3-Bromobenzaldehyde supplier

Name
3-Bromobenzaldehyde
EINECS 221-526-9
CAS No. 3132-99-8
Article Data224
CAS DataBase
Density 1.577 g/cm³
Solubility decomposes in water
Melting Point 18-21 °C(lit.)
Formula C₇H₅BrO
Boiling Point 235.3 °C at 760 mmHg
Molecular Weight 185.02
Flash Point 96.1 °C
Transport Information
Appearance clear colorless to yellow liquid after melting
Safety 26-36
Risk Codes 22-36/37/38
Molecular Structure
Hazard Symbols Xn,Xi
Synonyms NSC 66828;m-Bromobenzaldehyde;Benzaldehyde,m-bromo- (6CI,7CI,8CI);3-Formyl-1-bromobenzene;3-Formylbromobenzene;
PSA 17.07000
LogP 2.26160

Synthetic route

: 15852-73-0
(3-Bromophenyl)methanol

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With fluorosulfonyl fluoride; potassium carbonate; dimethyl sulfoxide at 20℃; for 12h; chemoselective reaction;	99%
With N-chloro-N-(benzenesulfonyl)benzenesulfonamide In acetonitrile at 20 - 25℃; for 0.25h; Inert atmosphere; chemoselective reaction;	98%
With tert.-butylhydroperoxide; 2,2′-((1E,1′E)-(1,2-phenylenebis(azanylylidene))bis(methanylylidene))diphenolcopper(II); sodium hydroxide In water; acetonitrile at 20℃;	97%

: 14473-91-7, 20595-41-9, 32862-97-8
3-bromocinnamic acid

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With aluminum oxide; potassium permanganate In dichloromethane at 20℃;	99%

: 108-36-1
1,3-dibromobenzene

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
Stage #1: 1,3-dibromobenzene With tri-n-butyllithium magnesate complex In toluene at 0℃; for 1.5h; Stage #2: N,N-dimethyl-formamide In toluene at 0℃; for 0.5h; Stage #3: With citric acid at 20℃;	99%
Stage #1: 1,3-dibromobenzene With n-butyllithium; isopropylmagnesium chloride In tetrahydrofuran; hexane at 0 - 5℃; for 1h; Stage #2: N,N-dimethyl-formamide In tetrahydrofuran at 0℃; for 1h; Further stages.;	90%
Stage #1: 1,3-dibromobenzene With n-butyllithium In tetrahydrofuran at -78℃; for 0.583333h; Stage #2: N,N-dimethyl-formamide In tetrahydrofuran at -78 - 20℃; for 1.5h;	63.21%

: 62247-78-3
1-bromo-3-(dibromomethyl)benzene

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With dimethyl sulfoxide at 120℃; for 1h;	95%
With potassium carbonate In dimethylsulfoxide-d6 at 60℃; for 24h; Kinetics; Hydrolysis;

: 75148-49-1
3-bromobenzaldehyde diethylacetal

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With iron(III) p-toluenesulfonate hexahydrate In water for 1h; Reflux;	95%
bismuth(III) iodide In water at 20℃; for 20h;	89%
With copper(II) sulfate; sodium iodide In acetone at 56℃; for 0.75h;	77%

: 62247-78-3
1-bromo-3-(dibromomethyl)benzene

: 67-68-5
dimethyl sulfoxide

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
at 120℃; for 1h;	95%

: 100-52-7
benzaldehyde

A: 3132-99-8
m-bromobenzoic aldehyde

B: 74553-29-0
2,5-dibromobenzaldehyde

Conditions

Conditions	Yield
With bromine fluoride In ethanol; chloroform at -40℃; for 0.0833333h;	A 94% B 5%
With bromine fluoride In ethanol; chloroform at -40℃; for 0.833333h;	A 5% B 90%

: 82436-20-2
2-(3-bromophenyl)-1,3-dithiolane

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With silica gel; ferric nitrate In hexane at 50℃; for 0.166667h;	94%

: 50793-32-3
C6H4(3-Br)(CHSCH2CH2CH2S-cyclic)

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With silica gel; iodic acid at 20℃; for 0.0125h;	94%
With quinolinium monofluorochromate(VI) In acetonitrile for 2.5h; Heating;	93%
With 1,3,5-trichloro-2,4,6-triazine; dimethyl sulfoxide In dichloromethane at 20℃; for 2h;	92%
With 2,6-dicarboxypyridinium chlorochromate In acetonitrile for 1.91667h; Heating;	90%

: 17789-14-9
3-(1,3-dioxolan-2-yl)-phenylbromide

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With carbon tetrabromide In water; acetonitrile at 45℃; for 2h; sonication;	93%
In(OSO2CF3)3 In acetone at 20℃; for 2.5h;	93%
With copper(II) sulfate; sodium iodide In acetone at 56℃; for 0.666667h;	92%

: 867371-13-9
1-bromo-3-(trimethylsilyloxy)methyl-benzene

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With cetyltrimethylammonium peroxodisulphate In acetonitrile for 0.2h; Reflux;	93%
With ethylenebis(N-methylimidazolium) chlorochromate In acetonitrile for 5.5h; Reflux;	85%
With trichloroisocyanuric acid In acetonitrile Reflux;

: 38407-30-6
1-(3-bromobenzylidene)semicarbazide

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; water; silica gel In dichloromethane at 20℃; for 3.5h;	92%

: 643734-33-2
(3-bromo-phenyl)-pyrrol-1-yl-methanol

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 20℃; for 12h;	90%

: 4885-18-1
3-bromo-N,N-dimethylbenzylamine

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With Selectfluor In acetonitrile at 20℃; for 0.333333h;	90%
With [bis(acetoxy)iodo]benzene; sodium hydrogencarbonate In chloroform at 60℃; for 12h; Polonovski type reaction;	42%

: 6952-59-6
3-cyanobromobenzene

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With calcium bis(hypophosphite); calcium acetate; nickel(II) acetate tetrahydrate In ethanol; water at 100℃; for 29h; Sealed tube;	90%

: 3-(3-bromobenzyl)-3-(tert-butylperoxy)indolin-2-one

A: 3132-99-8
m-bromobenzoic aldehyde

B: 91-56-5
indole-2,3-dione

Conditions

Conditions	Yield
With iron(III) chloride hexahydrate In acetonitrile at 100℃; Sealed tube;	A 76% B 90%

: 2-(3-bromophenyl)-4,5-dihydrooxazole

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With sodium tetrahydroborate; nickel dichloride In methanol at -10 - 10℃;	89%

: 51873-95-1, 52739-46-5, 32605-62-2
3-bromobenzaldehyde oxime

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With samarium; titanium tetrachloride In tetrahydrofuran at 20℃; for 0.166667h;	88%
With chromium(VI) oxide; silica gel In toluene at 72 - 75℃; for 3h; Oxidation; Deoximation;	86%
With manganese(IV) oxide; silica gel for 0.1h; microwave irradiation;	86%

: 1,1-diacetoxy-1-(3-bromophenyl)methane

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With N-sulfonic acid poly(4-vinylpyridinium) chloride In methanol at 20℃; for 0.583333h;	88%
With sulfonated rice husk ash In acetonitrile at 60℃; for 0.0833333h;	88%
With water at 20℃; for 0.25h; Green chemistry;	93 %Chromat.

: 1878-67-7
3-Bromophenylacetic acid

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With oxygen; copper diacetate In dimethyl sulfoxide at 120℃; for 18h; Sealed tube;	87%
With (2,2'-dipyridyl)bis(5-methyl-2-(4-fluoro)phenylpyridine-N,C)iridium(III) hexafluorophosphate; oxygen; sodium carbonate; 1,1'-diethyl-4,4'-bipyridinium diperchlorate In dimethyl sulfoxide at 20℃; under 760.051 Torr; for 16h; Irradiation;	71%

: 823-78-9
meta-bromobenzyl bromide

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With bis-{4-methoxy-phenyl}-selenoxyde; sodium hydrogencarbonate In acetonitrile at 75℃; for 5h;	86%
With chloroform; hexamethylenetetramine Kochen des Reaktionsprodukts mit wss. Essigsaeure;
With hydrogenchloride; ethanol; hexamethylenetetramine
Multi-step reaction with 2 steps 1: water / 5 h / Reflux 2: dihydrogen peroxide / water / 7 h / 20 °C View Scheme
With 4-methylmorpholine N-oxide at 20℃; for 3h; Reflux;	259 mg

: 591-17-3
meta-bromotoluene

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With carbon tetrabromide; oxygen In acetonitrile at 20℃; for 3h; Irradiation; Green chemistry;	85%
With oxygen In water at 150℃; under 30002.4 Torr; for 2h;	49%
With N-hydroxyphthalimide; oxygen; trifluoroacetic acid; sodium nitrite In water at 20℃; for 3.5h; Green chemistry;	13%

: 100-52-7
benzaldehyde

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With N-Bromosuccinimide; sulfuric acid; trifluoroacetic acid at 25℃; for 42h; Bromination;	84%
With potassium hydrogensulfate; isoquinolinium dichromate; potassium bromide In water at 20℃; Reagent/catalyst; Temperature; Sonication; regioselective reaction;	72%
With monobromoisocynaurate; sulfuric acid at 40℃; for 12h;	70%

: C6H4BrIZn*ClLi

: 27064-03-5
S-phenyl methanethioate

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With trifuran-2-yl-phosphane; palladium diacetate In tetrahydrofuran; toluene at 0℃; for 0.5h; Schlenk technique;	83%

: 64-18-6
formic acid

: 591-18-4
1-Bromo-3-iodobenzene

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With iodine; triethylamine; triphenylphosphine In toluene at 80℃; Inert atmosphere; Sealed tube;	83%

: 585-76-2
m-bromobenzoic acid

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With 1,2-bis(2,4,8,10-tetra-tert-butyl-5,7-dioxa-6-phosphadibenzo[a,c]cyclohepten-6-yloxy)ethane; methylphenylsilane; copper(l) cyanide; 2,2-dimethylpropanoic anhydride In dimethyl sulfoxide at 80℃; for 20h; Schlenk technique; Inert atmosphere;	82%

: 18257-89-1
1-allyl-3-bromo-benzene

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With iron(III) chloride; tetramethyldisiloxane In ethanol at 20℃; for 12h;	82%

: 591-18-4
1-Bromo-3-iodobenzene

: 201230-82-2
carbon monoxide

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With rhodium(III) chloride trihydrate; hydrogen; triethylamine; triphenylphosphine In N,N-dimethyl acetamide at 90℃; under 7500.75 Torr; for 12h; Autoclave;	82%

: 108-36-1
1,3-dibromobenzene

: 693-04-9
butyl magnesium bromide

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With n-butyllithium; acetic acid In tetrahydrofuran; hexane; N,N-dimethyl-formamide; toluene	78%

: 337535-82-7
N-acetyl-3-bromobenzylamine

: 3132-99-8
m-bromobenzoic aldehyde

Conditions

Conditions	Yield
With N-Bromosuccinimide In chloroform at 20℃; for 18h;	78%

: 3132-99-8
m-bromobenzoic aldehyde

: 925-90-6
ethylmagnesium bromide

: 74157-47-4
(+/-)-1-(3-bromophenyl)propanol

Conditions

Conditions	Yield
In diethyl ether at -78 - 20℃;	100%
In diethyl ether	92%
Stage #1: m-bromobenzoic aldehyde; ethylmagnesium bromide In diethyl ether for 1.08333h; Cooling with ice; Stage #2: With hydrogenchloride In diethyl ether; water	88%

: 3132-99-8
m-bromobenzoic aldehyde

: 51873-95-1, 52739-46-5, 32605-62-2
3-bromobenzaldehyde oxime

Conditions

Conditions	Yield
With hydroxylamine hydrochloride; sodium acetate In ethanol; water Reflux;	100%
With pyridine; hydroxylamine hydrochloride for 2h; Reflux;	91.5%
With hydroxylamine hydrochloride; sodium acetate In ethanol at 45℃; for 1h;	90.8%

: 3132-99-8
m-bromobenzoic aldehyde

: 109-77-3
malononitrile

: 2972-74-9
2-(3-bromobenzylidene)malononitrile

Conditions

Conditions	Yield
With glycine In dichloromethane	100%
With ethanolamine-phosphoric acid functionalized polyacrylonitrile fibers, hydrophobized with benzylamine (Bn-PANEAPF) In water at 20℃; for 2h; Knoevenagel Condensation; Green chemistry;	99%
In various solvent(s) at 50℃; for 3h; Knoevenagel condensation;	98%

: 3132-99-8
m-bromobenzoic aldehyde

: 1066-54-2
trimethylsilylacetylene

: 77123-55-8
3-((trimethylsilyl)ethynyl)benzaldehyde

Conditions

Conditions	Yield
With copper(l) iodide; bis(benzonitrile)palladium(II) dichloride; tri-tert-butyl phosphine; diisopropylamine In 1,4-dioxane Inert atmosphere;	100%
With copper(l) iodide; bis(benzonitrile)palladium(II) dichloride; tri-tert-butyl phosphine; diisopropylamine In 1,4-dioxane for 7h; Inert atmosphere;	100%
With palladium diacetate; triethylamine; triphenylphosphine at 100℃; for 6h; Inert atmosphere;	95%

: 3132-99-8
m-bromobenzoic aldehyde

: 504-63-2
trimethyleneglycol

: 67437-93-8
2-(3-bromophenyl)-[1,3]dioxane

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In toluene for 15.5h; Reflux; Dean-Stark;	100%
With toluene-4-sulfonic acid In toluene for 2.5h; Heating;	99%
With toluene-4-sulfonic acid In toluene at 20℃; for 2.5h;	96%

: 3132-99-8
m-bromobenzoic aldehyde

: 26138-64-7
3-acetyl-2,4-dihydroxyquinoline

: (E)-3-(3-Bromo-phenyl)-1-(2,4-dihydroxy-quinolin-3-yl)-propenone

Conditions

Conditions	Yield
	100%

: 3132-99-8
m-bromobenzoic aldehyde

: 107-21-1
ethylene glycol

: 17789-14-9
3-(1,3-dioxolan-2-yl)-phenylbromide

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In toluene for 5.5h; Heating / reflux;	100%
With toluene-4-sulfonic acid In toluene at 20 - 135℃;	98%
Stage #1: m-bromobenzoic aldehyde; ethylene glycol With toluene-4-sulfonic acid In toluene for 4h; Heating / reflux; Stage #2: With sodium hydrogencarbonate In water; toluene at 0℃;	97%

: 3132-99-8
m-bromobenzoic aldehyde

: 24455-93-4
N-(4-methoxyphenyl)ethane-1,2-diamine

: N-[1-(3-Bromo-phenyl)-meth-(E)-ylidene]-N'-(4-methoxy-phenyl)-ethane-1,2-diamine

Conditions

Conditions	Yield
In methanol at 25℃; for 1h; Condensation;	100%

: 3132-99-8
m-bromobenzoic aldehyde

: 6332-77-0
N-(4-nitrophenyl)ethylenediamine

: 250386-71-1
N-[1-(3-Bromo-phenyl)-meth-(E)-ylidene]-N'-(4-nitro-phenyl)-ethane-1,2-diamine

Conditions

Conditions	Yield
In methanol at 25℃; for 1h; Condensation;	100%

: 3132-99-8
m-bromobenzoic aldehyde

: 50622-50-9
N-(p-methylphenyl)-ethylenediamine

: N-(3-bromo-benzylidene)-N'-p-tolyl-ethane-1,2-diamine

Conditions

Conditions	Yield
In methanol at 25℃; for 1h; Condensation;	100%

: 3132-99-8
m-bromobenzoic aldehyde

: N-(p-dimethylaminophenyl)ethylenediamine

: N-{2-[(3-bromo-benzylidene)-amino]-ethyl}-N',N'-dimethyl-benzene-1,4-diamine

Conditions

Conditions	Yield
In methanol at 25℃; for 1h; Condensation;	100%

: 3132-99-8
m-bromobenzoic aldehyde

: 14088-83-6
N-(3-chlorophenyl)-1,2-diaminoethane

: N-[1-(3-Bromo-phenyl)-meth-(E)-ylidene]-N'-(3-chloro-phenyl)-ethane-1,2-diamine

Conditions

Conditions	Yield
In methanol at 25℃; for 1h; Condensation;	100%

: 110-89-4
piperidine

: 3132-99-8
m-bromobenzoic aldehyde

: 536-74-3
phenylacetylene

: 1-(1-(3-bromophenyl)-3-phenylprop-2-yn-1-yl)piperidine

Conditions

Conditions	Yield
With gold(III) tribromide In water at 100℃; for 12h;	100%
Stage #1: piperidine; m-bromobenzoic aldehyde With magnetic nanoparticles supported biimidazole Cu(I) complex for 0.166667h; Green chemistry; Stage #2: phenylacetylene In water for 1.5h; Reflux; Green chemistry;	98%
With gold(III) immobilized magnetic poly imidazole and imidazolium bromide nanoparticles In water at 60℃; for 13h; Green chemistry;	92%

...Expand

: 1450-72-2
5-methyl-2-hydroxyacetophenone

: 3132-99-8
m-bromobenzoic aldehyde

: (Z)-3-(3-Bromo-phenyl)-1-(2-hydroxy-5-methyl-phenyl)-propenone

Conditions

Conditions	Yield
Stage #1: 5-methyl-2-hydroxyacetophenone With sodium hydroxide In ethanol; water at 0 - 5℃; Stage #2: m-bromobenzoic aldehyde In ethanol; water	100%
With potassium hydroxide In ethanol at 20℃; for 24h;
Stage #1: 5-methyl-2-hydroxyacetophenone With sodium hydroxide In methanol; water at 20℃; for 0.5h; Claisen Condensation; Stage #2: m-bromobenzoic aldehyde In methanol; water at 20℃; for 4h; Claisen Condensation;

: 3132-99-8
m-bromobenzoic aldehyde

: 118-93-4
o-hydroxyacetophenone

: 3754-50-5, 108440-17-1
3-(3-bromophenyl)-1-(2-hydroxyphenyl)prop-2-en-1-one

Conditions

Conditions	Yield
Stage #1: o-hydroxyacetophenone With sodium hydroxide In ethanol; water at 0 - 5℃; Stage #2: m-bromobenzoic aldehyde In ethanol; water	100%
With sodium hydroxide In ethanol at 20℃;	93%
With potassium hydroxide In ethanol at 20℃; for 24h;

: 3132-99-8
m-bromobenzoic aldehyde

: cis-1-amino-2-hydroxymethylindane

: ((1R,2R)-1-{[1-(3-Bromo-phenyl)-meth-(E)-ylidene]-amino}-indan-2-yl)-methanol

Conditions

Conditions	Yield
In methanol at 20℃; for 24h;	100%

: 3132-99-8
m-bromobenzoic aldehyde

: 151-50-8
potassium cyanide

: 71412-88-9, 550313-02-5
2-(3-bromophenyl)-2-hydroxyacetonitrile

Conditions

Conditions	Yield
Stage #1: m-bromobenzoic aldehyde With sodium hydrogensulfite In water at 20℃; for 2.5h; Stage #2: potassium cyanide In water at 0 - 20℃; for 2h;	100%
With acetic acid In methanol at 0℃; for 1h;

: 913815-80-2
9-(4-aminobutyl)-9-azabicyclo[3.3.1]nonan-3α-yl 2-methoxy-5-methylphenylcarbamate

: 3132-99-8
m-bromobenzoic aldehyde

: (2-Methoxy-5-methyl-phenyl)-carbamic acid (1R,3R,5S)-9-(4-{[1-(3-bromo-phenyl)-meth-(E)-ylidene]-amino}-butyl)-9-aza-bicyclo[3.3.1]non-3-yl ester

Conditions

Conditions	Yield
In benzene at 90℃; for 2h;	100%
In benzene at 90℃; for 2h;

: 3132-99-8
m-bromobenzoic aldehyde

: 107-11-9
1-amino-2-propene

: 246509-64-8
Allyl-[1-(3-bromo-phenyl)-meth-(E)-ylidene]-amine

Conditions

Conditions	Yield
With magnesium sulfate In dichloromethane at 20℃; for 20h;	100%

: 3132-99-8
m-bromobenzoic aldehyde

: 36282-40-3
(3-methoxyphenyl)magnesium bromide

: 76778-33-1
3-bromo-α-(3-methoxyphenyl)benzenemethanol

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; for 0.25h;	100%
Stage #1: m-bromobenzoic aldehyde; (3-methoxyphenyl)magnesium bromide In tetrahydrofuran at 80℃; for 3h; Grignard reaction; Inert atmosphere; Stage #2: With water; sodium chloride In tetrahydrofuran at 20℃;

: 1122-62-9
2-acetylpyridine

: 3132-99-8
m-bromobenzoic aldehyde

: 29816-74-8
(E)-3-(3-bromophenyl)-1-phenyl-2-propen-1-one

Conditions

Conditions	Yield
With sodium hydroxide In methanol	100%

: 3132-99-8
m-bromobenzoic aldehyde

: 17789-14-9
3-(1,3-dioxolan-2-yl)-phenylbromide

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In ethylene glycol; toluene	100%
With sodium hydroxide In ethylene glycol; toluene	99%

: 96-20-8, 13054-87-0
2-aminobutanol

: 3132-99-8
m-bromobenzoic aldehyde

: C11H14BrNO

Conditions

Conditions	Yield
In methanol at 20℃; for 1h;	100%

: 6168-72-5
2-Amino-1-propanol

: 3132-99-8
m-bromobenzoic aldehyde

: C10H12BrNO

Conditions

Conditions	Yield
In methanol at 20℃; for 1h;	100%

: 3132-99-8
m-bromobenzoic aldehyde

: 2835-82-7
3-aminobutyric acid

: C11H14BrNO

Conditions

Conditions	Yield
In methanol at 20℃; for 1h;	100%

: 3132-99-8
m-bromobenzoic aldehyde

: 5699-54-7
3-amino-4-methylpentanoic acid

: C13H18BrNO

Conditions

Conditions	Yield
In methanol at 20℃; for 1h;	100%

: 3132-99-8
m-bromobenzoic aldehyde

: 18664-78-3
3-aminopentanoic acid

: C12H16BrNO

Conditions

Conditions	Yield
In methanol at 20℃; for 1h;	100%

: 3132-99-8
m-bromobenzoic aldehyde

: 112245-13-3
(S)-tert-leucinol

: C13H18BrNO

Conditions

Conditions	Yield
In methanol at 20℃; for 1h;	100%

: 3132-99-8
m-bromobenzoic aldehyde

: 204191-43-5
racemic 3-amino-4,4-dimethyl-pentanoic acid

: C14H20BrNO

Conditions

Conditions	Yield
In methanol at 20℃; for 1h;	100%

: 3132-99-8
m-bromobenzoic aldehyde

: 75-05-8
acetonitrile

: 1075178-25-4
3-(3-bromophenyl)-3-hydroxypropanenitrile

Conditions

Conditions	Yield
Stage #1: acetonitrile With potassium tert-butylate In tetrahydrofuran at -50℃; for 0.416667h; Inert atmosphere; Stage #2: m-bromobenzoic aldehyde In tetrahydrofuran at -40 - -10℃;	100%
Stage #1: acetonitrile With potassium tert-butylate In tetrahydrofuran at -50℃; for 0.583333h; Inert atmosphere; Stage #2: m-bromobenzoic aldehyde In tetrahydrofuran at -50℃; for 0.583333h; Stage #3: With ammonium chloride In tetrahydrofuran; water	96%
Stage #1: acetonitrile With potassium tert-butylate In tetrahydrofuran at -50℃; for 0.583333h; Stage #2: m-bromobenzoic aldehyde In tetrahydrofuran at -50 - 0℃;	96%
Stage #1: acetonitrile With lithium diisopropyl amide In tetrahydrofuran at -78℃; for 0.25h; Stage #2: m-bromobenzoic aldehyde In tetrahydrofuran at -78 - 20℃; Product distribution / selectivity;	81%
Stage #1: acetonitrile With potassium tert-butylate In tetrahydrofuran at -50℃; for 0.5 - 0.583333h; Stage #2: m-bromobenzoic aldehyde In tetrahydrofuran at -50 - 20℃; for 3.5h; Product distribution / selectivity;	69%

3-Bromobenzaldehyde Chemical Properties

Product Name: 3-Bromobenzaldehyde
Synonyms: m-bromo-benzaldehyd;nsc66828; 3-bromo-benzaldehyd;AKOS BBS-00003144;Benzaldehyde, m-bromo-;3-BROMOBENZALDEHYDE;AKOS B004042;benzaldehyde,3-bromo-;
The Molecular formula of 3-bromo benzaldehyde(3132-99-8): C₇H₅BrO
The Molecular Weight of 3-bromo benzaldehyde(3132-99-8): 185.02
Molecular Structure :

EINECS: 221-526-9
Melting point: 18-21 °C(lit.)
Boiling point: 233-236 °C(lit.)
density: 1.587 g/mL at 25 °C(lit.)
refractive index: n20/D 1.593(lit.)
Flash point: 96 °C
color: very faintly to deep brownish-yellow
Water Solubility: DECOMPOSES
Sensitive: Air Sensitive

3-Bromobenzaldehyde Safety Profile

The Hazard Codes of 3-bromo benzaldehyde(3132-99-8):

Xn,Xi
The Risk Statements information of 3-bromo benzaldehyde(3132-99-8):
22: Harmful if swallowed
36/37/38: Irritating to eyes, respiratory system and skin
The Safety Statements information of 3-bromo benzaldehyde(3132-99-8):
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
RIDADR: 2810
WGK Germany: 3
RTECS: CU4820000
F: 10
Hazard Note: Irritant

Product Name

3-Bromobenzaldehyde

Synthetic route

3-Bromobenzaldehyde Chemical Properties

3-Bromobenzaldehyde Safety Profile

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