hydrogenchloride
1,3-bis-(diphenylphosphino)propane
palladium
bis(diphenylphosphino)propanepalladium(II) dichloride
Conditions | Yield |
---|---|
Stage #1: hydrogenchloride; palladium With nitric acid In water Stage #2: 1,3-bis-(diphenylphosphino)propane In water; N,N-dimethyl-formamide at 50℃; for 1h; | 98.1% |
1,3-bis-(diphenylphosphino)propane
bis(diphenylphosphino)propanepalladium(II) dichloride
Conditions | Yield |
---|---|
With hydrogenchloride In ethanol; dichloromethane for 3h; Reflux; | 94% |
dichloro bis(acetonitrile) palladium(II)
1,3-bis-(diphenylphosphino)propane
bis(diphenylphosphino)propanepalladium(II) dichloride
Conditions | Yield |
---|---|
In benzene at 80℃; for 24h; Schlenk technique; Inert atmosphere; | 94% |
In benzene at 110℃; for 48h; Schlenk technique; Inert atmosphere; |
silver tetrafluoroborate
[PdCl(CH3)(bis(diphenylphosphino)propane)]
benzylidene phenylamine
bis(diphenylphosphino)propanepalladium(II) dichloride
Conditions | Yield |
---|---|
In dichloromethane; acetonitrile byproducts: AgCl; stirring (15 min); filtration, solvent removal, drying (reduced pressure, 1 d); | A 9% B 91% |
1,3-bis-(diphenylphosphino)propane
bis(diphenylphosphino)propanepalladium(II) dichloride
Conditions | Yield |
---|---|
In tetrahydrofuran; ethanol stirring for 2 h; evapn., washing with H2O, drying at 80°C for 12 h; | 88% |
dichloro(norbornadiene)palladium(II)
1,3-bis-(diphenylphosphino)propane
bis(diphenylphosphino)propanepalladium(II) dichloride
Conditions | Yield |
---|---|
In methanol at 30℃; for 3h; | 88% |
carbon monoxide
bis(diphenylphosphino)propanepalladium(II) dichloride
Pd(OC(CH3)N(C6H5)CHC6H5)(C27H26P2)(1+)*BF4(1-) = [Pd(OC(CH3)N(C6H5)CHC6H5)(C27H26P2)]BF4
Conditions | Yield |
---|---|
In chloroform-d1 Parr bomb (3.4 atm CO, room temp., 1 d); removal of excess CO, filtration to remove any metallic Pd; | A n/a B 83% |
hydrogenchloride
1,3-bis-(diphenylphosphino)propane
palladium diacetate
bis(diphenylphosphino)propanepalladium(II) dichloride
Conditions | Yield |
---|---|
In diethyl ether byproducts: CH3COOH; (Ar), mixed, stirred for 10 min, mixed with DPPPr dropwize with stirring, pptd., stirred for 1 h; filtered, washed with dry ethylether, dried in vac.; | 76% |
bis(benzonitrile)palladium(II) dichloride
bis(diphenylphosphino)propanepalladium(II) dichloride
Conditions | Yield |
---|---|
With 1,3-bis-(diphenylphosphino)propane In benzene stirring (30 min, N2-atmosphere); pptn. on pentane addn., filtration, washing (pentane), drying (vac., room temp.), dissoln. in DMF (85°C), filtration, cooling, Et2O addn., crystn. (ice bath); | 75% |
With 1,3-bis-(diphenylphosphino)propane In benzene absence of oxygen; elem. anal.; |
bis(diphenylphosphino)propanepalladium(II) dichloride
Conditions | Yield |
---|---|
With 1,3-bis-(diphenylphosphino)propane In acetone absence of oxygen; stirring (dissoln., then pptn.); | 51% |
potassium tetrachloropalladate(II)
1,3-bis-(diphenylphosphino)propane
bis(diphenylphosphino)propanepalladium(II) dichloride
Conditions | Yield |
---|---|
Stage #1: potassium tetrachloropalladate(II); 2-(2-hydroxy-3-methoxybenzylidene)-N-phenylhydrazinecarbothioamide In methanol; dichloromethane for 0.166667h; Reflux; Stage #2: 1,3-bis-(diphenylphosphino)propane In methanol; dichloromethane at 20℃; for 77h; Reflux; | A 25% B 48% |
potassium tetrachloropalladate(II)
2-(2-hydroxy-3-methoxybenzylidene)-N-methylhydrazinecarbothioamide
1,3-bis-(diphenylphosphino)propane
bis(diphenylphosphino)propanepalladium(II) dichloride
Conditions | Yield |
---|---|
Stage #1: potassium tetrachloropalladate(II); 2-(2-hydroxy-3-methoxybenzylidene)-N-methylhydrazinecarbothioamide In methanol; dichloromethane for 0.166667h; Reflux; Stage #2: 1,3-bis-(diphenylphosphino)propane In methanol; dichloromethane at 20℃; for 77h; Reflux; | A 23% B 46% |
potassium tetrachloropalladate(II)
3-methoxysalicylaldehydethiosemicarbazone
1,3-bis-(diphenylphosphino)propane
bis(diphenylphosphino)propanepalladium(II) dichloride
Conditions | Yield |
---|---|
Stage #1: potassium tetrachloropalladate(II); 3-methoxysalicylaldehydethiosemicarbazone In methanol; dichloromethane for 0.166667h; Reflux; Stage #2: 1,3-bis-(diphenylphosphino)propane In methanol; dichloromethane at 20℃; for 77h; Reflux; | A 26% B 43% |
potassium tetrachloropalladate(II)
3-methoxysalicylaldehyde 4(N)-ethylthiosemicarbazone
1,3-bis-(diphenylphosphino)propane
bis(diphenylphosphino)propanepalladium(II) dichloride
Conditions | Yield |
---|---|
Stage #1: potassium tetrachloropalladate(II); 3-methoxysalicylaldehyde-4(N)-ethylthiosemicarbazone In methanol; dichloromethane for 0.166667h; Reflux; Stage #2: 1,3-bis-(diphenylphosphino)propane In methanol; dichloromethane at 20℃; for 77h; Reflux; | A 28% B 43% |
dichloro(cycloocta-1,5-diene)palladium (II)
1,3-bis-(diphenylphosphino)propane
bis(diphenylphosphino)propanepalladium(II) dichloride
Conditions | Yield |
---|---|
In dichloromethane under N2, addn. of complex in CH2Cl2 to soln. of ligand in CH2Cl2, stirred for 25°C for 2 h, white pptn.; evapd. under reduced press., addn. of toluene, heated under reflux for 4 h, pptn., filtered, dried in vac.; |
bis(diphenylphosphino)propanepalladium(II) dichloride
cadmium(II) diethyldithiocarbamate
dichloromethane
Conditions | Yield |
---|---|
In dichloromethane stirred for 1 h; filtered, soln. concd. (vac.), pptd. (diethyl ether), ppt. filtered, washed (diethyl ether), dried (vac., 3 h), recrystd. (CH2Cl2); elem. anal.; | 94% |
bis(diphenylphosphino)propanepalladium(II) dichloride
bis(N,N-diethyldithiocarbamato)mercury(II)
dichloromethane
Conditions | Yield |
---|---|
In dichloromethane stirred for 1 h; filtered, soln. concd. (vac.), pptd. (diethyl ether), ppt. filtered, washed (diethyl ether), dried (vac., 3 h), recrystd. (CH2Cl2); elem. anal.; | 94% |
bis(diphenylphosphino)propanepalladium(II) dichloride
bis(N,N-diethyldithiocarbamate)lead
dichloromethane
Conditions | Yield |
---|---|
In dichloromethane stirred for 1 h; filtered, soln. concd. (vac.), pptd. (diethyl ether), ppt. filtered, washed (diethyl ether), dried (vac., 3 h), recrystd. (CH2Cl2); elem. anal.; | 94% |
bis(diphenylphosphino)propanepalladium(II) dichloride
tris(N,N-diethyldithiocarbamato)manganese(III)
dichloromethane
Conditions | Yield |
---|---|
In dichloromethane byproducts: tetraethylthiuram disulfide; stirred for 1 h; filtered, soln. concd. (vac.), pptd. (diethyl ether), ppt. filtered, washed (diethyl ether), dried (vac., 3 h), recrystd. (CH2Cl2); elem. anal.; | 93% |
bis(diphenylphosphino)propanepalladium(II) dichloride
Conditions | Yield |
---|---|
In dichloromethane for 4h; Reflux; | 93% |
bis(diphenylphosphino)propanepalladium(II) dichloride
silver trifluoromethanesulfonate
{(1,3-bis(diphenylphosphino)propane)ditriflatopalladium(II)}
Conditions | Yield |
---|---|
In dichloromethane room temp.; | 92% |
In dichloromethane (N2); stirring (25°C, 12 h, light exclsn.); pptn. (ether), drying (vac.); | 92% |
In dichloromethane Pd-complex reacted with AgCF3SO3 in CH2Cl2 at 25°C for 12 h; | 92% |
bis(diphenylphosphino)propanepalladium(II) dichloride
bis(N,N-diethyldithiocarbamato)zinc(II)
dichloromethane
Conditions | Yield |
---|---|
In dichloromethane stirred for 1 h; filtered, soln. concd. (vac.), pptd. (diethyl ether), ppt. filtered, washed (diethyl ether), dried (vac., 3 h), recrystd. (CH2Cl2); elem. anal.; | 92% |
bis(diphenylphosphino)propanepalladium(II) dichloride
silver trifluoromethanesulfonate
Conditions | Yield |
---|---|
In dichloromethane; acetone byproducts: AgCl; stirring Pd-complex (in CH2Cl2) with 2 equiv. AgOTf under Ar in dark for3 h, filtration off of AgCl, concn., addn. of 2 equiv. porphyrin and Me 2CO, stirring at room temp. for 5 h; solvent removal (reduced pressure), recrystn. (CH2Cl2/hexane); | 92% |
bis(diphenylphosphino)propanepalladium(II) dichloride
silver trifluoromethanesulfonate
acetonitrile
Conditions | Yield |
---|---|
at 20℃; Schlenk technique; Inert atmosphere; | 91% |
at 20℃; Schlenk technique; Inert atmosphere; | 86% |
bis(diphenylphosphino)propanepalladium(II) dichloride
5-(p-pyridyl)-10,15,20-tris(p-tolyl)porphyrinatozinc(II)
silver trifluoromethanesulfonate
Conditions | Yield |
---|---|
In dichloromethane; acetone byproducts: AgCl; stirring Pd-complex (in CH2Cl2) with 2 equiv. AgOTf under Ar in dark for3 h, filtration off of AgCl, concn., addn. of 2 equiv. Zn-complex and M e2CO, stirring at room temp. for 5 h; solvent removal (reduced pressure), recrystn. (CH2Cl2/hexane); | 90% |
silver tetrafluoroborate
bis(diphenylphosphino)propanepalladium(II) dichloride
dichloromethane
sodium N,N-diethyldithiocarbamate
Conditions | Yield |
---|---|
In acetonitrile refluxed for 3 h under Ar; cooled at room temp., filtered (Ar), washed (CH2Cl2), evapd., washed (Et2O), recrystd. (CH2Cl2 and n-hexane, 2 times); elem. anal.; | 90% |
bis(diphenylphosphino)propanepalladium(II) dichloride
thallium(I) pentafluorobenzoate
Conditions | Yield |
---|---|
With pyridine at 50℃; for 2h; Inert atmosphere; Schlenk technique; | 90% |
bis(diphenylphosphino)propanepalladium(II) dichloride
[N,N′-bis(2-mercaptidoethyl)-1,4-diazacycloheptane]nickel(II)
Conditions | Yield |
---|---|
In acetonitrile Schlenk technique; Inert atmosphere; | 89% |
bis(diphenylphosphino)propanepalladium(II) dichloride
phosphorous acid trimethyl ester
Conditions | Yield |
---|---|
In dichloromethane (Ar); stirring (96 h, 25°C); chromatography, solvent removal, washing (Et2O), drying (vac); elem. anal.; | 87% |
bis(diphenylphosphino)propanepalladium(II) dichloride
(((C6H5)2PCH2)2CH2)Pd(S2C2S2CC11H6N2)
Conditions | Yield |
---|---|
In not given | 87% |
bis(diphenylphosphino)propanepalladium(II) dichloride
Conditions | Yield |
---|---|
In acetonitrile Schlenk technique; Inert atmosphere; | 86% |
bis(diphenylphosphino)propanepalladium(II) dichloride
silver(I) 4-methylbenzenesulfonate
Conditions | Yield |
---|---|
In methanol; acetone suspending Pd complex and Ag salt in acetone/methanol; pptn. within a few min; filtering off ppt.; reducing volume to 1/3; addn. of diethyl ether; pptn.; filtration; drying; elem. anal.; | 85% |
bis(diphenylphosphino)propanepalladium(II) dichloride
Conditions | Yield |
---|---|
In methanol; benzene for 3h; Inert atmosphere; | 83% |
bis(diphenylphosphino)propanepalladium(II) dichloride
iodobenzene
Conditions | Yield |
---|---|
In tetrahydrofuran; diethyl ether dropwise addn. of Li2C8H6 soln. (dcolhyl ether) to stirred Pd complex suspension (THF) under Ar, -78°C; stirring, 20 min; addn. of iodobenzene soln. (THF); stirring, -30°C, 2h; evapn. to half the volume; dropwise addn. to hexane; pptn.; | 81% |
bis(diphenylphosphino)propanepalladium(II) dichloride
[MoS4Pd(1,3-bis(diphenylphosphino)propane)]
Conditions | Yield |
---|---|
In dichloromethane; acetonitrile for 12 h at room temp.; filtered, solid washed (CH2Cl2, distd. H2O, EtOH and ether), dried (air); elem. anal.; | 80% |
bis(diphenylphosphino)propanepalladium(II) dichloride
[WS4Pd(1,3-bis(diphenylphosphino)propane)]
Conditions | Yield |
---|---|
In dichloromethane; acetonitrile for 12 h at room temp.; filtered, solid washed (CH2Cl2, distd. H2O, EtOH and ether), dried (air); elem. anal.; | 76% |
bis(diphenylphosphino)propanepalladium(II) dichloride
[(4-methyl-C6H4COSe)2 (bis(diphenylphosphino)propane) palladium(II)]
sodium tetraphenyl borate
Conditions | Yield |
---|---|
In methanol; dichloromethane byproducts: NaCl; (Ar or N2); a mixture of Pd(SeCOC6H4Me-4)2(dppp)2 and PdCl2(dppp) in CH2Cl2 containing few drops of MeOH stirred for 20 min; methanolic soln. ofNaBPh4 added; further stirred for 40 min; solvents removed in vacuo; residue extracted with CH2Cl2; extract passedthrough a Florisil column, concentrated; recrystallized from CH2Cl2-hex ane; elem. anal.; | 76% |
The [1,3-Bis(diphenylphosphino)propane]palladium(II) dichloride is an organic compound with the formula C27H26Cl2P2Pd. The systematic name of this chemical is palladium(2+) dichloride - propane-1,3-diylbis(diphenylphosphane) (1:1). With the CAS registry number 59831-02-6, it is also named as Dichloropalladium - propane-1,3-diylbis(diphenylphosphine) (1:1). The product's categories are Metal Compounds; Catalysts for Organic Synthesis; Classes of Metal Compounds; Homogeneous Catalysts; Metal Complexes; Pd (Palladium) Compounds; Synthetic Organic Chemistry; Transition Metal Compounds.
Physical properties about [1,3-Bis(diphenylphosphino)propane]palladium(II) dichloride are: (1)ACD/LogP: 8.95; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 9; (4)ACD/LogD (pH 7.4): 9; (5)ACD/BCF (pH 5.5): 1000000; (6)ACD/BCF (pH 7.4): 1000000; (7)ACD/KOC (pH 5.5): 1767255; (8)ACD/KOC (pH 7.4): 1767255; (9)#Freely Rotating Bonds: 8; (10)Polar Surface Area: 27.18 Å2; (11)Flash Point: 291.5 °C; (12)Enthalpy of Vaporization: 77.45 kJ/mol; (13)Boiling Point: 529.7 °C at 760 mmHg; (14)Vapour Pressure: 9E-11 mmHg at 25°C
When you are using this chemical, please be cautious about it as the following:
It is harmful by inhalation, in contact with skin and if swallowed. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable gloves and eye/face protection.
You can still convert the following datas into molecular structure:
(1)SMILES: [Pd+2].[Cl-].[Cl-].P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4
(2)InChI: InChI=1/C27H26P2.2ClH.Pd/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2
(3)InChIKey: LDFBXJODFADZBN-NUQVWONBAR
(4)Std. InChI: InChI=1S/C27H26P2.2ClH.Pd/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2
(5)Std. InChIKey: LDFBXJODFADZBN-UHFFFAOYSA-L
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View