Product Name

  • Name

    DICHLORO[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]PALLADIUM(II)

  • EINECS 627-387-4
  • CAS No. 59831-02-6
  • Article Data19
  • CAS DataBase
  • Density
  • Solubility
  • Melting Point
  • Formula C27H26Cl2P2Pd
  • Boiling Point 529.7 °C at 760 mmHg
  • Molecular Weight 589.777
  • Flash Point 291.5 °C
  • Transport Information
  • Appearance
  • Safety 26-36/37/39-36/37
  • Risk Codes 36/37/38-20/21/22
  • Molecular Structure Molecular Structure of 59831-02-6 (DICHLORO[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]PALLADIUM(II))
  • Hazard Symbols HarmfulXn
  • Synonyms Palladium,dichloro[1,3-propanediylbis[diphenylphosphine-kP]]-, (SP-4-2)- (9CI);Palladium, dichloro[1,3-propanediylbis[diphenylphosphine]-P,P']-, (SP-4-2)-;Phosphine, 1,3-propanediylbis[diphenyl-, palladium complex;(Diphenylphosphinopropane)dichloropalladium;1,3-Propylenebis(diphenylphosphine)palladium dichloride;Dichloro[1,3-bis(diphenylphosphino)propane]palladium;Diphenylphosphinopropane palladium(II) chloride;[1,3-Bis(diphenylphosphino)propane]dichloropalladium;[1,3-Bis(diphenylphosphino)propane]palladium dichloride;
  • PSA 27.18000
  • LogP -0.34970

Synthetic route

hydrogenchloride
7647-01-0

hydrogenchloride

1,3-bis-(diphenylphosphino)propane
6737-42-4

1,3-bis-(diphenylphosphino)propane

palladium
7440-05-3

palladium

bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

Conditions
ConditionsYield
Stage #1: hydrogenchloride; palladium With nitric acid In water
Stage #2: 1,3-bis-(diphenylphosphino)propane In water; N,N-dimethyl-formamide at 50℃; for 1h;
98.1%
1,3-bis-(diphenylphosphino)propane
6737-42-4

1,3-bis-(diphenylphosphino)propane

palladium dichloride

palladium dichloride

bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

Conditions
ConditionsYield
With hydrogenchloride In ethanol; dichloromethane for 3h; Reflux;94%
dichloro bis(acetonitrile) palladium(II)
21264-30-2, 90243-59-7, 14592-56-4

dichloro bis(acetonitrile) palladium(II)

1,3-bis-(diphenylphosphino)propane
6737-42-4

1,3-bis-(diphenylphosphino)propane

bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

Conditions
ConditionsYield
In benzene at 80℃; for 24h; Schlenk technique; Inert atmosphere;94%
In benzene at 110℃; for 48h; Schlenk technique; Inert atmosphere;
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

[PdCl(CH3)(bis(diphenylphosphino)propane)]
139168-06-2

[PdCl(CH3)(bis(diphenylphosphino)propane)]

benzylidene phenylamine
538-51-2

benzylidene phenylamine

bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

Pd(CH3)(N(C6H5)CHC6H5)(C27H26P2)(1+)*BF4(1-)*C4H10O = [Pd(CH3)(N(C6H5)CHC6H5)(C27H26P2)]BF4*C4H10O

Pd(CH3)(N(C6H5)CHC6H5)(C27H26P2)(1+)*BF4(1-)*C4H10O = [Pd(CH3)(N(C6H5)CHC6H5)(C27H26P2)]BF4*C4H10O

Conditions
ConditionsYield
In dichloromethane; acetonitrile byproducts: AgCl; stirring (15 min); filtration, solvent removal, drying (reduced pressure, 1 d);A 9%
B 91%
sodium tetrachloropalladate(II)

sodium tetrachloropalladate(II)

1,3-bis-(diphenylphosphino)propane
6737-42-4

1,3-bis-(diphenylphosphino)propane

bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

Conditions
ConditionsYield
In tetrahydrofuran; ethanol stirring for 2 h; evapn., washing with H2O, drying at 80°C for 12 h;88%
dichloro(norbornadiene)palladium(II)
12317-46-3

dichloro(norbornadiene)palladium(II)

1,3-bis-(diphenylphosphino)propane
6737-42-4

1,3-bis-(diphenylphosphino)propane

bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

Conditions
ConditionsYield
In methanol at 30℃; for 3h;88%
Pd(CH3)(N(C6H5)CHC6H5)(C27H26P2)(1+)*BF4(1-)*C4H10O = [Pd(CH3)(N(C6H5)CHC6H5)(C27H26P2)]BF4*C4H10O

Pd(CH3)(N(C6H5)CHC6H5)(C27H26P2)(1+)*BF4(1-)*C4H10O = [Pd(CH3)(N(C6H5)CHC6H5)(C27H26P2)]BF4*C4H10O

carbon monoxide
201230-82-2

carbon monoxide

bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

Pd(OC(CH3)N(C6H5)CHC6H5)(C27H26P2)(1+)*BF4(1-) = [Pd(OC(CH3)N(C6H5)CHC6H5)(C27H26P2)]BF4
210413-33-5

Pd(OC(CH3)N(C6H5)CHC6H5)(C27H26P2)(1+)*BF4(1-) = [Pd(OC(CH3)N(C6H5)CHC6H5)(C27H26P2)]BF4

Conditions
ConditionsYield
In chloroform-d1 Parr bomb (3.4 atm CO, room temp., 1 d); removal of excess CO, filtration to remove any metallic Pd;A n/a
B 83%
hydrogenchloride
7647-01-0

hydrogenchloride

1,3-bis-(diphenylphosphino)propane
6737-42-4

1,3-bis-(diphenylphosphino)propane

palladium diacetate
3375-31-3

palladium diacetate

bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

Conditions
ConditionsYield
In diethyl ether byproducts: CH3COOH; (Ar), mixed, stirred for 10 min, mixed with DPPPr dropwize with stirring, pptd., stirred for 1 h; filtered, washed with dry ethylether, dried in vac.;76%
bis(benzonitrile)palladium(II) dichloride
15617-18-2, 39958-10-6, 14220-64-5

bis(benzonitrile)palladium(II) dichloride

bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

Conditions
ConditionsYield
With 1,3-bis-(diphenylphosphino)propane In benzene stirring (30 min, N2-atmosphere); pptn. on pentane addn., filtration, washing (pentane), drying (vac., room temp.), dissoln. in DMF (85°C), filtration, cooling, Et2O addn., crystn. (ice bath);75%
With 1,3-bis-(diphenylphosphino)propane In benzene absence of oxygen; elem. anal.;
palladium dichloride

palladium dichloride

bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

Conditions
ConditionsYield
With 1,3-bis-(diphenylphosphino)propane In acetone absence of oxygen; stirring (dissoln., then pptn.);51%
potassium tetrachloropalladate(II)
10025-98-6

potassium tetrachloropalladate(II)

1,3-bis-(diphenylphosphino)propane
6737-42-4

1,3-bis-(diphenylphosphino)propane

2-(2-hydroxy-3-methoxybenzylidene)-N-phenylhydrazinecarbothioamide

2-(2-hydroxy-3-methoxybenzylidene)-N-phenylhydrazinecarbothioamide

bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

(3-methoxysalicylaldehyde-4(N)-phenylthiosemicarbazone)(5-(2-hydroxy-3-methoxy-phenyl)-4-phenyl-2,4-dihydro-[1,2,4]triazole-3-thione)palladium(II) chloride

(3-methoxysalicylaldehyde-4(N)-phenylthiosemicarbazone)(5-(2-hydroxy-3-methoxy-phenyl)-4-phenyl-2,4-dihydro-[1,2,4]triazole-3-thione)palladium(II) chloride

Conditions
ConditionsYield
Stage #1: potassium tetrachloropalladate(II); 2-(2-hydroxy-3-methoxybenzylidene)-N-phenylhydrazinecarbothioamide In methanol; dichloromethane for 0.166667h; Reflux;
Stage #2: 1,3-bis-(diphenylphosphino)propane In methanol; dichloromethane at 20℃; for 77h; Reflux;
A 25%
B 48%
potassium tetrachloropalladate(II)
10025-98-6

potassium tetrachloropalladate(II)

2-(2-hydroxy-3-methoxybenzylidene)-N-methylhydrazinecarbothioamide
51146-65-7

2-(2-hydroxy-3-methoxybenzylidene)-N-methylhydrazinecarbothioamide

1,3-bis-(diphenylphosphino)propane
6737-42-4

1,3-bis-(diphenylphosphino)propane

bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

(3-methoxysalicylaldehyde-4(N)-methylthiosemicarbazone)(5-(2-hydroxy-3-methoxy-phenyl)-4-methyl-2,4-dihydro-[1,2,4]triazole-3-thione)palladium(II) chloride

(3-methoxysalicylaldehyde-4(N)-methylthiosemicarbazone)(5-(2-hydroxy-3-methoxy-phenyl)-4-methyl-2,4-dihydro-[1,2,4]triazole-3-thione)palladium(II) chloride

Conditions
ConditionsYield
Stage #1: potassium tetrachloropalladate(II); 2-(2-hydroxy-3-methoxybenzylidene)-N-methylhydrazinecarbothioamide In methanol; dichloromethane for 0.166667h; Reflux;
Stage #2: 1,3-bis-(diphenylphosphino)propane In methanol; dichloromethane at 20℃; for 77h; Reflux;
A 23%
B 46%
potassium tetrachloropalladate(II)
10025-98-6

potassium tetrachloropalladate(II)

3-methoxysalicylaldehydethiosemicarbazone
51146-75-9

3-methoxysalicylaldehydethiosemicarbazone

1,3-bis-(diphenylphosphino)propane
6737-42-4

1,3-bis-(diphenylphosphino)propane

bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

(3-methoxysalicylaldehyde-thiosemicarbazone)(5-(2-hydroxy-3-methoxy-phenyl)-2,4-dihydro-[1,2,4]triazole-3-thione)palladium(II) cloride

(3-methoxysalicylaldehyde-thiosemicarbazone)(5-(2-hydroxy-3-methoxy-phenyl)-2,4-dihydro-[1,2,4]triazole-3-thione)palladium(II) cloride

Conditions
ConditionsYield
Stage #1: potassium tetrachloropalladate(II); 3-methoxysalicylaldehydethiosemicarbazone In methanol; dichloromethane for 0.166667h; Reflux;
Stage #2: 1,3-bis-(diphenylphosphino)propane In methanol; dichloromethane at 20℃; for 77h; Reflux;
A 26%
B 43%
potassium tetrachloropalladate(II)
10025-98-6

potassium tetrachloropalladate(II)

3-methoxysalicylaldehyde 4(N)-ethylthiosemicarbazone
301202-22-2

3-methoxysalicylaldehyde 4(N)-ethylthiosemicarbazone

1,3-bis-(diphenylphosphino)propane
6737-42-4

1,3-bis-(diphenylphosphino)propane

bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

(3-methoxysalicylaldehyde-4(N)-ethylthiosemicarbazone)(4-ethyl-5-(2-hydroxy-3-methoxyphenyl)-2,4-dihydro-[1,2,4]triazole-3-thione)palladium(II) cloride

(3-methoxysalicylaldehyde-4(N)-ethylthiosemicarbazone)(4-ethyl-5-(2-hydroxy-3-methoxyphenyl)-2,4-dihydro-[1,2,4]triazole-3-thione)palladium(II) cloride

Conditions
ConditionsYield
Stage #1: potassium tetrachloropalladate(II); 3-methoxysalicylaldehyde-4(N)-ethylthiosemicarbazone In methanol; dichloromethane for 0.166667h; Reflux;
Stage #2: 1,3-bis-(diphenylphosphino)propane In methanol; dichloromethane at 20℃; for 77h; Reflux;
A 28%
B 43%
dichloro(cycloocta-1,5-diene)palladium (II)
12107-56-1

dichloro(cycloocta-1,5-diene)palladium (II)

1,3-bis-(diphenylphosphino)propane
6737-42-4

1,3-bis-(diphenylphosphino)propane

bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

Conditions
ConditionsYield
In dichloromethane under N2, addn. of complex in CH2Cl2 to soln. of ligand in CH2Cl2, stirred for 25°C for 2 h, white pptn.; evapd. under reduced press., addn. of toluene, heated under reflux for 4 h, pptn., filtered, dried in vac.;
bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

cadmium(II) diethyldithiocarbamate
14239-68-0

cadmium(II) diethyldithiocarbamate

dichloromethane
75-09-2

dichloromethane

(N,N-diethyldithiocarbamato)[bis(diphenylphosphino)propane]palladium(II) tetrachlorocadmate(II)*0.5CH2Cl2

(N,N-diethyldithiocarbamato)[bis(diphenylphosphino)propane]palladium(II) tetrachlorocadmate(II)*0.5CH2Cl2

Conditions
ConditionsYield
In dichloromethane stirred for 1 h; filtered, soln. concd. (vac.), pptd. (diethyl ether), ppt. filtered, washed (diethyl ether), dried (vac., 3 h), recrystd. (CH2Cl2); elem. anal.;94%
bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

bis(N,N-diethyldithiocarbamato)mercury(II)
14239-51-1

bis(N,N-diethyldithiocarbamato)mercury(II)

dichloromethane
75-09-2

dichloromethane

(N,N-diethyldithiocarbamato)[bis(diphenylphosphino)propane]palladium(II) tetrachloromercurate(II)*CH2Cl2*H2O

(N,N-diethyldithiocarbamato)[bis(diphenylphosphino)propane]palladium(II) tetrachloromercurate(II)*CH2Cl2*H2O

Conditions
ConditionsYield
In dichloromethane stirred for 1 h; filtered, soln. concd. (vac.), pptd. (diethyl ether), ppt. filtered, washed (diethyl ether), dried (vac., 3 h), recrystd. (CH2Cl2); elem. anal.;94%
bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

bis(N,N-diethyldithiocarbamate)lead
17549-30-3

bis(N,N-diethyldithiocarbamate)lead

dichloromethane
75-09-2

dichloromethane

(N,N-diethyldithiocarbamato)[bis(diphenylphosphino)propane]palladium(II) tetrachloroplumbate(II)*0.5CH2Cl2

(N,N-diethyldithiocarbamato)[bis(diphenylphosphino)propane]palladium(II) tetrachloroplumbate(II)*0.5CH2Cl2

Conditions
ConditionsYield
In dichloromethane stirred for 1 h; filtered, soln. concd. (vac.), pptd. (diethyl ether), ppt. filtered, washed (diethyl ether), dried (vac., 3 h), recrystd. (CH2Cl2); elem. anal.;94%
bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

tris(N,N-diethyldithiocarbamato)manganese(III)
15740-71-3

tris(N,N-diethyldithiocarbamato)manganese(III)

dichloromethane
75-09-2

dichloromethane

(N,N-diethyldithiocarbamato)[bis(diphenylphosphino)propane]palladium(II) tetrachloromanganate(II)*0.5CH2Cl2

(N,N-diethyldithiocarbamato)[bis(diphenylphosphino)propane]palladium(II) tetrachloromanganate(II)*0.5CH2Cl2

Conditions
ConditionsYield
In dichloromethane byproducts: tetraethylthiuram disulfide; stirred for 1 h; filtered, soln. concd. (vac.), pptd. (diethyl ether), ppt. filtered, washed (diethyl ether), dried (vac., 3 h), recrystd. (CH2Cl2); elem. anal.;93%
bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

S-1H-benzo[d] imidazole-2-yl benzothioate

S-1H-benzo[d] imidazole-2-yl benzothioate

[Pd(k2-dppp)(S-1H-benzo[d]imidazole-2-yl benzothioate)Cl]Cl

[Pd(k2-dppp)(S-1H-benzo[d]imidazole-2-yl benzothioate)Cl]Cl

Conditions
ConditionsYield
In dichloromethane for 4h; Reflux;93%
bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

silver trifluoromethanesulfonate
2923-28-6

silver trifluoromethanesulfonate

{(1,3-bis(diphenylphosphino)propane)ditriflatopalladium(II)}
137846-38-9

{(1,3-bis(diphenylphosphino)propane)ditriflatopalladium(II)}

Conditions
ConditionsYield
In dichloromethane room temp.;92%
In dichloromethane (N2); stirring (25°C, 12 h, light exclsn.); pptn. (ether), drying (vac.);92%
In dichloromethane Pd-complex reacted with AgCF3SO3 in CH2Cl2 at 25°C for 12 h;92%
bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

bis(N,N-diethyldithiocarbamato)zinc(II)
14324-55-1

bis(N,N-diethyldithiocarbamato)zinc(II)

dichloromethane
75-09-2

dichloromethane

(N,N-diethyldithiocarbamato)[bis(diphenylphosphino)propane]palladium(II) tetrachlorozincate(II)*0.5CH2Cl2

(N,N-diethyldithiocarbamato)[bis(diphenylphosphino)propane]palladium(II) tetrachlorozincate(II)*0.5CH2Cl2

Conditions
ConditionsYield
In dichloromethane stirred for 1 h; filtered, soln. concd. (vac.), pptd. (diethyl ether), ppt. filtered, washed (diethyl ether), dried (vac., 3 h), recrystd. (CH2Cl2); elem. anal.;92%
bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

5-(p-pyridyl)-10,15,20-tris(p-tolyl)porphyrin

5-(p-pyridyl)-10,15,20-tris(p-tolyl)porphyrin

silver trifluoromethanesulfonate
2923-28-6

silver trifluoromethanesulfonate

cis-[Pd(1,3-bis(diphenylphosphino)propane)(5-(p-pyridyl)-10,15,20-tris(p-tolyl)porphyrin)2](OTf)2

cis-[Pd(1,3-bis(diphenylphosphino)propane)(5-(p-pyridyl)-10,15,20-tris(p-tolyl)porphyrin)2](OTf)2

Conditions
ConditionsYield
In dichloromethane; acetone byproducts: AgCl; stirring Pd-complex (in CH2Cl2) with 2 equiv. AgOTf under Ar in dark for3 h, filtration off of AgCl, concn., addn. of 2 equiv. porphyrin and Me 2CO, stirring at room temp. for 5 h; solvent removal (reduced pressure), recrystn. (CH2Cl2/hexane);92%
bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

silver trifluoromethanesulfonate
2923-28-6

silver trifluoromethanesulfonate

acetonitrile
75-05-8

acetonitrile

Pd((P(C6H5)2CH2))2CH2(CH3CN)2(2+)*2CF3SO3(1-)=[Pd((P(C6H5)2CH2))2CH2(CH3CN)2](CF3SO3)2

Pd((P(C6H5)2CH2))2CH2(CH3CN)2(2+)*2CF3SO3(1-)=[Pd((P(C6H5)2CH2))2CH2(CH3CN)2](CF3SO3)2

Conditions
ConditionsYield
at 20℃; Schlenk technique; Inert atmosphere;91%
at 20℃; Schlenk technique; Inert atmosphere;86%
bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

5-(p-pyridyl)-10,15,20-tris(p-tolyl)porphyrinatozinc(II)
107302-31-8

5-(p-pyridyl)-10,15,20-tris(p-tolyl)porphyrinatozinc(II)

silver trifluoromethanesulfonate
2923-28-6

silver trifluoromethanesulfonate

cis-[Pd(1,3-bis(diphenylphosphino)propane)((5-(p-pyridyl)-10,15,20-tris(p-tolyl)porphyrinate)Zn)2](OTf)2

cis-[Pd(1,3-bis(diphenylphosphino)propane)((5-(p-pyridyl)-10,15,20-tris(p-tolyl)porphyrinate)Zn)2](OTf)2

Conditions
ConditionsYield
In dichloromethane; acetone byproducts: AgCl; stirring Pd-complex (in CH2Cl2) with 2 equiv. AgOTf under Ar in dark for3 h, filtration off of AgCl, concn., addn. of 2 equiv. Zn-complex and M e2CO, stirring at room temp. for 5 h; solvent removal (reduced pressure), recrystn. (CH2Cl2/hexane);90%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

dichloromethane
75-09-2

dichloromethane

sodium N,N-diethyldithiocarbamate
148-18-5

sodium N,N-diethyldithiocarbamate

(N,N-diethyldithiocarbamato)[1,3-bis(diphenylphosphino)propane]palladium(II) tetrafluoroborate - dichloromethane (3/1)

(N,N-diethyldithiocarbamato)[1,3-bis(diphenylphosphino)propane]palladium(II) tetrafluoroborate - dichloromethane (3/1)

Conditions
ConditionsYield
In acetonitrile refluxed for 3 h under Ar; cooled at room temp., filtered (Ar), washed (CH2Cl2), evapd., washed (Et2O), recrystd. (CH2Cl2 and n-hexane, 2 times); elem. anal.;90%
bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

thallium(I) pentafluorobenzoate
68558-86-1

thallium(I) pentafluorobenzoate

[Pd(1,2-bis(diphenylphosphano)propane)Cl(C6F5)]

[Pd(1,2-bis(diphenylphosphano)propane)Cl(C6F5)]

Conditions
ConditionsYield
With pyridine at 50℃; for 2h; Inert atmosphere; Schlenk technique;90%
ammonium hexafluorophosphate

ammonium hexafluorophosphate

bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

[N,N′-bis(2-mercaptidoethyl)-1,4-diazacycloheptane]nickel(II)
352232-62-3

[N,N′-bis(2-mercaptidoethyl)-1,4-diazacycloheptane]nickel(II)

[Ni(2,2'-(1,4-diazepane-1,4-diyl)bis(ethane-1-thiol))Pd(1,3-bis(diphenylphosphanyl)propane)](PF6)2

[Ni(2,2'-(1,4-diazepane-1,4-diyl)bis(ethane-1-thiol))Pd(1,3-bis(diphenylphosphanyl)propane)](PF6)2

Conditions
ConditionsYield
In acetonitrile Schlenk technique; Inert atmosphere;89%
bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

phosphorous acid trimethyl ester
121-45-9

phosphorous acid trimethyl ester

Pd(C6H5)2P(CH2)3P(C6H5)2(PO(OCH3)2)2

Pd(C6H5)2P(CH2)3P(C6H5)2(PO(OCH3)2)2

Conditions
ConditionsYield
In dichloromethane (Ar); stirring (96 h, 25°C); chromatography, solvent removal, washing (Et2O), drying (vac); elem. anal.;87%
bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

N2C11H6CS2C2S2(2-)

N2C11H6CS2C2S2(2-)

(((C6H5)2PCH2)2CH2)Pd(S2C2S2CC11H6N2)
1080460-83-8

(((C6H5)2PCH2)2CH2)Pd(S2C2S2CC11H6N2)

Conditions
ConditionsYield
In not given87%
ammonium hexafluorophosphate

ammonium hexafluorophosphate

bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

(bismercaptoethanediazacyclooctane)nickel(II)

(bismercaptoethanediazacyclooctane)nickel(II)

[Ni(2,2'-(piperazine-1,4-diyl)bis(ethane-1-thiol))Pd(1,3-bis(diphenylphosphanyl)propane)](PF6)2

[Ni(2,2'-(piperazine-1,4-diyl)bis(ethane-1-thiol))Pd(1,3-bis(diphenylphosphanyl)propane)](PF6)2

Conditions
ConditionsYield
In acetonitrile Schlenk technique; Inert atmosphere;86%
bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

silver(I) 4-methylbenzenesulfonate
16836-95-6

silver(I) 4-methylbenzenesulfonate

Pd(2+)*2CH3C6H4SO3(1-)*CH2(CH2P(C6H5)2)2*2H2O={Pd(CH3C6H4SO3)2(CH2(CH2P(C6H5)2)2)}*2H2O

Pd(2+)*2CH3C6H4SO3(1-)*CH2(CH2P(C6H5)2)2*2H2O={Pd(CH3C6H4SO3)2(CH2(CH2P(C6H5)2)2)}*2H2O

Conditions
ConditionsYield
In methanol; acetone suspending Pd complex and Ag salt in acetone/methanol; pptn. within a few min; filtering off ppt.; reducing volume to 1/3; addn. of diethyl ether; pptn.; filtration; drying; elem. anal.;85%
bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

sodium (6-methyl-2-pyridyl)tellurolate

sodium (6-methyl-2-pyridyl)tellurolate

[Pd3(μ-Te)2(dppp)3]Cl2

[Pd3(μ-Te)2(dppp)3]Cl2

Conditions
ConditionsYield
In methanol; benzene for 3h; Inert atmosphere;83%
bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

iodobenzene
591-50-4

iodobenzene

dilithio (cyclo-octatetraenide)

dilithio (cyclo-octatetraenide)

iodo{1,3-bis(diphenylphosphino)propane}{phenyl}palladium

iodo{1,3-bis(diphenylphosphino)propane}{phenyl}palladium

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether dropwise addn. of Li2C8H6 soln. (dcolhyl ether) to stirred Pd complex suspension (THF) under Ar, -78°C; stirring, 20 min; addn. of iodobenzene soln. (THF); stirring, -30°C, 2h; evapn. to half the volume; dropwise addn. to hexane; pptn.;81%
bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

tetraethylammonium tetrathiomolybdate

tetraethylammonium tetrathiomolybdate

[MoS4Pd(1,3-bis(diphenylphosphino)propane)]
289908-62-9

[MoS4Pd(1,3-bis(diphenylphosphino)propane)]

Conditions
ConditionsYield
In dichloromethane; acetonitrile for 12 h at room temp.; filtered, solid washed (CH2Cl2, distd. H2O, EtOH and ether), dried (air); elem. anal.;80%
bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

bis(tetraethylammonium) tetrathiotungstate

bis(tetraethylammonium) tetrathiotungstate

[WS4Pd(1,3-bis(diphenylphosphino)propane)]
289908-63-0

[WS4Pd(1,3-bis(diphenylphosphino)propane)]

Conditions
ConditionsYield
In dichloromethane; acetonitrile for 12 h at room temp.; filtered, solid washed (CH2Cl2, distd. H2O, EtOH and ether), dried (air); elem. anal.;76%
bis(diphenylphosphino)propanepalladium(II) dichloride
59831-02-6

bis(diphenylphosphino)propanepalladium(II) dichloride

[(4-methyl-C6H4COSe)2 (bis(diphenylphosphino)propane) palladium(II)]
877049-58-6

[(4-methyl-C6H4COSe)2 (bis(diphenylphosphino)propane) palladium(II)]

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

[(palladium(II))3 (μ3-Se)2 (bis(diphenylphosphino)propane)3] (tetraphenylborate)2

[(palladium(II))3 (μ3-Se)2 (bis(diphenylphosphino)propane)3] (tetraphenylborate)2

Conditions
ConditionsYield
In methanol; dichloromethane byproducts: NaCl; (Ar or N2); a mixture of Pd(SeCOC6H4Me-4)2(dppp)2 and PdCl2(dppp) in CH2Cl2 containing few drops of MeOH stirred for 20 min; methanolic soln. ofNaBPh4 added; further stirred for 40 min; solvents removed in vacuo; residue extracted with CH2Cl2; extract passedthrough a Florisil column, concentrated; recrystallized from CH2Cl2-hex ane; elem. anal.;76%

[1,3-Bis(diphenylphosphino)propane]palladium(II) dichloride Specification

The [1,3-Bis(diphenylphosphino)propane]palladium(II) dichloride is an organic compound with the formula C27H26Cl2P2Pd. The systematic name of this chemical is palladium(2+) dichloride - propane-1,3-diylbis(diphenylphosphane) (1:1). With the CAS registry number 59831-02-6, it is also named as Dichloropalladium - propane-1,3-diylbis(diphenylphosphine) (1:1). The product's categories are Metal Compounds; Catalysts for Organic Synthesis; Classes of Metal Compounds; Homogeneous Catalysts; Metal Complexes; Pd (Palladium) Compounds; Synthetic Organic Chemistry; Transition Metal Compounds.

Physical properties about [1,3-Bis(diphenylphosphino)propane]palladium(II) dichloride are: (1)ACD/LogP: 8.95; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 9; (4)ACD/LogD (pH 7.4): 9; (5)ACD/BCF (pH 5.5): 1000000; (6)ACD/BCF (pH 7.4): 1000000; (7)ACD/KOC (pH 5.5): 1767255; (8)ACD/KOC (pH 7.4): 1767255; (9)#Freely Rotating Bonds: 8; (10)Polar Surface Area: 27.18 Å2; (11)Flash Point: 291.5 °C; (12)Enthalpy of Vaporization: 77.45 kJ/mol; (13)Boiling Point: 529.7 °C at 760 mmHg; (14)Vapour Pressure: 9E-11 mmHg at 25°C

When you are using this chemical, please be cautious about it as the following:
It is harmful by inhalation, in contact with skin and if swallowed. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable gloves and eye/face protection.

You can still convert the following datas into molecular structure:
(1)SMILES: [Pd+2].[Cl-].[Cl-].P(c1ccccc1)(c2ccccc2)CCCP(c3ccccc3)c4ccccc4
(2)InChI: InChI=1/C27H26P2.2ClH.Pd/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2
(3)InChIKey: LDFBXJODFADZBN-NUQVWONBAR
(4)Std. InChI: InChI=1S/C27H26P2.2ClH.Pd/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2
(5)Std. InChIKey: LDFBXJODFADZBN-UHFFFAOYSA-L

Post buying leads

About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia

Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog

©2008 LookChem.com,License: ICP

NO.:Zhejiang16009103

complaints:service@lookchem.com Desktop View