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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 2-Methyl-6-nitroaniline(570-24-1)

Cas:570-24-1

Min.Order:100 Gram

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Taixing Joxin Bio-tec Co.,Ltd.

2-Methyl-6-nitroaniline (Synonyms:2-Amino-3-nitrotoluene,6-Nitro-o-toluidine,2-Amino-3-methylnitrobenzene) CAS Rn:570-24-1 EINECS NO.:209-329-6 Molecular Formula:C7H8N2O2 Molecular Weight:152.15 Specifications Appearance:Orange-yellow

2-Methyl-6-nitroaniline

Cas:570-24-1

Min.Order:100 Kilogram

FOB Price: $100.0

Type:Lab/Research institutions

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Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Capability on chemical synthesis 1. Beijing High-Tech Enterprises 2. Strong R&D Team 3. 8 years of experiences in R & D of high-tech Catalyst; 4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sal

2-Amino-3-nitrotoluene

Cas:570-24-1

Min.Order:0 Metric Ton

FOB Price: $100000.0 / 110000.0

Type:Manufacturers

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Methyl-6-Nitroaniline ??? supplier in China

Cas:570-24-1

Min.Order:0 Metric Ton

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com Product Name 2-Amino-3-nitrotoluene CAS No. 570-24-1 Appearance

2-Methyl-6-nitroaniline

Cas:570-24-1

Min.Order:1 Gram

FOB Price: $8.0

Type:Lab/Research institutions

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Wuhan Fortuna Chemical Co.,Ltd

Unique advantages for 2-Methyl-6-nitroaniline Cas 570-24-1 Guaranteed the purity High quality & competitive price Quality control Fast feedback Prompt shipment Appearance:Powder Storage:?20°C Package:1kg/foil bag, 25kg/drum or as

Factory supply 2-Methyl-6-nitroaniline Cas 570-24-1 with top quality best purity

Cas:570-24-1

Min.Order:1 Kilogram

FOB Price: $165.0

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

Good price Good quality Appearance:powder Storage:dry condition Package:According to the demand of customer Application:intermediate Transportation:By sea or by air Port:Shanghai Port

570-24-1,2-Methyl-6-nitroaniline

Cas:570-24-1

Min.Order:1 Gram

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Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 6-nitro-o-toluidine

Cas:570-24-1

Min.Order:1

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Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 570-24-1 2-Methyl-6-nitroaniline Manufacturer

Cas:570-24-1

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, intermedi

2-Methyl-6-nitroaniline

Cas:570-24-1

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

2-Methyl-6-Nitroaniline

Cas:570-24-1

Min.Order:1 Metric Ton

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Type:Manufacturers

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Shanghai Seasonsgreen Chemical Co.,Ltd

Shanghai Seasonsgreen Chemical is a high-tech research and development, production, sale and custom synthesis set in one high-tech chemical products enterprises. Our sales and marketing division is located in Shanghai, serving international pharmaceu

lower price High quality 2-Methyl-6-nitroaniline

Cas:570-24-1

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem’s R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. Near 20 years DayangChem has provi

High purity 2-Methyl-6-nitroaniline 98% TOP1 supplier in China

Cas:570-24-1

Min.Order:100 Gram

FOB Price: $1.0 / 2.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

6-Nitro-o-toluidine (NH2=1)

Cas:570-24-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

2-Methyl-6-nitroaniline Basic information Product Name: 2-Methyl-6-nitroaniline Synonyms: 2-Amino-3-methylnitrobenzene;6-Nitro-o-toluidine(2-Methyl-6-nitroaniline);Benzenamine, 2-methyl-

2-Methyl-6-nitroaniline 570-24-1

Cas:570-24-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

2-Methyl-6-nitroaniline

Cas:570-24-1

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 570-24-1 with best quality

Cas:570-24-1

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

2-Methyl-6-nitroaniline/ LIDE PHARMA- Factory supply / Best price

Cas:570-24-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Henan Sinotech Import&Export Corporation

Product Name 2-Methyl-6-nitroaniline Synonyms 2-Methyl-6-nitroaniline,99%;2-Methyl-6-nitroaniline ,98%;2-Methyl-6-nitroaniline, 99% 25GR;1-Nitro-2-aMino-3-Methylbenzene;NSC 286;NSC 52218;2-Amino-1-methyl-

2-Methyl-6-nitroaniline

Cas:570-24-1

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2-Methyl-6-nitroaniline 570-24-1

Cas:570-24-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Pharmaceutical Intermediate, 2-Methyl-6-nitroaniline CAS:570-24-1

Cas:570-24-1

Min.Order:1 Kilogram

FOB Price: $30.0 / 34.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

2-Methyl-6-nitroaniline CAS:570-24-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic int

2-Methyl-6-nitroaniline CAS:570-24-1

Cas:570-24-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2-Methyl-6-nitroaniline

Cas:570-24-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram Supply Ability 500 Kilograms/Month Storage store in cool, dry, ventilated place 20℃ Delivery Time 3 business days after payment Payment Term TT,western union,Paypal,

2-Amino-3-nitrotoluene, 570-24-1, in stock CAS NO.570-24-1

Cas:570-24-1

Min.Order:20 Metric Ton

Negotiable

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

2-Methyl-6-nitroaniline

Cas:570-24-1

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

Hebei Sankai Chemical Technology Co., LTD. is located in xingtai City, Hebei Province, China. It is a biotechnology enterprise engaged in the research, development, production and sales of animal and plant extracts, cosmetics, pharmaceutical raw mate

High Purity 570-24-1 570-24-1 GMP Manufacturer 570-24-1 In Bulk Supply

Cas:570-24-1

Min.Order:1 Kilogram

FOB Price: $5.0 / 10.0

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

2-Methyl-6-nitroaniline

Cas:570-24-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2 Nitro 6 Methyl Aniline

Cas:570-24-1

Min.Order:0

Negotiable

Type:Manufacturers

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Triumph International Development Limilted

Appearance:off-white to white solid Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for Synthesis API and Research Transportation:As customer request Port:Qingda

2-Methyl-6-nitroaniline 570-24-1

Cas:570-24-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality moderate price & quick delivery Appearance:Redish-Brown Solid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used in organi

2-Methyl-6-nitroaniline

Cas:570-24-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Synthetic route

2-aminotoluene-5-sulfonic acid
98-33-9

2-aminotoluene-5-sulfonic acid

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

Conditions
ConditionsYield
Stage #1: 2-aminotoluene-5-sulfonic acid With acetic acid; zinc(II) oxide at 80℃; for 4h;
Stage #2: With nitric acid at 10 - 12℃; for 2h;
Stage #3: With hydrogenchloride In water at 100℃; for 1h;
82%
o-toluidine
95-53-4

o-toluidine

A

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

B

2-methyl-4-nitro-benzenamine
99-52-5

2-methyl-4-nitro-benzenamine

Conditions
ConditionsYield
With bromine; silver nitrate; triphenylphosphine In acetonitrile at 20℃; for 0.0833333h;A 15%
B 67%
With 4-nitro-4-methyl-2,3,5,6-tetrabromo-2,5-cyclohexadien-1-one In acetic acid for 3h; Ambient temperature;A 30%
B 40%
With acetic anhydride anschliessend mit wss.Salpetersaeure und Erwaermen des Reaktionsprodukts mit wss.Salzsaeure;
2-methyl-6-nitroazidobenzene
16714-18-4

2-methyl-6-nitroazidobenzene

isobutyraldehyde
78-84-2

isobutyraldehyde

A

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

B

4-methyl-2-(1-methylethyl)benzimidazole

4-methyl-2-(1-methylethyl)benzimidazole

C

1,2-dihydro-2,2,5-trimethylquinoxaline

1,2-dihydro-2,2,5-trimethylquinoxaline

Conditions
ConditionsYield
Stage #1: 2-methyl-6-nitroazidobenzene With triphenylphosphine In diethyl ether at 20℃; for 1h;
Stage #2: isobutyraldehyde In chloroform for 144h; aza-Wittig reaction; Heating;
Stage #3: With carbon monoxide; 1,3-bis-(diphenylphosphino)propane; 1,10-phenanthroline hydrate; bis(dibenzylideneacetone)-palladium(0) In N,N-dimethyl-formamide at 70℃; under 4560.31 Torr; for 21h; Further stages.;
A 8%
B 62%
C 11%
N-(2-methylphenyl)acetamide
120-66-1

N-(2-methylphenyl)acetamide

A

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

B

2-methyl-4-nitro-benzenamine
99-52-5

2-methyl-4-nitro-benzenamine

Conditions
ConditionsYield
Stage #1: N-(2-methylphenyl)acetamide With nitric acid at 10 - 12℃;
Stage #2: With hydrogenchloride
A 60%
B n/a
With nitric acid; acetic acid at 7 - 8℃; man laesst bei Zimmertemperatur stehen, giesst in wenig Wasser, filtriert, und erhitzt das Nitrierungsprodukt mit Salzsaeure; destilliert man hierauf mit Wasserdampf und erhaelt man mit Natronlauge die freie Base;
With nitric acid Nitrierung und Verseifung;
With ammonium nitrate; nitric acid; acetic acid Nitrierung und Verseifung;
With water; nitric acid; acetic acid man versetzt den abfiltrierten Niederschlag mit konz.Salzsaeure und destilliert mit Wasserdampf, wobei 3-Nitro-2-amino-toluol uebergeht, waehrend 5-Nitro-2-amino-toluol in der salzsauren Loesung zurueckbleibt;
N-(2-methyl-6-nitrophenyl)acetamide
59907-22-1

N-(2-methyl-6-nitrophenyl)acetamide

A

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

B

2-methyl-4-nitroacetanilide
2719-15-5

2-methyl-4-nitroacetanilide

Conditions
ConditionsYield
With hydrogenchlorideA 46%
B n/a
nitro acetate
591-09-3

nitro acetate

N-(2-methylphenyl)acetamide
120-66-1

N-(2-methylphenyl)acetamide

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

Conditions
ConditionsYield
With acetic acid und Erwaermen des Reaktionsprodukts mit wss.Salzsaeure;
N-(2-methylphenyl)acetamide
120-66-1

N-(2-methylphenyl)acetamide

A

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

B

2-methyl-4-nitroacetanilide
2719-15-5

2-methyl-4-nitroacetanilide

Conditions
ConditionsYield
With nitric acid; acetic anhydride; acetic acid at 15 - 20℃; ueber mehrere Stufen;
1-methyl-2,3-dinitrobenzene
602-01-7

1-methyl-2,3-dinitrobenzene

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

Conditions
ConditionsYield
With ammonia at 150 - 160℃; unter Druck;
N-(2-methyl-6-nitrophenyl)acetamide
59907-22-1

N-(2-methyl-6-nitrophenyl)acetamide

sodium methylate
124-41-4

sodium methylate

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

Conditions
ConditionsYield
Rate constant;
N-(2-methyl-6-nitrophenyl)acetamide
59907-22-1

N-(2-methyl-6-nitrophenyl)acetamide

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

Conditions
ConditionsYield
With sodium methylate
With hydrogenchloride
(hydrolysis);
N-(2-methylphenyl)-p-toluenesulphonamide
80-28-4

N-(2-methylphenyl)-p-toluenesulphonamide

A

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

B

2-methyl-4,6-dinitroaniline
7477-94-3

2-methyl-4,6-dinitroaniline

Conditions
ConditionsYield
bei hoeherer Temperatur erhaelt man ein Gemisch von Nitrierungsprodukten.Hydrolysis;
N,N'-bis(o-tolyl)oxamide
3299-62-5

N,N'-bis(o-tolyl)oxamide

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

Conditions
ConditionsYield
With sulfuric acid Schuetteln des Reaktionsprodukts mit Salpeterschwefelsaeure bei hoechstens 50grad und Erhitzen nach Zusatz von Wasser auf 140-150grad;
N-nitro-o-toluidine

N-nitro-o-toluidine

A

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

B

2-methyl-4-nitro-benzenamine
99-52-5

2-methyl-4-nitro-benzenamine

Conditions
ConditionsYield
With mineral acid
6-amino-5-nitro-toluene-3-sulfonic acid

6-amino-5-nitro-toluene-3-sulfonic acid

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

Conditions
ConditionsYield
durch Abspaltung der Sulfogruppe;
N-(2-methylphenyl)acetamide
120-66-1

N-(2-methylphenyl)acetamide

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

Conditions
ConditionsYield
(i) HNO3, (ii) aq. HCl; Multistep reaction;
With nitric acid
Multi-step reaction with 2 steps
1: nitric acid; acetic anhydride / dichloromethane
2: hydrogenchloride / water / Reflux
View Scheme
Stage #1: N-(2-methylphenyl)acetamide With nitric acid In acetic anhydride at 10 - 12℃; for 2.5h;
Stage #2: With sulfuric acid In water for 3h; Reflux;
39.78 g
1-methyl-3-nitrobenzene
99-08-1

1-methyl-3-nitrobenzene

A

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

B

2-methyl-4-nitro-benzenamine
99-52-5

2-methyl-4-nitro-benzenamine

C

4-methyl-2-nitroaniline
89-62-3

4-methyl-2-nitroaniline

Conditions
ConditionsYield
With potassium tert-butylate; N,N,N-trimethylhydrazinium iodide In dimethyl sulfoxide Ambient temperature; Yield given. Yields of byproduct given;
N-(2-methylphenyl)acetamide
120-66-1

N-(2-methylphenyl)acetamide

A

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

B

acetyl derivative of 5-nitro-2-amino-toluene

acetyl derivative of 5-nitro-2-amino-toluene

Conditions
ConditionsYield
With nitric acid; acetic acid man kocht das entstehende Acetylderiv.in alkoh.Loesung mit der waessr.Kalilauge,wodurch nur das Acetylderiv.des 5-Nitro-2-amino-toluols verseift wird; das Acetylderiv.des 3-Nitro-2-amino-toluols verseift man mit konz.Salzsaeure;
1-methyl-2,3-dinitrobenzene
602-01-7

1-methyl-2,3-dinitrobenzene

ammonia
7664-41-7

ammonia

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

Conditions
ConditionsYield
at 150 - 160℃; unter Druck;
sulfuric acid
7664-93-9

sulfuric acid

N,N'-bis(o-tolyl)oxamide
3299-62-5

N,N'-bis(o-tolyl)oxamide

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

Conditions
ConditionsYield
anschliessenden Schuetteln mit Salpeterschwefelsaeure unterhalb 50grad und Erhitzen mit Wasser auf 140-150grad;
sulfuric acid
7664-93-9

sulfuric acid

6-amino-5-nitro-toluene-3-sulfonic acid

6-amino-5-nitro-toluene-3-sulfonic acid

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

hydrogenchloride
7647-01-0

hydrogenchloride

diethyl ether
60-29-7

diethyl ether

N-nitro-o-toluidine

N-nitro-o-toluidine

A

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

B

2-methyl-4-nitro-benzenamine
99-52-5

2-methyl-4-nitro-benzenamine

Conditions
ConditionsYield
at 0℃;
o-toluidine
95-53-4

o-toluidine

chloric acid

chloric acid

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: 12 - 13 °C
2.1: 65 percent HNO3 / 10 - 12 °C
2.2: 60 percent / conc. HCl
View Scheme
Multi-step reaction with 2 steps
2: HNO3
View Scheme
o-toluidine
95-53-4

o-toluidine

ester of glycine

ester of glycine

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 60 percent / HNO3
2: concd. HCl / 7 h / Heating
View Scheme
o-toluidine
95-53-4

o-toluidine

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
2: acetic acid anhydride; glacial acetic acid; nitric acid / 15 - 20 °C / ueber mehrere Stufen
View Scheme
Multi-step reaction with 3 steps
1: triethylamine / dichloromethane
2: nitric acid; acetic anhydride / dichloromethane
3: hydrogenchloride / water / Reflux
View Scheme
N-(2-methylphenyl)acetamide
120-66-1

N-(2-methylphenyl)acetamide

calcium chloride

calcium chloride

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: (nitration)
2: aq. HCl
View Scheme
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

4-iodo-2-methyl-6-nitroaniline
532934-93-3

4-iodo-2-methyl-6-nitroaniline

Conditions
ConditionsYield
With Iodine monochloride; acetic acid at 30℃; for 3h;100%
With sodium acetate; Iodine monochloride; acetic acid at 80℃; for 0.833333h;98%
With N-iodo-succinimide; acetic acid at 50 - 55℃; for 6h; Inert atmosphere;97%
With Iodine monochloride; acetic acid
With Iodine monochloride; sodium hydrogencarbonate In methanol; dichloromethane at 20℃; for 6h;
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

benzaldehyde
100-52-7

benzaldehyde

4-methyl-2-phenyl-1H-benzimidazole
3659-77-6

4-methyl-2-phenyl-1H-benzimidazole

Conditions
ConditionsYield
With hydrogen In ethyl acetate at 60℃; under 7500.75 Torr; for 20h; Autoclave; Green chemistry;99%
With hydrogen In ethyl acetate at 60℃; under 7500.75 Torr; for 20h; Autoclave;99%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

4-chloro-2-methyl-6-nitrophenylamine
62790-50-5

4-chloro-2-methyl-6-nitrophenylamine

Conditions
ConditionsYield
With N-chloro-succinimide In methanol at 60℃; for 4h;98%
With N-chloro-succinimide; acetic acid92%
With N-chloro-succinimide; acetic acid at 50 - 55℃; for 6h; Inert atmosphere;92%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

7-Nitroindazole
2942-42-9

7-Nitroindazole

Conditions
ConditionsYield
With acetic acid; sodium nitrite for 0.333333h;98%
With acetic acid; sodium nitrite In water98%
With acetic acid; sodium nitrite In water at 20℃; for 0.333333h; Inert atmosphere;97%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

benzyl bromide
100-39-0

benzyl bromide

1-Benzyloxy-4-methyl-2-phenyl-1H-benzoimidazole
161958-74-3

1-Benzyloxy-4-methyl-2-phenyl-1H-benzoimidazole

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran for 16h; Heating;98%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

acetylacetone
123-54-6

acetylacetone

3-(2-mehtyl-6-nitrophenylhydrazono)pentane-2,4-dione
864652-84-6

3-(2-mehtyl-6-nitrophenylhydrazono)pentane-2,4-dione

Conditions
ConditionsYield
Stage #1: 2-Methyl-6-nitroaniline With hydrogenchloride; sodium nitrite
Stage #2: acetylacetone With sodium hydroxide; sodium acetate In methanol; water at 0 - 20℃; for 1h; Further stages.;
98%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

4-bromo-2-methyl-6-nitroaniline
77811-44-0

4-bromo-2-methyl-6-nitroaniline

Conditions
ConditionsYield
With hydrogen bromide; dihydrogen peroxide In ethanol; water at 60℃; for 1h; Product distribution / selectivity;97.7%
With N-Bromosuccinimide; acetic acid at 50 - 55℃; for 6h; Inert atmosphere;93%
With sodium tungstate; dihydrogen peroxide; acetic acid; potassium bromide for 1h; Ambient temperature;90%
With sodium tungstate; sodium perborate; sulfuric acid; acetic anhydride; potassium bromide In acetic acid for 1h; Ambient temperature;69%
With N-Bromosuccinimide In tetrachloromethane Substitution; bromination;60%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

3-methyl-1,2-benzenediamine
2687-25-4

3-methyl-1,2-benzenediamine

Conditions
ConditionsYield
With hydrogen; palladium 10% on activated carbon In ethanol at 20℃; under 760.051 Torr; for 4h;97%
With hydrogenchloride; tin for 1h; Reflux;85.8%
Stage #1: 2-Methyl-6-nitroaniline With tin(ll) chloride In ethyl acetate for 6h; Reflux;
Stage #2: With water; sodium hydrogencarbonate In ethyl acetate Cooling;
70%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

2-Bromoacetyl bromide
598-21-0

2-Bromoacetyl bromide

C9H9BrN2O3

C9H9BrN2O3

Conditions
ConditionsYield
With potassium carbonate In dichloromethane; water at 0℃; for 1h;97%
With sodium carbonate In water for 0.5h; pH=8 - 9;
With sodium carbonate In water for 2h;
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

acrylic acid
79-10-7

acrylic acid

3-(2-methyl-6-nitrophenylamino)propionic acid
1296194-25-6

3-(2-methyl-6-nitrophenylamino)propionic acid

Conditions
ConditionsYield
With sulfuric acid at 25 - 80℃; Inert atmosphere;96%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

orthobenzoic acid trimethyl ester
707-07-3

orthobenzoic acid trimethyl ester

4-methyl-2-phenyl-1H-benzimidazole
3659-77-6

4-methyl-2-phenyl-1H-benzimidazole

Conditions
ConditionsYield
With indium; acetic acid In ethyl acetate for 1h; Reflux; Inert atmosphere;96%
2-chloro-3-methoxypyridine
52605-96-6

2-chloro-3-methoxypyridine

2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

C13H13N3O3

C13H13N3O3

Conditions
ConditionsYield
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); C35H38NO4P In 1,4-dioxane at 100℃; for 18h;96%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

2-iodo-3-nitrotoluene
6277-17-4

2-iodo-3-nitrotoluene

Conditions
ConditionsYield
Stage #1: 2-Methyl-6-nitroaniline With sodium nitrite In sulfuric acid; acetic acid
Stage #2: With potassium iodide In sulfuric acid; water; acetic acid Further stages.;
95%
Stage #1: 2-Methyl-6-nitroaniline With hydrogenchloride In water at 0℃; for 0.25h;
Stage #2: With sodium nitrite In water at 0℃; for 1.67h;
Stage #3: With potassium iodide In water at 0℃; for 2.17h;
88%
Stage #1: 2-Methyl-6-nitroaniline With sulfuric acid; sodium nitrite In acetic acid at 15 - 75℃;
Stage #2: With urea; potassium iodide
79%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

2-chloro-5-[(3,5-dimethoxyphenyl)methoxy]pyrimidine
1453211-57-8

2-chloro-5-[(3,5-dimethoxyphenyl)methoxy]pyrimidine

5-[(3,5-dimethoxyphenyl)methoxy]-N-(2-methyl-6-nitrophenyl)pyrimidin-2-amine

5-[(3,5-dimethoxyphenyl)methoxy]-N-(2-methyl-6-nitrophenyl)pyrimidin-2-amine

Conditions
ConditionsYield
With caesium carbonate; bis(dibenzylideneacetone)-palladium(0); XPhos In N,N-dimethyl acetamide at 110℃; for 3h; Inert atmosphere;94%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

2-bromo-3-nitrotoluene
41085-43-2

2-bromo-3-nitrotoluene

Conditions
ConditionsYield
With hydrogen bromide; copper(I) bromide; sodium nitrite In 1,4-dioxane; water at 0 - 60℃;93%
Stage #1: 2-Methyl-6-nitroaniline With hydrogen bromide In 1,4-dioxane; water at 60℃; for 0.75h; Inert atmosphere;
Stage #2: With sodium nitrite In 1,4-dioxane; water at 0 - 8℃; for 2.33333h; Inert atmosphere;
Stage #3: With hydrogen bromide; copper(I) bromide In 1,4-dioxane; water at 20 - 60℃; for 20.5h; Inert atmosphere;
82%
Stage #1: 2-Methyl-6-nitroaniline With hydrogen bromide In 1,4-dioxane; water at 60℃; for 0.75h; Inert atmosphere;
Stage #2: With sodium nitrite In 1,4-dioxane; water at 0 - 5℃; Inert atmosphere;
Stage #3: With hydrogen bromide; copper(I) bromide In 1,4-dioxane; water at 24 - 60℃; Inert atmosphere;
81%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

allyl bromide
106-95-6

allyl bromide

1-allyloxy-4-methyl-2-vinylbenzimidazole
161958-75-4

1-allyloxy-4-methyl-2-vinylbenzimidazole

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran for 16h; Heating;92%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

naphthalene-1-carbonic acid chloride
879-18-5

naphthalene-1-carbonic acid chloride

Naphthalene-1-carboxylic acid (2-methyl-6-nitro-phenyl)-amide
212503-73-6

Naphthalene-1-carboxylic acid (2-methyl-6-nitro-phenyl)-amide

Conditions
ConditionsYield
With pyridine In tetrahydrofuran for 6h; Ambient temperature;91%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

acetic anhydride
108-24-7

acetic anhydride

N-(2-methyl-6-nitrophenyl)acetamide
59907-22-1

N-(2-methyl-6-nitrophenyl)acetamide

Conditions
ConditionsYield
In chloroform for 12h; Time; Reflux;90.2%
With sulfuric acid
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

cyclohexane-1,2-epoxide
286-20-4

cyclohexane-1,2-epoxide

(1R,2R)-2-(2-Methyl-6-nitro-phenylamino)-cyclohexanol

(1R,2R)-2-(2-Methyl-6-nitro-phenylamino)-cyclohexanol

trans-2-chlorocyclohexanol
6628-80-4

trans-2-chlorocyclohexanol

Conditions
ConditionsYield
With bismuth(III) chloride In cyclohexane at 20℃;A 90%
B n/a
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

1,3-bis(2-methyl-6-nitrophenyl)-2λ4-diazathia-1,2-diene
1431381-87-1

1,3-bis(2-methyl-6-nitrophenyl)-2λ4-diazathia-1,2-diene

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane; disulfur dichloride In chloroform at -30℃; for 2h; Reflux;90%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

4-chlorobenzenesulfonyl chloride
98-60-2

4-chlorobenzenesulfonyl chloride

N-(2-methyl-6-nitrophenyl)-4-chlorobenzenesulfonamide

N-(2-methyl-6-nitrophenyl)-4-chlorobenzenesulfonamide

Conditions
ConditionsYield
With sodium carbonate In water pH=9 - 10;89%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

dimethylglyoxal
431-03-8

dimethylglyoxal

5-methyl-2,3-dimethylquinoxaline
17635-19-7

5-methyl-2,3-dimethylquinoxaline

Conditions
ConditionsYield
With indium; indium(III) chloride In methanol for 2.5h; Reflux; Inert atmosphere;89%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

benzil
134-81-6

benzil

5-methyl-2,3-diphenylquinoxaline

5-methyl-2,3-diphenylquinoxaline

Conditions
ConditionsYield
With indium; indium(III) chloride In methanol for 1.66667h; Reagent/catalyst; Reflux; Inert atmosphere;89%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

2.3-butanediol
513-85-9

2.3-butanediol

5-methyl-2,3-dimethylquinoxaline
17635-19-7

5-methyl-2,3-dimethylquinoxaline

Conditions
ConditionsYield
With sodium hydroxide In toluene at 120℃; for 3h; Inert atmosphere; Sealed tube; Green chemistry;89%
With dodecacarbonyl-triangulo-triruthenium; cesiumhydroxide monohydrate; 1,3-bis-(diphenylphosphino)propane In tert-Amyl alcohol at 150℃; for 8h; Schlenk technique; Inert atmosphere;80%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

1-Bromo-2-bromomethyl-benzene
3433-80-5

1-Bromo-2-bromomethyl-benzene

1-(o-bromobenzyloxy)-2-(o-bromophenyl)-4-methylbenzimidazole

1-(o-bromobenzyloxy)-2-(o-bromophenyl)-4-methylbenzimidazole

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran for 12h; Heating;87%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

3-bromo-2-methyl-6-nitroaniline

3-bromo-2-methyl-6-nitroaniline

Conditions
ConditionsYield
With N-Bromosuccinimide; acetic acid for 2h; Reflux; Inert atmosphere;87%
With N-Bromosuccinimide; acetic acid for 2h; Reflux;87%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

1-methyl-2,3-dinitrobenzene
602-01-7

1-methyl-2,3-dinitrobenzene

Conditions
ConditionsYield
With sodium perborate; titanium(IV) hydroxide; acetic acid at 90 - 100℃; for 1h; Inert atmosphere;86.8%
With dihydrogen peroxide In acetic acid at 90℃; for 3h;48%
With sulfuric acid Diazotization.Ueberfuehrung des Diazoniumsulfats in das Nitrit und Behandeln mit Kupfer(I)-oxyd;
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

sodium hydrogensulfite

sodium hydrogensulfite

2-iodo-3-nitrotoluene
6277-17-4

2-iodo-3-nitrotoluene

Conditions
ConditionsYield
With potassium iodide; sulfuric acid; sodium nitrite In ice-water; ethanol; dichloromethane84%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

9,10-phenanthrenequinone
84-11-7

9,10-phenanthrenequinone

10-methyldibenzo[a,c]phenazine
112657-94-0

10-methyldibenzo[a,c]phenazine

Conditions
ConditionsYield
With indium; acetic acid In methanol for 0.166667h; Reflux; Inert atmosphere;84%
2-Methyl-6-nitroaniline
570-24-1

2-Methyl-6-nitroaniline

acetic anhydride
108-24-7

acetic anhydride

N,N-diacetyl-6-nitro-o-toluidine
82344-53-4

N,N-diacetyl-6-nitro-o-toluidine

Conditions
ConditionsYield
at 120℃; for 12.5h;83.7%

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