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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Ethoxydiethylaluminium

Cas:1586-92-1

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality 99% Aluminum,ethoxydiethyl- 1586-92-1 ISO Manufacturer

Cas:1586-92-1

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

ethoxydiethylaluminium

Cas:1586-92-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

DIETHYLALUMINUM ETHOXIDE CAS 1586-92-1

Cas:1586-92-1

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 1586-92-1 with competitive price

Cas:1586-92-1

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Aluminum,ethoxydiethyl-

Cas:1586-92-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

DIETHYLALUMINUM ETHOXIDE CAS:1586-92-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic i

DIETHYLALUMINUM ETHOXIDE CAS:1586-92-1

Cas:1586-92-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Aluminum,ethoxydiethyl-

Cas:1586-92-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Wuhan Zenuo Biological Medicine Technology Co Ltd

Product Name: DIETHYLALUMINUM ETHOXIDE Synonyms: 25%w/winhexane;Diethylaluminium ethoxide, 1.3M solution in hexane;Diethylaluminium ethoxide, 25 wt% solution in toluene;diethylaluminum ethoxide solution;Diethylaluminiumethoxid;Diethylaluminum et

DIETHYLALUMINUM ETHOXIDE big supplier with lower price

Cas:1586-92-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Aluminum,ethoxydiethyl-

Cas:1586-92-1

Min.Order:0

Negotiable

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Triumph International Development Limilted

Appearance:off-white to white solid Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for Synthesis API and Research Transportation:By Sea/Air/Courier Port:Qingdao

ethoxydiethylaluminium 1586-92-1

Cas:1586-92-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Aluminum,ethoxydiethyl-

Cas:1586-92-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Aluminum,ethoxydiethyl-

Cas:1586-92-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Reliable Quality DIETHYLALUMINUM ETHOXIDE

Cas:1586-92-1

Min.Order:0

Negotiable

Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

Product Name: DIETHYLALUMINUM ETHOXIDE CAS: 1586-92-1 MF: C6H15AlO MW: 130.16 EINECS: 216-447-1 Mol File: 1586-92-1.mol DIETHYLALUMINUM ETHOXIDE Structure DIETHYLALUMINUM ETHOXIDE Chemical Properties Melting point 2.5-4.5 &deg

DIETHYLALUMINUM ETHOXIDE

Cas:1586-92-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

DIETHYLALUMINUM ETHOXIDE

Cas:1586-92-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

DIETHYLALUMINUM ETHOXIDE

Cas:1586-92-1

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

DIETHYLALUMINUM ETHOXIDE

Cas:1586-92-1

Min.Order:1 Kilogram

Negotiable

Type:Other

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Hebei Mojin Biotechnology Co.,Ltd

1, High quality with competitive price:2, Fast and safe delivery3.Excellent pre-sales and after-sales service4. Well-trained and professional technologist and sales with rich experience in the field for 5-10 yearsAppearance:see detailed specification

Aluminum,ethoxydiethyl-

Cas:1586-92-1

Min.Order:0

Negotiable

Type:Trading Company

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Aluminum,ethoxydiethyl-

Cas:1586-92-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

Aluminum,ethoxydiethyl-

Cas:1586-92-1

Min.Order:0

Negotiable

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

high qualityAppearance:white crystalline powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

4-Methylumbelliferyl caprylate

Cas:1586-92-1

Min.Order:0

Negotiable

Type:Manufacturers

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Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

DIETHYLALUMINUM ETHOXIDE

Cas:1586-92-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Aluminum,ethoxydiethyl-

Cas:1586-92-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

DIETHYLALUMINUM ETHOXIDE

Cas:1586-92-1

Min.Order:0

Negotiable

Type:Manufacturers

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Wuhan Circle Star Chem-medical Technology co.,Ltd.

1,we produce and sell good chemicals around the world.2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%.3,our staff consists of highly qualified in

DIETHYLALUMINUM ETHOXIDE

Cas:1586-92-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Aluminum,ethoxydiethyl-

Cas:1586-92-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:intermediate

DIETHYLALUMINUM ETHOXIDE

Cas:1586-92-1

Min.Order:0

Negotiable

Type:Trading Company

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DB BIOTECH CO., LTD

best seller Application:API

DIETHYLALUMINUM ETHOXIDE

Cas:1586-92-1

Min.Order:0

Negotiable

Type:Trading Company

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BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:yellow to light brown crystals Storage:Room temperature with sealed well Package:according to the clients requirement Applicatio

Diethylaluminum ethoxide

Cas:1586-92-1

Min.Order:0

Negotiable

Type:Trading Company

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Synthetic route

triethylaluminum
97-93-8

triethylaluminum

aluminium-triethylate

aluminium-triethylate

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

Conditions
ConditionsYield
at 170℃;
triethylaluminum
97-93-8

triethylaluminum

sodium ethanolate
141-52-6

sodium ethanolate

A

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

B

sodium tetraethylaluminate
2397-68-4

sodium tetraethylaluminate

Conditions
ConditionsYield
In hexane; n-heptane; toluene at 70℃; for 1h;
triethylaluminum
97-93-8

triethylaluminum

aluminum ethoxide
555-75-9

aluminum ethoxide

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

triethylaluminum
97-93-8

triethylaluminum

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

Conditions
ConditionsYield
With ethanol In hexane byproducts: ethane; Ar, ethanol in hexane added dropwise to a soln. of AlEt3 at -30°C; hexane was distilled off; residue was vac. distilled;
hexaethyldialuminum

hexaethyldialuminum

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

Conditions
ConditionsYield
With O2 In xylene shaking of Al2Et6 soln. with different amts. of dry atm. O2 (mole ratio 3.5/1 - 2/1); spect. anal. {(27)Al-NMR};
With O2 In n-heptane shaking of Al2Et6 soln. with different amts. of dry atm. O2 (mole ratio 3.5/1 - 2/1); spect. anal. {(27)Al-NMR};
nickel(II) acetylacetonate

nickel(II) acetylacetonate

methyltriphenylphosphonium bromide
106475-72-3

methyltriphenylphosphonium bromide

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

buta-1,3-diene
106-99-0

buta-1,3-diene

C(x)H(x)Br(x)Ni(x)

C(x)H(x)Br(x)Ni(x)

Conditions
ConditionsYield
In further solvent(s) solvent: ethyleneoxide, addn. of (C6H5)2C(Br)CH3 to the react. mixt. at 0-10°C;99%
In further solvent(s) solvent: ethyleneoxide, addn. of (C6H5)2C(Br)CH3 to the react. mixt. at 0-10°C;99%
In diethyl ether an orange soln. reacts with phenyl- and halide substituted methane derivative;
nickel(II) acetylacetonate

nickel(II) acetylacetonate

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

buta-1,3-diene
106-99-0

buta-1,3-diene

allyl bromide
106-95-6

allyl bromide

C(x)H(x)Br(x)Ni(x)

C(x)H(x)Br(x)Ni(x)

Conditions
ConditionsYield
In diethyl ether -80°C, filtration, addn. of allylbromide to the mixt. at 0°C;95%
In diethyl ether -80°C, filtration, addn. of allylbromide to the mixt. at 0°C;95%
In diethyl ether byproducts: (π-C3H5NiBr)2; -80°C, filtration, addn. of allylbromide to the mixt. at -20°C;
In diethyl ether byproducts: (π-C3H5NiBr)2; -80°C, filtration, addn. of allylbromide to the mixt. at -20°C;
bis(acetylacetonate)nickel(II)

bis(acetylacetonate)nickel(II)

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

1,5-dicyclooctadiene
5259-72-3, 10060-40-9, 111-78-4

1,5-dicyclooctadiene

bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

Conditions
ConditionsYield
In benzene molar ratio nickel acetylacetonat : cyclooctadiene = 1 : 2.5-5, benzene free from air, reduction between 0 and 5°C, 2 h, and room temp. 15 h;93.5%
In benzene molar ratio nickel acetylacetonate : cyclooctadiene = 1 : 2.5-5, benzene free from air, reduction between 0 and 5°C, 2 h, and room temp. 15 h; washing with cold benzene and ether;93.5%
In benzene molar ratio nickel acetylacetonate : cyclooctadiene = 1 : 2.5-5, benzene free from air, reduction between 0 and 5°C, 2 h, and room temp. 15 h; washing with cold benzene and ether;93.5%
In benzene molar ratio nickel acetylacetonat : cyclooctadiene = 1 : 2.5-5, benzene free from air, reduction between 0 and 5°C, 2 h, and room temp. 15 h;93.5%
diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

tin(IV) chloride
7646-78-8

tin(IV) chloride

tetraethyltin
597-64-8

tetraethyltin

Conditions
ConditionsYield
100°C;93%
(Z)-1-chloro-4-phenylbut-1-en-1-yl acetate
852919-31-4

(Z)-1-chloro-4-phenylbut-1-en-1-yl acetate

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

ethyl 4-phenylbutyrate
10031-93-3

ethyl 4-phenylbutyrate

Conditions
ConditionsYield
In tetrahydrofuran for 1h; Heating;92%
[2,2]bipyridinyl
366-18-7

[2,2]bipyridinyl

bis(acetylacetonate)nickel(II)

bis(acetylacetonate)nickel(II)

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

diethyl(2,2'-bipyridyl)nickel(II)
15218-76-5

diethyl(2,2'-bipyridyl)nickel(II)

Conditions
ConditionsYield
Stage #1: [2,2]bipyridinyl; bis(acetylacetonate)nickel(II) In diethyl ether at 25℃; Inert atmosphere; Schlenk technique;
Stage #2: diethyl(ethoxy)aluminum In diethyl ether at -20 - 25℃; for 52h; Inert atmosphere; Schlenk technique;
87%
(E)-1,2-diphenyl-ethene
103-30-0

(E)-1,2-diphenyl-ethene

bis(triphenylphosphine)ethylenenickel(0)
23777-40-4

bis(triphenylphosphine)ethylenenickel(0)

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

trans-C6H5CHCHC6H5Ni(P(C6H5)3)2
12151-25-6, 53586-21-3

trans-C6H5CHCHC6H5Ni(P(C6H5)3)2

Conditions
ConditionsYield
With triphenylphosphine In benzene byproducts: methylenecyclopropane, methylenecyclopropane trimers; Ar-atmosphere; molar ratio Ni-complex : olefin = 1:3, stirring (20°C, 22 h); evapn., pptn. with ether, filtration, washing (ether), drying (vac.);80%
triethylaluminum
97-93-8

triethylaluminum

aluminium-triethylate

aluminium-triethylate

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

Conditions
ConditionsYield
at 170℃;
triethylaluminum
97-93-8

triethylaluminum

sodium ethanolate
141-52-6

sodium ethanolate

A

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

B

sodium tetraethylaluminate
2397-68-4

sodium tetraethylaluminate

Conditions
ConditionsYield
In hexane; n-heptane; toluene at 70℃; for 1h;
triethylaluminum
97-93-8

triethylaluminum

aluminum ethoxide
555-75-9

aluminum ethoxide

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

triethylaluminum
97-93-8

triethylaluminum

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

Conditions
ConditionsYield
With ethanol In hexane byproducts: ethane; Ar, ethanol in hexane added dropwise to a soln. of AlEt3 at -30°C; hexane was distilled off; residue was vac. distilled;
hexaethyldialuminum

hexaethyldialuminum

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

Conditions
ConditionsYield
With O2 In xylene shaking of Al2Et6 soln. with different amts. of dry atm. O2 (mole ratio 3.5/1 - 2/1); spect. anal. {(27)Al-NMR};
With O2 In n-heptane shaking of Al2Et6 soln. with different amts. of dry atm. O2 (mole ratio 3.5/1 - 2/1); spect. anal. {(27)Al-NMR};
nickel(II) acetylacetonate

nickel(II) acetylacetonate

methyltriphenylphosphonium bromide
106475-72-3

methyltriphenylphosphonium bromide

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

buta-1,3-diene
106-99-0

buta-1,3-diene

C(x)H(x)Br(x)Ni(x)

C(x)H(x)Br(x)Ni(x)

Conditions
ConditionsYield
In further solvent(s) solvent: ethyleneoxide, addn. of (C6H5)2C(Br)CH3 to the react. mixt. at 0-10°C;99%
In further solvent(s) solvent: ethyleneoxide, addn. of (C6H5)2C(Br)CH3 to the react. mixt. at 0-10°C;99%
In diethyl ether an orange soln. reacts with phenyl- and halide substituted methane derivative;
nickel(II) acetylacetonate

nickel(II) acetylacetonate

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

buta-1,3-diene
106-99-0

buta-1,3-diene

allyl bromide
106-95-6

allyl bromide

C(x)H(x)Br(x)Ni(x)

C(x)H(x)Br(x)Ni(x)

Conditions
ConditionsYield
In diethyl ether -80°C, filtration, addn. of allylbromide to the mixt. at 0°C;95%
In diethyl ether -80°C, filtration, addn. of allylbromide to the mixt. at 0°C;95%
In diethyl ether byproducts: (π-C3H5NiBr)2; -80°C, filtration, addn. of allylbromide to the mixt. at -20°C;
In diethyl ether byproducts: (π-C3H5NiBr)2; -80°C, filtration, addn. of allylbromide to the mixt. at -20°C;
bis(acetylacetonate)nickel(II)

bis(acetylacetonate)nickel(II)

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

1,5-dicyclooctadiene
5259-72-3, 10060-40-9, 111-78-4

1,5-dicyclooctadiene

bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

Conditions
ConditionsYield
In benzene molar ratio nickel acetylacetonat : cyclooctadiene = 1 : 2.5-5, benzene free from air, reduction between 0 and 5°C, 2 h, and room temp. 15 h;93.5%
In benzene molar ratio nickel acetylacetonate : cyclooctadiene = 1 : 2.5-5, benzene free from air, reduction between 0 and 5°C, 2 h, and room temp. 15 h; washing with cold benzene and ether;93.5%
In benzene molar ratio nickel acetylacetonate : cyclooctadiene = 1 : 2.5-5, benzene free from air, reduction between 0 and 5°C, 2 h, and room temp. 15 h; washing with cold benzene and ether;93.5%
In benzene molar ratio nickel acetylacetonat : cyclooctadiene = 1 : 2.5-5, benzene free from air, reduction between 0 and 5°C, 2 h, and room temp. 15 h;93.5%
diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

tin(IV) chloride
7646-78-8

tin(IV) chloride

tetraethyltin
597-64-8

tetraethyltin

Conditions
ConditionsYield
100°C;93%
(Z)-1-chloro-4-phenylbut-1-en-1-yl acetate
852919-31-4

(Z)-1-chloro-4-phenylbut-1-en-1-yl acetate

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

ethyl 4-phenylbutyrate
10031-93-3

ethyl 4-phenylbutyrate

Conditions
ConditionsYield
In tetrahydrofuran for 1h; Heating;92%
[2,2]bipyridinyl
366-18-7

[2,2]bipyridinyl

bis(acetylacetonate)nickel(II)

bis(acetylacetonate)nickel(II)

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

diethyl(2,2'-bipyridyl)nickel(II)
15218-76-5

diethyl(2,2'-bipyridyl)nickel(II)

Conditions
ConditionsYield
Stage #1: [2,2]bipyridinyl; bis(acetylacetonate)nickel(II) In diethyl ether at 25℃; Inert atmosphere; Schlenk technique;
Stage #2: diethyl(ethoxy)aluminum In diethyl ether at -20 - 25℃; for 52h; Inert atmosphere; Schlenk technique;
87%
(E)-1,2-diphenyl-ethene
103-30-0

(E)-1,2-diphenyl-ethene

bis(triphenylphosphine)ethylenenickel(0)
23777-40-4

bis(triphenylphosphine)ethylenenickel(0)

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

trans-C6H5CHCHC6H5Ni(P(C6H5)3)2
12151-25-6, 53586-21-3

trans-C6H5CHCHC6H5Ni(P(C6H5)3)2

Conditions
ConditionsYield
With triphenylphosphine In benzene byproducts: methylenecyclopropane, methylenecyclopropane trimers; Ar-atmosphere; molar ratio Ni-complex : olefin = 1:3, stirring (20°C, 22 h); evapn., pptn. with ether, filtration, washing (ether), drying (vac.);80%
3-methyltetrahydrofuran
13423-15-9

3-methyltetrahydrofuran

vanadium(III) bromide
13470-26-3

vanadium(III) bromide

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

{V2(μ-Br)3(3-methyltetrahydrofuran)6}BPh4

{V2(μ-Br)3(3-methyltetrahydrofuran)6}BPh4

Conditions
ConditionsYield
In further solvent(s) (Ar); VBr3 and 3-methyltetrahydrofuran refluxed for 12 h; cooled (room temp.); addn. of soln. of AlEt2OEt in toluene; stirred (10 days; room temp.); filtration through Celite onto NaBPh4; stirred for 12 h at room temp.;; filtration (Celite); hexane placed on top of soln.; soln. allowed to stand for several days; crystals filtered, washed (hexane) and dried (vacuum);;76.5%
bis(acetylacetonate)nickel(II)

bis(acetylacetonate)nickel(II)

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

(1E,5E,9E)-cyclododeca-1,5,9-triene
676-22-2

(1E,5E,9E)-cyclododeca-1,5,9-triene

(trans,trans,trans-1,5,9-cyclododecatriene)nickel

(trans,trans,trans-1,5,9-cyclododecatriene)nickel

Conditions
ConditionsYield
In diethyl ether at about 0°C; recrystn. from ether;75%
In diethyl ether at about 0°C;57%
In diethyl ether at about 0°C;57%
5-methyl-2-furanone
591-12-8

5-methyl-2-furanone

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

benzaldehyde
100-52-7

benzaldehyde

(4S,5S)-4-Acetyl-5-phenyl-dihydro-furan-2-one
95891-75-1

(4S,5S)-4-Acetyl-5-phenyl-dihydro-furan-2-one

β-acetyl-γ-phenyl-γ-butyrolactone
95891-76-2

β-acetyl-γ-phenyl-γ-butyrolactone

C

3-(hydroxy-phenyl-methyl)-4-oxo-pentanoic acid ethyl ester

3-(hydroxy-phenyl-methyl)-4-oxo-pentanoic acid ethyl ester

Conditions
ConditionsYield
In tetrahydrofuran at 0℃; for 4h; crossed aldol reaction;A 74%
B n/a
C n/a
nickel(II) acetylacetonate

nickel(II) acetylacetonate

1,3,5,7-cycloocatetraene

1,3,5,7-cycloocatetraene

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

cyclooctatetraene nickel

cyclooctatetraene nickel

Conditions
ConditionsYield
In benzene 0-20°C;71%
In benzene 0-20°C;71%
In benzene 0-5°C;60%
In benzene 0-5°C;60%
[2,2]bipyridinyl
366-18-7

[2,2]bipyridinyl

iron(III) acetylacetonate

iron(III) acetylacetonate

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

(C2H5)2Fe(2,2'-bipyridyl)2

(C2H5)2Fe(2,2'-bipyridyl)2

Conditions
ConditionsYield
In diethyl ether from -20°C to 10°C, under N2, Ar or in vac.;70%
In diethyl ether from -20°C to 10°C, under N2, Ar or in vac.;50%
bis(acetylacetonato)palladium(II)

bis(acetylacetonato)palladium(II)

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

(2,2'-bipyridine)diethylpalladium(II)
102150-17-4

(2,2'-bipyridine)diethylpalladium(II)

B

Al(3+)*OC2H5(1-)*2CH(COCH3)2(1-)=Al(OC2H5)(CH(COCH3)2)2

Al(3+)*OC2H5(1-)*2CH(COCH3)2(1-)=Al(OC2H5)(CH(COCH3)2)2

Conditions
ConditionsYield
With [2,2]bipyridinyl In diethyl ether under Ar; Pd(acac)2 and 2,2'-bipyridine were suspensed; addition of Al(C2H5)2(OC2H5); stirred for 4 d at 22°C; filtered; washed 3 times with Et2O; dried in vacuo; crystals extracted (acetone) under reduced pressure; solid separated; dried in vacuo; elem.anal.;A 67%
B n/a
3-phenyl-propionaldehyde
104-53-0

3-phenyl-propionaldehyde

5-methyl-2-furanone
591-12-8

5-methyl-2-furanone

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

(4R,5S)-4-Acetyl-5-phenethyl-dihydro-furan-2-one

(4R,5S)-4-Acetyl-5-phenethyl-dihydro-furan-2-one

(4S,5S)-4-Acetyl-5-phenethyl-dihydro-furan-2-one

(4S,5S)-4-Acetyl-5-phenethyl-dihydro-furan-2-one

C

3-acetyl-4-hydroxy-6-phenyl-hexanoic acid ethyl ester

3-acetyl-4-hydroxy-6-phenyl-hexanoic acid ethyl ester

Conditions
ConditionsYield
In tetrahydrofuran at -10℃; for 4h; crossed aldol reaction;A 61%
B n/a
C n/a
tetrahydrofuran
109-99-9

tetrahydrofuran

vanadium(III) bromide
13470-26-3

vanadium(III) bromide

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

{V2(μ-Br)3(tetrahydrofuran)6}BPh4

{V2(μ-Br)3(tetrahydrofuran)6}BPh4

Conditions
ConditionsYield
In tetrahydrofuran (Ar); VBr3 and tetrahydrofuran refluxed for 12 h; cooled (room temp.); addn. of soln. of AlEt2OEt in toluene; stirred (10 days; room temp.); filtration through Celite onto NaBPh4; stirred for 12 h at room temp.;; filtration (Celite); hexane placed on top of soln.; soln. allowed to stand for several days; crystals filtered, washed (hexane) and dried (vacuum);;61%
2,2-[μ-(N,N'-piperazindiyl)dimethyl]-bis(4,6-di-tert-butyl-phenol)
110546-20-8

2,2-[μ-(N,N'-piperazindiyl)dimethyl]-bis(4,6-di-tert-butyl-phenol)

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

ethoxy aluminium-N,N-bis(benzyl-3,5-di-tert-butyl-phenol)piperazine
1214751-50-4

ethoxy aluminium-N,N-bis(benzyl-3,5-di-tert-butyl-phenol)piperazine

Conditions
ConditionsYield
In diethyl ether; toluene in atm. of N2 or Ar using Schlenk technique; AlEt2OEt in Et2O added dropwise to piperazine deriv. soln. in toluene at 50°C, stirred at 50°C ca. 30 min; mixt. refluxed at 110°C for 5 h; solvent removed in vacuo, solid washed with pentane 3 times; pumped dry;elem. anal.;59%
[2,2]bipyridinyl
366-18-7

[2,2]bipyridinyl

iron(III)-acetylacetonate
14024-18-1

iron(III)-acetylacetonate

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

(C2H5)2Fe(2,2'-bipyridyl)2

(C2H5)2Fe(2,2'-bipyridyl)2

Conditions
ConditionsYield
In diethyl ether under Ar; a mixt. of Fe-contg. compd. (12.9 mmol) and a ligand (30.3 mmol) in Et2O was treated dropwise at ca. -20°C with Al-contg. compd. (36.7 mmol); the mixt. was allowed to warm up to room temp.; stirring for 12 h at room temp.; the solid was filtered off, washed with Et2O, C7H16 and dried in vac.; IR-, NMR spectra;55%
iron(III)-acetylacetonate
14024-18-1

iron(III)-acetylacetonate

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

buta-1,3-diene
106-99-0

buta-1,3-diene

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

(1,3-butadiene)tris(dimetylphenylphosphine)iron(0)
88242-44-8

(1,3-butadiene)tris(dimetylphenylphosphine)iron(0)

Conditions
ConditionsYield
In not given reaction of Fe(acac)3 with AlEt2OEt in the presence of PPhMe2, excess of 1,3-butadiene, 0°C;52%
bis(acetylacetonate)nickel(II)

bis(acetylacetonate)nickel(II)

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

methylene cyclopropane
6142-73-0

methylene cyclopropane

(η2-methylenecyclopropane)bis(triphenylphosphine)nickel
89606-46-2

(η2-methylenecyclopropane)bis(triphenylphosphine)nickel

Conditions
ConditionsYield
With triphenylphosphine In benzene Ar-atmosphere; molar ratio Ni : PPh3 : Al : olefin = 1:2:3:4; stirring (20°C, 9 h, pptn.); filtration, washing (ether), drying (vac.);44%
diphenyl dicyclopentadienyl-zirconium
51177-89-0

diphenyl dicyclopentadienyl-zirconium

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

(C5H5)2Zr(C6H4Al(C2H5)2OC2H5)
169617-72-5

(C5H5)2Zr(C6H4Al(C2H5)2OC2H5)

Conditions
ConditionsYield
In tetrahydrofuran; toluene Ar or N2-atmosphere; 80°C (18 h); evapn. (vac., room temp.), toluene addn., evapn. (vac.), pptn. on pentane addn. (sonicating, 30 min), filtering, pptn. on concg., decanting, drying (vac.); elem. anal.;44%
C14H12Mg*3.3C4H8O

C14H12Mg*3.3C4H8O

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

magnesium-μ-(9,10-dihydro-9,10-anthrylen)ethoxidiethylaluminate*3THF

magnesium-μ-(9,10-dihydro-9,10-anthrylen)ethoxidiethylaluminate*3THF

Conditions
ConditionsYield
In tetrahydrofuran under Ar to C14H10Mg*nTHF in THF stirring at 20°C added during 30 min dropwise CH3CH2OAl(C2H5)2H in THF; after standing 1-2 d warmed to50-60°C, filtrated warm; crystn. in any h at -20°C; filtrated, washed with cooled ether,dried at 20°C/1E-3 torr; elem. anal.;43%
bis-(cinnamaldehyde-N,N'-propylenediimine)-bis-acetylacetonatonickel(II)

bis-(cinnamaldehyde-N,N'-propylenediimine)-bis-acetylacetonatonickel(II)

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

A

bis{bis(cinnamic aldehyde)-propylenediimine-nickel(0)}

bis{bis(cinnamic aldehyde)-propylenediimine-nickel(0)}

B

acetylacetonato(ethoxy)ethylaluminum

acetylacetonato(ethoxy)ethylaluminum

Conditions
ConditionsYield
In benzene suspn. of Ni-compd. in benzene is treated with the Al compd. at room temp. (under Ar) with stirring, further stirring for 3 d; filtn., evapn. (vac.), addn. of THF, filtn., addn. of ether to the filtrate and extn. with benzene; elem. anal.;A 40%
B n/a
(Z)-1-chloro-4-phenylbut-1-en-1-yl acetate
852919-31-4

(Z)-1-chloro-4-phenylbut-1-en-1-yl acetate

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

ethyl 3-oxo-6-phenyl-2-(2-phenylethyl)hexanoate

ethyl 3-oxo-6-phenyl-2-(2-phenylethyl)hexanoate

Conditions
ConditionsYield
With dimethyl sulfoxide In tetrahydrofuran at 0 - 20℃; for 15h; Claisen condensation;38%
4,4'-dimethyl-2,2'-bipyridines
1134-35-6

4,4'-dimethyl-2,2'-bipyridines

bis(acetylacetonato)palladium(II)

bis(acetylacetonato)palladium(II)

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

diethyl(4,4'-dimethyl-2,2'-bipyridine)palladium(II)

diethyl(4,4'-dimethyl-2,2'-bipyridine)palladium(II)

Conditions
ConditionsYield
In diethyl ether addn. of 11.0mmol (C2H5O)Al(C2H5)2 to 3.6mmol Pd-compound and 7.2mmol bipyridine in 50ml ether, stirring at 22°C for 6d, filtration, extractn. of residue with ethylether, concn. of ether extract, crystn. on cooling to -18°C (7d);; filtration under Ar, washing with ether, drying in vac.; elem. anal.;;32%
cis-3-benzyl-4-p-tolyl-oxetan-2-one

cis-3-benzyl-4-p-tolyl-oxetan-2-one

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

2-benzyl-3-hydroxy-3-p-tolyl-propionic acid ethyl ester

2-benzyl-3-hydroxy-3-p-tolyl-propionic acid ethyl ester

B

1-methyl-4-(3-phenyl-1-propen-1-yl)benzene
134539-87-0, 62056-37-5

1-methyl-4-(3-phenyl-1-propen-1-yl)benzene

Conditions
ConditionsYield
In tetrahydrofuran at 0 - 20℃; for 15h;A 27%
B 16%
1,10-Phenanthroline
66-71-7

1,10-Phenanthroline

bis(acetylacetonato)palladium(II)

bis(acetylacetonato)palladium(II)

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

diethyl(1.10-phenanthroline)palladium(II)
109298-81-9

diethyl(1.10-phenanthroline)palladium(II)

Conditions
ConditionsYield
In tetrahydrofuran addn. of 11.54mmol (C2H5O)Al(C2H5)2 to 3.84mmol Pd-compound and 7.88mmol phenanthroline in 30ml dry THF, stirring at room temp. for 160h, filtration, concn. of filtrate, crystn. on cooling to -18°C for several days; Ar atm.;; filtration under Ar, washing with ether, drying in vac.; elem. anal.;;17%
iron(III)-acetylacetonate
14024-18-1

iron(III)-acetylacetonate

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

bis(ethylene)tris(dimetylphenylphosphine)iron(0)
88326-00-5

bis(ethylene)tris(dimetylphenylphosphine)iron(0)

Conditions
ConditionsYield
In diethyl ether addn. of AlEt2OEt to soln. of Fe(acac)3 and PPhMe2, -39°C, warmed up to -5°C, stirred 30min, concd. up, soln. cooled down to -78°C, pptn., under deoxygenated Ar; recrystn. from ether below 0°C under Ar; elem. anal.;16%
diethyl ether
60-29-7

diethyl ether

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

Ni(C2H5)2(((C6H5)2PCH2)2)*0.5(C2H5)2O

Ni(C2H5)2(((C6H5)2PCH2)2)*0.5(C2H5)2O

Conditions
ConditionsYield
With bis-(diphenylphosphino)-ethane In diethyl ether AlEt2(OEt) added to mixt. of Ni(acac)2 and diphosphine in Et2O at -50°C, stirred at -20°C for 10 h; ppt. sepd. by filtration, washed with Et2O, dried in vac.; elem. anal.;12%
bis(acetylacetonate)nickel(II)

bis(acetylacetonate)nickel(II)

diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

1,5-dicyclooctadiene
5259-72-3, 10060-40-9, 111-78-4

1,5-dicyclooctadiene

cyclo-C8H12NiC5H7O2

cyclo-C8H12NiC5H7O2

Conditions
ConditionsYield
In benzene byproducts: Al(C5H7O2)3; 0°C; molar ratio of NiC5H7O2)2:1,5-cyclooctadiene:(C2H5)2AlOC2H5=1:2.5:2.3; 2.5h; solvolyse with ethanol and 2nHCl below 5°C; distn. in high vac. at 40-50°C; cooling and crystn.;10%
diethyl(ethoxy)aluminum
1586-92-1

diethyl(ethoxy)aluminum

methyl (2E)-penta-2,4-dienoate
2409-87-2

methyl (2E)-penta-2,4-dienoate

(Z)-3-carbomethoxy 4-(2-carbomethoxy vinyl) cyclohexene

(Z)-3-carbomethoxy 4-(2-carbomethoxy vinyl) cyclohexene

(Z)-3-carbomethoxy 4-(2-carboethoxy vinyl) cyclohexene

(Z)-3-carbomethoxy 4-(2-carboethoxy vinyl) cyclohexene

C

(Z)-cycloocta-3,7-diene-1,2-dicarboxylate de methyle

(Z)-cycloocta-3,7-diene-1,2-dicarboxylate de methyle

(Z)-1-carbomethoxy-2-carboethoxy cycloocta-3,7-diene

(Z)-1-carbomethoxy-2-carboethoxy cycloocta-3,7-diene

Conditions
ConditionsYield
With Ni(acac); threophos In toluene at 40℃; for 48h; Yield given. Further byproducts given. Yields of byproduct given;

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