1,10-Phenanthroline hydrate supplier

Name
1,10-Phenanthroline monohydrate
EINECS 200-629-2
CAS No. 5144-89-8
Density 1.10
Solubility <0.01 g/100 mL at 21 °C
Melting Point 100-104 °C(lit.)
Formula C₁₂H₈N₂^.H₂O
Boiling Point 365.1 °C at 760 mmHg
Molecular Weight 198.224
Flash Point 164.8 °C
Transport Information UN 2811
Appearance white crystals or powder
Safety 45-60-61
Risk Codes 25-50/53
Molecular Structure
Hazard Symbols T, N
Synonyms 4,5-Phenanthroline monohydrate;1,10-Phenanthroline Monohydrate;o-Phenanthroline monohydrate;1,10-Phenanthroline 1-hydrate;1,10-Phenanthroline GR monohydrate;1,10-Phenanthroline AR;
PSA 35.01000
LogP 2.71870

Synthetic route

: 6156-78-1
manganese (II) acetate tetrahydrate

: 5144-89-8
1,10-phenanthroline hydrate

: {Mn3(O2CCH3)6(1,10-phenanthroline)2}

Conditions

Conditions	Yield
In N,N-dimethyl-formamide stirred for 10 min; filtered, washed with DMF, acetone and diethyl ether, dried in vac.; elem. anal.;	99%

: tetrakis(acetonitrile)copper(I)tetrafluoroborate

: 5144-89-8
1,10-phenanthroline hydrate

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 498584-34-2
(1,10-phenanthroline)(1,2-bis(diphenylphosphino)ethane)copper(I) tetrafluoroborate

Conditions

Conditions	Yield
In dichloromethane (N2); Cu complex was reacted with P ligand in CH2Cl2; phenanthroline wasadded after dissolution; mixt. was stirred for 1 h; solvent removed (vac.); Et2O added; pptd.; washed (Et2O);	99%

...Expand

: 7647-01-0
hydrogenchloride

: sodium tetrachloropalladate(II)

: 5144-89-8
1,10-phenanthroline hydrate

: 14783-10-9
[palladium(II)dichloride(1,10-phenanthroline)]

Conditions

Conditions	Yield
In water stirring Na2PdCl4 with 1 equiv. ligand and excess HCl (80°C, 30 min); standing at room temp. for several h, collection (filtration), washing (water, MeOH); elem. anal.;	99%

...Expand

: 5144-89-8
1,10-phenanthroline hydrate

: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

: copper(II) nitrate

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 498584-36-4
[Cu(1,2-bis(diphenylphosphino)ethane)(1,10-phenanthroline)]NO3

Conditions

Conditions	Yield
In acetonitrile (N2); mixt. of Cu(NO3)2 and Cu in CH3CN was stirred for 2 h; filtered under N2; P ligand and phenanthroline were subsequently added to filtrate;soln. was stirred for 15 min; solvent removed (vac.); extd. (CH2Cl2); CH2Cl2 removed (vac.); Et2O added; washed (Et2O);	99%

...Expand

: 14057-91-1
tetrakis(acetonitrile)copper(I) perchlorate

: 5144-89-8
1,10-phenanthroline hydrate

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 498584-33-1
[Cu(1,2-bis(diphenylphosphino)ethane)(1,10-phenanthroline)]ClO4

Conditions

Conditions	Yield
In dichloromethane (N2); Cu complex was reacted with P ligand in CH2Cl2; phenanthroline wasadded after dissolution; mixt. was stirred for 1 h; solvent removed (vac.); Et2O added; pptd.; washed (Et2O);	99%

...Expand

: 5144-89-8
1,10-phenanthroline hydrate

: 65115-91-5
5,6-epoxy-5,6-dihydro-[1,10]phenanthroline

Conditions

Conditions	Yield
With industrial bleach (pH 8.2-8.3 with conc. HCl); tetra(n-butyl)ammonium hydrogensulfate In chloroform; water	98%

: 6046-93-1
copper(II) acetate monohydrate

: 5144-89-8
1,10-phenanthroline hydrate

: (1,10-Phen)Cu(OAc)2

Conditions

Conditions	Yield
In ethanol addn. of a soln. of 1,10-phenanthrolineH2O in ethanol to a filtered soln. of Cu(OAc)2H2O in ethanol; stirring the soln. for 1 h, evapn. of the solvent, washing the residue with benzene and drying in vacuo, elem. anal.;	98%

: nickel(II) chloride hexahydrate

: dicesium dodecachloro-closo-dodecaborate

: 5144-89-8
1,10-phenanthroline hydrate

: [nickel(II)(1,10-phenanthroline)3]B12Cl12

Conditions

Conditions	Yield
In ethanol; water addn. of a soln. of organic compound in boiling ethanol to a soln. of Ni-salt and B-compound in water with stirring; filtn., washing (warm water, hot ethanol, absolute ether), drying over P2O5, elem. anal.;	98%

...Expand

: manganese(II) chloride tetrahydrate

: caesium [3,3'-commo-bis(η5-nonahydro-1,2-dicarba-3-nickel-closo-decarborate)]

: 5144-89-8
1,10-phenanthroline hydrate

: [Mn(II)(1,10-phenantroline)3][bis(η5-1,2-B9C2H11)nickeliate(III)]2

Conditions

Conditions	Yield
With CH3COOH; CH3COONa; Na2SO3 In hydrogenchloride; water soln. of MnCl24H2O in acetate buffer (pH 4.56) mixed with phenH2O soln. in aq. HCl (H2O:HCl=1:4), Na2SO3 added, heated at 70°C, hot soln. Cs-Ni-complex in H2O added, stored for 12 h; ppt. filtered off, washed with H2O and C6H6, dried under vac. at 70°C; elem. anal.;	98%

...Expand

: manganese(II) chloride tetrahydrate

: cesium 1,2;1',2'-trans-bis[nonahydro-closo-decaborate]

: 5144-89-8
1,10-phenanthroline hydrate

: [tris(1,10-phenanthroline)manganese(II)] 1,2;1',2'-trans-bis[nonahydro-closo-decaborate]

Conditions

Conditions	Yield
With acetate buffer In water Mn salt dissolved in acetate buffer (pH 4.56); 1,10-phenanthroline monohydrate dissolved with stirring in acetate buffer soln.; solns. combined with stirring; soln. heated to 70°C; hot soln. of Cs2B20H18 in H2O added with stirring; ppt. formed; suspn. allowed to coagulate for 12 h; ppt. filtered off on glass frit; washed (H2O); dried (vac., 70°C);	98%

...Expand

: manganese(II) chloride tetrahydrate

: cesium nido-1,2-dicarbaundecaborate

: 5144-89-8
1,10-phenanthroline hydrate

: tris-(1,10-phenanthroline)manganese(II) nido-1,2-dicarbaundecaborate

Conditions

Conditions	Yield
With HCl In water Mn compd. dissolved (acetate buffer), mixed with a soln. of ligand (water, dilute HCl (drops)) under stirring, heated to 70°C, a hot soln. of borate added, kept for 12 h at 70°C; ppt. filtered, washed (water), dried (vac., 70°C); elem. anal.;	98%

...Expand

: 7647-01-0
hydrogenchloride

: 10025-99-7
potassium tetrachloroplatinate(II)

: 5144-89-8
1,10-phenanthroline hydrate

: 18432-95-6
dichloro(1,10-phenanthroline)platinum(II)

Conditions

Conditions	Yield
In water elem. anal.;	97.7%

...Expand

: 5144-89-8
1,10-phenanthroline hydrate

: cobalt(II) perchlorate hexahydrate

: 17356-08-0
thiourea

: {Co(C12H8N2)3(SC(NH2)2)}(2+)*2(ClO4)(1-) = Co(ClO4)2(C12H8N2)3(SC(NH2)2)

Conditions

Conditions	Yield
In ethanol Co-compound, PHA and Tu were suspended in EtOH; the product was stirred in its mother soln. for many h; washed (EtOH, Et2O); elem.anal.;	97%

...Expand

: 7697-37-2
nitric acid

: 5144-89-8
1,10-phenanthroline hydrate

: 7440-05-3
palladium

: 31476-92-3
Pd(phen)(ONO2)2

Conditions

Conditions	Yield
With water In ethanol; nitric acid addn. of a soln. of 1,10-phenanthroline*H2O in ethanol to the aq. HNO3 soln. obtained after dissolution of Pd black in concd. HNO3 and dilutionwith water; stirring the soln. at room temp. for 2 h, filtration of the yellow ppt., washing with ethanol and drying in vacuo, elem. anal.;	97%

...Expand

: trans-(S,S)-[PdBr2(NH2CH(CO2Me)CH2C6H4-I-2)2]

: 5144-89-8
1,10-phenanthroline hydrate

: 41876-11-3
(PdBr2(phen))

Conditions

Conditions	Yield
In dichloromethane byproducts: IC6H4CH2CH(CO2CH3)NH2; ligand added to a soln. of Pd complex, stirred for 3 h at room temp.; filtered, washed (Et2O), air-dried;	97%

: 5144-89-8
1,10-phenanthroline hydrate

: palladium dichloride

: 14783-10-9
[palladium(II)dichloride(1,10-phenanthroline)]

Conditions

Conditions	Yield
With hydrogenchloride In ethanol; water addn. of concd. HCl to an aq. PdCl2 soln., filtration of the soln. and addn. of a soln of 1,10-phenanthroloine*H2O in ethanol to the filtered soln.; stirring for 2 h, filtering the ppt., washing with ethanol and drying in vacuo, elem. anal.;	96%

: cadmium(II) bis(tri-tert-butoxysilanethiolate)

: 5144-89-8
1,10-phenanthroline hydrate

: 142372-83-6
(1,10-phenanthroline)cadmium(II) bis(tri-tert-butoxysilanethiolate)

Conditions

Conditions	Yield
In benzene mixing solns. of Cd-complex and ligand in benzene gives instantaneously a white voluminous ppt., addn. of more benzene, refluxing under Ar until a clear soln. is obtained; slow cooling to room temp., pptn., washing with benzene, drying in vacuo, elem. anal.;	96%

: 91409-21-1
chloro{2-(dimethylamino)-1-methylpropyl-C,N}(dimethylamine)palladium(II)

: 5144-89-8
1,10-phenanthroline hydrate

: {2-(dimethylamino)-1-methylpropyl-C,N}(phenanthroline)palladium(II) chloride

Conditions

Conditions	Yield
In acetone added at 0°C, stirred for 10 min; evaporated to dryness; elem. anal.;	96%

: [{Au(C6Cl5)2}Ag]n

: 5144-89-8
1,10-phenanthroline hydrate

: Au(1+)*Ag(1+)*2C6Cl5(1-)*N2C12H8=(AuAg(C6Cl5)2(N2C12H8))

Conditions

Conditions	Yield
In hexane; dichloromethane to a suspn. of (AuAg(C6Cl5)2)n in dichloromethane added 1,10-phenantroline in hexane and stirred at room temp. for 24 h; solid filtered off and washed with diethylether; elem. anal.;	96%

: chlorotris(triphenylphosphine)palladium(II) hexafluorophosphate * acetone

: 5144-89-8
1,10-phenanthroline hydrate

: 101019-70-9
chlorobis(triphenylphosphine)(1,10-phenanthroline)palladium(II) hexafluorophosphate

Conditions

Conditions	Yield
In acetone to suspn. of Pd complex ligand was added, standing for 30 min; soln. was reduced in vac., pptd. with ether, elem. anal.;	96%

: caesium cobalt(III)bis(1,2-dicarboilide)

: manganese(II) chloride tetrahydrate

: 5144-89-8
1,10-phenanthroline hydrate

: tris-(1,10-phenanthroline)manganese(II) 3,3-commo-bis[η5-1,2-dicarba-(3)-cobalt(III)-closo-dodecaborate]

Conditions

Conditions	Yield
With HCl In water Mn compd. dissolved (acetate buffer), mixed with a soln. of ligand (water, dilute HCl (drops)) under stirring, heated to 70°C, a hot soln. of borate added, kept for 12 h; ppt. filtered, washed (water), dried (vac., 70°C); elem. anal.;	96%

...Expand

: 6153-56-6
oxalic acid dihydrate

: 6046-93-1
copper(II) acetate monohydrate

: germanium dioxide

: 5144-89-8
1,10-phenanthroline hydrate

: 947503-45-9
[Cu(1,10'-phenanthroline)3][tris(oxalate-O,O')germanate]

Conditions

Conditions	Yield
In water addn. of distld. water to 1:3:1:3 mixt. of germanium dioxide, oxalic acid, copper acetate and phenanthroline, stirring for 30 min at room temp.,heating at 100°C for 72 h; isolation of crystals, washing with distld. water, filtration, air drying, elem. anal.;	95.6%

...Expand

: 90634-69-8
Ir(OClO3)(C6F4C6H6)2

: 5144-89-8
1,10-phenanthroline hydrate

: 90634-76-7
{Ir(tetrafluorobenzobarrelene)(1,10-phenanthroline)}ClO4

Conditions

Conditions	Yield
In dichloromethane (N2); complex suspn. treated for 30 min with stoich. amt. of ligand; concd. (vac.), pptd. (ether), filtered off, washed (ether), dried in vac.; elem. anal.;	95%

: 14104-20-2
silver tetrafluoroborate

: 88478-63-1
{IrCl(tetrafluorobenzobarrelene)2}

: 5144-89-8
1,10-phenanthroline hydrate

: 90634-85-8
[Ir(C6F4C6H6)(C12H8N2)](1+)*BF4(1-)=[Ir(C6F4C6H6)(C12H8N2)]BF4

Conditions

Conditions	Yield
In acetone byproducts: AgCl; under N2 and protected from daylight complex suspn. in acetone or CH2Cl2 treated for 30 min with ligand and with AgBF4 in acetone; AgCl filtered off, filtrate concd. (vac.), pptd. (ether), filtered off,washed with ether, dried in vac.; elem. anal.;	95%

...Expand

: 594-61-6
2-methyllactic acid

: 5144-89-8
1,10-phenanthroline hydrate

: 743369-26-8
zinc(II) carbonate

: [Zn(2-methyllactate)(1,10-phenanthroline)2](2-methyllactate)*4H2O

Conditions

Conditions	Yield
In ethanol mixt. of ZnCO3, α-hydroxycarboxylic acid, and diamine in EtOH refluxed for 4 h, allowed to cool to room temp., stirred for 1 wk; recrystd. from nethanol/isopropanol (1/1), dried under vac.; elem. anal.;	95%

...Expand

: lead(II) nitrate

: copper(II) choride dihydrate

: 5144-89-8
1,10-phenanthroline hydrate

: poly[chlorobis(1,10-phenanthroline)copper(II) trichloroplumbate(II)]

Conditions

Conditions	Yield
With HCl In water; N,N-dimethyl-formamide High Pressure; solvothermal synthesis; mixt. of Pb(NO3)2, phenH2O, CuCl22H2O (0.5:1:0.5 mmol) in DMF with 36 % aq. HCl (1 ml) heated in Teflon-lined stainless steel vessel at 120°C for 3 d; cooled to room temp. (rate 3°C/h); elem. anal.;	95%

...Expand

: cyclo-tetrakis-{tri-tert-butoxysilanethiolatocopper(I)}

: 5144-89-8
1,10-phenanthroline hydrate

: ((CH3)3CO)3SiS(1-)*Cu(1+)*C12H8N2=((CH3)3CO)3SiSCu*C12H8N2

Conditions

Conditions	Yield
In benzene addn. of phen*H2O to anhyd. benzene, refluxing (until a clear soln. was obtained), addn. of soln. of ((t-BuO)3SiSCu)4 (colour change to deep red), left to stand, 1 day, room temp., pptn.; filtered, washed (hexane), vac. dried, elem. anal.;	94%

: erbium(III) nitrate pentahydrate

: 5144-89-8
1,10-phenanthroline hydrate

: trinitrato-bis-(1,10-phenantroline)erbium(III)

Conditions

Conditions	Yield
In isopropyl alcohol soln. of Er-comp. in isopropanol treated with isopropanol-soln. of 2,2'-1,10-phenantroline monohydrate, mixt.allowed to stay for 24 h; filtered, crystals dried over P4O10, elem. anal.;	94%

: 81704-56-5, 68249-87-6
bis(dimethylphenylphosphine)bis(monothiobenzoato)ruthenium(II)

: 5144-89-8
1,10-phenanthroline hydrate

: 74244-05-6, 74215-94-4
bis(dimethylphenylphosphine)bis(monothiobenzoato)(1,10-phenanthroline)ruthenium(II)

Conditions

Conditions	Yield
In ethanol reflux for 2 h under N2; the volume of the soln. reduced, after standing for some h the product filtered; elem. anal.;	94%

: 10025-99-7
potassium tetrachloroplatinate(II)

: dicesium dodecachloro-closo-dodecaborate

: 5144-89-8
1,10-phenanthroline hydrate

: [platinum(II)(1,10-phenanthroline)2]B12Cl12

Conditions

Conditions	Yield
In ethanol; water addn. of a soln. of organic compound in ethanol to a soln. of B-compound in water, addn. of a soln. of Pt-complex in water, keeping the mixtureat 35°C. for 24 h; filtn., washing (warm water, ethanol, absolute ether), drying in vac. over P2O5, elem. anal.;	94%

...Expand

1,10-Phenanthroline hydrate Chemical Properties

Product Name: 1,10-Phenanthroline hydrate (CAS NO.5144-89-8)

Molecular Formula: C₁₂H₈N₂.H₂O
Molecular Weight: 198.22g/mol
Mol File: 5144-89-8.mol
Appearance: white crystals or powder
Melting Point: 100-104 °C(lit.)
Boiling point: 365.1 °C at 760 mmHg
Storage Temperature: Store at RT.
Flash Point: 164.8 °C
Water Solubility: <0.01 g/100 mL at 21 ºC
Stability: Stable. Incompatible with iron, other heavy metals, strong oxidizing agents, strong acids.
Enthalpy of Vaporization: 58.73 kJ/mol
Vapour Pressure: 3.38E-05 mmHg at 25°C
H-Bond Donor: 1
H-Bond Acceptor: 3
Structure Descriptors of 1,10-Phenanthroline hydrate (CAS NO.5144-89-8):
IUPAC Name: 1,10-phenanthroline hydrate
Canonical SMILES: C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.O
InChI: InChI=1S/C12H8N2.H2O/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;/h1-8H;1H2
InChIKey: PPQJCISYYXZCAE-UHFFFAOYSA-N
Product Categories: Miscellaneous; Analytical Chemistry; Chelating Reagents; Environmentally-friendly Oxidation; Ligands (Environmentally-friendly Oxidation); Phenanthrolines; Synthetic Organic Chemistry

1,10-Phenanthroline hydrate Uses

Used as a bidentate ligand in coordination chemistry.

1,10-Phenanthroline hydrate Safety Profile

Safety Information of 1,10-Phenanthroline hydrate (CAS NO.5144-89-8):
Hazard Codes: T Toxic ,N Dangerous
Risk Statements: 25-50/53
R20:Harmful by inhalation.
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 45-60-61
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60:This material and its container must be disposed of as hazardous waste.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN 2811 6.1/PG 3
WGK Germany: 3
RTECS: SF8437000
HazardClass: 6.1
PackingGroup: III
HS Code: 29339990

1,10-Phenanthroline hydrate Specification

1,10-Phenanthroline hydrate , its CAS NO. is 5144-89-8, the synonyms are 4,5-Phenanthroline monohydrate ; AI3-22011 ; o-Phenanthroline monohydrate .

Product Name

1,10-Phenanthroline monohydrate

Synthetic route

1,10-Phenanthroline hydrate Chemical Properties

1,10-Phenanthroline hydrate Uses

1,10-Phenanthroline hydrate Safety Profile

1,10-Phenanthroline hydrate Specification

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