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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

1,3-Dioxolane Manufacturer/High quality/Best price/In stock

Cas:646-06-0

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 1,3-Dioxolane supplier in China

Cas:646-06-0

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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EAST CHEMSOURCES LIMITED

1,3-Dioxolane Product Name: 1,3-Dioxolane Molecular Weight: 74.07 CAS NO: 646-06-0 EC NO: 211-463-5 Molecular Formula: C3H6O2

1,3-Dioxolane

Cas:646-06-0

Min.Order:1 Kilogram

FOB Price: $2.0 / 3.0

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 1,3-dioxolane

Cas:646-06-0

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1,3-Dioxolane

Cas:646-06-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co., LTD is a professional research, development and production Cyromazine、Azamethiphos、lead diacetate trihydrate /Lead acetate trihydrateC、 2-phenylacetamide 、 4-Aminophenyl-1-phenethylpiperidine 、Citric acid monohydrate 、

Gold quality 1,3-Dioxolane CAS:646-06-0

Cas:646-06-0

Min.Order:1 Kilogram

FOB Price: $11.0 / 16.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

1,3-Dioxolane Basic information Product Name: 1,3-Dioxolane Synonyms: 1,3-Dioxolan;1,3-Dioxole, dihydro-;1,3-dioxole,dihydro-;1,3-dixolane;dihydro-1,3-dioxole;dihydro-3-dioxole;Dioxolan;

646-06-0

Cas:646-06-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com Product Name 1,3-Dioxolane CAS No. 646-06-0 A

1,3-Dioxolane

Cas:646-06-0

Min.Order:1 Metric Ton

FOB Price: $12.0

Type:Lab/Research institutions

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Henan Sinotech Import&Export Corporation

[CAS NO.] 646-06-0 [Chemical name] 1,3-Dioxolane [Formula] C3H6O2 [Molecular weight] 74.08 [Appearance] colorless transparent liquid

1,3-Dioxolane

Cas:646-06-0

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

1,3-Dioxolane with CAS:646-06-0

Cas:646-06-0

Min.Order:1 Kilogram

FOB Price: $16.0 / 20.0

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:646-06-0

Cas:646-06-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Triumph International Development Limilted

Appearance:Colourless transparent liquid Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:Common produc

1,3-Dioxolane

Cas:646-06-0

Min.Order:100 Metric Ton

Negotiable

Type:Lab/Research institutions

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Afine Chemicals Limited

Our Services 1. New Molecules R&D 2. Own test center HPLC NMR GC LC-MS 3. API and Intermediates from China reputed manufacturers 4. Documents support COA MOA MSDS DMF open part Our advantages 1. Government awarded company. Top 100 enter

1,3-Dioxolane

Cas:646-06-0

Min.Order:1 Kilogram

FOB Price: $1.0 / 100000.0

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

1,3-Dioxolane

Cas:646-06-0

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,3-Dioxolane

Cas:646-06-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

1,3-Dioxolane

Cas:646-06-0

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 1,3-Dioxolane

Cas:646-06-0

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Hangzhou Lingrui Chemical Co.,Ltd.

1,3-DioxolaneAppearance:Colourless Liquid Storage:Refrigerator Package:according to customers' requirements Application:1,3-Dioxolane is an intermediate for the preparation of Acyclovir (A192400). Also, 1,3-Dioxolane is used in the synthesis of new V

1,3-Dioxolane

Cas:646-06-0

Min.Order:1 Gram

Negotiable

Type:Other

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:Colorless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum;200kg/drum as per your request Application:1,3-Dioxolane is an inter

1,3-Dioxolane

Cas:646-06-0

Min.Order:25 Kilogram

Negotiable

Type:Trading Company

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

1,3-Dioxolane

Cas:646-06-0

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

trans-2-Pentene

Cas:646-06-0

Min.Order:0

Negotiable

Type:Other

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Hangzhou Dingyan Chem Co., Ltd

high purity, manufacturer Application:Intermediate

1,3-Dioxolane

Cas:646-06-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Wuhan Fortuna Chemical Co.,Ltd

1.High quality : the purity is 99% min . through multiple producing procedures. 2.Competitive price : low price because of our skilled production technolpgy ,save the production cost at most , and give big profit room to our customers285.Safe and fa

1,3-Dioxolane

Cas:646-06-0

Min.Order:0

Negotiable

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

1,3-Dioxolane (stabilized with TriethylaMine)

Cas:646-06-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

hangzhou zeerrui chemical co., ltd. located in lingang industrial areas, our plant covers an area of 6000 square meters.zeerrui dedicated to the development, production and marketing of chemicals. we have earned ourselves a good reputation at home

1,3-Dioxolane

Cas:646-06-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 646-06-0 with competitive price

Cas:646-06-0

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1,3-Dioxolane

Cas:646-06-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

1,3-Dioxolane

Cas:646-06-0

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Ocean Chemical Co., Ltd.

★.Best quality according to requirement ★.Competitive price in China market ★.Mature Technical support ★.Professional logistic support

1,3-Dioxolane

Cas:646-06-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

low price and high purityAppearance:solid or liquid Storage:in sealed air resistant place Package:As customer require Application:Pharma;Industry;Agricultural Transportation:by sea or by airplane Port:any port in China

1,3-Dioxolane, 99.5%, stabilized 646-06-0

Cas:646-06-0

Min.Order:0

Negotiable

Type:Trading Company

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Synthetic route

formaldehyd
50-00-0

formaldehyd

ethanol
64-17-5

ethanol

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

Conditions
ConditionsYield
With C13H22N4O6S2(2+)*2CF3O3S(1-) In water at 130℃; for 2h; Reagent/catalyst;95.4%
formaldehyd
50-00-0

formaldehyd

ethylene glycol
107-21-1

ethylene glycol

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

Conditions
ConditionsYield
at 60 - 95℃; for 3h; Concentration; Temperature;94.3%
With phosphoric acid
With phosphoric acid; water
ethylene glycol
107-21-1

ethylene glycol

paraformaldehyde

paraformaldehyde

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

Conditions
ConditionsYield
With sulfur dioxide at 105 - 164℃; for 4h;85%
formaldehyd
50-00-0

formaldehyd

(CH2CH2O2)B(O-n-C4H9)
1124-68-1

(CH2CH2O2)B(O-n-C4H9)

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

Conditions
ConditionsYield
With zinc(II) chloride at 130 - 150℃;77%
methanol
67-56-1

methanol

ethylene glycol
107-21-1

ethylene glycol

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

Conditions
ConditionsYield
With iron(III) chloride hexahydrate; sodium nitrite at 50℃; for 24h; UV-irradiation;71%
acetaldehyde
75-07-0

acetaldehyde

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

Conditions
ConditionsYield
In toluene69%
ethylene glycol
107-21-1

ethylene glycol

polyoxymethylene

polyoxymethylene

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

Conditions
ConditionsYield
With bismuth(lll) trifluoromethanesulfonate In 1,4-dioxane at 100℃; for 3h; Sealed tube;66%
With iron(III) chloride
With phosphoric acid at 100℃; im Rohr;
With hydrogenchloride at 100℃;
2-ethoxy-1,3-dioxolane
4544-20-1

2-ethoxy-1,3-dioxolane

A

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

B

ethanol
64-17-5

ethanol

C

2-ethoxymethoxy-ethanol
4468-92-2

2-ethoxymethoxy-ethanol

Conditions
ConditionsYield
With diisobutylaluminium hydride In hexane at 35 - 40℃;A 45%
B n/a
C 45%
formaldehyd
50-00-0

formaldehyd

C9H19BO3
1309123-32-7

C9H19BO3

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

Conditions
ConditionsYield
With zinc(II) chloride at 130 - 150℃;31%
Fe(CO)4(COCH2CH2O)

Fe(CO)4(COCH2CH2O)

A

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

B

iron
7439-89-6

iron

Conditions
ConditionsYield
With H2 In decalin High Pressure; 71.5 atm H2 at room temp., heated to 200°C and stirred for 24 h; pressure realesed, detn. by GC and GC-MS;A 27%
B n/a
formaldehyd
50-00-0

formaldehyd

(CH2CH2O2)B(O-n-C6H13)
92673-07-9

(CH2CH2O2)B(O-n-C6H13)

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

Conditions
ConditionsYield
With zinc(II) chloride at 130 - 150℃;27%
formaldehyd
50-00-0

formaldehyd

2-(3-methyl-butoxy)-[1,3,2]dioxaborolane
118685-83-9

2-(3-methyl-butoxy)-[1,3,2]dioxaborolane

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

Conditions
ConditionsYield
With zinc(II) chloride at 130 - 150℃;24%
oxirane
75-21-8

oxirane

formaldehyd
50-00-0

formaldehyd

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

Conditions
ConditionsYield
With sulfuric acid; water Erhitzen des mit Calciumchlorid versetzten Reaktionsgemisches mit Aethylenglykol unter Zusatz von wss. Salzsaeure;
With sulfuric acid; water Erhitzen des mit Calciumchlorid versetzten Reaktionsgemisches mit Aethylenglykol unter Zusatz von wss. Salzsaeure;
[1,3,5,7,2,6]tetroxadithiocane 2,2,6,6-tetraoxide
20757-83-9

[1,3,5,7,2,6]tetroxadithiocane 2,2,6,6-tetraoxide

ethylene glycol
107-21-1

ethylene glycol

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

Conditions
ConditionsYield
With water
2-ethoxy-1,3-dioxolane
4544-20-1

2-ethoxy-1,3-dioxolane

triethylsilane
617-86-7

triethylsilane

A

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

B

ethoxytriethylsilane
597-67-1

ethoxytriethylsilane

C

1,2-bis (triethylsilyloxy) ethane
13175-68-3

1,2-bis (triethylsilyloxy) ethane

D

(2-Ethoxymethoxy-ethoxy)-triethyl-silane

(2-Ethoxymethoxy-ethoxy)-triethyl-silane

Conditions
ConditionsYield
With nickel at 65℃; for 2h; Yield given. Further byproducts given. Yields of byproduct given;
1,2-di(1,3-dioxolan-2-yloxy)ethane
4544-19-8

1,2-di(1,3-dioxolan-2-yloxy)ethane

A

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

B

2-ethoxy-1,3-dioxolane
4544-20-1

2-ethoxy-1,3-dioxolane

C

[1,3]-dioxolan-2-one
96-49-1

[1,3]-dioxolan-2-one

D

(1,3-dioxolan-2-yloxy)ethanal
85533-22-8

(1,3-dioxolan-2-yloxy)ethanal

E

2-(1,3-dioxolan-2-yloxy)ethyl carbonate
85533-21-7

2-(1,3-dioxolan-2-yloxy)ethyl carbonate

F

formic acid ethyl ester
109-94-4

formic acid ethyl ester

Conditions
ConditionsYield
With di-tert-butyl peroxide at 130℃; for 0.5h; Product distribution;A 0.01 mol
B 0.08 mol
C 0.08 mol
D 0.02 mol
E 0.009 mol
F 0.01 mol
carbon monoxide
201230-82-2

carbon monoxide

A

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

B

propan-1-ol
71-23-8

propan-1-ol

C

ethanol
64-17-5

ethanol

D

ethylene glycol
107-21-1

ethylene glycol

Conditions
ConditionsYield
With 2-hydroxypyridin; hydrogen; acetylacetonatodicarbonylrhodium(l) In various solvent(s) at 230℃; under 1499480 Torr; for 4.5h; Further byproducts given. Title compound not separated from byproducts;A 2 mmol
B 121 mmol
C 191 mmol
D 1000 mmol
ethylene glycol
107-21-1

ethylene glycol

A

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

B

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

C

2-hydroxymethyl-1,3-dioxolane
5694-68-8

2-hydroxymethyl-1,3-dioxolane

D

formic acid
64-18-6

formic acid

E

acetic acid
64-19-7

acetic acid

Conditions
ConditionsYield
With iron(III)-acetylacetonate; oxygen In water at 150℃; for 100h; Product distribution; other acetloacetonates, also in basic solution;
trans-9,10-dihydroxy-9,10-diphenyl-9,10-dihydroanthracene-1,3-dioxolane

trans-9,10-dihydroxy-9,10-diphenyl-9,10-dihydroanthracene-1,3-dioxolane

A

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

B

trans-9,10-dihydroxy-9,10-diphenyl-9,10-dihydroanthracene
36164-98-4

trans-9,10-dihydroxy-9,10-diphenyl-9,10-dihydroanthracene

Conditions
ConditionsYield
at 55℃; under 60 Torr; Thermodynamic data; ΔE(act.), var. temp and pressure;
oxirane
75-21-8

oxirane

1,3,5-Trioxan
110-88-3

1,3,5-Trioxan

A

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

B

1,3,5-trioxepane
5981-06-6

1,3,5-trioxepane

C

1,3,5,7-tetraoxacyclononane

1,3,5,7-tetraoxacyclononane

Conditions
ConditionsYield
With boron trifluoride-butyl ether complex In cyclohexane at 70℃; Title compound not separated from byproducts;
With boron trifluoride-butyl ether complex In cyclohexane at 70℃; Kinetics;
With boron trifluoride-butyl ether complex In cyclohexane at 70℃;A n/a
B n/a
C 33 % Chromat.
oxirane
75-21-8

oxirane

formaldehyd
50-00-0

formaldehyd

sulfuric acid
7664-93-9

sulfuric acid

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

formaldehyd
50-00-0

formaldehyd

sulfuric acid
7664-93-9

sulfuric acid

ethylene glycol
107-21-1

ethylene glycol

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

Conditions
ConditionsYield
at 140℃;
[1,3,5,7,2,6]tetroxadithiocane 2,2,6,6-tetraoxide
20757-83-9

[1,3,5,7,2,6]tetroxadithiocane 2,2,6,6-tetraoxide

water
7732-18-5

water

ethylene glycol
107-21-1

ethylene glycol

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

formaldehyd
50-00-0

formaldehyd

ethylene glycol
107-21-1

ethylene glycol

NaHSO4

NaHSO4

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

Conditions
ConditionsYield
at 140℃;
[1,3]Dioxolane; compound with iodine

[1,3]Dioxolane; compound with iodine

A

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

B

iodine

iodine

Conditions
ConditionsYield
In n-heptane at 20℃; Equilibrium constant; Thermodynamic data; 1/K=0.85 l/mole ΔH=3.0 kcal/mole;
Fe(CO)4(COCH2CH2O)

Fe(CO)4(COCH2CH2O)

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

Conditions
ConditionsYield
With CO; H2 In decalin in presence of 34 atm CO;0%
ethylene glycol
107-21-1

ethylene glycol

A

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

B

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

Conditions
ConditionsYield
With H5V2Mo10O40*34H2O In sulfolane Kinetics; Mechanism; Temperature; Time; Inert atmosphere;
carbon dioxide
124-38-9

carbon dioxide

ethylene glycol
107-21-1

ethylene glycol

A

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

B

2,2'-methanediyldioxy-bis-ethanol
2565-36-8

2,2'-methanediyldioxy-bis-ethanol

C

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

Conditions
ConditionsYield
With aluminium(III) triflate; [Ru(1,1,1-tris(diphenylphosphinomethyl)ethane)(trimethylenemethane)]; hydrogen In 1,4-dioxane at 80℃; under 60006 Torr; for 18h; Catalytic behavior; Solvent; Autoclave; Schlenk technique;
carbon dioxide
124-38-9

carbon dioxide

ethylene glycol
107-21-1

ethylene glycol

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

Conditions
ConditionsYield
With aluminium(III) triflate; [Ru(1,1,1-tris(diphenylphosphinomethyl)ethane)(trimethylenemethane)]; hydrogen In 1,4-dioxane at 80℃; under 60006 Torr; for 18h; Catalytic behavior; Autoclave; Schlenk technique;
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

acetyl chloride
75-36-5

acetyl chloride

1-acetoxy-2-chloromethoxyethane
40510-88-1

1-acetoxy-2-chloromethoxyethane

Conditions
ConditionsYield
With zinc(II) chloride In diethyl ether at 19 - 27℃; for 5.33333h;100%
Stage #1: 1,3-DIOXOLANE With zinc(II) chloride at 20℃; for 0.5h; Inert atmosphere;
Stage #2: acetyl chloride at 20 - 80℃; for 22h; Inert atmosphere;
92%
With zinc(II) chloride83%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

Acetyl bromide
506-96-7

Acetyl bromide

2-acetoxyethoxymethyl bromide
81777-40-4

2-acetoxyethoxymethyl bromide

Conditions
ConditionsYield
at 0 - 20℃;100%
for 2h;93%
at 0℃;88%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

acetaldehyde enolate
64723-93-9

acetaldehyde enolate

Conditions
ConditionsYield
With amide at 24.9℃; OH-;100%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

(S)-α,α-(2-thiophenylethylamino)(2-chlorophenyl)acetonitrile hydrochloride
216249-59-1

(S)-α,α-(2-thiophenylethylamino)(2-chlorophenyl)acetonitrile hydrochloride

(S)-2-(2-chlorophenyl)-2-(6,7-dihydrothieno[3,2-c]pyridin-5(4H)-yl)acetonitrile
444728-17-0

(S)-2-(2-chlorophenyl)-2-(6,7-dihydrothieno[3,2-c]pyridin-5(4H)-yl)acetonitrile

Conditions
ConditionsYield
at 90℃; for 11h;100%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

homoveratrylamine hydrochloride
635-85-8

homoveratrylamine hydrochloride

6,7-dimethoxy-1,2,3,4-tetrahydroisoquinoline
1745-07-9

6,7-dimethoxy-1,2,3,4-tetrahydroisoquinoline

Conditions
ConditionsYield
With hydrogenchloride99.8%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

(S,E)-3-(p-tolylsulfinyl)-3-pentene-2-one
207983-95-7

(S,E)-3-(p-tolylsulfinyl)-3-pentene-2-one

5,5-ethylenedioxy-4-methyl-3-(p-tolylsulfinyl)-2-pentanone

5,5-ethylenedioxy-4-methyl-3-(p-tolylsulfinyl)-2-pentanone

Conditions
ConditionsYield
With benzophenone for 0.166667h; Addition; Irradiation;99%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

2-<2-(phenylsulfonyl)ethyl>-1,3-dioxolane
56161-51-4

2-<2-(phenylsulfonyl)ethyl>-1,3-dioxolane

Conditions
ConditionsYield
With (Bu4N)2S2O8 at 25℃; for 3h; Inert atmosphere; regioselective reaction;99%
With 1-(tert-butylperoxy)-1,2-benziodoxol-3(1H)-one at 50℃; for 24h;76%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

ethyl 2-diazo-3-oxobutanoate
2009-97-4

ethyl 2-diazo-3-oxobutanoate

ethyl (4Z)-4-methyl-7,8-dihydro-1,3,6-trioxocine-5-carboxylate

ethyl (4Z)-4-methyl-7,8-dihydro-1,3,6-trioxocine-5-carboxylate

Conditions
ConditionsYield
With copper(II) bis(trifluoromethanesulfonate) In benzene at 80℃; for 4h;99%
With dirhodium tetraacetate at 60℃; for 2h; Inert atmosphere;90%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

boron trichloride
10294-34-5

boron trichloride

ClCH2CO(CH2)2OBCl2

ClCH2CO(CH2)2OBCl2

Conditions
ConditionsYield
-80°C;98.8%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

(S,E)-3-[(2,4,6-triisopropylphenyl)sulfinyl]-3-pentene-2-one
207983-99-1

(S,E)-3-[(2,4,6-triisopropylphenyl)sulfinyl]-3-pentene-2-one

(3R,4R,RS)-5,5-ethylenedioxy-4-methyl-3-[(2,4,6-triisopropylphenyl)sulfinyl]-2-pentanone
220077-33-8

(3R,4R,RS)-5,5-ethylenedioxy-4-methyl-3-[(2,4,6-triisopropylphenyl)sulfinyl]-2-pentanone

Conditions
ConditionsYield
With benzophenone for 0.166667h; Addition; Irradiation;98%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

methyl 4,4-ethylenedioxy-3-methyl-butanoate
77878-20-7

methyl 4,4-ethylenedioxy-3-methyl-butanoate

Conditions
ConditionsYield
With (Bu4N)2S2O8 at 25℃; for 15h; Inert atmosphere; regioselective reaction;98%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

dimethyl cis-but-2-ene-1,4-dioate
624-48-6

dimethyl cis-but-2-ene-1,4-dioate

2-(1,3-dioxolan-2-yl)butanedioic acid 1,4-dimethyl ester
88820-09-1

2-(1,3-dioxolan-2-yl)butanedioic acid 1,4-dimethyl ester

Conditions
ConditionsYield
With (Bu4N)2S2O8 at 25℃; for 1.5h; Inert atmosphere; regioselective reaction;98%
With 1-hydroxy-pyrrolidine-2,5-dione; dimethylglyoxal at 20℃; for 3h; Irradiation; Sealed tube; Inert atmosphere;96%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

1,4-dimethyl but-2-enedioate
23055-10-9

1,4-dimethyl but-2-enedioate

2-(1,3-dioxolan-2-yl)butanedioic acid 1,4-dimethyl ester
88820-09-1

2-(1,3-dioxolan-2-yl)butanedioic acid 1,4-dimethyl ester

Conditions
ConditionsYield
With (Bu4N)2S2O8 at 25℃; for 1.5h; Inert atmosphere; regioselective reaction;98%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

triethylsilane
617-86-7

triethylsilane

1-methoxy-2-(triethylsiloxy)-ethane
73993-16-5

1-methoxy-2-(triethylsiloxy)-ethane

Conditions
ConditionsYield
nickel at 80 - 100℃; for 1h;97%
zinc(II) chloride at 140℃; for 12h;62%
With zinc(II) chloride at 140℃; Product distribution; Rate constant;
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

dibenzo-18-crown-6
14187-32-7

dibenzo-18-crown-6

sodium thiocyanide
540-72-7

sodium thiocyanide

C20H24O6*C3H6O2*CNS(1-)*Na(1+)

C20H24O6*C3H6O2*CNS(1-)*Na(1+)

Conditions
ConditionsYield
for 1h; Ambient temperature;97%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

cyclopent-2-enone
930-30-3

cyclopent-2-enone

3-[1,3]Dioxolan-2-yl-cyclopentanone

3-[1,3]Dioxolan-2-yl-cyclopentanone

Conditions
ConditionsYield
With (Bu4N)2S2O8 at 20 - 25℃;97%
With (Bu4N)2S2O8 at 25℃; for 18h; Inert atmosphere; regioselective reaction;97%
With (Bu4N)2S2O8 at 25℃; Yield given;
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

(S)-2-[(2,4,6-triisopropylphenyl)sulfinyl]-2-cyclopentenone
151951-76-7

(S)-2-[(2,4,6-triisopropylphenyl)sulfinyl]-2-cyclopentenone

(2R,3R,RS)-3-(1,3-dioxolan-2-yl)-2-[(2,4,6-triisopropylphenyl)sulfinyl]-1-cyclopentanone
220077-00-9

(2R,3R,RS)-3-(1,3-dioxolan-2-yl)-2-[(2,4,6-triisopropylphenyl)sulfinyl]-1-cyclopentanone

Conditions
ConditionsYield
With benzophenone for 0.166667h; Addition; Irradiation;97%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

(E)-N-(4-bromophenyl)-1-(2,4-dichlorophenyl)methanimine

(E)-N-(4-bromophenyl)-1-(2,4-dichlorophenyl)methanimine

4-bromo-N-((2,4-dichlorophenyl)(1,3-dioxolan-2-yl)methyl)aniline

4-bromo-N-((2,4-dichlorophenyl)(1,3-dioxolan-2-yl)methyl)aniline

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile); 2,3,3,4,4,5-hexamethyl-2-hexanethiol at 80℃; for 10h; Sealed tube; Molecular sieve;97%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

dimethyl 2-benzylidenepropanedioate
6626-84-2

dimethyl 2-benzylidenepropanedioate

dimethyl 2-((1,3-dioxolan-2-yl)(phenyl)methyl)malonate

dimethyl 2-((1,3-dioxolan-2-yl)(phenyl)methyl)malonate

Conditions
ConditionsYield
With fac-tris[2-phenylpyridinato-C2,N]iridium(III); (Bu4N)2S2O8 at 30℃; for 24h; Reagent/catalyst; Inert atmosphere; Sealed tube; Irradiation;97%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

4'-methylpropiophenone
5337-93-9

4'-methylpropiophenone

piperidine hydrochloride
6091-44-7

piperidine hydrochloride

Tolperisone hydrochloride

Tolperisone hydrochloride

Conditions
ConditionsYield
With hydrogenchloride at 90℃; for 8h;96%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

(5S)-5-(tert-butyldiphenylsiloxymethyl)-2(5H)-furanone
99315-76-1

(5S)-5-(tert-butyldiphenylsiloxymethyl)-2(5H)-furanone

(4S,5S)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-4-[1,3]dioxolan-2-yl-dihydro-furan-2-one

(4S,5S)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-4-[1,3]dioxolan-2-yl-dihydro-furan-2-one

Conditions
ConditionsYield
With (Bu4N)2S2O896%
With (Bu4N)2S2O8 at 30℃; for 0.25h;96%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

2-[(S)-(4-methylphenyl)sulfinyl]cyclopent-2-en-1-one
79681-26-8

2-[(S)-(4-methylphenyl)sulfinyl]cyclopent-2-en-1-one

(2R*,3R*,RS)-3-(1,3-dioxolan-2-yl)-2-(p-tolylsulfinyl)-1-cyclopentanone

(2R*,3R*,RS)-3-(1,3-dioxolan-2-yl)-2-(p-tolylsulfinyl)-1-cyclopentanone

Conditions
ConditionsYield
With benzophenone for 0.166667h; Addition; Irradiation;96%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

dichloro-(2-chloromethoxy-ethoxy)-borane
856611-83-1

dichloro-(2-chloromethoxy-ethoxy)-borane

bis(chloromethoxyethoxy)chloroborane
89582-76-3

bis(chloromethoxyethoxy)chloroborane

Conditions
ConditionsYield
96%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

6-chloro-1-[(2'-hydroxyethoxy)methyl]-N-[(phenyl)methyl]-1,4-dihydro-4-oxoquinoline-3-carboxamide
1185869-41-3

6-chloro-1-[(2'-hydroxyethoxy)methyl]-N-[(phenyl)methyl]-1,4-dihydro-4-oxoquinoline-3-carboxamide

Conditions
ConditionsYield
Stage #1: C17H13ClN2O2 With chloro-trimethyl-silane; N,O-Bis(trimethylsilyl)trifluoroacetamide In acetonitrile for 4h; Inert atmosphere; Reflux;
Stage #2: 1,3-DIOXOLANE With chloro-trimethyl-silane; potassium iodide In acetonitrile at 20℃; for 24h;
Stage #3: With water; sodium hydrogencarbonate In acetonitrile
96%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

glyoxylic acid ethyl ester
924-44-7

glyoxylic acid ethyl ester

aniline
62-53-3

aniline

ethyl 2-(1,3-dioxolan-2-yl)-2-(phenylamino)acetate

ethyl 2-(1,3-dioxolan-2-yl)-2-(phenylamino)acetate

Conditions
ConditionsYield
Stage #1: 1,3-DIOXOLANE; glyoxylic acid ethyl ester; aniline In toluene at 20℃; for 1h; Sealed tube; Molecular sieve;
Stage #2: With 2,2'-azobis(isobutyronitrile); 2,3,3,4,4,5-hexamethyl-2-hexanethiol In toluene at 80℃; for 12h; Sealed tube; Molecular sieve; regioselective reaction;
96%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

glyoxylic acid ethyl ester
924-44-7

glyoxylic acid ethyl ester

4-methoxy-aniline
104-94-9

4-methoxy-aniline

ethyl 2-(1,3-dioxolan-2-yl)-2-((4-methoxyphenyl)amino)acetate

ethyl 2-(1,3-dioxolan-2-yl)-2-((4-methoxyphenyl)amino)acetate

Conditions
ConditionsYield
Stage #1: 1,3-DIOXOLANE; glyoxylic acid ethyl ester; 4-methoxy-aniline In toluene at 20℃; for 1h; Sealed tube; Molecular sieve;
Stage #2: With 2,2'-azobis(isobutyronitrile); 2,3,3,4,4,5-hexamethyl-2-hexanethiol In toluene at 80℃; for 12h; Sealed tube; Molecular sieve;
96%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

2,2,2-trifluoro-N-hexylethan-1-imine

2,2,2-trifluoro-N-hexylethan-1-imine

C11H20F3NO2

C11H20F3NO2

Conditions
ConditionsYield
With 1-hydroxy-pyrrolidine-2,5-dione; dimethylglyoxal at 20℃; Molecular sieve; Irradiation; Inert atmosphere;96%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

formic acid-(2-bromo-ethyl ester)
6065-67-4

formic acid-(2-bromo-ethyl ester)

Conditions
ConditionsYield
With Bromoform; (RCO2)2 at 20 - 60℃; for 3h; Irradiation;95%
With 1,4-Dioxane Dibromide In tetrachloromethane at 29.9℃; Rate constant; Thermodynamic data; Mechanism; ΔH(excit.), ΔS(excit.), ΔG(excit.), lg A; further temp., kinetics;
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

1-(4-ethylphenyl)-1-propanone
27465-51-6

1-(4-ethylphenyl)-1-propanone

piperidine hydrochloride
6091-44-7

piperidine hydrochloride

eperisone hydrochloride
56839-43-1

eperisone hydrochloride

Conditions
ConditionsYield
With hydrogenchloride at 90℃; for 6.5h;95%
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