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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for t

High purity 3-Chloro-2-methylaniline 98% TOP1 supplier in China

Cas:87-60-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Methyl-3-Chloroaniline supplier in China

Cas:87-60-5

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 3-chloro-o-toluidine

Cas:87-60-5

Min.Order:1

Negotiable

Type:Other

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price Dyes Pigments 3-Chloro-2-methylaniline 87-60-5 Manufacturer

Cas:87-60-5

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

3-Chloro-2-methylaniline

Cas:87-60-5

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

inquiry

COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

3-Chloro-2-Methylaniline

Cas:87-60-5

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Shanghai Seasonsgreen Chemical Co.,Ltd

Shanghai Seasonsgreen Chemical is a high-tech research and development, production, sale and custom synthesis set in one high-tech bio chemical products enterprises. The company's sales and marketing division is located in Shanghai, serving int

lower price high purity 3-Chloro-2-methylaniline CAS 87-60-5

Cas:87-60-5

Min.Order:1 Kilogram

FOB Price: $300.0

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-Chloro-o-toluidine (NH2=1)

Cas:87-60-5

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

CHENGDU YANXI is a comprehensive manufacturer and an international distribution of products throughout the world. Specialized in Scrap metal, Chemical raw materials, Paper products and color industry. We aim to become leading position in global dis

3-Chloro-2-methylaniline Pharmaceutical intermediates 87-60-5

Cas:87-60-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name: 3-Chloro-2-methylaniline Synonyms: 3-CHLORO-2-METHYLANILINE;Azoic Diazo Component 46;CI 37080;LABOTEST-BB LTBB000775;FAST SCARLET TR BASE;TIMTEC-BB SBB007550;1-Amino-3-chloro-2-methylbenzene;2-amino-6-chloro-toluen

87-60-5 2-amino-6-chloro-toluen

Cas:87-60-5

Min.Order:1 Gram

FOB Price: $8900.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

3-Chloro-2-methylaniline

Cas:87-60-5

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 87-60-5 with fast shipping

Cas:87-60-5

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

3-Chloro-2-methylaniline

Cas:87-60-5

Min.Order:1 Kilogram

FOB Price: $42.0 / 45.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Name: 3-Chloro-2-methylaniline Synonyms: 3-Chloro-o-toluidine CAS:87-60-5 MF: C7H8ClN Appearance: white powder Storage:Store in cool and dry place, away from sun light. Package: 25kgs/drum Application:Agrochemical Intermediates, Dyestuff Intermed

3-Chloro-2-methylaniline

Cas:87-60-5

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Appearance:Clear yellow to red or red-brown liquid Storage:Room temperature Package:25kg/Barrel, 200kg/Barrel Application:Organic Synthesis Intermediate Transportation:Express/Sea/Air Port:Any port in china

High Purity 3-Chloro-2-methylaniline 98% Factory Supply 3-chloro-o-toluidine

Cas:87-60-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzenamine,3-chloro-2-methyl- 87-60-5

Cas:87-60-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the

Benzenamine,3-chloro-2-methyl-/ LIDE PHARMA- Factory supply / Best price

Cas:87-60-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

3-Chloro-2-methylaniline CAS:87-60-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic int

3-Chloro-2-methylaniline CAS:87-60-5

Cas:87-60-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzenamine,3-chloro-2-methyl-

Cas:87-60-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Minimum Order Qty. 10 Gram Supply Ability 500 Kilograms/Month Storage store in cool, dry, ventilated place 20℃ Delivery Time 3 business days after payment Payment Term TT,western union,Paypal,MoneyGram Package 10g,20g,50g,100g,500g,1KGS,

High purity 3-Chloro-2-methylaniline supplier in China CAS NO.87-60-5

Cas:87-60-5

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:87-60-5

Cas:87-60-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Mojin Biotechnology Co.,Ltd

Hebei Mojin Biotechnology Co., Ltd, Our company is a professional chemical raw materials and chemical reagents research and development production enterprises. We have several production line,So we can control the lowest price. We also have several

3-Chloro-2-methylaniline cas:87-60-5

Cas:87-60-5

Min.Order:25 Gram

FOB Price: $90.0 / 100.0

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

87-60-5 3-Chloro-2-methylaniline

Cas:87-60-5

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

3-CHLORO-2-METHYLANILINE

Cas:87-60-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3-Chloro-2-methylaniline

Cas:87-60-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 2-Methyl-3-Chloroaniline

Cas:87-60-5

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

High purity 3-Chloro-2-methylaniline 98% TOP1 supplier in China CAS NO.87-60-5Appearance:clear yellow to red or red-brown liquid Storage:Store in Cool and dry .place, keep away from incompatible substances Package:according to customers' requireme

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

87-60-5 3-Chloro-2-methylaniline

Cas:87-60-5

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:clear yellow to red or red-brown liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:For medi

3-Chloro-2-methylaniline

Cas:87-60-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Siwei Development Group Ltd.

Product name: 3-Chloro-2-Methylaniline CAS No.: 87-60-5 Molecule Formula:C7H8ClN Molecule Weight:141.60 Purity: 99.0% Package: 200kg/drum Description:Light yellow liquid Manufacture Standards:Enterprise Standard TE

Lower Price 3-Chloro-2-Methylaniline

Cas:87-60-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Synthetic route

6-chloro-2-nitrotoluene
83-42-1

6-chloro-2-nitrotoluene

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

Conditions
ConditionsYield
With hydrazine hydrate In ethanol for 0.333333h; Reflux;99.2%
With C20H32Cl4Cu2N4O4 In water at 60℃; for 1h; Inert atmosphere; Schlenk technique;99%
With ammonia borane; cetyltrimethylammonim bromide; [Ru(p-cymene)(2,6-bis(1-methylimidazole-2-thione)pyridine)](PF6)2 In water; acetonitrile at 79.84℃; for 24h; Inert atmosphere; Schlenk technique;97%
benzo-phenone imine

benzo-phenone imine

2,6-dichlorotoluene
118-69-4

2,6-dichlorotoluene

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

Conditions
ConditionsYield
Stage #1: benzo-phenone imine; 2,6-dichlorotoluene With sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0); 1,1'-bis(diphenylphosphino) ferrocene In xylene at 125℃; for 6h;
Stage #2: With hydrogenchloride In water; xylene at 65℃;
75.5%
[3-Chloro-2-(2-oxo-propyl)-phenyl]-carbamic acid tert-butyl ester
791066-15-4

[3-Chloro-2-(2-oxo-propyl)-phenyl]-carbamic acid tert-butyl ester

A

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

B

4-chloro-2-methyl-1H-indole
6127-16-8

4-chloro-2-methyl-1H-indole

Conditions
ConditionsYield
With trifluoroacetic acid In dichloromethane at 20℃; for 120h;A n/a
B 69%
6-chloro-2-nitrotoluene
83-42-1

6-chloro-2-nitrotoluene

A

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

B

bis-(3-chloro-2-methyl-phenyl)-diazene-N-oxide
76273-99-9

bis-(3-chloro-2-methyl-phenyl)-diazene-N-oxide

Conditions
ConditionsYield
With alkaline aqueous methanol. sodium arsenite
6-chloro-2-nitrotoluene
83-42-1

6-chloro-2-nitrotoluene

sodium n-propoxide
6819-41-6

sodium n-propoxide

benzene
71-43-2

benzene

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

6-chloro-2-nitrotoluene
83-42-1

6-chloro-2-nitrotoluene

acid

acid

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

1-methyl-2-nitrobenzene
88-72-2

1-methyl-2-nitrobenzene

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: SbCl5; chlorine / <40
2: tin; hydrochloric acid
View Scheme
Multi-step reaction with 2 steps
1: iron turnings / durch Chlorierung
2: iron powder; diluted hydrochloric acid
View Scheme
Multi-step reaction with 2 steps
1: antimonypentachloride / durch Chlorierung
View Scheme
acetic anhydride
108-24-7

acetic anhydride

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

N-(3-chloro-2-methylphenyl)acetamide
7463-35-6

N-(3-chloro-2-methylphenyl)acetamide

Conditions
ConditionsYield
In ethanol at 20℃; for 2h;100%
In ethanol at 20℃; for 2h;100%
In ethanol at 20℃; for 2h;100%
3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

4-chloro-1H-indazole
13096-96-3

4-chloro-1H-indazole

Conditions
ConditionsYield
Stage #1: 3-chloro-2-methylbenzenamine With potassium acetate; acetic anhydride In chloroform at 0 - 25℃; for 1.03333h;
Stage #2: With isopentyl nitrite In chloroform at 60℃;
100%
Stage #1: 3-chloro-2-methylbenzenamine With potassium acetate; acetic anhydride In chloroform at 0 - 25℃; for 1.03333h;
Stage #2: With isopentyl nitrite In chloroform at 60℃;
Stage #3: With lithium hydroxide; water In tetrahydrofuran; chloroform at 0℃; for 3h;
100%
Stage #1: 3-chloro-2-methylbenzenamine With potassium acetate In chloroform at 0℃;
Stage #2: With acetic anhydride at 25℃; for 1h;
Stage #3: With lithium hydroxide; isopentyl nitrite
100%
3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

phenylboronic acid
98-80-6

phenylboronic acid

2-methyl-[1,1′-biphenyl]-3-amine
172975-98-3

2-methyl-[1,1′-biphenyl]-3-amine

Conditions
ConditionsYield
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); XPhos In 1,4-dioxane at 110℃; for 8h; Inert atmosphere;99.2%
3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

(3-chloro-2-methylphenyl)hydrazine
39943-64-1

(3-chloro-2-methylphenyl)hydrazine

Conditions
ConditionsYield
Stage #1: 3-chloro-2-methylbenzenamine With hydrogenchloride; trifluoroacetic acid In water at 20℃; for 0.166667h;
Stage #2: With sodium nitrite In water at 0℃; for 1h;
Stage #3: With hydrogenchloride; tin(ll) chloride In water at 20℃;
98%
With polystyrene-supported phenylsulfonylhydroxylamine In dichloromethane at 0 - 20℃;
N-isopropyldichloroacetimidoyl chloride

N-isopropyldichloroacetimidoyl chloride

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

N-3-Chloro-2-methylphenyl-N'-isopropyldichloroacetamidine
79165-61-0

N-3-Chloro-2-methylphenyl-N'-isopropyldichloroacetamidine

Conditions
ConditionsYield
With sodium hydroxide97.7%
3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

N-(4-bromo-3-chloro-2-methylphenyl)acetamide
125328-80-5

N-(4-bromo-3-chloro-2-methylphenyl)acetamide

Conditions
ConditionsYield
96%
Multi-step reaction with 2 steps
1: 100 percent / ethanol / 2 h / 20 °C
2: 96 percent / bromine; glacial acetic acid / 2 h
View Scheme
Multi-step reaction with 2 steps
1: AcOH; NaOH
2: Br2
View Scheme
pivaloyl chloride
3282-30-2

pivaloyl chloride

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

3'-chloro-2'-methylpivalanilide
114153-36-5

3'-chloro-2'-methylpivalanilide

Conditions
ConditionsYield
With sodium carbonate In dichloromethane; water at 80℃; for 2h;95%
With triethylamine In dichloromethane at 0℃;
3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

orthoformic acid triethyl ester
122-51-0

orthoformic acid triethyl ester

1-(2-methyl-3-chlorophenyl)-1H-1,2,3,4-tetrazole

1-(2-methyl-3-chlorophenyl)-1H-1,2,3,4-tetrazole

Conditions
ConditionsYield
With sodium azide In N,N-dimethyl-formamide at 50℃; for 1h; Green chemistry;95%
With sodium azide; ytterbium(III) triflate In 2-methoxy-ethanol at 100℃; for 9h;75%
3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

PCM-0102130
99585-94-1

PCM-0102130

Conditions
ConditionsYield
95%
formic acid
64-18-6

formic acid

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

N-(3-chloro-2-methylphenyl)formamide
71862-02-7

N-(3-chloro-2-methylphenyl)formamide

Conditions
ConditionsYield
With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 0 - 20℃; for 12h;95%
With Co3O4 nanoparticles at 40℃; for 0.25h; Green chemistry;92%
Stage #1: formic acid With acetic anhydride
Stage #2: 3-chloro-2-methylbenzenamine
3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

3-chloro-o-cresol
3260-87-5

3-chloro-o-cresol

Conditions
ConditionsYield
With sulfuric acid; sodium nitrite at 10 - 90℃; for 0.25h; Solvent;93.1%
Stage #1: 3-chloro-2-methylbenzenamine With sulfuric acid In water at 90℃;
Stage #2: With water; sodium nitrite at 0 - 20℃; for 2h;
Stage #3: With sulfuric acid; urea In water at 90℃; for 1h;
83%
Stage #1: 3-chloro-2-methylbenzenamine With sulfuric acid In water at 0 - 90℃;
Stage #2: With sodium nitrite In water at 0 - 20℃; for 2h;
Stage #3: With sulfuric acid; urea more than 3 stages;
83%
phthalic anhydride
85-44-9

phthalic anhydride

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

N-(3-chloro-2-methyl-phenyl)-phthalimide
57023-59-3

N-(3-chloro-2-methyl-phenyl)-phthalimide

Conditions
ConditionsYield
for 0.141667h; microwave irradiation;93%
3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

acrolein
107-02-8

acrolein

7-Chloro-8-methylquinoline
78941-93-2

7-Chloro-8-methylquinoline

Conditions
ConditionsYield
Stage #1: 3-chloro-2-methylbenzenamine With hydrogenchloride In octanol at 70 - 80℃;
Stage #2: acrolein With 6-chloro-2-nitrotoluene In octanol at 148 - 155℃; for 12h; Solvent; Reagent/catalyst;
93%
3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

glycerol
56-81-5

glycerol

7-Chloro-8-methylquinoline
78941-93-2

7-Chloro-8-methylquinoline

Conditions
ConditionsYield
Stage #1: 3-chloro-2-methylbenzenamine; glycerol With sulfuric acid; water; sodium iodide at 120 - 140℃; for 7h;
Stage #2: With water; sodium hydroxide In Petroleum ether at 30 - 120℃; for 1h; pH=9 - 10;
92.1%
Stage #1: 3-chloro-2-methylbenzenamine; glycerol With sulfuric acid; sodium iodide at 120 - 140℃; for 7h; Cooling with ice;
Stage #2: With water; sodium hydroxide In Petroleum ether at 30 - 120℃; for 1h; pH=9 - 10;
92.1%
With sulfuric acid; potassium iodide In water at 80 - 150℃; for 7h;92.9%
2,4,7-trinitrofluorene-9-one
129-79-3

2,4,7-trinitrofluorene-9-one

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

(3-Chloro-2-methyl-phenyl)-[2,4,7-trinitro-fluoren-(9E)-ylidene]-amine

(3-Chloro-2-methyl-phenyl)-[2,4,7-trinitro-fluoren-(9E)-ylidene]-amine

Conditions
ConditionsYield
With zinc(II) chloride at 150 - 170℃;92%
3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

2-(2-methyl-3-chlorophenyl)amino-carbonyl-3-pyridinecarboxylic acid

2-(2-methyl-3-chlorophenyl)amino-carbonyl-3-pyridinecarboxylic acid

Conditions
ConditionsYield
In tetrahydrofuran92%
1,3-cylohexanedione
504-02-9

1,3-cylohexanedione

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

3-(3-chloro-2-methylphenylamino)cyclohex-2-enone
153865-45-3

3-(3-chloro-2-methylphenylamino)cyclohex-2-enone

Conditions
ConditionsYield
With ytterbium(III) triflate In acetonitrile at 20℃; for 0.5h;92%
2-[(2-oxo-2H-chromen-4-yl)oxy]propanoic acid
1412905-05-5

2-[(2-oxo-2H-chromen-4-yl)oxy]propanoic acid

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

N-(3-chloro-2-methylphenyl)-2-(2-oxo-2H-chromen-4-yloxy)propanamide
1412905-06-6

N-(3-chloro-2-methylphenyl)-2-(2-oxo-2H-chromen-4-yloxy)propanamide

Conditions
ConditionsYield
With HATU In N,N-dimethyl-formamide at 20℃; Inert atmosphere;92%
4-chlorobenzaldehyde
104-88-1

4-chlorobenzaldehyde

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

benzil
134-81-6

benzil

1-(3-chloro-2-methylphenyl)-2(4-chlorophenyl)-4,5-diphenyl-1H-imidazole

1-(3-chloro-2-methylphenyl)-2(4-chlorophenyl)-4,5-diphenyl-1H-imidazole

Conditions
ConditionsYield
With zinc(II) oxide; ammonium acetate; acetic acid at 60℃; for 2h;92%
3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

dimethylglyoxal
431-03-8

dimethylglyoxal

bis[N,N'-(3-chloro-2-methylphenyl)imino]-1,2-dimethylethane
1331830-77-3

bis[N,N'-(3-chloro-2-methylphenyl)imino]-1,2-dimethylethane

Conditions
ConditionsYield
With formic acid In methanol for 24h; Reflux;91%
9-fluorenone
486-25-9

9-fluorenone

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

9,9-bis[2-chloro-3-methyl-4-aminophenyl]fluorene

9,9-bis[2-chloro-3-methyl-4-aminophenyl]fluorene

Conditions
ConditionsYield
Stage #1: 3-chloro-2-methylbenzenamine With sulfuric acid In ethylene glycol at 20 - 50℃; for 0.5h;
Stage #2: 9-fluorenone In ethylene glycol at 140℃;
90.1%
styrene oxide
96-09-3

styrene oxide

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

2-(3-chloro-2-methylphenylamino)-2-phenylethanol

2-(3-chloro-2-methylphenylamino)-2-phenylethanol

Conditions
ConditionsYield
With niobium pentachloride In dichloromethane at 20℃; for 1h;90%
ammonium thiocyanate
1147550-11-5

ammonium thiocyanate

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

4-amino-2-chloro-3-methylphenyl thiocyanate
14030-84-3

4-amino-2-chloro-3-methylphenyl thiocyanate

Conditions
ConditionsYield
With iodine In methanol at 20℃; for 48h;90%
3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

cyclohexane-1,2-dione
765-87-7

cyclohexane-1,2-dione

2-(3-chloro-2-methylphenylamino)cyclohex-2-en-1-one
1418129-50-6

2-(3-chloro-2-methylphenylamino)cyclohex-2-en-1-one

Conditions
ConditionsYield
In toluene for 12h; Inert atmosphere; Reflux;90%
4-methylphthalic anhydride
19438-61-0

4-methylphthalic anhydride

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

2-(3-chloro-2-methyl-phenyl)-5-methyl-isoindole-1,3-dione

2-(3-chloro-2-methyl-phenyl)-5-methyl-isoindole-1,3-dione

Conditions
ConditionsYield
for 0.141667h; microwave irradiation;89%
2-bromo-N,N-diethylbenzamide
76041-86-6

2-bromo-N,N-diethylbenzamide

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

N,N-diethyl-2-(3-chloro-2-methylanilino)benzamide
1093239-35-0

N,N-diethyl-2-(3-chloro-2-methylanilino)benzamide

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene at 100 - 110℃; for 14h; Buchwald-Hartwig C-N cross coupling;89%
3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

2,6-dichlorotoluene
118-69-4

2,6-dichlorotoluene

Conditions
ConditionsYield
Stage #1: 3-chloro-2-methylbenzenamine With potassium nitrite; potassium chloride In water at 8 - 90℃; for 0.666667h;
Stage #2: With nickel nitrate; potassium chloride In water at 60℃; for 2.83333h; Concentration; Temperature; Reagent/catalyst;
89%
4-methoxy-1,3-benzenedicarbonyl dichloride
13235-60-4

4-methoxy-1,3-benzenedicarbonyl dichloride

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

N1,N3-bis(3-chloro-2-methylphenyl)-4-methoxyisophthalamide

N1,N3-bis(3-chloro-2-methylphenyl)-4-methoxyisophthalamide

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 72h; Solvent; Temperature;89%
Stage #1: 4-methoxy-1,3-benzenedicarbonyl dichloride; 3-chloro-2-methylbenzenamine In tetrahydrofuran; dichloromethane at 20℃; for 10h;
Stage #2: With triethylamine In tetrahydrofuran; dichloromethane at 20℃; for 24h;
85.1%
dimedone
126-81-8

dimedone

3-chloro-2-methylbenzenamine
87-60-5

3-chloro-2-methylbenzenamine

α-bromoacetophenone
70-11-1

α-bromoacetophenone

1-(3-chloro-2-methylphenyl)-6,6-dimethyl-2-phenyl-1,5,6,7-tetrahydro-4H-indol-4-one

1-(3-chloro-2-methylphenyl)-6,6-dimethyl-2-phenyl-1,5,6,7-tetrahydro-4H-indol-4-one

Conditions
ConditionsYield
With aminosulfonic acid In neat (no solvent) at 20℃; for 1h; Milling; Green chemistry;89%
In ethanol; water at 20℃; for 4h; Irradiation; Green chemistry;89%
With Wang resin-supported sulfonic acid In water at 80 - 85℃;88%
With β‐cyclodextrin In water at 90 - 100℃; for 6.5h; Green chemistry;88%

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