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inquiryCAS Number 677-21-4 Product Name 3,3,3-trifluoropropene Synonyms 211-637-0; 3,3,3-trifluoroprop-1-ene; 3,3,3-trifluoropropylene; Difluoro(fluorosulfonyl)acetyl Fluoride; 1-propene, 3,3
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Product name: 3,3,3-Trifluoropropene CAS No.:677-21-4 Molecule Formula:C3H3F3 Molecule Weight:96.05 Purity: 99.0% Package: 200kg/drum Description:Colorless transparent liquefied gas Manufacture Standards:Enterprise Standard TESTI
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inquiryTrifluoropropene Basic information Product Name: Trifluoropropene Synonyms: 1,1,1-trifluoro-2-propene;1,1,1-Trifluoropropene;1-Propene, 3,3,3-trifluoro-;1-propene,3,3,3-trifluoro;1-propene,3,3,3-trifluoro-;3,3,3-Trifluoropropylene;FC-1243zf;pr
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Conditions | Yield |
---|---|
With hydrogen fluoride at 225 - 250℃; | 90% |
With hydrogen fluoride; activated by HF amorphous Zn/chromia catalyst at 200℃; under 760.051 Torr; for 15h; Inert atmosphere; | 100 %Chromat. |
With hydrogen fluoride; activated by HF amorphous Zn/chromia catalyst at 200℃; under 760.051 Torr; for 15h; Inert atmosphere; | 100 %Chromat. |
1,1,1-trifluoropropan-2-yl 1,1,2,2,3,3 ,4,4,4-nonafluorobutane-1-sulfonate
1,1,1-trifluoropropylene
Conditions | Yield |
---|---|
With potassium fluoride; 18-crown-6 ether In acetylacetone at 100 - 140℃; | 80% |
3,3,3-Trifluoropropanol
A
1,1,1,3-tetrafluoropropane
B
1,1,1-trifluoropropylene
Conditions | Yield |
---|---|
With cesium fluoride; sulphur hexafluoride; 1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene In dichloromethane-d2 at 20℃; for 0.5h; Inert atmosphere; UV-irradiation; Overall yield = 38%; | A 79% B n/a |
Conditions | Yield |
---|---|
With potassium fluoride; copper(l) iodide In N,N-dimethyl-formamide at 100℃; for 10h; | 56% |
With potassium fluoride; copper(l) iodide In N,N-dimethyl-formamide at 100 - 120℃; for 7h; |
2-bromo-3,3,3-trifluoropropene
A
1,1-difluoroallene
B
1,1,1-trifluoropropylene
Conditions | Yield |
---|---|
Stage #1: 2-bromo-3,3,3-trifluoropropene With n-butyllithium In diethyl ether at -78℃; for 0.25h; Stage #2: With methanol In diethyl ether at -78℃; | A 54% B 20% |
Stage #1: 2-bromo-3,3,3-trifluoropropene With sec.-butyllithium In diethyl ether; cyclohexane at -105℃; for 0.25h; Stage #2: With methanol In diethyl ether; cyclohexane at -105℃; | A 26 % Spectr. B 60 % Spectr. |
Stage #1: 2-bromo-3,3,3-trifluoropropene With n-butyllithium In diethyl ether; cyclohexane at -78℃; for 0.25h; Stage #2: With methanol In diethyl ether; cyclohexane at -78℃; | A 54 % Spectr. B 20 % Spectr. |
1,1,1,3,3,3-hexafluoro-2-methyl-propane
A
trifluoromethan
B
1,1,1-trifluoropropylene
C
1,1,3,3,3-pentafluoro-2-methyl-1-propene
Conditions | Yield |
---|---|
With nickel at 660℃; Product distribution / selectivity; | A 43.5% B 24.5 %Chromat. C 0% |
Conditions | Yield |
---|---|
With potassium hydroxide |
Conditions | Yield |
---|---|
With dichloromethane; alkali hydroxide | |
With alkaline solution | |
durch HCl-Abspaltung; |
Conditions | Yield |
---|---|
With potassium hydroxide | |
With potassium hydroxide |
Conditions | Yield |
---|---|
With antimony dichloride trifluoride; antimony(III) fluoride; 1,2-dichloro-ethane |
Conditions | Yield |
---|---|
at 490℃; |
Conditions | Yield |
---|---|
With sulfur tetrafluoride | |
With sulfur tetrafluoride at 130℃; for 8h; |
Conditions | Yield |
---|---|
(pyrolysis); |
propionic acid
trifluoroacetic acid
A
1,1,1-trifluoropropylene
B
1,1,1,4,4,4-hexafluorobutane
C
1,1,1,4,4,4-hexafluoro-2-(trifluoromethyl)butane
D
1,1,1,6,6,6-hexafluoro-3-trifluoromethyl-hexane
Conditions | Yield |
---|---|
With sodium proprionate In water (electrolysis); |
1,1,1-trifluoro-3-iodopropane
perfluorobis(methyl)propylmethyl carbanion
A
1,1,1-trifluoropropylene
B
1,1,1,2,2,3,3,5,5,5-decafluoro-4-trifluoromethyl-pentane
1,1,1-trifluoro-3-iodopropane
A
1,1,1-trifluoropropylene
B
perfluoro-2-methyl-2-pentene
C
1,1,1,2,2,3,3,5,5,5-decafluoro-4-trifluoromethyl-pentane
Conditions | Yield |
---|---|
With perfluoro-4-methyl-2-pentene; cesium fluoride In N,N-dimethyl-formamide at 60℃; for 18h; |
ethene
iodotrifluoromethane
A
1,1,1-trifluoro-3-iodopropane
B
vinyliodide
C
1,1,1-trifluoropropylene
D
acetylene
Conditions | Yield |
---|---|
under 820 Torr; Quantum yield; Irradiation; CO2 laser induced telomerization; |
perfluoro-4-methyl-2-pentene
A
1,1,1-trifluoropropylene
B
perfluoro-2-methyl-2-pentene
C
1,1,1,2,2,3,3,5,5,5-decafluoro-4-trifluoromethyl-pentane
Conditions | Yield |
---|---|
With 1,1,1-trifluoro-3-iodopropane; cesium fluoride In N,N-dimethyl-formamide at 60℃; for 18h; |
Conditions | Yield |
---|---|
Rate constant; |
ethene
trifluoroacetic anhydride
A
1,1,1-trifluoropropane
B
1,1,1-trifluoropropylene
C
1,1,1,6,6,6-hexafluorohexane
D
1,1,1,8,8,8-Hexafluoro-octane
Conditions | Yield |
---|---|
at 26.9℃; under 50.3 Torr; Irradiation; Further byproducts given; | A 9.5 % Chromat. B 9.8 % Chromat. C 71.0 % Chromat. D 7.8 % Chromat. |
at 26.9℃; under 50.3 Torr; Irradiation; Further byproducts given; | A 8.2 % Chromat. B 8.0 % Chromat. C 83.0 % Chromat. D 0.4 % Chromat. |
1,1,1-trifluoro-3-iodopropane
A
1,1,1-trifluoropropylene
B
1,1,1,6,6,6-hexafluorohexane
Conditions | Yield |
---|---|
With silver at -73.1 - 76.9℃; Thermodynamic data; activation energy: E(a); |
trifluoromethyl radical
3,3,3-trifluoro-propyl
A
1,1,1-trifluoropropane
B
1,1,1-trifluoropropylene
C
1,1,1,4,4,4-hexafluorobutane
D
1,1,1,6,6,6-hexafluorohexane
Conditions | Yield |
---|---|
disproportionation-combination rate constant ratio for gas-phase; comparison of substituent effects; |
3,3,3-trifluoro-propyl
A
1,1,1-trifluoropropane
B
1,1,1-trifluoropropylene
C
1,1,1,4,4,4-hexafluorobutane
D
1,1,1,6,6,6-hexafluorohexane
Conditions | Yield |
---|---|
disproportionation-combination rate constant ratio for gas-phase; comparison of substituent effects; |
3,3,3-trichloro-1-propene
antimony(III) fluoride
1,2-dichloro-ethane
1,1,1-trifluoropropylene
ethyl chlorooximidoacetate
1,1,1-trifluoropropylene
ethyl 5-(trifluoromethyl)-4,5-dihydroisoxazole-3-carboxylate
Conditions | Yield |
---|---|
With sodium hydrogencarbonate In ethyl acetate at -65 - 25℃; for 72h; Inert atmosphere; | 100% |
With sodium hydrogencarbonate In ethyl acetate at -78 - 20℃; for 60h; | 3.2 g |
Conditions | Yield |
---|---|
With pyridine; sodium metabisulfite; osmium(VIII) oxide multistep reaction; stoichiometric and catalytic oxidation of electron-poor olefins with OsO4; other fluoroolefins; | 99% |
With pyridine; sodium metabisulfite; osmium(VIII) oxide 1) n-hexane, r.t., 1 h, 2) H2O, pyridine, 24 h; Yield given. Multistep reaction; | |
With pyridine; potassium carbonate; sodium sulfite; potassium hexacyanoferrate(III); K2 1) H2O, t-BuOH, 24 h, 2) 1 h; Yield given. Multistep reaction; |
tetrachloromethane
1,1,1-trifluoropropylene
1,1,1,3-tetrachloro-4,4,4-trifluorobutane
Conditions | Yield |
---|---|
With phosphoric acid tributyl ester; iron at 110℃; for 3h; | 98.5% |
With 2,2'-azobis(isobutyronitrile); 4-fluoroaniline; copper(I) bromide at 60℃; for 4h; Reagent/catalyst; Temperature; Autoclave; Inert atmosphere; | 94.2% |
iron(III) chloride; phosphoric acid tributyl ester; iron at 80 - 100℃; under 2311.54 Torr; | 90% |
1,1,1-trifluoropropylene
Conditions | Yield |
---|---|
With antimony; iodine; iodine pentafluoride; sodium iodide at 15℃; under 2250.23 Torr; Temperature; Pressure; Inert atmosphere; Large scale; | 98.2% |
With iodine monofluoride |
Conditions | Yield |
---|---|
hydridocarbonyltris(triphenylphosphine)rhodium(I) In neat (no solvent) Kinetics; borazine and the propene (ratio 8.4:1) reacted in the presence of a catalytic amt. Rh-complex at room temp. for 1 h; vacuum line fractionation of mixt. through a 0, -45, -110 and -196°C trap series, product found in the -45°C trap, elem. anal.; | 98% |
1,1,1-trifluoropropylene
Methyl thioglycolate
methyl 2-(3,3,3-trifluoropropylthio)acetate
Conditions | Yield |
---|---|
2,2’-azobis(4-methoxy-2,4-dimethyl)valeronitrile at -78 - 20℃; for 20h; Product distribution / selectivity; | 98% |
Conditions | Yield |
---|---|
With bromine at 25℃; for 1.5h; Irradiation; | 96% |
With bromine Irradiation; | 84% |
With bromine |
Phenylselenyl chloride
1,1,1-trifluoropropylene
1-(trifluoromethyl)-2-chloroethyl phenyl selenide
Conditions | Yield |
---|---|
In dichloromethane 1) dry ice/acetone, 2) 60 deg C, overnight; | 95% |
1,1,1-trifluoropropylene
N-benzyl-N-(methoxymethyl)-N-[(trimethylsilyl)methyl]amine
Conditions | Yield |
---|---|
With trifluoroacetic acid In dichloromethane at -30 - 20℃; Inert atmosphere; | 95% |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 200℃; under 3750.38 Torr; | 93.2% |
Triethoxysilane
1,1,1-trifluoropropylene
triethoxy-(3,3,3-trifluoro-propyl)-silane
Conditions | Yield |
---|---|
With platinum immobilized on polystyrene functionalized with polyethylene glycol and pyridine groups (N/Pt atom ratio of 6:1) at 60℃; under 750.075 Torr; for 6h; Sealed vessel; | 92.5% |
RhCl(PPh3)3 at 120℃; for 24h; | 85% |
Conditions | Yield |
---|---|
Stage #1: carbon monoxide With hydroxo(1,5-cyclooctadiene)rhodium (I) dimer; hydrogen; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In N,N-dimethyl-formamide at 100℃; under 380.026 Torr; for 1h; Stage #2: 1,1,1-trifluoropropylene In N,N-dimethyl-formamide at 100℃; under 190.013 - 570.038 Torr; for 18h; | 92% |
With dichloro( 1,5-cyclooctadiene)platinum(ll); hydrogen; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; tin(ll) chloride In toluene at 80℃; under 72007.2 Torr; for 48h; Inert atmosphere; Autoclave; Schlenk technique; regioselective reaction; |
2,2,2-trifluoroethanol
1,1,1-trifluoropropylene
1,1-difluoro-3-(2,2,2-trifluoro-ethoxy)-propene
Conditions | Yield |
---|---|
With sodium hydroxide In 1-methyl-pyrrolidin-2-one at 60℃; under 1500.15 Torr; Autoclave; | 91.8% |
Conditions | Yield |
---|---|
With potassium hydroxide In dimethyl sulfoxide at 170℃; under 5250.53 Torr; | 91.2% |
Conditions | Yield |
---|---|
Stage #1: 1,1,1-trifluoropropylene With N-Bromosuccinimide; sulfuric acid; acetic acid at 80 - 100℃; for 4h; Stage #2: In methanol at 40℃; for 9h; | 90.2% |
With water; hypobromous acid at -10℃; | |
With mercury(II) diacetate; water; bromine |
1,1,1-trifluoropropylene
tris(trifluoromethyl)phosphine
A
1,1,1-trifluoropropane
B
tetrakis(trifluoromethyl)diphosphine
Conditions | Yield |
---|---|
Irradiation; | A 1% B 4% C 90% |
1,1,1-trifluoropropylene
carbon monoxide
A
4,4,4-trifluorobutanal
B
3,3,3-trifluoro-2-methylpropionaldehyde
Conditions | Yield |
---|---|
With hydrogen; carbonylhydridetris(triphenylphosphine)rhodium(I) In toluene at 80℃; for 15h; in an autoclave; | A 2.6% B 90% |
Stage #1: carbon monoxide With hydroxo(1,5-cyclooctadiene)rhodium (I) dimer; hydrogen; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In N,N-dimethyl-formamide at 80℃; under 190.013 - 570.038 Torr; for 1h; Stage #2: 1,1,1-trifluoropropylene In N,N-dimethyl-formamide at 80℃; for 15h; Solvent; Reagent/catalyst; Pressure; Temperature; | A 89% B 1.2% |
With hydrogen; dicobalt octacarbonyl 1.) toluene, room temperature, 130 atm, 2.) 100 deg C, 20 h; Yield given. Multistep reaction. Yields of byproduct given; |
Dichloromethylsilane
1,1,1-trifluoropropylene
(α-trifluoromethylethyl)dichloromethylsilane
Conditions | Yield |
---|---|
With bis(benzonitrile)palladium(II) dichloride; triphenylphosphine at 100℃; for 14h; | 88% |
1,1,1-trifluoropropylene
1,1-difluoro-3-(dimethylphenylsilyl)propene
Conditions | Yield |
---|---|
In benzene-d6 at 22℃; for 0.25h; Temperature; Solvent; Inert atmosphere; Schlenk technique; | 88% |
1,1,1-trifluoropropylene
Conditions | Yield |
---|---|
In pentane byproducts: CO; (Ar); a soln. of Ni complex treated with ligand, stirred for 30 min; evapd. (vac.), washed (cold pentane); elem. anal.; | A 87% B 0% |
1,1,1-trifluoropropylene
benzenesulfenyl chloride
1-(trifluoromethyl)-2-chloroethyl phenyl sulfide
Conditions | Yield |
---|---|
In dichloromethane 1) dry ice/acetone, 2) 60 deg C, overnight; | 86% |
In dichloromethane at 70℃; | 86% |
In chloroform at 20℃; sealed glass tube; | 11.31 g |
Conditions | Yield |
---|---|
Stage #1: o-iodo-methyl-benzoic acid With norbornene; tetrabutylammonium acetate; palladium diacetate; XPhos In N,N-dimethyl-formamide at 20℃; for 0.166667h; Inert atmosphere; Stage #2: 1,1,1-trifluoropropylene In N,N-dimethyl-formamide at 115℃; under 5171.62 Torr; for 2h; Inert atmosphere; Flow reactor; | 86% |
Dichloromethylsilane
1,1,1-trifluoropropylene
methyl(3,3,3-trifluoropropyl)dichlorosilane
Conditions | Yield |
---|---|
RhCl(PPh3)3 at 120℃; for 12h; | 85% |
Irradiation.unter Einwirkung von UV-Licht; | |
With platinum at 250℃; |
1,1,1-trifluoropropylene
1,1,1,2,2-pentamethyl-2-phenyldisilane
1,1-difluoro-3-(dimethylphenylsilyl)propene
Conditions | Yield |
---|---|
With tetrabutyl ammonium fluoride In tetrahydrofuran for 6h; Ambient temperature; | 85% |
1,1,1-trifluoropropylene
1,2-diphenyltetramethyldisilane
1,1-difluoro-3-(dimethylphenylsilyl)propene
Conditions | Yield |
---|---|
With tetrabutyl ammonium fluoride In N,N,N,N,N,N-hexamethylphosphoric triamide | 85% |
1,1,1-trifluoropropylene
tert-butyl 4-phenylbutanoate
Conditions | Yield |
---|---|
With n-butyllithium; diisopropylamine In tetrahydrofuran at -78℃; | 85% |
1,1,1-trifluoropropylene
(2,4-bis(2,6-diisopropylphenylimino)pentan-3-ide-.kappa2N,N')aluminum(I)
Conditions | Yield |
---|---|
In benzene-d6 at 24.84℃; Glovebox; Schlenk technique; Inert atmosphere; | 85% |
Conditions | Yield |
---|---|
In benzene-d6 at 79.84℃; for 5h; Glovebox; Schlenk technique; Inert atmosphere; | 85% |
1,1,1-trifluoropropylene
borazine
A
2-(trifluoropropyl)borazine
B
2,4-bis-(trifluoropropyl)borazine
C
2,4,6-tris-(trifluoropropyl)borazine
Conditions | Yield |
---|---|
hydridocarbonyltris(triphenylphosphine)rhodium(I) In neat (no solvent) Kinetics; borazine and excess of the propene (ratio 1:2.9) reacted in the presence of a catalytic amt. Rh-complex at room temp. for 16 h, resulting product was a solid with a moist appearance; vacuum line fractionation of mixt. through a -78 and -196°C traps, 2-substd. and 2,4-products found in the -78°C trap; extn. (CH2Cl2) of solid residue, evapn. (ac.), solid sublimed at 80°C (2,4,6-product), elem. anal.; | A 14% B 84% C n/a |
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