2,4,6-TRIBROMOPHENOL supplier

Name
2,4,6-Tribromophenol
EINECS 204-278-6
CAS No. 118-79-6
Article Data226
CAS DataBase
Density 2.55 g/cm³
Solubility 71 mg/L (15 °C) in water
Melting Point 90-94 °C(lit.)
Formula C₆H₃Br₃O
Boiling Point 286.8 °C at 760 mmHg
Molecular Weight 330.801
Flash Point 109.7 °C
Transport Information
Appearance Soft, long, white crystals with a bromine odor.
Safety 26-36-61-37/39-45-36/37-16-7-24/25-23-53
Risk Codes 36/37/38-51/53-20/22-39/23/24/25-23/24/25-11-63-43-45
Molecular Structure
Hazard Symbols Xn,N
Synonyms 1,3,5-Tribromo-2-hydroxybenzene;Bromkal Pur 3;Bromol;Flammex 3BP;NSC 2136;PH 73;
PSA 20.23000
LogP 3.67970

Synthetic route

: 108-95-2
phenol

: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With sulfuric acid; dihydrogen peroxide; acetic acid; sodium bromide at 20 - 45℃; Temperature; Reagent/catalyst;	99%
With tetrabutylammomium bromide; dihydrogen peroxide; vanadia In water; acetonitrile at 5℃; for 1h; Bromination;	98%
With tetra-N-butylammonium tribromide In water; acetonitrile at 5℃;	98%

: 106-41-2
4-bromo-phenol

: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With benzyltrimethylammonium tribromide; calcium carbonate In methanol; dichloromethane	99%
With dibromamine-T In acetonitrile at 20℃; for 0.166667h;	85%
Multi-step reaction with 2 steps 1: bromine / acetic acid; ethanol / 1 h / 0 °C 2: 3-oxo-1,3-dihydroisobenzofuran-1-carbonitrile; lithium tert-butoxide / tetrahydrofuran / 6.5 h / -78 - 25 °C / Inert atmosphere View Scheme

: 56579-86-3
2-(3,4-methylenedioxyphenyl)-1,3-dithiane

: 20244-61-5
2,4,4,6-Tetrabromo-2,5-cyclohexadien-1-one

A: 120-57-0
piperonal

B: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With dihydrogen peroxide In water; acetonitrile at 20℃; for 0.25h;	A 98% B 80%

...Expand

: 183547-02-6
4-Methanesulfonyloxy-benzenesulfonic acid 2,4,6-tribromo-phenyl ester

: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With sodium hydride In N,N,N,N,N,N-hexamethylphosphoric triamide for 2.16667h; Ambient temperature;	97%

: 95-56-7
2-hydroxybromobenzene

: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With benzyltrimethylammonium tribromide; calcium carbonate In methanol; dichloromethane	96%

: 607-99-8
2,4,6-tribromoanisole

: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With water; hydrogen bromide; Aliquat 336 at 105℃; for 5h; Catalytic behavior;	95%

: 3-(2,4,6-tribromo-phenoxymethyl)-benzoic acid methyl ester

: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With magnesium In tetrahydrofuran; methanol at 20℃; for 5h;	91%

: 98-80-6
phenylboronic acid

: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With bromine In dichloromethane at 20℃; regioselective reaction;	90%
Multi-step reaction with 2 steps 1: dihydrogen peroxide; water / ethanol / 0.02 h / 20 °C / Green chemistry 2: dihydrogen peroxide; hydrogen bromide; water / ethanol / 0.02 h / 20 °C / Green chemistry View Scheme

: 183547-04-8
4-Methanesulfonyl-benzenesulfonic acid 2,4,6-tribromo-phenyl ester

: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With sodium hydride In N,N,N,N,N,N-hexamethylphosphoric triamide for 2.16667h; Ambient temperature;	89%

: 118352-65-1
C6H5Br3O

: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With oxygen; copper diacetate; trifluoroacetic acid; lithium bromide In acetonitrile at 80℃; under 760.051 Torr; for 10h; Sealed tube;	89%

: 103-19-5
di(p-tolyl) disulfide

: 106-45-6
para-thiocresol

: 183547-02-6
4-Methanesulfonyloxy-benzenesulfonic acid 2,4,6-tribromo-phenyl ester

A: 17241-10-0
tris(p-tolylthio)methane

B: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With sodium hydride In N,N,N,N,N,N-hexamethylphosphoric triamide for 2.16667h; Ambient temperature;	A 22% B 87%

...Expand

: 608-33-3
2,6-dibromophenol

: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane; hydrogen bromide In water at 20℃; for 1.6h;	86%
With trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane; ammonium bromide; acetic acid at 20℃; for 2h; regioselective reaction;	85%

: 5467-74-3
4-Bromophenylboronic acid

: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With water; hydrogen bromide; dihydrogen peroxide In ethanol at 20℃; for 0.0166667h; Green chemistry;	84%

: 108-95-2
phenol

A: 106-41-2
4-bromo-phenol

B: 95-56-7
2-hydroxybromobenzene

C: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With pyridine; bromine; silver nitrate In acetonitrile for 2h; Ambient temperature;	A 3% B 82% C 3%
With N-Bromosuccinimide In acetonitrile at 20℃; for 0.166667h;	A 12 %Chromat. B 7 %Chromat. C 55 %Chromat.

...Expand

: 84998-84-5
(2,4,6-tribromo-phenoxy)-acetic acid

: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
Stage #1: (2,4,6-tribromo-phenoxy)-acetic acid With triethylamine In N,N-dimethyl-formamide; toluene for 3h; Curtius rearrangement; Heating; Stage #2: With potassium hydroxide In N,N-dimethyl-formamide; toluene at 25℃; for 0.133333h; Stage #3: With potassium hydroxide; glycerol In ethanol; N,N-dimethyl-formamide; toluene for 2h; Heating; Further stages.;	82%

: 95-56-7
2-hydroxybromobenzene

A: 608-33-3
2,6-dibromophenol

B: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With N-Bromosuccinimide; diisopropylamine In dichloromethane for 1h; Ambient temperature;	A 80% B 5.7 % Chromat.

: 2446-83-5
di-isopropyl azodicarboxylate

: 608-33-3
2,6-dibromophenol

A: 19740-72-8
bis(1-methylethyl) 1,2-hydrazinedicarboxylate

B: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With ZrBr4 In dichloromethane at 20℃; for 2h;	A n/a B 79%

...Expand

: 103-19-5
di(p-tolyl) disulfide

: 106-45-6
para-thiocresol

: 183547-04-8
4-Methanesulfonyl-benzenesulfonic acid 2,4,6-tribromo-phenyl ester

A: 17241-10-0
tris(p-tolylthio)methane

B: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With sodium hydride In N,N,N,N,N,N-hexamethylphosphoric triamide for 2.16667h; Ambient temperature;	A 4% B 78%

...Expand

: 105-87-3
3,7-dimethyl-2E,6-octadien-1-yl acetate

A: 75107-37-8
6-bromo-3,7-dimethylocta-2,7-dienyl acetate

B: 75107-39-0
(E)-6,7-dibromo-3,7-dimethyloct-2-en-1-yl acetate

C: 75107-38-9
8-bromo-3,7-dimethylocta-2,7-dienyl acetate

D: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With 2,4,4,6-Tetrabromo-2,5-cyclohexadien-1-one In dichloromethane for 15h; Ambient temperature; Title compound not separated from byproducts;	A n/a B 14% C n/a D 76%

...Expand

: 20244-61-5
2,4,4,6-Tetrabromo-2,5-cyclohexadien-1-one

A: 75107-37-8
6-bromo-3,7-dimethylocta-2,7-dienyl acetate

B: 75107-39-0
(E)-6,7-dibromo-3,7-dimethyloct-2-en-1-yl acetate

C: 75107-38-9
8-bromo-3,7-dimethylocta-2,7-dienyl acetate

D: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With methyl geranate In dichloromethane for 15h; Ambient temperature;	A n/a B 14% C n/a D 76%

...Expand

: 615-58-7
2,4-dibromophenol

: 2446-83-5
di-isopropyl azodicarboxylate

A: 19740-72-8
bis(1-methylethyl) 1,2-hydrazinedicarboxylate

B: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With ZrBr4 In dichloromethane at 20℃; for 4h;	A n/a B 75%

...Expand

: 20244-61-5
2,4,4,6-Tetrabromo-2,5-cyclohexadien-1-one

: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With betaine In ethanol at 60℃; for 72h;	71.4%
With 3-oxo-1,3-dihydroisobenzofuran-1-carbonitrile; lithium tert-butoxide In tetrahydrofuran at -78 - 25℃; for 6.5h; Inert atmosphere;	36%
With ammonium hydroxide; benzene

: 2,4,6-tribromophenyl acrylate

: 104-87-0
4-methyl-benzaldehyde

: 3-(hydroxy(p-tolyl)methyl)-5-p-tolyldihydrofuran-2(3H)-one

B: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With samarium; copper(l) iodide; potassium iodide In tetrahydrofuran at 20℃; Molecular sieve; diastereoselective reaction;	A 70% B n/a

...Expand

: 244205-40-1
(2-bromophenyl)boronic acid

: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With water; hydrogen bromide; dihydrogen peroxide In ethanol at 20℃; for 0.0166667h; Green chemistry;	55%

: 108-95-2
phenol

A: 106-41-2
4-bromo-phenol

B: 615-58-7
2,4-dibromophenol

C: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With hydrogenchloride; C20H17N5O4V(1+)*ClO4(1-); dihydrogen peroxide; potassium bromide In water; acetonitrile at 20℃; for 20h; pH=3;	A 5% B 51% C 2%
With [oxovanadium(V)(pyridine-2,6-dicarboxylate)(benzohydroxamate)]; dihydrogen peroxide; nitric acid; potassium bromide In water; acetonitrile pH=3; Reagent/catalyst; Overall yield = 72 %;	A 11% B 41% C 12%
With hydrogenchloride; dihydrogen peroxide; potassium bromide In water; acetonitrile at 20℃; for 20h; pH=Ca. 3;	A 13% B 27% C 41%

...Expand

: 108-95-2
phenol

A: 615-58-7
2,4-dibromophenol

B: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With bromine for 4h; Phase-vanishing reaction with phase screen; Neat (no solvent);	A 41% B 46%
With tetra-N-butylammonium tribromide In water; tert-butyl alcohol at 23℃; for 72h; pH=1;	A 13 %Spectr. B 86 %Spectr.

: 128702-12-5
5-bromo-2-geranyl-1,4-benzenediol

A: 98437-54-8
1,3,5-tribromo-2-methoxymethoxybenzene

: (2R,4aS,9aS)-2,6-Dibromo-7-methoxymethoxy-1,1,4a-trimethyl-1,2,3,4,4a,9,9a,10-octahydro-anthracene

C: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
	A 16% B 35% C 42%

...Expand

: 108-95-2
phenol

A: 106-41-2
4-bromo-phenol

B: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With dibromamine-T In acetonitrile at 20℃;	A 40% B 10%
With bromine In water; tert-butyl alcohol at 23℃; for 72h; pH=1;	A 8 %Spectr. B 88 %Spectr.

: 147-82-0
2,4,6-tribromoaniline

: 544-92-3
copper(I) cyanide

A: 626-39-1
1,3,5-trisbromobenzene

B: 634-89-9
1,2,3,5-tetrabromobenzene

C: 3463-40-9
2,4,6-tribromonitrobenzene

D: 35851-93-5
2,4,6-tribromobenzonitrile

E: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With tert.-butylnitrite In dimethyl sulfoxide at 60℃; for 1.5h; Product distribution; Mechanism; other anilines;	A 37% B 7% C 4% D 20% E 4%

...Expand

: 147-82-0
2,4,6-tribromoaniline

: 544-92-3
copper(I) cyanide

A: 626-39-1
1,3,5-trisbromobenzene

B: 3463-40-9
2,4,6-tribromonitrobenzene

C: 35851-93-5
2,4,6-tribromobenzonitrile

D: 118-79-6
2,4,6-tribromophenol

Conditions

Conditions	Yield
With tert.-butylnitrite In dimethyl sulfoxide at 60℃; for 1.5h; Further byproducts given;	A 37% B 4% C 20% D 4%

...Expand

: 118-79-6
2,4,6-tribromophenol

: triethylammonium 4-(diisopropylsilyl)benzoate

: 419573-14-1
4-diisopropylsilanyl-benzoic acid 2,4,6-tribromo-phenyl ester

Conditions

Conditions	Yield
With bis-(2-oxo-3-oxazolidinyl)phosphoryl chloride In pyridine at 20℃; for 0.5h;	100%

: 407-25-0
trifluoroacetic anhydride

: 118-79-6
2,4,6-tribromophenol

: 2,4,6-tribromophenyl trifluoroacetate

Conditions

Conditions	Yield
With tribenzylamine In benzene for 0.166667h;	99.8%

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

: 118-79-6
2,4,6-tribromophenol

: 108-95-2
phenol

: 25713-60-4
2,4,6-tris(2,4,6-tribromophenoxy)-1,3,5-triazine

Conditions

Conditions	Yield
With sodium hydroxide; hydrogen bromide; bromine; hydrazine In water; acetone	99%

...Expand

: 75-91-2
tert.-butylhydroperoxide

: 5395-43-7
tri(p-tolyl)antimony

: 118-79-6
2,4,6-tribromophenol

: 71-43-2
benzene

: μ2-oxobis[(2,4,6-tribromophenoxo)tris(para-tolyl)antimony] benzene monosolvate

Conditions

Conditions	Yield
Stage #1: tert.-butylhydroperoxide; tri(p-tolyl)antimony; 2,4,6-tribromophenol In diethyl ether at 20℃; for 24h; Stage #2: benzene In n-heptane	99%

...Expand

: 8-bromo-1-fluorooct-2-yne

: 118-79-6
2,4,6-tribromophenol

: 1,3,5-tribromo-2-((8-fluorooct-6-yn-1-yl)oxy)benzene

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide at 60℃; for 18h; Inert atmosphere;	99%

: 118-79-6
2,4,6-tribromophenol

: 107-07-3
2-chloro-ethanol

: bis-(2,4,6-tribromophenoxy)-bis-(2-chloroethoxy)silane

Conditions

Conditions	Yield
Stage #1: 2-chloro-ethanol With tetrachlorosilane In 1,4-dioxane at 0 - 50℃; for 2h; Inert atmosphere; Stage #2: 2,4,6-tribromophenol In 1,4-dioxane at 80℃; for 5h; Stage #3: 2-chloro-ethanol In 1,4-dioxane at 25 - 50℃; for 4.5h; Solvent; Temperature;	98.8%

: 616-23-9
2,3-Dichloro-1-propanol

: 118-79-6
2,4,6-tribromophenol

: bis(2,4,6-tribromophenoxy)bis(2,3-dichloro-1-propoxy)silane

Conditions

Conditions	Yield
Stage #1: 2,3-Dichloro-1-propanol With tetrachlorosilane In diethylene glycol dimethyl ether at 8 - 35℃; for 2h; Inert atmosphere; Stage #2: 2,4,6-tribromophenol In diethylene glycol dimethyl ether at 90℃; for 4h; Inert atmosphere; Stage #3: 2,3-Dichloro-1-propanol In diethylene glycol dimethyl ether at 50 - 95℃; for 5h; Temperature; Solvent; Inert atmosphere;	98.6%

: 1200-03-9
4-bromophenyl butyl ether

: 118-79-6
2,4,6-tribromophenol

: 959685-15-5
1,3,5-tribromo-2-phenoxybutoxybenzene

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide at 70℃; for 17h;	98.5%

: 112-89-0
1-Bromooctadecane

: 118-79-6
2,4,6-tribromophenol

: 959685-14-4
1,3,5-tribromo-2-octadecyloxybenzene

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide at 70℃; for 17h;	98.5%

: 7722-84-1
dihydrogen peroxide

: 603-36-1
triphenylantimony

: 118-79-6
2,4,6-tribromophenol

: μ-oxobis[(2,4,6-tribromophenoxy)triphenylantimony]

Conditions

Conditions	Yield
In diethyl ether; water aq. H2O2 was added to mixt. of SbPh3 and ligand in ether, allowed to stand for 12 h; solvent was evapd., washed with benzene, dried;	98%

...Expand

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

: 118-79-6
2,4,6-tribromophenol

: 25713-60-4
2,4,6-tris(2,4,6-tribromophenoxy)-1,3,5-triazine

Conditions

Conditions	Yield
With magnesium silicate; sodium hydroxide; sodium sulfite; trimethylamine In dichloromethane; water at 3 - 30℃; Product distribution / selectivity; Reflux;	98%
Stage #1: 2,4,6-tribromophenol With potassium carbonate In acetone for 1.5h; Heating / reflux; Stage #2: 1,3,5-trichloro-2,4,6-triazine In acetone at 25℃; for 3.25h; Heating / reflux;

: 14660-52-7
ethyl 5-bromovalerate

: 118-79-6
2,4,6-tribromophenol

: 1284287-06-4
ethyl 5-(2,4,6-tribromophenoxy)pentanoate

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide at 50℃; for 24h;	98%
With potassium carbonate In N,N-dimethyl-formamide at 50℃; for 12h; Inert atmosphere;	88%

: 96-23-1
1,3-Dichloro-2-propanol

: 118-79-6
2,4,6-tribromophenol

: bis(2,4,6-tribromophenoxy)bis(1,3-dichloro-2-propoxy)silane

Conditions

Conditions	Yield
Stage #1: 1,3-Dichloro-2-propanol With tetrachlorosilane In 1,1,2,2-tetrachloroethane at 8 - 35℃; for 2h; Inert atmosphere; Stage #2: 2,4,6-tribromophenol In 1,1,2,2-tetrachloroethane at 85℃; for 4.5h; Inert atmosphere; Stage #3: 1,3-Dichloro-2-propanol In 1,1,2,2-tetrachloroethane at 50 - 90℃; for 5.5h; Solvent; Temperature; Inert atmosphere;	98%

: 616-47-7
1-methyl-1H-imidazole

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

: 118-79-6
2,4,6-tribromophenol

: 25713-60-4
2,4,6-tris(2,4,6-tribromophenoxy)-1,3,5-triazine

Conditions

Conditions	Yield
Stage #1: 1-methyl-1H-imidazole; 2,4,6-tribromophenol In chlorobenzene at 40℃; for 2h; Stage #2: 1,3,5-trichloro-2,4,6-triazine In chlorobenzene at 20 - 25℃; for 4h; Temperature;	98%

...Expand

: 118-79-6
2,4,6-tribromophenol

: 540-51-2
2-bromoethanol

: bis-(2,4,6-tribromophenoxy)-bis-(2-bromoethoxy)silane

Conditions

Conditions	Yield
Stage #1: 2-bromoethanol With tetrachlorosilane In diethylene glycol dimethyl ether at 0 - 20℃; for 2h; Inert atmosphere; Stage #2: 2,4,6-tribromophenol In diethylene glycol dimethyl ether at 60℃; for 5h; Stage #3: 2-bromoethanol In diethylene glycol dimethyl ether at 25 - 45℃; for 5.5h; Solvent; Temperature;	97.3%

: 109-65-9
1-bromo-butane

: 118-79-6
2,4,6-tribromophenol

: 98625-07-1
1-butoxy-2,4,6-tribromobenzene

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide Heating;	97.1%

: 2809-18-9
methylbis(chloromethyl)phosphine oxide

: 118-79-6
2,4,6-tribromophenol

: C15H11Br6O3P

Conditions

Conditions	Yield
With sodium In methanol for 7h; Heating;	97%

: 5720-07-0
4-methoxyphenylboronic acid

: 118-79-6
2,4,6-tribromophenol

: 6863-51-0
2,4,6-tris(4-methoxyphenyl)phenol

Conditions

Conditions	Yield
With sodium carbonate; palladium diacetate In water; N,N-dimethyl-formamide at 60℃; for 12h; Suzuki;	97%

: 78-95-5
chloroacetone

: 118-79-6
2,4,6-tribromophenol

: 201160-26-1
(2,4,6-tribromo-phenoxy)-acetone

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide at 27℃;	97%

: 100-39-0
benzyl bromide

: 118-79-6
2,4,6-tribromophenol

: 88486-72-0
2-benzyloxy-1,3,5-tribromobenzene

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 18h;	97%
With sodium hydride In mineral oil at 80℃;

: 108-24-7
acetic anhydride

: 118-79-6
2,4,6-tribromophenol

: 607-95-4
2,4,6-tribromophenyl acetate

Conditions

Conditions	Yield
With pyrographite In dichloromethane at 20℃; for 1.5h; Acetylation;	96%
With lanthanum(III) nitrate at 20℃; for 0.3h;	95%
With sodium acetate
With sodium hydroxide
With sulfuric acid; acetic acid

: 118-79-6
2,4,6-tribromophenol

: 98-80-6
phenylboronic acid

: 3140-01-0
2,4,6-triphenylphenol

Conditions

Conditions	Yield
With sodium carbonate; palladium diacetate In water; N,N-dimethyl-formamide at 60℃; for 12h; Suzuki;	96%
With potassium fluoride; palladium diacetate for 0.166667h; Suzuki coupling reaction; microwave irradiation;	76%
With sodium carbonate In N,N-dimethyl-formamide at 120℃; for 6h; Suzuki-Miyaura coupling reaction; Inert atmosphere;	62%
With C28H40Br4N4Pd2; potassium carbonate In water; acetone at 20℃; for 24h; Suzuki Coupling;	50%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate at 100℃; for 0.5h; Suzuki-Miyaura Coupling; Microwave irradiation; Inert atmosphere;

: 37860-51-8
tetraethylene glycol di(p-toluenesulfonate)

: 118-79-6
2,4,6-tribromophenol

: C20H20Br6O5

Conditions

Conditions	Yield
With cesium fluoride In acetonitrile for 5h; Heating;	96%

: 824-72-6
P,P-dichlorophenylphosphine oxide

: 118-79-6
2,4,6-tribromophenol

: C18H9Br6O3P

Conditions

Conditions	Yield
With ammonia In chloroform at 55℃; for 2h; Temperature; Concentration; Solvent; Reagent/catalyst; Inert atmosphere; Sealed tube;	95.3%

: 81420-42-0
mononitrophenyl carbonate

: 118-79-6
2,4,6-tribromophenol

: 67990-32-3
bis(2,4,6-tribromophenyl) carbonate

Conditions

Conditions	Yield
dmap In dichloromethane at 25℃; for 8h;	95%

2,4,6-TRIBROMOPHENOL Chemical Properties

Molecular Formula: C₆H₃Br₃O

Formula Weight: 330.8
mp of 2,4,6-TRIBROMOPHENOL (118-79-6): 90-94 ^°C(lit.)
bp of 2,4,6-TRIBROMOPHENOL (118-79-6): 282-290 ^°C 746 mm Hg(lit.)
density : 2.55
vapor density : 11.4 (vs air)
Fp of 2,4,6-TRIBROMOPHENOL (118-79-6): 282-290^°C subl.
storage temp. : 2-8^°C
Water Solubility : 71 mg/L (15 ^oC)
Solubility : Soluble in alcohol, chloroform, ethyl ether and caustic solution, almost insoluble in water and suitable.
Appearance: white to pink powder

2,4,6-TRIBROMOPHENOL Uses

2,4,6-TRIBROMOPHENOL (118-79-6) can be used as antiseptic & germicide (eg, in pharmaceutical prepns). It is also used for producing disinfectant and preservative drug bismuth tribromophenate.
2,4,6-TRIBROMOPHENOL (118-79-6) is used also as an flame retardant in epoxy, polyurethane, plastics, paper, textiles and others; as well as an intermediate for the production of other commercial flame retardants and fire extinguishing media. It can be used as an antiseptic agent.

2,4,6-TRIBROMOPHENOL Production

2,4,6-TRIBROMOPHENOL (118-79-6) is synthesized from phenol by bromination.

2,4,6-TRIBROMOPHENOL Toxicity Data With Reference

orl-rat LD50:2 g/kg

85JCAE Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,524.

2,4,6-TRIBROMOPHENOL Consensus Reports

Reported in EPA TSCA Inventory.

2,4,6-TRIBROMOPHENOL Safety Profile

Hazard Codes :

Xi, Xn,

F
The Risk Statements information of 2,4,6-TRIBROMOPHENOL (118-79-6) : 36/37/38-51/53-20/22-39/23/24/25-23/24/25-11-63-43-45 (Irritating to eyes, respiratory system and skin; Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment; Harmful by inhalation and if swallowed; Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed; Toxic by inhalation, in contact with skin and if swallowed; Highly Flammable; Possible risk of harm to the unborn child; May cause sensitization by skin contact; May cause cancer)
The Safety Statements information of 2,4,6-TRIBROMOPHENOL (118-79-6): 26-36-61-37/39-45-36/37-16-7-24/25-23-53 (In case of contact with eyes, rinse immediately with plenty of water and seek medical advice; Wear suitable protective clothing; Avoid release to the environment; Wear suitable gloves and eye/face protection; In case of accident or if you feel unwell, seek medical advice immediately; Wear suitable protective clothing and gloves; Keep away from sources of ignition - No smoking; Keep container tightly closed; Avoid contact with skin and eyes; Do not breathe gas/fumes/vapor/spray; Avoid exposure - obtain special instruction before use)
RIDADR : UN 1230 3/PG 2
WGK Germany : 2
RTECS : SN1225000
Slightly toxic by ingestion. A powerful irritant to skin, eyes, and mucous membranes. May be absorbed dermally. When heated to decomposition it emits toxic fumes of Br⁻. See also BROMIDES and CHLOROPHENOLS.

Product Name

2,4,6-Tribromophenol

Synthetic route

2,4,6-TRIBROMOPHENOL Chemical Properties

2,4,6-TRIBROMOPHENOL Uses

2,4,6-TRIBROMOPHENOL Production

2,4,6-TRIBROMOPHENOL Toxicity Data With Reference

2,4,6-TRIBROMOPHENOL Consensus Reports

2,4,6-TRIBROMOPHENOL Safety Profile

2,4,6-TRIBROMOPHENOL Standards and Recommendations

2,4,6-TRIBROMOPHENOL Specification

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