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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

4-Tolyl ether

Cas:1579-40-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

Item Quality Standard Test Result Appearance colorless clear liquid colorless clear liquid Assay %

high purity 1579-40-4 P-tolyl ether

Cas:1579-40-4

Min.Order:1 Kilogram

FOB Price: $1.9 / 2.5

Type:Trading Company

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 4-Tolyl Ether

Cas:1579-40-4

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

4-Tolyl ether CAS 1579-40-4 p-Tolyl Ether CAS no 1579-40-4 Di-p-tolyl ether 4-Tolyl ether Manufacturer High quality Best price In stock factory CAS 1579-40-4 4-Tolyl ether COA TDS price MSDS highly quality and immedaite delivery 4-Tol

4-Tolyl ether CAS 1579-40-4 p-Tolyl Ether CAS no 1579-40-4 Di-p-tolyl ether

Cas:1579-40-4

Min.Order:5 Kiloliter

FOB Price: $3.5 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

4-Tolyl ether Basic information Product Name: 4-Tolyl ether Synonyms: 1,1’-oxybis(4-methyl-benzen;1,1’-oxybis(4-methylbenzene);1,1’-oxybis[4-methy

best offer 4-Tolyl ether

Cas:1579-40-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 1579-40-4 with best price

Cas:1579-40-4

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzene,1,1'-oxybis[4-methyl- 1579-40-4

Cas:1579-40-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

4-Tolyl ether CAS:1579-40-4 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediat

4-Tolyl ether CAS:1579-40-4

Cas:1579-40-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzene,1,1'-oxybis[4-methyl-

Cas:1579-40-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

4-Tolyl ether CAS:1579-40-4

Cas:1579-40-4

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

4-Tolyl Ether

Cas:1579-40-4

Min.Order:0

Negotiable

Type:Manufacturers

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Tolyl ether

Cas:1579-40-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 4-Tolyl Ether

Cas:1579-40-4

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Henan Sinotech Import&Export Corporation

Chemical Names: p-Tolyl ether, 4,4'-Dimethyldiphenyl ether Chemical Structure: Molecular Formula: C14H14O CAS: 1579-40-4 Pr

4,4'-Dimethyldiphenyl ether

Cas:1579-40-4

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Henan Wentao Chemical Product Co., Ltd.

1)quick response within 12 hours; 2)quality guarantee: all products are strictly tested by our qc, confirmed by qa and approved by third party lab in china, usa, canada, germany, uk, italy, france etc. 3) oem/odm available; 4) rea

best offer 4-Tolyl etherCAS NO.: 1579-40-4

Cas:1579-40-4

Min.Order:1 Gram

FOB Price: $2.0

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Product Name: 4-Tolyl ether Synonyms: 1,1’-oxybis(4-methyl-benzen;1,1’-oxybis(4-methylbenzene);1,1’-oxybis[4-methyl-benzen;Benzene, 1,1'-oxybis*4-methyl-;Benzene, 1,1'-oxybis[4-methyl-;Bis(4-methylphenyl) ether;bis(4-m

4-Tolyl ether

Cas:1579-40-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

4-Tolyl ether

Cas:1579-40-4

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Di-p-tolyl ether

Cas:1579-40-4

Min.Order:0

Negotiable

Type:Manufacturers

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

P-tolyl ether

Cas:1579-40-4

Min.Order:0

Negotiable

Type:Other

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GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

di-4-Tolyl ether

Cas:1579-40-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

4-Tolyl ether

Cas:1579-40-4

Min.Order:0

Negotiable

Type:Manufacturers

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Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

4-Tolyl Ether

Cas:1579-40-4

Min.Order:0

Negotiable

Type:Manufacturers

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Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

P-tolyl ether

Cas:1579-40-4

Min.Order:0

Negotiable

Type:Manufacturers

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Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

4-Tolyl ether

Cas:1579-40-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Benzene,1,1'-oxybis[4-methyl-

Cas:1579-40-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

4-tolyl ether

Cas:1579-40-4

Min.Order:0

Negotiable

Type:Other

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Luyunjia Chemistry Xiamen Limited

Specifications CAS No.: 1579-40-4 Other Names: 4-Tolyl ether MF: C14H14O EINECS No.: 216-423-0 Place of Origin: Shandong, China (Mainland) Grade Standard: Agriculture Grade, Electron Grade, Food Grade, Industrial Grade, Medicine Grade, Re

1579-40-4 P-tolyl ether

Cas:1579-40-4

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Wuhan Circle Star Chem-medical Technology co.,Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:White to Off-White Solid Storage:Keep it in dry,shady and cool place Package:as your requirement Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by Sea

4-Tolyl ether

Cas:1579-40-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fandachem Co.,Ltd

4-Tolyl ether cas 1579-40-4Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

4-Tolyl ether cas 1579-40-4

Cas:1579-40-4

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

4-Tolyl ether

Cas:1579-40-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Synthetic route

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
With copper diacetate; water; triethylamine In dichloromethane; acetonitrile at 25℃; for 6h;97%
Multi-step reaction with 2 steps
1: 85 percent / H2O2 / H2O / 20 °C
2: molecular sieves 4 Angstroem; Cu(OAc)2; Et3N / CH2Cl2 / 20 °C
View Scheme
p-cresol
106-44-5

p-cresol

4-tolyl iodide
624-31-7

4-tolyl iodide

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
With aluminum oxide; potassium fluoride; copper(l) iodide In toluene at 100 - 110℃; for 22h;95%
With caesium carbonate In N,N-dimethyl-formamide at 130℃; for 24h; Ullmann Condensation;90%
With potassium phosphate; copper(l) iodide; tetrabutylammomium bromide In N,N-dimethyl-formamide for 22h; Ullmann coupling; Heating;87%
p-cresol
106-44-5

p-cresol

2,4-dimethoxyphenyl(4-methylphenyl)iodonium tosylate
1428064-59-8

2,4-dimethoxyphenyl(4-methylphenyl)iodonium tosylate

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 50℃; for 6h; regioselective reaction;93%
p-cresol
106-44-5

p-cresol

para-bromotoluene
106-38-7

para-bromotoluene

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
With potassium phosphate In N,N-dimethyl-formamide at 80℃; for 4h; Ullmann Condensation;90%
With potassium carbonate In water for 2.41667h; Ullmann Condensation; Reflux; Green chemistry;87%
With potassium phosphate; 2-((o-toluidino)methyl)phenol; copper(l) chloride In acetonitrile at 81℃; for 24h; Catalytic behavior; Ullmann Condensation; Schlenk technique; Inert atmosphere;85%
4-tolyl iodide
624-31-7

4-tolyl iodide

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
With potassium phosphate; copper(l) iodide; 2,2,6,6-tetramethylheptane-3,5-dione; water In ethanol at 130℃; for 30h; Inert atmosphere; Sealed tube; chemoselective reaction;90%
Multi-step reaction with 2 steps
1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0.5 h / 20 °C
2: sodium hydroxide / dichloromethane / 22 h / 20 °C
View Scheme
Multi-step reaction with 2 steps
1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0.5 h / 20 °C
2: sodium hydroxide; piperidine / dichloromethane / 14 h / 40 °C
View Scheme
p-cresol
106-44-5

p-cresol

bis(4-methylphenyl)(trifluoromethanesulfonato)-λ3-iodane

bis(4-methylphenyl)(trifluoromethanesulfonato)-λ3-iodane

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
With potassium tert-butylate In tetrahydrofuran at 40℃;88%
para-bromotoluene
106-38-7

para-bromotoluene

tert-Butyl(dimethyl)-(4-methylphenoxy)silane
62790-85-6

tert-Butyl(dimethyl)-(4-methylphenoxy)silane

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
With copper(l) iodide; caesium carbonate In N,N-dimethyl-formamide at 100℃; for 8h;81%
para-bromotoluene
106-38-7

para-bromotoluene

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
With potassium phosphate; tri-tert-butyl phosphine; tris-(dibenzylideneacetone)dipalladium(0) In 1,4-dioxane at 100℃; for 20h;78%
para-chlorotoluene
106-43-4

para-chlorotoluene

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
With potassium phosphate; tri-tert-butyl phosphine; tris-(dibenzylideneacetone)dipalladium(0) In 1,4-dioxane at 100℃; for 20h;72%
piperazine
110-85-0

piperazine

para-bromotoluene
106-38-7

para-bromotoluene

A

p-cresol
106-44-5

p-cresol

B

1,4-bis(4-methylphenyl)piperazine
3367-48-4

1,4-bis(4-methylphenyl)piperazine

C

toluene
108-88-3

toluene

D

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
With Adipic acid; N'-phenyloxalyl bishydrazide; copper diacetate; sodium acetate; cetyltrimethylammonim bromide; 2,5-hexanedione; potassium hydroxide In water at 100℃; for 3h; Inert atmosphere;A 21 %Chromat.
B 68%
C 13 %Chromat.
D 11 %Chromat.
sodium 4-methylphenoxide
1121-70-6

sodium 4-methylphenoxide

poly(styrene p-tolyliodonium) hydrogensulfate

poly(styrene p-tolyliodonium) hydrogensulfate

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 100℃; for 24h;65%
p-cresol
106-44-5

p-cresol

para-chlorotoluene
106-43-4

para-chlorotoluene

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
Stage #1: para-chlorotoluene With potassium phosphate; N,N'-bis(2,5-dimethylpyrrol-1-yl)oxalamide; copper(I) bromide In dimethyl sulfoxide at 20℃; Inert atmosphere; Sealed tube; Glovebox;
Stage #2: p-cresol In dimethyl sulfoxide at 120℃; for 24h; Sealed tube; Inert atmosphere; Glovebox;
62%
para-bromotoluene
106-38-7

para-bromotoluene

diethylamine
109-89-7

diethylamine

A

p-cresol
106-44-5

p-cresol

B

N,N-diethyl-p-toluidine
613-48-9

N,N-diethyl-p-toluidine

C

toluene
108-88-3

toluene

D

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
With Adipic acid; N'-phenyloxalyl bishydrazide; copper diacetate; sodium acetate; cetyltrimethylammonim bromide; 2,5-hexanedione; potassium hydroxide In water at 100℃; for 3h; Inert atmosphere;A 18 %Chromat.
B 28%
C 5 %Chromat.
D 26 %Chromat.
bis(4-methylphenyl)(trifluoromethanesulfonato)-λ3-iodane

bis(4-methylphenyl)(trifluoromethanesulfonato)-λ3-iodane

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
With piperidine; sodium hydroxide In dichloromethane at 40℃; for 14h;11%
furan
110-00-9

furan

bis(4-methylphenyl)(trifluoromethanesulfonato)-λ3-iodane

bis(4-methylphenyl)(trifluoromethanesulfonato)-λ3-iodane

A

1,4-dihydro-1,4-epoxy-6-methylnaphthalene
19061-31-5

1,4-dihydro-1,4-epoxy-6-methylnaphthalene

B

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
With sodium hydroxide In dichloromethane at 20℃; for 22h; Diels-Alder Cycloaddition;A 11%
B 11%
p-cresol
106-44-5

p-cresol

carvacrol
499-75-2

carvacrol

A

(5-isopropyl-2-methyl-phenyl)-p-tolyl ether
98511-24-1

(5-isopropyl-2-methyl-phenyl)-p-tolyl ether

B

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
at 440 - 450℃;
p-cresol
106-44-5

p-cresol

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
at 400℃; durch Ueberleiten ueber ThO2;
at 400℃; beim Ueberleiten ueber ThO2;
With copper diacetate; 4 A molecular sieve; triethylamine In dichloromethane at 20℃;
para-bromotoluene
106-38-7

para-bromotoluene

potassium p-cresolate
1192-96-7

potassium p-cresolate

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
With p-cresol; copper at 200 - 240℃;
2-(5-methyl-2-p-tolyloxy-benzoyl)-benzoic acid
860595-00-2

2-(5-methyl-2-p-tolyloxy-benzoyl)-benzoic acid

A

benzene-1,2-dicarboxylic acid
88-99-3

benzene-1,2-dicarboxylic acid

B

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
in der Kalischmelze;
aluminium tris(p-methylphenoxide)
72269-62-6

aluminium tris(p-methylphenoxide)

A

p-cresol
106-44-5

p-cresol

B

2,7-dimethyl-xanthene
13333-92-1

2,7-dimethyl-xanthene

C

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
bei der trocknen Destillation;
p-cresol
106-44-5

p-cresol

p-toluidine
106-49-0

p-toluidine

A

4-Methyl-2-p-tolyl-phenol
107775-15-5

4-Methyl-2-p-tolyl-phenol

B

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
With sulfuric acid at 95℃; Diazotization;
tris(4-methylphenyl)sulfonium bromide
3744-11-4

tris(4-methylphenyl)sulfonium bromide

A

di-(p-tolyl)sulfane
620-94-0

di-(p-tolyl)sulfane

B

toluene
108-88-3

toluene

C

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
With sodium isopropylate In isopropyl alcohol at 72℃; for 23h; Product distribution; Mechanism; var. of solvent, reagent, temp., time; D-incorporation into toluene;A 100 % Chromat.
B 33 % Chromat.
C 35 % Chromat.
4,4'-oxybis-((bromomethyl)benzene)
4542-75-0

4,4'-oxybis-((bromomethyl)benzene)

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
With copper(II) sulfate; acetic acid; zinc
potassium p-cresolate
1192-96-7

potassium p-cresolate

bis(4-methylphenyl)iodonium bromide
6293-68-1

bis(4-methylphenyl)iodonium bromide

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
In N,N-dimethyl-formamide
tris(4-methylphenyl)sulfonium bromide
3744-11-4

tris(4-methylphenyl)sulfonium bromide

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
With potassium hydroxide at 150 - 160℃;
para-bromotoluene
106-38-7

para-bromotoluene

sodium 4-methylphenoxide
1121-70-6

sodium 4-methylphenoxide

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
With copper(I) oxide In N,N-dimethyl acetamide at 166℃;
3-Methylindole
83-34-1

3-Methylindole

p-tolyllead triacetate
3076-56-0

p-tolyllead triacetate

A

1-(4-methyl-phenyl)-3-methyl-1H-indole

1-(4-methyl-phenyl)-3-methyl-1H-indole

B

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
With copper diacetate; sodium hydride In dichloromethane 1.) r.t., 10 min, 2.) 50 deg C, 16 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
p-tolyllead triacetate
3076-56-0

p-tolyllead triacetate

A

1-(4-methyl-phenyl)-3-methyl-1H-indole

1-(4-methyl-phenyl)-3-methyl-1H-indole

B

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
With 3-Methylindole; copper diacetate; sodium hydride In dichloromethane 1.) r.t., 10 min, 2.) 50 deg C, 16 h; Yield given. Yields of byproduct given;
methanol
67-56-1

methanol

tri-p-tolyloxonium tetrafluoroborate

tri-p-tolyloxonium tetrafluoroborate

A

4-Methylanisole
104-93-8

4-Methylanisole

B

1-methoxy-3-methyl-benzene
100-84-5

1-methoxy-3-methyl-benzene

C

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

Conditions
ConditionsYield
With sodium hydroxide In water for 10h; Heating; Yield given. Title compound not separated from byproducts;
1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

2,8-Dimethyl-5-hydroxy-5-oxo-Pv-dibenzo<1,4>oxaphosphorin
15320-91-9

2,8-Dimethyl-5-hydroxy-5-oxo-Pv-dibenzo<1,4>oxaphosphorin

Conditions
ConditionsYield
Stage #1: 1,1'-oxybis(4-methyl-benzene) With aluminium trichloride; phosphorus trichloride Heating;
Stage #2: With sodium hydroxide; dihydrogen peroxide In water for 0.25h;
97.2%
Multi-step reaction with 3 steps
1: phosphorus trichloride; aluminium trichloride / 22 h / 80 °C
2: 10.2 g / H2O / 0 °C
3: 92 percent / O2; KOH / H2O
View Scheme
Multi-step reaction with 2 steps
1: PCl3, AlCl3
2: aq. Br2
View Scheme
phenylphosphinic acid
1779-48-2

phenylphosphinic acid

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

2,8-dimethyl-10-phenylphenoxaphosphinine 10-oxide
21990-63-6

2,8-dimethyl-10-phenylphenoxaphosphinine 10-oxide

Conditions
ConditionsYield
With dmap; trifluoromethylsulfonic anhydride In cis-1,2-Dichloroethylene at 120℃; for 16h; Schlenk technique; Inert atmosphere;94%
1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

methyl cyclohexane
82166-21-0

methyl cyclohexane

Conditions
ConditionsYield
With platinum on activated charcoal; N-methyldiethanolamine trifluoromethanesulfonate; hydrogen at 150℃; under 7500.75 Torr; for 6h; Autoclave;93.2%
With carbon nanotubes-supported ruthenium; hydrogen In dodecane; water at 220℃; under 37503.8 Torr; for 3h; Autoclave;89 %Chromat.
With hydrogen at 130℃; under 15001.5 Torr; for 6h; Ionic liquid; Autoclave; Schlenk technique;94.3 %Chromat.
With hydrogen In decalin at 200℃; under 75007.5 Torr; for 3h;
1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

4,4'-oxybis-((bromomethyl)benzene)
4542-75-0

4,4'-oxybis-((bromomethyl)benzene)

Conditions
ConditionsYield
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane at 80 - 90℃; for 6.5h; Inert atmosphere;93%
With bromine; ethylene dibromide; dibenzoyl peroxide Irradiation.Sonnenlicht;
With N-Bromosuccinimide; dibenzoyl peroxide
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane at 80℃;
With hydrogen bromide; dihydrogen peroxide In 1,2-dichloro-ethane for 12h; Cooling with ice; Irradiation;
1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

oxybis(benzoic acid)
2215-89-6

oxybis(benzoic acid)

Conditions
ConditionsYield
With dihydrogen peroxide; sodium carbonate at 100℃; under 7500.75 Torr; for 18h; Reagent/catalyst; Pressure;93%
With pyridine; cobalt(III) acetylacetonate; dihydrogen peroxide; sodium carbonate In acetic acid at 100℃; under 15001.5 Torr; for 6h; Reagent/catalyst; Temperature; Solvent; Pressure;92%
With 2-chloroanthracene-9,10-dione; water; oxygen; trifluoroacetic acid In ethyl acetate for 72h; Irradiation;70%
1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

2,8-dimethyl-10,10-dichlorophenoxatellurine
21797-71-7

2,8-dimethyl-10,10-dichlorophenoxatellurine

Conditions
ConditionsYield
With tellurium tetrachloride at 200℃; for 4h;93%
sodium methylate
124-41-4

sodium methylate

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

4,4'-Bis-methoxymethyl diphenyl ether
2509-26-4

4,4'-Bis-methoxymethyl diphenyl ether

Conditions
ConditionsYield
Stage #1: 1,1'-oxybis(4-methyl-benzene) With 2,2'-azobis(isobutyronitrile); bromine In benzene at 80℃; for 3h; Reflux;
Stage #2: sodium methylate In methanol at 45℃; for 2h; Temperature; Reflux;
92.8%
sodium isopropylate
683-60-3

sodium isopropylate

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

4,4'-diisopropoxymethyldiphenyl ether

4,4'-diisopropoxymethyldiphenyl ether

Conditions
ConditionsYield
Stage #1: 1,1'-oxybis(4-methyl-benzene) With 2,2'-azobis(isobutyronitrile); bromine In tetrachloromethane at 80℃; for 4.1h; Reflux;
Stage #2: sodium isopropylate In isopropyl alcohol at 50℃; for 3h; Reflux;
92.8%
benzoic acid
65-85-0

benzoic acid

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

2, 7-dimethyl-9-phenyl xanthen-9-ol
854864-70-3

2, 7-dimethyl-9-phenyl xanthen-9-ol

Conditions
ConditionsYield
With trichlorophosphate; zinc(II) chloride at 95℃; for 2h; Product distribution / selectivity; Friedel Crafts Reaction;91.8%
With zinc(II) chloride; trichlorophosphate at 95℃; for 4h;66%
With zinc(II) chloride; trichlorophosphate at 80 - 95℃;
With zinc(II) chloride; trichlorophosphate at 95℃; for 4h;
sodium ethanolate
141-52-6

sodium ethanolate

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

4,4'-diethoxymethyldiphenyl ether
3287-73-8

4,4'-diethoxymethyldiphenyl ether

Conditions
ConditionsYield
Stage #1: 1,1'-oxybis(4-methyl-benzene) With 2,2'-azobis(isobutyronitrile); bromine In tetrachloromethane at 80℃; for 3.2h; Reflux;
Stage #2: sodium ethanolate In ethanol at 46℃; for 2h; Reflux;
91.2%
oxalyl dichloride
79-37-8

oxalyl dichloride

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

2,7-dimethylxanthen-9-one
7573-15-1

2,7-dimethylxanthen-9-one

Conditions
ConditionsYield
With aluminium trichloride In carbon disulfide at 0 - 20℃; for 18h;90%
With aluminum (III) chloride In dichloromethane at 0℃; Friedel Crafts reaction; Inert atmosphere; Reflux;77%
With carbon disulfide; aluminium trichloride
benzoyl chloride
98-88-4

benzoyl chloride

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

2-<(p-methylphenyl)oxy>-5-methylbenzophenone
134312-16-6

2-<(p-methylphenyl)oxy>-5-methylbenzophenone

Conditions
ConditionsYield
With aluminium trichloride In carbon disulfide at 0℃; for 3h;90%
methanol
67-56-1

methanol

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

dimethyl 4,4'-oxydibenzoate
14387-30-5

dimethyl 4,4'-oxydibenzoate

Conditions
ConditionsYield
With hydrogenchloride; oxygen; 9-(2-mesityl)-10-methylacridinium perchlorate at 20℃; under 760.051 Torr; for 30h; Schlenk technique; Irradiation; Green chemistry;90%
With 2,3-dicarboxyanthraquinone; oxygen for 48h; Irradiation;80%
1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

p-cresol
106-44-5

p-cresol

Conditions
ConditionsYield
With lithium aluminium tetrahydride; iron(III)-acetylacetonate; sodium t-butanolate In toluene at 140℃; for 24h; Inert atmosphere;88%
1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

4-(4-formylphenoxy)benzaldehyde
2215-76-1

4-(4-formylphenoxy)benzaldehyde

Conditions
ConditionsYield
With sodium persulfate; copper diacetate; iron(II) sulfate; dimethyl sulfoxide In water; acetonitrile at 75℃; for 0.75h;87%
With sodium persulfate; dimethylsulfide; copper diacetate; iron(II) sulfate In water; acetonitrile at 75℃; for 1.08333h;84%
With sodium persulfate; racemic methyl phenyl sulfoxide; copper diacetate; iron(II) sulfate In water; acetonitrile at 75℃; for 0.75h;84%
Multi-step reaction with 2 steps
1: 1,2-dibromo-ethane; dibenzoyl peroxide; bromine / Irradiation.Sonnenlicht
2: CHCl3 / Erhitzen des Reaktionsprodukts mit wss. Essigsaeure und anschliessend mit wss. HCl
View Scheme
1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

4-nitro-benzoic acid
62-23-7

4-nitro-benzoic acid

2,7-dimethyl-9-(4-nitrophenyl)-xanthen-9-ol
1392228-32-8

2,7-dimethyl-9-(4-nitrophenyl)-xanthen-9-ol

Conditions
ConditionsYield
With zinc(II) chloride; trichlorophosphate at 95℃; for 4h;86%
5-t-butylisophthalic acid
2359-09-3

5-t-butylisophthalic acid

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

9,9'-(5-(tert-butyl)-1,3-phenylene)bis(2,7-dimethyl-9H-xanthen-9-ol)

9,9'-(5-(tert-butyl)-1,3-phenylene)bis(2,7-dimethyl-9H-xanthen-9-ol)

Conditions
ConditionsYield
With zinc(II) chloride; trichlorophosphate In neat (no solvent) at 100℃; for 24h; Inert atmosphere;85%
1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

4-(4'-methylphenoxy)benzonitrile
37563-42-1

4-(4'-methylphenoxy)benzonitrile

Conditions
ConditionsYield
With sodium azide; copper(ll) sulfate pentahydrate; [bis(acetoxy)iodo]benzene In acetonitrile at -40 - 25℃; Inert atmosphere;83%
1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

2,8-dimethyldibenzofuran
1136-79-4

2,8-dimethyldibenzofuran

Conditions
ConditionsYield
With oxygen; palladium diacetate at 55℃;82%
With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; copper dichloride 1.) Et2O, cyclohexane, RT, 16 h, 2.) Et2O, cyclohexane, 5 deg C, 3 h; Yield given. Multistep reaction;
1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

cis-4-methyl-N-(4-methylcyclohexyl)benzenamine

cis-4-methyl-N-(4-methylcyclohexyl)benzenamine

trans-4-methyl-N-(4-methylcyclohexyl)benzenamine

trans-4-methyl-N-(4-methylcyclohexyl)benzenamine

C

toluene
108-88-3

toluene

Conditions
ConditionsYield
With sodium tetrahydroborate; 10 wt% Pd(OH)2 on carbon; ammonia In water; m-xylene at 150℃; for 24h; Inert atmosphere; Sealed tube;A 82%
B n/a
C 88 %Chromat.
4-(1,1-dimethylethyl)benzoic acid
98-73-7

4-(1,1-dimethylethyl)benzoic acid

1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

2,7-dimethyl-9-(4-t-butyl)phenylxanthene-9-ol
862125-81-3

2,7-dimethyl-9-(4-t-butyl)phenylxanthene-9-ol

Conditions
ConditionsYield
With trichlorophosphate; zinc(II) chloride for 2h; Friedel Crafts Reaction;81%
With zinc(II) chloride; trichlorophosphate at 95℃; for 4h;70%
1,1'-oxybis(4-methyl-benzene)
1579-40-4

1,1'-oxybis(4-methyl-benzene)

2,7-dimethylxanthen-9-one
7573-15-1

2,7-dimethylxanthen-9-one

Conditions
ConditionsYield
With dipotassium peroxodisulfate; sulfuric acid; palladium diacetate; trifluoroacetic acid at 45℃;80%

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