Trifluoropropene supplier | CasNO.677-21-4

Name
Trifluoropropene
EINECS 211-637-0
CAS No. 677-21-4
Article Data68
CAS DataBase
Density 1.072 g/cm³
Solubility
Melting Point
Formula C₃H₃F₃
Boiling Point -18 °C
Molecular Weight 96.052
Flash Point
Transport Information UN 1954
Appearance gas with no known odor
Safety 16-38
Risk Codes 11
Molecular Structure
Hazard Symbols F
Synonyms Propene,3,3,3-trifluoro- (6CI,7CI,8CI);(Trifluoromethyl)ethene;(Trifluoromethyl)ethylene;1,1,1-Trifluoro-2-propene;1,1,1-Trifluoropropene;3,3,3-Trifluoro-1-propene;3,3,3-Trifluoropropene;3,3,3-Trifluoropropylene;HFC 1243zf;HFO 1243zf;R 1234zf;R 1243;R 1243b;
PSA 0.00000
LogP 2.08390

Synthetic route

: 1070-78-6
1,1,1,3-tetrachloropropane

: 677-21-4
1,1,1-trifluoropropylene

Conditions

Conditions	Yield
With hydrogen fluoride at 225 - 250℃;	90%
With hydrogen fluoride; activated by HF amorphous Zn/chromia catalyst at 200℃; under 760.051 Torr; for 15h; Inert atmosphere;	100 %Chromat.
With hydrogen fluoride; activated by HF amorphous Zn/chromia catalyst at 200℃; under 760.051 Torr; for 15h; Inert atmosphere;	100 %Chromat.

: 118334-94-4
1,1,1-trifluoropropan-2-yl 1,1,2,2,3,3 ,4,4,4-nonafluorobutane-1-sulfonate

: 677-21-4
1,1,1-trifluoropropylene

Conditions

Conditions	Yield
With potassium fluoride; 18-crown-6 ether In acetylacetone at 100 - 140℃;	80%

: 2240-88-2
3,3,3-Trifluoropropanol

A: 460-36-6
1,1,1,3-tetrafluoropropane

B: 677-21-4
1,1,1-trifluoropropylene

Conditions

Conditions	Yield
With cesium fluoride; sulphur hexafluoride; 1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene In dichloromethane-d2 at 20℃; for 0.5h; Inert atmosphere; UV-irradiation; Overall yield = 38%;	A 79% B n/a

: 593-60-2
Vinyl bromide

: 1514-87-0
metyhyl chlorodifluoroacetate

: 677-21-4
1,1,1-trifluoropropylene

Conditions

Conditions	Yield
With potassium fluoride; copper(l) iodide In N,N-dimethyl-formamide at 100℃; for 10h;	56%
With potassium fluoride; copper(l) iodide In N,N-dimethyl-formamide at 100 - 120℃; for 7h;

: 1514-82-5
2-bromo-3,3,3-trifluoropropene

A: 430-64-8
1,1-difluoroallene

B: 677-21-4
1,1,1-trifluoropropylene

Conditions

Conditions	Yield
Stage #1: 2-bromo-3,3,3-trifluoropropene With n-butyllithium In diethyl ether at -78℃; for 0.25h; Stage #2: With methanol In diethyl ether at -78℃;	A 54% B 20%
Stage #1: 2-bromo-3,3,3-trifluoropropene With sec.-butyllithium In diethyl ether; cyclohexane at -105℃; for 0.25h; Stage #2: With methanol In diethyl ether; cyclohexane at -105℃;	A 26 % Spectr. B 60 % Spectr.
Stage #1: 2-bromo-3,3,3-trifluoropropene With n-butyllithium In diethyl ether; cyclohexane at -78℃; for 0.25h; Stage #2: With methanol In diethyl ether; cyclohexane at -78℃;	A 54 % Spectr. B 20 % Spectr.

: 382-09-2
1,1,1,3,3,3-hexafluoro-2-methyl-propane

A: 75-46-7
trifluoromethan

B: 677-21-4
1,1,1-trifluoropropylene

C: 2253-00-1
1,1,3,3,3-pentafluoro-2-methyl-1-propene

Conditions

Conditions	Yield
With nickel at 660℃; Product distribution / selectivity;	A 43.5% B 24.5 %Chromat. C 0%

...Expand

: 460-37-7
1,1,1-trifluoro-3-iodopropane

: 677-21-4
1,1,1-trifluoropropylene

Conditions

Conditions	Yield
With potassium hydroxide

: 460-35-5
3-chloro-1,1,1-trifluoropropane

: 677-21-4
1,1,1-trifluoropropylene

Conditions

Conditions	Yield
With dichloromethane; alkali hydroxide
With alkaline solution
durch HCl-Abspaltung;

: 460-32-2
3-bromo-1,1,1-trifluoropropane

: 677-21-4
1,1,1-trifluoropropylene

Conditions

Conditions	Yield
With potassium hydroxide
With potassium hydroxide

: 2233-00-3
3,3,3-trichloro-1-propene

: 677-21-4
1,1,1-trifluoropropylene

Conditions

Conditions	Yield
With antimony dichloride trifluoride; antimony(III) fluoride; 1,2-dichloro-ethane

: 400-37-3
acetic acid-(β,β,β-trifluoro-isopropyl ester)

: 677-21-4
1,1,1-trifluoropropylene

Conditions

Conditions	Yield
at 490℃;

: 79-10-7
acrylic acid

: 677-21-4
1,1,1-trifluoropropylene

Conditions

Conditions	Yield
With sulfur tetrafluoride
With sulfur tetrafluoride at 130℃; for 8h;

: 815-37-2
chloro-(2,2,2-trifluoro-1-hydroxymethyl-ethyl)-mercury

: 677-21-4
1,1,1-trifluoropropylene

Conditions

Conditions	Yield
(pyrolysis);

: 802294-64-0
propionic acid

: 76-05-1
trifluoroacetic acid

A: 677-21-4
1,1,1-trifluoropropylene

B: 407-59-0
1,1,1,4,4,4-hexafluorobutane

C: 367-53-3
1,1,1,4,4,4-hexafluoro-2-(trifluoromethyl)butane

D: 40932-59-0
1,1,1,6,6,6-hexafluoro-3-trifluoromethyl-hexane

Conditions

Conditions	Yield
With sodium proprionate In water (electrolysis);

...Expand

: 460-37-7
1,1,1-trifluoro-3-iodopropane

: 80318-41-8
perfluorobis(methyl)propylmethyl carbanion

A: 677-21-4
1,1,1-trifluoropropylene

B: 30320-28-6
1,1,1,2,2,3,3,5,5,5-decafluoro-4-trifluoromethyl-pentane

...Expand

: 460-37-7
1,1,1-trifluoro-3-iodopropane

A: 677-21-4
1,1,1-trifluoropropylene

B: 359-72-8
perfluoro-2-methyl-2-pentene

C: 30320-28-6
1,1,1,2,2,3,3,5,5,5-decafluoro-4-trifluoromethyl-pentane

Conditions

Conditions	Yield
With perfluoro-4-methyl-2-pentene; cesium fluoride In N,N-dimethyl-formamide at 60℃; for 18h;

...Expand

: 74-85-1
ethene

: 2314-97-8
iodotrifluoromethane

A: 460-37-7
1,1,1-trifluoro-3-iodopropane

B: 593-66-8
vinyliodide

C: 677-21-4
1,1,1-trifluoropropylene

D: 74-86-2
acetylene

Conditions

Conditions	Yield
under 820 Torr; Quantum yield; Irradiation; CO2 laser induced telomerization;

...Expand

: 2070-70-4
perfluoro-4-methyl-2-pentene

A: 677-21-4
1,1,1-trifluoropropylene

B: 359-72-8
perfluoro-2-methyl-2-pentene

C: 30320-28-6
1,1,1,2,2,3,3,5,5,5-decafluoro-4-trifluoromethyl-pentane

Conditions

Conditions	Yield
With 1,1,1-trifluoro-3-iodopropane; cesium fluoride In N,N-dimethyl-formamide at 60℃; for 18h;

...Expand

: C10H10F3

A: 677-21-4
1,1,1-trifluoropropylene

B: 2154-56-5
benzyl radical

Conditions

Conditions	Yield
Rate constant;

: 74-85-1
ethene

: 407-25-0
trifluoroacetic anhydride

A: 421-07-8
1,1,1-trifluoropropane

B: 677-21-4
1,1,1-trifluoropropylene

C: 3834-39-7
1,1,1,6,6,6-hexafluorohexane

D: 4248-82-2
1,1,1,8,8,8-Hexafluoro-octane

Conditions

Conditions	Yield
at 26.9℃; under 50.3 Torr; Irradiation; Further byproducts given;	A 9.5 % Chromat. B 9.8 % Chromat. C 71.0 % Chromat. D 7.8 % Chromat.
at 26.9℃; under 50.3 Torr; Irradiation; Further byproducts given;	A 8.2 % Chromat. B 8.0 % Chromat. C 83.0 % Chromat. D 0.4 % Chromat.

...Expand

: 460-37-7
1,1,1-trifluoro-3-iodopropane

A: 677-21-4
1,1,1-trifluoropropylene

B: 3834-39-7
1,1,1,6,6,6-hexafluorohexane

Conditions

Conditions	Yield
With silver at -73.1 - 76.9℃; Thermodynamic data; activation energy: E(a);

: 2264-21-3
trifluoromethyl radical

: 2980-46-3
3,3,3-trifluoro-propyl

A: 421-07-8
1,1,1-trifluoropropane

B: 677-21-4
1,1,1-trifluoropropylene

C: 407-59-0
1,1,1,4,4,4-hexafluorobutane

D: 3834-39-7
1,1,1,6,6,6-hexafluorohexane

Conditions

Conditions	Yield
disproportionation-combination rate constant ratio for gas-phase; comparison of substituent effects;

...Expand

: 2980-46-3
3,3,3-trifluoro-propyl

A: 421-07-8
1,1,1-trifluoropropane

B: 677-21-4
1,1,1-trifluoropropylene

C: 407-59-0
1,1,1,4,4,4-hexafluorobutane

D: 3834-39-7
1,1,1,6,6,6-hexafluorohexane

Conditions

Conditions	Yield
disproportionation-combination rate constant ratio for gas-phase; comparison of substituent effects;

...Expand

: 79-10-7
acrylic acid

sulfur tetrafluoride: sulfur tetrafluoride

: 677-21-4
1,1,1-trifluoropropylene

: 2233-00-3
3,3,3-trichloro-1-propene

: 7783-56-4
antimony(III) fluoride

: 107-06-2
1,2-dichloro-ethane

antimony dichloride trifluoride: antimony dichloride trifluoride

: 677-21-4
1,1,1-trifluoropropylene

...Expand

: 460-37-7
1,1,1-trifluoro-3-iodopropane

ethanolic KOH-solution: ethanolic KOH-solution

: 677-21-4
1,1,1-trifluoropropylene

: 460-35-5
3-chloro-1,1,1-trifluoropropane

ethanolic KOH-solution: ethanolic KOH-solution

: 677-21-4
1,1,1-trifluoropropylene

: 460-35-5
3-chloro-1,1,1-trifluoropropane

KOH-solution: KOH-solution

: 677-21-4
1,1,1-trifluoropropylene

: 460-37-7
1,1,1-trifluoro-3-iodopropane

potassium hydroxide: potassium hydroxide

: 677-21-4
1,1,1-trifluoropropylene

: 95080-93-6
ethyl chlorooximidoacetate

: 677-21-4
1,1,1-trifluoropropylene

: 1432511-65-3
ethyl 5-(trifluoromethyl)-4,5-dihydroisoxazole-3-carboxylate

Conditions

Conditions	Yield
With sodium hydrogencarbonate In ethyl acetate at -65 - 25℃; for 72h; Inert atmosphere;	100%
With sodium hydrogencarbonate In ethyl acetate at -78 - 20℃; for 60h;	3.2 g

: 677-21-4
1,1,1-trifluoropropylene

: 431-39-0
(rac)-3,3,3-trifluoro-1,2-propanediol

Conditions

Conditions	Yield
With pyridine; sodium metabisulfite; osmium(VIII) oxide multistep reaction; stoichiometric and catalytic oxidation of electron-poor olefins with OsO4; other fluoroolefins;	99%
With pyridine; sodium metabisulfite; osmium(VIII) oxide 1) n-hexane, r.t., 1 h, 2) H2O, pyridine, 24 h; Yield given. Multistep reaction;
With pyridine; potassium carbonate; sodium sulfite; potassium hexacyanoferrate(III); K2 1) H2O, t-BuOH, 24 h, 2) 1 h; Yield given. Multistep reaction;

: 56-23-5
tetrachloromethane

: 677-21-4
1,1,1-trifluoropropylene

: 129612-89-1
1,1,1,3-tetrachloro-4,4,4-trifluorobutane

Conditions

Conditions	Yield
With phosphoric acid tributyl ester; iron at 110℃; for 3h;	98.5%
With 2,2'-azobis(isobutyronitrile); 4-fluoroaniline; copper(I) bromide at 60℃; for 4h; Reagent/catalyst; Temperature; Autoclave; Inert atmosphere;	94.2%
iron(III) chloride; phosphoric acid tributyl ester; iron at 80 - 100℃; under 2311.54 Torr;	90%

: 677-21-4
1,1,1-trifluoropropylene

: 1,3,3,3-tetrafluoro-2-iodo-propane

Conditions

Conditions	Yield
With antimony; iodine; iodine pentafluoride; sodium iodide at 15℃; under 2250.23 Torr; Temperature; Pressure; Inert atmosphere; Large scale;	98.2%
With iodine monofluoride

: 677-21-4
1,1,1-trifluoropropylene

: 6569-51-3
borazine

: 155862-04-7
2-(trifluoropropyl)borazine

Conditions

Conditions	Yield
hydridocarbonyltris(triphenylphosphine)rhodium(I) In neat (no solvent) Kinetics; borazine and the propene (ratio 8.4:1) reacted in the presence of a catalytic amt. Rh-complex at room temp. for 1 h; vacuum line fractionation of mixt. through a 0, -45, -110 and -196°C trap series, product found in the -45°C trap, elem. anal.;	98%

: 677-21-4
1,1,1-trifluoropropylene

: 2365-48-2
Methyl thioglycolate

: 1086277-19-1
methyl 2-(3,3,3-trifluoropropylthio)acetate

Conditions

Conditions	Yield
2,2’-azobis(4-methoxy-2,4-dimethyl)valeronitrile at -78 - 20℃; for 20h; Product distribution / selectivity;	98%

: 677-21-4
1,1,1-trifluoropropylene

: 431-21-0
1,2-Dibromo-3,3,3-trifluoropropane

Conditions

Conditions	Yield
With bromine at 25℃; for 1.5h; Irradiation;	96%
With bromine Irradiation;	84%
With bromine

: 5707-04-0
Phenylselenyl chloride

: 677-21-4
1,1,1-trifluoropropylene

: 73194-30-6
1-(trifluoromethyl)-2-chloroethyl phenyl selenide

Conditions

Conditions	Yield
In dichloromethane 1) dry ice/acetone, 2) 60 deg C, overnight;	95%

: 677-21-4
1,1,1-trifluoropropylene

: 93102-05-7
N-benzyl-N-(methoxymethyl)-N-[(trimethylsilyl)methyl]amine

: 1-benzyl-3-(trifluoromethyl)pyrrolidine

Conditions

Conditions	Yield
With trifluoroacetic acid In dichloromethane at -30 - 20℃; Inert atmosphere;	95%

: 67-56-1
methanol

: 677-21-4
1,1,1-trifluoropropylene

: 33119-49-2
1,1-difluoro-3-methoxy-propene

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 200℃; under 3750.38 Torr;	93.2%

: 998-30-1
Triethoxysilane

: 677-21-4
1,1,1-trifluoropropylene

: 681-97-0
triethoxy-(3,3,3-trifluoro-propyl)-silane

Conditions

Conditions	Yield
With platinum immobilized on polystyrene functionalized with polyethylene glycol and pyridine groups (N/Pt atom ratio of 6:1) at 60℃; under 750.075 Torr; for 6h; Sealed vessel;	92.5%
RhCl(PPh3)3 at 120℃; for 24h;	85%

: 677-21-4
1,1,1-trifluoropropylene

: 201230-82-2
carbon monoxide

: 406-87-1
4,4,4-trifluorobutanal

Conditions

Conditions	Yield
Stage #1: carbon monoxide With hydroxo(1,5-cyclooctadiene)rhodium (I) dimer; hydrogen; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In N,N-dimethyl-formamide at 100℃; under 380.026 Torr; for 1h; Stage #2: 1,1,1-trifluoropropylene In N,N-dimethyl-formamide at 100℃; under 190.013 - 570.038 Torr; for 18h;	92%
With dichloro( 1,5-cyclooctadiene)platinum(ll); hydrogen; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; tin(ll) chloride In toluene at 80℃; under 72007.2 Torr; for 48h; Inert atmosphere; Autoclave; Schlenk technique; regioselective reaction;

: 75-89-8
2,2,2-trifluoroethanol

: 677-21-4
1,1,1-trifluoropropylene

: 2145-58-6
1,1-difluoro-3-(2,2,2-trifluoro-ethoxy)-propene

Conditions

Conditions	Yield
With sodium hydroxide In 1-methyl-pyrrolidin-2-one at 60℃; under 1500.15 Torr; Autoclave;	91.8%

: 64-17-5
ethanol

: 677-21-4
1,1,1-trifluoropropylene

: 1993-84-6
3-ethoxy-1,1-difluoro-propene

Conditions

Conditions	Yield
With potassium hydroxide In dimethyl sulfoxide at 170℃; under 5250.53 Torr;	91.2%

: 677-21-4
1,1,1-trifluoropropylene

: 311-86-4
2-bromo-1,1,1-trifluoropropan-3-ol

Conditions

Conditions	Yield
Stage #1: 1,1,1-trifluoropropylene With N-Bromosuccinimide; sulfuric acid; acetic acid at 80 - 100℃; for 4h; Stage #2: In methanol at 40℃; for 9h;	90.2%
With water; hypobromous acid at -10℃;
With mercury(II) diacetate; water; bromine

: 677-21-4
1,1,1-trifluoropropylene

: 432-04-2
tris(trifluoromethyl)phosphine

A: 421-07-8
1,1,1-trifluoropropane

B: 2714-60-5
tetrakis(trifluoromethyl)diphosphine

C: bis(trifluoromethyl)-3,3,3-trifluoropropylphosphine

Conditions

Conditions	Yield
Irradiation;	A 1% B 4% C 90%

...Expand

: 677-21-4
1,1,1-trifluoropropylene

: 201230-82-2
carbon monoxide

A: 406-87-1
4,4,4-trifluorobutanal

B: 58928-28-2
3,3,3-trifluoro-2-methylpropionaldehyde

Conditions

Conditions	Yield
With hydrogen; carbonylhydridetris(triphenylphosphine)rhodium(I) In toluene at 80℃; for 15h; in an autoclave;	A 2.6% B 90%
Stage #1: carbon monoxide With hydroxo(1,5-cyclooctadiene)rhodium (I) dimer; hydrogen; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In N,N-dimethyl-formamide at 80℃; under 190.013 - 570.038 Torr; for 1h; Stage #2: 1,1,1-trifluoropropylene In N,N-dimethyl-formamide at 80℃; for 15h; Solvent; Reagent/catalyst; Pressure; Temperature;	A 89% B 1.2%
With hydrogen; dicobalt octacarbonyl 1.) toluene, room temperature, 130 atm, 2.) 100 deg C, 20 h; Yield given. Multistep reaction. Yields of byproduct given;

...Expand

: 75-54-7
Dichloromethylsilane

: 677-21-4
1,1,1-trifluoropropylene

: 84442-91-1
(α-trifluoromethylethyl)dichloromethylsilane

Conditions

Conditions	Yield
With bis(benzonitrile)palladium(II) dichloride; triphenylphosphine at 100℃; for 14h;	88%

: 677-21-4
1,1,1-trifluoropropylene

: (x)C4H8O*C8H11LiSi

: 88257-92-5
1,1-difluoro-3-(dimethylphenylsilyl)propene

Conditions

Conditions	Yield
In benzene-d6 at 22℃; for 0.25h; Temperature; Solvent; Inert atmosphere; Schlenk technique;	88%

: [Ni(1,3-di-tert-butyl-imidazolin-2-ylidene)(CO)2]

: 677-21-4
1,1,1-trifluoropropylene

A: Ni(CO)(trifluoropropene)(C3H2N2(C(CH3)3)2)

B: Ni(trifluoropropene)2(C3H2N2(C(CH3)3)2)

Conditions

Conditions	Yield
In pentane byproducts: CO; (Ar); a soln. of Ni complex treated with ligand, stirred for 30 min; evapd. (vac.), washed (cold pentane); elem. anal.;	A 87% B 0%

...Expand

: 677-21-4
1,1,1-trifluoropropylene

: 931-59-9
benzenesulfenyl chloride

: 73194-31-7
1-(trifluoromethyl)-2-chloroethyl phenyl sulfide

Conditions

Conditions	Yield
In dichloromethane 1) dry ice/acetone, 2) 60 deg C, overnight;	86%
In dichloromethane at 70℃;	86%
In chloroform at 20℃; sealed glass tube;	11.31 g

: 677-21-4
1,1,1-trifluoropropylene

: 610-97-9
o-iodo-methyl-benzoic acid

: dimethyl 2'-[(1E)-3,3,3-trifluoroprop-1-en-1-yl]biphenyl-2,3'-dicarboxylate

Conditions

Conditions	Yield
Stage #1: o-iodo-methyl-benzoic acid With norbornene; tetrabutylammonium acetate; palladium diacetate; XPhos In N,N-dimethyl-formamide at 20℃; for 0.166667h; Inert atmosphere; Stage #2: 1,1,1-trifluoropropylene In N,N-dimethyl-formamide at 115℃; under 5171.62 Torr; for 2h; Inert atmosphere; Flow reactor;	86%

: 75-54-7
Dichloromethylsilane

: 677-21-4
1,1,1-trifluoropropylene

: 675-62-7
methyl(3,3,3-trifluoropropyl)dichlorosilane

Conditions

Conditions	Yield
RhCl(PPh3)3 at 120℃; for 12h;	85%
Irradiation.unter Einwirkung von UV-Licht;
With platinum at 250℃;

: 677-21-4
1,1,1-trifluoropropylene

: 1130-17-2
1,1,1,2,2-pentamethyl-2-phenyldisilane

: 88257-92-5
1,1-difluoro-3-(dimethylphenylsilyl)propene

Conditions

Conditions	Yield
With tetrabutyl ammonium fluoride In tetrahydrofuran for 6h; Ambient temperature;	85%

: 677-21-4
1,1,1-trifluoropropylene

: 1145-98-8
1,2-diphenyltetramethyldisilane

: 88257-92-5
1,1-difluoro-3-(dimethylphenylsilyl)propene

Conditions

Conditions	Yield
With tetrabutyl ammonium fluoride In N,N,N,N,N,N-hexamethylphosphoric triamide	85%

: 677-21-4
1,1,1-trifluoropropylene

: 16537-11-4
tert-butyl 4-phenylbutanoate

: t-butyl 2-phenylethyl-5,5-difluoro-4-pentenoate

Conditions

Conditions	Yield
With n-butyllithium; diisopropylamine In tetrahydrofuran at -78℃;	85%

: 677-21-4
1,1,1-trifluoropropylene

: 325465-25-6
(2,4-bis(2,6-diisopropylphenylimino)pentan-3-ide-.kappa2N,N')aluminum(I)

: C32H44AlF3N2

Conditions

Conditions	Yield
In benzene-d6 at 24.84℃; Glovebox; Schlenk technique; Inert atmosphere;	85%

: 677-21-4
1,1,1-trifluoropropylene

: C36H51AlN2

: C32H44AlF3N2

Conditions

Conditions	Yield
In benzene-d6 at 79.84℃; for 5h; Glovebox; Schlenk technique; Inert atmosphere;	85%

: 677-21-4
1,1,1-trifluoropropylene

: 6569-51-3
borazine

A: 155862-04-7
2-(trifluoropropyl)borazine

B: 155862-05-8
2,4-bis-(trifluoropropyl)borazine

C: 155862-06-9
2,4,6-tris-(trifluoropropyl)borazine

Conditions

Yield

hydridocarbonyltris(triphenylphosphine)rhodium(I) In neat (no solvent) Kinetics; borazine and excess of the propene (ratio 1:2.9) reacted in the presence of a catalytic amt. Rh-complex at room temp. for 16 h, resulting product was a solid with a moist appearance; vacuum line fractionation of mixt. through a -78 and -196°C traps, 2-substd. and 2,4-products found in the -78°C trap; extn. (CH2Cl2) of solid residue, evapn. (ac.), solid sublimed at 80°C (2,4,6-product), elem. anal.;

A 14%
B 84%
C n/a

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Trifluoropropene Chemical Properties

MF: C₃H₃F₃
MW: 96.051130 g/mol
EINECS: 211-637-0
Density: 0.940 g/cm³
Product Name: Trifluoropropene
IUPAC Name: 3,3,3-trifluoroprop-1-ene
Boiling Point: −18-−16 °C(lit.)
Vapour Pressure: 3190 mmHg at 25°C
Product Categories: Industrial/Fine Chemicals ; Chemical Synthesis ; Compressed and Liquefied Gases ; Synthetic Reagents
Synonyms: 1,1,1-Trifluoro-2-propene ; 1,1,1-Trifluoropropene ; 1-Propene, 3,3,3-trifluoro- ; 1-Propene,3,3,3-trifluoro ; 1-Propene,3,3,3-trifluoro- ; 3,3,3-Trifluoropropylene ; FC-1243zf ; Propene,3,3,3-trifluoro-
Following is the molecular structure of 1,1,1-Trifluoropropene (677-21-4):

Trifluoropropene Uses

1,1,1-Trifluoropropene (677-21-4) is used as Fluoro-silicone rubber chemicals and fluorine intermediates. and used for the production of fluorine silicon rubber.

Trifluoropropene Toxicity Data With Reference

ihl-mus LC50:1691 g/m3/2H

85GMAT Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,116.

Trifluoropropene Consensus Reports

Reported in EPA TSCA Inventory.

Trifluoropropene Safety Profile

Slightly toxic by inhalation. When heated to decomposition it emits toxic vapors of F⁻.

Safety Information of 1,1,1-Trifluoropropene (677-21-4):
Hazard Codes: F
F: Highly Flammable
Risk Statements: 11
11: Highly Flammable
Safety Statements: 16-38
16: Keep away from sources of ignition - No smoking
38: In case of insufficient ventilation, wear suitable respiratory equipment
RIDADR: UN 1954 2.1
WGK Germany: 3
RTECS: UD2792000
Hazard Note: Flammable
TSCA: T
HazardClass: 2.1

Trifluoropropene Specification

First Aid Measures of 1,1,1-Trifluoropropene (677-21-4):
1.Ingestion: Seek medical assistance.
2.Inhalation: Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult.
3.Skin: Remove and isolate contaminated clothing and shoes. Clothing frozen to the skin should be thawed before being removed. In case of contact with liquefied gas, thaw frosted parts with lukewarm water
4.Eyes: Flush with running water for at least 20 minutes
Hazards Identification of 1,1,1-Trifluoropropene (677-21-4):
1.Inhalation: Vapors may cause dizziness or asphyxiation without warning. Some may be irritating if inhaled at high concentrations.
2.Skin: Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite.
3.Eyes: May cause irritation.
4.Hazards: Vapors from liquefied gas are initially heavier than air and spread along ground. Vapors may travel to source of ignition and flash back. Containers may explode when heated.

Product Name

Trifluoropropene

Synthetic route

Trifluoropropene Chemical Properties

Trifluoropropene Uses

Trifluoropropene Toxicity Data With Reference

Trifluoropropene Consensus Reports

Trifluoropropene Safety Profile

Trifluoropropene Specification

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