2-(Phenylthio)aniline supplier

Name
2-(Phenylthio)aniline
EINECS 413-030-8
CAS No. 1134-94-7
Article Data66
CAS DataBase
Density 1.19 g/cm³
Solubility
Melting Point 43 °C(lit.)
Formula C₁₂H₁₁NS
Boiling Point 330.5 °C at 760 mmHg
Molecular Weight 201.292
Flash Point 153.7 °C
Transport Information UN 3077 9/PG 3
Appearance Kind of white to yellow powder
Safety 24-37-61
Risk Codes 43-51/53
Molecular Structure
Hazard Symbols Xi；N
Synonyms Aniline,o-(phenylthio)- (6CI,7CI,8CI);2-(Phenylsulfanyl)phenylamine;2-(Phenylthio)benzenamine;2-Aminodiphenyl sulfide;2-Aminophenyl phenyl sulfide;2-Aminophenyl phenyl thioether;2-Phenylsulfanylaniline;o-(Phenylthio)aniline;
PSA 51.32000
LogP 4.00120

Synthetic route

: 591-50-4
iodobenzene

: 137-07-5
2-amino-benzenethiol

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
With iron; copper; potassium carbonate In N,N-dimethyl-formamide at 120℃; for 3h;	99%
With copper(l) iodide; (S,S)-1,2-diaminocyclohexane In water at 120℃;	98%
With 2,2'-biimidazole; copper(II) acetate monohydrate; caesium carbonate In dimethyl sulfoxide at 80℃; for 3h; Ullmann Condensation; Schlenk technique; Inert atmosphere; chemoselective reaction;	95%

: 95-16-9
1,3-Benzothiazole

: 591-50-4
iodobenzene

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
With tetra(n-butyl)ammonium hydroxide; water; copper(l) chloride at 50℃; for 12h; Inert atmosphere;	99%
With copper; caesium carbonate at 140℃; for 6h; Reagent/catalyst; Time; Solvent; Inert atmosphere;	96%
With iron(III) chloride; trans-1,2-Diaminocyclohexane; sodium hydroxide In water at 110℃; for 24h; Reagent/catalyst; Solvent; Green chemistry;	60%
With iron(III) chloride; (S,S)-1,2-diaminocyclohexane; sodium hydroxide In water at 110℃; for 24h; Reagent/catalyst; Solvent;	60%

: 4171-83-9
2-nitrophenyl phenyl sulfide

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
With hydrogen In methanol under 4137.29 Torr;	98%
With ethanol; calcium chloride; zinc for 2h; Reflux;	94%
With iron; ammonium chloride In ethanol; water for 1h; Reflux;	86%

: 615-43-0
2-iodophenylamine

: 108-98-5
thiophenol

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
With (1R,2R)-1,2-diaminocyclohexane; copper(l) chloride In water at 120℃; Schlenk technique; Sealed tube; Inert atmosphere;	97%
With copper(l) iodide; (S,S)-1,2-diaminocyclohexane In water at 120℃;	95%
With copper(l) iodide; potassium carbonate In 1-methyl-pyrrolidin-2-one at 100℃; for 16h;	92%

: 108-86-1
bromobenzene

: 137-07-5
2-amino-benzenethiol

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
With copper(l) iodide; N,N'-dihexyloxalamide; potassium tert-butylate In 1,4-dioxane at 110℃; for 24h; Sealed tube; Inert atmosphere;	91%

: 1141-88-4
2-Aminophenyl disulfide

: 98-80-6
phenylboronic acid

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
With sodium tetrahydroborate; 1,10-Phenanthroline; copper(ll) sulfate pentahydrate In ethanol at 20℃; for 8h;	82%

: 591-50-4
iodobenzene

: C12H12N2S2

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
With copper; potassium hydroxide at 110℃; for 12h; Green chemistry;	80%

: 14933-91-6
N-phenyl-benzenesulphenamide

A: 1135-14-4
4-aminophenyl phenyl sulfide

B: 1134-94-7
2-phenylsulfanyl-aniline

C: 110228-58-5
2'-(phenylthio)-benzenesulphenanilide

D: 882-33-7
diphenyldisulfane

Conditions

Conditions	Yield
In various solvent(s) at 85℃; for 720h; Further byproducts given;	A 5% B 3% C 4% D 78%

...Expand

: 108-86-1
bromobenzene

: 1141-88-4
2-Aminophenyl disulfide

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
With potassium tert-butylate In dimethyl sulfoxide at 40 - 80℃;	76%

: 591-50-4
iodobenzene

: 119072-55-8, 7188-38-7
tert-butylisonitrile

: 137-07-5
2-amino-benzenethiol

A: 883-93-2
2-Phenylbenzothiazole

B: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
With 1,1'-bis-(diphenylphosphino)ferrocene; copper(l) iodide; palladium diacetate; caesium carbonate In N,N-dimethyl-formamide at 120℃; for 24h; Inert atmosphere;	A 61% B 10%

...Expand

: 108-98-5
thiophenol

: 95-51-2
2-Chloroaniline

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
With C24H22N6Ni; sodium t-butanolate In N,N-dimethyl-formamide; acetonitrile at 80℃; Temperature; Inert atmosphere; Schlenk technique;	57%

: 2996-92-1
phenyl trimethylsiloxane

: 1141-88-4
2-Aminophenyl disulfide

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
With copper(l) iodide; tetrabutyl ammonium fluoride; johnphos at 100℃; for 24h;	49%

: 100-68-5
methyl-phenyl-thioether

: 622-37-7
Phenyl azide

A: 1135-14-4
4-aminophenyl phenyl sulfide

B: 1134-94-7
2-phenylsulfanyl-aniline

C: 105903-47-7
2-anilinothioanisole

D: 116924-82-4
4-(methylsulfanyl)diphenylamine

Conditions

Conditions	Yield
With trifluorormethanesulfonic acid; trifluoroacetic acid Ambient temperature;	A 33% B 25% C 2% D 10%

...Expand

: 1489-23-2
N-(2-(phenylthio)phenyl)acetamide

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
With hydrogenchloride
hydrolysis;

: 108-98-5
thiophenol

: 88-73-3
2-Chloronitrobenzene

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
(i) NaOH, EtOH, (ii) H2, Raney-Ni; Multistep reaction;
Stage #1: thiophenol; 2-Chloronitrobenzene With sodium hydroxide Stage #2: With hydrogenchloride; iron In methanol

: 14933-91-6
N-phenyl-benzenesulphenamide

A: 1135-14-4
4-aminophenyl phenyl sulfide

B: 1134-94-7
2-phenylsulfanyl-aniline

C: 134427-69-3, 3467-73-0
cyclohex-2-enyl phenyl sulfide

D: 108-98-5
thiophenol

E: 62-53-3
aniline

F: 882-33-7
diphenyldisulfane

Conditions

Conditions	Yield
In cyclohexene under 1 Torr; Product distribution; Mechanism; Irradiation; effect of solvent and lighting on the decomposition;

...Expand

: 49829-70-1
α-(phenylthio)benzalphenylhydrazone

A: 1134-94-7
2-phenylsulfanyl-aniline

B: 100-47-0
benzonitrile

Conditions

Conditions	Yield
With PPA at 110℃; for 6h;

: 110228-58-5
2'-(phenylthio)-benzenesulphenanilide

A: 1134-94-7
2-phenylsulfanyl-aniline

B: 882-33-7
diphenyldisulfane

Conditions

Conditions	Yield
With hydrogenchloride

: 108-98-5
thiophenol

benzoic acid-diazonium chloride-(2): benzoic acid-diazonium chloride-(2)

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 79 percent / aq. NaOH / ethanol / Heating 2: 50 percent / H2 / 5percent Pd/C / ethanol / 3 h / 2585.7 Torr View Scheme

: 88-73-3
2-Chloronitrobenzene

copper (I)-butane-1-thiolate: copper (I)-butane-1-thiolate

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 79 percent / aq. NaOH / ethanol / Heating 2: 50 percent / H2 / 5percent Pd/C / ethanol / 3 h / 2585.7 Torr View Scheme

: 14933-91-6
N-phenyl-benzenesulphenamide

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 4 percent / various solvent(s) / 720 h / 85 °C 2: 6 M hydrochloric acid View Scheme

: 108-98-5
thiophenol

α-phenyl-α.γ-butadiene: α-phenyl-α.γ-butadiene

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: triethylamine / ethanol / 6 h / Heating 2: polyphosphoric acid / 6 h / 110 °C View Scheme

: 15424-14-3
N-phenylbenzohydrazonoyl chloride

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: triethylamine / ethanol / 6 h / Heating 2: polyphosphoric acid / 6 h / 110 °C View Scheme

: 577-19-5
2-nitrophenyl bromide

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: copper powder 2: alcohol; tin dichloride; hydrochloric acid View Scheme

: 930-69-8
sodium thiophenolate

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: copper powder 2: alcohol; tin dichloride; hydrochloric acid View Scheme

: 108-98-5
thiophenol

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: copper; concentrated KOH-solution / 20 °C / zuletzt bei 170-185grad 2: iron; water; iron chloride View Scheme
Multi-step reaction with 2 steps 1: sodium hydroxide / dimethyl sulfoxide / 80 °C 2: hydrogen / methanol / 4137.29 Torr View Scheme
Multi-step reaction with 2 steps 1.1: potassium hydroxide / dimethyl sulfoxide / Inert atmosphere; Schlenk technique 1.2: 90 °C / Inert atmosphere; Schlenk technique 2.1: zinc / ethanol; acetic acid / Inert atmosphere; Schlenk technique View Scheme

: 88-73-3
2-Chloronitrobenzene

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: copper; concentrated KOH-solution / 20 °C / zuletzt bei 170-185grad 2: iron; water; iron chloride View Scheme
Multi-step reaction with 2 steps 1: sodium hydroxide / dimethyl sulfoxide / 80 °C 2: hydrogen / methanol / 4137.29 Torr View Scheme
Multi-step reaction with 2 steps 1.1: potassium hydroxide / dimethyl sulfoxide / Inert atmosphere; Schlenk technique 1.2: 90 °C / Inert atmosphere; Schlenk technique 2.1: zinc / ethanol; acetic acid / Inert atmosphere; Schlenk technique View Scheme
Multi-step reaction with 2 steps 1: sodium hydroxide / methanol 2: iron; ammonium chloride / water View Scheme

: 533-17-5
N-(2-chlorophenyl)acetamide

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: copper / 300 °C 2: aq.-ethanolic hydrochloric acid View Scheme

: 3111-52-2
potassium thiophenolate

: 1134-94-7
2-phenylsulfanyl-aniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: copper / 300 °C 2: aq.-ethanolic hydrochloric acid View Scheme

: 1134-94-7
2-phenylsulfanyl-aniline

: 1885-14-9
phenyl chloroformate

: 111974-73-3
phenyl [2-(phenylsulphanyl)phenyl]carbamate

Conditions

Conditions	Yield
Stage #1: 2-phenylsulfanyl-aniline; phenyl chloroformate In toluene at 4℃; for 0.0833333h; Stage #2: phenyl chloroformate With sodium carbonate; sodium hydroxide In water; toluene at 4℃; for 1.5h;	99.8%
With sodium carbonate; sodium hydroxide In water; toluene at 5 - 20℃; for 3h; Product distribution / selectivity;	92%
With sodium carbonate	90%

: 1134-94-7
2-phenylsulfanyl-aniline

: (2-azidophenyl)(phenyl)sulfide

Conditions

Conditions	Yield
Stage #1: 2-phenylsulfanyl-aniline With isopentyl nitrite In tetrahydrofuran at 0℃; Stage #2: With trimethylsilylazide In tetrahydrofuran at 0 - 20℃; under air;	99%
With trimethylsilylazide; isopentyl nitrite In tetrahydrofuran at 0 - 20℃;	90%
With sulfuric acid; sodium nitrite anschliessendes Behandeln mit Natriumazid;

: 1134-94-7
2-phenylsulfanyl-aniline

: C12H10NS(1-)*Li(1+)

Conditions

Conditions	Yield
With n-butyllithium In hexane at 20℃; for 1h; Inert atmosphere; Schlenk technique; Reflux;	99%

: 1121-60-4
pyridine-2-carbaldehyde

: 1134-94-7
2-phenylsulfanyl-aniline

: 2-(phenylthio)phenyl-1-(2-pyridyl)methylimine

Conditions

Conditions	Yield
In methanol for 24h; Reflux;	99%

: 1134-94-7
2-phenylsulfanyl-aniline

: 16714-31-1
phenyl-2-amine-phenylsulfoxide

Conditions

Conditions	Yield
With dihydrogen peroxide; Amberlyst 15 In methanol at 20℃; for 5h;	98%
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0℃; Inert atmosphere; Schlenk technique;	95%
With phosphoric acid; oxygen; uranyl(VI) acetate dihydrate In water; acetonitrile at 20℃; under 760.051 Torr; for 12h; Schlenk technique; Irradiation;	68%
With dihydrogen peroxide In methanol; water at 60℃; for 3h;
With C16H21MoNO9; urea hydrogen peroxide adduct In ethanol at 20℃; for 0.25h; Catalytic behavior; Reagent/catalyst;	98 %Chromat.

: 1134-94-7
2-phenylsulfanyl-aniline

: 4273-98-7
2-aminophenyl phenyl sulfone

Conditions

Conditions	Yield
With urea hydrogen peroxide adduct In ethanol at 20℃; for 0.25h;	98%

: 1134-94-7
2-phenylsulfanyl-aniline

: 1147550-11-5
ammonium thiocyanate

: 98-88-4
benzoyl chloride

: 76838-39-6
1-Benzoyl-3-(2-phenylsulfanyl-phenyl)-thiourea

Conditions

Conditions	Yield
In acetone for 1h; Heating;	97.1%

...Expand

: 1134-94-7
2-phenylsulfanyl-aniline

: 75-36-5
acetyl chloride

: 1489-23-2
N-(2-(phenylthio)phenyl)acetamide

Conditions

Conditions	Yield
With triethylamine In dichloromethane at -10 - 20℃; for 5.5h; Inert atmosphere;	95.6%
With acetic acid
Stage #1: 2-phenylsulfanyl-aniline With triethylamine In dichloromethane for 0.166667h; Cooling with ice; Stage #2: acetyl chloride In dichloromethane for 2.25h;

: 108-30-5
succinic acid anhydride

: 1134-94-7
2-phenylsulfanyl-aniline

: 1103975-97-8
C16H13NO2S

Conditions

Conditions	Yield
With acetic acid for 48h; Reflux;	95%

: 1003-29-8
2-pyrrole aldehyde

: 1134-94-7
2-phenylsulfanyl-aniline

: C17H14N2S

Conditions

Conditions	Yield
With formic acid In methanol for 24h;	95%
In ethanol at 65℃; for 72h;	30%
In methanol Reflux;

: 1134-94-7
2-phenylsulfanyl-aniline

: 99-61-6
3-nitro-benzaldehyde

: 762-04-9
phosphonic acid diethyl ester

: 1449063-88-0
diethyl α-(3-nitrophenyl)-α-[2-(phenylthio)phenylamino]methylphosphonate

Conditions

Conditions	Yield
With Nano-silica-supported boron trifluoride In neat (no solvent) for 0.1h; Reagent/catalyst; Kabachnik-Fields Reaction; Microwave irradiation;	93%

...Expand

: 1134-94-7
2-phenylsulfanyl-aniline

: 874-42-0
2,4-dichlorobenzaldeyhde

: 762-04-9
phosphonic acid diethyl ester

: 1449063-89-1
diethyl α-(2,4-dichlorophenyl)-α-[2-(phenylthio)phenylamino]methylphosphonate

Conditions

Conditions	Yield
With Nano-silica-supported boron trifluoride In neat (no solvent) for 0.116667h; Kabachnik-Fields Reaction; Microwave irradiation;	93%

...Expand

: 1134-94-7
2-phenylsulfanyl-aniline

: 762-04-9
phosphonic acid diethyl ester

: 16588-34-4
4-chloro-3-nitro-benzaldehyde

: 1449063-90-4
diethyl α-(4-chloro-3-nitrophenyl)-α-[2-(phenylthio)phenylamino]methylphosphonate

Conditions

Conditions	Yield
With Nano-silica-supported boron trifluoride In neat (no solvent) for 0.1h; Kabachnik-Fields Reaction; Microwave irradiation;	93%

...Expand

: 447-61-0
2-Trifluoromethylbenzaldehyde

: 1134-94-7
2-phenylsulfanyl-aniline

: C20H14F3NS

Conditions

Conditions	Yield
In ethanol at 20℃; for 1h; Inert atmosphere; Schlenk technique;	92%

: 1134-94-7
2-phenylsulfanyl-aniline

: 82-86-0
acenaphthene quinone

: C36H24N2S2

Conditions

Conditions	Yield
With acetic acid; zinc(II) chloride at 60 - 120℃; for 0.5h;	92%

: 1134-94-7
2-phenylsulfanyl-aniline

: 79-04-9
chloroacetyl chloride

: 22504-08-1
2-(N-(chloroacetyl)amine)-1-phenylthio-benzene

Conditions

Conditions	Yield
In toluene for 0.166667h; Microwave irradiation;	91%

: 1134-94-7
2-phenylsulfanyl-aniline

: 100-83-4
meta-hydroxybenzaldehyde

: 762-04-9
phosphonic acid diethyl ester

: 1449063-87-9
diethyl α-(3-hydroxyphenyl)-α-[2-(phenylthio)phenylamino]methyl phosphonate

Conditions

Conditions	Yield
With Nano-silica-supported boron trifluoride In neat (no solvent) for 0.133333h; Kabachnik-Fields Reaction; Microwave irradiation;	91%

...Expand

: 616-02-4
citraconic acid anhydride

: 1134-94-7
2-phenylsulfanyl-aniline

: 1103976-19-7
C17H13NO2S

Conditions

Conditions	Yield
With acetic acid for 48h; Reflux;	90%

: 1134-94-7
2-phenylsulfanyl-aniline

: 120-14-9
3,4-dimethoxy-benzaldehyde

: 762-04-9
phosphonic acid diethyl ester

: 1449063-92-6
diethyl α-(3,4-dimethoxyphenyl)-α-[2-(phenylthio)phenylamino]methylphosphonate

Conditions

Conditions	Yield
With Nano-silica-supported boron trifluoride In neat (no solvent) for 0.15h; Kabachnik-Fields Reaction; Microwave irradiation;	90%

...Expand

: 98-03-3
thiophene-2-carbaldehyde

: 1134-94-7
2-phenylsulfanyl-aniline

: 762-04-9
phosphonic acid diethyl ester

: 1449063-94-8
diethyl α-[2-(phenylthio)phenylamino]-α-(2-thienyl)methylphosphonate

Conditions

Conditions	Yield
With Nano-silica-supported boron trifluoride In neat (no solvent) for 0.116667h; Kabachnik-Fields Reaction; Microwave irradiation;	90%

...Expand

: 1134-94-7
2-phenylsulfanyl-aniline

: 121-33-5
vanillin

: 762-04-9
phosphonic acid diethyl ester

: 1449063-91-5
diethyl α-(4-hydroxy-3-methoxyphenyl)-α-[2-(phenylthio)phenylamino]methylphosphonate

Conditions

Conditions	Yield
With Nano-silica-supported boron trifluoride In neat (no solvent) for 0.133333h; Kabachnik-Fields Reaction; Microwave irradiation;	90%

...Expand

: 1134-94-7
2-phenylsulfanyl-aniline

: 635-93-8
5-chlorosalicyclaldehyde

: 4-chloro-2-((2-(phenylthio)phenylimino)methyl)phenol

Conditions

Conditions	Yield
In ethanol at 20℃; for 8h; Reflux;	90%

: 1134-94-7
2-phenylsulfanyl-aniline

: 446-52-6
2-Fluorobenzaldehyde

: 1382241-56-6
C19H14FNS

Conditions

Conditions	Yield
With magnesium sulfate In hexane at 20℃; for 12h; Inert atmosphere;	89%

: 1134-94-7
2-phenylsulfanyl-aniline

: 762-04-9
phosphonic acid diethyl ester

: 134-96-3
syringic aldehyde

: 1449063-93-7
diethyl α-(3,5-dimethoxy-4-hydroxyphenyl)-α-[2-(phenylthio)phenylamino]methylphosphonate

Conditions

Conditions	Yield
With Nano-silica-supported boron trifluoride In neat (no solvent) for 0.15h; Kabachnik-Fields Reaction; Microwave irradiation;	89%

...Expand

: 1134-94-7
2-phenylsulfanyl-aniline

: 104-88-1
4-chlorobenzaldehyde

: 762-04-9
phosphonic acid diethyl ester

: 1449063-85-7
diethyl α-(4-chlorophenyl)-α-[2-(phenylthio)phenylamino]methylphosphonate

Conditions

Conditions	Yield
With Nano-silica-supported boron trifluoride In neat (no solvent) for 0.15h; Kabachnik-Fields Reaction; Microwave irradiation;	89%

...Expand

2-(Phenylthio)aniline Specification

The Benzenamine,2-(phenylthio)-, with the CAS registry number 1134-94-7 and EINECS registry number 413-030-8, has the systematic name of 2-(phenylsulfanyl)aniline. It belongs to the following product category of Amines. And the molecular formula of the chemical is C₁₂H₁₁NS.

The characteristics of Benzenamine,2-(phenylthio)- are as followings: (1)ACD/LogP: 2.95; (2)# of Rule of 5 Violations: 0 ; (3)#H bond acceptors: 1; (4)#H bond donors: 2; (5)#Freely Rotating Bonds: 3; (6)Polar Surface Area: 28.54 Å²; (7)Index of Refraction: 1.675; (8)Molar Refractivity: 63.09 cm³; (9)Molar Volume: 167.9 cm³; (10)Polarizability: 25.01×10^-24cm³; (11)Surface Tension: 55.2 dyne/cm; (12)Density: 1.19 g/cm³; (13)Flash Point: 153.7 °C; (14)Enthalpy of Vaporization: 57.3 kJ/mol; (15)Boiling Point: 330.5 °C at 760 mmHg; (16)Vapour Pressure: 0.000166 mmHg at 25°C.

Preparation of Benzenamine,2-(phenylthio)-: This chemical can be prepared by 1-nitro-2-phenylsulfanyl-benzene. The reaction will need reagent H₂, catalyst 5% Pd/C, and the menstruum ethanol. The reaction time is 3 hours with Pressure 2585.7Pa, and the yield is about 50%.

Uses of Benzenamine,2-(phenylthio)-: It can react with 4-chloro-benzaldehyde to produce (4-chloro-benzylidene)-(2-phenylsulfanyl-phenyl)-amine. This reaction will need reagent p-TsOH, and the menstruum benzene. The reaction time is 5 hours with heating, and the yield is about 52%.

You should be cautious while dealing with this chemical. It may cause sensitization by skin contact, and it is also toxic to aquatic organisms, and may cause long-term adverse effects in the aquatic environment. Therefore, you had better take the following instructions: Wear suitable gloves, and avoid contacting with skin and release to the environment(Refer to special instructions safety data sheet).

Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: S(c1ccccc1)c2ccccc2N
(2)InChI: InChI=1/C12H11NS/c13-11-8-4-5-9-12(11)14-10-6-2-1-3-7-10/h1-9H,13H2
(3)InChIKey: DGBISJKLNVVJGD-UHFFFAOYAA

Product Name

2-(Phenylthio)aniline

Synthetic route

2-(Phenylthio)aniline Specification

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