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Shanghai Yui Sifluo Co.. Ltd.

In fluorine chemical, Yuji Tech has been dedicated to R&D of production of ODS alternatives, fluoropolymers and fluorinated fine chemicals for years, and has become an international leading innovation enterprise in fluorine chemical research an

Methyl Fluoride (HFC-41)

Cas:593-53-3

Min.Order:5 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Methyl fluoride

Cas:593-53-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Fluoromethane

Cas:593-53-3

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Fluoromethane

Cas:593-53-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Methane, fluoro-

Cas:593-53-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High Purity methyl fluoride;fluoromethane

Cas:593-53-3

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality Appearance:colourless gas with an ether-like odour Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used as Pharmaceutical Interme

METHYL FLUORIDE

Cas:593-53-3

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Methyl fluoride

Cas:593-53-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Methane, fluoro-

Cas:593-53-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory directly supply CAS 593-53-3 with best price

Cas:593-53-3

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Methane, fluoro-

Cas:593-53-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fandachem Co.,Ltd

METHYL FLUORIDE Package:as requirements Application:Fine Chemical

METHYL FLUORIDE

Cas:593-53-3

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

Methyl fluoride 593-53-3

Cas:593-53-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#593-53-3;CAT#A832279

Cas:593-53-3

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Zhengzhou Kingorgchem Chemical Technology Co., Ltd.

Zhengzhou Kingorgchem Chemical Technology Co., Ltd. was founded on the basis of Organophosphorus Chemistry Lab of Institute of Chemistry Henan Academy of Sciences in 2015. The laboratory covers 600 m2 and the pilot plant covers 2000 m2. Kingorgchem i

National Research Platform ISO 9001 593-53-3

Cas:593-53-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

Methane, fluoro-

Cas:593-53-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Foshan Huate Gas Co., Ltd

99.99%~99.999% Methyl Fluoride, CH3F. Purity :) 99.995% Guaranteed Specification: Oxygen … Package:44L/47L cylinder

Methyl Fluoride(CH3F)

Cas:593-53-3

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Pure Chemistry Scientific Inc.

Methyl fluoride Application:2025661

Methyl fluoride

Cas:593-53-3

Min.Order:1 Gram

FOB Price: $500.0

Type:Trading Company

inquiry

Nanjing Raymon Biotech Co., Ltd.

Methane, fluoro- Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By Sea,by Air,By courier like DHL or Fedx. Port:Shanghai/Shenzhen

Methane, fluoro-

Cas:593-53-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Weihai Moochun Bio-Tech Co., Ltd.

high quality;competitive price Storage:keep sealed and keep from direct light Package:Sample: 50g/ bottle 100g/ bottle 1000g/ bottle bulk: 25kg/drum 50kg/drum 559kg/drum Application:Scientific research Transportation:For small batches, they will

METHYL FLUORIDE

Cas:593-53-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Wuxi Morality Chemical Co., Ltd

Do best quality products, erect the morality model Application:please email us, thanks

METHYL FLUORIDE

Cas:593-53-3

Min.Order:0

Negotiable

Type:Other

inquiry

Skyrun Industrial Co.,Ltd

Good Price, prompt shipment Application:Used in organic synthesis; Catalytic agent; Petrochemical additive;

Methyl fluoride

Cas:593-53-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SUZHOU CHEMWELLS ADVANCED MATERIALS CO.,LTD.

Product name: fluoromethane CAS No.: 593-53-3 Molecular formula: CH3F Molecular weight: 34.03 Purity: >99% Appearance: colorless transparent gas Boiling point: -78.4 °C Freezing point: -142 °C Density: 0.61 g/ml, at 25 &d

Fluoromethane

Cas:593-53-3

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Sino-Biochemical Laboratory Co.,Ltd

High quality ,special structure, regular with stock , custom synthese ,quotation with 24hrsAppearance:Good Storage:G to KG to 100KG Application:With high quality for lab research or production in pharm or special material area . With stock or custom

Fluoromethane

Cas:593-53-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Ruishun Trade Co.,Ltd

Supply top quality products with a reasonable price Application:api

593-53-3

Cas:593-53-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemical Co.Ltd

Manufacturer,strong R&D,professional team Storage:Store in a cool, dry place. Store in a tightly closed container. Package:according to your requirement Application:ZhiShang Chemical is owned by ZhiShang Group, is a professional new-type chemicals en

Methane, fluoro-

Cas:593-53-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

dimethyl sulfate
77-78-1

dimethyl sulfate

Methyl fluoride
593-53-3

Methyl fluoride

Conditions
ConditionsYield
With potassium fluoride In water at 100℃; for 5h; Solvent; Reagent/catalyst; Temperature;100%
With potassium fluoride In water at 100℃; under 1125.11 Torr; for 5h; Reagent/catalyst; Solvent; Temperature;100%
With potassium fluoride In sulfolane at 100℃; under 750.075 Torr; for 0.166667h; Solvent; Temperature; Autoclave;92%
With potassium fluoride
With sodium fluoride In sulfolane
1,1,1,3,3-pentafluoro-3-methoxy-2-trifluoromethylpropane
382-26-3

1,1,1,3,3-pentafluoro-3-methoxy-2-trifluoromethylpropane

A

Methyl fluoride
593-53-3

Methyl fluoride

B

3,3,3-trifluoro-2-trifluoromethyl-propionyl fluoride
382-22-9

3,3,3-trifluoro-2-trifluoromethyl-propionyl fluoride

Conditions
ConditionsYield
With titanium(IV) oxide at 150℃; Reagent/catalyst; Temperature; Gas phase; Flow reactor;A 99%
B 100%
With alumina at 200℃; Catalytic behavior; Reagent/catalyst; Gas phase; Flow reactor;A 99%
B 91%
With alumina at 200℃; Catalytic behavior; Time; Gas phase; Flow reactor;A 99%
B 99%
C3CsF7O2S
96887-05-7

C3CsF7O2S

dimethyl sulfate
77-78-1

dimethyl sulfate

A

Methyl fluoride
593-53-3

Methyl fluoride

B

1,2,2-trifluoro-1-(trifluoromethyl)ethanesulfonyl fluoride
96025-71-7

1,2,2-trifluoro-1-(trifluoromethyl)ethanesulfonyl fluoride

C

cesium methyl sulfate

cesium methyl sulfate

Conditions
ConditionsYield
In diethylene glycol dimethyl ether at 40 - 45℃;A n/a
B 12.2%
C 95%
(Z)-4,4,5,5,5-Pentafluoro-3-methoxy-2-trifluoromethyl-pent-2-enoyl fluoride
84047-25-6

(Z)-4,4,5,5,5-Pentafluoro-3-methoxy-2-trifluoromethyl-pent-2-enoyl fluoride

A

Methyl fluoride
593-53-3

Methyl fluoride

B

pentafluoropropionyl(trifluoromethyl)ketene
53352-88-8

pentafluoropropionyl(trifluoromethyl)ketene

Conditions
ConditionsYield
titanium(IV) fluoride In neat (no solvent) Heating;A n/a
B 90.8%
iodotrifluoromethane
2314-97-8

iodotrifluoromethane

Methyl fluoride
593-53-3

Methyl fluoride

Conditions
ConditionsYield
With hydrogen In neat (no solvent) formation on heating to 250°C;;89%
1,1,2,2-tetrafluoro-1-methoxyethane
425-88-7

1,1,2,2-tetrafluoro-1-methoxyethane

A

Methyl fluoride
593-53-3

Methyl fluoride

B

2,2-difluoroacetyl fluoride
2925-22-6

2,2-difluoroacetyl fluoride

Conditions
ConditionsYield
antimony pentafluoride In neat (no solvent)A n/a
B 88%
aluminum phosphate treatment with HF at 300C for 72 h at 210℃; Product distribution / selectivity; Inert atmosphere;
With monoaluminum phosphate; hydrogen fluoride at 200℃; Inert atmosphere; Autoclave;
2-(Trifluoromethyl)-3-methoxy-1,1,1,3,4,4,5,5,5-nonafluoropentane
54376-60-2

2-(Trifluoromethyl)-3-methoxy-1,1,1,3,4,4,5,5,5-nonafluoropentane

A

Methyl fluoride
593-53-3

Methyl fluoride

B

2-(Trifluoromethyl)-1,1,1,4,4,5,5,5-octafluoropentan-3-one
61637-91-0

2-(Trifluoromethyl)-1,1,1,4,4,5,5,5-octafluoropentan-3-one

Conditions
ConditionsYield
antimony pentafluoride In neat (no solvent)A n/a
B 88%
1,3-Dimethoxy-2-(trifluoromethyl)-1,3,4,4,5,5,5-heptafluoro-1-pentene
77946-89-5

1,3-Dimethoxy-2-(trifluoromethyl)-1,3,4,4,5,5,5-heptafluoro-1-pentene

1,3-Dimethoxy-2-(trifluoromethyl)-1,1,4,4,5,5,5-heptafluoro-2-pentene
84047-24-5

1,3-Dimethoxy-2-(trifluoromethyl)-1,1,4,4,5,5,5-heptafluoro-2-pentene

A

Methyl fluoride
593-53-3

Methyl fluoride

B

(Z)-4,4,5,5,5-Pentafluoro-3-methoxy-2-trifluoromethyl-pent-2-enoyl fluoride
84047-25-6

(Z)-4,4,5,5,5-Pentafluoro-3-methoxy-2-trifluoromethyl-pent-2-enoyl fluoride

Conditions
ConditionsYield
titanium(IV) fluoride In neat (no solvent) Heating;A n/a
B 86.5%
1,1,2,3,3-pentafluoro-1,3-dimethoxy-propane
758-62-3

1,1,2,3,3-pentafluoro-1,3-dimethoxy-propane

A

Methyl fluoride
593-53-3

Methyl fluoride

B

2-Fluoro-propanedioyl difluoride
77946-94-2

2-Fluoro-propanedioyl difluoride

Conditions
ConditionsYield
antimony pentafluoride In neat (no solvent)A n/a
B 84%
cis- and trans-2-methoxyperfluoropentene-2

cis- and trans-2-methoxyperfluoropentene-2

A

Methyl fluoride
593-53-3

Methyl fluoride

B

perfluoro-2-pentene-4-one
76944-21-3

perfluoro-2-pentene-4-one

Conditions
ConditionsYield
With antimony pentafluoride cooling, then room t.;A n/a
B 84%
1,1,1,2,3,3-hexafluoro-3-methoxypropane
382-34-3

1,1,1,2,3,3-hexafluoro-3-methoxypropane

A

Methyl fluoride
593-53-3

Methyl fluoride

B

2,3,3,3-tetrafluoropropionylfluoride
6065-84-5

2,3,3,3-tetrafluoropropionylfluoride

Conditions
ConditionsYield
antimony pentafluoride In neat (no solvent)A n/a
B 82%
CO

CO

A

Methyl fluoride
593-53-3

Methyl fluoride

B

acetic acid methyl ester
79-20-9

acetic acid methyl ester

C

acetic acid
64-19-7

acetic acid

Conditions
ConditionsYield
hydrogen fluoride; boron trifluoride at 300℃; under 114000 Torr; for 6h;A 1%
B 9.5%
C 80.7%
2-methoxy-3-hydroperfluoropentane

2-methoxy-3-hydroperfluoropentane

A

Methyl fluoride
593-53-3

Methyl fluoride

B

3-hydroperfluoropentane-2-one
76944-22-4

3-hydroperfluoropentane-2-one

Conditions
ConditionsYield
With antimony pentafluoride cooling, then room t.;A n/a
B 79%
Dimethyl ether
115-10-6

Dimethyl ether

A

methane
34557-54-5

methane

B

Methyl fluoride
593-53-3

Methyl fluoride

C

acetic acid methyl ester
79-20-9

acetic acid methyl ester

D

acetic acid
64-19-7

acetic acid

Conditions
ConditionsYield
With carbon monoxide; hydrogen fluoride; boron trifluoride at 190℃; under 121600 Torr; for 24h; Product distribution; variation of molar ratios, temperature, time; other catalysts;A 0.1%
B 3%
C 76.1%
D 20.1%
Dimethyl ether
115-10-6

Dimethyl ether

CO

CO

A

methane
34557-54-5

methane

B

Methyl fluoride
593-53-3

Methyl fluoride

C

acetic acid methyl ester
79-20-9

acetic acid methyl ester

D

acetic acid
64-19-7

acetic acid

Conditions
ConditionsYield
hydrogen fluoride; boron trifluoride at 190℃; under 121600 Torr; for 24h;A 0.1%
B 3%
C 76.1%
D 20.1%
methoxyflurane
76-38-0

methoxyflurane

A

methylene chloride
74-87-3

methylene chloride

B

Methyl fluoride
593-53-3

Methyl fluoride

C

dichloroacetyl fluoride
359-31-9

dichloroacetyl fluoride

D

2,2,2-Trichloro-1,1-difluoroethyl methyl ether
661-75-6

2,2,2-Trichloro-1,1-difluoroethyl methyl ether

Conditions
ConditionsYield
Stage #1: methoxyflurane With potassium hydroxide Dehydrofluorination; Heating;
Stage #2: With chlorine at -40℃; Chlorination;
Stage #3: With antimonypentachloride at 40℃; for 0.833333h; Fluorination; Decomposition;
A n/a
B n/a
C n/a
D 74%
1,3-Dimethoxy-2-(trifluoromethyl)-1,3,4,4,5,5,5-heptafluoro-1-pentene
77946-89-5

1,3-Dimethoxy-2-(trifluoromethyl)-1,3,4,4,5,5,5-heptafluoro-1-pentene

1,3-Dimethoxy-2-(trifluoromethyl)-1,1,4,4,5,5,5-heptafluoro-2-pentene
84047-24-5

1,3-Dimethoxy-2-(trifluoromethyl)-1,1,4,4,5,5,5-heptafluoro-2-pentene

A

Methyl fluoride
593-53-3

Methyl fluoride

B

pentafluoropropionyl(trifluoromethyl)ketene
53352-88-8

pentafluoropropionyl(trifluoromethyl)ketene

Conditions
ConditionsYield
antimony pentafluoride In neat (no solvent)A n/a
B 67%
1,1,1,2,2-Pentafluoro-2-(1,2,2-trifluoro-2-methoxy-ethoxy)-ethane
84047-27-8

1,1,1,2,2-Pentafluoro-2-(1,2,2-trifluoro-2-methoxy-ethoxy)-ethane

A

Methyl fluoride
593-53-3

Methyl fluoride

B

Difluoromethyl 1,1,2,2,2-pentafluoroethyl ether
53997-64-1

Difluoromethyl 1,1,2,2,2-pentafluoroethyl ether

C

Fluoro-pentafluoroethyloxy-acetyl fluoride
77946-91-9

Fluoro-pentafluoroethyloxy-acetyl fluoride

Conditions
ConditionsYield
antimony pentafluoride In neat (no solvent) Ambient temperature;A n/a
B 27%
C 60%
trimethoxonium tetrafluoroborate
420-37-1

trimethoxonium tetrafluoroborate

A

methane
34557-54-5

methane

B

ethane
74-84-0

ethane

C

Methyl fluoride
593-53-3

Methyl fluoride

D

ethene
74-85-1

ethene

E

Dimethyl ether
115-10-6

Dimethyl ether

Conditions
ConditionsYield
With sodium hydride In Dimethyl ether for 8h; Product distribution; Mechanism; Ambient temperature; autoclave; other temperatures; also without solvent;A 58.4%
B 2.1%
C 4.6%
D 2.5%
E 32.4%
Dimethyl((trimethylsilyl)methyl)oxonium Tetrafluoroborate
89909-24-0

Dimethyl((trimethylsilyl)methyl)oxonium Tetrafluoroborate

A

Methyl fluoride
593-53-3

Methyl fluoride

B

Dimethyl ether
115-10-6

Dimethyl ether

C

trimethylsilyl fluoride
420-56-4

trimethylsilyl fluoride

D

dimethylethylfluorosilane
10132-71-5

dimethylethylfluorosilane

E

(methoxymethyl)trimethylsilane
14704-14-4

(methoxymethyl)trimethylsilane

F

Fluormethyltrimethylsilan
28871-61-6

Fluormethyltrimethylsilan

G

methane 0.1percent, ethylene 1.0percent, EtF 0.5percent, MeOEt 1.6percent

methane 0.1percent, ethylene 1.0percent, EtF 0.5percent, MeOEt 1.6percent

Conditions
ConditionsYield
With cesium fluoride Product distribution; Mechanism; 1.)-78 deg C, 2.)carefull heating;A 12.1%
B 55.9%
C 3.4%
D 4.1%
E 12.1%
F 9.2%
G n/a
dichloromethane
75-09-2

dichloromethane

ammonia
7664-41-7

ammonia

A

hydrogen cyanide
74-90-8

hydrogen cyanide

B

Methyl fluoride
593-53-3

Methyl fluoride

C

Difluoromethane
75-10-5

Difluoromethane

D

Chlorodifluoromethane
75-45-6

Chlorodifluoromethane

E

carbon dioxide
124-38-9

carbon dioxide

Conditions
ConditionsYield
With catalyst: Pt/C In neat (no solvent) steady-state flow reaction over Pt/C catalyst at 769 K;A 53.4%
B 0.3%
C 0.5%
D 7.6%
E 0.5%
Ethyl pentafluoro-1-propenyl ether
666-92-2

Ethyl pentafluoro-1-propenyl ether

A

Methyl fluoride
593-53-3

Methyl fluoride

B

2,3,3-trifluoroacryloyl fluoride
667-49-2

2,3,3-trifluoroacryloyl fluoride

Conditions
ConditionsYield
antimony pentafluoride In neat (no solvent)A n/a
B 47%
2-(N-perfluoro-tert-butyl-N-fluorocarbonylamino)tetrafluoropropenyltrimethoxyphosphorane
93636-91-0

2-(N-perfluoro-tert-butyl-N-fluorocarbonylamino)tetrafluoropropenyltrimethoxyphosphorane

A

Methyl fluoride
593-53-3

Methyl fluoride

B

dimethyl 2-(N-perfluoro-tert-butyl-N-fluorocarbonylamino)tetrafluoropropenylphosphonate

dimethyl 2-(N-perfluoro-tert-butyl-N-fluorocarbonylamino)tetrafluoropropenylphosphonate

Conditions
ConditionsYield
at 120 - 130℃; for 0.5h;A n/a
B 45%
1,2-dichloro-1,1,2-trifluoro-1-methoxyethane
754-28-9

1,2-dichloro-1,1,2-trifluoro-1-methoxyethane

A

methylene chloride
74-87-3

methylene chloride

B

Methyl fluoride
593-53-3

Methyl fluoride

C

chlorodifluoroacetyl fluoride
354-27-8

chlorodifluoroacetyl fluoride

D

metyhyl chlorodifluoroacetate
1514-87-0

metyhyl chlorodifluoroacetate

Conditions
ConditionsYield
With aluminum(III) fluoride at 200℃; for 1h; Product distribution; Further Variations:; Reagents;A n/a
B n/a
C n/a
D 43%
methanol
67-56-1

methanol

N-ethyl-N-(trifluoromethyl)ethanamine
1481-55-6

N-ethyl-N-(trifluoromethyl)ethanamine

A

Methyl fluoride
593-53-3

Methyl fluoride

B

Dimethyl ether
115-10-6

Dimethyl ether

C

N-(methoxycarbonyl)diethylamine
4652-44-2

N-(methoxycarbonyl)diethylamine

D

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

Conditions
ConditionsYield
for 0.25h; Heating;A 40%
B 12%
C 10%
D 37%
methanol
67-56-1

methanol

A

Methyl fluoride
593-53-3

Methyl fluoride

B

Dimethyl ether
115-10-6

Dimethyl ether

C

N-(methoxycarbonyl)diethylamine
4652-44-2

N-(methoxycarbonyl)diethylamine

D

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

Conditions
ConditionsYield
With N-ethyl-N-(trifluoromethyl)ethanamine for 0.25h; Heating;A 40%
B 12%
C 10%
D 37%
1,3,3,3-tetrafluoro-1-methoxy-2-trifluoromethyl-propene
360-53-2

1,3,3,3-tetrafluoro-1-methoxy-2-trifluoromethyl-propene

A

Methyl fluoride
593-53-3

Methyl fluoride

B

perfluoromethacryloyl fluoride
684-36-6

perfluoromethacryloyl fluoride

C

bis(trifluoromethyl)ketene
684-22-0

bis(trifluoromethyl)ketene

Conditions
ConditionsYield
antimony pentafluoride In neat (no solvent) Ambient temperature;A n/a
B 37%
C 35%
1,3,4,5,5,5-hexafluoro-1,3,4-trimethoxy-2-trifluoromethyl-pent-1-ene
59736-15-1

1,3,4,5,5,5-hexafluoro-1,3,4-trimethoxy-2-trifluoromethyl-pent-1-ene

A

Methyl fluoride
593-53-3

Methyl fluoride

B

(Z)-1,1,1,5-Tetrafluoro-5-methoxy-4-trifluoromethyl-pent-4-ene-2,3-dione
77946-93-1

(Z)-1,1,1,5-Tetrafluoro-5-methoxy-4-trifluoromethyl-pent-4-ene-2,3-dione

Conditions
ConditionsYield
antimony pentafluoride In neat (no solvent) Ambient temperature;A n/a
B 37%
methanol
67-56-1

methanol

1,2-difluoroethane
624-72-6

1,2-difluoroethane

Methyl fluoride
593-53-3

Methyl fluoride

methanol
67-56-1

methanol

phenylsulfonyl fluoride
368-43-4

phenylsulfonyl fluoride

Methyl fluoride
593-53-3

Methyl fluoride

Conditions
ConditionsYield
With potassium fluoride
Methyl fluoride
593-53-3

Methyl fluoride

Trimethylamin-phosphor(V)-fluorid
2991-77-7

Trimethylamin-phosphor(V)-fluorid

tetramethylammonium hexafluorophosphate
558-32-7

tetramethylammonium hexafluorophosphate

Conditions
ConditionsYield
at 200℃; under 23560 Torr; for 48h;98.2%
Methyl fluoride
593-53-3

Methyl fluoride

trimethylamine
75-50-3

trimethylamine

Tetramethylammonium pentafluorosilicate

Tetramethylammonium pentafluorosilicate

Conditions
ConditionsYield
With silicon tetrafluoride at 100℃; for 48h;96.4%
Methyl fluoride
593-53-3

Methyl fluoride

A

formyl fluoride
1493-02-3

formyl fluoride

B

fluoromethyl peroxate
137848-37-4

fluoromethyl peroxate

Conditions
ConditionsYield
With air; chlorine at 21.9℃; under 700 Torr; Mechanism; Rate constant; Irradiation;A 87%
B 11%
Methyl fluoride
593-53-3

Methyl fluoride

trimethylamine-trifluoroborane

trimethylamine-trifluoroborane

tetramethylammonium tetrafluoroborate
661-36-9

tetramethylammonium tetrafluoroborate

Conditions
ConditionsYield
under 23560 Torr; 1.) 152 deg C, 70 h, 2.) 171 deg C, 62 h;84.1%
sulfolane
126-33-0

sulfolane

Methyl fluoride
593-53-3

Methyl fluoride

tetrahydro-1-methoxythiophenium 1-oxide hexafluoroantimonate

tetrahydro-1-methoxythiophenium 1-oxide hexafluoroantimonate

Conditions
ConditionsYield
With sulfur dioxide; antimony pentafluoride for 0.25h; Ambient temperature; NMR study of products;82%
perfluoropropylene
116-15-4

perfluoropropylene

Methyl fluoride
593-53-3

Methyl fluoride

1,1,1,2,3,3,4-heptafluoro-butane
53005-35-9

1,1,1,2,3,3,4-heptafluoro-butane

Conditions
ConditionsYield
at 280℃; for 96h;76%
Methyl fluoride
593-53-3

Methyl fluoride

tetrabutylammonium octacyanotungstate(IV)

tetrabutylammonium octacyanotungstate(IV)

arsenic pentafluoride
7784-36-3

arsenic pentafluoride

octakis(methyl isocyanide)tungsten(IV) hexafluoroarsenate

octakis(methyl isocyanide)tungsten(IV) hexafluoroarsenate

Conditions
ConditionsYield
With sulfur dioxide at -196 - -78℃; for 1h;76%
Methyl fluoride
593-53-3

Methyl fluoride

para-bromotoluene
106-38-7

para-bromotoluene

A

1-bromo-2,4-dimethylbenzene
583-70-0

1-bromo-2,4-dimethylbenzene

B

4-bromo-o-xylene
583-71-1

4-bromo-o-xylene

Conditions
ConditionsYield
With oxygen at 40℃; under 720 Torr; Mechanism; Irradiation;A 72%
B 28%
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

Methyl fluoride
593-53-3

Methyl fluoride

1,1,1,2,2-pentafluoropropane
1814-88-6

1,1,1,2,2-pentafluoropropane

Conditions
ConditionsYield
With antimony pentafluoride at 25 - 50℃; for 16h;67%
Methyl fluoride
593-53-3

Methyl fluoride

tris(trifluoromethyl)phosphine
432-04-2

tris(trifluoromethyl)phosphine

antimony pentafluoride
7783-70-2

antimony pentafluoride

[tris(trifluoromethyl)methyl phosphonium][Sb2F11]
1165950-49-1

[tris(trifluoromethyl)methyl phosphonium][Sb2F11]

Conditions
ConditionsYield
In hydrogen fluoride HF (liquid); High Pressure; (N2); addn. of HF, phosphine deriv. and CF4 to antimony compd., warming to 40°C; concg. at -78°C, warming to 40°C, crystn. by cooling to 25°C, NMR;66%

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