DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe
Cas:614-27-7
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquiryProduct Name: METHYL 3-OXO-3-PHENYLPROPANOATE Synonyms: METHYL BENZOYLACETATE;METHYL 3-OXO-3-PHENYLPROPANOATE;methyl 3-oxo-3-phenylpropionate;3-Oxo-3-phenylpropanoic acid methyl ester;3-Phenyl-3-oxopropanoic acid methyl ester;3-Phenyl-
Cas:614-27-7
Min.Order:1 Kilogram
FOB Price: $8900.0
Type:Lab/Research institutions
inquiryOur Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con
Cas:614-27-7
Min.Order:1 Kilogram
FOB Price: $15.0 / 50.0
Type:Trading Company
inquiry1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ
Cas:614-27-7
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Cas:614-27-7
Min.Order:0 Metric Ton
Negotiable
Type:Lab/Research institutions
inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Cas:614-27-7
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryZhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed
Cas:614-27-7
Min.Order:1 Kilogram
FOB Price: $2.0
Type:Lab/Research institutions
inquiryHigh quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use
Cas:614-27-7
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryWe are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp
Cas:614-27-7
Min.Order:1 Metric Ton
FOB Price: $1.0
Type:Trading Company
inquiryhigh purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
Our own factory produces direct sales with absolute price advantage Application:Pharmaceutical industry Transportation:By sea Port:Shanghai/tianjin
Cas:614-27-7
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryBenzenepropanoic acid, β-oxo-, methyl ester cas 614-27-7Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express
Cas:614-27-7
Min.Order:0
Negotiable
Type:Other
inquiryfactory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin
Cas:614-27-7
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquirylaboratory Application:Synthetic building block
Cas:614-27-7
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryStock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai
factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin
Lower price, sample is available,large stock in warehouse.Best service, high quality and reasonable price.If you are looking for the material's manufacturer or supplier in China, Sibian chemical is your best choice. Application:Drug R&D
Cas:614-27-7
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiry1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G
Cas:614-27-7
Min.Order:10 Milligram
Negotiable
Type:Lab/Research institutions
inquiryfactory,reasonable price Appearance:detailed see specifications Storage:Store in dry, dark and ventilated place. Package:according to the clients requirement Application:pharmaceutical intermediates Transportation:by courier,air or sea Port:S
Cas:614-27-7
Min.Order:0
Negotiable
Type:Trading Company
inquiryR & D enterprises have their own stock in stock Appearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou
Cas:614-27-7
Min.Order:5 Gram
Negotiable
Type:Lab/Research institutions
inquiryApeptide is a famous-peptide manufacturer in China,We supply high quality peptides(Custom Peptides\Amino acids\API pepitdes and so on )with the best competitive price and short lead time.,Please check our website: www.apeptides.com/en/Appearance:pow
Cas:614-27-7
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiry1. Production capacity: we have three production base with high-tech production equipment and instruments, equipped with professional production personnel, meet your requirements.2. Quality assurance: we have a first-class testing equipment and testi
FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the METHYL 3-OXO-3-PHENYLPROPANOATE, CAS:614-27-7 with the most competitive price and the
Debyesci is here who supplied several kinds of chemical products to global pharmaceutical, drug discovery, agrochemical and biotechnology industries for four yearsOur key scientific leadership team has gained experience in top research and developmen
Cas:614-27-7
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryhigh purity Application:Drug intermediates Materials intermediates and active molecules
Cas:614-27-7
Min.Order:0
Negotiable
Type:Trading Company
inquiryCas:614-27-7
Min.Order:0
Negotiable
Type:Trading Company
inquiryMethyl?Benzoyl?Acetate
Cas:614-27-7
Min.Order:0
Negotiable
Type:Trading Company
inquiryConditions | Yield |
---|---|
With sodium hydride In toluene; mineral oil Reflux; Inert atmosphere; | 100% |
With sodium hydride In toluene; mineral oil at 95℃; | 100% |
Stage #1: carbonic acid dimethyl ester With sodium hydride In toluene; mineral oil Inert atmosphere; Sealed tube; Reflux; Stage #2: acetophenone In toluene; mineral oil for 0.5h; Inert atmosphere; Sealed tube; | 98% |
Conditions | Yield |
---|---|
With sodium hydride In tetrahydrofuran Reflux; | 95% |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide for 17h; Ambient temperature; | 92.4% |
In tetrahydrofuran; hexane; N,N-dimethyl-formamide for 3h; Ambient temperature; Yield given; |
Conditions | Yield |
---|---|
With Bis(3-morpholinylpropyl)phenylphosphine In dichloromethane | 89% |
methanol
5-benzoyl-2,2-dimethyl-1,3-dioxane-4,6-dione
methyl 3-oxo-3-phenylpropionate
Conditions | Yield |
---|---|
for 0.0833333h; microwave irradiation; | 89% |
methanol
carbon monoxide
1-chloroacetophenone
methyl 3-oxo-3-phenylpropionate
Conditions | Yield |
---|---|
With tributyl-amine; bis-triphenylphosphine-palladium(II) chloride at 110℃; under 7500.6 Torr; for 2h; | 86% |
With bis-triphenylphosphine-palladium(II) chloride; N-benzyl-N,N,N-triethylammonium chloride; sodium acetate; triphenylphosphine at 80℃; under 7500.6 Torr; for 10h; | 70% |
With palladium(II) acetylacetonate; tributyl-amine; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene at 90℃; under 7500.75 Torr; for 15h; Inert atmosphere; | 68 %Chromat. |
Conditions | Yield |
---|---|
With iron(II) chloride In ethanol at 80℃; for 6h; | 85% |
syn-benzaldehyde oxime
phenylpropynoic acid methyl ester
A
methyl 3-oxo-3-phenylpropionate
B
benzonitrile
Conditions | Yield |
---|---|
With sodium hydride In 1,4-dioxane; N,N-dimethyl-formamide 1.) r.t., 0.5 h, 2.) 0.5 h; | A 84% B n/a |
benzoyl chloride
acetoacetic acid methyl ester
methyl 3-oxo-3-phenylpropionate
Conditions | Yield |
---|---|
Stage #1: acetoacetic acid methyl ester With water; barium(II) oxide In toluene at 25 - 30℃; for 1h; Stage #2: benzoyl chloride In toluene at 25 - 30℃; for 2h; Stage #3: With methanol In toluene at 25 - 30℃; for 16h; | 84% |
methyl 2-benzoyl-4-methylvalerate
A
methyl 3-oxo-3-phenylpropionate
B
methyl 4-benzoyl-4-methylvalerate
methyl c-2-hydroxy-3,3-dimethyl-2-phenyl-r-1-cyclobutanecarboxylate
Conditions | Yield |
---|---|
In benzene for 3h; Irradiation; | A 83% B 1% C 8% |
In benzene for 3h; Mechanism; Irradiation; | A 83% B 1% C 8% |
Conditions | Yield |
---|---|
yttria-stabilized zirconia In 1,2-dichloro-ethane for 12h; Heating; | 83% |
With Cu(II)-Mont K 10 clay In benzene at 80℃; for 5h; Condensation; | 80% |
Conditions | Yield |
---|---|
With sulfuric acid for 20h; Heating; | 82% |
With hydrogenchloride In water at 80℃; for 24h; Inert atmosphere; | 18% |
With acetyl chloride for 16h; | |
With sulfuric acid for 20h; | |
With sodium methylate at 69.84℃; for 24h; | 3.75 g |
(Z)-3-amino-3-phenylacrylic acid methyl ester
methyl 3-oxo-3-phenylpropionate
Conditions | Yield |
---|---|
With hydrogenchloride In tetrahydrofuran for 0.5h; Ambient temperature; | 82% |
Conditions | Yield |
---|---|
With hydrogenchloride In methanol; dichloromethane at 20℃; for 240h; Ring cleavage; | A 58% B 76% |
methanol
cycl-isopropylidene malonate
benzoyl chloride
methyl 3-oxo-3-phenylpropionate
Conditions | Yield |
---|---|
Stage #1: cycl-isopropylidene malonate; benzoyl chloride With pyridine In dichloromethane at 20℃; for 2h; Stage #2: methanol In dichloromethane for 2h; Further stages.; | 75% |
Conditions | Yield |
---|---|
With lithium diisopropyl amide In tetrahydrofuran at -78℃; | 73% |
methyl 2-benzoyl-3-pyrrolidino-3-pheylpropionate
A
methyl 3-oxo-3-phenylpropionate
B
methyl (2Z)-2-benzoyl-3-phenyl-2-propenoate
Conditions | Yield |
---|---|
In acetonitrile at 20℃; for 10h; | A 11% B 70% |
1-benzoyl-3,5-dimethyl-1H-pyrazole
bromoacetic acid methyl ester
methyl 3-oxo-3-phenylpropionate
Conditions | Yield |
---|---|
With zinc In tetrahydrofuran for 1h; Heating; | 67% |
methyl pentafluorophenyl carbonate
acetophenone
methyl 3-oxo-3-phenylpropionate
Conditions | Yield |
---|---|
With dmap; magnesium bromide ethyl etherate; N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; for 27h; Inert atmosphere; | 66% |
Conditions | Yield |
---|---|
With hydrogenchloride In methanol; water for 24h; Reflux; | 60% |
A
methyl 3-oxo-3-phenylpropionate
Conditions | Yield |
---|---|
With oxygen; p-cyanobenzyl methanesulfonate In acetonitrile Irradiation; | A 22% B 59% |
methyl 2-benzoylprop-2-enoate
A
methyl 3-oxo-3-phenylpropionate
B
dimethyl 2,4-dibenzoylpentanedioate
Conditions | Yield |
---|---|
With ethylenediamine In chloroform at 20℃; for 0.00833333h; | A 33% B 56% |
methanol
carbon monoxide
α-bromoacetophenone
methyl 3-oxo-3-phenylpropionate
Conditions | Yield |
---|---|
With tributyl-amine; bis-triphenylphosphine-palladium(II) chloride at 110℃; under 7500.6 Torr; for 2h; | 53% |
1-chloroacetophenone
A
methoxymethyl phenyl ketone
B
methyl 3-oxo-3-phenylpropionate
C
acetophenone
Conditions | Yield |
---|---|
With dichlorobis(triphenylphosphine)palladium(II); N,N,N',N'-tetramethyl-1,8-diaminonaphthalene In methanol at 100℃; under 3750.38 Torr; for 24h; Gas phase; | A 6% B 38% C 45% |
styrene
hydrazinecarboxylic acid methyl ester
A
methyl 3-oxo-3-phenylpropionate
B
methyl 3-hydroxy-3-phenylpropionate
Conditions | Yield |
---|---|
With (phthalocyaninato)iron(II) In tetrahydrofuran at 65℃; for 35h; | A 37% B 42% |
[(1-methoxyvinyl)oxy]trimethylsilane
benzil
A
methyl 3-oxo-3-phenylpropionate
B
benzoic acid
C
Dimethyl succinate
Conditions | Yield |
---|---|
In benzene for 14.5h; Irradiation; | A 23% B 40% C 19% |
Conditions | Yield |
---|---|
With tributyl-amine; dichlorobis(triphenylphosphine)palladium(II) In methanol at 110℃; under 7500.75 Torr; for 24h; Gas phase; | 38% |
Multi-step reaction with 2 steps 1: aqueous ethanol 2: hydrogen chloride View Scheme |
Conditions | Yield |
---|---|
With C2H2Cl2F3O2V; oxygen In tert-butyl alcohol at 50℃; for 72h; | A 36% B 11% |
carbon dioxide
acetophenone
methyl iodide
methyl 3-oxo-3-phenylpropionate
Conditions | Yield |
---|---|
With poly(dimethylsiloxane-co-methylhydrosiloxane)trimethylsilyl terminated supported 1-carboxy-6-ethyl-1,8-diazabicyclo[5.4.0]undec-7-ene In methanol at 25 - 27℃; under 760.051 Torr; for 4h; | 29% |
diazomethane
3-oxo-3-phenylpropionic acid
methyl 3-oxo-3-phenylpropionate
Conditions | Yield |
---|---|
With diethyl ether | |
In diethyl ether Yield given; |
Conditions | Yield |
---|---|
With ammonium hydroxide; titanium(III) chloride In methanol at 20 - 25℃; for 0.0833333h; pH=10 - 11; | 100% |
With formic acid; triethylamine In ethyl acetate at 25℃; for 18h; Inert atmosphere; | 96% |
With formic acid; triethylamine In ethyl acetate at 25℃; for 18h; Inert atmosphere; | 96% |
Conditions | Yield |
---|---|
In ethanol for 3h; Reflux; | 100% |
methyl 3-oxo-3-phenylpropionate
Conditions | Yield |
---|---|
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 25℃; for 1h; Inert atmosphere; Stage #2: With 2-Chloromethylthiophene In tetrahydrofuran; mineral oil at 0 - 70℃; | 100% |
methyl 3-oxo-3-phenylpropionate
Conditions | Yield |
---|---|
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 25℃; for 1h; Inert atmosphere; Stage #2: 1-naphthylmethyl halide In tetrahydrofuran; mineral oil at 0℃; | 100% |
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 1h; Inert atmosphere; Stage #2: 1-naphthylmethyl halide In tetrahydrofuran; mineral oil Inert atmosphere; |
Conditions | Yield |
---|---|
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 25℃; for 1h; Inert atmosphere; Stage #2: 2-chlorobenzyl halide In tetrahydrofuran; mineral oil at 0℃; | 100% |
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 1h; Inert atmosphere; Stage #2: 2-chlorobenzyl halide In tetrahydrofuran; mineral oil Inert atmosphere; |
methyl 3-oxo-3-phenylpropionate
C18H18O3
Conditions | Yield |
---|---|
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 25℃; for 1h; Inert atmosphere; Stage #2: 2-mehylbenzyl halide In tetrahydrofuran; mineral oil at 0℃; | 100% |
methyl 3-oxo-3-phenylpropionate
(+/-)-methyl 2-(2-nitrobenzyl)-3-phenyl-3-oxopropanoate
Conditions | Yield |
---|---|
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 25℃; for 1h; Inert atmosphere; Stage #2: 2-nitrobenzyl halide In tetrahydrofuran; mineral oil at 0℃; | 100% |
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 1h; Inert atmosphere; Stage #2: 2-nitrobenzyl halide In tetrahydrofuran; mineral oil Inert atmosphere; |
methyl 3-oxo-3-phenylpropionate
Conditions | Yield |
---|---|
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 25℃; for 1h; Inert atmosphere; Stage #2: 3,5-bis(trifluoromethyl)benzyl halide In tetrahydrofuran; mineral oil at 0℃; | 100% |
Conditions | Yield |
---|---|
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 25℃; for 1h; Inert atmosphere; Stage #2: 3-mehylbenzyl halide In tetrahydrofuran; mineral oil at 0℃; | 100% |
Conditions | Yield |
---|---|
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 25℃; for 1h; Inert atmosphere; Stage #2: 4-bromobenzyl halide In tetrahydrofuran; mineral oil at 0℃; | 100% |
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 1h; Inert atmosphere; Stage #2: 4-bromobenzyl halide In tetrahydrofuran; mineral oil Inert atmosphere; |
Conditions | Yield |
---|---|
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 25℃; for 1h; Inert atmosphere; Stage #2: 4-fluorobenzyl halide In tetrahydrofuran; mineral oil at 0℃; | 100% |
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 1h; Inert atmosphere; Stage #2: 4-fluorobenzyl halide In tetrahydrofuran; mineral oil Inert atmosphere; |
methyl 3-oxo-3-phenylpropionate
Conditions | Yield |
---|---|
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 25℃; for 1h; Inert atmosphere; Stage #2: 4-mehylbenzyl halide In tetrahydrofuran; mineral oil at 0℃; | 100% |
Conditions | Yield |
---|---|
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 25℃; for 1h; Inert atmosphere; Stage #2: 4-methoxybenzyl halide In tetrahydrofuran; mineral oil at 0℃; | 100% |
methyl 3-oxo-3-phenylpropionate
Conditions | Yield |
---|---|
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 25℃; for 1h; Inert atmosphere; Stage #2: 4-trifluoromethylbenzyl halide In tetrahydrofuran; mineral oil at 0℃; | 100% |
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 1h; Inert atmosphere; Stage #2: 4-trifluoromethylbenzyl halide In tetrahydrofuran; mineral oil Inert atmosphere; |
Conditions | Yield |
---|---|
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 25℃; for 1h; Inert atmosphere; Stage #2: allyl halide In tetrahydrofuran; mineral oil at 0℃; | 100% |
methyl 3-oxo-3-phenylpropionate
methyl 2-benzyl-3-oxo-3-phenylpropanoate
Conditions | Yield |
---|---|
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 25℃; for 1h; Inert atmosphere; Stage #2: benzyl halide In tetrahydrofuran; mineral oil at 0℃; | 100% |
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 1h; Inert atmosphere; Stage #2: benzyl halide In tetrahydrofuran; mineral oil Inert atmosphere; |
Conditions | Yield |
---|---|
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 25℃; for 1h; Inert atmosphere; Stage #2: ethyl halide In tetrahydrofuran; mineral oil at 0℃; | 100% |
Stage #1: methyl 3-oxo-3-phenylpropionate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 1h; Inert atmosphere; Stage #2: ethyl halide In tetrahydrofuran; mineral oil Inert atmosphere; |
methyl 3-oxo-3-phenylpropionate
methyl (R)-3-hydroxy-3-phenylpropanoate
Conditions | Yield |
---|---|
With C32H40F6O6P2Pd; hydrogen In acetone at 0℃; under 23272.3 Torr; for 12h; Autoclave; enantioselective reaction; | 99% |
With (2R,2'R,3R,3'R)-3,3'-di-tert-butyl-2,2'-diisopropyl-2,2',3,3'-tetrahydro-4,4'-bibenzo[d][1,3]oxaphosphole; hydrogen; palladium diacetate In acetone at 0 - 20℃; under 22801.5 Torr; for 20h; Glovebox; | 99% |
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; (SC,SC,RFC)-1-(diphenylphosphino)-2-[1-N-((4S)-4-tert-butyl-2-oxazolinyl-2-ylmethyl)ethyl]ferrocene; potassium tert-butylate; hydrogen In methanol at 20℃; under 7500.75 Torr; for 12h; Reagent/catalyst; Autoclave; | 95% |
With hydrogen; [NH2Me2][{RuCl[(R)-segphos]}2(μ-Cl)3] In methanol at 80℃; under 22067.3 Torr; for 6h; | 100 % Turnov. |
In methanol |
methyl 3-oxo-3-phenylpropionate
2-(trimethylsilyl)phenyl trifluoromethanesulfonate
methyl 2-(2-benzoylphenyl) acetate
Conditions | Yield |
---|---|
With cesium fluoride In acetonitrile at 80℃; | 99% |
With cesium fluoride In acetonitrile at 80℃; | 99% |
With cesium fluoride In acetonitrile at 80℃; Inert atmosphere; | |
With cesium fluoride In acetonitrile at 80℃; for 1h; Sealed tube; Inert atmosphere; |
methyl 3-oxo-3-phenylpropionate
cyclohexanol
cyclohexyl 3-oxo-3-phenylpropanonate
Conditions | Yield |
---|---|
In toluene for 6h; Inert atmosphere; Heating; | 99% |
With zinc In toluene at 110℃; for 24h; |
methyl 3-oxo-3-phenylpropionate
methyl 2-oxo-2-phenylacetate
Conditions | Yield |
---|---|
With aluminum (III) chloride; Oxone In water at 20℃; for 24h; | 98% |
With iodine; dimethyl sulfoxide; copper(ll) bromide for 8h; Schlenk technique; Heating; | 81% |
methyl 3-oxo-3-phenylpropionate
3-Amino-5-phenyl-4H-1,2,4-triazole
2,5-diphenyl-[1,2,4]triazolo[1,5-a]pyrimidin-7(4H)-one
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In butan-1-ol at 125℃; for 24h; | 98% |
methyl 3-oxo-3-phenylpropionate
5-(4-methoxyphenyl)-4H-1,2,4-triazol-3-amine
2-(4-methoxyphenyl)-5-phenyl-[1,2,4]triazolo[1,5-a]pyrimidin-7(4H)-one
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In butan-1-ol at 125℃; for 24h; | 97% |
methyl 3-oxo-3-phenylpropionate
methyl (S)-3-hydroxy-3-phenylpropionate
Conditions | Yield |
---|---|
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; C37H35FeN2P; potassium tert-butylate; hydrogen In methanol at 20℃; under 15001.5 Torr; for 12h; Catalytic behavior; Reagent/catalyst; Solvent; Autoclave; Glovebox; enantioselective reaction; | 96% |
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; C37H35FeN2P; potassium tert-butylate; hydrogen In methanol at 20℃; under 15201 Torr; for 24h; Solvent; Reagent/catalyst; Pressure; Glovebox; | 96% |
With hydrogen; C2H8N(1+)*C76H57Cl5O8P4Ru2(1-) In methanol at 80℃; for 5.5h; autoclave; | 95.3% |
With [Ir(H)2((R)-N-((1,3-dithian-2-yl)methyl)-7'-(bis(3,5-di-tert-butylphenyl)phosphanyl)-1,1'-spirobiindanyl-7-amine)Cl]; hydrogen; sodium hydroxide In methanol at 25 - 30℃; under 7600.51 Torr; for 4h; Autoclave; enantioselective reaction; | 93% |
In methanol | 171 g (95%) |
1-adamanthanol
methyl 3-oxo-3-phenylpropionate
(3s,5s,7s)-adamantan-1-yl 3-oxo-3-phenylpropanoate
Conditions | Yield |
---|---|
With zinc(II) oxide In toluene for 6h; Reflux; | 96% |
methyl 3-oxo-3-phenylpropionate
acetaldehyde
urea
5-methoxycarbonyl-6-methyl-4-phenyl-3,4-dihydropyrimidin-2(1H)-one
Conditions | Yield |
---|---|
With protonated penta-6-hydroxypurine bismuth chloride cluster chlorine complex In ethanol for 6h; Biginelli Pyrimidone Synthesis; Reflux; Green chemistry; | 96% |
methyl 3-oxo-3-phenylpropionate
Conditions | Yield |
---|---|
Stage #1: 4,6-dihydroxy-2-methyl-3-(3-methylbut-2-en-1-yl)benzaldehyde With selenium bromide polystyrene resin In dichloromethane at 0 - 25℃; for 0.5h; Solid phase reaction; Stage #2: methyl 3-oxo-3-phenylpropionate With piperidine at 95℃; for 2h; Solid phase reaction; Stage #3: With dihydrogen peroxide In tetrahydrofuran at 25℃; for 0.5h; Oxidation; elimination; | 95% |
2,2,6,6-Tetramethyl-1-piperidinyloxy free radical
methyl 3-oxo-3-phenylpropionate
Conditions | Yield |
---|---|
With copper dichloride In acetonitrile at 80℃; for 9h; Temperature; Time; Reagent/catalyst; Solvent; | 95% |
Conditions | Yield |
---|---|
With iodine In water at 25℃; for 0.166667h; Sonication; Green chemistry; | 95% |
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View