Conditions | Yield |
---|---|
With thionyl chloride In toluene for 2h; Reflux; | 100% |
With thionyl chloride for 2h; Heating / reflux; | 98% |
With thionyl chloride for 2h; Heating; | 98% |
Conditions | Yield |
---|---|
With bis(tri-t-butylphosphine)palladium(0); benzyltriphenylphosphonium chloride In toluene at 110℃; under 38002.6 Torr; for 24h; Glovebox; Autoclave; Inert atmosphere; | 98% |
1-Iodonaphthalene
4-nitro-benzoyl chloride
A
p-nitrobenzene iodide
B
naphthalene-1-carbonic acid chloride
Conditions | Yield |
---|---|
With (Xantphos)Pd(4-C6H4NO2)(I) In benzene at 90℃; for 20h; Sealed tube; Inert atmosphere; | A n/a B 71% |
Conditions | Yield |
---|---|
With carbon disulfide; aluminium trichloride |
Conditions | Yield |
---|---|
at 190℃; |
Conditions | Yield |
---|---|
at 190℃; |
Conditions | Yield |
---|---|
at 190℃; |
Conditions | Yield |
---|---|
at 190℃; |
pyridine
naphthalene
trichloroacetic acid
A
phosgene
B
chloroform
C
naphthalene-1-carbonic acid chloride
Conditions | Yield |
---|---|
at 190℃; |
oxalyl dichloride
1-naphthalenecarboxylic acid
N,N-dimethyl-formamide
naphthalene-1-carbonic acid chloride
Conditions | Yield |
---|---|
In dichloromethane |
2-(4,5-Dihydro-1,3-oxazol-2-yl)aniline
1-naphthalenecarboxylic acid
naphthalene-1-carbonic acid chloride
Conditions | Yield |
---|---|
With oxalyl dichloride In dichloromethane; N,N-dimethyl-formamide |
carbon monoxide
1-Bromonaphthalene
naphthalene-1-carbonic acid chloride
Conditions | Yield |
---|---|
With bis(tri-t-butylphosphine)palladium(0); benzyltriphenylphosphonium chloride In toluene at 110℃; under 15201 Torr; for 24h; Autoclave; Glovebox; |
Conditions | Yield |
---|---|
With (Xantphos)Pd(4-C6H4NO2)(I) In benzene at 110℃; for 20h; Sealed tube; Inert atmosphere; | A n/a B 63 %Spectr. |
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In toluene at 125℃; for 12h; |
oxalyl dichloride
1-naphthalenecarboxylic acid
naphthalene-1-carbonic acid chloride
Conditions | Yield |
---|---|
With N,N-dimethyl-formamide In dichloromethane at 0 - 20℃; for 2h; Inert atmosphere; |
Conditions | Yield |
---|---|
With 1,4-diaza-bicyclo[2.2.2]octane; tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In toluene at 100℃; for 16h; Sealed tube; Inert atmosphere; |
IUPAC Name: Naphthalene-1-carbonyl chloride
Following is the structure of 1-Naphthoyl chloride (CAS NO.879-18-5):
Empirical Formula: C11H7ClO
Molecular Weight: 190.6257
EINECS: 212-903-9
Index of Refraction: 1.644
Molar Refractivity: 54.33 cm3
Molar Volume: 149.9 cm3
Density: 1.271 g/cm3
Flash Point: 141.2 °C
Melting point: 16-19 °C(lit.)
Sensitive: Moisture Sensitive
Surface Tension: 48.1 dyne/cm
Enthalpy of Vaporization: 53.74 kJ/mol
Boiling Point: 297.5 °C at 760 mmHg
Vapour Pressure: 0.00134 mmHg at 25 °C
Appearance of 1-Naphthoyl chloride (CAS NO.879-18-5): Low melting solid/Liquid
Stability of 1-Naphthoyl chloride (CAS NO.879-18-5): Stable. Incompatible with water, moisture, strong oxidizing agents, bases.
Product Categories of 1-Naphthoyl chloride (CAS NO.879-18-5): Miscellaneous; Acid Halides; Carbonyl Compounds; Organic Building Blocks
Canonical SMILES: C1=CC=C2C(=C1)C=CC=C2C(=O)Cl
InChI: InChI=1S/C11H7ClO/c12-11(13)10-7-3-5-8-4-1-2-6-9(8)10/h1-7H
InChIKey: NSNPSJGHTQIXDO-UHFFFAOYSA-N
1-Naphthoyl chloride (CAS NO.879-18-5) hasn't been listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Hazard Codes: C
Risk Statements: 34-37-14
R34:Causes burns.
R37:Irritating to respiratory system
R14 :Reacts violently with water.
Safety Statements: 26-36/37/39-45-28-60-30-20-8
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S28:After contact with skin, wash immediately with plenty of soap-suds.
S60:This material and its container must be disposed of as hazardous waste.
S20:When using, do not eat or drink.
S30:Never add water to this product.
S8:Keep container dry.
RIDADR: UN 3261 8/PG 2
WGK Germany: 3
F: 21
Hazard Note: Corrosive
HazardClass: 8
PackingGroup: II
1-Naphthoyl chloride , its cas register number 879-18-5. It also can be called 1-Naphthalenecarbonyl chloride ; 1-(Chlorocarbonyl)naphthalene ;1-Naphthoic acid chloride ; and alpha-Naphthoyl chloride . Its extinguishing agents is foam ,carbon dioxide, and sand.
1-Naphthoyl chloride (CAS NO.879-18-5) could be stable under normal temperatures and pressures. It should avoid the condition like exposure to moist air or water. It is not compatible with strong oxidizing agents, strong bases. And also prevent it to broken down into hazardous decomposition products: Hydrogen chloride, carbon monoxide, carbon dioxide. However, its hazardous polymerization has not been reported.
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