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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 6-Methoxyindole supplier in China

Cas:3189-13-7

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

6-Methoxyindole Manufacturer/High quality/Best price/In stock

Cas:3189-13-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Hebei yanxi chemical co.,LTD.

Our advantage: 1: High quality and Competitive price 2: Quality control, GC&HPLC&NMR or as your requested 3: Packing as your requested, and double check before shipment 4: Prompt shipment with professional documents 5: Excellent after-

6-Methoxyindole CAS NO.3189-13-7

Cas:3189-13-7

Min.Order:1 Kilogram

FOB Price: $1.0 / 3.0

Type:Trading Company

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

6-Methoxyindole

Cas:3189-13-7

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. High quality and competitive price: 1) Standard: BP/USP/EP/ enterprise standard 2) All purity ≥99% 3) We are manufacturers and can provide high quality products at factory prices. 2. Fast and safe delivery 1) The packag

6-Methoxyindole CAS:3189-13-7

Cas:3189-13-7

Min.Order:1 Kilogram

FOB Price: $1.5 / 2.5

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Henan Tianfu Chemical Co., Ltd. is located in Zhengzhou High-tech Development Zone with import and export license. We passed ISO 9001:2008 in 2009, and won "High-tech Enterprise" by provincial government in 2013.The objective of the com

TIANFU-CHEM - 6-Methoxyindole

Cas:3189-13-7

Min.Order:1 Gram

FOB Price: $1000.0

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

New production CAS 3189-13-7 with best quality

Cas:3189-13-7

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

CAS: 3189-13-7 MF: C9H9NO MW: 147.17 EINECS: 221-689-6 Mol File: 3189-13-7.mol Appearance:White powder

6-Methoxyindole CAS: 3189-13-7

Cas:3189-13-7

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:Powder Storage:Store in sealed containers at cool & dry pla

6-Methoxyindole CAS 3189-13-7

Cas:3189-13-7

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

6-Methoxyindole 3189-13-7

Cas:3189-13-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

6-Methoxyindole

Cas:3189-13-7

Min.Order:1 Kilogram

FOB Price: $85.0 / 100.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

6-Methoxyindole CAS:3189-13-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermedia

6-Methoxyindole CAS:3189-13-7

Cas:3189-13-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

6-Methoxyindole

Cas:3189-13-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:3189-13-7

Cas:3189-13-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

6-Methoxyindole

Cas:3189-13-7

Min.Order:0

Negotiable

Type:Manufacturers

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

6-Methoxyindole

Cas:3189-13-7

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

6-Methoxyindole

Cas:3189-13-7

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

6-METHOXYINDOLE

Cas:3189-13-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

6-methoxyindole

Cas:3189-13-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

6-methoxy-1H-indole

Cas:3189-13-7

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 6-methoxyindole

Cas:3189-13-7

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

our strengths: 1: Fast and guaranteed shipment (TNT;EMS;FEDEX;DHL;UPS;EUB, special line) 2: Various payment items accepted (Btc; MoneyGram; WU) 3: Valued package (Paraffin coating; Double aluminum foil bag; Vacuum packaging) 4: Efficient delivery

Reliable quality 3189-13-7 lowest price 6-Methoxyindole Fast Delivery

Cas:3189-13-7

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

6-Methoxyindole

Cas:3189-13-7

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

6-Methoxyindole Manufacturer

Cas:3189-13-7

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

6-Methoxyindole

Cas:3189-13-7

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

6-Methoxyindole

Cas:3189-13-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

6-Methoxyindole

Cas:3189-13-7

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

6-Methoxyindole

Cas:3189-13-7

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Hangzhou Huarong Pharm Co., Ltd.

We Huarong Pharm can provide Customized Synthesis & Process R&D & APIs and intermediates Production & Quality Research & Registration Application, especially our GMP validation service which complies with SFDA, FDA, WHO and EU EMPA. O

6-Methoxyindole

Cas:3189-13-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

6-Methoxyindole

Cas:3189-13-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

6-Methoxyindole-2-carboxylic acid
16732-73-3

6-Methoxyindole-2-carboxylic acid

6-methoxylindole
3189-13-7

6-methoxylindole

Conditions
ConditionsYield
In quinoline for 0.2h; microwave;99%
With copper In quinoline for 2h; Heating;97.6%
With quinoline; copper Heating;87%
With quinoline; copper at 220℃; for 0.2h; Microwave irradiation;70%
With quinoline; copper oxide-chromium oxide at 200 - 210℃;
tert-butyl 6-methoxy-1H-indole-1-carboxylate
138344-18-0

tert-butyl 6-methoxy-1H-indole-1-carboxylate

6-methoxylindole
3189-13-7

6-methoxylindole

Conditions
ConditionsYield
With sodium hydroxide In ethanol for 1h; Heating;98%
6-methoxy-N-(toluenesulfonyl)indole
107734-26-9

6-methoxy-N-(toluenesulfonyl)indole

6-methoxylindole
3189-13-7

6-methoxylindole

Conditions
ConditionsYield
With magnesium In methanol at 20℃; for 1.5h; Sonication;96%
1-(E)-(2-(4-methoxy-2-nitrophenyl)vinyl)pyrrolidine
1335101-95-5

1-(E)-(2-(4-methoxy-2-nitrophenyl)vinyl)pyrrolidine

6-methoxylindole
3189-13-7

6-methoxylindole

Conditions
ConditionsYield
With iron(III) chloride hexahydrate; pyrographite; hydrazine hydrate In ethanol at 75℃; for 7h;93%
(5-bromo-4-methoxy-2-nitrophenyl)acetonitrile
111795-95-0

(5-bromo-4-methoxy-2-nitrophenyl)acetonitrile

6-methoxylindole
3189-13-7

6-methoxylindole

Conditions
ConditionsYield
With hydrogen; acetic acid; 10% palladium on active carbon In ethanol under 2280 Torr; for 2h; Ambient temperature;90%
6-methoxy-1-tosylindoline

6-methoxy-1-tosylindoline

6-methoxylindole
3189-13-7

6-methoxylindole

Conditions
ConditionsYield
Stage #1: 6-methoxy-1-tosylindoline In tetrahydrofuran at -78℃; for 2h;
Stage #2: With oxygen In tetrahydrofuran at 20℃;
86%
acetaldehyde 3-methoxyphenylhydrazone
34158-98-0

acetaldehyde 3-methoxyphenylhydrazone

A

6-methoxylindole
3189-13-7

6-methoxylindole

B

4-methoxy-1H-indole
4837-90-5

4-methoxy-1H-indole

Conditions
ConditionsYield
GIPKh-115 In benzene at 260 - 280℃; (g) phase;A n/a
B 85%
GIPKh-115 In benzene at 180 - 320℃; (g) phase. Object of study: effect of electronic factors;A n/a
B 85%
GIPKh-115 at 260 - 280℃; Yield given. Yields of byproduct given;
6-methoxy-2,3-dihydro-1H-indole
7556-47-0

6-methoxy-2,3-dihydro-1H-indole

6-methoxylindole
3189-13-7

6-methoxylindole

Conditions
ConditionsYield
Stage #1: 6-methoxy-2,3-dihydro-1H-indole In tetrahydrofuran at -78℃; for 2h;
Stage #2: With oxygen In tetrahydrofuran at 20℃;
85%
With potassium tert-butylate In o-xylene at 140℃; for 36h; Inert atmosphere;70%
With oxygen In N,N-dimethyl acetamide at 20℃; Schlenk technique; Irradiation;44%
With monoamine oxidase D11 In aq. phosphate buffer; dimethyl sulfoxide at 37℃; for 168h; pH=7.8; Enzymatic reaction;40%
Multi-step reaction with 2 steps
1.1: pyridine / dichloromethane
2.1: / tetrahydrofuran / 2 h / -78 °C
2.2: 20 °C
View Scheme
2,2-dimethoxy-1-(4-methoxy-2-nitrophenyl)ethane

2,2-dimethoxy-1-(4-methoxy-2-nitrophenyl)ethane

6-methoxylindole
3189-13-7

6-methoxylindole

Conditions
ConditionsYield
With hydrogenchloride; iron; acetic acid In ethanol Temp. 70 - 75 deg C, 1 h. Temp. 85 deg C, 2 h;84%
6-bromo-1H-indole
52415-29-9

6-bromo-1H-indole

sodium methylate
124-41-4

sodium methylate

6-methoxylindole
3189-13-7

6-methoxylindole

Conditions
ConditionsYield
With copper(l) iodide In N,N-dimethyl-formamide for 12h;73%
cyano-(4-methoxy-2-nitro-phenyl)-acetic acid benzyl ester

cyano-(4-methoxy-2-nitro-phenyl)-acetic acid benzyl ester

A

6-methoxylindole
3189-13-7

6-methoxylindole

B

6-methoxy-2,3-dihydro-1H-indole
7556-47-0

6-methoxy-2,3-dihydro-1H-indole

C

2-(2-amino-ethyl)-5-methoxy-phenylamine
605668-99-3

2-(2-amino-ethyl)-5-methoxy-phenylamine

Conditions
ConditionsYield
With hydrogen; acetic acid; palladium on activated charcoal In ethanol; water at 25℃; under 2585.74 Torr; for 18h;A 73%
B n/a
C n/a
1-(2-Bromo-2-chloro-ethyl)-4-methoxy-2-nitro-benzene
85355-57-3

1-(2-Bromo-2-chloro-ethyl)-4-methoxy-2-nitro-benzene

6-methoxylindole
3189-13-7

6-methoxylindole

Conditions
ConditionsYield
With sodium acetate; iron; acetic acid In ethanol; water for 2h; Heating;71%
6-hydroxy-1H-indole
2380-86-1

6-hydroxy-1H-indole

methyl iodide
74-88-4

methyl iodide

6-methoxylindole
3189-13-7

6-methoxylindole

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at -20℃; for 0.166667h;68%
C10H9N3O3

C10H9N3O3

6-methoxylindole
3189-13-7

6-methoxylindole

Conditions
ConditionsYield
With quinoline; copper at 220℃; for 0.2h; Microwave irradiation;56%
Multi-step reaction with 2 steps
1: tetrakis(trifluoroacetato)rhodium(II) / toluene / 0.25 h / 100 °C / Microwave irradiation
2: quinoline; copper / 0.2 h / 220 °C / Microwave irradiation
View Scheme
ethene
74-85-1

ethene

4-bromo-3-nitroanizole
5344-78-5

4-bromo-3-nitroanizole

A

6-methoxylindole
3189-13-7

6-methoxylindole

B

1-methoxy-3-nitro-4-vinylbenzene
126759-34-0

1-methoxy-3-nitro-4-vinylbenzene

Conditions
ConditionsYield
With triethylamine; tris-(o-tolyl)phosphine; palladium diacetate In acetonitrile at 120℃; under 22800 Torr; for 24h;A 48%
B 32%
1-ethenyl-2-pyrrolidinone
88-12-0

1-ethenyl-2-pyrrolidinone

2-bromo-5-methoxyaniline
59557-92-5

2-bromo-5-methoxyaniline

6-methoxylindole
3189-13-7

6-methoxylindole

Conditions
ConditionsYield
With triethylamine; palladium diacetate; tris-(o-tolyl)phosphine In acetonitrile at 100℃; for 20h; sealed tube;46%
4-methoxy-1-ethyl-2-nitrobenzene
90610-20-1

4-methoxy-1-ethyl-2-nitrobenzene

6-methoxylindole
3189-13-7

6-methoxylindole

Conditions
ConditionsYield
With tetrakis(trifluoroacetato)rhodium(II); caesium carbonate In N,N-dimethyl-formamide at 140℃; for 24h; Schlenk technique; Inert atmosphere;45%
1-methoxy-3-nitro-4-vinylbenzene
126759-34-0

1-methoxy-3-nitro-4-vinylbenzene

6-methoxylindole
3189-13-7

6-methoxylindole

Conditions
ConditionsYield
With carbon monoxide; triphenylphosphine; palladium diacetate In acetonitrile under 3040 Torr; for 21h; Heating;40%
Multi-step reaction with 2 steps
1: 65 percent / O2 (1 atm) / Na2PdCl4 / 24 h
2: 84 percent / Fe, acetic acid, 10percent HCl / ethanol / Temp. 70 - 75 deg C, 1 h. Temp. 85 deg C, 2 h
View Scheme
Multi-step reaction with 2 steps
1: 80 percent / oxygen / palladium(II) chloride, copper(I) chloride / 1,2-dimethoxy-ethane / 24 h / 50 - 60 °C
2: 1.) H2, 2.) aq. HCl / 10percent rhodium-carbon / 1.) ethanol, room temperature, 1 atmosphere, 3 h, 2.) room temperature, 3 h
View Scheme
N-(3-methoxyphenyl)ethenesulfinamide
105896-37-5

N-(3-methoxyphenyl)ethenesulfinamide

A

6-methoxylindole
3189-13-7

6-methoxylindole

B

4-methoxy-1H-indole
4837-90-5

4-methoxy-1H-indole

Conditions
ConditionsYield
In toluene at 110℃; for 1h;A 25%
B 5%
2,β-Dinitro-4-methoxy-styrol
99459-34-4

2,β-Dinitro-4-methoxy-styrol

6-methoxylindole
3189-13-7

6-methoxylindole

Conditions
ConditionsYield
With palladium on activated charcoal; ethanol; ethyl acetate Hydrogenation.Reagens 4: Essigsaeure;
With ethanol; iron; acetic acid
pyrrolidine
123-75-1

pyrrolidine

4-Methyl-3-nitroanisole
17484-36-5

4-Methyl-3-nitroanisole

N,N-dimethyl-formamide dimethyl acetal
4637-24-5

N,N-dimethyl-formamide dimethyl acetal

6-methoxylindole
3189-13-7

6-methoxylindole

Conditions
ConditionsYield
With ammonium acetate; titanium(III) chloride 1) DMF, 100-110 deg C, 3 h, 2) water, DMF, 15 min; Yield given. Multistep reaction;
4-Methyl-3-nitroanisole
17484-36-5

4-Methyl-3-nitroanisole

6-methoxylindole
3189-13-7

6-methoxylindole

Conditions
ConditionsYield
With pyrrolidine; dimethylamide dimethyl acetal; hydrogen; palladium on activated charcoal 1.) DMF, 105 deg C, 19 h, 2.) ethyl acetate, 50 p.s.i., 3 h; Yield given. Multistep reaction;
Multi-step reaction with 2 steps
1: 4 h / 110 °C
2: TiCl3, 4M NH4OAc / acetone
View Scheme
Multi-step reaction with 2 steps
1: N,N-dimethyl-formamide / 20 h / 115 °C / Inert atmosphere
2: iron(III) chloride hexahydrate; pyrographite; hydrazine hydrate / ethanol / 7 h / 75 °C
View Scheme
2-(4-methoxy-2-nitrophenyl)acetaldehyde
69111-92-8

2-(4-methoxy-2-nitrophenyl)acetaldehyde

6-methoxylindole
3189-13-7

6-methoxylindole

Conditions
ConditionsYield
With sodium acetate; iron; acetic acid In ethanol; water for 2h; Heating; Yield given;
1-[(E)-2-(4-Methoxy-2-nitro-phenyl)-vinyl]-piperidine

1-[(E)-2-(4-Methoxy-2-nitro-phenyl)-vinyl]-piperidine

6-methoxylindole
3189-13-7

6-methoxylindole

Conditions
ConditionsYield
With titanium(III) chloride; ammonium acetate In acetone Yield given;
Acetic acid 1-chloro-2-(4-methoxy-2-nitro-phenyl)-ethyl ester
85355-35-7

Acetic acid 1-chloro-2-(4-methoxy-2-nitro-phenyl)-ethyl ester

6-methoxylindole
3189-13-7

6-methoxylindole

Conditions
ConditionsYield
With sodium acetate; iron; acetic acid In ethanol; water for 2h; Heating;
N-(2,2-Diethoxy-ethyl)-2,2,2-trifluoro-N-(3-methoxy-phenyl)-acetamide
75934-38-2

N-(2,2-Diethoxy-ethyl)-2,2,2-trifluoro-N-(3-methoxy-phenyl)-acetamide

A

6-methoxylindole
3189-13-7

6-methoxylindole

B

4-methoxy-1H-indole
4837-90-5

4-methoxy-1H-indole

Conditions
ConditionsYield
With potassium hydroxide; trifluoroacetic anhydride 1) CF3COOH, 56 deg C, 56 h; 2) methanol, room temperature; Yield given. Multistep reaction. Yields of byproduct given;
2-<(4-methoxy-2-nitrophenyl)methyl>-1,3-dioxane
126759-42-0

2-<(4-methoxy-2-nitrophenyl)methyl>-1,3-dioxane

6-methoxylindole
3189-13-7

6-methoxylindole

Conditions
ConditionsYield
With hydrogenchloride; hydrogen; rhodium contaminated with carbon 1.) ethanol, room temperature, 1 atmosphere, 3 h, 2.) room temperature, 3 h; Yield given. Multistep reaction;
triethanolamine
102-71-6

triethanolamine

m-Anisidine
536-90-3

m-Anisidine

A

6-methoxylindole
3189-13-7

6-methoxylindole

B

4-methoxy-1H-indole
4837-90-5

4-methoxy-1H-indole

Conditions
ConditionsYield
With tin(ll) chloride; ruthenium trichloride; triphenylphosphine In 1,4-dioxane at 180℃; for 20h; Yield given. Yields of byproduct given;
6-methoxy-indole-carboxylic acid-(2)

6-methoxy-indole-carboxylic acid-(2)

6-methoxylindole
3189-13-7

6-methoxylindole

6-methoxylindole
3189-13-7

6-methoxylindole

6-methoxy-2,3-dihydro-1H-indole
7556-47-0

6-methoxy-2,3-dihydro-1H-indole

Conditions
ConditionsYield
With borane-THF In tetrahydrofuran at 0℃; for 0.5h;100%
Stage #1: 6-methoxylindole With sodium cyanoborohydride; acetic acid In N,N-dimethyl-formamide at 20℃; for 2h;
Stage #2: With water; sodium hydroxide In N,N-dimethyl-formamide
100%
With sodium cyanoborohydride; acetic acid at 20℃; for 3h;97%
6-methoxylindole
3189-13-7

6-methoxylindole

N,N-dimethyl(methylene)ammonium chloride
30354-18-8

N,N-dimethyl(methylene)ammonium chloride

1-(6-methoxy-1H-indol-3-yl)-N,N-dimethylmethanamine
62467-65-6

1-(6-methoxy-1H-indol-3-yl)-N,N-dimethylmethanamine

Conditions
ConditionsYield
In dichloromethane100%
6-methoxylindole
3189-13-7

6-methoxylindole

p-methoxybenzyl chloride
824-94-2

p-methoxybenzyl chloride

6-methoxy-N-(4-methoxybenzyl)indole
1142120-31-7

6-methoxy-N-(4-methoxybenzyl)indole

Conditions
ConditionsYield
Stage #1: 6-methoxylindole With sodium hydride In N,N-dimethyl-formamide at 25℃;
Stage #2: p-methoxybenzyl chloride In N,N-dimethyl-formamide at 25℃; for 12h;
100%
6-methoxylindole
3189-13-7

6-methoxylindole

(C-benzyloxymethane-N-benzyl)nitrone
192220-12-5, 199463-78-0

(C-benzyloxymethane-N-benzyl)nitrone

1-[N-benzyl-N-(hydroxy)amino]-2-[N'-(tert-butoxycarbonyl)amino]-1-(6'-methoxyindol-3'-yl)ethane
952235-30-2

1-[N-benzyl-N-(hydroxy)amino]-2-[N'-(tert-butoxycarbonyl)amino]-1-(6'-methoxyindol-3'-yl)ethane

Conditions
ConditionsYield
Stage #1: 6-methoxylindole; (C-benzyloxymethane-N-benzyl)nitrone With hydrogenchloride In methanol at 0℃;
Stage #2: With sodium hydrogencarbonate In methanol; water
100%
6-methoxylindole
3189-13-7

6-methoxylindole

benzenesulfonyl chloride
98-09-9

benzenesulfonyl chloride

6-methoxy-1-(phenylsulfonyl)-1H-indole
56995-13-2

6-methoxy-1-(phenylsulfonyl)-1H-indole

Conditions
ConditionsYield
Stage #1: 6-methoxylindole With tetra(n-butyl)ammonium hydrogensulfate; sodium hydroxide In dichloromethane at 4℃; Inert atmosphere; Sealed tube;
Stage #2: benzenesulfonyl chloride In dichloromethane at 4 - 23℃; for 3h; Inert atmosphere; Sealed tube;
99%
Stage #1: 6-methoxylindole With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 0.333333h; Inert atmosphere;
Stage #2: benzenesulfonyl chloride In tetrahydrofuran; mineral oil at 0 - 20℃; Inert atmosphere;
93.8%
Stage #1: 6-methoxylindole With sodium hydride In tetrahydrofuran at 0 - 20℃;
Stage #2: benzenesulfonyl chloride In tetrahydrofuran at 20℃; for 1h;
92%
6-methoxylindole
3189-13-7

6-methoxylindole

benzyl bromide
100-39-0

benzyl bromide

1-benzyl-6-methoxy-1H-indole
90811-54-4

1-benzyl-6-methoxy-1H-indole

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 20℃; for 12h;99%
With potassium hydroxide In dimethyl sulfoxide at 20℃;93%
With sodium hydride In N,N-dimethyl-formamide; mineral oil at 20℃; Inert atmosphere;91%
maleiimide
541-59-3

maleiimide

6-methoxylindole
3189-13-7

6-methoxylindole

3-(6-methoxy-1H-indol-3-yl)pyrrolidine-2,5-dione
885320-48-9

3-(6-methoxy-1H-indol-3-yl)pyrrolidine-2,5-dione

Conditions
ConditionsYield
With acetic acid at 190℃; for 2h; Michael addition; microwave irradiation;99%
In acetic acid at 170℃; for 2h; Microwave irradiation;
6-methoxylindole
3189-13-7

6-methoxylindole

methyl 4-phenyl-2-oxo-3-butenoate
107969-78-8, 6395-86-4

methyl 4-phenyl-2-oxo-3-butenoate

4-(6-methoxyindol-3-yl)-2-oxo-4-phenylbutyric acid methyl ester

4-(6-methoxyindol-3-yl)-2-oxo-4-phenylbutyric acid methyl ester

Conditions
ConditionsYield
With C35H48N4O4; samarium(III) trifluoromethanesulfonate In dichloromethane at -20℃; for 0.5h; asymmetric Friedel-Crafts alkylation; Inert atmosphere; optical yield given as %ee;99%
6-methoxylindole
3189-13-7

6-methoxylindole

tert-butyl 3-((tert-butoxycarbonyl)imino)-2-oxoindoline-1-carboxylate
1373942-86-9

tert-butyl 3-((tert-butoxycarbonyl)imino)-2-oxoindoline-1-carboxylate

tert-butyl (R)-3-((tert-butoxycarbonyl)amino)-3-(6-methoxy-1H-indol-3-yl)-2-oxoindoline-1-carboxylate

tert-butyl (R)-3-((tert-butoxycarbonyl)amino)-3-(6-methoxy-1H-indol-3-yl)-2-oxoindoline-1-carboxylate

Conditions
ConditionsYield
Stage #1: tert-butyl 3-((tert-butoxycarbonyl)imino)-2-oxoindoline-1-carboxylate With C33H48N4O4; zinc trifluoromethanesulfonate In toluene at 35℃; for 0.5h; Inert atmosphere; Molecular sieve;
Stage #2: 6-methoxylindole In toluene at 50℃; for 48h; Friedel-Crafts Alkylation; Inert atmosphere; Molecular sieve; enantioselective reaction;
99%
6-methoxylindole
3189-13-7

6-methoxylindole

C16H18N2O5

C16H18N2O5

tert-butyl (R)-3-((ethoxycarbonyl)amino)-3-(6-methoxy-1H-indol-3-yl)-2-oxoindoline-1-carboxylate

tert-butyl (R)-3-((ethoxycarbonyl)amino)-3-(6-methoxy-1H-indol-3-yl)-2-oxoindoline-1-carboxylate

Conditions
ConditionsYield
Stage #1: C16H18N2O5 With C33H48N4O4; zinc trifluoromethanesulfonate In toluene at 35℃; for 0.5h; Inert atmosphere; Molecular sieve;
Stage #2: 6-methoxylindole In toluene at 50℃; for 48h; Friedel-Crafts Alkylation; Inert atmosphere; Molecular sieve; enantioselective reaction;
99%
6-methoxylindole
3189-13-7

6-methoxylindole

3-(1-phenylvinyl)-1H-indole

3-(1-phenylvinyl)-1H-indole

(R)-3-(1-(1H-indol-3-yl)-1-phenylethyl)-6-methoxy-1H-indole

(R)-3-(1-(1H-indol-3-yl)-1-phenylethyl)-6-methoxy-1H-indole

Conditions
ConditionsYield
Stage #1: 3-(1-phenylvinyl)-1H-indole With C76H57F12NO6P2 In 1,2-dichloro-ethane at -20℃; for 0.166667h; Molecular sieve;
Stage #2: 6-methoxylindole In 1,2-dichloro-ethane at -20℃; for 24h; Molecular sieve; enantioselective reaction;
99%
6-methoxylindole
3189-13-7

6-methoxylindole

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

6-methoxy-1H-indole-3-carbaldehyde
70555-46-3

6-methoxy-1H-indole-3-carbaldehyde

Conditions
ConditionsYield
With trichlorophosphate at 20℃; for 2.5h;98%
With trichlorophosphate at 0 - 40℃; Vilsmeier formylation;89%
Stage #1: N,N-dimethyl-formamide With trichlorophosphate for 0.333333h; Vilsmeier-Haack Formylation; Cooling with ice;
Stage #2: 6-methoxylindole at 20℃; for 1.5h; Vilsmeier-Haack Formylation;
59%
6-methoxylindole
3189-13-7

6-methoxylindole

tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

1-(tert-butyldimethylsilyl)-6-methoxy-1H-indole
180635-97-6

1-(tert-butyldimethylsilyl)-6-methoxy-1H-indole

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; hexane at 20℃; for 10h;98%
Stage #1: 6-methoxylindole With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 0.75h; Inert atmosphere;
Stage #2: tert-butyldimethylsilyl chloride In tetrahydrofuran; mineral oil at 0 - 20℃; for 6h; Inert atmosphere;
79%
Stage #1: 6-methoxylindole With n-butyllithium In tetrahydrofuran; hexane at -10℃; for 0.25h;
Stage #2: tert-butyldimethylsilyl chloride In tetrahydrofuran; hexane at 0℃; for 3h;
6-methoxylindole
3189-13-7

6-methoxylindole

(2-bromo-ethoxy)-tert-butyl-dimethyl-silane
1220198-08-2

(2-bromo-ethoxy)-tert-butyl-dimethyl-silane

1-[2-(tert-butyldimethylsilyloxy)-eth-1-yl]-6-methoxy-1H-indole
408355-39-5

1-[2-(tert-butyldimethylsilyloxy)-eth-1-yl]-6-methoxy-1H-indole

Conditions
ConditionsYield
In N,N-dimethyl-formamide98%
6-methoxylindole
3189-13-7

6-methoxylindole

ethyl 5-methyl-2-oxo-3,4-dihydro-2H-benzo[b][1,4]oxazine-3-carboxylate
1533443-74-1

ethyl 5-methyl-2-oxo-3,4-dihydro-2H-benzo[b][1,4]oxazine-3-carboxylate

ethyl (R)-3-(6-methoxy-1H-indol-3-yl)-5-methyl-2-oxo-3,4-dihydro-2H-benzo[b][1,4]oxazine-3-carboxylate
1533444-34-6

ethyl (R)-3-(6-methoxy-1H-indol-3-yl)-5-methyl-2-oxo-3,4-dihydro-2H-benzo[b][1,4]oxazine-3-carboxylate

Conditions
ConditionsYield
With C38H33O4P In toluene at -78℃; for 6h; enantioselective reaction;98%
6-methoxylindole
3189-13-7

6-methoxylindole

benzyl alcohol
100-51-6

benzyl alcohol

3-benzyl-6-methoxy-1H-indole

3-benzyl-6-methoxy-1H-indole

Conditions
ConditionsYield
With C18H18Cl4N2Ni2O2; potassium 2-methylbutan-2-olate In neat (no solvent) at 140℃; for 6h;98%
Stage #1: 6-methoxylindole; benzyl alcohol With potassium phosphate; C24H20FeN2O4 In neat (no solvent) at 20℃; for 2h; Schlenk technique; Inert atmosphere; UV-irradiation;
Stage #2: In neat (no solvent) at 110℃; for 16h; Schlenk technique; Inert atmosphere;
73%
6-methoxylindole
3189-13-7

6-methoxylindole

ethyl-4-cyanobenzoylformate
302912-31-8

ethyl-4-cyanobenzoylformate

(4-cyano-phenyl)-hydroxy-(6-methoxy-1H-indol-3-yl)-acetic acid ethyl ester

(4-cyano-phenyl)-hydroxy-(6-methoxy-1H-indol-3-yl)-acetic acid ethyl ester

Conditions
ConditionsYield
With PHN-DHQ-OH In diethyl ether at 23℃; for 58h; Friedel-Crafts reaction;97%
6-methoxylindole
3189-13-7

6-methoxylindole

ethyl-4-cyanobenzoylformate
302912-31-8

ethyl-4-cyanobenzoylformate

(4-cyano-phenyl)-hydroxy-(6-methoxy-1H-indol-3-yl)-acetic acid ethyl ester

(4-cyano-phenyl)-hydroxy-(6-methoxy-1H-indol-3-yl)-acetic acid ethyl ester

Conditions
ConditionsYield
With 4-((S)-(phenanthren-9-yloxy)((2R,4S,8R)-8-vinylquinuclidin-2-yl)methyl)quinolin-6-ol In diethyl ether at 23℃; for 59h; Friedel-Crafts reaction;97%
6-methoxylindole
3189-13-7

6-methoxylindole

2-nitrobenzenesulfenyl chloride
7669-54-7

2-nitrobenzenesulfenyl chloride

6-methoxy-3-(2-nitro-phenylsulfanyl)-1H-indole
691399-75-4

6-methoxy-3-(2-nitro-phenylsulfanyl)-1H-indole

Conditions
ConditionsYield
In diethyl ether at 20℃; for 1.06667h;97%
6-methoxylindole
3189-13-7

6-methoxylindole

triisopropylsilyl chloride
13154-24-0

triisopropylsilyl chloride

6-methoxy-1-(triisopropylsilyl)-1H-indole

6-methoxy-1-(triisopropylsilyl)-1H-indole

Conditions
ConditionsYield
Stage #1: 6-methoxylindole With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 0.5h;
Stage #2: triisopropylsilyl chloride In tetrahydrofuran; mineral oil at 0 - 20℃;
97%
6-methoxylindole
3189-13-7

6-methoxylindole

formaldehyd
50-00-0

formaldehyd

dimethyl amine
124-40-3

dimethyl amine

1-(6-methoxy-1H-indol-3-yl)-N,N-dimethylmethanamine
62467-65-6

1-(6-methoxy-1H-indol-3-yl)-N,N-dimethylmethanamine

Conditions
ConditionsYield
In acetic acid for 15h; Ambient temperature;96%
With ethanol; acetic acid
With 1,4-dioxane; acetic acid
With acetic acid at 0 - 20℃; for 4h;
With acetic acid at 0 - 25℃; for 12h;
6-methoxylindole
3189-13-7

6-methoxylindole

di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

tert-butyl 6-methoxy-1H-indole-1-carboxylate
138344-18-0

tert-butyl 6-methoxy-1H-indole-1-carboxylate

Conditions
ConditionsYield
With dmap In dichloromethane at 20℃; for 8h; Inert atmosphere;96%
With dmap In dichloromethane at 0 - 20℃; Inert atmosphere;90%
With dmap; triethylamine In dichloromethane at 0 - 20℃; for 16h;89%
With dmap In dichloromethane at 40℃;86%
6-methoxylindole
3189-13-7

6-methoxylindole

acetyl chloride
75-36-5

acetyl chloride

1-(6-methoxy-1H-indol-3-yl)ethan-1-one
99532-52-2

1-(6-methoxy-1H-indol-3-yl)ethan-1-one

Conditions
ConditionsYield
Stage #1: 6-methoxylindole With diethylaluminium chloride In hexane; dichloromethane at 0℃; for 0.5h;
Stage #2: acetyl chloride In hexane; dichloromethane at 50℃; for 0.166667h; microwave irradiation; Further stages.;
96%
Stage #1: 6-methoxylindole With diethylaluminium chloride In hexane; dichloromethane at 0℃; for 0.5h; Inert atmosphere;
Stage #2: acetyl chloride In hexane; dichloromethane at 0℃; Inert atmosphere;
Stage #1: 6-methoxylindole; acetyl chloride In toluene at 0℃; for 0.166667h;
Stage #2: With tin(IV) chloride In toluene for 12h;
Stage #1: 6-methoxylindole With diethylaluminium chloride In hexane; dichloromethane at 0℃; for 0.5h; Inert atmosphere;
Stage #2: acetyl chloride In hexane; dichloromethane at 0℃; Inert atmosphere;
p-nitrobenzene iodide
636-98-6

p-nitrobenzene iodide

6-methoxylindole
3189-13-7

6-methoxylindole

6-methoxy-1-(4-nitrophenyl)-1H-indole
1234333-70-0

6-methoxy-1-(4-nitrophenyl)-1H-indole

Conditions
ConditionsYield
With 1,2-ethanedione dioxime; tetrabutylammomium bromide; copper(l) chloride; sodium hydroxide In water at 100℃; for 24h; Inert atmosphere; sealed tube;96%
6-methoxylindole
3189-13-7

6-methoxylindole

cyanoacetic acid
372-09-8

cyanoacetic acid

3-(6-methoxy-1H-indol-3-yl)-3-oxopropanenitrile
1082892-90-7

3-(6-methoxy-1H-indol-3-yl)-3-oxopropanenitrile

Conditions
ConditionsYield
With propionic acid anhydride at 65 - 75℃; for 0.116667h;96%
With propionic acid anhydride at 100℃;
6-methoxylindole
3189-13-7

6-methoxylindole

methyl bromide
74-83-9

methyl bromide

6-methoxy-1-methyl-1H-indole
1968-17-8

6-methoxy-1-methyl-1H-indole

Conditions
ConditionsYield
With potassium hydroxide In dimethyl sulfoxide at 20℃;96%
6-methoxylindole
3189-13-7

6-methoxylindole

1-phenylmethyl-4-piperidone
3612-20-2

1-phenylmethyl-4-piperidone

6-methoxy-3-(1-benzyl-1,2,3,6-tetrahydropyridin-4-yl)-1H-indole
52157-77-4

6-methoxy-3-(1-benzyl-1,2,3,6-tetrahydropyridin-4-yl)-1H-indole

Conditions
ConditionsYield
With sodium methylate In methanol for 5h; Heating;95%

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