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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Chloroform-d

Cas:865-49-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply (2H)chloroform

Cas:865-49-6

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price Deuterated reagents Chloroform-d 865-49-6 Manufacturer

Cas:865-49-6

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Chloroform-d

Cas:865-49-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 865-49-6 with best quality

Cas:865-49-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Methane-d, trichloro-(9CI) 865-49-6

Cas:865-49-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Product Name: Chloroform-d CAS: 865-49-6 MF: CCl3D MW: 120.38 EINECS: 212-742-4 Mol File: 865-49-6.mol Chloroform-d Structure Chloroform-d Chemical Properties Melting point −64 °C(lit.) Boiling point 60.9 °C(

Chloroform-d

Cas:865-49-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

Chloroform-d CAS:865-49-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates

Chloroform-d CAS:865-49-6

Cas:865-49-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Methane-d, trichloro-(9CI)

Cas:865-49-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:865-49-6

Cas:865-49-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Miheng Trading Co., Ltd.

Chloroform-d cas 865-49-6 Our advantage 1.Top quality: Using high quality material and establishing a strict quality control system,assigning specific persons in charge of each part of production,from raw material purchase to assembly. 2 Pr

Chloroform-d cas 865-49-6

Cas:865-49-6

Min.Order:1 Kilogram

FOB Price: $10.0 / 50.0

Type:Trading Company

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

Chloroform-d

Cas:865-49-6

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Methane-d, trichloro-(9CI)

Cas:865-49-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hefei Zhaobo Technology Co., Ltd.

Chloroform-d CAS 865-49-6 Description Purity: 99% Min Application: Intermediates Appearance: Powder Package: Bag Delivery: 3-5days Our Advantage & Service 1.Top quality: Using high quality material and establishing a strict quality

Chloroform-d CAS 865-49-6

Cas:865-49-6

Min.Order:1 Kilogram

FOB Price: $50.0 / 100.0

Type:Trading Company

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

CAS NO.865-49-6

Cas:865-49-6

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

TaiChem Taizhou Limited

Established in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site

Chloroform-d

Cas:865-49-6

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung, LG, Merck, Thermo Fisher Scientific and so o

865-49-6 Chloroform-d

Cas:865-49-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

CHLOROFORM-D

Cas:865-49-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Product Name:Chloroform-d CAS No:865-49-6 Synonyms:

Chloroform-d

Cas:865-49-6

Min.Order:1 Gram

Negotiable

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Chloroform-d

Cas:865-49-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

865-49-6 CAS NO.865-49-6

Cas:865-49-6

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

CHLOROFORM-D

Cas:865-49-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

CHLOROFORM-D CClas no.865-49-6 98%

Cas:865-49-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Chloroform-d

Cas:865-49-6

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Chloroform-d 100g

Cas:865-49-6

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Synonym:deuterated chloroform;Trichloromethane-d CAS NO.:865-49-6 CBNumber:CB2103569 Molecular formula:CDCl3 Molecular weight:120.38 EINECS:212-742-4 Dangerous goods transportation No.:UN 1888 6.1/PG 3 HS:2845900010 MDL:MFCD00000827 Sp

Chloroform-d china manufacture

Cas:865-49-6

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

ChloroforM-d 99.6atoM%D (stabilized with Silver chip)

Cas:865-49-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

Chloroform-d

Cas:865-49-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Wuhan Circle Star Chem-medical Technology co.,Ltd.

1,we produce and sell good chemicals around the world.2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%.3,our staff consists of highly qualified in

Chloroform-d

Cas:865-49-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Methane-d, trichloro-(9CI)

Cas:865-49-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

(CD(CH3)2CH2)3SnOC3H7-i

(CD(CH3)2CH2)3SnOC3H7-i

Bromotrichloromethane
75-62-7

Bromotrichloromethane

A

chloroform-d1
865-49-6

chloroform-d1

B

chloroform
67-66-3

chloroform

C

1,1,1-trichloro-3,3-dimethyl-3-bromopropane
23153-21-1

1,1,1-trichloro-3,3-dimethyl-3-bromopropane

D

isopropyl alcohol
67-63-0

isopropyl alcohol

E

acetone
67-64-1

acetone

Conditions
ConditionsYield
byproducts: CHCl3; Irradiation (UV/VIS); 70°C;A n/a
B n/a
C 10%
D 35%
E 60%
byproducts: CHCl3; Irradiation (UV/VIS); 70°C;A n/a
B n/a
C 10%
D 35%
E 60%
(C4H9)3SnOC6H10D

(C4H9)3SnOC6H10D

Bromotrichloromethane
75-62-7

Bromotrichloromethane

A

chloroform-d1
865-49-6

chloroform-d1

B

3-bromo-1,1,1-trichloro-pentane
101774-42-9

3-bromo-1,1,1-trichloro-pentane

C

chloroform
67-66-3

chloroform

D

cyclohexanone
108-94-1

cyclohexanone

E

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
38% yield of CHCl3 and CDCl3;A n/a
B 18%
C n/a
D 14%
E 38%
38% yield of CHCl3 and CDCl3;A n/a
B 18%
C n/a
D 14%
E 38%
tetrachloromethane
56-23-5

tetrachloromethane

A

chloroform-d1
865-49-6

chloroform-d1

B

chloroform
67-66-3

chloroform

Conditions
ConditionsYield
With d8-isopropanol In water at 25℃; pH=7; Kinetics;A 33%
B 13%
2,2,2-trichloro-O,O'-dideuterio-ethane-1,1-diol
19220-07-6

2,2,2-trichloro-O,O'-dideuterio-ethane-1,1-diol

chloroform-d1
865-49-6

chloroform-d1

Conditions
ConditionsYield
With deuteriated sodium hydroxide; water-d2
chloroform
67-66-3

chloroform

chloroform-d1
865-49-6

chloroform-d1

Conditions
ConditionsYield
With water-d2; potassium carbonate at 100 - 105℃;
With deuteriated sodium hydroxide In water-d2 at 26℃; Rate constant; Product distribution; Kinetics;
With cis-[RuCl2(1,4-bis(diphenylphosphine)butane)(2,2′-bipyridine)]; water-d2; potassium hydroxide at 20℃; for 3h; Catalytic behavior; Reagent/catalyst; Time;
2,2,2-trichloroacetophenone
2902-69-4

2,2,2-trichloroacetophenone

chloroform-d1
865-49-6

chloroform-d1

Conditions
ConditionsYield
With deuteriated sodium hydroxide; water-d2 at -78℃;
chloral
75-87-6

chloral

chloroform-d1
865-49-6

chloroform-d1

Conditions
ConditionsYield
With water-d2; calcium oxide
Trichloroacetyl chloride
76-02-8

Trichloroacetyl chloride

chloroform-d1
865-49-6

chloroform-d1

Conditions
ConditionsYield
With water-d2; sodium carbonate; calcium carbonate
trichloromethyltrimethylsilane
5936-98-1

trichloromethyltrimethylsilane

A

chloroform-d1
865-49-6

chloroform-d1

B

chloroform
67-66-3

chloroform

Conditions
ConditionsYield
With methanol; deuteromethanol; sodium methylate at 21℃; Product distribution; value of product isotope effect;
toluene-d3
1124-18-1

toluene-d3

tert-butyl trichloroperacetate
69093-96-5

tert-butyl trichloroperacetate

chloroform-d1
865-49-6

chloroform-d1

Conditions
ConditionsYield
In tetrachloromethane at 80℃; for 12h; Rate constant; relative rate constants, presence of subst. toluenes or cyclohexane;
Cyclohexane-d12
1735-17-7

Cyclohexane-d12

tert-butyl trichloroperacetate
69093-96-5

tert-butyl trichloroperacetate

chloroform-d1
865-49-6

chloroform-d1

Conditions
ConditionsYield
In tetrachloromethane at 80℃; for 12h; Rate constant; relative rate constants, presence of cyclohexane;
calcium trichloroacetate

calcium trichloroacetate

chloroform-d1
865-49-6

chloroform-d1

Conditions
ConditionsYield
With deuteriated sodium hydroxide; water-d2
chloroform
67-66-3

chloroform

chlorine
7782-50-5

chlorine

deuterium chloride

deuterium chloride

chloroform-d1
865-49-6

chloroform-d1

Conditions
ConditionsYield
at 85℃; UV-Licht.Irradiation;
chloroform
67-66-3

chloroform

D2O

D2O

K2CO3

K2CO3

chloroform-d1
865-49-6

chloroform-d1

Conditions
ConditionsYield
at 100 - 105℃;
2,2,2-trichloro-O,O'-dideuterio-ethane-1,1-diol
19220-07-6

2,2,2-trichloro-O,O'-dideuterio-ethane-1,1-diol

NaOD

NaOD

D2O

D2O

chloroform-d1
865-49-6

chloroform-d1

chloroform-d1
865-49-6

chloroform-d1

Ru(CO)4(P(CH3)2C6H5)
157808-52-1, 31447-09-3

Ru(CO)4(P(CH3)2C6H5)

Ru2(CO)4[P(CH3)2C6H5]2Cl2
157699-27-9

Ru2(CO)4[P(CH3)2C6H5]2Cl2

Conditions
ConditionsYield
With CHCl3 In chloroform under N2; light yellow soln. Ru-complex/CHCl3 stirred at 45°C for 2.5 h (soln. turned bright yellow); evapn., column chromy. (Kieselgel 60, hexane/CH2Cl2 (20/1));100%
chloroform-d1
865-49-6

chloroform-d1

(2-(diphenylphosphanyl)benzaldehyde benzoylhydrazone)PdMe(Cl)
422313-58-4

(2-(diphenylphosphanyl)benzaldehyde benzoylhydrazone)PdMe(Cl)

carbon monoxide
201230-82-2

carbon monoxide

[((2-(diphenylphosphanyl)benzaldehyde benzoylhydrazone)PdCOMe(Cl)]*CDCl3

[((2-(diphenylphosphanyl)benzaldehyde benzoylhydrazone)PdCOMe(Cl)]*CDCl3

Conditions
ConditionsYield
In chloroform-d1 sapphire NMR tube, 30 atm., stirring at 20 °C for 20 h; soln. was filtered through Celite, Et2O was added, ppt. was filtered off, washed with Et2O, slow diffusion of Et2O into CDCl3 soln. at -20 °C, elem. anal.;99%
chloroform-d1
865-49-6

chloroform-d1

[RhH(O2)((C4H9)2PCH2CH2C(CH2)CH2CH2P(C4H9)2)]
181188-40-9

[RhH(O2)((C4H9)2PCH2CH2C(CH2)CH2CH2P(C4H9)2)]

ClRh((CH3)3C)2PCH2CH2C(CH2)CH2CH2P(C(CH3)3)2
72051-17-3

ClRh((CH3)3C)2PCH2CH2C(CH2)CH2CH2P(C(CH3)3)2

Conditions
ConditionsYield
In chloroform-d1 1 d;99%
chloroform-d1
865-49-6

chloroform-d1

ortho-B10H10C(Pt-Bu2)C(PEt2)
1021604-41-0

ortho-B10H10C(Pt-Bu2)C(PEt2)

nido-B10H10C(PDt-Bu2)C(PClEt2)

nido-B10H10C(PDt-Bu2)C(PClEt2)

Conditions
ConditionsYield
In chloroform-d1 standing in CDCl3 for 28 h; detected by NMR spectra;99%
chloroform-d1
865-49-6

chloroform-d1

(IPr)2NiCl
1220982-83-1

(IPr)2NiCl

trans-(1,3-bis(2,6-diisopropylphenyl)imidazolin-2-yliden)2NiCl2

trans-(1,3-bis(2,6-diisopropylphenyl)imidazolin-2-yliden)2NiCl2

Conditions
ConditionsYield
In chloroform-d199%
chloroform-d1
865-49-6

chloroform-d1

[Ru(hydridotris(pyrazol-1-yl)borato)2(tetrahydrothiophene)2]

[Ru(hydridotris(pyrazol-1-yl)borato)2(tetrahydrothiophene)2]

[Ru(hydridotris(pyrazol-1-yl)borato)2] * CDCl3

[Ru(hydridotris(pyrazol-1-yl)borato)2] * CDCl3

Conditions
ConditionsYield
In chloroform-d1 N2-atmosphere; standing for 1 week; pptn. on partial evapn.; elem. anal.;97%
chloroform-d1
865-49-6

chloroform-d1

di(C6H3(NMe2)2)stannylene

di(C6H3(NMe2)2)stannylene

SnCl(SiDCl2)(C6H3(N(CH3)2)2)2

SnCl(SiDCl2)(C6H3(N(CH3)2)2)2

Conditions
ConditionsYield
In diethyl ether; chloroform-d1 under Ar atm. using Schlenk techniques; excess CDCl3 added to soln. of Sn(C6H3(NMe)2)2 in Et2O at 25°C; soln. stirred for 2 h; solvent removed (vac.); ppt. treated (hexane); kept at -30°C for 12 h;96%
dichloro bis(acetonitrile) palladium(II)
21264-30-2, 90243-59-7, 14592-56-4

dichloro bis(acetonitrile) palladium(II)

chloroform-d1
865-49-6

chloroform-d1

sulfur dioxide
7446-09-5

sulfur dioxide

oxygen
80937-33-3

oxygen

4,4',4-tri-tert-butyl-2,2':6',2-terpyridine

4,4',4-tri-tert-butyl-2,2':6',2-terpyridine

(4,4',4''-tri(tert-butyl)-2,2':6',2''-terpyridine)(S-sulfito)palladium(II)
484652-13-3, 484652-19-9

(4,4',4''-tri(tert-butyl)-2,2':6',2''-terpyridine)(S-sulfito)palladium(II)

(4,4',4''-tri(tert-butyl)-2,2':6',2''-terpyridine)chloropalladium(II) chloride*2.5(CDCl3)

(4,4',4''-tri(tert-butyl)-2,2':6',2''-terpyridine)chloropalladium(II) chloride*2.5(CDCl3)

Conditions
ConditionsYield
In acetonitrile byproducts: acetamide; Pd complex dissolved in MeCN at room temp.; stirred for 10 min; O2-SO2 bubbled into the soln.; solid ligand (0.26 equiv.) added; dissolved over 10 min; remaining ligand (0.6 equiv.) added; stirred under O2-SO2 gas flow at room temp. for 2 h; flushed with O2 to remove SO2; H2O and MeOH added; kept for 48 h; recrystd. from CDCl3; ratio of the final compds. depended on react. microconditions; elem. anal.;A n/a
B 95%
chloroform-d1
865-49-6

chloroform-d1

C20H28AuOP
1428578-80-6

C20H28AuOP

C21H27AuCl3P
1428579-07-0

C21H27AuCl3P

Conditions
ConditionsYield
With triphenylphosphine95%
chloroform-d1
865-49-6

chloroform-d1

C19H33FN3Pd(1+)*CF3O3S(1-)
1571889-94-5

C19H33FN3Pd(1+)*CF3O3S(1-)

C19H33ClN3Pd(1+)*CF3O3S(1-)

C19H33ClN3Pd(1+)*CF3O3S(1-)

Conditions
ConditionsYield
at 80℃; for 9.5h; Inert atmosphere; Schlenk technique; Glovebox; Sealed tube;95%
[1-(2-Hex-1-ynyl-phenyl)-meth-(E)-ylidene]-phenyl-amine

[1-(2-Hex-1-ynyl-phenyl)-meth-(E)-ylidene]-phenyl-amine

chloroform-d1
865-49-6

chloroform-d1

C20H19(2)HCl3N
1028420-12-3

C20H19(2)HCl3N

Conditions
ConditionsYield
With 1,2-bis-(diphenylphosphino)ethane; bis-triphenylphosphine-palladium(II) chloride at 100℃;94%
chloroform-d1
865-49-6

chloroform-d1

([(i-Pr)2C3N2Me2]Ge(2,4,6-trimethylphenyl)2Et)I
1239426-13-1

([(i-Pr)2C3N2Me2]Ge(2,4,6-trimethylphenyl)2Et)I

chloro(ethyl)bis(2,4,6-trimethylphenyl)germanium
1239426-11-9

chloro(ethyl)bis(2,4,6-trimethylphenyl)germanium

Conditions
ConditionsYield
In chloroform-d1 (N2), Schlenk techniques; soln. of Ge compd. in CDCl3 stored for 10 min; extn. with satd. soln. of NH4Cl, aq. phase washed with CH2Cl2, combined org. phases dried over MgSO4, filtration, filtrate evapd., residue dissolved in hexanes, filtration through silica, evapn.;94%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

chloroform-d1
865-49-6

chloroform-d1

A

tris(trimethylsilyl)deuteriomethane
65426-07-5

tris(trimethylsilyl)deuteriomethane

B

C7H19(2)HSi2
123145-84-6

C7H19(2)HSi2

Conditions
ConditionsYield
With 4,4'-di-tert-butylbiphenyl; lithium In tetrahydrofuran at -90 - -80℃;A 92%
B n/a
chloroform-d1
865-49-6

chloroform-d1

[(Ir(μ-pyrazolato)(H)(CN-t-Bu)2)2(μ-Cl)]CF3SO3
581797-57-1

[(Ir(μ-pyrazolato)(H)(CN-t-Bu)2)2(μ-Cl)]CF3SO3

[(Ir(μ-pyrazolato)(Cl)(CN-t-Bu)2)2(μ-Cl)]CF3SO3
581797-59-3

[(Ir(μ-pyrazolato)(Cl)(CN-t-Bu)2)2(μ-Cl)]CF3SO3

Conditions
ConditionsYield
In chloroform-d1 byproducts: CD2Cl2; Irradiation (UV/VIS); (Ar); Ir complex soln. irradiated in a sealed NMR tube with the direct sun light; layered with Et2O, crystd. for 2 d, filtered, washed (cold Et2O), dried (vac.); elem. anal.;90%
chloroform-d1
865-49-6

chloroform-d1

[W(CO)5(PH(CH(SiMe3)2)(OPh))]
1352656-20-2

[W(CO)5(PH(CH(SiMe3)2)(OPh))]

[W(CO)5(PCl(CH(SiMe3)2)(OPh))]
1416967-42-4

[W(CO)5(PCl(CH(SiMe3)2)(OPh))]

Conditions
ConditionsYield
With 12-crown-4, lithium diisopropylamide In diethyl ether under Ar, soln. of phosphane complex (0.1 mmol) and 12-crown-4 (0.1 mmol) in Et2O added dropwise to soln. of lithium diisopropylamide at -78°C, stirred for 0.5 h, solvent evapd. in vac., solid dissolved in CDCl3; volatiles evapd., residue washed with n-pentane at ca. -60°C, dried, crystd. from Et2O at ambient temp., detd. by 1H NMR, 13C NMR, 31P NMR, IR, MS, elem. anal., XRD;90%
chloroform-d1
865-49-6

chloroform-d1

(iPrP2SiH)Co(CO)2

(iPrP2SiH)Co(CO)2

(iPrP2SiCl)Co(CO)2

(iPrP2SiCl)Co(CO)2

Conditions
ConditionsYield
In chloroform-d1; benzene-d6 at 85℃; for 20h; Sealed tube; Inert atmosphere; Glovebox;90%
chloroform-d1
865-49-6

chloroform-d1

2-ethynylbenzaldehyde
38846-64-9

2-ethynylbenzaldehyde

aniline
62-53-3

aniline

C16H11(2)HCl3N

C16H11(2)HCl3N

Conditions
ConditionsYield
With 4 A molecular sieve In dichloromethane at 25℃; for 48h;89%
With MS4A at 20℃; for 48h;81%
chloromethyl(1,5-cyclooctadiene)palladium(II)

chloromethyl(1,5-cyclooctadiene)palladium(II)

chloroform-d1
865-49-6

chloroform-d1

((C6H5)2PCH2)2NC6H3(OH)COOH
909273-79-6

((C6H5)2PCH2)2NC6H3(OH)COOH

6Pd(2+)*6Cl(1-)*6((C6H5)2PCH2)2NC6H3(OH)COO(1-)*99C(2)HCl3=(PdCl(((C6H5)2PCH2)2NC6H3(OH)COO))6*99C(2)HCl3

6Pd(2+)*6Cl(1-)*6((C6H5)2PCH2)2NC6H3(OH)COO(1-)*99C(2)HCl3=(PdCl(((C6H5)2PCH2)2NC6H3(OH)COO))6*99C(2)HCl3

Conditions
ConditionsYield
In chloroform-d1 byproducts: CH4; ligand and Pd complex dissolved in CDCl3; stored for ca. 5 d; resultant Pd complex contained between 1 and 3 mol of CDCl3; ppt. isolated; elem. anal.; monitored by (1)H and (31)P NMR spectra;88%
chloroform-d1
865-49-6

chloroform-d1

dichlorofluoromethane-d
558-19-0

dichlorofluoromethane-d

Conditions
ConditionsYield
With antimony(III) fluoride; antimony pentafluoride at 35℃; for 4h;87%
chloroform-d1
865-49-6

chloroform-d1

Ir(CO)(H)2(C6H3(CH2P(CH(CH3)2)2)2)
193084-66-1, 193158-89-3

Ir(CO)(H)2(C6H3(CH2P(CH(CH3)2)2)2)

Ir(H)(Cl)(CO)(C6H3(CH2P(CH(CH3)2)2)2)
193084-78-5

Ir(H)(Cl)(CO)(C6H3(CH2P(CH(CH3)2)2)2)

Conditions
ConditionsYield
With triphenylphosphine In chloroform-d1 N2-atmosphere; room temp. (5 d); pptn. on pentane addn., washing (pentane);86.1%
dichloro bis(acetonitrile) palladium(II)
21264-30-2, 90243-59-7, 14592-56-4

dichloro bis(acetonitrile) palladium(II)

chloroform-d1
865-49-6

chloroform-d1

(E)-N,N'-dicyclohexyl-N-diphenylphosphino-4-acetamidine
1018686-28-6

(E)-N,N'-dicyclohexyl-N-diphenylphosphino-4-acetamidine

N,N'-dicyclohexyl-N-diphenylphosphino-acetamidine palladium dichloride*chloroform-d1
1018686-41-3

N,N'-dicyclohexyl-N-diphenylphosphino-acetamidine palladium dichloride*chloroform-d1

Conditions
ConditionsYield
In dichloromethane (N2); addn. of CH2Cl2 soln. of amidine deriv. to suspn. of palladium compd. in CH2Cl2, stirring for 18 h; evapn., washing with ether, dissolving in CDCl3, layering with hexane, keeping for 1 wk, isolation of crystals, elem. anal.;84%
2-ethyl-4,5-dihydrooxazole
10431-98-8

2-ethyl-4,5-dihydrooxazole

chloroform-d1
865-49-6

chloroform-d1

2-(trimethylsilyl)phenyl trifluoromethanesulfonate
88284-48-4

2-(trimethylsilyl)phenyl trifluoromethanesulfonate

C12H13(2)HCl3NO

C12H13(2)HCl3NO

Conditions
ConditionsYield
With potassium fluoride; 18-crown-6 ether at 60℃; for 12h; Inert atmosphere;80%
methyl 7β-[syn-2-(2-tritylaminothiazol-4-yl)-2-methoxyiminoacetamido]-3-acetoxymethyl-3-cephem-4-carboxylate

methyl 7β-[syn-2-(2-tritylaminothiazol-4-yl)-2-methoxyiminoacetamido]-3-acetoxymethyl-3-cephem-4-carboxylate

chloroform-d1
865-49-6

chloroform-d1

trimethylsilyl iodide
16029-98-4

trimethylsilyl iodide

Methyl 7β-[syn-2-(2-tritylaminothiazol-4-yl)-2-methoxyiminoacetamido]-3-iodomethyl-3-cephem-4-carboxylate

Methyl 7β-[syn-2-(2-tritylaminothiazol-4-yl)-2-methoxyiminoacetamido]-3-iodomethyl-3-cephem-4-carboxylate

Conditions
ConditionsYield
With sodium hydrogencarbonate; sodium hydrogensulfite76%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

chloroform-d1
865-49-6

chloroform-d1

1’-(diphenylphosphanyl)-1-cyanoferrocene

1’-(diphenylphosphanyl)-1-cyanoferrocene

[Ag(μ-1’-(diphenylphosphino)-1-cyanoferrocene)]2[BF4]2*0.1CHCl3

[Ag(μ-1’-(diphenylphosphino)-1-cyanoferrocene)]2[BF4]2*0.1CHCl3

Conditions
ConditionsYield
for 1h; Inert atmosphere; Darkness;76%
chloroform-d1
865-49-6

chloroform-d1

Cp(*)Ru[η(5)-CH2CHCHCHN(CMe3)]
222721-28-0

Cp(*)Ru[η(5)-CH2CHCHCHN(CMe3)]

A

Cp(*)Ru[η(4)-CH2=CHCH=CHNH(CMe3)]Cl
222721-22-4

Cp(*)Ru[η(4)-CH2=CHCH=CHNH(CMe3)]Cl

Cp(*)Ru[η(3)-CH2CHCHCH=N(CMe3)](Cl)2-syn-cis

Cp(*)Ru[η(3)-CH2CHCHCH=N(CMe3)](Cl)2-syn-cis

Cp(*)Ru[η(3)-CH2CHCHCH=N(CMe3)](Cl)2-syn-trans

Cp(*)Ru[η(3)-CH2CHCHCH=N(CMe3)](Cl)2-syn-trans

Conditions
ConditionsYield
In chloroform-d1 N2-atmosphere; 30 min; not isolated; detd. by (1)H NMR spectroscopy;A 12.5%
B 75%
C 12.5%
Grubbs catalyst first generation

Grubbs catalyst first generation

chloroform-d1
865-49-6

chloroform-d1

p-chlorophenyl isocyanide
1885-81-0

p-chlorophenyl isocyanide

[Ru(tricyclohexylphosphine)Cl2(p-chlorophenyl isocyanide)3]*CDCl3

[Ru(tricyclohexylphosphine)Cl2(p-chlorophenyl isocyanide)3]*CDCl3

Conditions
ConditionsYield
In benzene byproducts: PhCHP(C6H11)3; treatment of RuCl2(CHPh)(PCy3)2 with 3.3 equiv. of ClC6H4NC in benzene; crystn. from CDCl3 by slow diffusion of pentanes;75%

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