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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

4-Fluoro-3-phenoxybenzaldehyde Manufacturer/High quality/Best price/In stock

Cas:68359-57-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality M-Phenoxy-P-Fluorobenzaldehyde supplier in China

Cas:68359-57-9

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product Description Product Name 4-Fluoro-3-phenoxybenzaldehyde CAS No. 68359-57-9 Appearance

4-Fluoro-3-phenoxybenzaldehyde

Cas:68359-57-9

Min.Order:10 Gram

FOB Price: $2.0 / 4.0

Type:Lab/Research institutions

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality 99% 68359-57-9 4-Fluoro-3-phenoxybenzaldehyde Manufacturer

Cas:68359-57-9

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

4-Fluoro-3-Phenoxybenzaldehyde

Cas:68359-57-9

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Fluoro-3-phenoxybenzaldehyde

Cas:68359-57-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 68359-57-9 with best price

Cas:68359-57-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hangzhou Sartort Biopharma Co., Ltd

Appearance:Clear light yellow liquid Storage:R.T Package:200kg/Barrel Application:Insecticide Intermediate Transportation:Express/Sea/Air Port:Any port in China

99% 4-fluoro-3-phenoxybenzaldehyde cas 68359-57-9

Cas:68359-57-9

Min.Order:25 Kilogram

FOB Price: $55.0 / 150.0

Type:Lab/Research institutions

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzaldehyde,4-fluoro-3-phenoxy- 68359-57-9

Cas:68359-57-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzaldehyde,4-fluoro-3-phenoxy-

Cas:68359-57-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Mojin Biotechnology Co.,Ltd

Hebei Mojin Biological Technology Co., Ltd. is specialize in the production of chemical raw materials and reagents,located in Shijiazhuang, Hebei Province. In recent decades, under the efforts of all staff, in Shandong, Henan, Guangdong and many othe

4-Fluoro-3-phenoxybenzaldehyde CAS 68359-57-9

Cas:68359-57-9

Min.Order:1 Kilogram

FOB Price: $20.0 / 40.0

Type:Trading Company

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

4-Fluoro-3-phenoxybenzaldehyde

Cas:68359-57-9

Min.Order:1 Kilogram

FOB Price: $50.0 / 90.0

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzaldehyde,4-fluoro-3-phenoxy-

Cas:68359-57-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

4-Fluoro-3-phenoxybenzaldehyde CAS68359-57-9

Cas:68359-57-9

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

4-Fluoro-3-Phenoxybenzaldehyde

Cas:68359-57-9

Min.Order:0

Negotiable

Type:Manufacturers

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-Fluoro-3-phenoxybenzaldehyde

Cas:68359-57-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

4-FLUORO-3-PHENOXY BENZALDEHYDE

Cas:68359-57-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Fluoro-3-phenoxybenzaldehyde

Cas:68359-57-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 4-fluoro-3-phenoxybenzaldehyde

Cas:68359-57-9

Min.Order:0 Metric Ton

Negotiable

Type:Other

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

4-Fluoro-3-phenoxybenzaldehyde

Cas:68359-57-9

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Product Name: 4-Fluoro-3-phenoxybenzaldehyde Synonyms: M-PHENOXY-P-FLUOROBENZALDEHYDE;2-FLUORO-5-FORMYLDIPHENYL ETHER;3-(phenoxy)-4-fluoro-benzaldehyde;4-FLUORO-3-PHENOXYBENZALDEHYDE;4-Fluoro-3-phenoxybenzaldehyde 98%;4-Fluoro-3-phenoxybe

4-Fluoro-3-phenoxybenzaldehyde 68359-57-9

Cas:68359-57-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Sinotech Import&Export Corporation

Chemical Names: 3-(Phenoxy)-4-fluoro-benzaldehyde, 4-Fluoro-3-phenoxybenzaldehyde Chemical Structure: Molecular Formula: C13H9FO2 CAS: 68359-57

4-Fluoro-3-phenoxybenzaldehyde

Cas:68359-57-9

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Shanghai Minstar Chemical Co., Ltd

Product Name: 4-Fluoro-3-phenoxybenzaldehyde Synonyms: M-PHENOXY-P-FLUOROBENZALDEHYDE;2-FLUORO-5-FORMYLDIPHENYL ETHER;3-(phenoxy)-4-fluoro-benzaldehyde;4-FLUORO-3-PHENOXYBENZALDEHYDE;4-Fluoro-3-phenoxybenzaldehyde 98%;4-Fluoro-3-phenoxybenzald

4-Fluoro-3-phenoxybenzaldehyde

Cas:68359-57-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

4-Fluoro-3-phenoxybenzaldehyde

Cas:68359-57-9

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

4-Fluoro-3-phenoxybenzaldehyde

Cas:68359-57-9

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

4-Fluoro-3-phenoxybenzaldehyde

Cas:68359-57-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

4-Fluoro-3-phenoxybenzaldehyde

Cas:68359-57-9

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

4-Fluoro-3-phenoxybenzaldehyde

Cas:68359-57-9

Min.Order:0

Negotiable

Type:Manufacturers

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healthtide biotech co.,ltd

Our advantages: 1, High quality with competitive price: 1) Standard:BP/USP/EP/Enterprise standard 2) All Purity≥99% 3) We are manufacturer and can provide high quality products with factory price. 2, Fast and safe delivery 1) Parcel can be

Factory Supply 4-Fluoro-3-phenoxybenzaldehyde CAS 68359-57-9

Cas:68359-57-9

Min.Order:1 Gram

FOB Price: $1.0

Type:Trading Company

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colorless transparent liquid Storage:stored in a cool, dry and ventilated place to provent sun and rain Package:25kg/drum, or as per your request. Application:Used for Pesticide

4-Fluoro-3-phenoxybenzaldehyd

Cas:68359-57-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Synthetic route

cyfluthrin
68359-37-5

cyfluthrin

A

4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

B

3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid
55701-05-8

3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid

Conditions
ConditionsYield
With sodium hydroxide In methanol for 2h; Heating;
4-fluoro-3-phenoxybenzyl bromide
68359-55-7

4-fluoro-3-phenoxybenzyl bromide

1-Nitropropane
108-03-2

1-Nitropropane

4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

Conditions
ConditionsYield
In ethanol
4-fluoro-3-phenoxy-benzaldehyde ethyleneacetal
77771-05-2

4-fluoro-3-phenoxy-benzaldehyde ethyleneacetal

4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

Conditions
ConditionsYield
With hydrogenchloride In ethanol; water; toluene
cis-α-cyano-3-phenoxy-4-fluoro-benzyl 2,2-dimethyl-3-(2-chloro-vinyl)cyclopropanecarboxylate

cis-α-cyano-3-phenoxy-4-fluoro-benzyl 2,2-dimethyl-3-(2-chloro-vinyl)cyclopropanecarboxylate

A

3-Methylbutenoic acid
541-47-9

3-Methylbutenoic acid

B

3-(2-chloro-vinyl)-2,2-dimethylcyclopropanecarboxylic acid
60310-82-9

3-(2-chloro-vinyl)-2,2-dimethylcyclopropanecarboxylic acid

C

4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

D

C8H11ClO

C8H11ClO

E

2-(4-fluoro-3-phenoxyphenyl)-2-hydroxyethanenitrile
76783-44-3

2-(4-fluoro-3-phenoxyphenyl)-2-hydroxyethanenitrile

F

4-fluoro-3-phenoxy benzoic acid
77279-89-1

4-fluoro-3-phenoxy benzoic acid

Conditions
ConditionsYield
In hexane for 17h; UV-irradiation;
4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

4-fluoro-3-phenoxy benzoic acid
77279-89-1

4-fluoro-3-phenoxy benzoic acid

Conditions
ConditionsYield
With dihydrogen peroxide; acetic acid In ethanol for 4h; Heating;100%
With potassium permanganate In water for 2h; Heating;65%
With dihydrogen peroxide; acetic acid at 60 - 80℃; for 2h;
4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

4-fluoro-3-phenoxyphenylmethanol
68359-53-5

4-fluoro-3-phenoxyphenylmethanol

Conditions
ConditionsYield
With formic acid; C20H29ClIrN4(1+)*Cl(1-) In ethanol; water at 80℃; for 0.25h; chemoselective reaction;98%
With sodium hydroxide In diethyl ether; water
With sodium hydroxide In diethyl ether; water
With sodium hydroxide In diethyl ether; water
potassium cyanide

potassium cyanide

4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

C9H9Br2Cl2F3O

C9H9Br2Cl2F3O

C23H18Br2ClF4NO2

C23H18Br2ClF4NO2

Conditions
ConditionsYield
With tetrabutylammomium bromide In water; benzene at 15 - 20℃; for 10h;95%
sodium cyanide
773837-37-9

sodium cyanide

4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

cis-2,2-dimethyl-3-(2-chloropropenyl)cyclopropanecarboxylic acid chloride

cis-2,2-dimethyl-3-(2-chloropropenyl)cyclopropanecarboxylic acid chloride

cis-α-cyano-4-fluoro-3-phenoxybenzyl-2,2-dimethyl-3-(2-chloropropenyl)cyclopropanecarboxylate

cis-α-cyano-4-fluoro-3-phenoxybenzyl-2,2-dimethyl-3-(2-chloropropenyl)cyclopropanecarboxylate

Conditions
ConditionsYield
With triethylamine In water; toluene at 20℃; for 4h;95%
potassium cyanide

potassium cyanide

4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

(1R)-trans-2,2-dimethyl-3-(2-chloropropenyl)cyclopropanecarboxylic acid chloride

(1R)-trans-2,2-dimethyl-3-(2-chloropropenyl)cyclopropanecarboxylic acid chloride

(1R)-trans-α-cyano-4-fluoro-3-phenoxybenzyl-2,2-dimethyl-3-(2-chloropropenyl)cyclopropanecarboxylate

(1R)-trans-α-cyano-4-fluoro-3-phenoxybenzyl-2,2-dimethyl-3-(2-chloropropenyl)cyclopropanecarboxylate

Conditions
ConditionsYield
With pyridine In cyclohexane; water at 20℃; for 4h;93%
Dibenzyl phosphite
17176-77-1

Dibenzyl phosphite

4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

dibenzyl α-hydroxy(4-fluoro-3-phenoxy)benzylphosphonate

dibenzyl α-hydroxy(4-fluoro-3-phenoxy)benzylphosphonate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 14h;92%
4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

permethric acid chloride
52314-67-7

permethric acid chloride

sodium sulfate
7757-82-6

sodium sulfate

3'-phenoxy-4'-fluoro-benzyl 2,2-dimethyl-3-(2,2-dichlorovinyl)-cyclopropane-carboxylate
68359-33-1

3'-phenoxy-4'-fluoro-benzyl 2,2-dimethyl-3-(2,2-dichlorovinyl)-cyclopropane-carboxylate

Conditions
ConditionsYield
In water; ethyl acetate91.5%
4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

2-amino-N'-hydroxychroman-3-carboxamidine
1384471-91-3

2-amino-N'-hydroxychroman-3-carboxamidine

N-(4-fluoro-3-phenoxybenzylidene)-3-(5-(4-fluoro-3-phenoxyphenyl)-1,2,4-oxadiazol-3-yl)-3,4-dihydro-2H-chromen-2-amine
1384471-90-2

N-(4-fluoro-3-phenoxybenzylidene)-3-(5-(4-fluoro-3-phenoxyphenyl)-1,2,4-oxadiazol-3-yl)-3,4-dihydro-2H-chromen-2-amine

Conditions
ConditionsYield
for 0.0833333h; Irradiation;91%
sodium cyanide
773837-37-9

sodium cyanide

4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

cis/trans-2,2-dimethyl-3-(2-chloropropenyl)cyclopropanecarboxylic acid chloride

cis/trans-2,2-dimethyl-3-(2-chloropropenyl)cyclopropanecarboxylic acid chloride

cis/trans-α-cyano-4-fluoro-3-phenoxybenzyl-2,2-dimethyl-3-(2-chloropropenyl)cyclopropanecarboxylate

cis/trans-α-cyano-4-fluoro-3-phenoxybenzyl-2,2-dimethyl-3-(2-chloropropenyl)cyclopropanecarboxylate

Conditions
ConditionsYield
With pyridine In cyclohexane; water at 20℃; for 4h;91%
pyridine-2,6-dicarbohydrazide
5112-36-7

pyridine-2,6-dicarbohydrazide

4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

N'2,N’6-bis [(4-fluoro-3-phenoxyphenyl)methylidene]pyridine-2,6-dicarbohydrazide

N'2,N’6-bis [(4-fluoro-3-phenoxyphenyl)methylidene]pyridine-2,6-dicarbohydrazide

Conditions
ConditionsYield
With acetic acid In ethanol Reflux;89%
4-bromo-β-nitrostyrene
3156-37-4

4-bromo-β-nitrostyrene

4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

β-naphthol
135-19-3

β-naphthol

C31H19BrFNO2

C31H19BrFNO2

Conditions
ConditionsYield
With ammonium acetate; sodium hydroxide In water at 80℃; for 8h; Green chemistry;87%
ethyl 4-[4-(methylthio)phenyl]-6-methyl-2-thioxo-1,2,3,4-tetrahydropyrimidine-5-carboxylate
292871-44-4

ethyl 4-[4-(methylthio)phenyl]-6-methyl-2-thioxo-1,2,3,4-tetrahydropyrimidine-5-carboxylate

4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

chloroacetic acid
79-11-8

chloroacetic acid

CH3SC6H4C6HN2SOCH3CO2CH2CH3CHC6H3FOC6H5

CH3SC6H4C6HN2SOCH3CO2CH2CH3CHC6H3FOC6H5

Conditions
ConditionsYield
With sodium acetate; acetic anhydride; acetic acid for 3h; Heating;84%
4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

toluene-4-sulfonic acid hydrazide
1576-35-8

toluene-4-sulfonic acid hydrazide

N'-[(4-fluoro-3-phenoxyphenyl)methylidene]-4-methylbenzenesulfonohydrazide

N'-[(4-fluoro-3-phenoxyphenyl)methylidene]-4-methylbenzenesulfonohydrazide

Conditions
ConditionsYield
In ethanol Reflux;84%
4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

m-tyramine
588-05-6

m-tyramine

C21H18FNO2

C21H18FNO2

Conditions
ConditionsYield
With acetic acid at 50℃; for 5h; Pictet-Spengler Synthesis; Molecular sieve; Inert atmosphere;83%
tert-butyl diethylphosphonoacetate
27784-76-5

tert-butyl diethylphosphonoacetate

4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

tert-butyl (E)-3-(3'-phenoxy-4'-fluorophenyl)prop-2-enoate
1393363-56-8

tert-butyl (E)-3-(3'-phenoxy-4'-fluorophenyl)prop-2-enoate

Conditions
ConditionsYield
Stage #1: tert-butyl diethylphosphonoacetate With methylmagnesium bromide In tetrahydrofuran; diethyl ether at 20℃; for 0.25h; Inert atmosphere;
Stage #2: 4-fluoro-3-phenoxybenzaldehyde In tetrahydrofuran; diethyl ether for 15h; Horner-Wadsworth-Emmons olefination; Inert atmosphere; Reflux; optical yield given as %de; diastereoselective reaction;
82%
indole
120-72-9

indole

4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

C29H21FN2O

C29H21FN2O

Conditions
ConditionsYield
With sulfated anatase titania In neat (no solvent) at 20℃; for 0.5h; Green chemistry;82%
With BiCl3-loaded montmorillonite K10 In neat (no solvent) at 20℃; for 0.666667h; Green chemistry;82%
(2-nitroethenyl)benzene
102-96-5

(2-nitroethenyl)benzene

4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

malonic acid dimethyl ester
108-59-8

malonic acid dimethyl ester

6-(4-fluoro-3-phenoxyphenyl)-5-nitro-4-phenylpiperidin-2-one

6-(4-fluoro-3-phenoxyphenyl)-5-nitro-4-phenylpiperidin-2-one

Conditions
ConditionsYield
Stage #1: (2-nitroethenyl)benzene; malonic acid dimethyl ester With sodium hydroxide In methanol at 0℃; for 0.75h;
Stage #2: 4-fluoro-3-phenoxybenzaldehyde; formamide In methanol Reflux;
78%
4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

2-[3-cyano-4-(2-methylpropoxy)phenyl]-4-methyl-1,3-thiazole-5-carbohydrazide

2-[3-cyano-4-(2-methylpropoxy)phenyl]-4-methyl-1,3-thiazole-5-carbohydrazide

(E)-2-(3-cyano-4-isobutoxyphenyl)-N’-(4-fluoro-3-phenoxybenzylidene)-4-methylthiazole-5-carbohydrazide

(E)-2-(3-cyano-4-isobutoxyphenyl)-N’-(4-fluoro-3-phenoxybenzylidene)-4-methylthiazole-5-carbohydrazide

Conditions
ConditionsYield
With acetic acid In ethanol for 8h; Reflux;72%
1,5-dioxaspiro[5.5]undecane-2,4-dione
1658-27-1

1,5-dioxaspiro[5.5]undecane-2,4-dione

(2-nitroethenyl)benzene
102-96-5

(2-nitroethenyl)benzene

4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

2-aza-1,3-di(4-fluoro-3-phenoxyphenyl)-4-nitro5-phenyl-8,15-dioxa-7,16-dioxodispiro[5,2,59,26]hexadecane

2-aza-1,3-di(4-fluoro-3-phenoxyphenyl)-4-nitro5-phenyl-8,15-dioxa-7,16-dioxodispiro[5,2,59,26]hexadecane

Conditions
ConditionsYield
Stage #1: 1,5-dioxaspiro[5.5]undecane-2,4-dione; (2-nitroethenyl)benzene With triethylamine In ethanol at 20℃; for 3h; Michael Addition;
Stage #2: 4-fluoro-3-phenoxybenzaldehyde With ammonium acetate In ethanol at 45℃; for 20h; Mannich Aminomethylation;
71%
4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

ethyl acetoacetate
141-97-9

ethyl acetoacetate

malononitrile
109-77-3

malononitrile

6-amino-4-(4-fluoro-3-phenoxyphenyl)-3-methyl-1,4-dihydropyrano[2,3-c]pyrazole-5-carbonitrile

6-amino-4-(4-fluoro-3-phenoxyphenyl)-3-methyl-1,4-dihydropyrano[2,3-c]pyrazole-5-carbonitrile

Conditions
ConditionsYield
With hydrazine hydrate; morpholine triflate In ethanol; water for 8h; Reflux; Green chemistry;67%
4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

5-amino-1-(2-hydroxy-2-phenylethyl)-1H-pyrazole-4-carbohydrazide

5-amino-1-(2-hydroxy-2-phenylethyl)-1H-pyrazole-4-carbohydrazide

(E)-5-amino-1-(2-hydroxy-2-phenylethyl)-N’-(4-fluoro-3-phenoxybenzylidene)-1H-pyrazole-4-carbohydrazide

(E)-5-amino-1-(2-hydroxy-2-phenylethyl)-N’-(4-fluoro-3-phenoxybenzylidene)-1H-pyrazole-4-carbohydrazide

Conditions
ConditionsYield
In methanol; ethanol at 100℃; for 18h;65%
1-methoxy-4-(2-nitro-vinyl)-benzene
3179-10-0

1-methoxy-4-(2-nitro-vinyl)-benzene

4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

malonic acid dimethyl ester
108-59-8

malonic acid dimethyl ester

6-(4-fluoro-3-phenoxyphenyl)-4-(4-methoxyphenyl)-5-nitropiperidin-2-one

6-(4-fluoro-3-phenoxyphenyl)-4-(4-methoxyphenyl)-5-nitropiperidin-2-one

Conditions
ConditionsYield
Stage #1: 1-methoxy-4-(2-nitro-vinyl)-benzene; malonic acid dimethyl ester With sodium hydroxide In methanol at 0℃; for 0.75h;
Stage #2: 4-fluoro-3-phenoxybenzaldehyde; formamide In methanol Reflux;
63%
4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

2-amino-4,6-di-tertbutylphenol
1643-39-6

2-amino-4,6-di-tertbutylphenol

2,4-di-tert-butyl-6-{[(4-fluoro-3-phenoxyphenyl)methylene]amino}phenol

2,4-di-tert-butyl-6-{[(4-fluoro-3-phenoxyphenyl)methylene]amino}phenol

Conditions
ConditionsYield
for 2h; Heating;62%
1-methoxy-4-(2-nitro-vinyl)-benzene
3179-10-0

1-methoxy-4-(2-nitro-vinyl)-benzene

4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

1,3-cylohexanedione
504-02-9

1,3-cylohexanedione

2-(4-fluoro-3-phenoxybenzylideneamino)-3-(4-methoxyphenyl)benzofuran-4-ol

2-(4-fluoro-3-phenoxybenzylideneamino)-3-(4-methoxyphenyl)benzofuran-4-ol

Conditions
ConditionsYield
With piperidine; ammonium acetate In N,N-dimethyl-formamide at 20℃; for 7h; Michael Addition; Reflux;61%
4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

3-(4-Ethoxyphenyl)-3-methyl-2-butanone
89765-17-3

3-(4-Ethoxyphenyl)-3-methyl-2-butanone

1-(4-Fluoro-3-phenoxyphenyl)-4-(4-ethoxyphenyl)-4-methylpent-1-ene-3-one
89765-18-4

1-(4-Fluoro-3-phenoxyphenyl)-4-(4-ethoxyphenyl)-4-methylpent-1-ene-3-one

Conditions
ConditionsYield
With potassium hydroxide In ethanol at 20℃; for 6h; Condensation;60%
4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

ethyltriphenylphosphonium bromide
1530-32-1

ethyltriphenylphosphonium bromide

(E)-1-fluoro-2-phenoxy-4-(prop-1-en-1-yl)benzene

(E)-1-fluoro-2-phenoxy-4-(prop-1-en-1-yl)benzene

Conditions
ConditionsYield
With potassium carbonate In 1,4-dioxane at 110℃;56.8%
cycl-isopropylidene malonate
2033-24-1

cycl-isopropylidene malonate

1-methoxy-4-(2-nitro-vinyl)-benzene
3179-10-0

1-methoxy-4-(2-nitro-vinyl)-benzene

4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

8-aza-7,9-di(4-fluoro-3-phenoxyphenyl)-11-(p-methoxyphenyl)-3,3-dimethyl-10-nitro-2,4-dioxa-1,5-dioxospiro[5,5]undecane

8-aza-7,9-di(4-fluoro-3-phenoxyphenyl)-11-(p-methoxyphenyl)-3,3-dimethyl-10-nitro-2,4-dioxa-1,5-dioxospiro[5,5]undecane

Conditions
ConditionsYield
Stage #1: cycl-isopropylidene malonate; 1-methoxy-4-(2-nitro-vinyl)-benzene With triethylamine In ethanol at 20℃; for 3h; Michael Addition;
Stage #2: 4-fluoro-3-phenoxybenzaldehyde With ammonium acetate In ethanol at 45℃; for 20h; Mannich Aminomethylation;
55%
o-(chloromethyl)benzoic acid methyl ester
34040-62-5

o-(chloromethyl)benzoic acid methyl ester

4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

3-(4-fluoro-3-phenoxyphenyl)-3,4-dihydroisocoumarin

3-(4-fluoro-3-phenoxyphenyl)-3,4-dihydroisocoumarin

Conditions
ConditionsYield
With N1,N1,N12,N12-tetramethyl-7,8-dihydro-6H-dipyrido[1,2-a:2,1'-c][1,4]diazepine-2,12-diamine In N,N-dimethyl-formamide at 20℃; for 16h; Glovebox; Inert atmosphere;55%
(E)-1-methoxy-4-(2-nitrovinyl)benzene
3179-10-0, 5576-97-6

(E)-1-methoxy-4-(2-nitrovinyl)benzene

4-fluoro-3-phenoxybenzaldehyde
68359-57-9

4-fluoro-3-phenoxybenzaldehyde

malonic acid dimethyl ester
108-59-8

malonic acid dimethyl ester

C26H23FN2O7

C26H23FN2O7

Conditions
ConditionsYield
Stage #1: (E)-1-methoxy-4-(2-nitrovinyl)benzene; malonic acid dimethyl ester With sodium hydroxide In methanol at 0℃; for 0.75h;
Stage #2: 4-fluoro-3-phenoxybenzaldehyde With ammonium acetate In methanol at 20 - 85℃; for 40h;
53%

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