Zhejiang Zhengshuo Biotechnology Co., Ltd. is a vigorous and fast-growing green biosynthesis company, specializing in the R&D, production and sales of functional active substances, daily chemical raw materials, pharmaceutical chemicals, intermedi
Cas:6169-06-8
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inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
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inquiry1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s
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inquiryDayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities
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inquiryOur main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
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inquiryOur Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
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inquiry1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd
Cas:6169-06-8
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inquiryName: S-(+)-2-Octanol Synonyms: 2-Octanol, (2S)-; 2-Octanol, (S)-; d-Octan-2-ol; D(+)-2-Octanol; (S)-octan-2-ol; (S)-2-Octanol CAS: 6169-06-8 MF: C8H18O Appearance:Colorless Clear Liquid Storage:Preserve in well-closed, light-resistant and airtigh
1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:6169-06-8
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inquiryOur advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva
Cas:6169-06-8
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Type:Trading Company
inquiryD(+)-2-Octanol CAS:6169-06-8 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediat
Cas:6169-06-8
Min.Order:1 Gram
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inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
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inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc
Cas:6169-06-8
Min.Order:4 Kilogram
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inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:6169-06-8
Min.Order:10 Gram
FOB Price: $100.0
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inquiryWe are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov
Cas:6169-06-8
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Type:Lab/Research institutions
inquiryOur company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung, LG, Merck, Thermo Fisher Scientific and so o
Cas:6169-06-8
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryProduct Name: D(+)-2-Octanol Synonyms: (s)-2-octano;(S)-octan-2-ol;D(+)-2-OCTANOL;D-2-OCTANOL;(S)-(+)-2-HYDROXYOCTANE;(S)-2-HYDROXYOCTANE;(S)-(+)-2-OCTANOL;(S)-2-OCTANOL CAS: 6169-06-8 MF: C8H18O MW: 130.23 EINECS: 228-213-6 Produc
factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B
Cas:6169-06-8
Min.Order:1 Kilogram
FOB Price: $18.0 / 20.0
Type:Trading Company
inquiryShandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W
Cas:6169-06-8
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiry1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer
Cas:6169-06-8
Min.Order:1 Metric Ton
FOB Price: $1.5
Type:Trading Company
inquiryAppearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea
High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use
We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp
Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai
Cas:6169-06-8
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Negotiable
Type:Lab/Research institutions
inquiryLower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe
high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
(R)-2-octyl sulfate
(S)-2-Octanol
Conditions | Yield |
---|---|
With His-tagged Pseudomonas sp. metallo-β-lactamase-type alkylsulfatase Pisa1; water; tris hydrochloride at 30℃; for 6h; pH=8.2; Enzymatic reaction; optical yield given as %ee; stereoselective reaction; | 100% |
Conditions | Yield |
---|---|
With alcohol dehydrogenase from Lactobacillus kefir; alcohol dehydrogenase from Rhodococcus ruber DSM 44541; YcnD-oxidoreductase at 30℃; for 3h; pH=7.5; aq. buffer; Resolution of racemate; Enzymatic reaction; optical yield given as %ee; enantiospecific reaction; | 99% |
With phosphate buffer; tributyrin for 140h; Ambient temperature; | 77% |
Conditions | Yield |
---|---|
With NAD; Co2+immobilized acetophenone reductase from Geotrichum candidum In aq. phosphate buffer; isopropyl alcohol at 30℃; for 3h; pH=7.2; Green chemistry; Enzymatic reaction; enantioselective reaction; | 99% |
With glucose dehydrogenase; D-Glucose; alcohol dehydrogenase from Thermoanaerobacter sp.; NADPH In aq. buffer at 30℃; for 24h; pH=7.5; Concentration; Time; Ionic liquid; Green chemistry; Enzymatic reaction; enantioselective reaction; | 85% |
With acetophenone reductase from Geotrichum candidum NBRC 4597; NAD In isopropyl alcohol at 30℃; for 3h; pH=7.2; Enzymatic reaction; enantioselective reaction; | 85% |
(R)-2-octyl sulfate
(S)-2-Octanol
Conditions | Yield |
---|---|
With His-tagged Pseudomonas sp. metallo-β-lactamase-type alkylsulfatase Pisa1; water; tris hydrochloride at 30℃; for 6h; pH=8.2; Enzymatic reaction; optical yield given as %ee; stereoselective reaction; | 100% |
Conditions | Yield |
---|---|
With alcohol dehydrogenase from Lactobacillus kefir; alcohol dehydrogenase from Rhodococcus ruber DSM 44541; YcnD-oxidoreductase at 30℃; for 3h; pH=7.5; aq. buffer; Resolution of racemate; Enzymatic reaction; optical yield given as %ee; enantiospecific reaction; | 99% |
With phosphate buffer; tributyrin for 140h; Ambient temperature; | 77% |
Conditions | Yield |
---|---|
With NAD; Co2+immobilized acetophenone reductase from Geotrichum candidum In aq. phosphate buffer; isopropyl alcohol at 30℃; for 3h; pH=7.2; Green chemistry; Enzymatic reaction; enantioselective reaction; | 99% |
With glucose dehydrogenase; D-Glucose; alcohol dehydrogenase from Thermoanaerobacter sp.; NADPH In aq. buffer at 30℃; for 24h; pH=7.5; Concentration; Time; Ionic liquid; Green chemistry; Enzymatic reaction; enantioselective reaction; | 85% |
With acetophenone reductase from Geotrichum candidum NBRC 4597; NAD In isopropyl alcohol at 30℃; for 3h; pH=7.2; Enzymatic reaction; enantioselective reaction; | 85% |
rac-octan-2-ol
A
(S)-2-Octanol
B
(R)-Octan-2-ol
C
hexyl-methyl-ketone
Conditions | Yield |
---|---|
With Arthrobacter atrocyaneus In N,N-dimethyl-formamide at 32℃; for 48h; Microbiological reaction; enantioselective reaction; | A 94% B n/a C n/a |
With lyophilised cells of Escherichia coli overexpressing the solvent-tolerant alcohol dehydrogenase from Rhodococcus ruber DSM44541 In aq. buffer at 30℃; for 24h; pH=7.5; Reagent/catalyst; Resolution of racemate; Enzymatic reaction; | A n/a B n/a C n/a |
With NADP In acetone at 50℃; for 22h; pH=8; Resolution of racemate; |
(R)-(+)-2-hydroxyoctyl tosylate
(S)-2-Octanol
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride In tetrahydrofuran | 93% |
Conditions | Yield |
---|---|
With water; sodium hydroxide In methanol for 6h; Reflux; Inert atmosphere; | 87% |
With potassium hydroxide Heating; | 3.4 g |
rac-2-octyl sulfate
(S)-2-Octanol
Conditions | Yield |
---|---|
Stage #1: rac-2-octyl sulfate With His-tagged Pseudomonas sp. metallo-β-lactamase-type alkylsulfatase Pisa1; water; tris hydrochloride at 30℃; for 24h; pH=8.2; Resolution of racemate; Enzymatic reaction; Stage #2: With water; toluene-4-sulfonic acid In 1,4-dioxane; tert-butyl methyl ether at 40℃; for 5h; optical yield given as %ee; stereoselective reaction; | 87% |
Multi-step reaction with 2 steps 1: His-tagged Pseudomonas sp. metallo-β-lactamase-type alkylsulfatase Pisa1; water; tris hydrochloride / 6 h / 30 °C / pH 8.2 / Resolution of racemate; Enzymatic reaction 2: water; toluene-4-sulfonic acid / 1,4-dioxane; tert-butyl methyl ether / 2 h / 40 °C View Scheme |
(S)-2-Octanol
Conditions | Yield |
---|---|
With sodium hypophosphite; Raney-Ni (W-2) In ethanol; water for 0.5h; Ambient temperature; pH=5.2; | 85% |
With sodium hypophosphite; Raney Ni(W-2) In ethanol; water for 0.5h; Ambient temperature; | 75% |
(S)-N-(oct-2-yloxy)-4-(p-chlorophenyl)-thiazole-2(3H)-thione
(S)-2-Octanol
Conditions | Yield |
---|---|
With tri-n-butyl-tin hydride In dichloromethane at 18℃; for 0.416667h; Inert atmosphere; Photolysis; enantioselective reaction; | 85% |
(R)-1-Phenylsulfanyl-octan-2-ol
(S)-2-Octanol
Conditions | Yield |
---|---|
With sodium hypophosphite; Raney Ni(W-2) In ethanol; water for 0.5h; Ambient temperature; | 84% |
With sodium hypophosphite; Raney-Ni (W-2) In ethanol; water for 0.5h; Ambient temperature; pH=5.2; | 84% |
(S)-2-Octanol
Conditions | Yield |
---|---|
With sodium hypophosphite; Raney Ni(W-2) In ethanol; water for 0.5h; Ambient temperature; | 82% |
With sodium hypophosphite; Raney-Ni (W-2) In ethanol; water for 0.5h; Ambient temperature; pH=5.2; | 82% |
Conditions | Yield |
---|---|
A 77% B 75% |
Conditions | Yield |
---|---|
(1S,2R)-(-)-2-(N,N-di-n-butylamino)-1-phenylpropan-1-ol In hexane 1.) r.t., 20 min; 2.) 0 deg C, 16 h; | 70% |
Conditions | Yield |
---|---|
With methanesulfonic acid; (R,R)-dihydroborate In hexane at -20℃; for 48h; Title compound not separated from byproducts; | A n/a B 68% |
With hydrogen; tartaric acid-NaBr-mod. Raney nickel In tetrahydrofuran at 100℃; for 8h; Product distribution; enantioface hydrogenation with various carboxylic acids; | |
With hydrogen; TA-NaBr-MRNi In tetrahydrofuran at 60℃; under 66195.7 Torr; for 96h; Product distribution; RNi(prepared from 3.8 g of the alloy(Ni/Al=42/58))modified with 200 ml of aq. solution containing (R,R)-TA(2 g) and NaBr(12 g) at pH 3.2, 100 deg C for 1 h. hydrogenations of var. 2-alkanones, reactions at var. temperatures; |
rac-octan-2-ol
benzeneacetic acid methyl ester
A
(S)-2-Octanol
B
(R)-Octan-2-ol
C
(R)-2-octyl phenylacetate
D
hexyl-methyl-ketone
Conditions | Yield |
---|---|
With [(C4Ph4COHOCC4Ph4)(μ-H)][(CO)4Ru2]; Novozym(R) 435; 2,4-dimethylpentan-3-one In toluene at 70℃; under 142.511 Torr; for 40h; | A n/a B n/a C 63% D n/a |
(S)-N-(oct-2-yloxy)-pyridine-2(1H)-thione
(S)-2-Octanol
Conditions | Yield |
---|---|
With tri-n-butyl-tin hydride In dichloromethane at 18℃; for 0.0333333h; Inert atmosphere; Photolysis; enantioselective reaction; | 59% |
Conditions | Yield |
---|---|
With Candida antarctica lipase B; 1-(10-carboxydecyl)-3-methylimidazolium hexafluorophosphate; diisopropyl-carbodiimide In acetone at 40℃; for 2h; Resolution of racemate; Enzymatic reaction; enantioselective reaction; | A 51% B 35% |
Title compound not separated from byproducts; | |
With sodium acetate In water at 40℃; enantioselective reaction; | A n/a B n/a |
Conditions | Yield |
---|---|
With Candida antarctica lipase B In acetone at 35℃; for 3h; Resolution of racemate; Enzymatic reaction; enantioselective reaction; | A 51% B n/a |
vinyl acetate
rac-octan-2-ol
A
(S)-2-Octanol
B
(R)-2-octyl acetate
Conditions | Yield |
---|---|
With sol-gel encapsulated Candida antarctica lipase SP 525 at 20℃; for 17h; | A 50% B 47% |
With 4 A molecular sieve; immobilized lipase PS In di-isopropyl ether at 30℃; for 15h; | A 49% B 48.7% |
With immobilized lipase B from Candida antarctica In hexane at 32℃; for 1h; Resolution of racemate; Enzymatic reaction; | A 40% B 35% |
(S)-N-(oct-2-yloxy)-4-methylthiazole-2(3H)-thione
(S)-2-Octanol
Conditions | Yield |
---|---|
With tri-n-butyl-tin hydride In dichloromethane at 18℃; for 0.416667h; Inert atmosphere; Photolysis; enantioselective reaction; | 50% |
(R)-octan-2-yl methanesulfonate
(S)-2-Octanol
Conditions | Yield |
---|---|
With sulfuric acid In tetrahydrofuran for 19h; Heating; | 46% |
Conditions | Yield |
---|---|
With Lipase Amano AK at 20℃; for 72h; pH=7; aq. phosphate buffer; Enzymatic reaction; | A 42% B 43% |
Conditions | Yield |
---|---|
With oleic acid hydratase from Elizabethkingia meningoseptica A248L mutant; water; hexanoic acid In dimethyl sulfoxide at 25℃; for 144h; pH=6; Reagent/catalyst; Enzymatic reaction; enantioselective reaction; | 22% |
(S)-2-Octanol
Conditions | Yield |
---|---|
bei der Verseifung; succinic acid methyl ester--ester; |
(S)-2-Octanol
Conditions | Yield |
---|---|
Hydrolysis; malonic acid ethyl ester--ester; |
(S)-2-Octanol
Conditions | Yield |
---|---|
bei der Verseifung; succinic acid ethyl ester--ester; |
malonic acid bis-(1-methyl-heptyl ester)
(S)-2-Octanol
Conditions | Yield |
---|---|
Hydrolysis; malonic acid di--ester; |
bis(1-methylheptyl)butanedioate
(S)-2-Octanol
Conditions | Yield |
---|---|
bei der Verseifung; succinic acid di--ester; |
(S)-2-Octanol
(S)-(+)-2-methoxy-2-trifluoromethyl-2-phenylacetyl chloride
(R)-2-octyl (R)-α-methoxy-α-trifluoromethylphenylacetate
Conditions | Yield |
---|---|
With dmap In dichloromethane at 0 - 20℃; | 100% |
Conditions | Yield |
---|---|
With dmap; triethylamine In dichloromethane at 20℃; for 13h; | 99% |
With pyridine | 93.1% |
for 1h; Heating; | 82% |
With dmap at 30℃; for 18h; | |
With dmap |
(S)-2-Octanol
(R)-(-)-2-iodooctane
Conditions | Yield |
---|---|
With 1H-imidazole; iodine; triphenylphosphine In dichloromethane for 1h; Ambient temperature; | 98% |
With iodine In Petroleum ether for 6h; Heating; | 25% |
With hydrogen iodide |
(S)-2-Octanol
methanesulfonyl chloride
(S)-2-<(Methanesulfonyl)oxy>octane
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 0℃; | 98% |
With pyridine for 2h; | 86% |
With triethylamine In dichloromethane at 15 - 20℃; for 1h; | |
With pyridine | |
With pyridine |
(S)-2-Octanol
2,2,6-trimethyl-4H-1,3-dioxin-4-one
(S)-2-octyl acetoacetate
Conditions | Yield |
---|---|
for 0.1h; microwave irradiation; | 98% |
(S)-2-Octanol
Acetylenedicarboxylic acid
bis[(1S)-1-methylheptyl] acetylenedicarboxylate
Conditions | Yield |
---|---|
With sulfuric acid In tetrahydrofuran for 14h; Reflux; | 97% |
(S)-2-Octanol
benzoic acid
(S)-benzoic acid 1-methylheptyl ester
Conditions | Yield |
---|---|
With cyanomethylenetributyl-phosphorane In benzene at 100℃; for 24h; | 96% |
Conditions | Yield |
---|---|
With azodicarboxylic acid bis(2-methoxyethyl) ester; triphenylphosphine In toluene at 20℃; Product distribution / selectivity; Mitsunobu reaction; | 96% |
With azodicarboxylic acid bis(2-methoxyethyl) ester; triphenylphosphine In toluene at 20℃; for 3.5h; Mitsunobu reaction; Inert atmosphere; stereospecific reaction; | 96% |
With ethyl 2-(3,4-dichlorophenyl)azocarboxylate; triphenylphosphine In toluene at 20℃; for 5h; Mitsunobu Displacement; Inert atmosphere; | 93% |
Conditions | Yield |
---|---|
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran; toluene at 0 - 20℃; for 17.5h; Inert atmosphere; | 96% |
(S)-2-Octanol
(R)-2-chlorooctane
Conditions | Yield |
---|---|
With 1-chloro-1-(dimethylamino)-2-methyl-1-propene In dichloromethane 1.) 0 deg C; 2.) rt., 3h; | 95% |
With trichloroacetonitrile; triphenylphosphine In acetonitrile for 1h; Ambient temperature; | 70% |
With diethyl ether; phosphorus trichloride |
(S)-2-Octanol
methyl 5-chloro-2-fluoro-4-hydroxy-benzoate
(R)-5-chloro-2-fluoro-4-(2-octyloxy)benzoate
Conditions | Yield |
---|---|
With di-isopropyl azodicarboxylate; triphenylphosphine In dichloromethane at 25℃; for 2h; Etherification; | 95% |
Conditions | Yield |
---|---|
for 0.333333h; microwave irradiation; | 95% |
Conditions | Yield |
---|---|
With trimethylamine hydrochloride; triethylamine In dichloromethane at 0℃; for 1h; Inert atmosphere; | 94% |
With trimethylamine hydrochloride; triethylamine In dichloromethane at 0℃; for 2h; Inert atmosphere; | 94% |
With pyridine at 4℃; Inert atmosphere; | 92% |
(S)-2-Octanol
4-(methoxycarbonyloxy)benzoic acid
4-methoxycarbonyloxybenzoic acid (S)-1-methylheptyl ester
Conditions | Yield |
---|---|
With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran at 20℃; for 48h; | 94% |
(S)-2-Octanol
methyl 4-hydroxylbenzoate
methyl 4-{[(1R)-1-methylheptyl]oxy} benzoate
Conditions | Yield |
---|---|
Stage #1: (S)-2-Octanol; methyl 4-hydroxylbenzoate With triphenylphosphine In tetrahydrofuran at 0℃; for 0.25h; Mitsunobu reaction; Stage #2: With di-isopropyl azodicarboxylate In tetrahydrofuran at 0 - 20℃; for 8h; Mitsunobu reaction; | 94% |
With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran |
(S)-2-Octanol
benzoic acid
(R)-benzoic acid 1-methylheptyl ester
Conditions | Yield |
---|---|
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran; toluene at 20℃; Product distribution / selectivity; Mitsunobu reaction; | 93% |
With tributylphosphine; 1,1'-azodicarbonyl-dipiperidine In benzene at 60℃; for 24h; | 91% |
With azodicarboxylic acid bis(2-methoxyethyl) ester; triphenylphosphine In diethyl ether at 20℃; for 2h; Mitsunobu reaction; Inert atmosphere; stereospecific reaction; | 89% |
(S)-2-Octanol
N,N-diethyl 4'-bromo-4-methoxybiphenyl-2-carboxamide
(R)-N,N-diethyl 4'-bromo-4-(1-methylheptyloxy)biphenyl-2-carboxamide
Conditions | Yield |
---|---|
With di-isopropyl azodicarboxylate; triphenylphosphine In dichloromethane at 25℃; for 4h; Mitsunobu reaction; | 93% |
(S)-2-Octanol
Conditions | Yield |
---|---|
In chlorobenzene for 0.5h; microwave irradiation; | 92% |
Conditions | Yield |
---|---|
92% |
(S)-2-Octanol
4-Bromobenzoic acid
(S)-1-methylheptyl 4-bromobenzoate
Conditions | Yield |
---|---|
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 20℃; | 92% |
4-nitro-phenol
(S)-2-Octanol
(S)-4-(1-methylheptyl)oxy-1-nitrobenzene
Conditions | Yield |
---|---|
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 10 - 20℃; Inert atmosphere; | 91% |
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 20℃; for 18h; Mitsunobu Displacement; | 91% |
With di-isopropyl azodicarboxylate; triphenylphosphine In diethyl ether at 0 - 20℃; | 90% |
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran |
Conditions | Yield |
---|---|
With triethylsilane; ytterbium(III) triflate In 1,2-dichloro-ethane for 4h; Reflux; | 91% |
With triethylsilane; iron(III) chloride In nitromethane at 20℃; for 1h; | 81% |
Conditions | Yield |
---|---|
With potassium fluoride In diethyl ether at 0℃; | 90% |
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