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inquiryName: Phosphonitrilic fluoride trimer Synonyms: 1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexafluoro-2,2,4,4,6,6,-hexahydro- CAS:15599-91-4 MF: F6N3P3 Appearance: white powder Storage:Store in cool and dry place, away from sun light. Package
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inquiryHEXAFLUOROCYCLOTRIPHOSPHAZENE CAS:15599-91-4 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality or
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inquiry1,3,5,2,4,6-Triazatriphosphorine,2,2,4,4,6,6-hexafluoro-2,2,4,4,6,6-hexahydro-Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express
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inquiryFINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the HEXAFLUOROCYCLOTRIPHOSPHAZENE, CAS:15599-91-4 with the most competitive price and the
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
hexafluorophosphazene
Conditions | Yield |
---|---|
With 1-butyl-3-methylimidazolium Tetrafluoroborate In N,N-dimethyl-formamide at 50℃; for 5h; Reagent/catalyst; Solvent; Temperature; | 99.8% |
With H2O or HF In nitrobenzene dissolving (NPCl2)3 in freshly distd. C6H5NO2; addn. of an excess of NaF or a small amount of H2O or HF under exclusion of H2O (drying tube with P2O5); heating on refluxing;; fractionation;; | |
In gas byproducts: NaCl; (NPCl2)3 gas was passed over heated NaF at 550°C; monitoring by IR spectroscopy; |
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
hexafluorophosphazene
Conditions | Yield |
---|---|
With 4-n-butyl-4-methylmorpholinium hydroxide In acetonitrile at 30℃; for 2h; Temperature; Solvent; Reagent/catalyst; Ionic liquid; | 98.7% |
Reflux; | 90% |
With catalyst: 18-crown-6 In tetrahydrofuran refluxing KF with catalytic amt. of crown for 20 min, dropwise addn. of 0.1 equiv. of N3P3Cl6, refluxing (1 h); fractional distn.; |
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
hexafluorophosphazene
Conditions | Yield |
---|---|
With potassium fluoride; Triethylene glycol dimethyl ether; ethanol In hexane at 0 - 30℃; for 2h; Solvent; Reagent/catalyst; Temperature; | 97.2% |
With sodium fluoride In diethylene glycol dimethyl ether at 100℃; for 2h; Temperature; Solvent; Inert atmosphere; | 86% |
In not given (N2); as in: (Schmutzler, R. Inorg Synth. 1967, 9, 75); fractional distn.; | |
With sodium fluoride In ethyl acetate at 10℃; for 3h; Solvent; Temperature; Reflux; | 130 g |
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
hexafluorophosphazene
Conditions | Yield |
---|---|
In neat (no solvent) react. at 280-350 °C; complete react. after 2 1/2 h; passing through N2 at the end of the react.;; distn. off the product or removal of product with N2;; | 84.5% |
In neat (no solvent) react. at 280-350 °C; complete react. after 2 1/2 h; passing through N2 at the end of the react.;; distn. off the product or removal of product with N2;; | 84.5% |
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
sulfur dioxide
hexafluorophosphazene
Conditions | Yield |
---|---|
In neat (no solvent) condensation of 80 ml liquid SO2 on a mixt. of 200 g (NPCl2)3 and 300 g KF; heating at 98-100 °C for 22 days;; removal of an excess of SO2; fractionation, transition temp. 49-49.8 °C at 747 Torr; yield 115.3 (NPCl2)3;; | 80% |
In neat (no solvent) heating (NPCl2)3 with KF and SO2;; | |
In neat (no solvent) heating (NPCl2)3 with a 50 % excess of KF and less than the stoichiometric amount of SO2 at 100 °C in an autoclave for a few days on stirring;; | |
In neat (no solvent) heating (NPCl2)3 with a 50 % excess of KF and less than the stoichiometric amount of SO2 at 100 °C in an autoclave for a few days on stirring;; | |
In neat (no solvent) heating (NPCl2)3 with KF and SO2;; |
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
potassium fluorosulphinate
A
hexafluorophosphazene
B
sulfur dioxide
Conditions | Yield |
---|---|
In nitrobenzene heating a soln. of (NPCl2)3 in C6H5NO2 with solid 90 % KSO2F on refluxing; react. starting at 100. degree.C under evolution of gas;; condensation of (NPCl2)3 and formed SO2 on cooling with dry ice; isolation on distg. at 0 °C;; | A 64.5% B n/a |
In nitrobenzene heating a soln. of (NPCl2)3 in C6H5NO2 with solid 90 % KSO2F on refluxing; react. starting at 100. degree.C under evolution of gas;; condensation of (NPCl2)3 and formed SO2 on cooling with dry ice; isolation on distg. at 0 °C;; | A 64.5% B n/a |
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
hexafluorophosphazene
nitrogen trifluoride
A
octafluorophosphazene
B
hexafluorophosphazene
Conditions | Yield |
---|---|
In neat (no solvent) react. of P3N5 with NF3 at 710 °C;; fractional vac. distn.;; | |
In neat (no solvent) react. of P3N5 with NF3 at 710 °C;; fractional vac. distn.;; |
CF3SF5
A
Hexafluoroethane
B
sulfur tetrafluoride
C
octafluorophosphazene
D
hexafluorophosphazene
E
trifluorophosphane
Conditions | Yield |
---|---|
In neat (no solvent) heating P3N5 at 710 °C on passing in gaseous CF3SF5; flushing with N2 before and after react.; cooling the receivers with dry ice-actone;; fractional vac. distn.;; | |
In neat (no solvent) heating P3N5 at 710 °C on passing in gaseous CF3SF5; flushing with N2 before and after react.; cooling the receivers with dry ice-actone;; fractional vac. distn.;; |
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
potassium fluorosulphinate
A
hexafluorophosphazene
C
sulfur dioxide
Conditions | Yield |
---|---|
In neat (no solvent) react. of (NPCl2)3 with KSO2F at 120-125 °C;; | |
In neat (no solvent) react. of (NPCl2)3 with KSO2F at 120-125 °C;; |
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
A
hexafluorophosphazene
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine In tetrahydrofuran; benzene room temp., Cl/F ratio 1-2/1, 1 h; |
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
hexafluorophosphazene
Conditions | Yield |
---|---|
With water In not given no formation in presence of H2O;; | 0% |
With H2O In not given no formation in presence of H2O;; | 0% |
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
A
2,2-difluoro-4,4,6,6-tetrachlorocyclotriphosphazene
B
2,2-dichloro-4,4,6,6-tetrafluorocyclotriphosphazene
D
octafluorophosphazene
E
hexafluorophosphazene
Conditions | Yield |
---|---|
In not given byproducts: N4P4F4Cl4; react. of (NPCl2)3 with PbF2;; freezing out, dissolving in petroleum ether; fractionation, at 50 °C (NPF2)3, at 70-95 °C (NPF2)4;; | |
In not given byproducts: N4P4F4Cl4; react. of (NPCl2)3 with PbF2;; freezing out, dissolving in petroleum ether; fractionation, at 50 °C (NPF2)3, at 70-95 °C (NPF2)4;; |
nitrogen trifluoride
A
octafluorophosphazene
B
hexafluorophosphazene
Conditions | Yield |
---|---|
In neat (no solvent) react. at 710°C;; |
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
hexafluorophosphazene
Conditions | Yield |
---|---|
In acetonitrile at 0℃; for 2h; |
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
cesium fluoride
hexafluorophosphazene
Conditions | Yield |
---|---|
In acetonitrile at 0℃; for 2h; |
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
hydrogen fluoride
hexafluorophosphazene
Conditions | Yield |
---|---|
With α,α,α-trifluorotoluene; antimonypentachloride at 20 - 30℃; for 10h; Reagent/catalyst; Temperature; Flow reactor; Cooling; | 75 g |
hexafluorophosphazene
tris(dimethylamino)sulfonium trimethylsilyldifluoride
Conditions | Yield |
---|---|
In acetonitrile 235 K, then slight warming; | 99% |
Conditions | Yield |
---|---|
In Petroleum ether at 10 - 20℃; for 10h; Solvent; | 97% |
Conditions | Yield |
---|---|
In benzonitrile at 10 - 20℃; for 10h; Solvent; | 97% |
Conditions | Yield |
---|---|
In hexane at 40℃; for 10h; Solvent; Temperature; | 96% |
hexafluorophosphazene
ammonia
2,4,4,6,6-pentafluoro-2λ5,4λ5,6λ5-cyclotriphosphazen-2-ylamine
Conditions | Yield |
---|---|
In diethyl ether High Pressure; (N2); Schlenk techniques; P3N3F6, liq. NH3 (1:8) in Et2O sealed into a tube; kept at 20°C for 24 h; detn. by GC/MS; | 95% |
n-butyllithium
ferroceneacetylene
hexafluorophosphazene
(ethynylferrocenyl)pentafluorocyclotriphosphazene
Conditions | Yield |
---|---|
In tetrahydrofuran (N2); using Schlenk techniques; cooling of soln. of HCCC5H4FeC5H5 in THFto -78°C, addn. of soln. of n-BuLi, stirring at room temp. for 3 h, cooling to -78°C, addn. to cooled to -78°C soln. of N3 P3F6, stirring at room temp. for 24 h; evapn. of solvent, chromy. over silica gel, elution with ethyl acetate/hexane (2%), slow evapn., crystn.; elem. anal.; | 80% |
n-butyllithium
bromoferrocene
hexafluorophosphazene
A
ferrocene
C
N3P3F4{(C5H4)Fe(C5H5)}2
Conditions | Yield |
---|---|
In diethyl ether reaction of C4H9Li (1.2 equiv.) and Br(C5H4)Fe(C5H5) to Li(C5H4)Fe(C5H5) in diethyl ether, warmed up to room temp., stirred 45min, recooled to -78°C, dropwise addn. of (NPF2)3 in diethyl ether, stirred, 6h, room temp., solvent removed, under N2; chromy. (hexane (Fe(C5H5)2) - dichloromethane/hexane(1:5) (N3P3F5(C5H4)Fe(C5H5)), elem. anal. - dichloromethane/hexane(1:1) (N3P3F4((C5H4)Fe(C5H5))2)); | A n/a B 77% C n/a |
Conditions | Yield |
---|---|
In diethyl ether Fe-complex and ligand were reacted in Et2O at -78°C for 6 h, warmed to 25°C; solvent was removed, chromd. on silica gel with hexane-CH2Cl2; | 77% |
hexafluorophosphazene
dimethyl amine
cyclopentene
A
fluorocyclopentane
B
Dimethylaminopentafluorocyclotriphosphonitril
Conditions | Yield |
---|---|
In acetonitrile at -10 - 0℃; for 1h; Inert atmosphere; | A n/a B 77% |
hexafluorophosphazene
dimethyl amine
Dimethylaminopentafluorocyclotriphosphonitril
Conditions | Yield |
---|---|
With Trimethylmethoxysilane at -10 - 0℃; for 2h; Reagent/catalyst; Inert atmosphere; | 75% |
In 1-methyl-pyrrolidin-2-one at -10 - 0℃; for 1h; Solvent; Temperature; | 49% |
ethanol
hexafluorophosphazene
1-ethoxy-1,3,3,5,5-pentafluorocyclotriphosphazene
Conditions | Yield |
---|---|
With ammonia In benzene at 10℃; for 2h; Solvent; Temperature; | 69.6% |
n-butyllithium
ferroceneacetylene
hexafluorophosphazene
gem-ethynylferrocenyltetrafluorocyclotriphosphazene
Conditions | Yield |
---|---|
In tetrahydrofuran (N2); using Schlenk techniques; cooling of soln. of HCCC5H4FeC5H5 (2 equiv) in THF to -78°C, addn. of soln. of BuLi, stirring at room temp. for 3h, cooling to -78°C, addn. to soln. of N3P3Cl6 at -78°C, stirring at room temp. for 24h; evapn. of solvent, chromy. over silica gel, elution with ethyl acetate/hexane (2%), slow evapn., crystn.; elem. anal.; | 68% |
Conditions | Yield |
---|---|
With NEt3 In tetrahydrofuran byproducts: NEt3*HF; Ar atm.; equimolar ratio, cooling (-78°C), stirring (overnight, room temp.); concn. (vac.); | 60% |
hexafluorophosphazene
[Fe(C5H4S)2P3N3F4]
Conditions | Yield |
---|---|
With NEt3 In tetrahydrofuran byproducts: LiF; Ar atm.; molar ratio Fe complex:phosphazene:NEt3 1:1:2, cooling (-78°C), stirring (overnight, room temp.); filtn., concn. (vac.), chromatography (SiO2/CH2Cl2); | 59% |
(C5H5)Fe(C5H4)CH2P(S)(CH2OSi(CH3)3)2
hexafluorophosphazene
[(ferrocenyl)CH2P(S)(CH2O)2PN](F2PN)2
Conditions | Yield |
---|---|
cesium fluoride In tetrahydrofuran (N2); Schlenk glassware; N3P3F6 was sublimed into oven-dried, evacuatedflask; CsF added; Fe complex in dry THF added into flask by syringe; stirred at 60°C for 12 h; solvent removed in vac.; chromd. (ethyl acetate/hexane); elem. anal.; | 52% |
Conditions | Yield |
---|---|
at 10 - 20℃; for 0.5h; | 48% |
hexafluorophosphazene
diethylamine
Diethyl-(2,4,4,6,6-pentafluoro-2λ5,4λ5,6λ5-[1,3,5,2,4,6]triazatriphosphinin-2-yl)-amine
Conditions | Yield |
---|---|
In 1-methyl-pyrrolidin-2-one at 0 - 10℃; for 0.5h; Temperature; Solvent; | 47% |
hexafluorophosphazene
[Fe(C5H4Se)2P3N3F4]
Conditions | Yield |
---|---|
With NEt3 In tetrahydrofuran byproducts: LiF; Ar atm.; molar ratio Fe complex:phosphazene:NEt3 1:1:2, cooling (-78°C), stirring (overnight, room temp.); filtn., concn. (vac.), chromatography (SiO2/CH2Cl2); | 46% |
n-butyllithium
(ferrocenyl)CH2P(S)(CH2OH)2
hexafluorophosphazene
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: LiF; (N2); Schlenk glassware; various product yields for various conditions;compd. FcCH2P(S)(CH2OH)2 was treated with N-BuLi in THF at -80°C; stirred for 4 h; soln. of N3P3F6 in THF added at -80°C; stirredat room temp. for 12 h; solvent removed in vac.; residue dissolved in toluene; filtered; analyzed by TLC; chromd. (SiO2, ethyl acetate/hexane); recrystd. (ethyl acetate/hexane); elem. anal.; | A 18.9% B 44.5% |
hexafluorophosphazene
ammonia*phosphorus pentafluoride (1/1)
Conditions | Yield |
---|---|
With HF In acetonitrile warmed from -15°C to room temp.; KF added, filtration, filtrate extd. (ether), elem. anal.; | 41% |
Conditions | Yield |
---|---|
In diethyl ether byproducts: butane; prepn. of Li2(C5H5)2Fe by addn. of C4H9Li to soln. of (C5H5)Fe(C5H5), 0°C, stirring, 4h, 0°C, soln. added to soln. of (NPF2)3 in diethyl ether, -78°C, warmed up to room temp., stirred 17h, solvent removed, under N2; chromy. ((hexane) (Fe(C5H5)2) - dichloromethane-hexane(1:9));; | 40% |
Conditions | Yield |
---|---|
With NEt3 In tetrahydrofuran byproducts: NEt3*HF; Ar atm.; molar ratio Fe(C5H4OH)2:phosphazene:NEt3 1:1:2, cooling (-78°C), stirring (overnight, room temp.); filtn., concn. (vac.), chromatography (SiO2/CH2Cl2); | 39% |
hexafluorophosphazene
Conditions | Yield |
---|---|
Stage #1: 1,4-bis(ferrocenyl)butadiyne With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 3.25h; Schlenk technique; Inert atmosphere; Stage #2: hexafluorophosphazene In tetrahydrofuran; hexane at -78℃; for 12h; Schlenk technique; Inert atmosphere; | A 36% B 32% |
lithiated bis(η(6)-benzene)chromium
hexafluorophosphazene
N3P3F4(C6H5)2Cr
Conditions | Yield |
---|---|
In cyclohexane byproducts: LiF; dry N2 atmosphere, 25°C, 4 h; washing (2-propanol), filtration, crystn. (-10°C); elem. anal.; | 35% |
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