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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem’s R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantiti

2-(4-Bromomethyl)phenylpropionic acid

Cas:111128-12-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 4-Bromomethyl Phenyl Propionic Acid supplier in China

Cas:111128-12-2

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com/pro01en/id/1072.html Product Name 2-(4-Bromomethyl)phenylpropionic acid CAS No.

2-(4-Bromomethyl)phenylpropionic acid

Cas:111128-12-2

Min.Order:1 Gram

FOB Price: $66.0

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

2-[4-(Bromomethyl)phenyl]propinic acid CAS No.: 111128-12-2 CAS Number: 111128-12-2 Name: 2-(4-Bromomethyl)phenylpropionic acid Formula: C10H11BrO2 Molecular Weight: 243.10 Synonyms: 2-[p-(Bromomethyl)phenyl]propionicacid;Benzen

CAS:111128-12-2 Phenacetin2-(4-Bromomethyl)phenylpropionic acid

Cas:111128-12-2

Min.Order:1 Kilogram

Negotiable

Type:Other

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Wuhan Fortuna Chemical Co.,Ltd

Unique advantages of 2-(4-Bromomethyl)phenylpropionic acid Cas 111128-12-2 Guaranteed purity High quality & competitive price Quality control Fast feedback Prompt shipment Appearance:White to off-white crystalline powder Storage:cool dry pla

Manufacturer high quality 2-(4-Bromomethyl)phenylpropionic acid Cas 111128-12-2 with good price

Cas:111128-12-2

Min.Order:25 Kilogram

Negotiable

Type:Trading Company

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Hangzhou Think Chemical Co. Ltd

2-(4-Bromomethyl)phenylpropionic acid CAS No.:111128-12-2 Name: 2-(4-Bromomethyl)phenylpropionic acid Molecular Structure: Molecular Formula: C10H11BrO2 Molecular

High purity 2-(4-Bromomethyl)phenylpropionic acid CAS No.:111128-12-2

Cas:111128-12-2

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Other

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 4-Bromomethyl Phenyl Propionic Acid

Cas:111128-12-2

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality Oled CAS 111128-12-2 2-(4-Bromomethyl)phenylpropionic acid

Cas:111128-12-2

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

2-[4-(Bromomethyl)Phenyl]Propanoic Acid

Cas:111128-12-2

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co., LTD is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low carb

2-[4-(Bromomethyl)phenyl]propinic acid

Cas:111128-12-2

Min.Order:1 Kilogram

FOB Price: $1.0 / 3.0

Type:Trading Company

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Chemwill Asia Co., Ltd.

2-(4-Bromomethyl)phenylpropionic acid CAS 111128-12-2 4-Bromomethyl Phenyl Propionic Acid CAS no 111128-12-2 4-(BROMOMETHYL)HYDRATROPIC ACID 2-(4-Bromomethyl)phenylpropionic acide CAS 111128-12-2 4-Bromomethyl Phenyl Propionic Acid IN Stock CAS

Hubei DiBo chemical co., LTD

2-(4-bromomethyl) phenylpropionic acid high quality spot supply, low price and rapid delivery Chinese Name: 2-(4-bromomethyl) phenylpropionic acid Chinese aliases: p-bromomethylphenylpropionic acid; 2-(4-bromomethylphenyl) propionic acid; loxopro

Loxoprofen/Loxoprofen Acid/Cas: 111128-12-2 /99.10% High purity

Cas:111128-12-2

Min.Order:1 Metric Ton

FOB Price: $6.0 / 9.0

Type:Other

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Henan Tianfu Chemical Co., Ltd.

TIANFUCHEM--111128-12-2--2-(4-Bromomethyl)phenylpropionic acid factory price Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established s

TIANFUCHEM--111128-12-2--2-(4-Bromomethyl)phenylpropionic acid factory price

Cas:111128-12-2

Min.Order:1 Metric Ton

FOB Price: $2000.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu

Bmppa 2- (4-Bromomethyl) Phenylpropionic Acid CAS 111128-12-2

Cas:111128-12-2

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 111128-12-2 with fast shipping

Cas:111128-12-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by email in time prod

2-(4-Bromomethyl)phenylpropionic acid

Cas:111128-12-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Sinotech Import&Export Corporation

Product Name: 2-(4-Bromomethyl)phenylpropionic acid Chemical Name: 2-(4-Bromomethyl)phenylpropionic acid CAS No.: 111128-12-2 Molecular Formula: C10H11BrO2 Molecular Weight: 243.09714 Appearance:White powder Storage:RT

2-(4-Bromomethyl)phenylpropionic acid

Cas:111128-12-2

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:Beige-cream crystalline powder Storage:Store in sealed conta

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2-(4-Bromomethyl)phenylpropionic acid 111128-12-2

Cas:111128-12-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd. established since 2009 , has been always focusing on supplying products and services to our clients in the field of small molecule drug. Huarong Pharm has built platforms for the research, development and manufac

2-(4-Bromomethyl)phenylpropionic acid

Cas:111128-12-2

Min.Order:1 Gram

FOB Price: $1.0 / 2.0

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

2-(4-BROMOMETHYL)PHENYLPROPIONIC ACID CAS: 111128-12-2

Cas:111128-12-2

Min.Order:1 Kilogram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

2-(4-Bromomethyl)phenylpropionic acid CAS:111128-12-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high q

2-(4-Bromomethyl)phenylpropionic acid CAS:111128-12-2

Cas:111128-12-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Changchun Artel lmport and Export trade company

Superiority We can customize and synthesize products that other suppliers may not be able to provide. Advantage cof, mof ligand manufacturer Product Detail bes

factory supply 99% 2-(4-BroMoMethyl-phenyl)-propionic acid CAS:111128-12-2

Cas:111128-12-2

Min.Order:100 Kilogram

Negotiable

Type:Trading Company

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Hebei Mojin Biotechnology Co.,Ltd

Hebei Mojin Biotechnology Co., Ltd, Our company is a professional chemical raw materials and chemical reagents research and development production enterprises. We have several production line,So we can control the lowest price. We also have several

2-(4-Bromomethyl)phenylpropionic acid cas:111128-12-2

Cas:111128-12-2

Min.Order:25 Gram

FOB Price: $90.0 / 100.0

Type:Trading Company

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Lonwin Chemical Group Limited

2-(4-Bromomethyl)phenylpropionic acid(BMPPA) CAS: 111128-12-2 Specification Item Standard Identification A.H-NMR:Comply with the structure B.LC-MS:Comply with the structure

Factory supply 2-(4-Bromomethyl)phenylpropionic acid(BMPPA)

Cas:111128-12-2

Min.Order:1 Kilogram

Negotiable

Type:Other

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

2-(4-Bromomethyl)phenylpropionic acid

Cas:111128-12-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Wuhan Zenuo Biological Medicine Technology Co Ltd

2-(4-Bromomethyl)phenylpropionic acid Product Name: 2-(4-Bromomethyl)phenylpropionic acid Synonyms: 4-(BROMOMETHYL)HYDRATROPIC ACID;2-[4-(BROMOMETHYL)PHENYL]PROPANOIC ACID;2-[4-(BROMOMETHYL)PHENYL]PROPIONIC ACID;2-[(P-BROMOMETHYL)PHENYL]PROPION

2-(4-Bromomethyl)phenylpropionic acid Manufactuered in China best quality

Cas:111128-12-2

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

4-Bromomethyl Phenyl Propionic Acid

Cas:111128-12-2

Min.Order:0

Negotiable

Type:Manufacturers

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

2-(4-Bromomethyl)phenylpropionic acid CAS 111128-12-2

Cas:111128-12-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-[4-(bromomethyl)phenyl]propanoic acid

Cas:111128-12-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Synthetic route

formaldehyd
50-00-0

formaldehyd

hydratropic acid
492-37-5, 2328-24-7

hydratropic acid

2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

Conditions
ConditionsYield
With sulfuric acid; hydrogen bromide at 35 - 70℃; for 11h; Temperature;99%
With sulfuric acid; hydrogen bromide at 35 - 90℃; for 11.5h; Temperature;96%
Stage #1: formaldehyd; hydratropic acid With hydrogen bromide at 55 - 65℃;
Stage #2: With sulfuric acid at 20 - 65℃;
96%
(R,S)-2-(4'-methylphenyl) propionic acid
938-94-3

(R,S)-2-(4'-methylphenyl) propionic acid

2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

Conditions
ConditionsYield
With bromine; dibenzoyl peroxide In dichloromethane Reflux;92%
With bromine; dibenzoyl peroxide In dichloromethane at 40℃; for 0.0416667h; Temperature;90%
With hydrogen bromide; bromine In ethyl acetate at 20℃; for 2h;79%
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In dichloromethane Solvent; Reflux;42.05 g
With hydrogen bromide; dihydrogen peroxide; dibenzoyl peroxide In dichloromethane at 10 - 15℃; Irradiation;
C10H10Br2O2

C10H10Br2O2

2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide; phosphonic acid diethyl ester In water; toluene at 5 - 85℃; for 6h; Reagent/catalyst; Inert atmosphere;85.3%
trioxane
188680-60-6

trioxane

hydratropic acid
492-37-5, 2328-24-7

hydratropic acid

cetyltrimethylammonim bromide
57-09-0

cetyltrimethylammonim bromide

2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

Conditions
ConditionsYield
With hydrogen bromide; acetic acid
With hydrogen bromide; acetic acid
sodium 2-phenyl-2-cyanopropionate

sodium 2-phenyl-2-cyanopropionate

2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: toluene / 3 h / 35 - 75 °C
2.1: sodium hydroxide / 1 h / 80 °C
3.1: sodium hydroxide / 12.5 h / 105 °C / Reflux
3.2: 0.58 h / pH 3
4.1: sulfuric acid; hydrogen bromide / 11.5 h / 35 - 90 °C
View Scheme
phenylacetonitrile
140-29-4

phenylacetonitrile

2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1.1: sodium methylate / methanol; toluene / 10 h / 20 °C
2.1: toluene / 3 h / 35 - 75 °C
3.1: sodium hydroxide / 1 h / 80 °C
4.1: sodium hydroxide / 12.5 h / 105 °C / Reflux
4.2: 0.58 h / pH 3
5.1: sulfuric acid; hydrogen bromide / 11.5 h / 35 - 90 °C
View Scheme
Multi-step reaction with 3 steps
1: potassium carbonate / 15 h / 250 °C / 30003 Torr / Autoclave
2: sodium hydroxide; water / 8 h / 40 °C
3: sulfuric acid; hydrogen bromide / 11 h / 35 - 70 °C
View Scheme
2-methoxycarbonyl-2-phenylpropionitrile
79341-72-3

2-methoxycarbonyl-2-phenylpropionitrile

2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: sodium hydroxide / 1 h / 80 °C
2.1: sodium hydroxide / 12.5 h / 105 °C / Reflux
2.2: 0.58 h / pH 3
3.1: sulfuric acid; hydrogen bromide / 11.5 h / 35 - 90 °C
View Scheme
CH3C6H4CH(CH3)OH
536-50-5

CH3C6H4CH(CH3)OH

2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: triethylamine; calcium chloride / dichloromethane / 40 h
2: dimethyl sulfoxide / 18 h / 90 °C / Reflux
3: hydrogenchloride / 1 h / Reflux
4: hydrogen bromide; bromine / ethyl acetate / 2 h / 20 °C
View Scheme
Multi-step reaction with 4 steps
1: thionyl chloride / toluene / Reflux
2: tetrabutylammomium bromide / toluene; water / 8 h / 60 - 70 °C
3: sodium hydroxide / 100 - 105 °C
4: dibenzoyl peroxide; bromine / dichloromethane / Reflux
View Scheme
1-(4-methylphenyl)ethyl 4-methylbenzenesulfonate
82925-34-6

1-(4-methylphenyl)ethyl 4-methylbenzenesulfonate

2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: dimethyl sulfoxide / 18 h / 90 °C / Reflux
2: hydrogenchloride / 1 h / Reflux
3: hydrogen bromide; bromine / ethyl acetate / 2 h / 20 °C
View Scheme
para-methylacetophenone
122-00-9

para-methylacetophenone

2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: sodium tetrahydroborate / methanol
2: triethylamine; calcium chloride / dichloromethane / 40 h
3: dimethyl sulfoxide / 18 h / 90 °C / Reflux
4: hydrogenchloride / 1 h / Reflux
5: hydrogen bromide; bromine / ethyl acetate / 2 h / 20 °C
View Scheme
Multi-step reaction with 5 steps
1: sodium tetrahydroborate / methanol / 15 - 35 °C
2: thionyl chloride / toluene / Reflux
3: tetrabutylammomium bromide / toluene; water / 8 h / 60 - 70 °C
4: sodium hydroxide / 100 - 105 °C
5: dibenzoyl peroxide; bromine / dichloromethane / Reflux
View Scheme
(+/-)-2-(4'-methylphenyl)-propionitrile
75920-45-5

(+/-)-2-(4'-methylphenyl)-propionitrile

2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: hydrogenchloride / 1 h / Reflux
2: hydrogen bromide; bromine / ethyl acetate / 2 h / 20 °C
View Scheme
1-(1-chloroethyl)-4-methylbenzene
2362-36-9

1-(1-chloroethyl)-4-methylbenzene

2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: magnesium / tetrahydrofuran / 1.5 h / 20 - 30 °C / Inert atmosphere
2: N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) / dichloromethane / Reflux
View Scheme
Multi-step reaction with 2 steps
1.1: magnesium / tetrahydrofuran; ethylene dibromide / 13 h / 60 - 65 °C / Inert atmosphere
1.2: 20 - 25 °C
2.1: bromine; 2,2'-azobis(isobutyronitrile) / dichloromethane / 40 - 55 °C / Inert atmosphere
View Scheme
Multi-step reaction with 3 steps
1.1: magnesium / tetrahydrofuran; ethylene dibromide / 13 h / 60 - 65 °C / Inert atmosphere
1.2: 20 - 25 °C
2.1: bromine; 2,2'-azobis(isobutyronitrile) / dichloromethane / 40 - 55 °C / Inert atmosphere
3.1: tetra-(n-butyl)ammonium iodide; phosphonic acid diethyl ester / water; toluene / 6 h / 5 - 85 °C / Inert atmosphere
View Scheme
Multi-step reaction with 3 steps
1: tetrabutylammomium bromide / toluene; water / 8 h / 60 - 70 °C
2: sodium hydroxide / 100 - 105 °C
3: dibenzoyl peroxide; bromine / dichloromethane / Reflux
View Scheme
1-ethenyl-4-methylbenzene
622-97-9

1-ethenyl-4-methylbenzene

2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: hydrogenchloride / water / 6 h / 65 - 70 °C / Inert atmosphere
2.1: magnesium / tetrahydrofuran; ethylene dibromide / 13 h / 60 - 65 °C / Inert atmosphere
2.2: 20 - 25 °C
3.1: bromine; 2,2'-azobis(isobutyronitrile) / dichloromethane / 40 - 55 °C / Inert atmosphere
View Scheme
Multi-step reaction with 3 steps
1: hydrogen bromide / 5 h / 60 - 65 °C / Inert atmosphere
2: magnesium / tetrahydrofuran; ethylene dibromide / 55 - 65 °C
3: bromine; 2,2'-azobis(isobutyronitrile) / dichloromethane / 40 - 55 °C / Inert atmosphere
View Scheme
Multi-step reaction with 4 steps
1.1: hydrogenchloride / water / 6 h / 65 - 70 °C / Inert atmosphere
2.1: magnesium / tetrahydrofuran; ethylene dibromide / 13 h / 60 - 65 °C / Inert atmosphere
2.2: 20 - 25 °C
3.1: bromine; 2,2'-azobis(isobutyronitrile) / dichloromethane / 40 - 55 °C / Inert atmosphere
4.1: tetra-(n-butyl)ammonium iodide; phosphonic acid diethyl ester / water; toluene / 6 h / 5 - 85 °C / Inert atmosphere
View Scheme
Multi-step reaction with 4 steps
1: hydrogen bromide / 5 h / 60 - 65 °C / Inert atmosphere
2: magnesium / tetrahydrofuran; ethylene dibromide / 55 - 65 °C
3: bromine; 2,2'-azobis(isobutyronitrile) / dichloromethane / 40 - 55 °C / Inert atmosphere
4: tetra-(n-butyl)ammonium iodide; phosphonic acid diethyl ester / water; toluene / 6 h / 5 - 85 °C / Inert atmosphere
View Scheme
1-(1-bromoethyl)-4-methylbenzene
159755-12-1

1-(1-bromoethyl)-4-methylbenzene

2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: magnesium / tetrahydrofuran; ethylene dibromide / 55 - 65 °C
2: bromine; 2,2'-azobis(isobutyronitrile) / dichloromethane / 40 - 55 °C / Inert atmosphere
View Scheme
Multi-step reaction with 3 steps
1: magnesium / tetrahydrofuran; ethylene dibromide / 55 - 65 °C
2: bromine; 2,2'-azobis(isobutyronitrile) / dichloromethane / 40 - 55 °C / Inert atmosphere
3: tetra-(n-butyl)ammonium iodide; phosphonic acid diethyl ester / water; toluene / 6 h / 5 - 85 °C / Inert atmosphere
View Scheme
(R,S)-2-(4'-methylphenyl) propionic acid
938-94-3

(R,S)-2-(4'-methylphenyl) propionic acid

A

2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

B

C10H10Br2O2

C10H10Br2O2

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile); bromine In dichloromethane at 40 - 55℃; Solvent; Reagent/catalyst; Temperature; Inert atmosphere;
styrene
292638-84-7

styrene

2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: hydrogenchloride / dichloromethane / 5 h / 10 - 20 °C
2.1: magnesium / 2-methyltetrahydrofuran / 5 h / 20 - 30 °C
2.2: 5 h / 20 - 30 °C
3.1: sulfuric acid; hydrogen bromide / 3 h / 50 - 120 °C
View Scheme
methanol
67-56-1

methanol

2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

2-(4-bromomethylphenyl)propionic acid methyl ester
99807-54-2

2-(4-bromomethylphenyl)propionic acid methyl ester

Conditions
ConditionsYield
In 2,2,4-trimethylpentane at 65℃; for 0.5h; Solvent; Temperature;99.7%
Stage #1: methanol With sulfuric acid In toluene at 35℃;
Stage #2: 2-[4-(bromomethyl)phenyl]propanoic acid In toluene at 281℃; for 5h;
98.7%
With sulfuric acid at 0 - 5℃; for 6h;98%
2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

ethanol
64-17-5

ethanol

ethyl 2-(4-bromomethylphenyl)propanoate

ethyl 2-(4-bromomethylphenyl)propanoate

Conditions
ConditionsYield
In toluene at 79℃; for 0.333333h; Time;97.8%
2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

2-(4-(azidomethyl)phenyl)propanoic acid

2-(4-(azidomethyl)phenyl)propanoic acid

Conditions
ConditionsYield
With sodium azide In N,N-dimethyl-formamide at 20℃; Inert atmosphere;96%
With sodium azide; 15-crown-5 In 1,4-dioxane at 80℃; for 16h;
With sodium azide In N,N-dimethyl-formamide at 100℃; for 12h; Temperature; Inert atmosphere;
With sodium azide In N,N-dimethyl-formamide at 100℃; for 12h; Inert atmosphere;
2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

1-hydroxy-pyrrolidine-2,5-dione
6066-82-6

1-hydroxy-pyrrolidine-2,5-dione

triphenylphosphine
603-35-0

triphenylphosphine

[4-(methyl)phenyl-2-propionyl-N-succinimido]-triphenylphosphonium bromide

[4-(methyl)phenyl-2-propionyl-N-succinimido]-triphenylphosphonium bromide

Conditions
ConditionsYield
With dicyclohexyl-carbodiimide In acetonitrile at 20℃; for 16h;94.9%
2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

2-ethoxycarbonyl-1-cyclopentanone
611-10-9

2-ethoxycarbonyl-1-cyclopentanone

sodium 2-<4-<(2-oxocyclopentyl)methyl>phenyl>propionate
80382-23-6

sodium 2-<4-<(2-oxocyclopentyl)methyl>phenyl>propionate

Conditions
ConditionsYield
Stage #1: 2-[4-(bromomethyl)phenyl]propanoic acid; 2-ethoxycarbonyl-1-cyclopentanone With sodium hydroxide In N,N-dimethyl-formamide under 760.051 Torr; for 8h;
Stage #2: With hydrogenchloride In water; N,N-dimethyl-formamide pH=5 - 6; Further stages;
92%
2-methyl-1-buten-4-ol
763-32-6

2-methyl-1-buten-4-ol

2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

C15H19BrO2

C15H19BrO2

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 23℃; Inert atmosphere;87%
2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

dimethylmonochlorosilane
1066-35-9

dimethylmonochlorosilane

diethyl ether
60-29-7

diethyl ether

hexane I ethyl acetate

hexane I ethyl acetate

2-[(4-dimethylsilylmethyl)phenyl]propionic acid
1096356-08-9

2-[(4-dimethylsilylmethyl)phenyl]propionic acid

Conditions
ConditionsYield
With triethylamine In (2S)-N-methyl-1-phenylpropan-2-amine hydrate85%
2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

1H-[1,2,4]triazole-3-thiol
3179-31-5

1H-[1,2,4]triazole-3-thiol

2-(4-(((1H-1,2,4-triazol-3-yl)thio)methyl)phenyl)propanoic acid

2-(4-(((1H-1,2,4-triazol-3-yl)thio)methyl)phenyl)propanoic acid

Conditions
ConditionsYield
In acetone at 40℃; for 12h; Reflux;85%
2-(4-(bromomethyl)phenyl)propanoic acid
111128-12-2

2-(4-(bromomethyl)phenyl)propanoic acid

5-chloro-2-mercaptobenzothiazole
5331-91-9

5-chloro-2-mercaptobenzothiazole

2-(4-(((5-chlorobenzo[d]thiazol-2-yl)thio)methyl)phenyl)propanoic acid

2-(4-(((5-chlorobenzo[d]thiazol-2-yl)thio)methyl)phenyl)propanoic acid

Conditions
ConditionsYield
In acetone at 40℃; for 12h; Reflux;85%

Raw Materials

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