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Qingdao KMS Biochemical Technology Co.,Ltd.

Appearance:White crystal powder Storage:Be airtight in a cool and dry environment Package:25 kg cardboard barrels Application:Due to the fluidity of the phosphorus-chlorine bond, chlorine can be easily replaced, and a series of phosphoronitrile deriv

Phosphonitrilic chloride trimer

Cas:940-71-6

Min.Order:25 Kilogram

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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Phosphonitrilic chloride trimer Manufacturer/High quality/Best price/In stock

Cas:940-71-6

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Assay (Ursolic acid) 98%min 98.22% ----------------------------------------------------------------

High purity 940-71-6 HEXACHLOROCYCLOTRIPHOSPHAZENE

Cas:940-71-6

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Jinan Finer Chemical Co., Ltd

Product Name Phosphonitrilic chloride trimer CAS No. 940-71-6 Appearance White crystal powder Assay ≥99% Capacity 500mt/year MOQ 100G Application Polyphosphazene h

Phosphonitrilic chloride trimer

Cas:940-71-6

Min.Order:1 Kilogram

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience 2. Free samples will be provided,ensure specifications and quality are right for customer 3. Customers will receive the most professional techn

Large Stock 99.0% Phosphonitrilic chloride trimer 940-71-6 Producer

Cas:940-71-6

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Phosphonitrilic Chloride Trimer

Cas:940-71-6

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Chemwill Asia Co., Ltd.

Phosphonitrilic chloride trimer Manufacturer Factory CAS 940-71-6 Phosphonitrilic chloride trimer Manufacturer High quality Best price In stock factory CAS 940-71-6 Phosphonitrilic chloride trimer COA TDS price MSDS highly quality and immeda

Phosphonitrilic chloride trimer Manufacturer Factory CAS 940-71-6

Cas:940-71-6

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Hubei DiBo chemical co., LTD

Name:Phosphonitrilic chloride trimer CAS NO: 940-71-6 Grade:Medical scientific research and export Molecular formula:Cl6N3P3 Molecular weight: 347.6594 Product Quality 12 years of chemical raw materials Mature operation of the industry Sys

Phosphonitrilic chloride trimer/ CAS:940-71-6/ raw material/ high-quality

Cas:940-71-6

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Henan Tianfu Chemical Co., Ltd.

Phosphonitrilic chloride trimer Basic information Product Name: Phosphonitrilic chloride trimer Synonyms: PPZ;PHOSPHORUS NITRILE DICHLORIDE TRIMER;PHOSPHONITRILIC CHLORIDE TRIMER;PHOSPHO

940-71-6

Cas:940-71-6

Min.Order:1 Kilogram

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 940-71-6 with best quality

Cas:940-71-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

TIANFUCHEM--940-71-6---Phosphonitrilic chloride trimer

Cas:940-71-6

Min.Order:10 Kilogram

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

Phosphonitrilic chloride trimer CAS940-71-6

Cas:940-71-6

Min.Order:1 Kilogram

FOB Price: $298.0 / 478.0

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Henan Sinotech Import&Export Corporation

Name: Phosphonitrilic chloride trimer Synonyms: 1,3,5-Triaza-2,4,6-triphosphorin-2,2,4,4,6,6-hexachloride CAS: 940-71-6 MF: Cl6N3P3 Appearance: white powder Storage:Store in cool and dry place, away from sun light. Package: 25kgs/drum Applic

Phosphonitrilic chloride trimer CAS: 940-71-6

Cas:940-71-6

Min.Order:1 Kilogram

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:white or off-white powder Storage:Store in sealed containers

Factory supply Phosphonitrilic chloride trimer CAS:940-71-6 in hot selling

Cas:940-71-6

Min.Order:100 Gram

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Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Phosphonitrilic chloride trimer 940-71-6

Cas:940-71-6

Min.Order:1 Kilogram

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Hebei Nengqian Chemical Import and Export Co., LTD

Product Name Triethanolamine Other names Triethanolamine supplier,Triethanolamine factory,Triethanolamin eprice,Triethanolamine manufactuer,Triethanolamine china CAS NO 102-71-6 Molecular Formula

Hexachlorocyclotriphosphazene CAS 940-71-6 Phosphonitrilic Chloride Trimer

Cas:940-71-6

Min.Order:1 Gram

FOB Price: $1.0 / 5.0

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Phosphonitrilic chloride trimer 99%

Cas:940-71-6

Min.Order:1 Kilogram

FOB Price: $76.0 / 85.0

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Qingdao Beluga Import and Export Co., LTD

Phosphonitrilic chloride trimer CAS:940-71-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality or

Phosphonitrilic chloride trimer CAS:940-71-6

Cas:940-71-6

Min.Order:1 Gram

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Phosphonitrilic chloride trimer

Cas:940-71-6

Min.Order:1 Kilogram

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

Phosphonitrilic chloride trimerl,3,5-Triaza-2,4,6- triphosphorin-2,2,4,4,6,6- CAS 940-71-6

Cas:940-71-6

Min.Order:1 Kilogram

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:940-71-6

Cas:940-71-6

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Hangzhou Fandachem Co.,Ltd

Hangzhou Fanda Chemical Co.,Ltd (FandaChem) , a China-based chemical company, specialize in exporting Phosphonitrilic chloride trimer;Ppz CAS:940-71-6 , Please contact us by email freely. We are leading exporter in China. If you reall

Phosphonitrilic chloride trimer;Ppz CAS:940-71-6 from FandaChem

Cas:940-71-6

Min.Order:1 Metric Ton

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Phosphonitrilic Chloride Trimer

Cas:940-71-6

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

PHOSPHONITRILIC CHLORIDE TRIMER

Cas:940-71-6

Min.Order:1 Gram

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Phosphonitrilic chloride trimer

Cas:940-71-6

Min.Order:0

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Sinoway Industrial Co., Ltd.

Why is SINOWAY: 1) Specialized in pharmaceutical and healthcare industrial for 34 years. 2) ISO 9001:2015 & SGS audited supplier . 3) Accept various payment terms : T.T 30-60 days. 4) We have warehouse in USA with quickly shipment . 5) We c

98% up Phosphonitrilic chloride trimer 940-71-6

Cas:940-71-6

Min.Order:1 Kilogram

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Wuhan Xinhao Biotechnology Co., Ltd.

1. We can provide customers with "one-stop"packaging service,from research,development,production,export and so on 2. Powerful R&D strength let our technology in a leading level,forever,in turn,to provide customers with better service .

Hexachlorocyclotriphosphazene 99.5% CAS NO.940-71-6

Cas:940-71-6

Min.Order:100 Gram

FOB Price: $10.0 / 100.0

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Phosphonitrilic Chloride Trimer

Cas:940-71-6

Min.Order:10 Gram

FOB Price: $100.0

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and als

Phosphonitrilic chloride trimer

Cas:940-71-6

Min.Order:1 Gram

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:white crystalline powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used in

Phosphonitrilic chloride trimer

Cas:940-71-6

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Synthetic route

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

ammonium chloride
12125-02-9

ammonium chloride

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

Conditions
ConditionsYield
With pyridine; magnesium chloride In chlorobenzene at 80 - 132℃; Inert atmosphere;71%
Stage #1: ammonium chloride With pyridine; magnesium chloride In 1,1,2,2-tetrachloroethane at 145℃; for 12h;
Stage #2: phosphorus pentachloride In 1,1,2,2-tetrachloroethane at 145℃; Solvent; Temperature;
61.78%
In chlorobenzene at 120 - 130℃; Inert atmosphere; Reflux;60.6%
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

ammonium chloride
12125-02-9

ammonium chloride

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

(NPCl2)8
14514-98-8

(NPCl2)8

C

octachlorocyclotetraphosphazene
2950-45-0

octachlorocyclotetraphosphazene

D

Cl18N9P9

Cl18N9P9

E

pentakisphosphorus nitride dichloride
13596-41-3

pentakisphosphorus nitride dichloride

F

hexakisphosphorus nitride dichloride
2851-52-7

hexakisphosphorus nitride dichloride

G

heptakisphosphorus nitride dichloride
13827-30-0

heptakisphosphorus nitride dichloride

Conditions
ConditionsYield
In chlorobenzene Schlenk technique; Reflux;A 64%
B 6%
C 5%
D 2%
E 16%
F 16%
G 13%
tris(trimethylsilyl)amine
1586-73-8

tris(trimethylsilyl)amine

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

Conditions
ConditionsYield
In dichloromethane inert atmosphere; dropwise addn. of 1 equiv. PCl5 to amine at 25°C, stirring for 12 h; not isolated, detd. by (31)P-NMR spectroscopy;49%
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

ammonium chloride

ammonium chloride

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

Conditions
ConditionsYield
In chlorobenzene react. of PCl5 with NH4Cl (ratio 1:1.5) in C6H5Cl at 124-127 °C (20-50 h);;40%
In chlorobenzene react. of PCl5 with NH4Cl (ratio 1:1.2) in C6H5Cl at 132-134 °C (20 h);;20-22
In further solvent(s) in 1,1,2,2-tetrachloroethane; recrystn. from petroleum ether;
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

ammonia
7664-41-7

ammonia

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

Conditions
ConditionsYield
In further solvent(s) passing gaseous NH3 in a soln. of PCl5 in (CHCl2)2;;16%
tris(trimethylsilyl)amine
1586-73-8

tris(trimethylsilyl)amine

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

trichloro(trimethylsilyl)phosphoranimine
40678-60-2

trichloro(trimethylsilyl)phosphoranimine

Conditions
ConditionsYield
In dichloromethane inert atmosphere; dropwise addn. of 0.5-1 equiv. PCl5 to amine at -78 or25°C, stirring for 30 min to 12 h; yields depending on educt rat io, reaction temp., time and rate of addn.; product mixt. not sepd., detd. by (31)P-NMR spectroscopy;A 5%
B 5%
thionyl chloride
7719-09-7

thionyl chloride

tetrasulfur tetranitride
28950-34-7

tetrasulfur tetranitride

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

Conditions
ConditionsYield
In benzene addn. of PCl3 to a soln. of S4N4 in C6H6 containing SOCl2; formation of a brown main product and crystals of (PNCl2)3;;
In benzene addn. of PCl3 to a soln. of S4N4 in C6H6 containing SOCl2; formation of a brown main product and crystals of (PNCl2)3;;
mercury amidochloride
10124-48-8

mercury amidochloride

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

phosphorus chloride nitride

phosphorus chloride nitride

C

ammonium chloride

ammonium chloride

D

mercury dichloride

mercury dichloride

Conditions
ConditionsYield
In neat (no solvent) heating with HgNH2Cl; formation of a mixture of P3N3Cl6, (PNCl2)(n), HgCl2 and NH4Cl;;
In neat (no solvent) heating with HgNH2Cl; formation of a mixture of P3N3Cl6, (PNCl2)(n), HgCl2 and NH4Cl;;
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

ammonia
7664-41-7

ammonia

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

octachlorocyclotetraphosphazene
2950-45-0

octachlorocyclotetraphosphazene

C

ammonium chloride

ammonium chloride

Conditions
ConditionsYield
In tetrachloromethane pptn. of NH4Cl from a soln. of 3 g PCl5 in 1000 ml CCl4 half-saturated with gaseous NH3 at -3 °C; soln. contains (PNCl2)3 and (PNCl2)4;; evapn. of the mother liquor, fractional crystn. from toluene;;
In tetrachloromethane pptn. of NH4Cl from a soln. of 3 g PCl5 in 1000 ml CCl4 half-saturated with gaseous NH3 at -3 °C; soln. contains (PNCl2)3 and (PNCl2)4;; evapn. of the mother liquor, fractional crystn. from toluene;;
ammonium chloride

ammonium chloride

chlorine
7782-50-5

chlorine

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

cyclic polyphosphorus nitride dichloride

cyclic polyphosphorus nitride dichloride

C

octachlorocyclotetraphosphazene
2950-45-0

octachlorocyclotetraphosphazene

Conditions
ConditionsYield
In further solvent(s) dissolving PCl3 distd. under N2 in benzyl chloride distd. under N2; addn. of NH4Cl dryed in vac. and passing in the corresponding amount of Cl2; heating in a stream of N2 at 130 °C; removal of formed HCl by a stream of N2;; filtration, distg. off the solvent at 40 °C and 0.5 Torr; recrystn. from petroleum ether; product contains small amounts of higher polymers;;
ammonium chloride

ammonium chloride

chlorine
7782-50-5

chlorine

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

C

cyclic polyphosphorus nitride dichloride

cyclic polyphosphorus nitride dichloride

D

octachlorocyclotetraphosphazene
2950-45-0

octachlorocyclotetraphosphazene

Conditions
ConditionsYield
In further solvent(s) dissolving PCl3 distd. under N2 in (CHCl2)2 distd. under N2; addn. of NH4Cl dryed in vac. and passing in the corresponding amount of Cl2; heating in a stream of N2 at 130 °C; removal of formed HCl by a stream of N2;; filtration, distg. off the solvent at 40 °C and 0.5 Torr; recrystn. from petroleum ether; products (NPCl2)3, (NPCl2)4 and a small amount of oily polymers;;
In chlorobenzene dissolving PCl3 distd. under N2 in C6H5Cl distd. under N2; addn. of NH4Cl dryed in vac. and passing in the corresponding amount of Cl2; heating in a stream of N2 at 130 °C; removal of formed HCl by a stream of N2;; filtration, distg. off the solvent at 40 °C and 0.5 Torr; recrystn. from petroleum ether; product contains small amounts of higher polymers;;
In further solvent(s) dissolving PCl3 distd. under N2 in (CHCl2)2 distd. under N2; addn. of NH4Cl dryed in vac. and passing in the corresponding amount of Cl2; heating in a stream of N2 at 130 °C; removal of formed HCl by a stream of N2;; filtration, distg. off the solvent at 40 °C and 0.5 Torr; recrystn. from petroleum ether; yield 35-40 %, product contains small amounts of higher polymers;;A n/a
B 35-40
C n/a
D n/a
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

ammonium chloride

ammonium chloride

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

cyclic polyphosphorus nitride dichloride

cyclic polyphosphorus nitride dichloride

C

octachlorocyclotetraphosphazene
2950-45-0

octachlorocyclotetraphosphazene

Conditions
ConditionsYield
In not given react. of 400 g PCl5 with 120 g NH4Cl in an inert solvent;; sucking off the formed mass, washing with ice-cold C6H6; fractional distn.; yield 50 % (NPCl2)3, 25 % (NPCl2)4 and 25 % higher polymers;;
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

ammonium chloride

ammonium chloride

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

octachlorocyclotetraphosphazene
2950-45-0

octachlorocyclotetraphosphazene

Conditions
ConditionsYield
In not given react. of 400 g PCl5 with 120 g NH4Cl in an inert solvent;; sucking off the formed mass, washing with ice-cold C6H6; fractional distn.; yield 75 g (NPCl2)3, 25 g (NPCl2)4;;
In not given react. of PCl5 with NH4Cl;; fractionation at 185-190 °C and 13 Torr; fraction contains 10 % (NPCl2)3;;
In not given react. of PCl5 with NH4Cl;; fractionation at 185-190 °C and 13 Torr; fraction contains 10 % (NPCl2)3;;
In further solvent(s) react. of finely divided NH4Cl and PCl5 in refluxing sym-tetrachloroethane; fractional crystn. from glacial acetic acid, cold benzene and conc. H2SO4;
phosphorus(V) nitride

phosphorus(V) nitride

chlorine
7782-50-5

chlorine

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

cyclic polyphosphorus nitride dichloride

cyclic polyphosphorus nitride dichloride

C

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

D

nitrogen
7727-37-9

nitrogen

Conditions
ConditionsYield
In neat (no solvent) formation of a mixt. of phosphorus nitride dichlorides with a large amount of (NPCl2)3 and a small amount of PCl5 by react. of P3N5 with Cl2 at 700 °C;;
sodium azide

sodium azide

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

Conditions
ConditionsYield
In nitrobenzene small amount of azide; detected by NMR;
lithium azide
19597-69-4

lithium azide

trichloro(o-phenylenedioxy)phosphorane
2007-97-8

trichloro(o-phenylenedioxy)phosphorane

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

hexaazido cyclotriphosphazene
22295-99-4

hexaazido cyclotriphosphazene

C

octachlorocyclotetraphosphazene
2950-45-0

octachlorocyclotetraphosphazene

Conditions
ConditionsYield
In nitrobenzene not isolated, detected by NMR;
2,4-dichloro-1,3-bis(dichlorophosphoryl)-2,4-dioxocyclodiphosph(V)azane
64373-45-1

2,4-dichloro-1,3-bis(dichlorophosphoryl)-2,4-dioxocyclodiphosph(V)azane

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

dichlorophosphinylphosphorimidic trichloride
13966-08-0

dichlorophosphinylphosphorimidic trichloride

C

octachlorocyclotetraphosphazene
2950-45-0

octachlorocyclotetraphosphazene

Conditions
ConditionsYield
In trichlorophosphate byproducts: Cl2(O)P(NPCl2)5Cl; under reflux; treatment of the crude product with n-heptane, products identified in the sol. and in the insol. phase with NMR spectroscopy;
P4N6

P4N6

chlorine
7782-50-5

chlorine

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

cyclic polyphosphorus nitride dichloride

cyclic polyphosphorus nitride dichloride

C

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

D

nitrogen
7727-37-9

nitrogen

Conditions
ConditionsYield
In neat (no solvent) formation of a mixt. of phosphorus nitride dichlorides with a large amount of (NPCl2)3 and a small amount of PCl5 by react. of P4N6 with Cl2 at 700 °C;;
thionyl chloride
7719-09-7

thionyl chloride

tetrasulfur tetranitride
28950-34-7

tetrasulfur tetranitride

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

cyclic polyphosphorus nitride dichloride

cyclic polyphosphorus nitride dichloride

Conditions
ConditionsYield
In benzene formation of phosphorus nitride dichlorides with a large amount of (NPCl2)3 as by-products by addn. of PCl3 to a soln. of S4N4 in C6H6 containing SOCl2;;
In benzene
phospham

phospham

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

Conditions
ConditionsYield
With hydrogenchloride In further solvent(s) passing dry gaseous HCl into a suspension of phospham in 1.1.2.2-tetrachlorethane at 148°C for several h;;
phosphorus(V) chloride * 8 NH3

phosphorus(V) chloride * 8 NH3

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

cyclic polyphosphorus nitride dichloride

cyclic polyphosphorus nitride dichloride

Conditions
ConditionsYield
In neat (no solvent) formation of phosphorus nitride dichlorides with a large amount of (NPCl2)3 on heating PCl5*8NH3 at 175-200 °C and 50 Torr;;
phosphorus(V) chloride * 8 NH3

phosphorus(V) chloride * 8 NH3

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
In neat (no solvent) sublimation of (PNCl2)3 at 175-200 °C and 50 Torr;;
In neat (no solvent) sublimation of (PNCl2)3 at 175-200 °C and 50 Torr;;
Mg2PN3

Mg2PN3

chlorine
7782-50-5

chlorine

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

cyclic polyphosphorus nitride dichloride

cyclic polyphosphorus nitride dichloride

C

nitrogen
7727-37-9

nitrogen

D

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In neat (no solvent) formation of phosphorus nitride dichlorides with a large amount of (NPCl2)3 on heating PN3Mg2 in a stream of Cl2 at 700 °C;;
{Cl(Cl2PN)3PCl3}(1+)*{BCl4}(1-)={Cl(Cl2PN)3PCl3}{BCl4}
21246-65-1

{Cl(Cl2PN)3PCl3}(1+)*{BCl4}(1-)={Cl(Cl2PN)3PCl3}{BCl4}

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

{PCl4}(1+)*{BCl4}(1-)={PCl4}{BCl4}
18460-54-3

{PCl4}(1+)*{BCl4}(1-)={PCl4}{BCl4}

Conditions
ConditionsYield
130°C;
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

heptakisphosphorus nitride dichloride
13827-30-0

heptakisphosphorus nitride dichloride

Conditions
ConditionsYield
With quinoline In further solvent(s) heating a soln. of PCl5 in (CHCl2)2 with quinoline at 145 °C on refluxing;; distn. off solvent; formation of a mixt. of 40 % (NPCl2)3, 55-60 % (PNCl2)7 and 0-5 % impurities;;
With quinoline
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

C

dichlorophosphinylphosphorimidic trichloride
13966-08-0

dichlorophosphinylphosphorimidic trichloride

Conditions
ConditionsYield
In further solvent(s) react. of a soln. in tetrachlorethane with PCl5; immediate removal of HCl on passing thruogh a stream of air;;
In further solvent(s) react. of a soln. in tetrachlorethane with PCl5; immediate removal of HCl on passing thruogh a stream of air;;
tris(trimethylsilyl)amine
1586-73-8

tris(trimethylsilyl)amine

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

octachlorocyclotetraphosphazene
2950-45-0

octachlorocyclotetraphosphazene

C

pentakisphosphorus nitride dichloride
13596-41-3

pentakisphosphorus nitride dichloride

D

hexakisphosphorus nitride dichloride
2851-52-7

hexakisphosphorus nitride dichloride

Conditions
ConditionsYield
In dichloromethane byproducts: high oligomers; inert atmosphere; dropwise addn. of 1 equiv. PCl5 to amine at reflux, refluxing for 8 h; distn.; product mixt. not sepd., detd. by (31)P-NMR spectroscopy;
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

ammonia
7664-41-7

ammonia

A

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

B

octachlorocyclotetraphosphazene
2950-45-0

octachlorocyclotetraphosphazene

Conditions
ConditionsYield
In tetrachloromethane incomplete satn. of a soln. of PCl5 in CCl4 with gaseous NH3;;
In tetrachloromethane
lithium azide
19597-69-4

lithium azide

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

Conditions
ConditionsYield
In nitrobenzene small amount of azide; detected by NMR;
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

hydrogen fluoride
7664-39-3

hydrogen fluoride

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

ammonium hexafluorophosphate

ammonium hexafluorophosphate

Conditions
ConditionsYield
In not given react. with HF;;A n/a
B 100%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

sodium fluoride

sodium fluoride

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

Conditions
ConditionsYield
With 1-butyl-3-methylimidazolium Tetrafluoroborate In N,N-dimethyl-formamide at 50℃; for 5h; Reagent/catalyst; Solvent; Temperature;99.8%
With H2O or HF In nitrobenzene dissolving (NPCl2)3 in freshly distd. C6H5NO2; addn. of an excess of NaF or a small amount of H2O or HF under exclusion of H2O (drying tube with P2O5); heating on refluxing;; fractionation;;
In gas byproducts: NaCl; (NPCl2)3 gas was passed over heated NaF at 550°C; monitoring by IR spectroscopy;
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

potassium thioacyanate
333-20-0

potassium thioacyanate

A

hexaisothiocyanatocyclotriphosphazene
1858-42-0

hexaisothiocyanatocyclotriphosphazene

B

potassium chloride

potassium chloride

Conditions
ConditionsYield
In acetoneA n/a
B 99%
In acetoneA n/a
B 99%
potassium fluoride

potassium fluoride

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

Conditions
ConditionsYield
With 4-n-butyl-4-methylmorpholinium hydroxide In acetonitrile at 30℃; for 2h; Temperature; Solvent; Reagent/catalyst; Ionic liquid;98.7%
Reflux;90%
With catalyst: 18-crown-6 In tetrahydrofuran refluxing KF with catalytic amt. of crown for 20 min, dropwise addn. of 0.1 equiv. of N3P3Cl6, refluxing (1 h); fractional distn.;
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

4-bromo-phenol
106-41-2

4-bromo-phenol

hexakis(4-bromophenoxy)cyclotriphosphazene
4376-72-1

hexakis(4-bromophenoxy)cyclotriphosphazene

Conditions
ConditionsYield
With potassium carbonate In acetone for 18h; Inert atmosphere; Reflux;98%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

hexafluorophosphazene
15599-91-4

hexafluorophosphazene

Conditions
ConditionsYield
With potassium fluoride; Triethylene glycol dimethyl ether; ethanol In hexane at 0 - 30℃; for 2h; Solvent; Reagent/catalyst; Temperature;97.2%
With sodium fluoride In diethylene glycol dimethyl ether at 100℃; for 2h; Temperature; Solvent; Inert atmosphere;86%
In not given (N2); as in: (Schmutzler, R. Inorg Synth. 1967, 9, 75); fractional distn.;
With sodium fluoride In ethyl acetate at 10℃; for 3h; Solvent; Temperature; Reflux;130 g
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

isobutylamine
78-81-9

isobutylamine

hexakis(iso-butylamino) cyclotriphosphazene
101201-65-4

hexakis(iso-butylamino) cyclotriphosphazene

Conditions
ConditionsYield
In toluene for 24h; Reflux;97%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

2,2'-dihydroxybiphenyl
1806-29-7

2,2'-dihydroxybiphenyl

2,2-dichloro-4,4,6,6-bis[spiro(2',2''-dioxy-1'',1''-biphenyl)]cyclotriphosphazene
128175-80-4

2,2-dichloro-4,4,6,6-bis[spiro(2',2''-dioxy-1'',1''-biphenyl)]cyclotriphosphazene

Conditions
ConditionsYield
With potassium carbonate In tetrahydrofuran at 65℃; for 12h; Inert atmosphere;95.4%
With potassium carbonate In acetone at 0 - 20℃; for 24h; Inert atmosphere;92%
With potassium carbonate In acetone at 0 - 20℃; for 24h; Inert atmosphere;92%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

phenol
108-95-2

phenol

2,2,4,4,6,6-hexaphenoxycyclotriphosphazene
1184-10-7

2,2,4,4,6,6-hexaphenoxycyclotriphosphazene

Conditions
ConditionsYield
Stage #1: phenol With tetrabutylammomium bromide; chlorobenzene; potassium hydroxide at 50℃; for 0.5h;
Stage #2: 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine at 90℃; for 9h; Reagent/catalyst; Temperature;
95.04%
Stage #1: phenol With sodium hydride In tetrahydrofuran Inert atmosphere;
Stage #2: 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine In tetrahydrofuran at 70℃; Inert atmosphere;
85%
With potassium carbonate In tetrahydrofuran at 50℃; for 24h;85.6%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

ammonia
7664-41-7

ammonia

2,2-diamino-4,4,6,6-tetrachlorocyclotriphosphazene
10535-05-4

2,2-diamino-4,4,6,6-tetrachlorocyclotriphosphazene

Conditions
ConditionsYield
In diethyl ether at 0℃; for 1.5h;95%
In diethyl ether; ammonia NH3 (liquid); molar ratio P3N3Cl2:NH3 1:4;
In diethyl ether Schlenk technique;
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

4-hydroxy-benzaldehyde
123-08-0

4-hydroxy-benzaldehyde

hexakis(4-formylphenoxy)cyclotriphosphazene
77958-57-7

hexakis(4-formylphenoxy)cyclotriphosphazene

Conditions
ConditionsYield
With caesium carbonate In tetrahydrofuran at 20℃; for 48.5h; Reagent/catalyst; Cooling with ice;94%
Stage #1: 4-hydroxy-benzaldehyde With triethylamine In acetone at 0℃; for 0.5h;
Stage #2: 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine In acetone at 0 - 20℃;
94.19%
With potassium carbonate In tetrahydrofuran for 24h; Reflux;92.8%
In tetrahydrofuran for 48h; Reflux;82%
With sodium hydride In tetrahydrofuran at 65℃; for 48h; Inert atmosphere;
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

methyl 4-hydroxylbenzoate
99-76-3

methyl 4-hydroxylbenzoate

hexa(4-carbomethoxyphenoxy)cyclotriphosphazene

hexa(4-carbomethoxyphenoxy)cyclotriphosphazene

Conditions
ConditionsYield
With potassium carbonate In acetone at 80℃;93.6%
With caesium carbonate In tetrahydrofuran for 16h; Reflux; Schlenk technique; Inert atmosphere;79%
hydrogenchloride
7647-01-0

hydrogenchloride

gallium(III) trichloride

gallium(III) trichloride

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

Cl6N3P3*Cl4Ga(1-)*H(1+)

Cl6N3P3*Cl4Ga(1-)*H(1+)

Conditions
ConditionsYield
In chloroform at 20℃; Glovebox; Darkness;92%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

2,2,4,4-tetraamino-6,6-dichlorocyclotriphosphazene

2,2,4,4-tetraamino-6,6-dichlorocyclotriphosphazene

Conditions
ConditionsYield
With ammonia at 20℃; for 1.5h;92%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

1-amino-2-propene
107-11-9

1-amino-2-propene

hexakis(allylamino)cyclotriphosphazene
986-11-8

hexakis(allylamino)cyclotriphosphazene

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran for 4h; Inert atmosphere; Reflux;92%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

4-Vinylphenol
2628-17-3

4-Vinylphenol

2,2,4,4,6,6-hexakis-(4-vinyl-phenoxy)-2λ5,4λ5,6λ5-[1,3,5,2,4,6]triazatriphosphinine

2,2,4,4,6,6-hexakis-(4-vinyl-phenoxy)-2λ5,4λ5,6λ5-[1,3,5,2,4,6]triazatriphosphinine

Conditions
ConditionsYield
With potassium carbonate In tetrahydrofuran at 20 - 60℃; for 23h;91%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

ammonia
7664-41-7

ammonia

A

2,2-diamino-4,4,6,6-tetrachlorocyclotriphosphazene
10535-05-4

2,2-diamino-4,4,6,6-tetrachlorocyclotriphosphazene

B

2,2,4,4-tetraamino-6,6-dichlorocyclotriphosphazene

2,2,4,4-tetraamino-6,6-dichlorocyclotriphosphazene

Conditions
ConditionsYield
In acetonitrile at 20℃; for 1.5h; Solvent;A 1%
B 91%
In diethyl ether at 20℃; for 1.5h; Solvent;A 80%
B 3%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

Boc-Tyr-OMe

Boc-Tyr-OMe

C90H120N9O30P3

C90H120N9O30P3

Conditions
ConditionsYield
With caesium carbonate In tetrahydrofuran at 20℃; for 16h; Schlenk technique; Inert atmosphere;91%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

2,2'-diaminodiethyl ether
2752-17-2

2,2'-diaminodiethyl ether

1,9,11,11,13,21,23,23-Octachloro-5,17-dioxa-2,8,10,12,14,20,22,24,25,26-decaaza-1λ5,9λ5,11λ5,13λ5,21λ5,23λ5-hexaphospha-tricyclo[19.3.1.19,13]hexacosa-1(25),9,11,13(26),21,23-hexaene
129577-49-7

1,9,11,11,13,21,23,23-Octachloro-5,17-dioxa-2,8,10,12,14,20,22,24,25,26-decaaza-1λ5,9λ5,11λ5,13λ5,21λ5,23λ5-hexaphospha-tricyclo[19.3.1.19,13]hexacosa-1(25),9,11,13(26),21,23-hexaene

Conditions
ConditionsYield
In diethyl ether; water Ambient temperature;90%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

3,6-dioxa-1,8-diaminooctane
929-59-9

3,6-dioxa-1,8-diaminooctane

1,12,14,14,16,27,29,29-Octachloro-5,8,20,23-tetraoxa-2,11,13,15,17,26,28,30,31,32-decaaza-1λ5,12λ5,14λ5,16λ5,27λ5,29λ5-hexaphospha-tricyclo[25.3.1.112,16]dotriaconta-1(31),12,14,16(32),27,29-hexaene
129577-50-0

1,12,14,14,16,27,29,29-Octachloro-5,8,20,23-tetraoxa-2,11,13,15,17,26,28,30,31,32-decaaza-1λ5,12λ5,14λ5,16λ5,27λ5,29λ5-hexaphospha-tricyclo[25.3.1.112,16]dotriaconta-1(31),12,14,16(32),27,29-hexaene

Conditions
ConditionsYield
In diethyl ether; water Ambient temperature;90%
aluminium trichloride
7446-70-0

aluminium trichloride

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

(PCl2N)3AlCl3

(PCl2N)3AlCl3

Conditions
ConditionsYield
In dichloromethane (under vac.); AlCl3 reacted with (PCl2N)3 in CH2Cl2;90%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

tetraethylene glycol monomethyl ether
23783-42-8

tetraethylene glycol monomethyl ether

2,2,4,4,6,6-hexakis-(2-(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)ethoxy)cyclotriphosphazene
1289636-24-3

2,2,4,4,6,6-hexakis-(2-(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)ethoxy)cyclotriphosphazene

Conditions
ConditionsYield
Stage #1: tetraethylene glycol monomethyl ether With sodium hydride In 1,4-dioxane at 50℃; for 24h; Inert atmosphere;
Stage #2: 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine In 1,4-dioxane at 60℃; for 48h; Inert atmosphere;
90%
hydrogenchloride
7647-01-0

hydrogenchloride

aluminum (III) chloride
7446-70-0, 7784-13-6

aluminum (III) chloride

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

Cl6N3P3*AlCl4(1-)*H(1+)

Cl6N3P3*AlCl4(1-)*H(1+)

Conditions
ConditionsYield
In chloroform at 21.84℃; Schlenk technique; Glovebox;90%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

2-[tricarbonyl(η(6)-phenoxy)chromium]ethanol
134177-52-9

2-[tricarbonyl(η(6)-phenoxy)chromium]ethanol

sodium hydride
7646-69-7

sodium hydride

N3P3{(η6-OCH2CH2OC6H5)Cr(CO)3}6
134208-38-1

N3P3{(η6-OCH2CH2OC6H5)Cr(CO)3}6

Conditions
ConditionsYield
In tetrahydrofuran (N2), added at 0. degree.C, warmed to 25°C and stirred for 5 h, added dropwise N3P3Cl6, stirred at 40-45°C for 12 h; removed solvent in vac., column chromy.; elem. anal., IR, mass. spectra,NMR;89%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

(Z)-oct-5-en-1-ol
64275-73-6

(Z)-oct-5-en-1-ol

2,2,4,4,6,6-hexakis-(cis-5-octenyl-1-oxy)cyclotriphosphazene
1289636-29-8

2,2,4,4,6,6-hexakis-(cis-5-octenyl-1-oxy)cyclotriphosphazene

Conditions
ConditionsYield
Stage #1: (Z)-oct-5-en-1-ol With sodium hydride In 1,4-dioxane at 50℃; for 24h; Inert atmosphere;
Stage #2: 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine In 1,4-dioxane at 60℃; for 48h; Inert atmosphere;
89%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

2-Allylphenol
1745-81-9

2-Allylphenol

C54H54N3O6P3

C54H54N3O6P3

Conditions
ConditionsYield
With sodium hydroxide In tetrahydrofuran at 20 - 60℃; for 13.5h;89%
5,5-difluoro-10-(4-hydroxyphenyl)-5H-dipyrrolo[1,2-c :2’,1’-f][1,3,2]diazaborinin-4-ium-5-uide

5,5-difluoro-10-(4-hydroxyphenyl)-5H-dipyrrolo[1,2-c :2’,1’-f][1,3,2]diazaborinin-4-ium-5-uide

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

hexakis[4,4-difluoroboryl-8-(p-phenoxy)-4-bora-3a,4a-diaza-s-indacene]cyclotriphosphazene

hexakis[4,4-difluoroboryl-8-(p-phenoxy)-4-bora-3a,4a-diaza-s-indacene]cyclotriphosphazene

Conditions
ConditionsYield
With Cs2CO3 In tetrahydrofuran hydroxyphenyl and Cs2CO3 was added to hexachlorotriphosphazene in THF at0°C, stirred for 6 h at 50°C; concd. in vac., column chromy. (silica, CH2Cl2), evapd. in vac.;88%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

2,2'-dihydroxybiphenyl
1806-29-7

2,2'-dihydroxybiphenyl

4',4',6',6'-tetrachloro-4'λ5,6λ5,6'λ5-spiro[dibenzo[d,f][1–3]-dioxaphosphepine-6,2'-[1–6]triazatriphosphinine]
128175-79-1

4',4',6',6'-tetrachloro-4'λ5,6λ5,6'λ5-spiro[dibenzo[d,f][1–3]-dioxaphosphepine-6,2'-[1–6]triazatriphosphinine]

Conditions
ConditionsYield
In acetone at 20℃; for 0.25h;87%
With caesium carbonate In tetrahydrofuran at 20℃; for 10h;
With potassium carbonate
C16H20NPO4
918636-17-6

C16H20NPO4

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

C96H114N9O24P9

C96H114N9O24P9

Conditions
ConditionsYield
With caesium carbonate In acetonitrile at 20℃; for 24h;87%
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

aluminium bromide
7727-15-3

aluminium bromide

(PCl2N)3AlBr3

(PCl2N)3AlBr3

Conditions
ConditionsYield
In dichloromethane (under vac.); AlBr3 reacted with (PCl2N)3 in CH2Cl2;87%
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