1-Hexene supplier | CasNO.592-41-6

Name
1-Hexene
EINECS 209-753-1
CAS No. 592-41-6
Article Data612
CAS DataBase
Density 0.686 g/cm³
Solubility 0.005 g/100 mL
Melting Point -140 °C
Formula C₆H₁₂
Boiling Point 62.81 °C at 760 mmHg
Molecular Weight 84.1613
Flash Point -9.444 °C
Transport Information
Appearance colourless liquid
Safety 9-16-23-29-62-57-33
Risk Codes 11-65-67-51/53
Molecular Structure
Hazard Symbols F,Xn,N
Synonyms 1-n-Hexene;Dialen 6;Hexene;Linealene 6;NSC 74121;
PSA 0.00000
LogP 2.36260

Synthetic route

: 74-85-1
ethene

: 592-41-6
1-hexene

Conditions

Conditions	Yield
With trimethylamine-N-oxide; [N(4-C6H4Br)3][B(C6F5)4]; triethylaluminum; [Cr(CO)4(2-C6H4(MeO))2PN(Me)P(2-C6H4(MeO))2] In toluene at 60℃; under 30002.4 Torr; for 1h;	100%
In chlorobenzene at 45℃; under 36201.3 Torr; for 4h; Product distribution / selectivity;	99%
In chlorobenzene at 60℃; under 36201.3 Torr; for 4h; Product distribution / selectivity;	99%

: 1436-34-6
1,2-Epoxyhexane

: 592-41-6
1-hexene

Conditions

Conditions	Yield
With triphenylphosphine at 200℃; for 6h;	100%
With carbon monoxide; C29H32IrN5O; bis(trifluoromethane)sulfonimide lithium In benzene-d6 at 80℃; under 7500.75 Torr; for 24h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Time; Schlenk technique; chemoselective reaction;	98%
With zirconium(IV) chloride; sodium iodide In acetonitrile for 0.0166667h; Heating;	88%

: 624-20-4
1,2-dibromohexane

: 592-41-6
1-hexene

Conditions

Conditions	Yield
With 1,2-bis(diphenylphosphino)ethane nickel(II) chloride; ethylmagnesium bromide In tetrahydrofuran at 0℃;	100%
With sodium tetrahydroborate; nickel dichloride In tetrahydrofuran at 20℃; for 1h;	80%
With tetramethylammonium perchlorate In N,N-dimethyl-formamide Electrolysis;

: 16643-09-7
trimethylstannyl sodium

: 2695-47-8
6-Bromo-1-hexene

A: 592-41-6
1-hexene

B: (CH3)3Sn((CH2)4CH)

C: 73017-75-1
(CH3)3Sn(CH2C5H9)

Conditions

Conditions	Yield
With tert-butylamine In tetrahydrofuran react. at 0°C under Ar;	A 0% B 100% C 0%
With DPCH In tetrahydrofuran react. at 0°C under Ar;	A <1 B 98% C 0%
In tetrahydrofuran react. at 0°C under Ar;	A 0% B 98% C 0%
In tetrahydrofuran; benzene react. at 0°C under Ar;	A <1 B 85% C 10%
With DCPH In tetrahydrofuran; benzene react. at 0°C under Ar;	A 15% B 79% C 1.5%

...Expand

: 693-02-7
hex-1-yne

: 592-41-6
1-hexene

Conditions

Conditions	Yield
With hydrogen; N,N′-bis(salicylidene)-ethylenediamino‑palladium In pyridine for 0.35h;	98%
With hydrogen In methanol at 20℃; under 760.051 Torr; for 4.5h; Green chemistry;	94%
With hydrogen In methanol under 760.051 Torr; for 5.5h;	93%

: 1631-73-8
trimethylstannane

: 2695-47-8
6-Bromo-1-hexene

: 4111-54-0
lithium diisopropyl amide

A: 592-41-6
1-hexene

B: 96-37-7
methyl-cyclopentane

C: 661-69-8
hexamethyldistannane

Conditions

Conditions	Yield
In diethyl ether; cyclohexane to 6-bromo-1-hexene (1.04 mmol) and 2 equiv. of Me3SnH in Et2O at 0°C added LDA (1.04 mmol, in cyclohexane) under Ar, react. time 20 min, quenched with water; analyzed by GLPC;	A 77% B 16% C 97%
In diethyl ether; cyclohexane to 6-bromo-1-hexene (1.04 mmol) and 1 equiv. of Me3SnH in Et2O at 0°C added LDA (1.04 mmol, in cyclohexane) under Ar, react. time 20 min, quenched with water; analyzed by GLPC;	A 41% B 18% C 86%
In hexane; cyclohexane to 6-bromo-1-hexene (1.04 mmol) and 2 equiv. of Me3SnH in hexane at 0°C added LDA (1.04 mmol, in cyclohexane) under Ar, react. time 20 min, quenched with water; analyzed by GLPC;	A 76% B 18% C 27%
In hexane; cyclohexane to 6-bromo-1-hexene (1.04 mmol) and 1 equiv. of Me3SnH in hexane at 0°C added LDA (1.04 mmol, in cyclohexane) under Ar, react. time 20 min, quenched with water; analyzed by GLPC;	A 45% B 32% C 48%

...Expand

: 74-85-1
ethene

A: 592-41-6
1-hexene

B polyethylene: polyethylene

Conditions

Conditions	Yield
In chlorobenzene at 60℃; for 4h; Product distribution / selectivity; Autoclave;	A 96% B n/a
In chlorobenzene at 60℃; under 36201.3 Torr; for 4h; Product distribution / selectivity;	A 91% B n/a
methylaluminoxane; tantalum pentachloride In chlorobenzene at 45℃; under 36201.3 Torr; for 4h; Product distribution / selectivity;	A 84% B n/a
In chlorobenzene at 45℃; under 36201.3 Torr; for 4h; Product distribution / selectivity;	A 84% B n/a
In chlorobenzene at 45℃; under 36201.3 Torr; for 4h; Product distribution / selectivity;	A 26% B n/a

: 2695-47-8
6-Bromo-1-hexene

A: 592-41-6
1-hexene

B: 96-37-7
methyl-cyclopentane

C: 110-82-7
cyclohexane

Conditions

Conditions	Yield
With tris-(trimethylsilyl)silane; 2,2'-azobis(isobutyronitrile) at 70℃;	A 4.1% B 93% C 2%
With tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) at 70℃;	A 15% B 83% C 1.2%
With 9-borabicyclo[3.3.1]nonane dimer; tribenzyltin hydride In toluene at 0℃; Product distribution; variation of reagent;	A 29% B 68% C 3%

...Expand

: 74-85-1
ethene

A: 592-41-6
1-hexene

B: 872-05-9
1-Decene

Conditions

Conditions	Yield
Cl(1-)*NPr4(1+) at 50℃; under 22502.3 Torr; for 1h;	A 91.7% B 5.5%
modified methylalumoxane; C28H24Cl2FeN2S In n-heptane at 30 - 52℃; under 21446.5 Torr; for 0.5h; Product distribution / selectivity;
With [η5-(3-SiMe3)C5H3CMe2-3,5-Me2C6H3]Ti(TEA) In toluene at 20℃; under 7500.75 Torr; for 0.25h; Pressure; Reagent/catalyst; Temperature; Inert atmosphere;

: 693-02-7
hex-1-yne

A: 592-41-6
1-hexene

B: 110-54-3
hexane

Conditions

Conditions	Yield
With hydrogen; copper-palladium; silica gel In ethanol at 25℃; under 760 Torr; Kinetics;	A 91% B n/a
With hydrogen; platinum In ethanol at 30℃; under 15200 Torr; Product distribution; 80 atm;	A 41.7% B 57.3%
With hydrogen; Ni(C17H35COO)2; triethylaluminum In toluene at 40℃; Kinetics; Object of study: selectivity;

: 74-85-1
ethene

A: 592-41-6
1-hexene

B: 111-66-0
oct-1-ene

Conditions

Conditions	Yield
With CrCl2(tetrahydrofuran)2; N,N'-bis(diphenylphosphino)-N,N'-dimethylpropane-1,3-diamine In methyl cyclohexane at 80℃; under 30003 Torr; for 0.5h; Inert atmosphere;	A 9% B 91%
bis(2-(decylthio)ethyl)amine; chromium chloride In toluene at 90℃; under 33753.4 Torr; for 0.502778 - 0.527778h; Product distribution / selectivity;	A 90.85% B 0.5%
chromium(III)2-ethylhexanoate; trimethylaluminum; N-[bis(2-methoxyphenyl)phosphino]-P,P-bis(2-methoxyphenyl)-N-methylphosphinous amide In methyl cyclohexane; toluene at 60℃; under 36003.6 - 37503.8 Torr; for 0.175h; Product distribution / selectivity;	A 89.7% B 8.5%

: 74-85-1
ethene

A: 106-98-9
1-butylene

B: 592-41-6
1-hexene

Conditions

Conditions	Yield
[Ph2PC6H4C(OB(C6F5)3)O-κ2P,O](η3-CH2CMeCH2) In toluene at 0℃; under 2280.15 Torr; for 1h; Product distribution; Further Variations:; Temperatures; Pressures; oligomerization;	A 90% B 6%
With tetraphenyl phosphonium chloride; chromium at 80℃; under 37503.8 Torr; for 1h; Product distribution / selectivity;	A 7.5% B 88.3%
With [6,6'-diphenyl-[2,2']-bipyridinyl]NiBr2; triethyl aluminum sesquichloride In toluene Catalytic behavior; Reagent/catalyst; Inert atmosphere; Schlenk technique;	A 88% B 9%

: 52056-08-3
di-n-hexyl diselenide

A: 592-41-6
1-hexene

B: 112-40-3
dodecane

Conditions

Conditions	Yield
at 600℃; under 20 Torr; for 0.0333333h;	A 90% B 7%

: 64851-26-9
1-(Dichloroamino)-n-hexane

A: 592-41-6
1-hexene

B: 628-73-9
hexanenitrile

Conditions

Conditions	Yield
	A 7% B 88%

: 20449-21-2
2-(but-3-en-1-yl)-2-methyl-1,3-dioxolane

: 19689-19-1
5-decene

A: 592-41-6
1-hexene

B: 2-Methyl-2-((E)-oct-3-enyl)-[1,3]dioxolane

Conditions

Conditions	Yield
aluminum oxide; tetramethylstannane; rhenium(VII) oxide In chlorobenzene at 25℃; for 3h; Yields of byproduct given;	A n/a B 87%

...Expand

: 626-93-7
n-hexan-2-ol

: 592-41-6
1-hexene

Conditions

Conditions	Yield
With hydrogen bromide; tetrabutyl phosphonium bromide at 200℃; for 0.25h; Menshutkin Reaction; Inert atmosphere;	86%

: 82963-28-8
{bis(triphenylphosphine)nitrogen}{cis-HW(CO)4P(OMe)3}

: 2695-47-8
6-Bromo-1-hexene

A: 592-41-6
1-hexene

B: 100504-27-6
BrW(CO)4P(OCH3)3(1-)

Conditions

Conditions	Yield
In tetrahydrofuran	A 85% B n/a

...Expand

: 1629-60-3
1-hexene-3-one

: 592-41-6
1-hexene

Conditions

Conditions	Yield
With n-butylsilane; tris(pentafluorophenyl)borate In dichloromethane	84%

: 74-85-1
ethene

A homopolymer of ethylene: homopolymer of ethylene

B: 592-41-6
1-hexene

Conditions

Conditions	Yield
methylaluminoxane; C33H29Cl3CrNP2 at 24 - 30℃; under 2250.23 - 22502.3 Torr; for 1 - 2h; Product distribution / selectivity;	A 3% B 83%
methylaluminoxane; C23H24Cl3CrNPS at 24 - 30℃; under 22502.3 Torr; for 1h; Product distribution / selectivity;	A 18% B 82%
[CrCl2Me(tetrahydrofuran)3]; C27H26N2; polyamethylaluminoxane-IP; trimethylaluminum In toluene at 50℃; under 7757.43 Torr; for 1h; Product distribution / selectivity;

: 112-17-4
n-decyl acetate

A: 592-41-6
1-hexene

B: 872-05-9
1-Decene

C: 822-50-4, 1192-18-3, 13012-46-9, 134932-08-4, 2452-99-5
1,2-dimethylcyclopentane

D: 2511-92-4
1-Butyl-2-methylcyclopropane

E: 41977-37-1
1-Methyl-2-pentylcyclopropane

F: 142-29-0
cyclopentene

Conditions

Conditions	Yield
at 495℃; for 0.00727778h; Rate constant; Product distribution; various temp., also in toluene, also with 14C-labelled ester;	A 1.03% B 81.3% C 1.91% D 1.2% E 0.497% F 0.45%

...Expand

: 74-85-1
ethene

A homopolymer of ethylene: homopolymer of ethylene

B: 592-41-6
1-hexene

C: 111-66-0
oct-1-ene

Conditions

Conditions	Yield
methylaluminoxane; C64H58Cl6Cr2N2O2P4 In dodecane; toluene at 25℃; under 3040.2 Torr; for 1.5h; Product distribution / selectivity;	A 80% B n/a C n/a
methylaluminoxane, aged; C54H54Cl6Cr2N2P4 In dodecane; toluene at 25℃; under 3040.2 Torr; for 1.5h; Product distribution / selectivity;	A 50% B n/a C n/a
methylaluminoxane; C64H58Cl6Cr2N2O2P4 In toluene at 25℃; under 3040.2 Torr; for 1.5h; Product distribution / selectivity;	A 20% B n/a C n/a

...Expand

: 1436-34-6
1,2-Epoxyhexane

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

A: 592-41-6
1-hexene

B: 39741-97-4
formic acid 1-bromomethylpentyl ester

Conditions

Conditions	Yield
With bromine; triphenylphosphine at 0℃; for 0.583333h;	A n/a B 78%

...Expand

: 1631-73-8
trimethylstannane

: 2695-47-8
6-Bromo-1-hexene

A: 592-41-6
1-hexene

B: 96-37-7
methyl-cyclopentane

C: 1527-99-7
n-butyltrimethyltin

Conditions

Conditions	Yield
With n-butyllithium In octane TMTH (1.00 mmol) and 6-bromo-1-hexene (1.08 mmol) in octane cooled to 0°C under Ar, n-BuLi (1.00 mmol, in octane) added via syringe, stirred for 15 min, quenched with water; analyzed by GC;	A 56% B 30% C 78%

...Expand

: 95903-96-1
triethylbenzylammonium ethanolate

: 638-45-9
1-Iodohexane

A: 592-41-6
1-hexene

B: 5756-43-4
ethyl n-hexyl ether

Conditions

Conditions	Yield
at 20 - 25℃; for 1h; Product distribution; other halogenoalkanes, other alkoxides and alcoholates; var. reaction conditions;	A 4.8% B 75%
at 20 - 25℃; for 1h;	A 4.8% B 75%

...Expand

: 638-45-9
1-Iodohexane

A: 592-41-6
1-hexene

B: 5756-43-4
ethyl n-hexyl ether

Conditions

Conditions	Yield
With triethylbenzylammonium ethanolate at 20 - 25℃; for 1h;	A 4.8% B 75%

: 629-03-8
1 ,6-dibromohexane

A: 592-41-6
1-hexene

B: 110-54-3
hexane

C: 592-42-7
1,5-Hexadien

D: 111-27-3
hexan-1-ol

Conditions

Conditions	Yield
With tetramethylammonium perchlorate In 2,2,2-trifluoroethanol; N,N-dimethyl-formamide Electrolysis;	A 4% B 75% C 5% D 18%

...Expand

: 629-03-8
1 ,6-dibromohexane

: 592-41-6
1-hexene

Conditions

Conditions	Yield
With magnesium at 600℃;	72%

: 1631-73-8
trimethylstannane

: 2695-47-8
6-Bromo-1-hexene

A: 592-41-6
1-hexene

B: 96-37-7
methyl-cyclopentane

Conditions

Conditions	Yield
In diethyl ether Irradiation (UV/VIS); photoinduced react. of 6-bromo-1-hexene (1.04 mmol) with 2 equiv. of Me3SnH in Et2O under Ar; analyzed by GLPC;	A 71% B 20%
In hexane Irradiation (UV/VIS); photoinduced react. of 6-bromo-1-hexene (1.04 mmol) with 1 equiv. of Me3SnH in hexane under Ar; analyzed by GLPC;	A 51% B 46%
In diethyl ether Irradiation (UV/VIS); photoinduced react. of 6-bromo-1-hexene (1.04 mmol) with 1 equiv. of Me3SnH in Et2O under Ar; analyzed by GLPC;	A 51% B 45%

...Expand

: 37555-23-0
2-trifluoromethylsulfonyloxy-1-hexene

: 124-38-9
carbon dioxide

A: 592-41-6
1-hexene

B: 4380-88-5
2-butylacrylic acid

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride; tetrabutylammonium tetrafluoroborate In N,N-dimethyl-formamide at 20℃; under 760 Torr; electrolyses, carbon cathode, Mg anode, E=-2.2 V;	A 8% B 70%
With nBuNBF4; bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide at 20℃; electrochemical reaction;	A 8% B 70%

...Expand

: 2695-47-8
6-Bromo-1-hexene

A: 592-41-6
1-hexene

B: 5876-87-9
1,11-dodecadiene

C: 96-37-7
methyl-cyclopentane

Conditions

Conditions	Yield
With potassium In ammonia; tert-butyl alcohol Product distribution; Mechanism; Heating;	A 63.6% B 20.7% C 0.7%
With potassium In ammonia; tert-butyl alcohol Heating;	A 63.6% B 20.7% C 0.7%

...Expand

: 75-54-7
Dichloromethylsilane

: 592-41-6
1-hexene

: 14799-94-1
n-hexylmethyldichlorosilane

Conditions

Conditions	Yield
at 90℃; for 5h; Inert atmosphere;	100%
at 90℃; for 5h; Inert atmosphere;	100%
Stage #1: 1-hexene With diethylenetriaminepentaacetic acid (DTPA)-functionalized silica supported Pt at 60℃; for 0.5h; Stage #2: Dichloromethylsilane at 60℃; for 4h; Catalytic behavior; Temperature; Reagent/catalyst;	99.6%

: 592-41-6
1-hexene

: 1436-34-6
1,2-Epoxyhexane

Conditions

Conditions	Yield
With C20H24CoN2O6(1+)NO3(1-)H2O; oxygen; isobutyraldehyde In acetonitrile at 60℃; under 760.051 Torr; for 8h; Time; chemoselective reaction;	100%
With dihydrogen peroxide; (Bu4N)3K[γ-SiW10O36(PhPO)2] In water at 65℃; for 2h; microwave irradiation;	99%
With tert.-butylhydroperoxide In acetonitrile at 65 - 68℃; for 24h;	99%

: 592-41-6
1-hexene

: 624-20-4
1,2-dibromohexane

Conditions

Conditions	Yield
With bromine In chloroform at 0℃; for 0.166667h;	100%
With bromine In chloroform at 0 - 5℃;	93%
With propane 3-bromo-1-(triphenylphosphonium) tribromide In dichloromethane at 20℃; for 0.5h;	92%

: 592-41-6
1-hexene

: 6920-22-5
Hexane-1,2-diol

Conditions

Conditions	Yield
With poly{[CuBa(pyridine-2,5-dicarboxylate)2(H2O)5]*H2O}; dihydrogen peroxide In acetonitrile at 60℃; for 6h; Catalytic behavior; Reagent/catalyst;	100%
With N-methyl-2-indolinone; fluorous OsO4 In water; acetone; tert-butyl alcohol at 20℃; for 36h;	97%
With N-methyl-2-indolinone; polysulfone microencapsulated OsO4 In water; acetone; acetonitrile at 20℃; for 0.416667h;	96%

: 592-41-6
1-hexene

: 110-54-3
hexane

Conditions

Conditions	Yield
With hydrogen; In tetrahydrofuran at 90℃; under 5250.4 Torr; for 0.166667h; Product distribution; other olefins, other catalysts; var. temp., solv., press., and time;	100%
With hydrogen; (iPrPDI)Fe(N2)2 at 20℃; under 3040 Torr; for 19h;	100%
With Wilkinson's catalyst; hydrogen In dichloromethane-d2 at 45℃; under 3000.3 Torr; for 6h; Concentration; Reagent/catalyst; Solvent; Temperature; Time; Sealed tube; Inert atmosphere;	100%

: 592-41-6
1-hexene

: 591-78-6
n-hexan-2-one

Conditions

Conditions	Yield
With water; palladium dichloride In N,N-dimethyl-formamide under 1300 Torr; for 5h; Rate constant; Mechanism; oxidation of different olefines by Wacker process; variation of solvent: formamide, tensioactive and cotensioactive component in microemulsions; reaction time;	100%
With water; palladium dichloride In various solvent(s) under 1300 Torr; for 0.833333h; closed reactor, in microemulsion with formamide;	100%
With Pd(II)(15-crown-5-phen)Cl2; dinitrogen monoxide In N,N-dimethyl acetamide; water at 150℃; under 2250.23 Torr; for 18h;	99%

: 592-41-6
1-hexene

: 928-65-4
hexyltrichlorosilane

Conditions

Conditions	Yield
With trichlorosilane at 90℃; for 5h; Inert atmosphere;	100%
With trichlorosilane at 90℃; for 5h; Inert atmosphere;	100%
With trichlorosilane; nickel In tetrahydrofuran at 20 - 25℃;	94%

: 592-41-6
1-hexene

: 592-43-8
2-hexene

Conditions

Conditions	Yield
With C10H19B11Cl11PPd In dichloromethane-d2 at 25℃; for 0.0833333h; Inert atmosphere;	100%
With aluminum (III) chloride; [(2,6-iPrC6H3NC(Me)C(Me)N-2,6-iPrC6H3)Pd(CH3)(Cl)]; acetonitrile In dichloromethane at 25℃; for 18h; Reagent/catalyst; Darkness; Inert atmosphere;	81%
With platinum on activated charcoal; carbon dioxide at 300 - 305℃;

: 617-86-7
triethylsilane

: 592-41-6
1-hexene

: 13810-04-3
n-hexyltriethylsilane

Conditions

Conditions	Yield
at 90℃; for 5h; Inert atmosphere;	100%
at 90℃; for 5h; Inert atmosphere;	100%
With C26H31F5NZn(1+)*C24BF20(1-) In dichloromethane-d2 at 20℃; for 28h; Reagent/catalyst; Inert atmosphere; Glovebox;	100%

: 592-41-6
1-hexene

: 1066-35-9
dimethylmonochlorosilane

: 3634-59-1
dimethylhexylsilyl chloride

Conditions

Conditions	Yield
at 90℃; for 5h; Inert atmosphere;	100%
With platinum on carbon nanotubes In neat (no solvent) at 20℃; for 24h;	97%
dihydrogen hexachloroplatinate In diethyl ether for 15h; Heating;	80%

: 592-41-6
1-hexene

: 2487-90-3
trimethoxysilane

: 3069-19-0
n-hexyltrimethoxysilane

Conditions

Conditions	Yield
at 90℃; for 5h; Inert atmosphere;	100%
at 90℃; for 5h; Inert atmosphere;	100%
With dichlorobis-(ethylene)-μ,μ'-dichloroplatinum(II)

: 592-41-6
1-hexene

: 998-30-1
Triethoxysilane

: 18166-37-5
hexyltriethoxysilane

Conditions

Conditions	Yield
at 90℃; for 5h; Inert atmosphere;	100%
at 90℃; for 5h; Inert atmosphere;	100%
With platinum on carbon nanotubes In neat (no solvent) at 20℃; for 24h;	98%

: 592-41-6
1-hexene

: 938-24-9
indantrione

: 145046-47-5
2-((E)-Hex-2-enyl)-2-hydroxy-indan-1,3-dione

Conditions

Conditions	Yield
In chloroform at 80℃; for 4h;	100%

: 592-41-6
1-hexene

: 13412-55-0
triphenylmethylacetonitrile oxide

: 123622-72-0
5-butyl-3-(triphenylmethyl)-2-isoxazoline

Conditions

Conditions	Yield
In benzene at 85℃; for 48h;	100%

: 592-41-6
1-hexene

: 824-79-3
sodium 4-methylbenzenesulfinate

: 71963-96-7
2-iodo-1-tosylhexane

Conditions

Conditions	Yield
With iodine In water; ethyl acetate at 20℃; for 1.33333h; iodosulfonization;	100%
With iodine In water; ethyl acetate for 2h; Ambient temperature;

: 592-41-6
1-hexene

: 114341-77-4
α-bromopropionyl 2-oxazolidinone amide

: 4-bromo-2-methyloctanoyl 2-oxazolidinone amide

Conditions

Conditions	Yield
With triethyl borane; scandium tris(trifluoromethanesulfonate) In hexane; 1,2-dichloro-ethane at 25℃; for 1h;	100%

: 592-41-6
1-hexene

: 141353-28-8
3-bromoacetyl-1,3-oxazolidin-2-one

: 224804-26-6
4-bromooctanoyl 2-oxazolidinone amide

Conditions

Conditions	Yield
With triethyl borane; ytterbium(III) triflate In hexane; 1,2-dichloro-ethane at 25℃; for 1h;	100%
With air; triethyl borane In 2,2,2-trifluoroethanol at 25℃; for 1.5h;	90%
With triethyl borane; oxygen; ytterbium(III) triflate In hexane; 1,2-dichloro-ethane at 20℃; for 0.5h;	83%

: 592-41-6
1-hexene

: 114341-80-9
(S)-4-Benzyl-3-((R)-2-bromo-propionyl)-oxazolidin-2-one

: 4-bromo-2-methyloctanoyl (5(S)-benzyl-2-oxazolidone) amide

Conditions

Conditions	Yield
With triethyl borane; scandium tris(trifluoromethanesulfonate) In hexane; 1,2-dichloro-ethane at 25℃; for 1h;	100%

: 592-41-6
1-hexene

: 280-64-8
9-bora-bicyclo[3.3.1]nonane

: 42371-64-2
9-hexyl-9-borabicyclo[3.3.1]nonane

Conditions

Conditions	Yield
In tetrahydrofuran at 60℃; for 12h; Schlenk technique; Inert atmosphere;	100%
In tetrahydrofuran at 25℃; for 24h; Schlenk technique; Inert atmosphere;	100%
In tetrahydrofuran at 20℃; for 2h;	87%

: 592-41-6
1-hexene

: 56252-56-3
diisobutyl(2,6-di-tert-butyl-4- methylphenoxy)aluminum

: 106751-52-4
C6H13Al(OC6H2(CH3)(C(CH3)3)2(CH2CH(CH3)2))

Conditions

Conditions	Yield
With catalyst: ZrCl2(C5H5)2/AlH(CH2CH(CH3)2)2 In xylene react. of the Al compd. with the olefin (mol ratio 1:3) in dry xylene at 140°C for 5-7 h;	100%
With catalyst: ZrCl4/AlH(CH2CH(CH3)2)2 In toluene react. of the Al compd. with the olefin (mol ratio 1:3) in toluene for 10 h;	78%
With catalyst: (C5H5)2ZrCl2-iBu2AlH In xylene byproducts: isobutene; addn. of Cp2ZrCl2 to phenoxide at 20°C, mixt. stirred 0.5h, addn. of i-Bu2AlH, refluxed and addn. of olefin, reaction time 5 h at 140°C; isobutene condensed in a trap cooled to -78°C;
With catalyst: (C5H5)2ZrCl2-iBu2AlH In toluene byproducts: isobutene; addn. of Cp2ZrCl2 to phenoxide at 20°C, mixt. stirred 0.5h, addn. of i-Bu2AlH, refluxed and addn. of olefin, reaction time 10h at 140°C; isobutene condensed in a trap cooled to -78°C;
With catalyst: ZrCl4/AlH(CH2CH(CH3)2)2 In xylene react. of the Al compd. with the olefin (mol ratio 1:3) in dry xylene at 140°C for 5-7 h;	<50

: 592-41-6
1-hexene

: 892-20-6
triphenylstannane

: 103047-76-3
n-hexyltriphenylstannane

Conditions

Conditions	Yield
Irradiation (UV/VIS); UV-irradiation at 25-50 °C for 18 h;;	100%
Irradiation (UV/VIS); UV-irradiation at 25-50 °C for 18 h;;	100%

: 592-41-6
1-hexene

: 1145706-23-5
[Re(Br)(H)(NO)(PiPr3)2]

: 1260114-02-0
[Re(Br)(H)(NO)(Pi-Pr3)2(η2-CH2=CHBu)]

Conditions

Conditions	Yield
In benzene-d6 (N2, Schlenk) complex and 1-hexane were mixed in C6D6; evapd. in vac. for 24 h; elem. anal.;	100%
With BH3THF or B(C6F5)3 or B(C2H5)3 or B(C6H5)3 (Ar) the complex and boron Lewis acid (B(C6F5)3 or BH3THF or B(C2H5)3 or B(C6H5)3) were mixed in 1-hexane; detected by NMR spectra;

: 592-41-6
1-hexene

: 1873-88-7
1,1,1,3,5,5,5-heptamethyltrisiloxan

: 1873-90-1
3-n-hexyl-1,1,1,3,5,5,5-heptamethyltrisiloxane

Conditions

Conditions	Yield
With 1,3-bis(tert-buthylethynyl)-1,1,3,3-tetramethyldisiloxane platinum (0) at 50℃; for 16h; Time; Reagent/catalyst;	100%
With C27H55NOPtSi5 In benzene-d6; toluene at 50℃; for 5h; Reagent/catalyst; Concentration; Schlenk technique; Inert atmosphere;	95%
With C24H33N2ORh In tetrahydrofuran at 20℃; for 24h; Time; Inert atmosphere; Glovebox; regioselective reaction;	86%

: 67-56-1
methanol

: 592-41-6
1-hexene

: 1514956-43-4
2-methoxyhexyltellurium tribromide

Conditions

Conditions	Yield
With tellurium(IV) tetrabromide for 8h; Heating; regioselective reaction;	100%

: 592-41-6
1-hexene

: 1333-74-0
hydrogen

: 110-54-3
hexane

Conditions

Conditions	Yield
With C61H98ClN3P2Ru In dichloromethane-d2 at 50℃; under 3040.2 Torr; for 4h; Reagent/catalyst; Time;	100%
With triethylsilane; ReH(NO)2(P(CH(CH3)2)3)2; tris(pentafluorophenyl)borate at 100℃; under 30003 Torr; for 1h; Catalytic behavior; Autoclave;
With triethylsilane; [ReH(NO)2(P(C6H11)3)2]; tris(pentafluorophenyl)borate at 100℃; under 30003 Torr; for 1h; Catalytic behavior; Autoclave;

: 1295-35-8
bis(1,5-cyclooctadiene)nickel (0)

: 592-41-6
1-hexene

: 4141-59-7
1,2-bis(di-tert-butyl)phosphinoethane

: [(dtbpe)Ni(1-hexene)]

Conditions

Conditions	Yield
In tetrahydrofuran-d8 at 60℃; for 24h; Inert atmosphere;	100%

...Expand

1-Hexene Consensus Reports

Reported in EPA TSCA Inventory.

1-Hexene Standards and Recommendations

ACGIH TLV: TWA 50 ppm

1-Hexene Specification

The 1-Hexene is an organic compound with the formula C₆H₁₂. The IUPAC name of this chemical is hex-1-ene. With the CAS registry number 592-41-6, it is also named as Hexene. The product's categories are Industrial/Fine Chemicals; 1-Olefins (GC Standard); Analytical Chemistry; Standard Materials for GC; HA-HTGasoline, Diesel & Petroleum; Alpha Sort; E-LAlphabetic; H; Olefins; Substance Classes; Volatiles/ Semivolatiles; Acyclic; Alkenes; Organic Building Blocks. Besides, it is colourless liquid, which should be stored in a closed cool and dry place.

The primary use of 1-hexene is as a comonomer in production of polyethene. Another significant use of 1-hexene is the production of linear aldehyde via hydroformylation ( oxo synthesis ) for later production of the short-chain fatty acid heptanoic acid.

Physical properties about 1-Hexene are: (1)ACD/LogP: 3.36; (2)ACD/LogD (pH 5.5): 3.356; (3)ACD/LogD (pH 7.4): 3.356; (4)ACD/BCF (pH 5.5): 209.093; (5)ACD/BCF (pH 7.4): 209.093; (6)ACD/KOC (pH 5.5): 1594.066; (7)ACD/KOC (pH 7.4): 1594.066; (8)#Freely Rotating Bonds: 3; (9)Index of Refraction: 1.397; (10)Molar Refractivity: 29.571 cm³; (11)Molar Volume: 122.67 cm³; (12)Polarizability: 11.723×10^-24cm³; (13)Surface Tension: 20.139 dyne/cm; (14)Density: 0.686 g/cm³; (15)Enthalpy of Vaporization: 29.24 kJ/mol; (16)Boiling Point: 62.81 °C at 760 mmHg; (17)Vapour Pressure: 188.145 mmHg at 25°C.

Preparation: this chemical can be prepared by ethene. This reaction will need reagent methylaluminoxane, catalyst tridentate PNP Cr(III) complex. The reaction time is 30 min with reaction temperature of 80 °C. The yield is about 100%.

Uses of 1-Hexene: it can be used to produce hex-1-en-3-one at temperature of 55 °C. It will need reagent HgSO₄ and diluted H₂SO₄.

When you are using this chemical, please be cautious about it as the following:
It is highly flammable and toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Please keep container in a well-ventilated place and keep away from sources of ignition - No smoking. Take precautionary measures against static discharges. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical may cause lung damage if swallowed. It is vapours may cause drowsiness and dizziness. When you are using it, do not empty into drains and do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer). In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: CCCCC=C
(2)InChI: InChI=1/C6H12/c1-3-5-6-4-2/h3H,1,4-6H2,2H3
(3)InChIKey: LIKMAJRDDDTEIG-UHFFFAOYAY
(4)Std. InChI: InChI=1S/C6H12/c1-3-5-6-4-2/h3H,1,4-6H2,2H3
(5)Std. InChIKey: LIKMAJRDDDTEIG-UHFFFAOYSA-N

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rabbit	LD	skin	> 10gm/kg (10000mg/kg)	SKIN AND APPENDAGES (SKIN): HAIR: OTHER	National Technical Information Service. Vol. OTS0535205,
rat	LC50	inhalation	32000ppm/4H (32000ppm)	BEHAVIORAL: GENERAL ANESTHETIC BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES	National Technical Information Service. Vol. OTS0535205,
rat	LD	oral	> 10gm/kg (10000mg/kg)		National Technical Information Service. Vol. OTS0535205,

Product Name

1-Hexene

Synthetic route

1-Hexene Consensus Reports

1-Hexene Standards and Recommendations

1-Hexene Specification

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