1-Tridecanol supplier | CasNO.112-70-9

Name
1-Tridecanol
EINECS 203-998-8
CAS No. 112-70-9
Article Data42
CAS DataBase
Density 0.822 g/mL at 25 °C(lit.)
Solubility chloroform: 0.1 g/mL, clear,insoluble in water
Melting Point 29-34 °C(lit.)
Formula C13H28 O
Boiling Point 272.1 °C at 760 mmHg
Molecular Weight 200.365
Flash Point 121.1 °C
Transport Information
Appearance white solid.
Safety Mildly toxic by ingestion and skin contact. A skin irritant. Combustible when exposed to heat or flame. To fight fire, use mist, spray, dry chemical, foam. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALCOHOL, DENATURED; ALCOHOLS, C6-12; ALCOHOLS, C9-11; ALCOHOLS, C12-13, ETHOXYLATED; ALCOHOLS, C12-15, ETHOXYLATED; ALCOHOLS, C12-16, ETHOXYLATED; ALCOHOLS, C14-15, ETHOXYLATED; ALCOHOLS, C16-18, ETHOXYLATED; ALCOHOLS, C8-10, ETHOXYLATED PROPOXYLATED; ALCOHOLS, C12-15, ETHOXYLATED PROPOXYLATED; ALCOHOLS, N.O.S..
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms NSC 5252;Tridecyl alcohol; n-Tridecan-1-ol; n-Tridecanol; n-Tridecyl alcohol
PSA 20.23000
LogP 4.28970

Synthetic route

: 638-53-9
tridecanoic acid

: 112-70-9
tridecan-1-ol

Conditions

Conditions	Yield
With hydrogen; Rh/Al2O3; molybdenum hexacarbonyl In 1,2-dimethoxyethane at 150℃; under 76000 Torr; for 16h;	97%

: C13H25Cl3O

: 112-70-9
tridecan-1-ol

Conditions

Conditions	Yield
With lithium borohydride; sodium hydroxide In isopropyl alcohol Temperature; Jocic Reaction; Heating; Inert atmosphere;	95%

: 1731-88-0
methyl tridecanoate

: 112-70-9
tridecan-1-ol

Conditions

Conditions	Yield
Stage #1: methyl tridecanoate With bis(acetylacetonato)dioxidomolybdenum(VI); 1,1,3,3-Tetramethyldisiloxane; Triphenylphosphine oxide In toluene at 100℃; for 20h; Inert atmosphere; Sealed tube; Stage #2: With tetrabutyl ammonium fluoride In tetrahydrofuran; toluene for 2h; Inert atmosphere;	94%

: 1436673-44-7
C18H36O2

: 112-70-9
tridecan-1-ol

Conditions

Conditions	Yield
With methanol; toluene-4-sulfonic acid at 20℃; for 2h;	90%

: 32466-55-0
(E)-tridec-2-enoic acid

: 112-70-9
tridecan-1-ol

Conditions

Conditions	Yield
With hydrogen; Rh/Al2O3; molybdenum hexacarbonyl In 1,2-dimethoxyethane at 150℃; under 76000 Torr; for 16h;	89%

: 110023-67-1
1-Methyl-4-(1-methylsulfanyl-tridecane-1-sulfinyl)-benzene

: 112-70-9
tridecan-1-ol

Conditions

Conditions	Yield
With sodium tetrahydroborate In 1,4-dioxane; water Irradiation;	80%

: 28267-29-0
ethyl tridecanoate

: 112-70-9
tridecan-1-ol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In diethyl ether at 0 - 20℃;	79%
With ethanol; sodium

: 130340-56-6
2-(3-carboxypropyl)-5-(12-hydroxydodecyl)thiophene

A: 629-76-5
pentadecanol

B: 112-70-9
tridecan-1-ol

C: 36653-82-4
1-Hexadecanol

D: 62643-46-3
20-hydroxyeicosanoic acid

Conditions

Conditions	Yield
With Raney nickel W-2 In ethanol for 2h; Heating; Further byproducts given;	A 2.8% B 3.5% C 12.6% D 65%

...Expand

: 130340-56-6
2-(3-carboxypropyl)-5-(12-hydroxydodecyl)thiophene

A: 112-70-9
tridecan-1-ol

B: 112-72-1
1-Tetradecanol

C: 36653-82-4
1-Hexadecanol

D: 62643-46-3
20-hydroxyeicosanoic acid

Conditions

Conditions	Yield
With Raney nickel W-2 In ethanol for 2h; Heating; Further byproducts given;	A 3.5% B 6% C 12.6% D 65%

...Expand

: 130340-56-6
2-(3-carboxypropyl)-5-(12-hydroxydodecyl)thiophene

A: 112-70-9
tridecan-1-ol

B: 112-72-1
1-Tetradecanol

C: 117197-09-8
tridecyl hexanoate

D: 62643-46-3
20-hydroxyeicosanoic acid

Conditions

Conditions	Yield
With Raney nickel W-2 In ethanol for 2h; Heating; Further byproducts given;	A 3.5% B 6% C 0.5% D 65%

...Expand

: 130340-56-6
2-(3-carboxypropyl)-5-(12-hydroxydodecyl)thiophene

A: 112-70-9
tridecan-1-ol

B: 112-72-1
1-Tetradecanol

C: 71801-23-5
tetradecyl hexanoate

D: 62643-46-3
20-hydroxyeicosanoic acid

Conditions

Conditions	Yield
With Raney nickel W-2 In ethanol for 2h; Heating; Further byproducts given;	A 3.5% B 6% C 0.6% D 65%

...Expand

: 130340-56-6
2-(3-carboxypropyl)-5-(12-hydroxydodecyl)thiophene

A: 112-70-9
tridecan-1-ol

B: 112-72-1
1-Tetradecanol

C: 62643-46-3
20-hydroxyeicosanoic acid

D: 130340-57-7
n-hexanoic acid 1-hexadecyl

Conditions

Conditions	Yield
With Raney nickel W-2 In ethanol for 2h; Heating; Further byproducts given;	A 3.5% B 6% C 65% D 0.1%

...Expand

: 130340-56-6
2-(3-carboxypropyl)-5-(12-hydroxydodecyl)thiophene

A: 112-70-9
tridecan-1-ol

B: 112-72-1
1-Tetradecanol

C: 62643-46-3
20-hydroxyeicosanoic acid

D: 14331-11-4
hexadecyl hexanoate

Conditions

Conditions	Yield
With Raney nickel W-2 In ethanol for 2h; Heating; Further byproducts given;	A 3.5% B 6% C 65% D 0.25%

...Expand

: 130340-56-6
2-(3-carboxypropyl)-5-(12-hydroxydodecyl)thiophene

A: 112-70-9
tridecan-1-ol

B: 112-72-1
1-Tetradecanol

C: 62643-46-3
20-hydroxyeicosanoic acid

D: 29710-33-6
tetradecyl heptanoate

Conditions

Conditions	Yield
With Raney nickel W-2 In ethanol for 2h; Heating; Further byproducts given;	A 3.5% B 6% C 65% D 0.4%

...Expand

: 110023-68-2
C27H40OS2

: 112-70-9
tridecan-1-ol

Conditions

Conditions	Yield
With sodium tetrahydroborate In 1,4-dioxane; water Irradiation;	61%

: 201230-82-2
carbon monoxide

: 143-15-7
1-dodecylbromide

: 112-70-9
tridecan-1-ol

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; sodium cyanoborohydride In tert-butyl alcohol; benzene at 90℃; under 60800 Torr; for 3h;	60%

: 64-18-6
formic acid

: 112-41-4
1-dodecene

A: 22663-61-2
2-methyl-1-dodecanol

B: 112-70-9
tridecan-1-ol

Conditions

Conditions	Yield
With dodecacarbonyl-triangulo-triruthenium; sodium formate; lithium chloride at 150℃; for 24h; Autoclave; Ionic liquid;	A 8.5% B 42%

...Expand

: 50-00-0
formaldehyd

: 18996-28-6
dodecylmagnesium chloride

A: 68975-76-8
formaldehyde ditridecylacetal

B: 112-70-9
tridecan-1-ol

Conditions

Conditions	Yield
With diethyl ether

...Expand

: 50-00-0
formaldehyd

: 18996-28-6
dodecylmagnesium chloride

: 112-70-9
tridecan-1-ol

Conditions

Conditions	Yield
With diethyl ether

: 765-09-3
1-bromotridecane

: 563-63-3
silver(I) acetate

: 112-70-9
tridecan-1-ol

Conditions

Conditions	Yield
at 150℃; und Erwaermen des Reaktionsprodukts mit aethanol.Kalilauge;

: 7069-41-2
(2E)-tridecenal

: 112-70-9
tridecan-1-ol

Conditions

Conditions	Yield
With ethanol; platinum Hydrogenation;

: 50-00-0
formaldehyd

: 60-29-7
diethyl ether

: 112-52-7
1-chlorododecane

A: 68975-76-8
formaldehyde ditridecylacetal

B: 112-70-9
tridecan-1-ol

Conditions

Conditions	Yield
Reaktion der Magnesiumverbindung;

...Expand

: 29780-00-5
methyl 12-tridecenoate

: 112-70-9
tridecan-1-ol

Conditions

Conditions	Yield
(i) H2, Raney-Ni, (ii) LiAlH4, Et2O; Multistep reaction;

: 50-00-0
formaldehyd

: 143-15-7
1-dodecylbromide

: 112-70-9
tridecan-1-ol

Conditions

Conditions	Yield
(i) Mg, Et2O, (ii) /BRN= 1209228/; Multistep reaction;

: 50-00-0
formaldehyd

: dodecyl magnesium iodide

: 112-70-9
tridecan-1-ol

Conditions

Conditions	Yield
With water Multistep reaction;

: 13362-52-2
1,13-tridecanediol

: 112-70-9
tridecan-1-ol

Conditions

Conditions	Yield
With lithium triethylborohydride In various solvent(s) for 0.416667h; Thermodynamic data; ΔH;

: 1725-04-8
oxacyclotetradecan-2-one

: 112-70-9
tridecan-1-ol

Conditions

Conditions	Yield
With lithium triethylborohydride In various solvent(s) for 0.416667h; Thermodynamic data; ΔH;

: (S)-12,13-epoxy-2,4,6,8,10-tridecapentayne

: 112-70-9
tridecan-1-ol

Conditions

Conditions	Yield
With hydrogen; platinum(IV) oxide In ethanol for 1h;

: 10486-19-8
tridecanal

: 112-70-9
tridecan-1-ol

Conditions

Conditions	Yield
With ruthenium trichloride; trisodium tris(3-sulfophenyl)phosphine; heptakis(2,6-di-O-methyl)cyclomaltoheptaose; hydrogen; sodium iodide In water; toluene at 80℃; under 22501.8 Torr; for 2.5h;

: 112-70-9
tridecan-1-ol

: 10486-19-8
tridecanal

Conditions

Conditions	Yield
Stage #1: tridecan-1-ol With oxalyl dichloride; dimethyl sulfoxide In dichloromethane at -60℃; for 1.5h; Stage #2: With triethylamine In dichloromethane at -60℃; for 0.5h;	100%
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; trichloroisocyanuric acid In diethyl ether at -30℃; for 0.5h;	95%
With N-chloro-succinimide; N-(phenylthio)-N-(tert-butyl)amine; potassium carbonate; 4 A molecular sieve In dichloromethane at 20℃; for 1h;	91%

: 112-70-9
tridecan-1-ol

: 6214-59-1
3-(thymine-1-yl)propionic acid

: tridecyl 3-(thymin-1-yl)propionate

Conditions

Conditions	Yield
With dicyclohexyl-carbodiimide In pyridine at 0 - 20℃; for 48h;	100%

: 112-70-9
tridecan-1-ol

: 35599-77-0
1-iodotridecane

Conditions

Conditions	Yield
With 1H-imidazole; iodine; triphenylphosphine In dichloromethane at 20℃; for 0.5h;	98%
With iodine; triphenylphosphine In dichloromethane at 23℃; for 3h;	96.3%
With iodine; 1,2-bis-(diphenylphosphino)ethane In dichloromethane at 25℃; for 2h;	87%
With 1H-imidazole; iodine; triphenylphosphine In dichloromethane at 0 - 20℃; for 3h;	84%
With phosphorus; iodine at 180℃;

: 112-70-9
tridecan-1-ol

: 36617-19-3
tridecyl tridecanoate

Conditions

Conditions	Yield
With iodine; potassium carbonate In tert-butyl alcohol at 20℃; for 41h;	98%

: 75-15-0
carbon disulfide

: 111-87-5
octanol

: 112-70-9
tridecan-1-ol

: dithiocarbonic acid S-octyl ester O-tridecyl ester

Conditions

Conditions	Yield
Stage #1: carbon disulfide; tridecan-1-ol With triphenylphosphine; diethylazodicarboxylate In dimethyl sulfoxide at 20℃; Stage #2: octanol In dimethyl sulfoxide at 20℃; for 4h;	98%

...Expand

: 111-87-5
octanol

: 112-70-9
tridecan-1-ol

: 124-38-9
carbon dioxide

: C22H44O3

Conditions

Conditions	Yield
With triphenylphosphine; diethylazodicarboxylate In dimethyl sulfoxide for 4h;	98%

...Expand

: 40336-85-4
sulphomaleic anhydride

: 112-70-9
tridecan-1-ol

: (E)-2-Sulfo-but-2-enedioic acid 4-tridecyl ester

Conditions

Conditions	Yield
at 70℃; for 1h;	96%

: 43153-20-4
5,5-bis-bromomethyl-2,2-dimethyl-[1,3]dioxane

: 112-70-9
tridecan-1-ol

: 2,2-bis((tridecyloxy)methyl)propane-1,3-diol

Conditions

Conditions	Yield
Stage #1: tridecan-1-ol With sodium hydride In N,N-dimethyl-formamide at 0 - 20℃; for 0.25h; Inert atmosphere; Stage #2: 5,5-bis-bromomethyl-2,2-dimethyl-[1,3]dioxane In N,N-dimethyl-formamide at 120℃; for 15h; Inert atmosphere;	95%

: 112-70-9
tridecan-1-ol

: 124-63-0
methanesulfonyl chloride

: 62732-69-8
tridecyl mesylate

Conditions

Conditions	Yield
With triethylamine In tetrahydrofuran at 0 - 20℃; for 18h; Inert atmosphere;	93%

: 44855-53-0
6-methylheptylamine

: 112-70-9
tridecan-1-ol

: isooctyl isotridecyl amine

Conditions

Conditions	Yield
Stage #1: tridecan-1-ol With hydrogen at 180 - 200℃; under 6000.6 - 11251.1 Torr; for 1h; Large scale; Stage #2: 6-methylheptylamine With hydrogen at 210 - 220℃; under 6000.6 - 7500.75 Torr; Temperature; Pressure; Large scale;	92%

: 112-70-9
tridecan-1-ol

: 629-60-7
tridecanenitrile

Conditions

Conditions	Yield
With ammonium hydroxide; iodine at 60℃; for 8h;	91%
With ammonium hydroxide; iodine at 60℃; for 8h;	91%

: 112-70-9
tridecan-1-ol

: 124-07-2
Octanoic acid

: 42231-41-4
tridecyl octanoate

Conditions

Conditions	Yield
With silphos at 20℃; for 0.0833333h; Neat (no solvent);	90%

: 17573-92-1
3-methoxy-thiophene

: 112-70-9
tridecan-1-ol

: 120621-20-7
3-tridecanoxythiophene

Conditions

Conditions	Yield
With sodium hydrogencarbonate In toluene at 110℃; for 20h; Inert atmosphere;	89%

: 112-70-9
tridecan-1-ol

: 765-09-3
1-bromotridecane

Conditions

Conditions	Yield
With carbon tetrabromide In dichloromethane at -30 - 20℃;	88%
With hydrogen bromide at 100℃;
With hydrogen bromide

: 112-70-9
tridecan-1-ol

: 98-59-9
p-toluenesulfonyl chloride

: 41240-48-6
1-tosyloxytridecane

Conditions

Conditions	Yield
With LACTIC ACID; triethylamine 1.) 4 deg C, 5 d, CH2Cl2; 2.) 4 deg C, 1 d;	87%

: 4530-20-5
BOC-glycine

: 112-70-9
tridecan-1-ol

: 1380680-72-7
tridecyl 2-((tert-butoxycarbonyl)amino)acetate

Conditions

Conditions	Yield
With dmap; 2-chloro-1-methyl-pyridinium iodide In dichloromethane at 0℃; for 0.5h;	86%

: 104-53-0
3-phenyl-propionaldehyde

: 112-70-9
tridecan-1-ol

: tridecyl 3-phenylpropanoate

Conditions

Conditions	Yield
With iodine; potassium carbonate In tert-butyl alcohol at 20℃; for 24h;	84%

: 112-70-9
tridecan-1-ol

: 421-85-2
Trifluoromethanesulfonamide

: N,N-bis(tridecyl)trifluoromethanesulfonamide

Conditions

Conditions	Yield
With di-isopropyl azodicarboxylate; triphenylphosphine In diethyl ether at 20℃; Mitsunobu reaction;	84%

: 112-70-9
tridecan-1-ol

: 302-72-7
rac-Ala-OH

: 1614221-39-4
tridecyl 2-aminopropanoate

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In toluene Reflux;	83.15%

: 112-70-9
tridecan-1-ol

: 102148-31-2
3β-chlorocarbonylmercaptocholest-5-ene

: Thiocarbonic acid S-[(3S,8S,9S,10R,13R,14S,17R)-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl] ester O-tridecyl ester

Conditions

Conditions	Yield
With pyridine In diethyl ether; benzene for 4h; Heating;	80%

: 112-70-9
tridecan-1-ol

: 3303-84-2
3-(tert-butyloxycarbonylamino)propionic acid

: 1380680-76-1
tridecyl 3-((tert-butoxycarbonyl)amino)propanoate

Conditions

Conditions	Yield
With dmap; 2-chloro-1-methyl-pyridinium iodide In dichloromethane at 0℃; for 0.5h;	79%

: 64-17-5
ethanol

: 112-70-9
tridecan-1-ol

: 75-05-8
acetonitrile

A: 66577-48-8
diethyl-tridecyl-amine

B: 121-44-8
triethylamine

Conditions

Conditions	Yield
With hydrogen; copper at 240℃; under 7600 Torr;	A 78% B n/a

...Expand

: 112-70-9
tridecan-1-ol

: 149-91-7
3,4,5-trihydroxybenzoic acid

: tridecyl 3,4,5-trihydroxybenzoate

Conditions

Conditions	Yield
With dicyclohexyl-carbodiimide In tetrahydrofuran for 20h;	77%
With dicyclohexyl-carbodiimide In tetrahydrofuran for 20h;	77%

1-Tridecanol Chemical Properties

IUPAC Name: Tridecan-1-ol
Synonyms : N-Tridecanol ; N-Tridecyl alcohol ; Rarechem al bd 0158 ; Tridecanol ; Tridecyl alcohol ; 1-Hydroxytridecane ; C₁₃ linear primary alcohol ; N-Tridecan-1-ol
Product Categories: 1-Alkanols;Biochemistry;Higher Fatty Acids & Higher Alcohols;Monofunctional & alpha,omega-Bifunctional Alkanes;Monofunctional Alkanes;Saturated Higher Alcohols
CAS NO: 112-70-9
Molecular Formula: C₁₃H₂₈O
Molecular Weight: 200.36
Molecular Structure:
EINECS: 203-998-8
BRN : 1739991
Mol File: 112-70-9.mol
Index of Refraction: 1.443
Surface Tension: 30.6 dyne/cm
Density: 0.832 g/cm³
Flash Point: 121.1 °C
Enthalpy of Vaporization: 59.25 kJ/mol
Boiling Point: 272.1 °C at 760 mmHg
Vapour Pressure: 0.000807 mmHg at 25°C
Melting point: 29-34 °C(lit.)
Appearance: 1-Tridecanol (CAS NO.112-70-9) is white low melting solid.
Solubility: 1-Tridecanol (CAS NO.112-70-9) is soluble in alcohol and ether, insoluble in water.

1-Tridecanol Uses

1-Tridecanol (CAS NO.112-70-9) is used raw materials in production of lubricants, surfactants, pesticides, and ink solvents.

1-Tridecanol Toxicity Data With Reference

1.	skn-rbt 410 mg open MLD	UCDS** Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 10/14 ,1964.
2.	orl-rat LD50:17,200 mg/kg	NPIRI* Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. 1 (1974),114.
3.	skn-rbt LD50:5600 mg/kg	NPIRI* Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. 1 (1974),114.

1-Tridecanol Consensus Reports

Reported in EPA TSCA Inventory.

1-Tridecanol Safety Profile

Hazard Codes Irritant Xi
Risk Statements 36/37/38
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements 26-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
WGK Germany 3
RTECS YD4200000

1-Tridecanol Specification

1.General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
2.Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage: Store 1-Tridecanol (CAS NO.112-70-9) in a cool, dry place. Keep container closed when not in use.

Product Name

1-Tridecanol

Synthetic route

1-Tridecanol Chemical Properties

1-Tridecanol Uses

1-Tridecanol Toxicity Data With Reference

1-Tridecanol Consensus Reports

1-Tridecanol Safety Profile

1-Tridecanol Specification

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