Conditions | Yield |
---|---|
With hydrogenchloride In tetrahydrofuran; water; ethyl acetate | 90% |
Conditions | Yield |
---|---|
In methanol for 25.5h; Reflux; | 45% |
(CH2)6NNH2*BH3
water
A
hydrogen
B
boric acid
C
1-azepanylamine
Conditions | Yield |
---|---|
In water | |
In water |
1-azepanylamine
diethyl 2-ethoxymethylenemalonate
(hexahydro-1H azepinyl-1 amino)-3 ethoxycarbonyl-2 propenoate d'ethyle
Conditions | Yield |
---|---|
In methanol for 1h; Ambient temperature; | 98% |
Conditions | Yield |
---|---|
With potassium hydride In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide for 24h; Ambient temperature; | 97% |
Conditions | Yield |
---|---|
With sodium sulfite In diethyl ether for 24h; Ambient temperature; | 95% |
Conditions | Yield |
---|---|
for 0.25h; Heating; | 94% |
2-chloro-6-methylphenyl isocyanate
1-azepanylamine
Conditions | Yield |
---|---|
In benzene Heating; | 92% |
1-azepanylamine
2,6-dimethylphenylisocyanate
Conditions | Yield |
---|---|
In benzene Heating; | 92% |
Conditions | Yield |
---|---|
With triethylamine In diethyl ether for 2h; Ambient temperature; | 92% |
2-chloro-5-nitrobenzoylchloride
1-azepanylamine
2-chloro-5-nitro-N-(1-azepanyl)benzamide
Conditions | Yield |
---|---|
With triethylamine In diethyl ether for 2h; Ambient temperature; | 90% |
Conditions | Yield |
---|---|
In benzene Heating; | 88% |
N‑methyl‑2‑oxo‑2‑phenylacetamide
1-azepanylamine
Conditions | Yield |
---|---|
With acetic acid In ethanol for 24h; Heating; | 88% |
1-azepanylamine
5-(4-bromophenyl)-1-(2,4-dichlorophenyl)-4-methyl-1H-pyrazole-3-carboxylic chloride
Conditions | Yield |
---|---|
With triethylamine In dichloromethane for 3h; Ambient temperature; | 88% |
3-pyridinecarboxaldehyde
1-azepanylamine
Azepan-1-yl-[1-pyridin-3-yl-meth-(E)-ylidene]-amine
Conditions | Yield |
---|---|
In ethanol for 0.5h; heating on a steam bath; | 87% |
Conditions | Yield |
---|---|
With potassium tert-butylate; tris(dibenzylideneacetone)dipalladium (0) In 1,4-dioxane at 120℃; for 5h; | 87% |
2-oxo-propionic acid ethyl ester
1-azepanylamine
ethyl 2-(azepan-1-ylimino)propanoate
Conditions | Yield |
---|---|
In ethanol at 0 - 20℃; | 87% |
In ethanol at 20℃; for 4h; |
1-azepanylamine
benzil
2-[(Z)-Azepan-1-ylimino]-1,2-diphenyl-ethanone
Conditions | Yield |
---|---|
With potassium hydroxide In ethanol for 24h; Ambient temperature; | 86% |
With acetic acid In ethanol for 20h; Ambient temperature; | 58% |
Conditions | Yield |
---|---|
With potassium tert-butylate; tris(dibenzylideneacetone)dipalladium (0) In 1,4-dioxane at 120℃; for 4.5h; | 86% |
Conditions | Yield |
---|---|
With potassium tert-butylate; tris(dibenzylideneacetone)dipalladium (0) In 1,4-dioxane at 120℃; for 5h; | 85% |
Conditions | Yield |
---|---|
With potassium tert-butylate; tris(dibenzylideneacetone)dipalladium (0) In 1,4-dioxane at 120℃; for 6h; | 85% |
1-azepanylamine
N-methyleneazepan-1-amine
Conditions | Yield |
---|---|
85% |
Conditions | Yield |
---|---|
In methanol for 3h; Reflux; | 85% |
1-azepanylamine
cyclohexanecarbaldehyde
Azepan-1-yl-[1-cyclohexyl-meth-(E)-ylidene]-amine
Conditions | Yield |
---|---|
In ethanol for 0.5h; heating on a steam bath; | 84% |
Conditions | Yield |
---|---|
With N,N'-dimethylpiperazine In tetrahydrofuran at 0 - 50℃; for 4.5h; | 84% |
Conditions | Yield |
---|---|
In methanol at 20℃; for 24h; | 83% |
1-(4-chlorophenyl)-2-(2,4-dichlorophenyl)-5-methyl-1H-imidazole-4-carboxylic acid
1-azepanylamine
Conditions | Yield |
---|---|
With O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate; N-ethyl-N,N-diisopropylamine In acetonitrile at 20℃; for 16h; | 82% |
1-azepanylamine
2-fluoro-5-nitrophenylacetic acid chloride
N-(Azepan-1-yl)(2-fluoro-5-nitrophenyl)acetamide
Conditions | Yield |
---|---|
With sodium hydrogencarbonate In chloroform for 2h; Ambient temperature; | 81% |
Conditions | Yield |
---|---|
In ethanol for 8h; Condensation; Heating; | 81% |
Glyoxal
1-azepanylamine
Conditions | Yield |
---|---|
In methanol; water at 20℃; for 1h; | 80% |
Conditions | Yield |
---|---|
In ethanol | 79% |
piperonal
1-azepanylamine
N-(1,3-benzodioxol-5-ylmethylene)azepan-1-amine
Conditions | Yield |
---|---|
In ethanol for 7.5h; Heating; | 79% |
IUPAC Name: Azepan-1-amine
Synonyms : 1-Aminohexahydroazepine ; 1-Azepanamine ; 1H-Azepin-1-amine, hexahydro- ; 1,1-Hexamethylenehydrazine
Product Categories: Heterocyclic Compounds
CAS NO: 5906-35-4
Molecular Formula of 1,1-Hexamethylenehydrazine (CAS NO.5906-35-4) :C6H14N2
Molecular Weight of 1,1-Hexamethylenehydrazine (CAS NO.5906-35-4) :114.19
Molecular structure of 1,1-Hexamethylenehydrazine (CAS NO.5906-35-4) :
EINECS: 227-609-6
Index of Refraction:1.478
Surface Tension: 34 dyne/cm
Density: 0.929 g/cm3
Flash Point: 56.1 °C
Enthalpy of Vaporization: 40.2 kJ/mol
Boiling Point: 165.6 °C at 760 mmHg
Vapour Pressure: 1.86 mmHg at 25°C
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
rat | LDLo | oral | 300mg/kg (300mg/kg) | Acute Toxicity Data. Journal of the American College of Toxicology, Part B. Vol. 1, Pg. 93 |
A poison by ingestion. Mutation data reported. When heated to decomposition it emits toxic vapors of NOx.
Hazard CodesXi
Risk Statements 36/37/38
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements 26-36/37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
RIDADR UN 1993 3/PG 3
WGK Germany 3
RTECS CM3165000
HazardClass 3.2
PackingGroup III
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