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Henan Allgreen Chemical Co.,Ltd

T he company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality service Appearance:white pow

HEXAFLUOROCYCLOTRIPHOSPHAZENE

Cas:15599-91-4

Min.Order:1 Gram

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Hexafluorocyclotriphosphazene Manufacturer Factory CAS 15599-91-4 Hexafluorocyclotriphosphazene Manufacturer High quality Best price In stock factory CAS 15599-91-4 Hexafluorocyclotriphosphazene COA TDS price MSDS Name Phosphonitrili

Hexafluorocyclotriphosphazene Manufacturer Factory CAS 15599-91-4

Cas:15599-91-4

Min.Order:5 Kiloliter

FOB Price: $3.5 / 5.0

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis

HEXAFLUOROCYCLOTRIPHOSPHAZENE

Cas:15599-91-4

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

HEXAFLUOROCYCLOTRIPHOSPHAZENE CAS 15599-91-4

Cas:15599-91-4

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 15599-91-4 with competitive price

Cas:15599-91-4

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name: Phosphonitrilic fluoride trimer Synonyms: 1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexafluoro-2,2,4,4,6,6,-hexahydro- CAS:15599-91-4 MF: F6N3P3 Appearance: white powder Storage:Store in cool and dry place, away from sun light. Package

Phosphonitrilic fluoride trimer

Cas:15599-91-4

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Qingdao Beluga Import and Export Co., LTD

HEXAFLUOROCYCLOTRIPHOSPHAZENE CAS:15599-91-4 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality or

HEXAFLUOROCYCLOTRIPHOSPHAZENE CAS:15599-91-4

Cas:15599-91-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

1,3,5,2,4,6-Triazatriphosphorine,2,2,4,4,6,6-hexafluoro-2,2,4,4,6,6-hexahydro-

Cas:15599-91-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Triumph International Development Limilted

Appearance:white powder without visible impurities Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:It is used as a sensitive reagent and rubber promoter for deposi

phosphonitrilic fluoride trimer

Cas:15599-91-4

Min.Order:100 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

Hexafluorocyclotriphosphazene

Cas:15599-91-4

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

HEXAFLUOROCYCLOTRIPHOSPHAZENE

Cas:15599-91-4

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Tianfu Chemical, built in 2009, is a professional supplier for API materials in China. With 10 years development, we have bulit our own factory and lab to produce a certain of products. And we have established stable business relationship

TIANFU CHEM 15599-91-4 HEXAFLUOROCYCLOTRIPHOSPHAZENE

Cas:15599-91-4

Min.Order:1 Kilogram

FOB Price: $200.0

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

HEXAFLUOROCYCLOTRIPHOSPHAZENE

Cas:15599-91-4

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Hexafluorocyclotriphosphazene

Cas:15599-91-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Hexafluorocyclotriphosphazene 5g

Cas:15599-91-4

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

HEXAFLUOROCYCLOTRIPHOSPHAZENE

Cas:15599-91-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Finebiotech Co.,Ltd.

Shanghai Finebiotech Co.,Ltd.was established in 2020, which providing professional chemical services. As a customer-oriented company, we have distinguished ourself from others in providing worldwide customers with cost-effective and efficient service

Phosphonitrilic fluoride trimer

Cas:15599-91-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

phosphonitrilic fluoride trimer

Cas:15599-91-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

factory?direct?sale Application:healing drugs

1,3,5,2,4,6-Triazatriphosphorine,2,2,4,4,6,6-hexafluoro-2,2,4,4,6,6-hexahydro-

Cas:15599-91-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Guangdong Juda Chemical Industrial Co.,Limited

Appearance:solid or liquid Storage:sealed in cool and dry place Package:As customer's requested Application:Pharma Intermediate Transportation:by courier/air/sea Port:Any port in China

HEXAFLUOROCYCLOTRIPHOSPHAZENE CAS No.15599-91-4

Cas:15599-91-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as primary and sec

PHOSPHONITRILIC FLUORIDE TRIMER, 99%

Cas:15599-91-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

1,3,5,2,4,6-Triazatriphosphorine,2,2,4,4,6,6-hexafluoro-2,2,4,4,6,6-hexahydro-Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Chemlyte Solutions

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Hexafluorocyclotriphosphazene

Cas:15599-91-4

Min.Order:0

Negotiable

Type:Other

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

HEXAFLUOROCYCLOTRIPHOSPHAZENE

Cas:15599-91-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Hexafluorocyclotriphosphazene

Cas:15599-91-4

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Toda Biotechnology Co., Limited.

Todachem specialize in exporting chemicals for 10 years, we manufacture and distribute high quality pharmaceutical APIs, intermediates, special chemicals, active molecule and other fine chemicals. We have our research laboratory and more than 100 n

Factory direct supply HEXAFLUOROCYCLOTRIPHOSPHAZENE with best quality

Cas:15599-91-4

Min.Order:1 Kilogram

FOB Price: $90.0 / 100.0

Type:Trading Company

inquiry

Nanjing Chemlin Chemical Co., Ltd.

Compound sourcing ServicesAgency of testing serviceFactory audit serviceFounded in Dec. 1999, Nanjing Chemlin Chemical Industrial Co.,Ltd(CHEMLIN) has been covering the business scope from trading of chemicals to custom-synthesis & Manufacturing. Co

15599-91-4

Cas:15599-91-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Share Chemical Co., Ltd

At Share Chemical Company, we scrupulously abide by our policy of “Excellent Quality at a Reasonable Price”. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi

HEXAFLUOROCYCLOTRIPHOSPHAZENE

Cas:15599-91-4

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Nanjing Norris Pharm Technology Co., Ltd.

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Port:Shanghai;Guangzhou

1,2,3,4,4,6-hexafluoro-1,2,3,6-tetrahydro-1,3,5,2,4,6-triazatriphosphinine

Cas:15599-91-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Finetech Industry Limited

FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the HEXAFLUOROCYCLOTRIPHOSPHAZENE, CAS:15599-91-4 with the most competitive price and the

HEXAFLUOROCYCLOTRIPHOSPHAZENE

Cas:15599-91-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

sodium fluoride

sodium fluoride

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

Conditions
ConditionsYield
With 1-butyl-3-methylimidazolium Tetrafluoroborate In N,N-dimethyl-formamide at 50℃; for 5h; Reagent/catalyst; Solvent; Temperature;99.8%
With H2O or HF In nitrobenzene dissolving (NPCl2)3 in freshly distd. C6H5NO2; addn. of an excess of NaF or a small amount of H2O or HF under exclusion of H2O (drying tube with P2O5); heating on refluxing;; fractionation;;
In gas byproducts: NaCl; (NPCl2)3 gas was passed over heated NaF at 550°C; monitoring by IR spectroscopy;
potassium fluoride

potassium fluoride

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

Conditions
ConditionsYield
With 4-n-butyl-4-methylmorpholinium hydroxide In acetonitrile at 30℃; for 2h; Temperature; Solvent; Reagent/catalyst; Ionic liquid;98.7%
Reflux;90%
With catalyst: 18-crown-6 In tetrahydrofuran refluxing KF with catalytic amt. of crown for 20 min, dropwise addn. of 0.1 equiv. of N3P3Cl6, refluxing (1 h); fractional distn.;
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

Conditions
ConditionsYield
With potassium fluoride; Triethylene glycol dimethyl ether; ethanol In hexane at 0 - 30℃; for 2h; Solvent; Reagent/catalyst; Temperature;97.2%
With sodium fluoride In diethylene glycol dimethyl ether at 100℃; for 2h; Temperature; Solvent; Inert atmosphere;86%
In not given (N2); as in: (Schmutzler, R. Inorg Synth. 1967, 9, 75); fractional distn.;
With sodium fluoride In ethyl acetate at 10℃; for 3h; Solvent; Temperature; Reflux;130 g
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

sodium hexafluorosilicate

sodium hexafluorosilicate

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

Conditions
ConditionsYield
In neat (no solvent) react. at 280-350 °C; complete react. after 2 1/2 h; passing through N2 at the end of the react.;; distn. off the product or removal of product with N2;;84.5%
In neat (no solvent) react. at 280-350 °C; complete react. after 2 1/2 h; passing through N2 at the end of the react.;; distn. off the product or removal of product with N2;;84.5%
potassium fluoride

potassium fluoride

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

sulfur dioxide
7446-09-5

sulfur dioxide

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

Conditions
ConditionsYield
In neat (no solvent) condensation of 80 ml liquid SO2 on a mixt. of 200 g (NPCl2)3 and 300 g KF; heating at 98-100 °C for 22 days;; removal of an excess of SO2; fractionation, transition temp. 49-49.8 °C at 747 Torr; yield 115.3 (NPCl2)3;;80%
In neat (no solvent) heating (NPCl2)3 with KF and SO2;;
In neat (no solvent) heating (NPCl2)3 with a 50 % excess of KF and less than the stoichiometric amount of SO2 at 100 °C in an autoclave for a few days on stirring;;
In neat (no solvent) heating (NPCl2)3 with a 50 % excess of KF and less than the stoichiometric amount of SO2 at 100 °C in an autoclave for a few days on stirring;;
In neat (no solvent) heating (NPCl2)3 with KF and SO2;;
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

potassium fluorosulphinate
14986-57-3

potassium fluorosulphinate

A

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

B

sulfur dioxide
7446-09-5

sulfur dioxide

Conditions
ConditionsYield
In nitrobenzene heating a soln. of (NPCl2)3 in C6H5NO2 with solid 90 % KSO2F on refluxing; react. starting at 100. degree.C under evolution of gas;; condensation of (NPCl2)3 and formed SO2 on cooling with dry ice; isolation on distg. at 0 °C;;A 64.5%
B n/a
In nitrobenzene heating a soln. of (NPCl2)3 in C6H5NO2 with solid 90 % KSO2F on refluxing; react. starting at 100. degree.C under evolution of gas;; condensation of (NPCl2)3 and formed SO2 on cooling with dry ice; isolation on distg. at 0 °C;;A 64.5%
B n/a
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

silver fluoride

silver fluoride

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

nitrogen trifluoride
7783-54-2

nitrogen trifluoride

phosphorus(V) nitride

phosphorus(V) nitride

A

octafluorophosphazene
14700-00-6

octafluorophosphazene

B

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

Conditions
ConditionsYield
In neat (no solvent) react. of P3N5 with NF3 at 710 °C;; fractional vac. distn.;;
In neat (no solvent) react. of P3N5 with NF3 at 710 °C;; fractional vac. distn.;;
phosphorus(V) nitride

phosphorus(V) nitride

CF3SF5
373-80-8

CF3SF5

A

Hexafluoroethane
76-16-4

Hexafluoroethane

B

sulfur tetrafluoride
7783-60-0

sulfur tetrafluoride

C

octafluorophosphazene
14700-00-6

octafluorophosphazene

D

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

E

trifluorophosphane
7783-55-3

trifluorophosphane

Conditions
ConditionsYield
In neat (no solvent) heating P3N5 at 710 °C on passing in gaseous CF3SF5; flushing with N2 before and after react.; cooling the receivers with dry ice-actone;; fractional vac. distn.;;
In neat (no solvent) heating P3N5 at 710 °C on passing in gaseous CF3SF5; flushing with N2 before and after react.; cooling the receivers with dry ice-actone;; fractional vac. distn.;;
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

potassium fluorosulphinate
14986-57-3

potassium fluorosulphinate

A

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

B

potassium chloride

potassium chloride

C

sulfur dioxide
7446-09-5

sulfur dioxide

Conditions
ConditionsYield
In neat (no solvent) react. of (NPCl2)3 with KSO2F at 120-125 °C;;
In neat (no solvent) react. of (NPCl2)3 with KSO2F at 120-125 °C;;
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

(C2H5)3N*0.6HF

(C2H5)3N*0.6HF

A

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

B

hexafluorophosphate anion

hexafluorophosphate anion

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In tetrahydrofuran; benzene room temp., Cl/F ratio 1-2/1, 1 h;
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

lead(II) fluoride

lead(II) fluoride

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

Conditions
ConditionsYield
With water In not given no formation in presence of H2O;;0%
With H2O In not given no formation in presence of H2O;;0%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

lead(II) fluoride

lead(II) fluoride

A

2,2-difluoro-4,4,6,6-tetrachlorocyclotriphosphazene
21846-67-3

2,2-difluoro-4,4,6,6-tetrachlorocyclotriphosphazene

B

2,2-dichloro-4,4,6,6-tetrafluorocyclotriphosphazene
21846-69-5

2,2-dichloro-4,4,6,6-tetrafluorocyclotriphosphazene

C

N4P4F6Cl2

N4P4F6Cl2

D

octafluorophosphazene
14700-00-6

octafluorophosphazene

E

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

Conditions
ConditionsYield
In not given byproducts: N4P4F4Cl4; react. of (NPCl2)3 with PbF2;; freezing out, dissolving in petroleum ether; fractionation, at 50 °C (NPF2)3, at 70-95 °C (NPF2)4;;
In not given byproducts: N4P4F4Cl4; react. of (NPCl2)3 with PbF2;; freezing out, dissolving in petroleum ether; fractionation, at 50 °C (NPF2)3, at 70-95 °C (NPF2)4;;
nitrogen trifluoride
7783-54-2

nitrogen trifluoride

phosphorus nitride

phosphorus nitride

A

octafluorophosphazene
14700-00-6

octafluorophosphazene

B

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

Conditions
ConditionsYield
In neat (no solvent) react. at 710°C;;
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

lithium fluoride

lithium fluoride

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

Conditions
ConditionsYield
In acetonitrile at 0℃; for 2h;
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

cesium fluoride
13400-13-0

cesium fluoride

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

Conditions
ConditionsYield
In acetonitrile at 0℃; for 2h;
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

hydrogen fluoride
7664-39-3

hydrogen fluoride

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

Conditions
ConditionsYield
With α,α,α-trifluorotoluene; antimonypentachloride at 20 - 30℃; for 10h; Reagent/catalyst; Temperature; Flow reactor; Cooling;75 g
hexafluorophosphazene
15599-91-4

hexafluorophosphazene

tris(dimethylamino)sulfonium trimethylsilyldifluoride
150746-76-2

tris(dimethylamino)sulfonium trimethylsilyldifluoride

2S(N(CH3)2)3(1+)*P3N3F5NPF2NPF2NPF5(2-) = [S(N(CH3)2)3]2[P3N3F5NPF2NPF2NPF5]

2S(N(CH3)2)3(1+)*P3N3F5NPF2NPF2NPF5(2-) = [S(N(CH3)2)3]2[P3N3F5NPF2NPF2NPF5]

Conditions
ConditionsYield
In acetonitrile 235 K, then slight warming;99%
hexafluorophosphazene
15599-91-4

hexafluorophosphazene

sodium trimethylsilanolate
18027-10-6

sodium trimethylsilanolate

C3H9F5N3OP3Si

C3H9F5N3OP3Si

Conditions
ConditionsYield
In Petroleum ether at 10 - 20℃; for 10h; Solvent;97%
hexafluorophosphazene
15599-91-4

hexafluorophosphazene

lithium trimethylsilanolate
2004-14-0

lithium trimethylsilanolate

C3H9F5N3OP3Si

C3H9F5N3OP3Si

Conditions
ConditionsYield
In benzonitrile at 10 - 20℃; for 10h; Solvent;97%
hexafluorophosphazene
15599-91-4

hexafluorophosphazene

potassium trimethylsilonate
10519-96-7

potassium trimethylsilonate

C3H9F5N3OP3Si

C3H9F5N3OP3Si

Conditions
ConditionsYield
In hexane at 40℃; for 10h; Solvent; Temperature;96%
hexafluorophosphazene
15599-91-4

hexafluorophosphazene

ammonia
7664-41-7

ammonia

2,4,4,6,6-pentafluoro-2λ5,4λ5,6λ5-cyclotriphosphazen-2-ylamine
21475-58-1

2,4,4,6,6-pentafluoro-2λ5,4λ5,6λ5-cyclotriphosphazen-2-ylamine

Conditions
ConditionsYield
In diethyl ether High Pressure; (N2); Schlenk techniques; P3N3F6, liq. NH3 (1:8) in Et2O sealed into a tube; kept at 20°C for 24 h; detn. by GC/MS;95%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

ferroceneacetylene
1271-47-2

ferroceneacetylene

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

(ethynylferrocenyl)pentafluorocyclotriphosphazene
1231713-57-7

(ethynylferrocenyl)pentafluorocyclotriphosphazene

Conditions
ConditionsYield
In tetrahydrofuran (N2); using Schlenk techniques; cooling of soln. of HCCC5H4FeC5H5 in THFto -78°C, addn. of soln. of n-BuLi, stirring at room temp. for 3 h, cooling to -78°C, addn. to cooled to -78°C soln. of N3 P3F6, stirring at room temp. for 24 h; evapn. of solvent, chromy. over silica gel, elution with ethyl acetate/hexane (2%), slow evapn., crystn.; elem. anal.;80%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

bromoferrocene
1273-73-0

bromoferrocene

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

A

ferrocene
102-54-5

ferrocene

B

N3P3F5(η-C5H4)Fe(η-C5H5)

N3P3F5(η-C5H4)Fe(η-C5H5)

C

N3P3F4{(C5H4)Fe(C5H5)}2
84462-68-0

N3P3F4{(C5H4)Fe(C5H5)}2

Conditions
ConditionsYield
In diethyl ether reaction of C4H9Li (1.2 equiv.) and Br(C5H4)Fe(C5H5) to Li(C5H4)Fe(C5H5) in diethyl ether, warmed up to room temp., stirred 45min, recooled to -78°C, dropwise addn. of (NPF2)3 in diethyl ether, stirred, 6h, room temp., solvent removed, under N2; chromy. (hexane (Fe(C5H5)2) - dichloromethane/hexane(1:5) (N3P3F5(C5H4)Fe(C5H5)), elem. anal. - dichloromethane/hexane(1:1) (N3P3F4((C5H4)Fe(C5H5))2));A n/a
B 77%
C n/a
lithiumferrocene
1271-15-4

lithiumferrocene

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

N3P3F5(η-C5H4)Fe(η-C5H5)

N3P3F5(η-C5H4)Fe(η-C5H5)

Conditions
ConditionsYield
In diethyl ether Fe-complex and ligand were reacted in Et2O at -78°C for 6 h, warmed to 25°C; solvent was removed, chromd. on silica gel with hexane-CH2Cl2;77%
hexafluorophosphazene
15599-91-4

hexafluorophosphazene

dimethyl amine
124-40-3

dimethyl amine

cyclopentene
142-29-0

cyclopentene

A

fluorocyclopentane
1481-36-3

fluorocyclopentane

B

Dimethylaminopentafluorocyclotriphosphonitril
23208-17-5

Dimethylaminopentafluorocyclotriphosphonitril

Conditions
ConditionsYield
In acetonitrile at -10 - 0℃; for 1h; Inert atmosphere;A n/a
B 77%
hexafluorophosphazene
15599-91-4

hexafluorophosphazene

dimethyl amine
124-40-3

dimethyl amine

Dimethylaminopentafluorocyclotriphosphonitril
23208-17-5

Dimethylaminopentafluorocyclotriphosphonitril

Conditions
ConditionsYield
With Trimethylmethoxysilane at -10 - 0℃; for 2h; Reagent/catalyst; Inert atmosphere;75%
In 1-methyl-pyrrolidin-2-one at -10 - 0℃; for 1h; Solvent; Temperature;49%
ethanol
64-17-5

ethanol

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

1-ethoxy-1,3,3,5,5-pentafluorocyclotriphosphazene
33027-66-6

1-ethoxy-1,3,3,5,5-pentafluorocyclotriphosphazene

Conditions
ConditionsYield
With ammonia In benzene at 10℃; for 2h; Solvent; Temperature;69.6%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

ferroceneacetylene
1271-47-2

ferroceneacetylene

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

gem-ethynylferrocenyltetrafluorocyclotriphosphazene
1231713-65-7

gem-ethynylferrocenyltetrafluorocyclotriphosphazene

Conditions
ConditionsYield
In tetrahydrofuran (N2); using Schlenk techniques; cooling of soln. of HCCC5H4FeC5H5 (2 equiv) in THF to -78°C, addn. of soln. of BuLi, stirring at room temp. for 3h, cooling to -78°C, addn. to soln. of N3P3Cl6 at -78°C, stirring at room temp. for 24h; evapn. of solvent, chromy. over silica gel, elution with ethyl acetate/hexane (2%), slow evapn., crystn.; elem. anal.;68%
hydroxyferrocene

hydroxyferrocene

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

[Fe(C5H5)(C5H4O)P3N3F5]
198129-12-3

[Fe(C5H5)(C5H4O)P3N3F5]

Conditions
ConditionsYield
With NEt3 In tetrahydrofuran byproducts: NEt3*HF; Ar atm.; equimolar ratio, cooling (-78°C), stirring (overnight, room temp.); concn. (vac.);60%
dilithium ferrocene dithiolate * 2 tetrahydrofuran

dilithium ferrocene dithiolate * 2 tetrahydrofuran

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

[Fe(C5H4S)2P3N3F4]
198129-17-8

[Fe(C5H4S)2P3N3F4]

Conditions
ConditionsYield
With NEt3 In tetrahydrofuran byproducts: LiF; Ar atm.; molar ratio Fe complex:phosphazene:NEt3 1:1:2, cooling (-78°C), stirring (overnight, room temp.); filtn., concn. (vac.), chromatography (SiO2/CH2Cl2);59%
(C5H5)Fe(C5H4)CH2P(S)(CH2OSi(CH3)3)2
301155-77-1

(C5H5)Fe(C5H4)CH2P(S)(CH2OSi(CH3)3)2

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

[(ferrocenyl)CH2P(S)(CH2O)2PN](F2PN)2
301155-79-3

[(ferrocenyl)CH2P(S)(CH2O)2PN](F2PN)2

Conditions
ConditionsYield
cesium fluoride In tetrahydrofuran (N2); Schlenk glassware; N3P3F6 was sublimed into oven-dried, evacuatedflask; CsF added; Fe complex in dry THF added into flask by syringe; stirred at 60°C for 12 h; solvent removed in vac.; chromd. (ethyl acetate/hexane); elem. anal.;52%
N-Ethylmethylamine
624-78-2

N-Ethylmethylamine

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

C3H8F5N4P3

C3H8F5N4P3

Conditions
ConditionsYield
at 10 - 20℃; for 0.5h;48%
hexafluorophosphazene
15599-91-4

hexafluorophosphazene

diethylamine
109-89-7

diethylamine

Diethyl-(2,4,4,6,6-pentafluoro-2λ5,4λ5,6λ5-[1,3,5,2,4,6]triazatriphosphinin-2-yl)-amine
38668-23-4

Diethyl-(2,4,4,6,6-pentafluoro-2λ5,4λ5,6λ5-[1,3,5,2,4,6]triazatriphosphinin-2-yl)-amine

Conditions
ConditionsYield
In 1-methyl-pyrrolidin-2-one at 0 - 10℃; for 0.5h; Temperature; Solvent;47%
dilithium ferrocene diselenolato * 2 tetrahydrofuran

dilithium ferrocene diselenolato * 2 tetrahydrofuran

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

[Fe(C5H4Se)2P3N3F4]
198129-18-9

[Fe(C5H4Se)2P3N3F4]

Conditions
ConditionsYield
With NEt3 In tetrahydrofuran byproducts: LiF; Ar atm.; molar ratio Fe complex:phosphazene:NEt3 1:1:2, cooling (-78°C), stirring (overnight, room temp.); filtn., concn. (vac.), chromatography (SiO2/CH2Cl2);46%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

(ferrocenyl)CH2P(S)(CH2OH)2
180794-53-0

(ferrocenyl)CH2P(S)(CH2OH)2

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

A

exo-FcCH2P(S)(CH2O)2[P(F)N]2(F2PN)

exo-FcCH2P(S)(CH2O)2[P(F)N]2(F2PN)

B

endo-FcCH2P(S)(CH2O)2[P(F)N]2(F2PN)

endo-FcCH2P(S)(CH2O)2[P(F)N]2(F2PN)

Conditions
ConditionsYield
In tetrahydrofuran byproducts: LiF; (N2); Schlenk glassware; various product yields for various conditions;compd. FcCH2P(S)(CH2OH)2 was treated with N-BuLi in THF at -80°C; stirred for 4 h; soln. of N3P3F6 in THF added at -80°C; stirredat room temp. for 12 h; solvent removed in vac.; residue dissolved in toluene; filtered; analyzed by TLC; chromd. (SiO2, ethyl acetate/hexane); recrystd. (ethyl acetate/hexane); elem. anal.;A 18.9%
B 44.5%
hexafluorophosphazene
15599-91-4

hexafluorophosphazene

ammonia*phosphorus pentafluoride (1/1)
84724-54-9

ammonia*phosphorus pentafluoride (1/1)

Conditions
ConditionsYield
With HF In acetonitrile warmed from -15°C to room temp.; KF added, filtration, filtrate extd. (ether), elem. anal.;41%
ferrocene
102-54-5

ferrocene

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

tert.-butyl lithium
594-19-4

tert.-butyl lithium

N3P3F4(η-C5H4)Fe

N3P3F4(η-C5H4)Fe

Conditions
ConditionsYield
In diethyl ether byproducts: butane; prepn. of Li2(C5H5)2Fe by addn. of C4H9Li to soln. of (C5H5)Fe(C5H5), 0°C, stirring, 4h, 0°C, soln. added to soln. of (NPF2)3 in diethyl ether, -78°C, warmed up to room temp., stirred 17h, solvent removed, under N2; chromy. ((hexane) (Fe(C5H5)2) - dichloromethane-hexane(1:9));;40%
1,1′-ferrocenediol

1,1′-ferrocenediol

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

[Fe(C5H4O)2P3N3F4]
198129-15-6

[Fe(C5H4O)2P3N3F4]

Conditions
ConditionsYield
With NEt3 In tetrahydrofuran byproducts: NEt3*HF; Ar atm.; molar ratio Fe(C5H4OH)2:phosphazene:NEt3 1:1:2, cooling (-78°C), stirring (overnight, room temp.); filtn., concn. (vac.), chromatography (SiO2/CH2Cl2);39%
1,4-bis(ferrocenyl)butadiyne

1,4-bis(ferrocenyl)butadiyne

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

A

FcC≡C-C≡CP3N3F5

FcC≡C-C≡CP3N3F5

B

[(FcC≡C-C≡C)2PN](F2PN)2

[(FcC≡C-C≡C)2PN](F2PN)2

Conditions
ConditionsYield
Stage #1: 1,4-bis(ferrocenyl)butadiyne With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 3.25h; Schlenk technique; Inert atmosphere;
Stage #2: hexafluorophosphazene In tetrahydrofuran; hexane at -78℃; for 12h; Schlenk technique; Inert atmosphere;
A 36%
B 32%
lithiated bis(η(6)-benzene)chromium
125594-39-0

lithiated bis(η(6)-benzene)chromium

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

N3P3F4(C6H5)2Cr
104213-56-1

N3P3F4(C6H5)2Cr

Conditions
ConditionsYield
In cyclohexane byproducts: LiF; dry N2 atmosphere, 25°C, 4 h; washing (2-propanol), filtration, crystn. (-10°C); elem. anal.;35%

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