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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

1,2,3-Trichlorobenzene Manufacturer/High quality/Best price/In stock

Cas:87-61-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 1,2,3-Trichlorobenzene supplier in China

Cas:87-61-6

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory supply 1,2,3-Trichlorobenzene

Cas:87-61-6

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1,2,3-Trichlorobenzene

Cas:87-61-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:87-61-6

Cas:87-61-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

1,2,3-Trichlorobenzene

Cas:87-61-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,2,3-Trichlorobenzene

Cas:87-61-6

Min.Order:0

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Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 1,2,3-Trichlorobenzene

Cas:87-61-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality Appearance:White crystalline Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Mainly used for making all pyromellitic dianhydride,

1,2,3-Trichlorobenzene

Cas:87-61-6

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

1,2,3-Trichlorobenzene Chemical Properties Melting point 51-53 °C(lit.) Boiling point 218-219 °C(lit.)

87-61-6 1,2,3-Trichlorobenzene

Cas:87-61-6

Min.Order:1 Metric Ton

FOB Price: $20.0

Type:Lab/Research institutions

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Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

1,2,3-Trichlorobenzene

Cas:87-61-6

Min.Order:0

Negotiable

Type:Trading Company

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

1,2,3-Trichlorobenzene

Cas:87-61-6

Min.Order:0

Negotiable

Type:Manufacturers

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Greenutra Resource Inc

3-Chloro-2-methylanilineAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air

3-Chloro-2-methylaniline

Cas:87-61-6

Min.Order:0

Negotiable

Type:Trading Company

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

3-Chloro-2-methylaniline

Cas:87-61-6

Min.Order:0

Negotiable

Type:Other

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

1,2,3-Trichlorobenzene (1Mg/ML in Methanol) [for Water Analysis]

Cas:87-61-6

Min.Order:0

Negotiable

Type:Manufacturers

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Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

1,2,3-Trichlorobenzene

Cas:87-61-6

Min.Order:0

Negotiable

Type:Manufacturers

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city?in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api,?intermediat

1,2,3-Trichlorobenzene

Cas:87-61-6

Min.Order:0

Negotiable

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 87-61-6 with competitive price

Cas:87-61-6

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1,2,3-Trichlorobenzene

Cas:87-61-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

1,2,3-Trichlorobenzene

Cas:87-61-6

Min.Order:0

Negotiable

Type:Other

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Hangzhou Fandachem Co.,Ltd

1,2,3-TrichlorobenzeneAppearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

1,2,3-Trichlorobenzene

Cas:87-61-6

Min.Order:0

Negotiable

Type:Other

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Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

1,2,3-Trichlorobenzene 87-61-6

Cas:87-61-6

Min.Order:0

Negotiable

Type:Trading Company

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Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

1,2,3-Trichlorobenzene

Cas:87-61-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Bide Pharmatech Ltd

Our mission is to provide high-quality and innovative products to our customers. By offering a broad range of products, custom synthesis and personalized services, Bide can help scientists speeding up their research in the chemical and pharmaceutical

1,2,3-Trichlorobenzene

Cas:87-61-6

Min.Order:0

Negotiable

Type:Other

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Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#87-61-6;CAT#A842294

Cas:87-61-6

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

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Hebei Yingong New Material Technology Co.,Ltd .

High quality, best service,competitive price are our principle 1.Low price & high quality products (G-KG) & first-class service are waiting for our clients 2.Professional transport team to ensure the goods safety and on time arrived your

1,2,3-trichlorobenzene

Cas:87-61-6

Min.Order:10 Gram

FOB Price: $3.0 / 4.0

Type:Trading Company

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HENAN SUNLAKE ENTERPRISE CORPORATION

1,2,3-Trichlorobenzene Basic information Product Name: 1,2,3-Trichlorobenzene Synonyms: 1,2,3-TRICHLOROBENZENE;1,2,3-TCB;1,2,3-trcb;1,2,3-trichloro-benzen;1,2,6-Tri

1,2,3-Trichlorobenzene

Cas:87-61-6

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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SuZhou LaiTeou

1, Quality: Our company is a professional production of intermediates and chemicals for many years, our products have exported to Germany, Spain, UK, USA, Australia, Middle East, and so on other country, and we have got very good feedback

1,2,3-Trichlorobenzene

Cas:87-61-6

Min.Order:1 Kilogram

FOB Price: $23.0

Type:Trading Company

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suzhou BetterBioChem Co., Ltd.

Betterbiochem is specialized in APIs, pharmaceutical intermediates & fine chemicals. 1. The best quality, competitive price. 2. The best service before or after shipment. 3. Rich experience in export operation. 4. Rich experience in

1,2,3-TRICHLOROBENZENE

Cas:87-61-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Xiamen BaiFuchem Co.,Ltd

BaiFuChem is a Professional chemical raw material supplier in China, our main products include Biochemical , Pharma Intermediate and Organic chemical etc. BaiFuChem have wealth of products,experience , expertise and state-of-the-art

High purity 1,2,3-Trichlorobenzene

Cas:87-61-6

Min.Order:1 Kilogram

Negotiable

Type:Other

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Synthetic route

1,2-Dichloro-3-nitrobenzene
3209-22-1

1,2-Dichloro-3-nitrobenzene

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
With Dichlorophenylphosphine In various solvent(s) at 170℃; for 5h;93%
LINDANE
58-89-9

LINDANE

A

1,3,5-trichlorobenzene
108-70-3

1,3,5-trichlorobenzene

B

1,2,4-Trichlorobenzene
120-82-1

1,2,4-Trichlorobenzene

C

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
With ammonia at 25℃; Product distribution; Further Variations:; Reagents; Dehalogenation;A 5%
B 87%
C 8%
at 25℃; pH=8.32; Kinetics; Product distribution; Further Variations:; pH-values;
With (5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato)iron(III) chloride; tetrabutylammonium perchlorate In N,N-dimethyl-formamide for 4h; Electrolysis;
bromobenzene
108-86-1

bromobenzene

2,5-bis-trimethylstannanyl-thiophene
86134-26-1

2,5-bis-trimethylstannanyl-thiophene

tributylphenylstannane
960-16-7

tributylphenylstannane

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0) In methanol; chloroform; chlorobenzene83%
1,2-dichloro-benzene
95-50-1

1,2-dichloro-benzene

A

1,2,4-Trichlorobenzene
120-82-1

1,2,4-Trichlorobenzene

B

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
With chlorine; K-L' zeolite at -25.1℃; for 10h;A 81.1%
B 5.8%
With chlorine; H.K-L zeolite at -25.1℃; for 3h; Product distribution; further catalysts;A 65.8%
B 16.9%
With chlorine; iron(III) chloride at -25.1℃; for 2h;A 39%
B 17.6%
1,2,3,5-tetrachlorobenzene
634-90-2

1,2,3,5-tetrachlorobenzene

A

1,3,5-trichlorobenzene
108-70-3

1,3,5-trichlorobenzene

B

1,2,4-Trichlorobenzene
120-82-1

1,2,4-Trichlorobenzene

C

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
With radical anion of p,p'-di-tert-butylbiphenyl; triethylamine In tetrahydrofuran at 45℃; Irradiation;A 18.8%
B 75.5%
C 5.7%
With radical anion of p,p'-di-tert-butylbiphenyl; triethylamine In tetrahydrofuran at 45℃; Product distribution; Rate constant; Mechanism; Irradiation; radical anion of naphthalene, different temperatures, without Et3N;A 18.8%
B 75.5%
C 5.7%
With radical anion of p,p'-di-tert-butylbiphenyl In tetrahydrofuran at 45℃; Irradiation;A 59.2%
B 40.5%
C 0.3%
In acetonitrile at 40℃; Product distribution; Mechanism; Quantum yield; Irradiation; in the presence of triethylamine;A 18.77 % Chromat.
B 75.45 % Chromat.
C 5.78 % Chromat.
With sodium bis(2-methoxyethoxy)aluminium dihydride In toluene at 70℃; Rate constant; relative reactivity in dehalogenation;
bromobenzene
108-86-1

bromobenzene

tributylphenylstannane
960-16-7

tributylphenylstannane

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0) In methanol; chloroform; chlorobenzene26%
2,6-dichloroanisole
1984-65-2

2,6-dichloroanisole

A

2,6-dichloro(dichloromethoxy) benzene

2,6-dichloro(dichloromethoxy) benzene

B

1,3-Dichloro-2-trichloromethoxy-benzene
97608-48-5

1,3-Dichloro-2-trichloromethoxy-benzene

C

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
With chlorine; phosphorus pentachloride at 195℃; for 11.5h;A n/a
B 24.5%
C n/a
pyridine
110-86-1

pyridine

alpha-hexachlorocyclohexane
319-84-6

alpha-hexachlorocyclohexane

A

1,3,5-trichlorobenzene
108-70-3

1,3,5-trichlorobenzene

B

1,2,4-Trichlorobenzene
120-82-1

1,2,4-Trichlorobenzene

C

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

quinoline
91-22-5

quinoline

alpha-hexachlorocyclohexane
319-84-6

alpha-hexachlorocyclohexane

A

1,3,5-trichlorobenzene
108-70-3

1,3,5-trichlorobenzene

B

1,2,4-Trichlorobenzene
120-82-1

1,2,4-Trichlorobenzene

C

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
at 105 - 110℃;
ethanol
64-17-5

ethanol

delta-lindane
319-86-8

delta-lindane

furan-2,3,5(4H)-trione pyridine (1:1)

furan-2,3,5(4H)-trione pyridine (1:1)

A

1,3,5-trichlorobenzene
108-70-3

1,3,5-trichlorobenzene

B

1,2,4-Trichlorobenzene
120-82-1

1,2,4-Trichlorobenzene

C

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
Product distribution;
ethanol
64-17-5

ethanol

LINDANE
58-89-9

LINDANE

furan-2,3,5(4H)-trione pyridine (1:1)

furan-2,3,5(4H)-trione pyridine (1:1)

A

1,3,5-trichlorobenzene
108-70-3

1,3,5-trichlorobenzene

B

1,2,4-Trichlorobenzene
120-82-1

1,2,4-Trichlorobenzene

C

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
Product distribution;
ethanol
64-17-5

ethanol

beta-hexachlorocyclohexane
319-85-7

beta-hexachlorocyclohexane

furan-2,3,5(4H)-trione pyridine (1:1)

furan-2,3,5(4H)-trione pyridine (1:1)

A

1,3,5-trichlorobenzene
108-70-3

1,3,5-trichlorobenzene

B

1,2,4-Trichlorobenzene
120-82-1

1,2,4-Trichlorobenzene

C

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
Product distribution;
ethanol
64-17-5

ethanol

alpha-hexachlorocyclohexane
319-84-6

alpha-hexachlorocyclohexane

furan-2,3,5(4H)-trione pyridine (1:1)

furan-2,3,5(4H)-trione pyridine (1:1)

A

1,3,5-trichlorobenzene
108-70-3

1,3,5-trichlorobenzene

B

1,2,4-Trichlorobenzene
120-82-1

1,2,4-Trichlorobenzene

C

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
Product distribution;
2,3,4-trichloroaniline
634-67-3

2,3,4-trichloroaniline

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
Diazotization.Erwaermen der Diazoniumsalz-Loesung mit Aethanol;
With ethyl nitrite
alpha-hexachlorocyclohexane
319-84-6

alpha-hexachlorocyclohexane

furan-2,3,5(4H)-trione pyridine (1:1)

furan-2,3,5(4H)-trione pyridine (1:1)

A

1,3,5-trichlorobenzene
108-70-3

1,3,5-trichlorobenzene

B

1,2,4-Trichlorobenzene
120-82-1

1,2,4-Trichlorobenzene

C

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

2,3-dichloroaniline
608-27-5

2,3-dichloroaniline

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
Diazotization;
3,4,5-trichloroaniline
634-91-3

3,4,5-trichloroaniline

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

2,6-Dichloroaniline
608-31-1

2,6-Dichloroaniline

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
Durch Ersatz der NH2-Gruppe durch Cl;
Diazotization;
benzene
71-43-2

benzene

A

para-dichlorobenzene
106-46-7

para-dichlorobenzene

B

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
With chlorine at 65℃;
1,2,3,4,-tetrachlorobenzene
634-66-2

1,2,3,4,-tetrachlorobenzene

A

1,2,4,5-tetrachlorobenzene
95-94-3

1,2,4,5-tetrachlorobenzene

B

chloroacetonitrile
107-14-2

chloroacetonitrile

C

1,2,4-Trichlorobenzene
120-82-1

1,2,4-Trichlorobenzene

D

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
In acetonitrile for 8h; Product distribution; Irradiation;A 3 % Chromat.
B 1 % Chromat.
C 18 % Chromat.
D 2 % Chromat.
1,2,3,4,-tetrachlorobenzene
634-66-2

1,2,3,4,-tetrachlorobenzene

A

para-dichlorobenzene
106-46-7

para-dichlorobenzene

B

chlorobenzene
108-90-7

chlorobenzene

C

1,2-dichloro-benzene
95-50-1

1,2-dichloro-benzene

D

1,3-Dichlorobenzene
541-73-1

1,3-Dichlorobenzene

E

1,2,4-Trichlorobenzene
120-82-1

1,2,4-Trichlorobenzene

F

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
With sodium tetrahydroborate In ethanol; acetonitrile at 40℃; for 1.3h; Product distribution; tetrahydro derivative of (2,12-dimethyl-3,7,11,17-tetraazabicyclo<11.3.1>heptadeca-1(17),2,11,13,15-pentaene)nickel(II) bis(tetrafluoroborate); other catalysts and solvents; other tetra-, tri- and dichlorobenzenes; with cumene; NH2OH*H2O used a reductor;
1,2,3,4,-tetrachlorobenzene
634-66-2

1,2,3,4,-tetrachlorobenzene

A

1,2,4-Trichlorobenzene
120-82-1

1,2,4-Trichlorobenzene

B

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
In acetonitrile at 40℃; Product distribution; Mechanism; Quantum yield; Irradiation; in the presence of triethylamine;A 80.12 % Chromat.
B 19.88 % Chromat.
With triethylamine; zinc sulfide In N,N-dimethyl-formamide Quantum yield; Further Variations:; Catalysts; UV-irradiation;
1,2,3-trichloro-4-iodobenzene
62720-28-9

1,2,3-trichloro-4-iodobenzene

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
With sodium methylate In methanol; dimethyl sulfoxide at 50.1℃; Rate constant;
1,2-dichloro-benzene
95-50-1

1,2-dichloro-benzene

benzene
71-43-2

benzene

A

para-dichlorobenzene
106-46-7

para-dichlorobenzene

B

chlorobenzene
108-90-7

chlorobenzene

C

1,3-Dichlorobenzene
541-73-1

1,3-Dichlorobenzene

D

1,2,4-Trichlorobenzene
120-82-1

1,2,4-Trichlorobenzene

E

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
PdCl2/C at 400℃; Mechanism; Product distribution; effect of different metal chloride catalyst supported on activated charcoal; effect of other carriers;
benzene
71-43-2

benzene

A

para-dichlorobenzene
106-46-7

para-dichlorobenzene

B

1,2-dichloro-benzene
95-50-1

1,2-dichloro-benzene

C

1,2,4-Trichlorobenzene
120-82-1

1,2,4-Trichlorobenzene

D

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
With potassium chloride; cobalt(III) acetate; trifluoroacetic acid at 25℃; for 168h; Product distribution; 1 - 5 d, various ratio of Co(CH3COO)3, KCl and benzene;
chlorobenzene
108-90-7

chlorobenzene

A

para-dichlorobenzene
106-46-7

para-dichlorobenzene

B

1,2-dichloro-benzene
95-50-1

1,2-dichloro-benzene

C

1,3-Dichlorobenzene
541-73-1

1,3-Dichlorobenzene

D

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

E

benzene
71-43-2

benzene

Conditions
ConditionsYield
With iron(II,III) oxide In cyclohexane at 224.9 - 349.9℃; Product distribution; other polychlorobenzenes, var. temp. and solv.;
pentachlorobenzene
608-93-5

pentachlorobenzene

A

1,2,4,5-tetrachlorobenzene
95-94-3

1,2,4,5-tetrachlorobenzene

B

1,2,3,4,-tetrachlorobenzene
634-66-2

1,2,3,4,-tetrachlorobenzene

C

1,2,4-Trichlorobenzene
120-82-1

1,2,4-Trichlorobenzene

D

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
With sodium tetrahydroborate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran for 90h; Product distribution; Ambient temperature; various highly chlorinated benzenes under different reaction conditions;
iron(III) chloride
7705-08-0

iron(III) chloride

1,2-dichloro-benzene
95-50-1

1,2-dichloro-benzene

A

1,3,5-trichlorobenzene
108-70-3

1,3,5-trichlorobenzene

B

1,2,4-Trichlorobenzene
120-82-1

1,2,4-Trichlorobenzene

C

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
at 135 - 188℃; Chlorierung;
ε-benzene hexachloride

ε-benzene hexachloride

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

Conditions
ConditionsYield
With sodium hydroxide at 20℃;
ethyl 2-hydroxyacetate
623-50-7

ethyl 2-hydroxyacetate

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

(dichloro-2,3 phenoxy)acetate d'ethyle
37536-92-8

(dichloro-2,3 phenoxy)acetate d'ethyle

Conditions
ConditionsYield
Stage #1: ethyl 2-hydroxyacetate With potassium methanolate at 30℃;
Stage #2: 1,2,3-trichlorobenzene at 100℃;
99.1%
isopropyl glycolate
623-61-0

isopropyl glycolate

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

isopropyl 2,3-dichlorophenoxyacetate

isopropyl 2,3-dichlorophenoxyacetate

Conditions
ConditionsYield
Stage #1: isopropyl glycolate With sodium isopropylate at 50℃;
Stage #2: 1,2,3-trichlorobenzene at 110℃;
98.9%
1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

A

4-nitro-1,2,3-trichlorobenzene
17700-09-3

4-nitro-1,2,3-trichlorobenzene

B

3,4,5-trichloronitrobenzen
20098-48-0

3,4,5-trichloronitrobenzen

Conditions
ConditionsYield
With nitric acid at 35℃; for 1h; Yields of byproduct given;A 98.1%
B n/a
With Nitrogen dioxide; ozone at 0 - 5℃; for 1.5h; Yield given. Yields of byproduct given;
With sulfuric acid; nitric acid at 80 - 85℃; for 2h; Yield given. Yields of byproduct given;
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
25015-63-8

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

3,4,5-trichlorophenylboronic acid pinacol ester

3,4,5-trichlorophenylboronic acid pinacol ester

Conditions
ConditionsYield
With IrH2(Bpin){κ3-P,O,P-[9,9-dimethyl-4,5-bis(diisopropylphosphino)xanthene]}; cyclohexene at 110℃; for 18h; Inert atmosphere; Glovebox;98%
With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine In neat (no solvent) at 80℃; for 2h; Inert atmosphere; Sealed tube;91%
With (η5-indenyl)(η4-1,5-cyclooctadiene)iridium(I); 1,2-bis(dimethylphosphanyl)ethane In cyclohexane at 150℃; for 3h;
(Ind)Ir(COD); 1,2-bis(dimethylphosphanyl)ethane In cyclohexane at 150℃; for 3h;
1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

phenylboronic acid
98-80-6

phenylboronic acid

1,2,3-triphenylbenzene
1165-14-6

1,2,3-triphenylbenzene

Conditions
ConditionsYield
With potassium phosphate; palladium bis(dibenzylideneacetone)palladium(0); catacxium A In toluene at 110℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere; Sealed tube;98%
4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

1,2,3-tris(4-methoxyphenyl)benzene

1,2,3-tris(4-methoxyphenyl)benzene

Conditions
ConditionsYield
With potassium phosphate; palladium bis(dibenzylideneacetone)palladium(0); catacxium A In toluene at 110℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere; Sealed tube;97%
4-trifluoromethylphenylboronic acid
128796-39-4

4-trifluoromethylphenylboronic acid

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

1,2,3-tris(4-(trifluoromethyl)phenyl)benzene

1,2,3-tris(4-(trifluoromethyl)phenyl)benzene

Conditions
ConditionsYield
With potassium phosphate; palladium bis(dibenzylideneacetone)palladium(0); catacxium A In toluene at 110℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere; Sealed tube;96%
3-methoxyphenylboronic acid
10365-98-7

3-methoxyphenylboronic acid

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

1,2,3-tris(3-methoxyphenyl)benzene

1,2,3-tris(3-methoxyphenyl)benzene

Conditions
ConditionsYield
With potassium phosphate; palladium bis(dibenzylideneacetone)palladium(0); catacxium A In toluene at 110℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere; Sealed tube;95%
1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

1-bromo-2,3,4-trichlorobenzene
81067-37-0

1-bromo-2,3,4-trichlorobenzene

Conditions
ConditionsYield
With N-Bromosuccinimide; sulfuric acid at 10 - 30℃; for 0.5h; Temperature;93.5%
With 1,3,5-tribromo-1,3,5-triazinane-2,4,6-trione In trifluoroacetic acid at 20℃; for 0.5h;68%
With bromine; iron In tetrachloromethane at 100℃; for 18h; Reagent/catalyst; Temperature; Solvent;1.68 g
1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

A

1,2,3-trichloro-4,6-dinitrobenzene
6379-46-0

1,2,3-trichloro-4,6-dinitrobenzene

B

1,2,3-trichloro-4,5-dinitro-benzene
13554-16-0

1,2,3-trichloro-4,5-dinitro-benzene

Conditions
ConditionsYield
With Concentrated HNO3; sulfuric acidA 93%
B n/a
4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

1,2,3-tris(4-tert-butylphenyl)benzene

1,2,3-tris(4-tert-butylphenyl)benzene

Conditions
ConditionsYield
With potassium phosphate; palladium bis(dibenzylideneacetone)palladium(0); catacxium A In toluene at 110℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere; Sealed tube;93%
carbon dioxide
124-38-9

carbon dioxide

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

2,3,4-trichlorobenzoic acid
50-75-9

2,3,4-trichlorobenzoic acid

Conditions
ConditionsYield
Stage #1: 1,2,3-trichlorobenzene With 2,2,6,6-tetramethylpiperidinyl-lithium In tetrahydrofuran; cyclohexane at -75℃; for 0.75h;
Stage #2: carbon dioxide In tetrahydrofuran; cyclohexane
90%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

trimethyl(2,3,4-trichlorophenyl)silane
915144-97-7

trimethyl(2,3,4-trichlorophenyl)silane

Conditions
ConditionsYield
Stage #1: 1,2,3-trichlorobenzene With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -75℃; for 2h;
Stage #2: chloro-trimethyl-silane In tetrahydrofuran; hexane
89%
sodium isopropanethiolate
20607-43-6

sodium isopropanethiolate

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

1,2,3-tris(isopropylthio)benzene
74542-66-8

1,2,3-tris(isopropylthio)benzene

Conditions
ConditionsYield
In N,N,N,N,N,N-hexamethylphosphoric triamide at 100℃; for 3h;88%
para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

1-chloro-2,6-bis(4-methylphenyl)benzene

1-chloro-2,6-bis(4-methylphenyl)benzene

Conditions
ConditionsYield
With 1-[2-(diphenylphosphino)phenyl]ethanol; bis(acetylacetonate)nickel(II) In diethyl ether at 20℃; for 24h;87%
Stage #1: para-methylphenylmagnesium bromide; 1,2,3-trichlorobenzene; 1-[2-(diphenylphosphino)phenyl]ethanol; bis(acetylacetonate)nickel(II) In diethyl ether for 24h;
Stage #2: With methanol In diethyl ether Product distribution / selectivity;
85%
1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

4-nitro-1,2,3-trichlorobenzene
17700-09-3

4-nitro-1,2,3-trichlorobenzene

Conditions
ConditionsYield
With sulfuric acid; nitric acid In 1,2-dichloro-ethane at 50 - 60℃; for 2.5h;86%
With nitric acid
With nitric acid In sulfuric acid; ethyl acetate
2-Methoxyphenylboronic acid
5720-06-9

2-Methoxyphenylboronic acid

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

1,2,3-tris(2-methoxyphenyl)benzene

1,2,3-tris(2-methoxyphenyl)benzene

Conditions
ConditionsYield
With potassium phosphate; palladium bis(dibenzylideneacetone)palladium(0); catacxium A In toluene at 110℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere; Sealed tube;82%
trichlorofluoromethane
75-69-4

trichlorofluoromethane

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

4,5,6-trichloro-1,3-bis(trifluoromethyl)benzene
327-72-0

4,5,6-trichloro-1,3-bis(trifluoromethyl)benzene

Conditions
ConditionsYield
With aluminium trichloride 1a) 8 h, r.t., 1b) 16 h, -10 deg C; 2) repetition of the procedure;80%
C8H7ClN2OS

C8H7ClN2OS

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

6-chloro-5-(2,3-dichlorophenoxy)-2-(methylthio)-1H-benzo[d]imidazole
68786-66-3

6-chloro-5-(2,3-dichlorophenoxy)-2-(methylthio)-1H-benzo[d]imidazole

Conditions
ConditionsYield
With N-benzyl-N,N,N-triethylammonium chloride; potassium carbonate In sulfolane at 100℃; for 3h; Temperature;77.3%
octylmagnesium bromide
17049-49-9

octylmagnesium bromide

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

2-Chloro-1,3-di-n-octylbenzene
87969-79-7

2-Chloro-1,3-di-n-octylbenzene

Conditions
ConditionsYield
1,2-bis(diphenylphosphino)ethane nickel(II) chloride In diethyl ether for 72h; Heating;71%
trichlorofluoromethane
75-69-4

trichlorofluoromethane

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

A

2,3,4-trichloro-1-(trifluoromethyl)benzene
61841-45-0

2,3,4-trichloro-1-(trifluoromethyl)benzene

B

4,5,6-trichloro-1,3-bis(trifluoromethyl)benzene
327-72-0

4,5,6-trichloro-1,3-bis(trifluoromethyl)benzene

Conditions
ConditionsYield
With aluminium trichloride for 4h; Ambient temperature;A 61%
B 5.5%
cyclopentadienylruthenium(II) trisacetonitrile hexafluorophosphate

cyclopentadienylruthenium(II) trisacetonitrile hexafluorophosphate

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

(η(5)-2,4-cyclopentadien-1-yl)(η(6)-1,2,3-trichlorobenzene)ruthenium hexafluorophosphate
174498-87-4

(η(5)-2,4-cyclopentadien-1-yl)(η(6)-1,2,3-trichlorobenzene)ruthenium hexafluorophosphate

Conditions
ConditionsYield
In 1,2-dichloro-ethane N2-atmosphere; refluxing Ru-complex with 0.84 equiv. of benzene derivative for 14-18 h; solvent removal, treatment with hexanes, chromy. (Al2O3, CH2Cl2/hexanes=1:1, CH2Cl2, CH2Cl2/EtOH=49:1); can be recrystallized (Me2CO/Et2O);61%
bis(tetra-n-butylammonium) dodecahydro-closo-dodecaborate

bis(tetra-n-butylammonium) dodecahydro-closo-dodecaborate

cesium acetate
3396-11-0

cesium acetate

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

2Cs(1+)*{(Cl3C6H2)B12H11}(2-) = Cs2{(Cl3C6H2)B12H11}

2Cs(1+)*{(Cl3C6H2)B12H11}(2-) = Cs2{(Cl3C6H2)B12H11}

Conditions
ConditionsYield
In neat (no solvent) absence of light, (NBu4)2(B12H12) and excess 1,2,3-C6H3Cl3 heated at 180°C for 4 h; cooling, excess 1,2,3-C6H3Cl3 removed with ether, residue dissolved in CH2Cl2, addn. of alc. Cs-acetate, pptn. of Cs2(1-(m,p,m-Cl3H6H2)B12H11); recrystn. from hot water; elem. anal.;60%
morpholine
110-91-8

morpholine

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

1-(2,3-dichlorophenyl)-piperazine hydrochloride

1-(2,3-dichlorophenyl)-piperazine hydrochloride

Conditions
ConditionsYield
Stage #1: morpholine With lithium hexamethyldisilazane In tetrahydrofuran at 65℃; for 0.166667h; Sealed tube;
Stage #2: 1,2,3-trichlorobenzene In tetrahydrofuran at 65℃; for 22h; Sealed tube;
Stage #3: With hydrogenchloride In tetrahydrofuran; water Sealed tube;
51%
piperazine
110-85-0

piperazine

1,2,3-trichlorobenzene
87-61-6

1,2,3-trichlorobenzene

1-(2,3-dichlorophenyl)piperazine hydrochloride

1-(2,3-dichlorophenyl)piperazine hydrochloride

Conditions
ConditionsYield
Stage #1: piperazine; 1,2,3-trichlorobenzene With lithium hexamethyldisilazane In tetrahydrofuran at 65℃; for 22h;
Stage #2: With hydrogenchloride In water; acetonitrile
51%

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