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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

1,4-phenylene diisothiocyanate

Cas:4044-65-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

p-Phenylenediisothiocyanate

Cas:4044-65-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name: 1,4-PHENYLENE DIISOTHIOCYANATE Synonyms: 1,4-diisothiocyanato-benzen;1,4-diisothiocyanatobenzene[qr];1,4-phenylenedi-isothiocyanicaci;16842(uspddn)[qr];ai3-28258[qr];Benzene, 1,4-diisothiocyanato-;benzene,1,4-diisothiocya

4044-65-9 1,4-PHENYLENE DIISOTHIOCYANATE

Cas:4044-65-9

Min.Order:1 Gram

FOB Price: $8900.0

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 4044-65-9 with best quality

Cas:4044-65-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

1,4-Phenylenediisothiocyanic acid

Cas:4044-65-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply p-Phenylene Diisothiocyanate

Cas:4044-65-9

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,4-Phenylenediisothiocyanic acid

Cas:4044-65-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

1,4-PHENYLENE DIISOTHIOCYANATE/High quality/Best price

Cas:4044-65-9

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

1,4-Diisothiocyanatobenzene

Cas:4044-65-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

1,4-Phenylene Diisothiocyanate

Cas:4044-65-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

3,4-dehydro-L-proline

Cas:4044-65-9

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

1,4-Phenylene Diisothiocyanate

Cas:4044-65-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

p-Phenylene diisothiocyanate

Cas:4044-65-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Chemical intermediate

1,4-PHENYLENE DIISOTHIOCYANATE

Cas:4044-65-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

1,4-PHENYLENE DIISOTHIOCYANATECASAppearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

1,4-PHENYLENE DIISOTHIOCYANATECAS

Cas:4044-65-9

Min.Order:0

Negotiable

Type:Other

inquiry

BOC Sciences

BOC Sciences provides a wide range of research chemicals and biochemicals including inhibitors, building blocks, GMP Products, impurities and metabolites, APIs for Veterinary, Natural Compounds, ADCs, Stem Cell Molecule and chiral compounds.Appearanc

Bitoscanate

Cas:4044-65-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Yuanye Bio-Technology Co., Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:1g Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by express or by sea Port:Any port

p-Phenylene diisothiocyanate(PDITC)

Cas:4044-65-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemlyte Solutions

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

1,4-PHENYLENE DIISOTHIOCYANATE

Cas:4044-65-9

Min.Order:0

Negotiable

Type:Other

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

1,4-Diisothiocyanatobenzene 4044-65-9

Cas:4044-65-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Scochem Technology Co., Ltd.

High quality suppliers Application:healing drugs

1,4-phenylene diisothiocyanate

Cas:4044-65-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shenzhen Foris Technology Co. LTD

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

1,4-Diisothiocyanatobenzene 4044-65-9

Cas:4044-65-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

1,4-PHENYLENE DIISOTHIOCYANATE

Cas:4044-65-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

1,4-PHENYLENE DIISOTHIOCYANATE Basic information Product Name: 1,4-PHENYLENE DIISOTHIOCYANATE

4044-65-9 C8H4N2S2 1,4-PHENYLENE DIISOTHIOCYANATE

Cas:4044-65-9

Min.Order:100 Gram

Negotiable

Type:Trading Company

inquiry

Changzhou Xuanming Chemical Co., Ltd.

Changzhou Xuanming Chemical Co., Ltd. is dedicated to the technology development, manufacturing, import and export chemicals, which are specialized in pharmaceutical intermediates, pesticide intermediate, industry of fine chemicals and custom synth

1,4-PHENYLENE DIISOTHIOCYANATE

Cas:4044-65-9

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Ningbo Inno Pharmchem Co., Ltd.

We listen carefully to our customers' opinions and needs, and provide timely and effective feedback, and continue to improve and improve, ready to accept greater challengesAppearance:See details Storage:Room temperature Package:See details Applicatio

CAS:4044-65-9 1,4-Phenylene Diisothiocyanate

Cas:4044-65-9

Min.Order:1 Metric Ton

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Yinghao Pharm Co.,Ltd.

Yinghao Pharm products include: leader molecule, heterocyclic compounds,chiral compounds, photoelectric materials, biochemical reagents etc. For example:benzene, pyrimidine, boricacid,pyridine, pyrazole, imidazole, pyrrole, fluorine and other derivat

1,4-PHENYLENE DIISOTHIOCYANATE

Cas:4044-65-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

U-Chemo Holding Co.,Limited

U-CHEMO is a high-tech enterprise taking pharmaceutical intermediates and fine chemicals as main products. We pay high attention on product quality and apply quality management in the whole manufacturing process from research to production. In additi

1,4-DIISOTHIOCYANATOBENZENE; PDITC

Cas:4044-65-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Share Chemical Co., Ltd

At Share Chemical Company, we scrupulously abide by our policy of “Excellent Quality at a Reasonable Price”. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi

1,4-Phenylene diisothiocyanate

Cas:4044-65-9

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Finetech Industry Limited

FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the 1,4-PHENYLENE DIISOTHIOCYANATE, CAS:4044-65-9 with the most competitive price and the

1,4-PHENYLENE DIISOTHIOCYANATE

Cas:4044-65-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Pure Chemistry Scientific Inc.

1,4-Diisothiocyanatobenzene Application:827047

1,4-Diisothiocyanatobenzene

Cas:4044-65-9

Min.Order:1 Gram

FOB Price: $500.0

Type:Trading Company

inquiry

Synthetic route

N,N'-(1,4-Phenylene)bis(methyldithiocarbamate)
19972-69-1

N,N'-(1,4-Phenylene)bis(methyldithiocarbamate)

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

Conditions
ConditionsYield
With ammonium hydroxide; mercury(II) oxide In N,N-dimethyl-formamide at 40℃; for 4h; also with other bis(dithiocarbamates) to form the corresponding p-arylenediisothiocyanates;83%
With ammonium hydroxide; mercury(II) oxide In N,N-dimethyl-formamide at 40℃; for 4h;83%
carbon disulfide
75-15-0

carbon disulfide

1,4-phenylenediamine
106-50-3

1,4-phenylenediamine

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

Conditions
ConditionsYield
Stage #1: carbon disulfide; 1,4-phenylenediamine With triethylamine In tetrahydrofuran at 0 - 20℃; for 16h;
Stage #2: With p-toluenesulfonyl chloride In tetrahydrofuran at 0 - 20℃; for 16h;
72%
Stage #1: carbon disulfide; 1,4-phenylenediamine With ammonium hydroxide at 0 - 5℃;
Stage #2: With lead(II) nitrate
With ammonium hydroxide und Eintragen des Reaktionsloesung in wss.Eisen(III)-chlorid-Loesung;
carbon disulfide
75-15-0

carbon disulfide

4-nitro-aniline
100-01-6

4-nitro-aniline

A

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

B

p-nitrophenyl isothiocyanate
2131-61-5

p-nitrophenyl isothiocyanate

Conditions
ConditionsYield
Stage #1: carbon disulfide; 4-nitro-aniline With potassium carbonate In water at 40℃; for 72h; Inert atmosphere;
Stage #2: With 1,3,5-trichloro-2,4,6-triazine In dichloromethane; water; N,N-dimethyl-formamide at 0℃; Inert atmosphere;
Stage #3: With sodium hydroxide In dichloromethane; water pH=11; Inert atmosphere;
A 50%
B 13%
Langlois reagent
2926-29-6

Langlois reagent

1,4-phenylenediamine
106-50-3

1,4-phenylenediamine

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

Conditions
ConditionsYield
With copper(l) iodide; phosphonic acid diethyl ester In toluene at 110℃; for 16h; Schlenk technique; Green chemistry;32%
thiophosgene
463-71-8

thiophosgene

chloroform
67-66-3

chloroform

1,4-phenylenediamine
106-50-3

1,4-phenylenediamine

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

thiophosgene
463-71-8

thiophosgene

1,4-phenylenediamine
106-50-3

1,4-phenylenediamine

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

Conditions
ConditionsYield
With chloroform
In acetone Ambient temperature;
thiophosgene
463-71-8

thiophosgene

p-phenylenediamine hydrochloride
540-24-9

p-phenylenediamine hydrochloride

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

Conditions
ConditionsYield
With sodium hydroxide
thiophosgene
463-71-8

thiophosgene

N-(p-aminophenyl)-N',N"-dicarbomethoxyguanidine
107167-58-8

N-(p-aminophenyl)-N',N"-dicarbomethoxyguanidine

A

dimethyl N,N'-carbonylbis(carbamate)
17616-33-0

dimethyl N,N'-carbonylbis(carbamate)

B

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

Conditions
ConditionsYield
In 1,4-dioxane; water 1) 5 deg C, 2) r.t., overnight;
thiourea
17356-08-0

thiourea

C8H5ClN2OS

C8H5ClN2OS

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran Ambient temperature; Yield given;
1,4-phenylenediamine
106-50-3

1,4-phenylenediamine

CS2

CS2

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

Conditions
ConditionsYield
With ammonium hydroxide Behandeln des Reaktionsprodukts mit Natrium-chloracetat und ZnCl2 in H2O bei pH 7;
acetic anhydride
108-24-7

acetic anhydride

polymer(ic) p-phenylenethiourea

polymer(ic) p-phenylenethiourea

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

4-Isothiocyanato-benzaldehyde oxime

4-Isothiocyanato-benzaldehyde oxime

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: N-chlorosuccinimide / dimethylformamide; H2O / 0.5 h / Ambient temperature
2: triethylamine / tetrahydrofuran / Ambient temperature
View Scheme
1,4-phenylenediamine
106-50-3

1,4-phenylenediamine

KHCO3

KHCO3

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: p-toluenesulphonic acid / methanol / 3 h / Heating
2: dioxane; H2O / 1) 5 deg C, 2) r.t., overnight
View Scheme
1,4-phenylenediamine
106-50-3

1,4-phenylenediamine

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: triethylamine / 0.5 h / 20 °C
2: di-tert-butyl dicarbonate; dmap / 20 °C / Cooling with ice
View Scheme
1,4-dithiocarbamatobenzene
46350-14-5

1,4-dithiocarbamatobenzene

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

Conditions
ConditionsYield
With dmap; di-tert-butyl dicarbonate at 20℃; Cooling with ice;
1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

dimethyl amine
124-40-3

dimethyl amine

3-[4-(3,3-dimethyl-thioureido)-phenyl]-1,1-dimethyl-thiourea
16349-56-7

3-[4-(3,3-dimethyl-thioureido)-phenyl]-1,1-dimethyl-thiourea

Conditions
ConditionsYield
at 20℃; under 750.06 Torr; Addition; solid-gas reaction;100%
1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

methylamine
74-89-5

methylamine

1-methyl-3-[4-(3-methyl-thioureido)-phenyl]-thiourea
16349-55-6

1-methyl-3-[4-(3-methyl-thioureido)-phenyl]-thiourea

Conditions
ConditionsYield
at 20℃; under 750.06 Torr; Addition; solid-gas reaction;100%
(S)-valinol
2026-48-4

(S)-valinol

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

C18H30N4O2S2
1355364-01-0

C18H30N4O2S2

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.583333h; Inert atmosphere;98%
(η3-allyl)Pd(N3)(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)

(η3-allyl)Pd(N3)(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

[(η3-allyl)Pd{SCN4-}(3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)]2(μ-C6H4)

[(η3-allyl)Pd{SCN4-}(3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)]2(μ-C6H4)

Conditions
ConditionsYield
In tetrahydrofuran for 3h;98%
(η3-2-methylallyl)Pd(N3)(1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene)

(η3-2-methylallyl)Pd(N3)(1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene)

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

[(η3-2-methylallyl)Pd{SCN4-}(1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene)]2(μ-C6H4)

[(η3-2-methylallyl)Pd{SCN4-}(1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene)]2(μ-C6H4)

Conditions
ConditionsYield
In tetrahydrofuran for 3h;97%
bis(trichloromethyl) carbonate

bis(trichloromethyl) carbonate

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

C10H4F8N2O2

C10H4F8N2O2

Conditions
ConditionsYield
With silver fluoride In acetonitrile at 20℃;96%
1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

4-methoxy-aniline
104-94-9

4-methoxy-aniline

N1,N2-bis[N-(4-methoxyphenyl)thiocarbamoyl]-1,4-diaminobenzene

N1,N2-bis[N-(4-methoxyphenyl)thiocarbamoyl]-1,4-diaminobenzene

Conditions
ConditionsYield
With triethylamine In 1,4-dioxane for 6h; Heating;95%
at 60℃; for 0.05h; Neat (no solvent); Microwave irradiation;92%
1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

4-Ethoxyaniline
156-43-4

4-Ethoxyaniline

1,4-phenylene-bis[3-(4'-ethoxylphenyl)thiourea]

1,4-phenylene-bis[3-(4'-ethoxylphenyl)thiourea]

Conditions
ConditionsYield
With triethylamine In 1,4-dioxane for 6h; Heating;95%
at 60℃; for 0.0333333h; Neat (no solvent); Microwave irradiation;91%
1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

4-amino-o-xylene
95-64-7

4-amino-o-xylene

1,4-phenylene-bis[3-(3',4'-dimethylphenyl)thiourea]
479054-96-1

1,4-phenylene-bis[3-(3',4'-dimethylphenyl)thiourea]

Conditions
ConditionsYield
at 60℃; for 0.0166667h; Neat (no solvent); Microwave irradiation;94%
1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

p-toluidine
106-49-0

p-toluidine

1,4-phenylene-bis[3-(4'-methylphenyl)thiourea]

1,4-phenylene-bis[3-(4'-methylphenyl)thiourea]

Conditions
ConditionsYield
at 60℃; for 0.0333333h; Neat (no solvent); Microwave irradiation;93%
With triethylamine In 1,4-dioxane for 6h; Heating;90%
1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

p-aminoiodobenzene
540-37-4

p-aminoiodobenzene

1,4-phenylene-bis[3-(4'-iodophenyl)thiourea]
77006-86-1

1,4-phenylene-bis[3-(4'-iodophenyl)thiourea]

Conditions
ConditionsYield
at 60℃; for 0.0333333h; Neat (no solvent); Microwave irradiation;93%
methyl 2-chloroacetoacetate
4755-81-1

methyl 2-chloroacetoacetate

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

para-methylbenzylamine
104-84-7

para-methylbenzylamine

dimethyl 3,3'-(1,4-phenylene)-bis-[2-(4-methylbenzylimino)-4-methyl-2,3-dihydrothiazole-5-carboxylate]

dimethyl 3,3'-(1,4-phenylene)-bis-[2-(4-methylbenzylimino)-4-methyl-2,3-dihydrothiazole-5-carboxylate]

Conditions
ConditionsYield
Stage #1: 1 ,4-phenylenediisothiocyanate; para-methylbenzylamine at 20℃; for 1h; Green chemistry;
Stage #2: methyl 2-chloroacetoacetate at 20℃; Green chemistry; regioselective reaction;
93%
methanol
67-56-1

methanol

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

N,N'-(1,4-Phenylen)bis(methylthionocarbamat)
19972-59-9

N,N'-(1,4-Phenylen)bis(methylthionocarbamat)

Conditions
ConditionsYield
With sodium hydroxide93%
1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

3-methyl-2-methylene-1,3-thiazolidine
734510-89-5

3-methyl-2-methylene-1,3-thiazolidine

2-(3-methyl-thiazolidin-2-ylidene)-N-{4-[2-(3-methyl-thiazolidin-2-ylidene)-thioacetylamino]-phenyl}-thioacetamide

2-(3-methyl-thiazolidin-2-ylidene)-N-{4-[2-(3-methyl-thiazolidin-2-ylidene)-thioacetylamino]-phenyl}-thioacetamide

Conditions
ConditionsYield
In tetrahydrofuran at 20 - 25℃;92%
1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

o-toluidine
95-53-4

o-toluidine

1,4-phenylene-bis[3-(2'-methylphenyl)thiourea]
150660-38-1

1,4-phenylene-bis[3-(2'-methylphenyl)thiourea]

Conditions
ConditionsYield
at 60℃; for 0.0333333h; Neat (no solvent); Microwave irradiation;92%
1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

4-bromo-aniline
106-40-1

4-bromo-aniline

1,4-phenylene-bis[3-(4'-bromophenyl)thiourea]
77006-85-0

1,4-phenylene-bis[3-(4'-bromophenyl)thiourea]

Conditions
ConditionsYield
at 60℃; for 0.05h; Neat (no solvent); Microwave irradiation;92%
1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

α-bromoacetophenone
70-11-1

α-bromoacetophenone

4-Ethoxyaniline
156-43-4

4-Ethoxyaniline

2,2′-(1,4-phenylene)-bis-[3-(4'-ethoxyphenyl)-2-imino-4-phenyl-3H-thiazole]

2,2′-(1,4-phenylene)-bis-[3-(4'-ethoxyphenyl)-2-imino-4-phenyl-3H-thiazole]

Conditions
ConditionsYield
With polyvinyl pyridine (PVP) In ethanol at 20℃; for 18h; regioselective reaction;92%
1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

1,3,5-tris(4-aminophenyl)benzene
118727-34-7

1,3,5-tris(4-aminophenyl)benzene

1,3,5-tris[4-(1,3-diphenylthiourea)]benzene

1,3,5-tris[4-(1,3-diphenylthiourea)]benzene

Conditions
ConditionsYield
In tetrahydrofuran Inert atmosphere;92%
hexane
110-54-3

hexane

[(C5H5)Ru(P(C6H5)3)2(SSi(CH(CH3)2)3)]
266342-85-2

[(C5H5)Ru(P(C6H5)3)2(SSi(CH(CH3)2)3)]

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

1,4-[CpRu(PPh3)S2CN(Si(i)Pr3)]2C6H4*1.6(hexane)

1,4-[CpRu(PPh3)S2CN(Si(i)Pr3)]2C6H4*1.6(hexane)

Conditions
ConditionsYield
In tetrahydrofuran; acetone byproducts: PPh3; (N2 or Ar); mixed at room temp., stirred overnight; solvent-removed (vac.), residue dissolved in CH2Cl2, filtered (Celite), concd. (vac.), layered with hexane, crystd. at room temp., filtered, dried; elem. anal.;91%
1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

4-chloro-aniline
106-47-8

4-chloro-aniline

1,4-phenylene-bis[3-(4'-chlorophenyl)thiourea]
77006-84-9

1,4-phenylene-bis[3-(4'-chlorophenyl)thiourea]

Conditions
ConditionsYield
at 60℃; for 0.0666667h; Neat (no solvent); Microwave irradiation;91%
1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

4-methoxy-benzylamine
2393-23-9

4-methoxy-benzylamine

ethyl 2-chloro-3-oxo-butyrate
609-15-4

ethyl 2-chloro-3-oxo-butyrate

diethyl 3,3'-(1,4-phenylene)-bis-[2-(4-methoxybenzylimino)-4-methyl-2,3-dihydrothiazole-5-carboxylate]

diethyl 3,3'-(1,4-phenylene)-bis-[2-(4-methoxybenzylimino)-4-methyl-2,3-dihydrothiazole-5-carboxylate]

Conditions
ConditionsYield
Stage #1: 1 ,4-phenylenediisothiocyanate; 4-methoxy-benzylamine at 20℃; for 1h; Green chemistry;
Stage #2: ethyl 2-chloro-3-oxo-butyrate at 20℃; Green chemistry; regioselective reaction;
91%
1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

N-[2-(2-Amino-acetylamino)-ethyl]-2-[4-(2,6-dioxo-1,3-dipropyl-2,3,6,7-tetrahydro-1H-purin-8-yl)-phenoxy]-acetamide; compound with trifluoro-acetic acid

N-[2-(2-Amino-acetylamino)-ethyl]-2-[4-(2,6-dioxo-1,3-dipropyl-2,3,6,7-tetrahydro-1H-purin-8-yl)-phenoxy]-acetamide; compound with trifluoro-acetic acid

2-[4-(2,6-Dioxo-1,3-dipropyl-2,3,6,7-tetrahydro-1H-purin-8-yl)-phenoxy]-N-(2-{2-[3-(4-isothiocyanato-phenyl)-thioureido]-acetylamino}-ethyl)-acetamide

2-[4-(2,6-Dioxo-1,3-dipropyl-2,3,6,7-tetrahydro-1H-purin-8-yl)-phenoxy]-N-(2-{2-[3-(4-isothiocyanato-phenyl)-thioureido]-acetylamino}-ethyl)-acetamide

Conditions
ConditionsYield
In N,N-dimethyl-formamide90%
1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

potassium cyanide
151-50-8

potassium cyanide

1,4-bis(cyanothioformamido)benzene
625855-55-2

1,4-bis(cyanothioformamido)benzene

Conditions
ConditionsYield
at 20℃;90%
3,4,4-trimethyl-2-methyleneoxazolidine
159064-15-0

3,4,4-trimethyl-2-methyleneoxazolidine

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

2-(3,4,4-trimethyl-oxazolidin-2-ylidene)-N-{4-[2-(3,4,4-trimethyl-oxazolidin-2-ylidene)-thioacetylamino]-phenyl}-thioacetamide

2-(3,4,4-trimethyl-oxazolidin-2-ylidene)-N-{4-[2-(3,4,4-trimethyl-oxazolidin-2-ylidene)-thioacetylamino]-phenyl}-thioacetamide

Conditions
ConditionsYield
In tetrahydrofuran at 20 - 25℃;90%
[(η5-trimethylsilylcyclopentadienyl)2Nb(III)(CO)(diphenylphosphanido)]
880870-87-1

[(η5-trimethylsilylcyclopentadienyl)2Nb(III)(CO)(diphenylphosphanido)]

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

[(η5-C5H4SiMe3)2(CO)niobium(III)]2(μ-(κ1-S-1,4-SC(diphenylphosphanyl)N)2(C6H4))

[(η5-C5H4SiMe3)2(CO)niobium(III)]2(μ-(κ1-S-1,4-SC(diphenylphosphanyl)N)2(C6H4))

Conditions
ConditionsYield
In toluene Nb complex treated with 0.5 equiv. of Ph(NCS)2 in dry toluene at room temp. for 15 min; filtered, washed (dry hexane) at 0°C, elem. anal.;90%
(η5-C5H4SiMe3)2(diphenylphosphanyl)niobium(II)(CNXylyl)

(η5-C5H4SiMe3)2(diphenylphosphanyl)niobium(II)(CNXylyl)

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

[(η5-C5H4SiMe3)2(CNXylyl)niobium(III)]2(μ-(κ1-S-1,4-SC(diphenylphosphanyl)N)2(C6H4))

[(η5-C5H4SiMe3)2(CNXylyl)niobium(III)]2(μ-(κ1-S-1,4-SC(diphenylphosphanyl)N)2(C6H4))

Conditions
ConditionsYield
In toluene Nb complex treated with 0.5 equiv. of Ph(NCS)2 in dry toluene at room temp. for 30 min; filtered, washed (dry hexane) at 0°C, elem. anal.;90%
1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

2-Chloroaniline
95-51-2

2-Chloroaniline

1,4-phenylene-bis[3-(2'-chlorophenyl)thiourea]
105169-81-1

1,4-phenylene-bis[3-(2'-chlorophenyl)thiourea]

Conditions
ConditionsYield
at 60℃; for 0.05h; Neat (no solvent); Microwave irradiation;90%
1,2-distearoyl-sn-glycero-3-phosphoethanolamine
1069-79-0

1,2-distearoyl-sn-glycero-3-phosphoethanolamine

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

C49H86N3O8PS2

C49H86N3O8PS2

Conditions
ConditionsYield
With triethylamine In methanol; chloroform for 5h;90%
N-(Rhodamine-B) lactam-hydrazine
188944-67-4

N-(Rhodamine-B) lactam-hydrazine

1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

C36H36N6O2S2
1033581-68-8

C36H36N6O2S2

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 5h;89%
1 ,4-phenylenediisothiocyanate
4044-65-9

1 ,4-phenylenediisothiocyanate

4-fluoroaniline
371-40-4

4-fluoroaniline

1,4-phenylene-bis[3-(4'-fluorophenyl)thiourea]
349640-45-5

1,4-phenylene-bis[3-(4'-fluorophenyl)thiourea]

Conditions
ConditionsYield
at 60℃; for 0.133333h; Neat (no solvent); Microwave irradiation;89%

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