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Hangzhou Keyingchem Co.,Ltd

Hangzhou Keying Chem Co., Ltd. Is a comprehensive enterprise, dedicated to the development, production and marketing of chemicals. As a technology innovative and service professional enterprise, Our company mainly engages in global pharmaceutical,

Olivetol

Cas:500-66-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Olivetol Basic information Olivetol Chemical Properties Melting point 46-48 °C(lit.) Boiling point 164 °C density 1.068±0.06 g/cm3(Predicted) Fp >230 °F storage temp. Refrigerator pka

3,5-dihydroxyamylbenzene Large in stock

Cas:500-66-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and

3,5-hydroxypentylbenzene

Cas:500-66-3

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Ality Chemical Corporation

Olivetol Basic information Product Name: Olivetol Synonyms: 5-PENTYLRESORCINOL;5-PENTYL 1,3-BENZENEDIOL;5-N-PENTYLRESORCINOL;5-AMYL RESORCINOL;3,5-dihydroxyamylbenzene;AURORA KA-7378;OLIVETOL;Oliveto

Factory Supply Olivetol

Cas:500-66-3

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Kunshan Push Trading Co.,LTD

ADVANTAGE 1.Professional: More than 10 years chemical exporting experience. We have produced chemical more than fifteen years, 95% products are for export . More than 10 years chemical exporting experience. Good and stabilized factory price. 2.

livetol

Cas:500-66-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Olivetol,3,5-hydroxypentylbenzene

Cas:500-66-3

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Jinan Finer Chemical Co., Ltd

Product Description

Olivetol powder

Cas:500-66-3

Min.Order:1 Kilogram

FOB Price: $5.0 / 30.0

Type:Lab/Research institutions

inquiry

Shanxi Ankesi Biotechnology Co., Ltd

Our Advantage 1. Rich experience We specialize in this filed for many years, our APIs exported to all over the world and and we established long friendly relations of cooperation with our clients. 2. Great quality,purity and favorable Good qual

Competitive price High quality Olivetol CAS 500-66-3

Cas:500-66-3

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Olivetol Manufacturer/High quality/Best price/In stock

Cas:500-66-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Assay 98%min ----------------------------------------------------------------------------------------------

High purity Various Specifications 3,5-hydroxypentylbenzene CAS:500-66-3

Cas:500-66-3

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Manufacturers

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Olivetol supplier in China

Cas:500-66-3

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Kono Chem Co.,Ltd

Product Product name Olivetol Synonyms 3,5-Dihydroxyamylbenzene; 5-Pentyl-1,3-benzenediol CAS No. 500-66

Pharmaceutical Intermediate 99% CAS 500-66-3 Olivetol

Cas:500-66-3

Min.Order:1 Kilogram

FOB Price: $3000.0

Type:Other

inquiry

LIDE PHARMACEUTICALS LIMITED

LIDE PHARMACEUTICALS LIMITED is a professional chemicals and APIs leading manufacturer in China. Our core business line covers APIs, Intermediates, Herb extract, etc. We are specialized in chemical synthesis, process development of pharmaceu

Olivetol

Cas:500-66-3

Min.Order:1 Kilogram

FOB Price: $0.9 / 1.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

5-Pentyl-1,3-benzenediol Product attributes Product name: Olivetol CAS No.: 500-66-3 Alias: 5-Pentyl-1,3-benzenediol; 5-Pentylresorcinol; Pentyl-3,5-dihydroxybenzene; Oilvetol; n-Amylresolcinol; 5-Pentyl Resorc

5-Pentyl-1,3-benzenediol

Cas:500-66-3

Min.Order:1 Kilogram

FOB Price: $2.0 / 3.0

Type:Manufacturers

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality 99% 500-66-3 3,5-dihydroxyamylbenzene Manufacturer

Cas:500-66-3

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Chengdu Lemeitian Pharmaceutical Technology Co,. Ltd

ADVANTAGE: 1. More than 3,000 Chinese medicine reference substances / standard products available from stock, issued on the same day, multiple cities can be delivered the next day 2. The products are provided with COA, HPLC, NMR, quality assurance,

Olivetol

Cas:500-66-3

Min.Order:5 Milligram

Negotiable

Type:Manufacturers

inquiry

Xi`an Eastling Biotech Co., Ltd.

ESTLING Advantage: 1. Professional bile acid manufacturer 2. Complete product range (combined bile acid and free bile acid) 3. Humanized purchase quantity (sample packaging with100g, 500g, conventional packaging 1kg, 25kg) 4. Fast delivery with on ti

Raw materials of healthcare products 500-66-3 Olivetol

Cas:500-66-3

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Trading Company

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Olivetol

Cas:500-66-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hubei DiBo chemical co., LTD

Name:Olive alcohol The alias:3, 5-dihydroxypentylene CAS NO:500-66-3 Molecular formula:C11H16O2 Molecular weight:180.24 Product Quality 12 years of chemical raw materials Mature operation of the industry System stability Data storage Se

Olive alcohol/CAS:500-66-3/High quality

Cas:500-66-3

Min.Order:25 Kilogram

FOB Price: $1.0 / 2.0

Type:Other

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name: Olivetol Synonyms: AURORA KA-7378;5-PENTYLRESORCINOL;5-PENTYL 1,3-BENZENEDIOL;5-N-PENTYLRESORCINOL;5-AMYL RESORCINOL;3,5-dihydroxyamylbenzene;OLIVETOL;5-n-amylresorcinol CAS: 500-66-3 MF: C11H16O2 MW: 18

500-66-3 Olivetol

Cas:500-66-3

Min.Order:1 Gram

FOB Price: $8900.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

Olivetol Powder CAS:500-66-3

Cas:500-66-3

Min.Order:1 Gram

FOB Price: $6.0 / 9.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 500-66-3 with fast shipping

Cas:500-66-3

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by email in time prod

1,3-Benzenediol,5-pentyl-

Cas:500-66-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Appearance:Off-white to light yellow powder Storage:R.T Package:25kg/drum Application:Intermediate Transportation:Express/Sea/Air Port:Any port in China

High quality 5-Pentylresorcinol Olivetol cas 500-66-3

Cas:500-66-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

Advantages: Hubei XinRunde Chemical Co., Ltd is a renowned pharmaceutical manufacturer. We can offer high quality products at competitive price in quick delivery with 100% custom pass guaranteed. Never stop striving to offer our best service is

Olivetol CAS NO 500-66-3

Cas:500-66-3

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

1,3-Benzenediol,5-pentyl- 500-66-3

Cas:500-66-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xi'an Faithful Biotech Co., Ltd.

We are the manufacturers and suppliers of API in China, and warehouse in Germany and USA of California, which can quickly and safely deliver to your address 1.High quality and competitive price. 2.Free sample for your evaluation. 3.Promptly delivery

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

1,3-Benzenediol,5-pentyl-

Cas:500-66-3

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

Olivetol/CAS:500-66-3

Cas:500-66-3

Min.Order:500 Gram

FOB Price: $724.0 / 782.4

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

Olivetol CAS:500-66-3 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates, ste

Olivetol CAS:500-66-3

Cas:500-66-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

1,3-dimethoxy-5-pentylbenzene
22976-40-5

1,3-dimethoxy-5-pentylbenzene

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
With boron tribromide In dichloromethane at -15 - 20℃; for 1.5h; Solvent; Reagent/catalyst; Inert atmosphere;95%
With boron tribromide In dichloromethane at -15 - 20℃; for 1.5h; Inert atmosphere;92%
With boron tribromide In dichloromethane at -15 - 20℃; for 1.5h; Inert atmosphere;92%
methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
With water; potassium hydroxide at 50 - 100℃;94%
1,3-Bis-benzyloxy-5-((Z)-pent-1-enyl)-benzene

1,3-Bis-benzyloxy-5-((Z)-pent-1-enyl)-benzene

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
With sodium; butan-1-ol at 80 - 90℃; for 1h;81%
With hydrogen; palladium on activated charcoal In ethanol Yield given;
3,5-diamino-1-pentylbenzene

3,5-diamino-1-pentylbenzene

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
Stage #1: 3,5-diamino-1-pentylbenzene With sulfuric acid; sodium nitrite In dichloromethane at 5℃;
Stage #2: With sulfuric acid; sodium sulfate In water for 1h; Reflux;
78%
methyl 6-n-pentyl-2-hydroxy-4-oxo-cyclohex-2-ene-1-carboxylate
27871-89-2

methyl 6-n-pentyl-2-hydroxy-4-oxo-cyclohex-2-ene-1-carboxylate

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
With bromine In N,N-dimethyl-formamide at 160℃; for 10h; Cooling with ice;69.3%
With bromine In N,N-dimethyl-formamide at 80 - 160℃;69.3%
With bromine In N,N-dimethyl-formamide at 160℃; for 11.5h; Cooling with ice;69.3%
With bromine In N,N-dimethyl-formamide at 160℃; for 10h; Cooling with ice;69.3%
With bromine In N,N-dimethyl-formamide at 80 - 160℃; for 11.5h; Cooling with ice;69.3%
4-Benzenesulfinyl-5-pentyl-cyclohexane-1,3-dione
74732-76-6

4-Benzenesulfinyl-5-pentyl-cyclohexane-1,3-dione

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
With calcium carbonate In benzene for 5h; Heating;48%
5-n-amyl-2-bromocyclohex-2-ene-3-ol-1-one
58016-30-1

5-n-amyl-2-bromocyclohex-2-ene-3-ol-1-one

A

4-bromo-5-pentylbenzene-1,3-diol
78463-35-1

4-bromo-5-pentylbenzene-1,3-diol

B

4,6-dibromo-5-pentylbenzene-1,3-diol
78463-34-0

4,6-dibromo-5-pentylbenzene-1,3-diol

C

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
In diphenylether heating to 155 deg C during 1 h;A 32%
B 10%
C 40%
methanol
67-56-1

methanol

olivetoric acid
491-47-4

olivetoric acid

A

6,8-dihydroxy-3-pentyl-1H-2-benzopyran-1-one
3734-54-1

6,8-dihydroxy-3-pentyl-1H-2-benzopyran-1-one

B

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
at 150 - 200℃;
formic acid
64-18-6

formic acid

olivetoric acid
491-47-4

olivetoric acid

A

6,8-dihydroxy-3-pentyl-1H-2-benzopyran-1-one
3734-54-1

6,8-dihydroxy-3-pentyl-1H-2-benzopyran-1-one

B

Olivetol
500-66-3

Olivetol

pyridine hydrochloride
628-13-7

pyridine hydrochloride

A

4-methylisopropylbenzene
99-87-6

4-methylisopropylbenzene

B

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
at 210 - 230℃;
2,4-dihydroxy-6-n-pentylbenzoic acid ethyl ester
38862-65-6

2,4-dihydroxy-6-n-pentylbenzoic acid ethyl ester

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
With sodium hydroxide
With sodium hydroxide
With sodium hydroxide In water Heating;
5-n-amyl-2-bromocyclohex-2-ene-3-ol-1-one
58016-30-1

5-n-amyl-2-bromocyclohex-2-ene-3-ol-1-one

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
With N,N-dimethyl-formamide
2-Hydroxy-4-oxo-6-pentyl-cyclohex-2-enecarboxylic acid ethyl ester
751419-63-3

2-Hydroxy-4-oxo-6-pentyl-cyclohex-2-enecarboxylic acid ethyl ester

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
(i) CuBr2, DME, (ii) (heating in DMF), (iii) aq. NaOH; Multistep reaction;
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

O-methylorcinol
3209-13-0

O-methylorcinol

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
Yield given. Multistep reaction;
Non-3-en-2-on
14309-57-0

Non-3-en-2-on

methyl 2-phenylsulfinylacetate
14090-83-6

methyl 2-phenylsulfinylacetate

(4S,5S)-4-Benzenesulfinyl-3-hydroxy-5-pentyl-cyclohex-2-enone
67222-03-1, 74779-22-9, 74779-23-0

(4S,5S)-4-Benzenesulfinyl-3-hydroxy-5-pentyl-cyclohex-2-enone

(4S,5R)-4-Benzenesulfinyl-3-hydroxy-5-pentyl-cyclohex-2-enone
67222-03-1, 74779-22-9, 74779-23-0

(4S,5R)-4-Benzenesulfinyl-3-hydroxy-5-pentyl-cyclohex-2-enone

C

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
With magnesium methanolate In methanol 1.) 1 h, 2.) room temperature, 2 d; Yield given. Yields of byproduct given;
2-hydroxy-4-(2-hydroxy-4-methoxy-6-pentylbenzoyloxy)-6-pentylbenzoic acid
529-47-5

2-hydroxy-4-(2-hydroxy-4-methoxy-6-pentylbenzoyloxy)-6-pentylbenzoic acid

A

3-hydroxy-5-pentylphenyl 2,4-dihydroxy-6-pentylbenzoate

3-hydroxy-5-pentylphenyl 2,4-dihydroxy-6-pentylbenzoate

B

2'-O-methylperlatolol

2'-O-methylperlatolol

C

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
at 160℃; for 1h; Product distribution; pyrolysis; rate of decarboxylation;
methyl 2,6-dihydroxy-4-pentylbenzoate
83578-32-9

methyl 2,6-dihydroxy-4-pentylbenzoate

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
With sodium hydroxide In methanol; water
diethyl 1,3-acetonedicarboxylate
105-50-0

diethyl 1,3-acetonedicarboxylate

3-oxo-octanoic acid (1)-ethyl ester

3-oxo-octanoic acid (1)-ethyl ester

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
With sodium at 140 - 150℃; Erhitzen des Reaktionsprodukts mit KOH auf 250grad;
2-hydroxy-4-(2-hydroxy-4-methoxy-6-pentylbenzoyloxy)-6-pentylbenzoic acid
529-47-5

2-hydroxy-4-(2-hydroxy-4-methoxy-6-pentylbenzoyloxy)-6-pentylbenzoic acid

aqueous KOH-solution

aqueous KOH-solution

A

2-hydroxy-4-methoxy-6-pentylbenzoic acid
52189-68-1

2-hydroxy-4-methoxy-6-pentylbenzoic acid

B

Olivetol
500-66-3

Olivetol

methanol
67-56-1

methanol

olivetoric acid
491-47-4

olivetoric acid

A

methylammonium carbonate
15719-64-9, 15719-76-3, 97762-63-5

methylammonium carbonate

B

Olivetol
500-66-3

Olivetol

C

olivetonide

olivetonide

Conditions
ConditionsYield
at 150℃; im Rohr;
formic acid
64-18-6

formic acid

olivetoric acid
491-47-4

olivetoric acid

A

methylammonium carbonate
15719-64-9, 15719-76-3, 97762-63-5

methylammonium carbonate

B

Olivetol
500-66-3

Olivetol

C

olivetonide

olivetonide

3,5-dimethoxybenzyl alcohol
705-76-0

3,5-dimethoxybenzyl alcohol

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: Et3N / tetrahydrofuran / 1 h / 0 - 20 °C
2: 41 percent / Li, naphthalene / tetrahydrofuran / 2 h / -30 - 0 °C
3: 96 percent / Et3N / tetrahydrofuran / 1.08 h / 0 °C
4: 95 percent / NaI, Zn / 1,2-dimethoxy-ethane / 8 h / Heating
5: 81 percent / 45percent HBr, glacial AcOH / 3 h / Heating
View Scheme
Multi-step reaction with 3 steps
1: PBr3
2: CuI
3: aq. HCl, Py
View Scheme
3,5-dimethoxybenzyl trimethylsilyl ether
185249-83-6

3,5-dimethoxybenzyl trimethylsilyl ether

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 41 percent / Li, naphthalene / tetrahydrofuran / 2 h / -30 - 0 °C
2: 96 percent / Et3N / tetrahydrofuran / 1.08 h / 0 °C
3: 95 percent / NaI, Zn / 1,2-dimethoxy-ethane / 8 h / Heating
4: 81 percent / 45percent HBr, glacial AcOH / 3 h / Heating
View Scheme
1,3-dimethoxy-5-(2'-hydroxypentyl)benzene
185249-84-7

1,3-dimethoxy-5-(2'-hydroxypentyl)benzene

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 96 percent / Et3N / tetrahydrofuran / 1.08 h / 0 °C
2: 95 percent / NaI, Zn / 1,2-dimethoxy-ethane / 8 h / Heating
3: 81 percent / 45percent HBr, glacial AcOH / 3 h / Heating
View Scheme
Methanesulfonic acid 1-(3,5-dimethoxy-benzyl)-butyl ester
185249-86-9

Methanesulfonic acid 1-(3,5-dimethoxy-benzyl)-butyl ester

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 95 percent / NaI, Zn / 1,2-dimethoxy-ethane / 8 h / Heating
2: 81 percent / 45percent HBr, glacial AcOH / 3 h / Heating
View Scheme
3,5-dimethoxybenzaldehdye
7311-34-4

3,5-dimethoxybenzaldehdye

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 1.) Mg; MeI / diethyl ether / 1.) 3 h, reflux; 2.) 1 h, reflux
2: hydrogen, conc. H2SO4 / 10percent Pd-C / ethyl acetate / 4 h / 2942.03 Torr / Ambient temperature
3: NaI, ClSiMe3 / acetonitrile / 36 h / Heating
View Scheme
1-(1-hydroxypentyl)-3,5-dimethoxybenzene
38228-28-3

1-(1-hydroxypentyl)-3,5-dimethoxybenzene

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: hydrogen, conc. H2SO4 / 10percent Pd-C / ethyl acetate / 4 h / 2942.03 Torr / Ambient temperature
2: NaI, ClSiMe3 / acetonitrile / 36 h / Heating
View Scheme
3,5-dimethoxybenzoic acid
1132-21-4

3,5-dimethoxybenzoic acid

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: 89 percent / (COCl)2 / benzene / 2 h, room t., 1 h, reflux
2: 70 percent / NaOAc, H2 / 10percent Pd-C / 2427.2 Torr / 1h, then 60 degC, overnight
3: 1.) Mg; MeI / diethyl ether / 1.) 3 h, reflux; 2.) 1 h, reflux
4: hydrogen, conc. H2SO4 / 10percent Pd-C / ethyl acetate / 4 h / 2942.03 Torr / Ambient temperature
5: NaI, ClSiMe3 / acetonitrile / 36 h / Heating
View Scheme
Multi-step reaction with 7 steps
4: 28.8 g / fluoroboric acid, sodium nitrite / H2O
5: 7.6 g / warming, distillation
6: 60 percent / lithium chips / 0.5 h
7: boron tribromide, pyridine hydrochloride / CH2Cl2 / 24 h / -78 °C
View Scheme
Multi-step reaction with 4 steps
1: LiAlH4
2: PBr3
3: CuI
4: aq. HCl, Py
View Scheme
3,5-dimethoxybenzoyl chloride
17213-57-9

3,5-dimethoxybenzoyl chloride

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 70 percent / NaOAc, H2 / 10percent Pd-C / 2427.2 Torr / 1h, then 60 degC, overnight
2: 1.) Mg; MeI / diethyl ether / 1.) 3 h, reflux; 2.) 1 h, reflux
3: hydrogen, conc. H2SO4 / 10percent Pd-C / ethyl acetate / 4 h / 2942.03 Torr / Ambient temperature
4: NaI, ClSiMe3 / acetonitrile / 36 h / Heating
View Scheme
Multi-step reaction with 6 steps
3: 28.8 g / fluoroboric acid, sodium nitrite / H2O
4: 7.6 g / warming, distillation
5: 60 percent / lithium chips / 0.5 h
6: boron tribromide, pyridine hydrochloride / CH2Cl2 / 24 h / -78 °C
View Scheme
dimethyl sulfate
77-78-1

dimethyl sulfate

Olivetol
500-66-3

Olivetol

1,3-dimethoxy-5-pentylbenzene
22976-40-5

1,3-dimethoxy-5-pentylbenzene

Conditions
ConditionsYield
With potassium carbonate In acetone at 60℃; for 4h;98%
With potassium carbonate In acetone at 80℃; for 12.083h; Inert atmosphere;98%
With potassium carbonate In acetone for 4h; Heating;89%
chloromethyl methyl ether
107-30-2

chloromethyl methyl ether

Olivetol
500-66-3

Olivetol

1,3-Bis(methoxymethoxy)-5-pentylbenzene
94450-80-3

1,3-Bis(methoxymethoxy)-5-pentylbenzene

Conditions
ConditionsYield
Stage #1: Olivetol With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.5h; Inert atmosphere;
Stage #2: chloromethyl methyl ether In N,N-dimethyl-formamide at 25℃; Inert atmosphere;
97%
Stage #1: Olivetol With sodium hydride In N,N-dimethyl-formamide; mineral oil at 20℃; Inert atmosphere;
Stage #2: chloromethyl methyl ether In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; Inert atmosphere;
92%
With N-ethyl-N,N-diisopropylamine In dichloromethane for 16h; Ambient temperature;91%
4-cyanobenzyl bromide
17201-43-3

4-cyanobenzyl bromide

Olivetol
500-66-3

Olivetol

1,3-bis{4-cyanobenzyloxy}-5-(n-pentyl)benzene

1,3-bis{4-cyanobenzyloxy}-5-(n-pentyl)benzene

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃;95%
2,6-dichloropyridine-3,5-dicarbonitrile
151229-84-4

2,6-dichloropyridine-3,5-dicarbonitrile

Olivetol
500-66-3

Olivetol

25,27-diaza-4,6,16,18-tetracyano-11,23-di-n-pentyl-2,8,14,20-tetraoxacalix[4]arene

25,27-diaza-4,6,16,18-tetracyano-11,23-di-n-pentyl-2,8,14,20-tetraoxacalix[4]arene

Conditions
ConditionsYield
With caesium carbonate In dimethyl sulfoxide at 25℃; for 0.5h;93%
Olivetol
500-66-3

Olivetol

1,3-dihydroxy-2-iodo-5-pentylbenzene
112639-12-0

1,3-dihydroxy-2-iodo-5-pentylbenzene

Conditions
ConditionsYield
With iodine; sodium hydrogencarbonate In tert-butyl methyl ether; water at 0℃; for 1h; Reagent/catalyst; Solvent; Temperature;92%
With N-iodo-succinimide In methanol at 0℃; for 18h;85%
With 18-crown-6 ether; 3-chloro-benzenecarboperoxoic acid; potassium iodide In dichloromethane 1) room temp., 2) 0 deg C, 15 min.;82%
With 3-chloro-benzenecarboperoxoic acid; potassium iodide In dichloromethane at 0℃; for 0.333333h;67%
1,5-difluoro-2,4-dinitrobenzene
327-92-4

1,5-difluoro-2,4-dinitrobenzene

Olivetol
500-66-3

Olivetol

C34H32N4O12

C34H32N4O12

Conditions
ConditionsYield
With potassium carbonate In dimethyl sulfoxide at 25℃; for 0.25h;91%
ethyl vinyl ether
109-92-2

ethyl vinyl ether

Olivetol
500-66-3

Olivetol

1,3-bis(1-ethoxyethoxy)-5-pentylbenzene
125265-27-2

1,3-bis(1-ethoxyethoxy)-5-pentylbenzene

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In dichloromethane; N,N-dimethyl-formamide at 0℃; for 7h; Inert atmosphere;91%
4,6-dichloropyrimidine
1193-21-1

4,6-dichloropyrimidine

Olivetol
500-66-3

Olivetol

4,6,16,18-tetraaza-11,23-di-n-pentyl-2,8,14,20-tetraoxacalix[4]arene

4,6,16,18-tetraaza-11,23-di-n-pentyl-2,8,14,20-tetraoxacalix[4]arene

Conditions
ConditionsYield
With caesium carbonate In dimethyl sulfoxide at 120℃; for 18h;90%
N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

Olivetol
500-66-3

Olivetol

2,4-dihydroxy-6-pentylbenzaldehyde
855875-40-0

2,4-dihydroxy-6-pentylbenzaldehyde

Conditions
ConditionsYield
With trichlorophosphate at 0 - 20℃; for 8.5h; Vilsmeier-Haack Formylation; Inert atmosphere; regioselective reaction;90%
With trichlorophosphate at 0 - 20℃; for 18h; Vilsmeier-Haack Formylation;56%
[1,3]-dioxolan-2-one
96-49-1

[1,3]-dioxolan-2-one

Olivetol
500-66-3

Olivetol

2,2'-((5-pentyl-1,3-phenylene)bis(oxy))bis(ethan-1-ol)

2,2'-((5-pentyl-1,3-phenylene)bis(oxy))bis(ethan-1-ol)

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride In N,N-dimethyl-formamide at 170℃; for 1h; Inert atmosphere; Schlenk technique;90%
2,6-dichloropyrazine
4774-14-5

2,6-dichloropyrazine

Olivetol
500-66-3

Olivetol

5,17,25,27-tetraaza-11,23-di-n-pentyl-2,8,14,20-tetraoxacalix[4]arene

5,17,25,27-tetraaza-11,23-di-n-pentyl-2,8,14,20-tetraoxacalix[4]arene

Conditions
ConditionsYield
With caesium carbonate In dimethyl sulfoxide at 120℃; for 18h;89%
2,3,5,6-tetrachloropyridine
2402-79-1

2,3,5,6-tetrachloropyridine

Olivetol
500-66-3

Olivetol

25,27-diaza-4,6,16,18-tetrachloro-11,23-di-n-pentyl-2,8,14,20-tetraoxacalix[4]arene

25,27-diaza-4,6,16,18-tetrachloro-11,23-di-n-pentyl-2,8,14,20-tetraoxacalix[4]arene

Conditions
ConditionsYield
With caesium carbonate In dimethyl sulfoxide at 120℃; for 18h;88%
Olivetol
500-66-3

Olivetol

4,6-dibromo-5-pentylbenzene-1,3-diol
78463-34-0

4,6-dibromo-5-pentylbenzene-1,3-diol

Conditions
ConditionsYield
With hydrogen bromide In dimethyl sulfoxide; ethyl acetate at 60℃; for 1h; Temperature; Solvent;87%
With bromine In dichloromethane at -15℃; Large scale;82%
With bromine In dichloromethane at -30 - -28℃; for 0.75h;73%
Olivetol
500-66-3

Olivetol

methyl iodide
74-88-4

methyl iodide

1,3-dimethoxy-5-pentylbenzene
22976-40-5

1,3-dimethoxy-5-pentylbenzene

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; Inert atmosphere;85%
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 3 - 5h;
Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at 20℃; for 0.25h; Inert atmosphere; diastereoselective reaction;85%
carbon dioxide
124-38-9

carbon dioxide

Olivetol
500-66-3

Olivetol

2,6-dihydroxy-4-pentylbenzoic acid
61695-63-4

2,6-dihydroxy-4-pentylbenzoic acid

Conditions
ConditionsYield
With potassium hydrogencarbonate In glycerol at 145℃; for 5h;84%
Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at 20℃; for 0.5h; Inert atmosphere; diastereoselective reaction;84%
ethyl 2-oxocyclohexane carboxylate
1655-07-8

ethyl 2-oxocyclohexane carboxylate

Olivetol
500-66-3

Olivetol

1-hydroxy-3-pentyl-7,8,9,10-tetrahydro-benzo[c]chromen-6-one
40683-93-0

1-hydroxy-3-pentyl-7,8,9,10-tetrahydro-benzo[c]chromen-6-one

Conditions
ConditionsYield
Stage #1: ethyl 2-oxocyclohexane carboxylate; Olivetol With trichlorophosphate In toluene at 20℃; for 38h;
Stage #2: With water In toluene for 0.5h;
82%
With trichlorophosphate; benzene
With sulfuric acid
Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at 20℃; for 0.333333h; Inert atmosphere; diastereoselective reaction;82%
Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at 20℃; for 0.5h; Inert atmosphere; diastereoselective reaction;82%
Geraniol
106-24-1

Geraniol

Olivetol
500-66-3

Olivetol

2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol
25654-31-3

2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol

Conditions
ConditionsYield
With toluene-4-sulfonic acid In chloroform at 20℃; for 12h; Darkness;80%
With toluene-4-sulfonic acid In chloroform at 20℃; for 12h; Darkness;39.9%
With toluene-4-sulfonic acid In chloroform at 20℃; for 12h; Darkness;39.9%
4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Olivetol
500-66-3

Olivetol

C19H24O2

C19H24O2

Conditions
ConditionsYield
With potassium carbonate In acetone at 20 - 50℃;80%
1,3,5-trichloro-2,4,6-triazine
108-77-0

1,3,5-trichloro-2,4,6-triazine

Olivetol
500-66-3

Olivetol

5-Pentyl-O,O'-bis(4,6-dichlor-1,3,5-triazin-2-yl)-resorcin
205182-16-7

5-Pentyl-O,O'-bis(4,6-dichlor-1,3,5-triazin-2-yl)-resorcin

Conditions
ConditionsYield
With 2,3,5-trimethyl-pyridine In acetone at 0℃; for 2h;79.8%
(3S,4S)-p-menth-1-ene-3,8-diol
119678-35-2

(3S,4S)-p-menth-1-ene-3,8-diol

Olivetol
500-66-3

Olivetol

2-[(1S,6S)-6-(1-Hydroxy-1-methyl-ethyl)-3-methyl-cyclohex-2-enyl]-5-pentyl-benzene-1,3-diol
190083-64-8

2-[(1S,6S)-6-(1-Hydroxy-1-methyl-ethyl)-3-methyl-cyclohex-2-enyl]-5-pentyl-benzene-1,3-diol

Conditions
ConditionsYield
With toluene-4-sulfonic acid In dichloromethane at 0℃; for 7h;79%
With toluene-4-sulfonic acid In dichloromethane at 0℃; for 7h; Alkylation;79%
pyridine-2-sulfonyl chloride
66715-65-9

pyridine-2-sulfonyl chloride

4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

Olivetol
500-66-3

Olivetol

3-((4-Methylbenzyl)oxy)-5-pentylphenyl pyridine-2-sulfonate

3-((4-Methylbenzyl)oxy)-5-pentylphenyl pyridine-2-sulfonate

Conditions
ConditionsYield
Stage #1: Olivetol With potassium carbonate In acetone at 20℃; for 0.5h;
Stage #2: 4-Methylbenzyl bromide In acetone at 50℃;
Stage #3: pyridine-2-sulfonyl chloride Further stages;
78%
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