Conditions | Yield |
---|---|
With iodoform; sodium iodide In N,N-dimethyl-formamide for 3h; Catalytic behavior; Irradiation; | 91% |
With acetyl iodide at 80 - 90℃; for 1.5h; | 24% |
With iodine; aluminium |
(i-C3H7)3SbI2
A
2-iodo-propane
B
tri(isopropyl)antimony
C
diisopropylantimony iodide
Conditions | Yield |
---|---|
under Ar, decomposed at 135°C for 30 min; distd., not separated from triisopropyl stibine; elem. anal.; | A 89% B n/a C n/a |
Conditions | Yield |
---|---|
With 2-fluoro-2-(piperidin-1-yl)-4-(2,3,5,6-tetrafluoropyridin-4-yl)-5-(2,4,6-triisopropylphenyl)-1,3-dithiole In 1,4-dioxane at 45℃; for 14h; Schlenk technique; Inert atmosphere; | 74% |
Conditions | Yield |
---|---|
With N-iodo-succinimide In chlorobenzene for 3h; Irradiation; | A 51% B 18% |
Conditions | Yield |
---|---|
With CCl4*2AlI3 In dichloromethane at -20℃; for 1.5h; | 50% |
5'-O-(4,4'-dimethoxytrityl)-2-N-<2-<(tert-butyldiphenylsilyloxy)methyl>benzoyl>guanosine
tert-butyldimethylsilyl chloride
A
2-iodo-propane
B
5'-O-(4,4'-dimethoxytrityl)-3'-O-(tert-butyldimethylsilyl)-2-N-<2-<(tert-butyldiphenylsilyloxy)methyl>benzoyl>guanosine
Conditions | Yield |
---|---|
With pyridine; silver nitrate In tetrahydrofuran | A 42% B 16% |
Conditions | Yield |
---|---|
With water; hydrogen iodide |
propene
2-iodo-propane
Conditions | Yield |
---|---|
With hydrogen iodide | |
With ascaridole; hydrogen iodide | |
With hydrogen iodide; diphenylamine | |
With hydrogen iodide |
Conditions | Yield |
---|---|
With hydrogen iodide; diphenylamine |
Conditions | Yield |
---|---|
With hydrogen iodide |
1,2-iodochloropropane
2-iodo-propane
Conditions | Yield |
---|---|
With hydrogen iodide |
Conditions | Yield |
---|---|
With phosphoric acid; potassium iodide | |
With diiodosilane In chloroform-d1 Ambient temperature; relative rates, other reagents, var. ethers; |
Conditions | Yield |
---|---|
With water; potassium iodide |
Conditions | Yield |
---|---|
mit UV-Licht (253.7 nm),in fluess. Zustand;bei Abwesenheit von Sauerstoff.Irradiation; |
Conditions | Yield |
---|---|
With phosphorus; water; iodine und nachfolgendes Dastillieren des Reaktionsprodukts; | |
With water; hydrogen iodide | |
With phosphorous; water; iodine | |
With hydrogen iodide In water; benzene at 100℃; under 15514.9 Torr; for 16h; Inert atmosphere; Autoclave; | 100 %Chromat. |
Conditions | Yield |
---|---|
With pyridine; tributyltin iodide at 125℃; Thermodynamic data; Equilibrium constant; Δ G; | |
With sodium iodide In acetone at 55℃; Kinetics; quantitative reaction kinetics in liquid state by in situ X-ray absorption fine structure spectroscopy; | |
With acetone; sodium iodide |
triisopropyl phosphite
methyl iodide
A
2-iodo-propane
B
diisopropyl methanephosphonate
Conditions | Yield |
---|---|
reagiert analog mit Brom-diphenyl-p-biphenylyl-methan und Homologen; |
Conditions | Yield |
---|---|
With diiodosilane In chloroform-d1 at 22℃; for 4h; | 99 % Spectr. |
allyl iodid
Chloroiodomethane
isopropylmagnesium chloride
A
2-iodo-propane
B
Isobutyl iodide
C
4-iodobut-1-ene
Conditions | Yield |
---|---|
In tetrahydrofuran; diethyl ether at -40℃; for 4.5h; Product distribution; | |
In tetrahydrofuran at -40℃; for 4.5h; |
diisopropyl ethylphosphonite
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane
A
2-iodo-propane
B
isopropyl ethyl(heptafluoropropyl)phosphinate
Conditions | Yield |
---|---|
In octane Rate constant; Kinetics; Thermodynamic data; E (activ.); ΔH(excit.); ΔS(excit.); ΔG(excit.); |
propene
acetic acid
A
2-iodo-propane
B
Isopropyl acetate
C
isopropyl alcohol
Conditions | Yield |
---|---|
With carbon monoxide; water; hydrogen iodide; TsVK-2; palladium at 110℃; under 60800 Torr; for 2h; Product distribution; further temperature (130 deg C); |
Conditions | Yield |
---|---|
With diiodosilane; iodine 1.) CDCl3, 22 deg C, 10 min, 2.) 30 min; Yield given. Multistep reaction; |
Conditions | Yield |
---|---|
With diiodosilane; iodine In chloroform-d1 at 22℃; for 3h; | 100 % Spectr. |
Conditions | Yield |
---|---|
With diiodosilane In chloroform-d1 for 0.166667h; Ambient temperature; other reaction time: 80 min, effect of iodine; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts; |
propene
carbon monoxide
isobutyric Acid
A
2-iodo-propane
B
isopropyl isobutyrate
C
isopropyl butyrate
D
isopropyl alcohol
E
butyric acid
Conditions | Yield |
---|---|
With water; hydrogen iodide; TsVK-2; palladium at 130℃; under 60800 Torr; for 2h; Product distribution; further temperature (110, 150, 170, 200 deg C); effect of the concentration of HI; effect of the pressure of CO; |
isopropyl radical
methyl iodide
A
2-iodo-propane
B
methyl radical
Conditions | Yield |
---|---|
Equilibrium constant; |
phenol
A
2-iodo-propane
B
tetrachloromethane
C
phenoxy radical
Conditions | Yield |
---|---|
In tetrachloromethane at 22℃; Rate constant; multistep reaction; |
Conditions | Yield |
---|---|
With trimethylsilyl iodide; bismuth(III) iodide In neat (no solvent) at 80℃; for 0.25h; | 98 % Chromat. |
N-methylcyclohexylamine
2-iodo-propane
1-isopropyl-1-methyl-piperidinium; iodide
Conditions | Yield |
---|---|
In chloroform at 60℃; for 8h; | 100% |
In chloroform Heating; |
2-iodo-propane
3-methylenebicyclo[2.2.1]heptan-2-one
3-isobutylbicyclo<2.2.1>heptan-2-one
Conditions | Yield |
---|---|
With copper(l) iodide; zinc In water Product distribution; further solvent: aq. ethanol, further activators: ammonium formate, ammonium chloride; ultrasonic irradiation; | 100% |
With copper(l) iodide; zinc In water ultrasonic irradiation; | 100% |
2-iodo-propane
5-hydroxynaphtho-1,4-quinone
5-isopropoxy-1,4-naphthoquinone
Conditions | Yield |
---|---|
With silver(l) oxide In dichloromethane at 20℃; for 20h; Green chemistry; regioselective reaction; | 100% |
With silver(l) oxide In chloroform for 0.333333h; Ambient temperature; | 77% |
2-iodo-propane
Conditions | Yield |
---|---|
In acetonitrile for 43h; | 100% |
2-iodo-propane
3-(4-hydroxy-2-nitrophenyl)pyridine
3-(4-isopropoxy-2-nitrophenyl)pyridine
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 40℃; for 6h; | 100% |
Conditions | Yield |
---|---|
With sodium azide; [bis(acetoxy)iodo]benzene; trifluoroacetic acid In isopropyl alcohol Product distribution; various solvents; | 100% |
With sodium azide; [bis(acetoxy)iodo]benzene; trifluoroacetic acid In isopropyl alcohol Heating; | 100% |
With tert.-butylhydroperoxide; acetic acid ; ferriacetate; trifluoroacetic acid In acetic acid for 4h; Heating; | 92% |
2-iodo-propane
benzeneacetic acid methyl ester
2-phenyl-3-methylbutyric acid methyl ester
Conditions | Yield |
---|---|
With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium diisopropyl amide In tetrahydrofuran at -78℃; | 100% |
With 2-pyrrolidinon In N,N-dimethyl-formamide Flow reactor; | 16% |
With 1) EGB.2 1) -78 deg C, 2) -78 deg C, 15 min; Yield given. Multistep reaction; |
2-iodo-propane
3-(2,3-Dihydro-benzo[1,4]dioxin-6-yl)-2,6-diethyl-7-hydroxy-chromen-4-one
Conditions | Yield |
---|---|
With potassium carbonate In acetone for 34.5h; Heating; | 100% |
With potassium carbonate In acetone Heating; | 99.8% |
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 60℃; | 100% |
2-iodo-propane
2-[(E)-2-nitroethenyl]furan
(E)-1-(2-furyl)-3-methyl-1-butene
Conditions | Yield |
---|---|
With triethylaluminum; dibenzoyl peroxide In diethyl ether at 20℃; for 2h; | 100% |
With air; triethyl borane In tetrahydrofuran at 20℃; | 100% |
Conditions | Yield |
---|---|
With air; triethyl borane In tetrahydrofuran at 20℃; | 100% |
With triethylaluminum; dibenzoyl peroxide In diethyl ether at 20℃; for 2h; | 98% |
2-iodo-propane
(E)-1-methoxy-4-(2-nitrovinyl)benzene
(E)-1-methoxy-4-(3-methyl-but-1-en-1-yl)benzene
Conditions | Yield |
---|---|
With triethyl borane; oxygen In tetrahydrofuran at 20℃; | 100% |
With triethylaluminum; dibenzoyl peroxide In diethyl ether at 20℃; for 2h; | 99% |
With triethyl borane In diethyl ether; water | |
With triethyl borane In tetrahydrofuran at 20℃; |
2-iodo-propane
1-nitro-2-(4-chlorophenyl)ethylene
Conditions | Yield |
---|---|
With triethylaluminum; dibenzoyl peroxide In diethyl ether at 20℃; for 2h; | 100% |
With air; triethyl borane In tetrahydrofuran at 20℃; | 98% |
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In benzene at 80℃; for 4h; | 100% |
Conditions | Yield |
---|---|
With hydrogenchloride; water; sodium chloride In acetonitrile for 20h; pH=2; Solvent; pH-value; Electrochemical reaction; Green chemistry; | 100% |
With 2,2'-azobis(isobutyronitrile); tert-butyl(2,6-dimethoxy-1-methylcyclohexa-2,5-dien-1-yl)dimethylsilane In hexane for 14h; Giese-type addition; Heating; | 89% |
With indium In methanol; water at 20℃; for 0.5h; | 86% |
2-iodo-propane
Conditions | Yield |
---|---|
With triethyl borane; tri-n-butyl-tin hydride; magnesium bromide In hexane; dichloromethane at 0℃; for 1h; | 100% |
2-iodo-propane
4-(7-hydroxy-6-methoxy-4-quinazolinyl)-1-piperazinecarboxylic acid tert-butyl ester
4-(7-isopropoxy-6-methoxy-4-quinazolinyl)-1-piperazinecarboxylic acid tert-butyl ester
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 20℃; | 100% |
2-iodo-propane
3-hydroxy-4-aminobenzoic acid methyl ester
4-amino-3-isopropoxybenzoic acid methyl ester
Conditions | Yield |
---|---|
With caesium carbonate In acetone at 60℃; for 2h; Inert atmosphere; | 100% |
With caesium carbonate In acetone for 10h; Heating; | 90% |
With caesium carbonate In acetone for 10h; Heating / reflux; | 90% |
With caesium carbonate In acetone at 120℃; for 1h; Microwave; | 60% |
With caesium carbonate In acetone |
2-iodo-propane
1-triphenylphosphoranylidene-2-propanone
4-methyl-1-(triphenylphosphaneylidene)pentan-2-one
Conditions | Yield |
---|---|
Stage #1: 1-triphenylphosphoranylidene-2-propanone With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Stage #2: 2-iodo-propane In tetrahydrofuran; hexane at -78 - 20℃; | 100% |
2-iodo-propane
4-tert-butylbenzyl mercaptan
Conditions | Yield |
---|---|
Stage #1: 4-tert-butylbenzyl mercaptan With tetra-(n-butyl)ammonium iodide; caesium carbonate In N,N-dimethyl-formamide at 20℃; for 1h; Stage #2: 2-iodo-propane In N,N-dimethyl-formamide at 0 - 20℃; for 18h; | 100% |
Conditions | Yield |
---|---|
Stage #1: 9H-fluorene With n-butyllithium In tetrahydrofuran; hexane at 20℃; for 1.5h; Stage #2: 2-iodo-propane In tetrahydrofuran; hexane at 20℃; for 2h; Further stages.; | 100% |
Stage #1: 9H-fluorene With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -15℃; for 0.333333h; Stage #2: 2-iodo-propane In tetrahydrofuran; hexane at -15℃; for 0.5h; Further stages.; | |
With lithium diisopropyl amide In tetrahydrofuran at -10℃; |
2-iodo-propane
5,6-bis(4-methoxyphenyl)-2H-pyridazin-3-one
Conditions | Yield |
---|---|
100% |
1,1-dimethylethyl 4-(4'-pyridinyloxy)-1-piperidinecarboxylate
2-iodo-propane
4-[(1-{tert-butoxycarbonyl}-4-piperidinyl)oxy]-1-(1-methylethyl)pyridinium iodide
Conditions | Yield |
---|---|
In dichloromethane at 20℃; | 100% |
In dichloromethane at 90℃; for 2.5 - 48h; |
2-iodo-propane
methyl 3-cyano-4-hydroxybenzoate
3-cyano-4-isopropoxybenzoic acid methyl ester
Conditions | Yield |
---|---|
With potassium carbonate In DMF (N,N-dimethyl-formamide) at 50℃; for 16h; | 100% |
With potassium carbonate In N,N-dimethyl-formamide at 50℃; for 16h; | 100% |
With potassium carbonate In N,N-dimethyl-formamide at 90℃; for 12h; Inert atmosphere; |
2-iodo-propane
4-chloro-5-iodo-7H-pyrrolo[2,3-d]pyrimidine
4-chloro-5-iodo-7-isopropyl-7H-pyrrolo[2,3-d]pyrimidine
Conditions | Yield |
---|---|
Stage #1: 4-chloro-5-iodo-7H-pyrrolo[2,3-d]pyrimidine With caesium carbonate In N,N-dimethyl-formamide at 20℃; for 0.05h; Stage #2: 2-iodo-propane | 100% |
In N,N-dimethyl-formamide |
2-iodo-propane
5-(1-methyl-6-trifluoromethyl-2(1H)-pyridon-3-yl)-2-chloro-4-fluorobenzoic acid
isopropyl 5-(1-methyl-6-trifluoromethyl-2(1H)-pyridon-3-yl)-2-chloro-4-fluorobenzoate
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide | 100% |
2-iodo-propane
tert-butyl 6-bromopyridin-2-ylcarbamate
tert-butyl N-(6-bromo-2-pyridyl)-N-isopropylcarbamate
Conditions | Yield |
---|---|
With sodium hydride In N,N-dimethyl-formamide at 0 - 20℃; for 25.5h; | 100% |
2-iodo-propane
7-benzyloxy-6-bromo-2-isopropylaminoquinazoline
Conditions | Yield |
---|---|
Stage #1: 7-benzyloxy-6-bromo-2-aminoquinazoline With sodium hydride In N,N-dimethyl-formamide at 5℃; for 0.5h; Stage #2: 2-iodo-propane In N,N-dimethyl-formamide at 60℃; for 1.5h; Stage #3: 2-iodo-propane With sodium hydride Product distribution / selectivity; more than 3 stages; | 100% |
Conditions | Yield |
---|---|
With caesium carbonate In N,N-dimethyl-formamide | 100% |
Conditions | Yield |
---|---|
In tetrahydrofuran-d8 byproducts: I(1-); react. in a glove box under Ar at 20°C, addn. of the organic halide via syringe to a soln. of Cp3UiPr(1-) in THF-d8, react. time: 10 min; determination by 1H NMR spectroscopy; | 100% |
1. | ihl-rat LC50:320,000 mg/m3/30M | FAVUAI Fiziologicheski Aktivnye Veshchestva. Physiologically Active Substances. 7 (1975),35. | ||
2. | ipr-mus LD50:1300 mg/kg | 34ZIAG Toxicology of Drugs and Chemicals ,Deichmann, W.B.,New York, NY.: Academic Press, Inc.,1969,756. |
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