Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Cyanides (as CN);Cyanides, except hydrogen cyanide, cyanogen & cyanogen chloride, (as CN);cyanide ion;Cyanogen ion;Cyanide;TIANFU-CHEM Methyl4-(cyanomethyl)benzoate57-12-5 CAS:57-12-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific
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Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
57-12-5 Methyl4-(cyanomethyl)benzoate Application:57-12-5 Methyl4-(cyanomethyl)benzoate
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57-12-5 Methyl4-(cyanomethyl)benzoateAppearance:powder Storage:room tempurature Package:As required Application:medical Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airport to airport) or by sea LCL/FCL f
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United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat
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Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers. Prompt reaction, good quality and best service make us reliable and outstanding in this industry.Appearance:yellow to white solid or po
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inquiry57-12-5 Methyl4-(cyanomethyl)benzoate Application:medical
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Type:Lab/Research institutions
inquiryKnown for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers.Appearance:yellow to white solid or powder Storage:keep sealed and keep from direct light Package:According client's requirements Applic
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inquiryN-chloro-succinimide
mercury(II) diacetate
potassium thioacyanate
A
Succinimide
B
cyanide(1-)
C
chloride
D
Sulfate
Conditions | Yield |
---|---|
With perchloric acid In methanol; water Kinetics; oxidation of SCN(1-) by NCS in aq. methanol in presence of mercuric acetate and HClO4 (room temp.); gravimetric and iodometric methods; | A n/a B n/a C n/a D 94% E n/a |
With sodium hydroxide In methanol; water Kinetics; oxidation of SCN(1-) by NCS in aq. methanol in presence of mercuric acetate and NaOH at 303 K; gravimetric and iodometric methods; | A n/a B n/a C n/a D 94% E n/a |
Conditions | Yield |
---|---|
With D2O*DO- at 24.9℃; Rate constant; amount of added solvent vapor dependence; | |
With CH3OH*CH3O- at 24.9℃; Rate constant; amount of added solvent vapor dependence; |
methyl isocyanate
methanolate
A
cyanide(1-)
B
isocyanomethide anion
C
acetone
Conditions | Yield |
---|---|
at 24.9℃; under 0.4 Torr; Product distribution; Thermodynamic data; reaction enthalpy; |
methyl isocyanate
A
methanol
B
cyanide(1-)
C
isocyanomethide anion
Conditions | Yield |
---|---|
With hydroxide at 24.9℃; under 0.4 Torr; Product distribution; Thermodynamic data; reaction enthalpy; |
Conditions | Yield |
---|---|
With fluoride at 24.9℃; under 0.4 Torr; Product distribution; Thermodynamic data; Rate constant; reaction enthalpy; |
thiophenolate
sodium ethanolate
A
cyanide(1-)
B
PVS
C
2-ethoxyethyl phenyl sulphone
D
(2-Isocyano-ethylsulfanyl)-benzene
Conditions | Yield |
---|---|
Rate constant; Product distribution; multistep reaction, 1.) ethanol, 25 deg C; 2.) ethanol; |
thiophenolate
A
cyanide(1-)
B
vinyl phenyl ether
C
phenolate
D
(2-Isocyano-ethylsulfanyl)-benzene
Conditions | Yield |
---|---|
With sodium ethanolate Rate constant; Product distribution; multistep reaction, 1.) ethanol, 25 deg C; 2.) ethanol; |
Conditions | Yield |
---|---|
With tetrafluoroborate ion In water; acetonitrile at 23℃; Equilibrium constant; |
3,6-Bis-dimethylamino-9H-thioxanthene-9-carbonitrile
A
cyanide(1-)
Conditions | Yield |
---|---|
With tetrafluoroborate ion In water; acetonitrile at 23℃; Equilibrium constant; |
potassium cyanide
(2-Isocyano-ethylsulfanyl)-benzene
A
thiophenolate
B
cyanide(1-)
D
phenylthioethylene
Conditions | Yield |
---|---|
With sodium ethanolate Rate constant; Product distribution; multistep reaction, 1.) ethanol, 25 deg C; 2.) ethanol; |
Conditions | Yield |
---|---|
In sulfolane; water at 25℃; Rate constant; |
Conditions | Yield |
---|---|
With oxygen at 24.9℃; under 0.4 Torr; Product distribution; various neutral molecules with or without acidic hydrogen; |
cyclopentadienylidene anion radical
acrylonitrile
A
1-cyano-vinyl
B
1-cyano-ethenide
C
cyanide(1-)
D
cyclopenta-2,4-dienyl
E
cyclopentadienide
Conditions | Yield |
---|---|
at 24.9℃; under 0.5 Torr; Rate constant; Mechanism; Product distribution; different α,β-unsaturated molecules; |
Conditions | Yield |
---|---|
With dinitrogen monoxide In gas under 0.4 Torr; |
methyl cyanoformate
methanolate
A
cyanide(1-)
B
Nitrilo-acetic acid anion
Conditions | Yield |
---|---|
for 0.000416667h; Mechanism; |
methyl cyanoformate
phenylmethanide
A
cyanide(1-)
B
Nitrilo-acetic acid anion
C
benzeneacetic acid methyl ester
Conditions | Yield |
---|---|
for 0.000416667h; Mechanism; |
4-cyano-1-(2,6-dichloro-benzyl)-1,4-dihydro-pyridine-3,5-dicarboxylic acid diamide
water
A
cyanide(1-)
Conditions | Yield |
---|---|
at 20℃; Equilibrium constant; |
methyl isocyanate
A
methyl hydroperoxide
B
cyanide(1-)
C
cyanate
Conditions | Yield |
---|---|
With hydroperoxide anion In gaseous matrix at 26.9℃; Rate constant; Product distribution; in a flowing afterglow system (flow rector affixed to a quadrupole mass spectrometer); |
Conditions | Yield |
---|---|
at 140 - 150℃; |
Conditions | Yield |
---|---|
at 110 - 120℃; | |
at 110 - 120℃; |
cyanide(1-)
cyanate
Conditions | Yield |
---|---|
With 4,40-Di-tert-butyl-2,20-bipyridine; dihydrogen peroxide In N,N-dimethyl-formamide at 20℃; for 2.5h; Catalytic behavior; Kinetics; Reagent/catalyst; | 100% |
With alkali peroxide In not given in alkaline soln.;; | |
With chlorine In water byproducts: Cl(1-); introduction of Cl2 into alkali cyanide soln.; |
Conditions | Yield |
---|---|
With chlorine In tetrachloromethane with alkali cyanides, under 3°C; | 98% |
With chlorine In neat (no solvent) alkali cyanides, at -18°C; | 85% |
With chlorine In neat (no solvent) alkali cyanides mixed with sand at 3°C; | 80% |
With chlorine In tetrachloromethane alkali cyanides, at 0°C; | |
With hydrogenchloride In not given |
cyanide(1-)
[(η6-p-(i-Pr)C6H4Me)RuCl(κ2-2,2'-dipyridylamine)]BF4
[(η6-p-(i-Pr)C6H4Me)Ru(κ2-2,2'-dipyridylamine)(CN)]BF4
Conditions | Yield |
---|---|
In methanol CN(1-) was added to suspn. of Ru complex in MeOH; refluxed for 4 h; evapd. (vac.); dissolved in CH2Cl2; filtered; concd.; hexane added; septd.; washed (Et2O); dried (vac.); elem. anal.; | 98% |
cyanide(1-)
[(η6-p-(i-Pr)C6H4Me)Ru(κ2-di-2-pyridylbenzylamine)(CN)]BF4
Conditions | Yield |
---|---|
In methanol CN(1-) was added to suspn. of Ru complex in MeOH; refluxed for 4 h; evapd. (vac.); dissolved in CH2Cl2; filtered; concd.; hexane added; septd.; washed (Et2O); dried (vac.); elem. anal.; | 97% |
cyanide(1-)
Conditions | Yield |
---|---|
91% |
Conditions | Yield |
---|---|
With chlorine In hydrogenchloride alkali cyanides, pH=9; | A n/a B 90% |
cyanide(1-)
para-bromophenacyl bromide
3-(4-bromophenyl)-3-oxopropanenitrile
Conditions | Yield |
---|---|
With β-cyclodextrin-silica nanocomposite linked by propyl spacer In water at 90℃; for 1.25h; Green chemistry; | 90% |
cyanide(1-)
Conditions | Yield |
---|---|
89% |
Conditions | Yield |
---|---|
With β-cyclodextrin-silica nanocomposite linked by propyl spacer In water at 90℃; for 1h; Green chemistry; | 80% |
cyanide(1-)
Conditions | Yield |
---|---|
With NMe4(1+) In dichloromethane; water mixt. of Mo complex in CH2Cl2 and CN(1-) in water stirred in presence of NMe4(1+) as phase-transfer catalyst for 4 h; CH2Cl2 layer sepd., evapd. under vac., recrystd. from CH2Cl2-MeOH; elem. anal.; | 73% |
cyanide(1-)
Conditions | Yield |
---|---|
In acetonitrile byproducts: P(C6H5)3; under N2; monitored by (1)H-NMR; | A 14% B 70% |
(3aR,5R,6S,6aR)-6-methoxy-2,2-dimethyl-5-((E)-2-nitrovinyl)tetrahydrofuro[2,3-d][1,3]dioxole
cyanide(1-)
5,6-Dideoxy-1,2-O-isopropylidene-3-O-methyl-5-C-methylene-α-D-xylo-hexofuranurononitrile
Conditions | Yield |
---|---|
68% |
cyanide(1-)
A
(2Z,4Z)-5-[2-(4-Chloro-phenyl)-2H-tetrazol-5-yl]-penta-2,4-dienenitrile
B
(2E,4Z)-5-[2-(4-Chloro-phenyl)-2H-tetrazol-5-yl]-penta-2,4-dienenitrile
Conditions | Yield |
---|---|
In acetonitrile | A 15% B 67% |
In acetonitrile | A 67% B 15% |
cyanide(1-)
(C10H11CN)Fe(CO)3
Conditions | Yield |
---|---|
In diethyl ether addn. of cyanide to suspn. of Fe-complex (molar ratio = 1 : 1, 15°C), stirring (15°C, 3 - 4 h); concentrating (reduced pressure), addn. of ice-cold H2O, extn. (ether), drying (Na2SO4), solvent removal, chromy. (SiO2, pentane), solvent removal, recrystn. (pentane); elem. anal.; | 54% |
Conditions | Yield |
---|---|
In tetrahydrofuran NaCN or KCN was added to a THF soln. of Nb-compound in 2:1 ratio under anhyd. conditions, mixt. was stirred and refluxed for ca. 12 h at 65-70°C; filtered, ppt. was washed with THF, filtrate and washings were evapd. in vacuo (2 h), residue was recrystd. from EtOH, dried under vac. (0.4 mmHg); elem. anal.; | 45% |
cyanide(1-)
Conditions | Yield |
---|---|
In tetrahydrofuran NaCN or KCN was added to a THF soln. of Nb-compound in 2:1 ratio under anhyd. conditions, mixt. was stirred and refluxed for ca. 12 h at 65-70°C; filtered, ppt. was washed with THF, filtrate and washings were evapd. in vacuo (2 h), residue was recrystd. from EtOH, dried under vac. (0.4 mmHg); elem. anal.; | 45% |
Conditions | Yield |
---|---|
In quinoline at 240℃; | A 35% B 32% |
[2,2]bipyridinyl
cyanide(1-)
cobalt(II) diacetate tetrahydrate
butane-2,3-dione dioxime
Conditions | Yield |
---|---|
With ogygen In ethanol; water under N2 atm. aq. soln. Co(OAc)2*4H2O and MCN (M = Na or K) was added toboiling soln. ligand in EtOH, refluxed for 2 h, cooled to room temp., b ipy was added, O2 was bubbled through react. mixt. for 3 h; ppt. was filtered, washed with 50 % aq. EtOH and EtOH and dried over CaCl2; elem. anal.; | 14.4% |
ethylenediaminetetraacetatonickel(II)(2-)
cyanide(1-)
Conditions | Yield |
---|---|
1% | |
1% | |
With ethylenediaminetetraacetic acid Kinetics; slow react.; | |
With EDTA Kinetics; slow react.; |
cyanide(1-)
[Pt(CN(tert-butyl))2(7,8-benzoquinolate)](1+)
[Pt(benzoquinolate)(CN)(CN-tBu)]
[Pt(benzoquinolate)(CN)(CNtBu)]
Conditions | Yield |
---|---|
A 1% B n/a |
cyanide(1-)
[Pt(benzoquinolinate)(2,6-dimethylphenylisocyanide)2](1+)
[Pt(benzoquinolate)(CN)(CN-2,6-dimethylphenyl)]
[Pt(benzoquinolate)(CN)(CN-2,6-dimethylphenyl)]
Conditions | Yield |
---|---|
A 1% B n/a |
Conditions | Yield |
---|---|
Mechanism; |
Conditions | Yield |
---|---|
With ammonia; sulfur |
cyanide(1-)
selenocyanic acid
Conditions | Yield |
---|---|
With methanol; selenium at 0 - 25℃; Kinetik der Uebertragung; |
cyanide(1-)
bis-(1,1-dimethoxy-2,6-diphenyl-1λ5-phosphinin-4-yl)-acetonitrile
S-Phenyl benzenethiosulfonate
cyanide(1-)
A
phenyl thiocyanate
B
phenylsulphinate anion
Conditions | Yield |
---|---|
In water; acetonitrile at 25℃; Rate constant; tris/tris-H+ buffer; |
(4S,4'R,5R)-2,2,2',2'-tetramethyl-5-((E)-2-nitrovinyl)-4,4'-bi(1,3-dioxolane)
cyanide(1-)
2-((4S,5R,4'R)-2,2,2',2'-Tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-acrylonitrile
Conditions | Yield |
---|---|
Yield given; |