1

cyclohexane-1,4-dimethyl chloride

Conditions
ConditionsYield
With pyridine; thionyl chloride Chlorination; Heating;92%
bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

phenyl chloroformate
1885-14-9

phenyl chloroformate

1,4-cyclohexanedimethanol diphenyl dicarbonate
22563-70-8

1,4-cyclohexanedimethanol diphenyl dicarbonate

Conditions
ConditionsYield
With pyridine; dmap In tetrahydrofuran at 0 - 20℃;90.2%
2-Isocyanatoethyl methacrylate
30674-80-7

2-Isocyanatoethyl methacrylate

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

C15H25NO5

C15H25NO5

Conditions
ConditionsYield
With dibutyltin dilaurate In toluene for 5h;90.1%
bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

acetyl chloride
75-36-5

acetyl chloride

1,4-cyclohexanedimethylene diacetate
6308-18-5

1,4-cyclohexanedimethylene diacetate

Conditions
ConditionsYield
With pyridine; dmap In chloroform at 0 - 20℃;87%
bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

(R)-1-C-(1-Cyclohexen-5-yl)carbaldehyde
60631-76-7

(R)-1-C-(1-Cyclohexen-5-yl)carbaldehyde

cyclohexylmethyl alcohol
100-49-2

cyclohexylmethyl alcohol

acetal oligomer

acetal oligomer

Conditions
ConditionsYield
With N,N-dimethyl acetamide; toluene-4-sulfonic acid at 140℃; for 20h;85%
bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

chlorophosphoric acid diphenyl ester
2524-64-3

chlorophosphoric acid diphenyl ester

1,4-cyclohexanedimethanol bis(diphenyl phosphate)
476371-27-4

1,4-cyclohexanedimethanol bis(diphenyl phosphate)

Conditions
ConditionsYield
With magnesium chloride In methanol; hexane82.2%
bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

C17H20O5
1033761-69-1

C17H20O5

C42H52O10

C42H52O10

Conditions
ConditionsYield
With dmap; 2,6-di-tert-butyl-4-methyl-phenol; dicyclohexyl-carbodiimide In dichloromethane at 20℃; for 48h;81%
bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

cyclohexane-1,4-dicarbonitrile
10534-13-1

cyclohexane-1,4-dicarbonitrile

Conditions
ConditionsYield
With 1,10-Phenanthroline; ammonia; oxygen In 1,4-dioxane at 30 - 60℃; under 3750.38 Torr; for 12h; Pressure; Temperature; Reagent/catalyst; Solvent;80.5%
maleic anhydride
108-31-6

maleic anhydride

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

(Z)-2-butenedioic-acid-1,4-cyclohexanediylbis(methylene) ester
551929-43-2

(Z)-2-butenedioic-acid-1,4-cyclohexanediylbis(methylene) ester

Conditions
ConditionsYield
In acetonitrile at 50℃; for 72h;80%
In acetonitrile at 50℃; for 72h;80%
4-(hydroxymethyl)cyclohexane-1-carboxylic acid
13380-84-2

4-(hydroxymethyl)cyclohexane-1-carboxylic acid

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

[4-(hydroxymethyl)cyclohexyl]methyl 4-(hydroxymethyl)cyclohexane-1-carboxylate

[4-(hydroxymethyl)cyclohexyl]methyl 4-(hydroxymethyl)cyclohexane-1-carboxylate

Conditions
ConditionsYield
Stage #1: bis-1,4-(hydroxymethyl)cyclohexane With dmap; dicyclohexyl-carbodiimide In dimethyl sulfoxide at 20℃; for 0.5h;
Stage #2: 4-(hydroxymethyl)cyclohexane-1-carboxylic acid In dimethyl sulfoxide at 20℃; for 5h;
80%
Stage #1: bis-1,4-(hydroxymethyl)cyclohexane With dmap; dicyclohexyl-carbodiimide In dimethyl sulfoxide at 20℃; for 0.5h;
Stage #2: 4-(hydroxymethyl)cyclohexane-1-carboxylic acid In dimethyl sulfoxide at 20℃; for 5h;
80%
bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

2-(diphenylmethoxy)-pyridine

2-(diphenylmethoxy)-pyridine

(4-(benzhydryloxymethyl)cyclohexyl)methanol

(4-(benzhydryloxymethyl)cyclohexyl)methanol

Conditions
ConditionsYield
With iron(III) chloride In 1,2-dichloro-ethane at 70℃; for 10h;78%
bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

(4-chlorophenyl)(phenyl)carbamic chloride
1187856-44-5

(4-chlorophenyl)(phenyl)carbamic chloride

(4-(hydroxymethyl)cyclohexyl)methyl (4-chlorophenyl)(phenyl)carbamate

(4-(hydroxymethyl)cyclohexyl)methyl (4-chlorophenyl)(phenyl)carbamate

Conditions
ConditionsYield
With pyridine at 120℃; for 18h;78%
bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

1,5-dioxa-3,3-bis(ethoxycarbonyl)-8,8,10,10-tetramethyl-9-azaspiro<5.5>undecane
110844-29-6

1,5-dioxa-3,3-bis(ethoxycarbonyl)-8,8,10,10-tetramethyl-9-azaspiro<5.5>undecane

8,8,10,10-Tetramethyl-1,5-dioxa-9-azaspiro-[5.5]undecane-3,3-dicarboxylic acid
110839-53-7

8,8,10,10-Tetramethyl-1,5-dioxa-9-azaspiro-[5.5]undecane-3,3-dicarboxylic acid

Conditions
ConditionsYield
In dichloromethane; acetic acid77%
Isopropenyl acetate
108-22-5

Isopropenyl acetate

bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

A

1,4-cyclohexanedimethylene diacetate
6308-18-5

1,4-cyclohexanedimethylene diacetate

B

diisopropenyl 1,4-cyclohexanedimethanol ether

diisopropenyl 1,4-cyclohexanedimethanol ether

C

C13H22O3

C13H22O3

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; sodium carbonate In toluene at 100℃; for 6h;A n/a
B 75%
C n/a
bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

trans-1,4-Cyclohexanedimethanol
3236-48-4

trans-1,4-Cyclohexanedimethanol

Conditions
ConditionsYield
With Ni/NiO-diatomite at 200℃; for 3h; Reagent/catalyst; Autoclave; Inert atmosphere;72.6%
Multi-step reaction with 2 steps
1: 52.1 percent / 140 - 165 °C
2: 46.3 percent / aq. NaOH / 10 h / Heating
View Scheme
bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

[4-(p-toluenesulfonyloxymethyl)cyclohexyl]methanol
109004-13-9

[4-(p-toluenesulfonyloxymethyl)cyclohexyl]methanol

Conditions
ConditionsYield
With pyridine; dmap; triethylamine In dichloromethane at 20℃; for 3h;72%
In pyridine at 20℃; for 36h;61%
With pyridine In dichloromethane186 g
bis-1,4-(hydroxymethyl)cyclohexane
105-08-8

bis-1,4-(hydroxymethyl)cyclohexane

ethyl 3-diazoindole-2-carboxylate
89607-68-1

ethyl 3-diazoindole-2-carboxylate

3-(4-hydroxymethyl-cyclohexylmethoxy)-3H-indole-2-carboxylic acid ethyl ester

3-(4-hydroxymethyl-cyclohexylmethoxy)-3H-indole-2-carboxylic acid ethyl ester

Conditions
ConditionsYield
dirhodium tetraacetate In dichloromethane at 85℃; for 3h; Substitution; O-H insertation;72%
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