4-Tolyl ether supplier | CasNO.1579-40-4

Name
4-Tolyl ether
EINECS 216-423-0
CAS No. 1579-40-4
Article Data59
CAS DataBase
Density 1.029 g/cm³
Solubility
Melting Point 47-49 °C(lit.)
Formula C₁₄H₁₄O
Boiling Point 285.5 °C at 760 mmHg
Molecular Weight 198.265
Flash Point 121.3 °C
Transport Information UN 3077 9/PG 3
Appearance
Safety 26-36-61
Risk Codes 36/37/38-50/53
Molecular Structure
Hazard Symbols Xi, N
Synonyms p-Tolylether (6CI,7CI,8CI);4,4'-Dimethyldiphenyl ether;Bis(4-methylphenyl) ether;Di-p-Tolyl ether;p-(p-Tolyloxy)toluene;
PSA 9.23000
LogP 4.09570

Synthetic route

: 5720-05-8
4-methylphenylboronic acid

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
With copper diacetate; water; triethylamine In dichloromethane; acetonitrile at 25℃; for 6h;	97%
Multi-step reaction with 2 steps 1: 85 percent / H2O2 / H2O / 20 °C 2: molecular sieves 4 Angstroem; Cu(OAc)2; Et3N / CH2Cl2 / 20 °C View Scheme

: 106-44-5
p-cresol

: 624-31-7
4-tolyl iodide

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
With aluminum oxide; potassium fluoride; copper(l) iodide In toluene at 100 - 110℃; for 22h;	95%
With caesium carbonate In N,N-dimethyl-formamide at 130℃; for 24h; Ullmann Condensation;	90%
With potassium phosphate; copper(l) iodide; tetrabutylammomium bromide In N,N-dimethyl-formamide for 22h; Ullmann coupling; Heating;	87%

: 106-44-5
p-cresol

: 1428064-59-8
2,4-dimethoxyphenyl(4-methylphenyl)iodonium tosylate

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
With potassium carbonate In acetonitrile at 50℃; for 6h; regioselective reaction;	93%

: 106-44-5
p-cresol

: 106-38-7
para-bromotoluene

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
With potassium phosphate In N,N-dimethyl-formamide at 80℃; for 4h; Ullmann Condensation;	90%
With potassium carbonate In water for 2.41667h; Ullmann Condensation; Reflux; Green chemistry;	87%
With potassium phosphate; 2-((o-toluidino)methyl)phenol; copper(l) chloride In acetonitrile at 81℃; for 24h; Catalytic behavior; Ullmann Condensation; Schlenk technique; Inert atmosphere;	85%

: 624-31-7
4-tolyl iodide

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
With potassium phosphate; copper(l) iodide; 2,2,6,6-tetramethylheptane-3,5-dione; water In ethanol at 130℃; for 30h; Inert atmosphere; Sealed tube; chemoselective reaction;	90%
Multi-step reaction with 2 steps 1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0.5 h / 20 °C 2: sodium hydroxide / dichloromethane / 22 h / 20 °C View Scheme
Multi-step reaction with 2 steps 1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0.5 h / 20 °C 2: sodium hydroxide; piperidine / dichloromethane / 14 h / 40 °C View Scheme

: 106-44-5
p-cresol

: bis(4-methylphenyl)(trifluoromethanesulfonato)-λ3-iodane

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
With potassium tert-butylate In tetrahydrofuran at 40℃;	88%

: 106-38-7
para-bromotoluene

: 62790-85-6
tert-Butyl(dimethyl)-(4-methylphenoxy)silane

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
With copper(l) iodide; caesium carbonate In N,N-dimethyl-formamide at 100℃; for 8h;	81%

: 106-38-7
para-bromotoluene

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
With potassium phosphate; tri-tert-butyl phosphine; tris-(dibenzylideneacetone)dipalladium(0) In 1,4-dioxane at 100℃; for 20h;	78%

: 106-43-4
para-chlorotoluene

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
With potassium phosphate; tri-tert-butyl phosphine; tris-(dibenzylideneacetone)dipalladium(0) In 1,4-dioxane at 100℃; for 20h;	72%

: 110-85-0
piperazine

: 106-38-7
para-bromotoluene

A: 106-44-5
p-cresol

B: 3367-48-4
1,4-bis(4-methylphenyl)piperazine

C: 108-88-3
toluene

D: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
With Adipic acid; N'-phenyloxalyl bishydrazide; copper diacetate; sodium acetate; cetyltrimethylammonim bromide; 2,5-hexanedione; potassium hydroxide In water at 100℃; for 3h; Inert atmosphere;	A 21 %Chromat. B 68% C 13 %Chromat. D 11 %Chromat.

...Expand

: 1121-70-6
sodium 4-methylphenoxide

poly(styrene p-tolyliodonium) hydrogensulfate: poly(styrene p-tolyliodonium) hydrogensulfate

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 100℃; for 24h;	65%

: 106-44-5
p-cresol

: 106-43-4
para-chlorotoluene

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
Stage #1: para-chlorotoluene With potassium phosphate; N,N'-bis(2,5-dimethylpyrrol-1-yl)oxalamide; copper(I) bromide In dimethyl sulfoxide at 20℃; Inert atmosphere; Sealed tube; Glovebox; Stage #2: p-cresol In dimethyl sulfoxide at 120℃; for 24h; Sealed tube; Inert atmosphere; Glovebox;	62%

: 106-38-7
para-bromotoluene

: 109-89-7
diethylamine

A: 106-44-5
p-cresol

B: 613-48-9
N,N-diethyl-p-toluidine

C: 108-88-3
toluene

D: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
With Adipic acid; N'-phenyloxalyl bishydrazide; copper diacetate; sodium acetate; cetyltrimethylammonim bromide; 2,5-hexanedione; potassium hydroxide In water at 100℃; for 3h; Inert atmosphere;	A 18 %Chromat. B 28% C 5 %Chromat. D 26 %Chromat.

...Expand

: bis(4-methylphenyl)(trifluoromethanesulfonato)-λ3-iodane

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
With piperidine; sodium hydroxide In dichloromethane at 40℃; for 14h;	11%

: 110-00-9
furan

: bis(4-methylphenyl)(trifluoromethanesulfonato)-λ3-iodane

A: 19061-31-5
1,4-dihydro-1,4-epoxy-6-methylnaphthalene

B: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
With sodium hydroxide In dichloromethane at 20℃; for 22h; Diels-Alder Cycloaddition;	A 11% B 11%

...Expand

: 106-44-5
p-cresol

: 499-75-2
carvacrol

A: 98511-24-1
(5-isopropyl-2-methyl-phenyl)-p-tolyl ether

B: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
at 440 - 450℃;

...Expand

: 106-44-5
p-cresol

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
at 400℃; durch Ueberleiten ueber ThO2;
at 400℃; beim Ueberleiten ueber ThO2;
With copper diacetate; 4 A molecular sieve; triethylamine In dichloromethane at 20℃;

: 106-38-7
para-bromotoluene

: 1192-96-7
potassium p-cresolate

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
With p-cresol; copper at 200 - 240℃;

: 860595-00-2
2-(5-methyl-2-p-tolyloxy-benzoyl)-benzoic acid

A: 88-99-3
benzene-1,2-dicarboxylic acid

B: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
in der Kalischmelze;

: 72269-62-6
aluminium tris(p-methylphenoxide)

A: 106-44-5
p-cresol

B: 13333-92-1
2,7-dimethyl-xanthene

C: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
bei der trocknen Destillation;

...Expand

: 106-44-5
p-cresol

: 106-49-0
p-toluidine

A: 107775-15-5
4-Methyl-2-p-tolyl-phenol

B: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
With sulfuric acid at 95℃; Diazotization;

...Expand

: 3744-11-4
tris(4-methylphenyl)sulfonium bromide

A: 620-94-0
di-(p-tolyl)sulfane

B: 108-88-3
toluene

C: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
With sodium isopropylate In isopropyl alcohol at 72℃; for 23h; Product distribution; Mechanism; var. of solvent, reagent, temp., time; D-incorporation into toluene;	A 100 % Chromat. B 33 % Chromat. C 35 % Chromat.

...Expand

: 4542-75-0
4,4'-oxybis-((bromomethyl)benzene)

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
With copper(II) sulfate; acetic acid; zinc

: 1192-96-7
potassium p-cresolate

: 6293-68-1
bis(4-methylphenyl)iodonium bromide

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
In N,N-dimethyl-formamide

: 3744-11-4
tris(4-methylphenyl)sulfonium bromide

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
With potassium hydroxide at 150 - 160℃;

: 106-38-7
para-bromotoluene

: 1121-70-6
sodium 4-methylphenoxide

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
With copper(I) oxide In N,N-dimethyl acetamide at 166℃;

: 83-34-1
3-Methylindole

: 3076-56-0
p-tolyllead triacetate

A: 1-(4-methyl-phenyl)-3-methyl-1H-indole

B: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
With copper diacetate; sodium hydride In dichloromethane 1.) r.t., 10 min, 2.) 50 deg C, 16 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

...Expand

: 3076-56-0
p-tolyllead triacetate

A: 1-(4-methyl-phenyl)-3-methyl-1H-indole

B: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
With 3-Methylindole; copper diacetate; sodium hydride In dichloromethane 1.) r.t., 10 min, 2.) 50 deg C, 16 h; Yield given. Yields of byproduct given;

: 67-56-1
methanol

: tri-p-tolyloxonium tetrafluoroborate

A: 104-93-8
4-Methylanisole

B: 100-84-5
1-methoxy-3-methyl-benzene

C: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

Conditions

Conditions	Yield
With sodium hydroxide In water for 10h; Heating; Yield given. Title compound not separated from byproducts;

...Expand

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

: 15320-91-9
2,8-Dimethyl-5-hydroxy-5-oxo-Pv-dibenzo<1,4>oxaphosphorin

Conditions

Conditions	Yield
Stage #1: 1,1'-oxybis(4-methyl-benzene) With aluminium trichloride; phosphorus trichloride Heating; Stage #2: With sodium hydroxide; dihydrogen peroxide In water for 0.25h;	97.2%
Multi-step reaction with 3 steps 1: phosphorus trichloride; aluminium trichloride / 22 h / 80 °C 2: 10.2 g / H2O / 0 °C 3: 92 percent / O2; KOH / H2O View Scheme
Multi-step reaction with 2 steps 1: PCl3, AlCl3 2: aq. Br2 View Scheme

: 1779-48-2
phenylphosphinic acid

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

: 21990-63-6
2,8-dimethyl-10-phenylphenoxaphosphinine 10-oxide

Conditions

Conditions	Yield
With dmap; trifluoromethylsulfonic anhydride In cis-1,2-Dichloroethylene at 120℃; for 16h; Schlenk technique; Inert atmosphere;	94%

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

: 82166-21-0
methyl cyclohexane

Conditions

Conditions	Yield
With platinum on activated charcoal; N-methyldiethanolamine trifluoromethanesulfonate; hydrogen at 150℃; under 7500.75 Torr; for 6h; Autoclave;	93.2%
With carbon nanotubes-supported ruthenium; hydrogen In dodecane; water at 220℃; under 37503.8 Torr; for 3h; Autoclave;	89 %Chromat.
With hydrogen at 130℃; under 15001.5 Torr; for 6h; Ionic liquid; Autoclave; Schlenk technique;	94.3 %Chromat.
With hydrogen In decalin at 200℃; under 75007.5 Torr; for 3h;

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

: 4542-75-0
4,4'-oxybis-((bromomethyl)benzene)

Conditions

Conditions	Yield
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane at 80 - 90℃; for 6.5h; Inert atmosphere;	93%
With bromine; ethylene dibromide; dibenzoyl peroxide Irradiation.Sonnenlicht;
With N-Bromosuccinimide; dibenzoyl peroxide
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane at 80℃;
With hydrogen bromide; dihydrogen peroxide In 1,2-dichloro-ethane for 12h; Cooling with ice; Irradiation;

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

: 2215-89-6
oxybis(benzoic acid)

Conditions

Conditions	Yield
With dihydrogen peroxide; sodium carbonate at 100℃; under 7500.75 Torr; for 18h; Reagent/catalyst; Pressure;	93%
With pyridine; cobalt(III) acetylacetonate; dihydrogen peroxide; sodium carbonate In acetic acid at 100℃; under 15001.5 Torr; for 6h; Reagent/catalyst; Temperature; Solvent; Pressure;	92%
With 2-chloroanthracene-9,10-dione; water; oxygen; trifluoroacetic acid In ethyl acetate for 72h; Irradiation;	70%

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

: 21797-71-7
2,8-dimethyl-10,10-dichlorophenoxatellurine

Conditions

Conditions	Yield
With tellurium tetrachloride at 200℃; for 4h;	93%

: 124-41-4
sodium methylate

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

: 2509-26-4
4,4'-Bis-methoxymethyl diphenyl ether

Conditions

Conditions	Yield
Stage #1: 1,1'-oxybis(4-methyl-benzene) With 2,2'-azobis(isobutyronitrile); bromine In benzene at 80℃; for 3h; Reflux; Stage #2: sodium methylate In methanol at 45℃; for 2h; Temperature; Reflux;	92.8%

: 683-60-3
sodium isopropylate

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

: 4,4'-diisopropoxymethyldiphenyl ether

Conditions

Conditions	Yield
Stage #1: 1,1'-oxybis(4-methyl-benzene) With 2,2'-azobis(isobutyronitrile); bromine In tetrachloromethane at 80℃; for 4.1h; Reflux; Stage #2: sodium isopropylate In isopropyl alcohol at 50℃; for 3h; Reflux;	92.8%

: 65-85-0
benzoic acid

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

: 854864-70-3
2, 7-dimethyl-9-phenyl xanthen-9-ol

Conditions

Conditions	Yield
With trichlorophosphate; zinc(II) chloride at 95℃; for 2h; Product distribution / selectivity; Friedel Crafts Reaction;	91.8%
With zinc(II) chloride; trichlorophosphate at 95℃; for 4h;	66%
With zinc(II) chloride; trichlorophosphate at 80 - 95℃;
With zinc(II) chloride; trichlorophosphate at 95℃; for 4h;

: 141-52-6
sodium ethanolate

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

: 3287-73-8
4,4'-diethoxymethyldiphenyl ether

Conditions

Conditions	Yield
Stage #1: 1,1'-oxybis(4-methyl-benzene) With 2,2'-azobis(isobutyronitrile); bromine In tetrachloromethane at 80℃; for 3.2h; Reflux; Stage #2: sodium ethanolate In ethanol at 46℃; for 2h; Reflux;	91.2%

: 79-37-8
oxalyl dichloride

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

: 7573-15-1
2,7-dimethylxanthen-9-one

Conditions

Conditions	Yield
With aluminium trichloride In carbon disulfide at 0 - 20℃; for 18h;	90%
With aluminum (III) chloride In dichloromethane at 0℃; Friedel Crafts reaction; Inert atmosphere; Reflux;	77%
With carbon disulfide; aluminium trichloride

: 98-88-4
benzoyl chloride

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

: 134312-16-6
2-<(p-methylphenyl)oxy>-5-methylbenzophenone

Conditions

Conditions	Yield
With aluminium trichloride In carbon disulfide at 0℃; for 3h;	90%

: 67-56-1
methanol

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

: 14387-30-5
dimethyl 4,4'-oxydibenzoate

Conditions

Conditions	Yield
With hydrogenchloride; oxygen; 9-(2-mesityl)-10-methylacridinium perchlorate at 20℃; under 760.051 Torr; for 30h; Schlenk technique; Irradiation; Green chemistry;	90%
With 2,3-dicarboxyanthraquinone; oxygen for 48h; Irradiation;	80%

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

: 106-44-5
p-cresol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride; iron(III)-acetylacetonate; sodium t-butanolate In toluene at 140℃; for 24h; Inert atmosphere;	88%

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

: 2215-76-1
4-(4-formylphenoxy)benzaldehyde

Conditions

Conditions	Yield
With sodium persulfate; copper diacetate; iron(II) sulfate; dimethyl sulfoxide In water; acetonitrile at 75℃; for 0.75h;	87%
With sodium persulfate; dimethylsulfide; copper diacetate; iron(II) sulfate In water; acetonitrile at 75℃; for 1.08333h;	84%
With sodium persulfate; racemic methyl phenyl sulfoxide; copper diacetate; iron(II) sulfate In water; acetonitrile at 75℃; for 0.75h;	84%
Multi-step reaction with 2 steps 1: 1,2-dibromo-ethane; dibenzoyl peroxide; bromine / Irradiation.Sonnenlicht 2: CHCl3 / Erhitzen des Reaktionsprodukts mit wss. Essigsaeure und anschliessend mit wss. HCl View Scheme

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

: 62-23-7
4-nitro-benzoic acid

: 1392228-32-8
2,7-dimethyl-9-(4-nitrophenyl)-xanthen-9-ol

Conditions

Conditions	Yield
With zinc(II) chloride; trichlorophosphate at 95℃; for 4h;	86%

: 2359-09-3
5-t-butylisophthalic acid

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

: 9,9'-(5-(tert-butyl)-1,3-phenylene)bis(2,7-dimethyl-9H-xanthen-9-ol)

Conditions

Conditions	Yield
With zinc(II) chloride; trichlorophosphate In neat (no solvent) at 100℃; for 24h; Inert atmosphere;	85%

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

: 37563-42-1
4-(4'-methylphenoxy)benzonitrile

Conditions

Conditions	Yield
With sodium azide; copper(ll) sulfate pentahydrate; [bis(acetoxy)iodo]benzene In acetonitrile at -40 - 25℃; Inert atmosphere;	83%

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

: 1136-79-4
2,8-dimethyldibenzofuran

Conditions

Conditions	Yield
With oxygen; palladium diacetate at 55℃;	82%
With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; copper dichloride 1.) Et2O, cyclohexane, RT, 16 h, 2.) Et2O, cyclohexane, 5 deg C, 3 h; Yield given. Multistep reaction;

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

: cis-4-methyl-N-(4-methylcyclohexyl)benzenamine

: trans-4-methyl-N-(4-methylcyclohexyl)benzenamine

C: 108-88-3
toluene

Conditions

Conditions	Yield
With sodium tetrahydroborate; 10 wt% Pd(OH)2 on carbon; ammonia In water; m-xylene at 150℃; for 24h; Inert atmosphere; Sealed tube;	A 82% B n/a C 88 %Chromat.

...Expand

: 98-73-7
4-(1,1-dimethylethyl)benzoic acid

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

: 862125-81-3
2,7-dimethyl-9-(4-t-butyl)phenylxanthene-9-ol

Conditions

Conditions	Yield
With trichlorophosphate; zinc(II) chloride for 2h; Friedel Crafts Reaction;	81%
With zinc(II) chloride; trichlorophosphate at 95℃; for 4h;	70%

: 16712-16-6, 64165-14-6, 65387-22-6, 70179-79-2, 540-69-2
ammonium formate

: 1579-40-4
1,1'-oxybis(4-methyl-benzene)

: 7573-15-1
2,7-dimethylxanthen-9-one

Conditions

Conditions	Yield
With dipotassium peroxodisulfate; sulfuric acid; palladium diacetate; trifluoroacetic acid at 45℃;	80%

4-Tolyl ether Chemical Properties

MF: C₁₄H₁₄O
MW: 198.260 g/mol
EINECS: 216-423-0
Flash Point: 121.3 °C
Index of Refraction: 1.56
Melting Point: 47-49 °C(lit.)
Enthalpy of Vaporization: 50.35 kJ/mol
Boiling Point: 285.5 °C at 760 mmHg
Vapour Pressure: 0.0048 mmHg at 25°C
IUPAC Name: 1-methyl-4-(4-methylphenoxy)benzene
Density of P-(p-Tolyloxy)toluene (1579-40-4): 1.029 g/cm³
Synonyms: 1,1’-Oxybis(4-methyl-benzen ; 1,1’-Oxybis(4-methylbenzene) ; 1,1’-Oxybis[4-methyl-benzen ; Benzene, 1,1'-Oxybis*4-methyl- ; Benzene, 1,1'-Oxybis[4-methyl- ; Bis(4-methylphenyl) ether ; Bis(4-methylphenyl)ether ; P-(p-Tolyloxy)toluene
Product Categories: Ethers ; Organic Building Blocks ; Oxygen Compounds
Following is the molecular structure of P-(p-Tolyloxy)toluene (1579-40-4):

4-Tolyl ether Toxicity Data With Reference

1.	skn-rbt 500 mg/24H SEV	NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0545443 .
2.	orl-rat LDLo:2250 mg/kg	NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0537676 .
3.	ihl-rat LC :>184 ppm/4H	NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0537676 .
4.	skn-rbt LDLo:7940 mg/kg	NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0545443 .

4-Tolyl ether Consensus Reports

Reported in EPA TSCA Inventory.

4-Tolyl ether Safety Profile

Moderately toxic by ingestion and inhalation. Low toxicity by skin contact. A severe skin irritant. When heated to decomposition it emits acrid smoke and irritating vapors.
Safety Information of P-(p-Tolyloxy)toluene (1579-40-4):
Hazard Codes: Xi,N
Xi: Irritant N: Dangerous for the environment
Risk Statements: 36/37/38-50/53
36/37/38: Irritating to eyes, respiratory system and skin
50/53: Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety Statements: 26-36-61
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
61: Avoid release to the environment. Refer to special instructions safety data sheet
RIDADR: UN 3077 9/PG 3
WGK Germany: 2
RTECS: DA6625000

Product Name

4-Tolyl ether

Synthetic route

4-Tolyl ether Chemical Properties

4-Tolyl ether Toxicity Data With Reference

4-Tolyl ether Consensus Reports

4-Tolyl ether Safety Profile

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