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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Dimethylaminoborane Manufacturer/High quality/Best price/In stock

Cas:74-94-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Dimethylaminoborane supplier in China

Cas:74-94-2

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

good quality Appearance:white powder Storage:cold storage Package:meet the demand of customer Application:diagnostic reagent Transportation:by sea or by air Port:shanghai

Borane-dimethylamine cimplex

Cas:74-94-2

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Dimethylamine--borane (1:1)

Cas:74-94-2

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Borane-dimethylamine complex

Cas:74-94-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

Dimethylaminoborane / LIDE PHARMA- Factory supply / Best price

Cas:74-94-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

Dimethylaminoborane 74-94-2

Cas:74-94-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

Dimethylamine-Borane(DMAB) CAS 74-94-2

Cas:74-94-2

Min.Order:1 Kilogram

FOB Price: $3.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 74-94-2 with best quality

Cas:74-94-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Dimethylaminoborane 74-94-2

Cas:74-94-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

Dimethylaminoborane Cyclic monoamines, polyamines and their derivatives and salts

Cas:74-94-2

Min.Order:1 Kilogram

FOB Price: $16.0 / 20.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

Dimethylaminoborane CAS:74-94-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermed

Dimethylaminoborane CAS:74-94-2

Cas:74-94-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Dimethylaminoborane

Cas:74-94-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Dimethylaminoborane

Cas:74-94-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Dimethylaminoborane

Cas:74-94-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

74-94-2

Cas:74-94-2

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

74-94-2 Dimethylaminoborane

Cas:74-94-2

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Dimethylaminoborane

Cas:74-94-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

BORANE-DIMETHYLAMINE COMPLEX

Cas:74-94-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

Dimethylaminoborane

Cas:74-94-2

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Dimethylaminoborane

Cas:74-94-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:White Crystalline Powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:as per your request Application:A reverse transcriptase inhibitor. Antivir

Dimethylaminoborane

Cas:74-94-2

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Dimethylaminoborane

Cas:74-94-2

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Reliable Quality Dimethylaminoborane

Cas:74-94-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

Dimethylaminoborane

Cas:74-94-2

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

Dimethylaminoborane Basic information Product Name: Dimethylaminoborane Synonyms: Borane-dimethylamine complex, 98+%;dimethylamine,compd.withborane(1:1);DimethylamineBorane(DMAB);Dimethylaminoboran;borane, compd. with dimethylamine;dimethylami

Dimethylaminoborane

Cas:74-94-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

74-94-2 Dimethylaminoborane

Cas:74-94-2

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

Dimethylaminoborane

Cas:74-94-2

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Dimethylaminoborane

Cas:74-94-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

74-94-2 Dimethylaminoborane

Cas:74-94-2

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Synthetic route

sodium tetrahydroborate
16940-66-2

sodium tetrahydroborate

dimethylammonium salt

dimethylammonium salt

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 4h;93%
dimethyl amine
124-40-3

dimethyl amine

diborane
19287-45-7

diborane

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
In neat (no solvent) excess amine, 30-40°C, concn. of soln.;; distn. in vac. (60°C/2Torr) or recrystn. (petroleum ether);;91%
In neat (no solvent) excess amine, 30-40°C, concn. of soln.;; distn. in vac. (60°C/2Torr) or recrystn. (petroleum ether);;91%
In diethyl ether product in liquid form, crystn. on standing;; distn. in vac.;;961 %
In gas determination of react.-enthalpy;;
for 2h; Inert atmosphere; Gas phase; Cooling with ice;
sodium tetrahydroborate
16940-66-2

sodium tetrahydroborate

dimethyl amine
124-40-3

dimethyl amine

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
With iodine In 1,2-dimethoxyethane byproducts: NaI, H2; dropwise addn. of NaBH4 and I2 in DME to amine in DME, removal of solvent, addn. of C6H6, filtration, evapn. of filtrate in a N2 stream, drying in vac.;; recrystn. from CH2Cl2/hexane mixture;;84.4%
With potassium dihydrogenphosphate In water at -20 - 5℃; for 10h; Solvent; Reagent/catalyst; Autoclave; Large scale;84.5%
With boron trifluoride diethyl etherate In tetrahydrofuran refluxing, filtartion, evapn. of solvent;;
N,N-dimethylammonium chloride
506-59-2

N,N-dimethylammonium chloride

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
With sodium tetrahydroborate In 1,2-dimethoxyethane at 20℃; Cooling with ice;71%
With lithium borohydride In diethyl ether at -78 - 20℃;
lithium borohydride

lithium borohydride

N,N-dimethylammonium chloride
506-59-2

N,N-dimethylammonium chloride

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
In neat (no solvent) in vac., 3h;; distn. in vac. at 75-76°C/0.5Torr;;70%
In diethyl ether byproducts: H2, LiCl; room temp., 3h, filtration, evapn.;; recrystn. from C6H6/petroleum ether;;
In diethyl ether amine hydrochloride was added at -78°C to soln. LiBH4 in Et2O andstirred for 30 min, allowed to warm to room temp. and stirred for 5 h; react. mixt. was cooled to -45°C, slvent was removed in vacuo, residue was heated in vacuo at 65°C for sublimation;
potassium borohydride

potassium borohydride

N,N-dimethylammonium chloride
506-59-2

N,N-dimethylammonium chloride

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
With sodium hydroxide In 1,2-dimethoxyethane; water at -5 - 15℃; for 6 - 10h; Conversion of starting material;55.1%
With sodium hydroxide In tetrahydrofuran; water at -10 - 15℃; for 10 - 14h; Conversion of starting material;54%
Me3N*BH2SPh

Me3N*BH2SPh

dimethyl amine
124-40-3

dimethyl amine

A

dimethylamine borane
74-94-2

dimethylamine borane

B

Me2NH*BH2SPh
1387442-05-8

Me2NH*BH2SPh

Conditions
ConditionsYield
at 20℃; for 36h;A 10%
B 46%
dimethylamine borane
1838-13-7

dimethylamine borane

lithium borohydride

lithium borohydride

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
In tetrahydrofuran; water at 20℃; for 4h; Inert atmosphere;10%
calcium borohydride

calcium borohydride

dimethyl amine
124-40-3

dimethyl amine

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
In tetrahydrofuran
boron trioxide

boron trioxide

hydrogen
1333-74-0

hydrogen

dimethyl amine
124-40-3

dimethyl amine

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
With aluminium trichloride; aluminium In neat (no solvent) High Pressure; heating the mixture under a H2-pressure of 800-900kg/cm**2 to 273°C for 10h; in mixture with other products;;
sodium dimethylamidotrihydridoborate

sodium dimethylamidotrihydridoborate

water
7732-18-5

water

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
In hydrogenchloride hydrolysis with 0.05n HCl, equilibrium;;
sodium tetrahydroborate
16940-66-2

sodium tetrahydroborate

dimethylammonium dihydrogen phosphate
23307-08-6

dimethylammonium dihydrogen phosphate

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
In neat (no solvent) heating; dissolving in (CH3)2NH2;; evapn. in vac. or recrystn. (petroleum ether);;
dimethylamine borane
1838-13-7

dimethylamine borane

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
With pyrographite In not given with C generated in an electric arc; further by-products;;
dimethylamine borane
1838-13-7

dimethylamine borane

methylamine
74-89-5

methylamine

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
In tetrahydrofuran byproducts: HB{N(CH3)2}(NHCH3);
In cyclohexane byproducts: HB{N(CH3)2}(NHCH3);
dimethylamine borane
1838-13-7

dimethylamine borane

N,N',N''-triethylborazane
26200-45-3, 7270-53-3, 26200-44-2

N,N',N''-triethylborazane

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
In neat (no solvent) byproducts: (HBNC2H5)3; on heating;;
dimethylamine borane
1838-13-7

dimethylamine borane

N,N',N''-tripropylborazane
26200-46-4, 26200-47-5

N,N',N''-tripropylborazane

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
In neat (no solvent) byproducts: (HB-N-n-C3H7)3; on heating;;
dimethylamine borane
1838-13-7

dimethylamine borane

N,N',N''-triisopropylborazane
272443-95-5

N,N',N''-triisopropylborazane

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
In neat (no solvent) byproducts: (HB-N-i-C3H7)3; on heating;;
dimethyl amine
124-40-3

dimethyl amine

diborane
19287-45-7

diborane

A

[H2B((CH3)2NH)2](1+)*[BH4](1-)=[H2B((CH3)2NH)2][BH4]

[H2B((CH3)2NH)2](1+)*[BH4](1-)=[H2B((CH3)2NH)2][BH4]

B

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
In neat (no solvent) prepared by condensing diborane in small portions to the amine until anexcess of diborane is present as indicated by the vapour pressure; detected by (13)C-NMR;
lithium borohydride

lithium borohydride

N,N-dimethylaminodichlorophosphane
683-85-2

N,N-dimethylaminodichlorophosphane

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
In neat (no solvent) at 80°C in mixture with other products;;
phosphine-borane
19121-56-3

phosphine-borane

dimethyl amine
124-40-3

dimethyl amine

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
In neat (no solvent) byproducts: {(CH3)2NH2}{H2P{BH3)2}; < -45°C, at higher temp. formation of ionic by-product; discussion of mechanism;;
lithium borohydride

lithium borohydride

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

A

dimethylamine borane
74-94-2

dimethylamine borane

B

trimethylamine-borane
75-22-9

trimethylamine-borane

Conditions
ConditionsYield
In N,N-dimethyl-formamide soln. of LiBH4 in DMF under dry, oxygen free N2 (after 7 ds at ambient temp.); not isolated; (11)B-NMR;
trimethylamine-borane
75-22-9

trimethylamine-borane

dimethyl amine
124-40-3

dimethyl amine

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
In neat (no solvent) excess amine, room temp.;;
P(BH3)F3
14931-39-6

P(BH3)F3

dimethyl amine
124-40-3

dimethyl amine

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
In diethyl ether byproducts: PF3; excess amine;;
triethylamine-borane
1722-26-5

triethylamine-borane

dimethyl amine
124-40-3

dimethyl amine

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
In neat (no solvent) excess amine, room temp.;;
N,N',N''-triisopropylborazane
272443-95-5

N,N',N''-triisopropylborazane

H2BN(CH3)2*2H2B-NH-(i-C3H7)

H2BN(CH3)2*2H2B-NH-(i-C3H7)

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
In neat (no solvent) byproducts: (HB-N-i-C3H7)3; on heating;;
H3BCO*2NH(CH3)2

H3BCO*2NH(CH3)2

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
byproducts: (CH3)2NH, CO; at room temp.;;
byproducts: (CH3)2NH, CO; at room temp.;;
{(CH3)2N}F2PBH3

{(CH3)2N}F2PBH3

dimethyl amine
124-40-3

dimethyl amine

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
In diethyl ether byproducts: (CH3)2NPF2; very slow react.;;
bis(dimethylamino)phosphine borane

bis(dimethylamino)phosphine borane

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
byproducts: H2, HB{N(CH3)2}2; at 65°C;;
{Cd(NH3)6}(2+)*2{BH4}(1-)={Cd(NH3)6}{BH4}2

{Cd(NH3)6}(2+)*2{BH4}(1-)={Cd(NH3)6}{BH4}2

dimethyl amine
124-40-3

dimethyl amine

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
With hydrogen sulfide In neat (no solvent) treatment with H2S; filtration, removal of excess amine;; distn. or treatment with activated coal in ether;;>99
With hydrogen sulfide In neat (no solvent) treatment with H2S; filtration, removal of excess amine;; distn. or treatment with activated coal in ether;;>99
(CH3)2AsN(CH3)2BH3
106587-23-9

(CH3)2AsN(CH3)2BH3

dimethylarsine
593-57-7

dimethylarsine

A

tetramethyldiarsine
471-35-2

tetramethyldiarsine

B

dimethylamine borane
74-94-2

dimethylamine borane

Conditions
ConditionsYield
In (2)H8-toluene Me2AsH is condensed onto the frozen soln. of B-compd. (-196°C) in a NMR-tube, sealing of the tube, agitating at -95°C, reaction is studied from -80 to -10°C; monitored by NMR-spectroscopy;
dimethylamine borane
74-94-2

dimethylamine borane

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
With [IrH2{(P(phenyl)2(o-C6H4CO))2H}] In tetrahydrofuran; water for 0.133333h; Catalytic behavior; Kinetics; Thermodynamic data; Reagent/catalyst;100%
With ethanol; ReBr2(NO)(CH3CN)(PTA)2 In ethanol Kinetics; byproducts: B(OC2H5)3, (CH3)2NH; ethanolysis of amine-borane with 1 mol.-% ReBr2(NO)(MeCN)(1,3,5-triaza-7-phosphaadamantane)2 at room temp. or at 50°C;
With ethanol In ethanol byproducts: B(OC2H5)3, (CH3)2NH; ethanolysis of amine-borane at 50°C;
dimethylamine borane
74-94-2

dimethylamine borane

cyclic(dimethylamino borane) dimer
23884-11-9

cyclic(dimethylamino borane) dimer

Conditions
ConditionsYield
With N-benzylidene tert-butylamine; C28H24BF12P In benzene at 25℃; for 6h; Temperature;99%
With 2,2,6,6-tetramethyl-piperidine; trimethylsilyl trifluoromethanesulfonate In 1,2-dichloro-benzene at 20℃; for 2h; Inert atmosphere;89%
With Mes2P-C{=C(H)-Ph}-AltBu2 at 45 - 90℃; Catalytic behavior; Concentration; Time;77%
dimethylamine borane
74-94-2

dimethylamine borane

benzoic acid
65-85-0

benzoic acid

N,N-dimethylbenzamide
611-74-5

N,N-dimethylbenzamide

Conditions
ConditionsYield
In 5,5-dimethyl-1,3-cyclohexadiene for 12h; Reflux;99%
dimethylamine borane
74-94-2

dimethylamine borane

hexanoic acid
142-62-1

hexanoic acid

N,N-dimethylhexanamide
5830-30-8

N,N-dimethylhexanamide

Conditions
ConditionsYield
In 5,5-dimethyl-1,3-cyclohexadiene for 12h; Reflux;98%
dimethylamine borane
74-94-2

dimethylamine borane

Trimethylacetic acid
75-98-9

Trimethylacetic acid

Tripivaloyloxyboran-dimethylamin-Addukt

Tripivaloyloxyboran-dimethylamin-Addukt

Conditions
ConditionsYield
In 5,5-dimethyl-1,3-cyclohexadiene at 100℃; for 4h;98%
1,4-dioxane
123-91-1

1,4-dioxane

n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

dimethylamine borane
74-94-2

dimethylamine borane

lithium (dimethylamino)hydroborate, adduct with 1,4-dioxane

lithium (dimethylamino)hydroborate, adduct with 1,4-dioxane

Conditions
ConditionsYield
In hexane byproducts: butane; (anhydrous conditions); dissoln. of BH3*NHMe2 in 1,4-dioxane, after cooling in an ice-bath addn. of n-BuLi in hexane within 1 h with stirring, further stirring at room temp. for 2 h; crystn. (toluene); elem. anal.;97%
dimethylamine borane
74-94-2

dimethylamine borane

dimethylamine borane
1838-13-7

dimethylamine borane

Conditions
ConditionsYield
With tri-tert-butyl phosphine; tris(pentafluorophenyl)borate In C6D5Cl for 24h;97%
With phenylmagnesium bromide In tetrahydrofuran at 20℃; for 5h; Inert atmosphere;6%
With bis(cyclopentadienyl)titanium dichloride; n-butyllithium In toluene at 20℃; for 20h; Inert atmosphere;
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

dimethylamine borane
74-94-2

dimethylamine borane

A

lithium (dimethylamino)hydroborate

lithium (dimethylamino)hydroborate

B

tris(dimethylamino)borane
4375-83-1

tris(dimethylamino)borane

C

Dimethylamino-di-n-butyl-boran
7289-86-3

Dimethylamino-di-n-butyl-boran

D

Li{B(n-C4H9)4}
15243-31-9

Li{B(n-C4H9)4}

Conditions
ConditionsYield
In hexane byproducts: butane; (anhydrous conditions); stirring (4 h); centrifugation, washing (hexane), drying (vac.); elem. anal.;A 96%
B n/a
C n/a
D n/a
dimethylamine borane
74-94-2

dimethylamine borane

C19H42BFeN3P2

C19H42BFeN3P2

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

C21H46BFeN4P2(1+)*C24H20B(1-)

C21H46BFeN4P2(1+)*C24H20B(1-)

Conditions
ConditionsYield
With N,N-dimethylammonium chloride In tetrahydrofuran at 50℃; for 18h; Inert atmosphere;96%
1-indoline
496-15-1

1-indoline

dimethylamine borane
74-94-2

dimethylamine borane

1-borylindoline
1355176-05-4

1-borylindoline

Conditions
ConditionsYield
In neat (no solvent) byproducts: H2; (inert atm., Schlenk technique); heating mixt. of 1 equiv. of indoline and 1 equiv. of borane deriv. at 100°C under Ar flow; extn. (CHCl3), filtration through celite, evapn., washing with hexanes, NMR and IR;95%
With catalyst: Pd/C In neat (no solvent) byproducts: H2, (CH3)2NH; (inert atm., Schlenk technique); heating mixt. of 1 equiv. of indoline, 1 equiv. of borane deriv. and Pd/C at 100°C for 2 h under Ar flow; extn. (CHCl3), filtration through celite, evapn., washing with hexanes, NMR and IR;87%
dimethylamine borane
74-94-2

dimethylamine borane

[(2,6-(t-Bu2PO)2C5H3N)Rh(H2)][tetrakis(3,5-bis(trifluoromethyl)phenyl)borate]
1361399-35-0

[(2,6-(t-Bu2PO)2C5H3N)Rh(H2)][tetrakis(3,5-bis(trifluoromethyl)phenyl)borate]

C23H49BN2O2P2Rh(1+)*C32H12BF24(1-)

C23H49BN2O2P2Rh(1+)*C32H12BF24(1-)

Conditions
ConditionsYield
Inert atmosphere;95%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

dimethylamine borane
74-94-2

dimethylamine borane

lithium (dimethylamino)hydroborate

lithium (dimethylamino)hydroborate

Conditions
ConditionsYield
Stage #1: n-butyllithium; dimethylamine borane In hexane at -78℃; for 1h; Inert atmosphere;
Stage #2: In hexane at 20℃; for 1h; Inert atmosphere;
94%
dimethylchloroamine
1585-74-6

dimethylchloroamine

dimethylamine borane
74-94-2

dimethylamine borane

(bisdimethylamine)dihydroboronium(+) chloride

(bisdimethylamine)dihydroboronium(+) chloride

Conditions
ConditionsYield
In tetrachloromethane dropwise addn. of (CH3)2NCl in CCl4, pptn.;;92%
dimethylamine borane
74-94-2

dimethylamine borane

Cyclohexanecarboxylic acid
98-89-5

Cyclohexanecarboxylic acid

N,N-dimethylcyclohexanecarboxamide
17566-51-7

N,N-dimethylcyclohexanecarboxamide

Conditions
ConditionsYield
In 5,5-dimethyl-1,3-cyclohexadiene for 12h; Reflux;92%
dimethylamine borane
74-94-2

dimethylamine borane

A

bis(dimethylamino)borane
2386-98-3

bis(dimethylamino)borane

B

cyclic(dimethylamino borane) dimer
23884-11-9

cyclic(dimethylamino borane) dimer

Conditions
ConditionsYield
With 2,2,6,6-tetramethyl-piperidine; tributylstannyl trifluoromethanesulfonate In 1,2-dichloro-benzene at 20℃; for 2h; Inert atmosphere;A 7%
B 91%
With C56H65FeN2 In toluene at 20℃; for 7h; Catalytic behavior; Inert atmosphere; Glovebox; Schlenk technique;A 10%
B 90%
With [Mg{CH(SiMe3)2}(THF)2] In benzene-d6 at 60℃; Mechanism; Inert atmosphere;
dimethylamine borane
74-94-2

dimethylamine borane

tributylstannyl trifluoromethanesulfonate
68725-14-4

tributylstannyl trifluoromethanesulfonate

A

(μ-dimethylamino)diborane
23273-02-1

(μ-dimethylamino)diborane

B

tri-n-butyl-tin hydride
688-73-3

tri-n-butyl-tin hydride

C

cyclic(dimethylamino borane) dimer
23884-11-9

cyclic(dimethylamino borane) dimer

Conditions
ConditionsYield
With 2,2,6,6-tetramethylpiperidine In further solvent(s) byproducts: H2; N2 or Ar; 1,2-dichlorobenzene soln. of nBuSnOTf (0.39 mmol) and 2,2,6,6-tetramethylpiperidine (0.4 mmol) added to soln. of B compd. (0.42 mmol), mixt. stirred at 20°c for 2 h; NMR;A 2%
B n/a
C 91%
1,3,5-Trioxan
110-88-3

1,3,5-Trioxan

n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

dimethylamine borane
74-94-2

dimethylamine borane

lithium (dimethylamino)hydroborate, adduct with 1,3,5-trioxane

lithium (dimethylamino)hydroborate, adduct with 1,3,5-trioxane

Conditions
ConditionsYield
In hexane; toluene byproducts: butane; (anhydrous conditions); dissoln. of BH3*NHMe2 and 1,3,5-trioxane in toluene, addn. of n-BuLi in hexane within 10 min with stirring, reflux (1 h); filtration while hot, crystn. on cooling, recrystn. (hot toluene); elem.anal.;90%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

N,N,N,N,-tetramethylethylenediamine
110-18-9

N,N,N,N,-tetramethylethylenediamine

dimethylamine borane
74-94-2

dimethylamine borane

lithium (dimethylamino)hydroborate, adduct with N,N,N',N'-tetramethylethylenediamine

lithium (dimethylamino)hydroborate, adduct with N,N,N',N'-tetramethylethylenediamine

Conditions
ConditionsYield
In hexane byproducts: butane; (anhydrous conditions); dissoln. of BH3*NHMe2 in TMEDA, after cooling inan ice-bath addn. of n-BuLi in hexane within 1 h with stirring, further stirring at room temp. for 2 h; addn. of hexane, filtration, crystn. within 12 h and additionally by cooling of the supernatant to -18°C; elem. anal.;90%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

(1,4,7,10-tetraoxacyclododecane)
294-93-9

(1,4,7,10-tetraoxacyclododecane)

dimethylamine borane
74-94-2

dimethylamine borane

lithium (dimethylamino)hydroborate, adduct with 12-crown-4

lithium (dimethylamino)hydroborate, adduct with 12-crown-4

Conditions
ConditionsYield
In hexane; toluene byproducts: butane; (anhydrous conditions); dissoln. of BH3*NHMe2 and 12-crown-4 in toluene,addn. of n-BuLi in hexane within 10 min with stirring, reflux (1 h); filtration while hot, crystn. on cooling; elem. anal.;90%
dimethylamine borane
74-94-2

dimethylamine borane

A

(μ-dimethylamino)diborane
23273-02-1

(μ-dimethylamino)diborane

B

cyclic(dimethylamino borane) dimer
23884-11-9

cyclic(dimethylamino borane) dimer

Conditions
ConditionsYield
With 2,2,6,6-tetramethylpiperidine; Me3SiOTf In further solvent(s) byproducts: H2; N2 or Ar; 1,2-dichlorobenzene soln. of Me3SiOTf (0.39 mmol) and 2,2,6,6-tetramethylpiperidine (0.4 mmol) added to soln. of B compd. (0.42 mmol), mixt. stirred at 20°c for 2 h; NMR;A 3%
B 89%
With 2,2,6,6-tetramethylpiperidine; Et3SiOTf In further solvent(s) byproducts: H2; N2 or Ar; 1,2-dichlorobenzene soln. of Et3SiOTf (0.39 mmol) and 2,2,6,6-tetramethylpiperidine (0.4 mmol) added to soln. of B compd. (0.42 mmol), mixt. stirred at 20°c for 2 h; NMR;A 1%
B 87%
With 2,6-di-tert-burtylpyridine; Me3SiOTf In further solvent(s) byproducts: H2; N2 or Ar; 1,2-dichlorobenzene soln. of Me3SiOTf (0.39 mmol) and 2,6-di-tert-butylpyridine (0.4 mmol) added to soln. of B compd. (0.42 mmol), mixt. stirred at 20°c for 2 h; NMR;A 18%
B 31%
tris(pentafluorophenyl)alane toluene

tris(pentafluorophenyl)alane toluene

dimethylamine borane
74-94-2

dimethylamine borane

C20H10AlBF15N

C20H10AlBF15N

Conditions
ConditionsYield
In toluene for 0.0833333h; Inert atmosphere; Schlenk technique;87%
hydrogenchloride
7647-01-0

hydrogenchloride

dimethylamine borane
74-94-2

dimethylamine borane

N-Dimethyl-B-monochlor-borazan

N-Dimethyl-B-monochlor-borazan

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether Inert atmosphere; Schlenk technique; Glovebox;86%
with stoichiometric amounts;;
with stoichiometric amounts;;
dimethylamine borane
74-94-2

dimethylamine borane

C33H51CaN3O

C33H51CaN3O

C35H61BCaN4O

C35H61BCaN4O

Conditions
ConditionsYield
In toluene at 20℃; for 0.5h; Inert atmosphere;86%
dimethylamine borane
74-94-2

dimethylamine borane

oxalic acid
144-62-7

oxalic acid

C2H7N*C4BO8(1-)*H(1+)

C2H7N*C4BO8(1-)*H(1+)

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 64h; Inert atmosphere;85%
dimethylamine borane
74-94-2

dimethylamine borane

potassium hydride

potassium hydride

potassium dimethylaminoborohydride

potassium dimethylaminoborohydride

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 3 - 5h; Inert atmosphere;83%
dimethylamine borane
74-94-2

dimethylamine borane

{(CH3)2NBH2}2

{(CH3)2NBH2}2

Conditions
ConditionsYield
With C52H46BFeO2P4(1+)*Br(1-); potassium tert-butylate In toluene at 23℃; for 16h; Catalytic behavior;83%
dimethylamine borane
74-94-2

dimethylamine borane

water-d2
7789-20-0

water-d2

BH3*NDMe2
65761-09-3

BH3*NDMe2

Conditions
ConditionsYield
In D2O (Ar); a soln. of B compd. stirred at 40°C for 24 h; extd. (CH2Cl2), the org. layer dried (MgSO4), filtered, evapd., sublimedtwice under dynamic vac. at 20°C;82%
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