4-Dodecylaniline supplier | CasNO.104-42-7

Name
4-Dodecylaniline
EINECS 203-201-3
CAS No. 104-42-7
Article Data19
CAS DataBase
Density 0.902 g/cm³
Solubility
Melting Point 35-39 °C(lit.)
Formula C₁₈H₃₁N
Boiling Point 364 °C at 760 mmHg
Molecular Weight 261.451
Flash Point 162.7 °C
Transport Information
Appearance WHITE TO TAN POWDER, CRYSTALS AND/OR CHUNKS
Safety 22-24/25
Risk Codes 22
Molecular Structure
Hazard Symbols Xn
Synonyms Aniline,p-dodecyl- (6CI,7CI,8CI);(p-Aminododecyl)benzene;1-(p-Aminophenyl)dodecane;4-Dodecylbenzenamine;4-Dodecylphenylamine;4-n-Dodecylaniline;p-Dodecylaniline;
PSA 26.02000
LogP 6.31340

Synthetic route

: 112-53-8
1-dodecyl alcohol

: 62-53-3
aniline

: 104-42-7
4-dodecylaniline

Conditions

Conditions	Yield
With zinc(II) chloride at 255 - 258℃; for 21h;	45%

: 1022975-57-0
1-(dodec-1-yn-1-yl)-4-nitrobenzene

: 104-42-7
4-dodecylaniline

Conditions

Conditions	Yield
With 5%-palladium/activated carbon; hydrogen In ethanol; ethyl acetate at 20℃; under 15001.5 Torr; for 24h; Autoclave;	41%

: 3007-74-7
N-dodecylaniline

: 142-04-1
aniline hydrochloride

: 104-42-7
4-dodecylaniline

Conditions

Conditions	Yield
With zinc(II) chloride at 240℃;

: 3007-74-7
N-dodecylaniline

A: 104-42-7
4-dodecylaniline

B: 854306-07-3
4,N-didodecyl-aniline

Conditions

Conditions	Yield
With cobalt(II) chloride at 247℃;

: 101874-34-4
1-chloro-4-dodecylbenzene

: 104-42-7
4-dodecylaniline

Conditions

Conditions	Yield
With ammonia; water; copper(l) chloride

: 101778-21-6
4'-aminododecanoylphenone

: 104-42-7
4-dodecylaniline

Conditions

Conditions	Yield
With hydrogenchloride; amalgamated zinc
With potassium hydroxide; hydrazine hydrate; diethylene glycol

: 72617-54-0
p'-(ω-(trimethylammonio)butyloxy)-p-(dodecylbenzylidene)aniline

A: 104-42-7
4-dodecylaniline

B: 72617-53-9
4-(p-formylphenyloxy)butyltrimethylammonium bromide

Conditions

Conditions	Yield
With phosphate buffer In water at 30℃; Rate constant; Kinetics; ΔE(excit.); influence of pH and concentration of azometine on velocity constant;

: 72621-04-6
[10-(4-{[(E)-4-Dodecyl-phenylimino]-methyl}-phenoxy)-decyl]-trimethyl-ammonium; bromide

A: 104-42-7
4-dodecylaniline

B: 73000-51-8
10-(p-formylphenyloxy)decyltrimethylammonium bromide

Conditions

Conditions	Yield
With phosphate buffer In water at 30℃; Rate constant; Kinetics; ΔE(excit.); influence of pH and concentration of azometine on velocity constant, var. solvents;

: 70987-23-4
(4-{[(E)-4-Dodecyl-phenylimino]-methyl}-phenyl)-trimethyl-ammonium; bromide

A: 104-42-7
4-dodecylaniline

B: 72621-22-8
4-formyl-N,N,N-trimethyl-benzenaminium bromide

Conditions

Conditions	Yield
With phosphate buffer In water at 30℃; Rate constant; Kinetics; ΔE(excit.); influence of pH and concetration of azometine on velocity constant;

: 3007-74-7
N-dodecylaniline

cobalt (II)-chloride: cobalt (II)-chloride

A: 104-42-7
4-dodecylaniline

B: 854306-07-3
4,N-didodecyl-aniline

C: 62-53-3
aniline

Conditions

Conditions	Yield
at 250℃;

...Expand

: 112-16-3
n-dodecanoyl chloride

: 104-42-7
4-dodecylaniline

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: AlCl3 2: CuCl; aqueous NH3 / 250 - 270 °C 3: amalgamated zinc; aqueous HCl View Scheme
Multi-step reaction with 3 steps 1: AlCl3; CS2 2: ethanolic NaOH 3: N2H4+H2O; KOH; diethylene glycol View Scheme
Multi-step reaction with 3 steps 1: aluminum (III) chloride 2: hydrazine 3: aluminum (III) chloride; acetyl chloride View Scheme

: 4292-19-7
1-Iodododecane

: 104-42-7
4-dodecylaniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 2: cobalt (II)-chloride / 247 °C View Scheme

: 408333-43-7
1-(4-chloro-phenyl)-dodecan-1-one

: 104-42-7
4-dodecylaniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: CuCl; aqueous NH3 / 250 - 270 °C 2: amalgamated zinc; aqueous HCl View Scheme
Multi-step reaction with 4 steps 1: aluminium isopropylate; isopropyl alcohol 2: KHSO4 / 200 °C / 10 Torr 3: Raney nickel; ethanol / Hydrogenation 4: water; CuCl; NH3 View Scheme

: 112508-20-0
acetic acid-(4-lauroyl-anilide)

: 104-42-7
4-dodecylaniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: ethanolic NaOH 2: N2H4+H2O; KOH; diethylene glycol View Scheme

: 62-53-3
aniline

: 104-42-7
4-dodecylaniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 2: cobalt (II)-chloride / 247 °C View Scheme

: 108-90-7
chlorobenzene

: 104-42-7
4-dodecylaniline

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: AlCl3 2: CuCl; aqueous NH3 / 250 - 270 °C 3: amalgamated zinc; aqueous HCl View Scheme

: 103-84-4
Acetanilid

: 104-42-7
4-dodecylaniline

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: AlCl3; CS2 2: ethanolic NaOH 3: N2H4+H2O; KOH; diethylene glycol View Scheme

: 101887-54-1
1ξ-(4-chloro-phenyl)-dodec-1-ene

: 104-42-7
4-dodecylaniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: Raney nickel; ethanol / Hydrogenation 2: water; CuCl; NH3 View Scheme

: 101874-35-5
1-(4-chloro-phenyl)-dodecan-1-ol

: 104-42-7
4-dodecylaniline

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: KHSO4 / 200 °C / 10 Torr 2: Raney nickel; ethanol / Hydrogenation 3: water; CuCl; NH3 View Scheme

: 112-41-4
1-dodecene

: 62-53-3
aniline

: 104-42-7
4-dodecylaniline

Conditions

Conditions	Yield
With aluminum (III) chloride; methyl tributylammonium chloride at 46 - 160℃; for 27.8h;

: 123-01-3
1-dodecylbenzene

: 104-42-7
4-dodecylaniline

Conditions

Conditions	Yield
Stage #1: 1-dodecylbenzene With aluminum (III) chloride; acetyl chloride Stage #2: Schmidt reaction;

: 1674-38-0
dodecanophenone

: 104-42-7
4-dodecylaniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: hydrazine 2: aluminum (III) chloride; acetyl chloride View Scheme

: 71-43-2
benzene

: 104-42-7
4-dodecylaniline

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: aluminum (III) chloride 2: hydrazine 3: aluminum (III) chloride; acetyl chloride View Scheme

: 636-98-6
p-nitrobenzene iodide

: 104-42-7
4-dodecylaniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); triethylamine / 2 h / 80 °C / Inert atmosphere 2: 5%-palladium/activated carbon; hydrogen / ethanol; ethyl acetate / 24 h / 20 °C / 15001.5 Torr / Autoclave View Scheme

: 765-03-7
1-dodecyne

: 104-42-7
4-dodecylaniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); triethylamine / 2 h / 80 °C / Inert atmosphere 2: 5%-palladium/activated carbon; hydrogen / ethanol; ethyl acetate / 24 h / 20 °C / 15001.5 Torr / Autoclave View Scheme

: 40938-30-5
2-dodecylaniline

: 104-42-7
4-dodecylaniline

Conditions

Conditions	Yield
With hydrogen sulfide

: 104-42-7
4-dodecylaniline

: 148402-69-1
5,11,17,23-tetraformyl-25,26,27,28-tetrakis(methoxy)calix[4]arene

: 143519-67-9
C108H148N4O4

Conditions

Conditions	Yield
With 4 A molecular sieve In chloroform for 29h; Heating;	100%

: cobalt(II) perchlorate hydrate

: 104-42-7
4-dodecylaniline

: Co(NC5H4NNC6H4NC6H4(CH2)11CH3)2(1+)*ClO4(1-)=(Co(NC5H4NNC6H4NC6H4(CH2)11CH3)2)ClO4

Conditions

Conditions	Yield
In not given ligand reacted with Co salt instaneously;	99%

: 2033-24-1
cycl-isopropylidene malonate

: 104-42-7
4-dodecylaniline

: 149-73-5
trimethyl orthoformate

: C25H37NO4

Conditions

Conditions	Yield
Stage #1: cycl-isopropylidene malonate; trimethyl orthoformate for 1h; Reflux; Stage #2: 4-dodecylaniline for 2h; Reflux;	98%

...Expand

: 104-42-7
4-dodecylaniline

: 814-68-6
acryloyl chloride

: 372941-32-7
N-(para(dodecyl)phenyl)acrylamide

Conditions

Conditions	Yield
Stage #1: 4-dodecylaniline With 1H-imidazole; triethylamine In tetrahydrofuran for 0.166667h; Stage #2: acryloyl chloride In tetrahydrofuran at 0 - 25℃; for 15.33h; Inert atmosphere;	95%
With triethylamine In tetrahydrofuran at 0 - 20℃; for 15.16h; Inert atmosphere;	95%

: 104-42-7
4-dodecylaniline

: 4-dodecyl-2-iodoaniline

Conditions

Conditions	Yield
With iodine; sodium hydrogencarbonate In water; toluene at 20℃; Inert atmosphere; Schlenk technique;	94%

: 104-42-7
4-dodecylaniline

: 106-89-8
epichlorohydrin

: N,N-bis(2-hydroxy-3-chloropropyl)dodecylaniline

Conditions

Conditions	Yield
In ethanol at 20℃; for 18h;	91.5%

: 104-42-7
4-dodecylaniline

: 49669-26-3
2,2'-bipyridine-6,6'-dicarbaldehyde

: C48H66N4

Conditions

Conditions	Yield
With acid	90%

: 104-42-7
4-dodecylaniline

: 118-91-2
ortho-chlorobenzoic acid

: 1373551-67-7
2-((4-dodecylphenyl)amino)benzoic acid

Conditions

Conditions	Yield
With copper diacetate; potassium carbonate In N,N-dimethyl-formamide for 3h; Inert atmosphere; Reflux;	90%

: 104-42-7
4-dodecylaniline

: 4637-24-5
N,N-dimethyl-formamide dimethyl acetal

: N'-(4-dodecylphenyl)-N,N-dimethylethanimidamide

Conditions

Conditions	Yield
In acetonitrile at 80℃; under 760.051 Torr; for 0.25h;	90%

: 104-42-7
4-dodecylaniline

: 79-04-9
chloroacetyl chloride

: 2-chloro-N-(4-dodecylphenyl)acetamide

Conditions

Conditions	Yield
Stage #1: 4-dodecylaniline With potassium carbonate In dichloromethane at 20℃; for 0.5h; Stage #2: chloroacetyl chloride In dichloromethane for 4h; Reflux;	89%
Stage #1: chloroacetyl chloride With potassium carbonate In dichloromethane at 20℃; for 0.5h; Stage #2: 4-dodecylaniline In dichloromethane for 4h; Reflux;	89%

: 108-73-6
3,5-dihydroxyphenol

: 104-42-7
4-dodecylaniline

: 1198578-78-7
1,3,5-tris(4-n-dodecylanilino)benzene

Conditions

Conditions	Yield
iodine In toluene at 130℃; for 2h;	87.8%

: 104-42-7
4-dodecylaniline

: 111772-62-4
2-hydroxy-4-n-dodecyloxybenzaldehyde

: 4-(dodecyloxy)-N-(4-dodecyl)-phenyl-2-hydroxybenzaldimine

Conditions

Conditions	Yield
With acetic acid In ethanol for 18h; Reflux;	86%

: 1333471-38-7
trans-(2,6-diformyl-3,5-bis(2,5,8,11-tetraoxadecyl)phenyl)chlorobis(triphenylphosphine)palladium

: 104-42-7
4-dodecylaniline

: 1333471-36-5
(3,5-bis(2,5,8,11-tetraoxadecyl)-2,6-bis(N-4-dodecylphenylimino)phenyl)chloropalladium

Conditions

Conditions	Yield
With (H2N)2CO*H2O2 In acetonitrile (N2); refluxing soln. of palladium compd. and aniline deriv. in anhyd. CH3CN for 72 h, cooling to 25°C, addn. of urea hydrogen peroxide, stirring at 50°C for 11 h; evapn., chromy. (silica gel, 0-5% methanol/ethyl acetate), gel permeating chromy. (CHCl3), elem. anal.;	85%

: 104-42-7
4-dodecylaniline

: 637-44-5
phenylpropyolic acid

: N-(p-dodecylphenyl)-3-phenylpropiolamide

Conditions

Conditions	Yield
Stage #1: 4-dodecylaniline; phenylpropyolic acid With dmap In tetrahydrofuran at 0℃; for 0.166667h; Inert atmosphere; Stage #2: With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In tetrahydrofuran at 20℃; for 5h; Inert atmosphere;	80%

: 104-42-7
4-dodecylaniline

: 147622-34-2
4'-formyl-2-diphenylphosphino-acetophenone

: N-<4-(2-diphenylphosphinoacetyl)benzylidene>-4-(dodecyl)aniline

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In benzene for 2h; Heating;	79%

: 104-42-7
4-dodecylaniline

: 148347-18-6, 139141-81-4
1,2-epox-[60]fullerene

A: 1092060-75-7
1-(4-dodecylanilino)-2-hydroxy-1,2-dihydro[60]fullerene

B: 1092060-70-2
5'-dodecylindolino[2',3':1,2][60]fullerene

Conditions

Conditions	Yield
With sepiolite In chlorobenzene at 100℃;	A n/a B 78%

...Expand

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

: 104-42-7
4-dodecylaniline

: 90850-59-2
(4,6-Dichloro-[1,3,5]triazin-2-yl)-(4-dodecyl-phenyl)-amine

Conditions

Conditions	Yield
With sodium hydroxide In water; acetone 1. 0 deg C, 1 h; 2. 20 deg C, 1 h;	76%

: 872-85-5
pyridine-4-carbaldehyde

: 104-42-7
4-dodecylaniline

: C24H34N2

Conditions

Conditions	Yield
With acetic acid	76%

: 1943-83-5
2-chloroethyl isothiocyanate

: 104-42-7
4-dodecylaniline

: 4-dodecyl-1-[3-(2-chloroethyl)ureido]benzene

Conditions

Conditions	Yield
at 20℃;	74%
for 6h; Ambient temperature;

: 104-42-7
4-dodecylaniline

: 2,6-dibromo-4-dodecylaniline

Conditions

Conditions	Yield
With benzyltriethylammonium tribromide; calcium carbonate In methanol; dichloromethane at 20℃; for 1h;	74%
With hydrogenchloride; bromine In water for 3h;

: 104-42-7
4-dodecylaniline

: 471-25-0
Propiolic acid

: N-(p-dodecylphenyl)propiolamide

Conditions

Conditions	Yield
Stage #1: 4-dodecylaniline; Propiolic acid With dmap In tetrahydrofuran at 0℃; for 0.166667h; Inert atmosphere; Stage #2: With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In tetrahydrofuran at 20℃; for 5h; Inert atmosphere;	74%

: 104-42-7
4-dodecylaniline

: (S)-4-(3,7-dimethyloctyloxy)phenyl 4-formylbenzoate

: (S)-4-(3,7-dimethyloctyloxy)phenyl 4-{[4-(dodecyl)phenylimino]methyl}benzoate

Conditions

Conditions	Yield
With acetic acid In ethanol at 100℃; Inert atmosphere;	73%

: 104-42-7
4-dodecylaniline

: 104010-92-6
2,3-bis(tert-butoxycarbonyl amino)propanoic acid

: di-tert-butyl (3-((4-dodecylphenyl)amino)-3-oxopropane-1,2-diyl)dicarbamate

Conditions

Conditions	Yield
Stage #1: 2,3-bis(tert-butoxycarbonyl amino)propanoic acid With 1-hydroxy-pyrrolidine-2,5-dione; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In chloroform at 20℃; for 2h; Inert atmosphere; Stage #2: 4-dodecylaniline With dmap In chloroform at 50℃; Inert atmosphere;	72%

: 104-42-7
4-dodecylaniline

: 47173-80-8
N-Boc-D-serine(Bzl)-OH

: 448959-69-1
[2-benzyloxy-1-(4-decyl-phenylcarbamoyl)-ethyl]-carbamic acid tert-butyl ester

Conditions

Conditions	Yield
With benzotriazol-1-yloxyl-tris-(pyrrolidino)-phosphonium hexafluorophosphate; N-ethyl-N,N-diisopropylamine	71%

: [Co(2-(phenylazo)pyridine)3](ClO4)2

: 104-42-7
4-dodecylaniline

: Co(NC5H4NNC6H4NC6H4(CH2)11CH3)2(1+)*ClO4(1-)=(Co(NC5H4NNC6H4NC6H4(CH2)11CH3)2)ClO4

Conditions

Conditions	Yield
In neat (no solvent) Co complex mixed with ligand; heated on steam bath for 1 h; purified by preparative TLC (alumina, CHCl3); elem. anal.;	70%

: 13669-05-1
1,4-bis(thiophen-2-yl)butane-1,4-dione

: 104-42-7
4-dodecylaniline

: 499793-93-0
1-(p-dodecylphenyl)-2,5-di(2-thienyl)pyrrole

Conditions

Conditions	Yield
In acetic acid; toluene at 140 - 150℃;	69%

: 104-42-7
4-dodecylaniline

: 891780-19-1
2-bromo-4-dodecylaniline

Conditions

Conditions	Yield
With N-Bromosuccinimide In dichloromethane at 20℃; for 20h;	66%
With sodium perborate; acetic acid; potassium bromide; sodium vanadate at 20℃; for 10h;	59%
With N-Bromosuccinimide; ammonium acetate In acetonitrile at 20℃; for 3h;

: 104-42-7
4-dodecylaniline

: 170698-90-5
1-dodecyl-4-iodobenzene

Conditions

Conditions	Yield
With C5H11NO2; potassium iodide	65%
Stage #1: 4-dodecylaniline With hydrogenchloride; sodium nitrite at 0℃; Stage #2: With potassium iodide at 40℃; for 0.333333h;	49%

: 104-42-7
4-dodecylaniline

: 108-95-2
phenol

: 141510-15-8
4-dodecyl-4’-hydroxyazobenzene

Conditions

Conditions	Yield
Stage #1: 4-dodecylaniline With hydrogenchloride; sodium nitrite In tetrahydrofuran; water at 0℃; for 2h; Inert atmosphere; Stage #2: phenol With sodium carbonate; potassium carbonate In tetrahydrofuran; water at 20℃; for 12h;	65%
With hydrogenchloride; sodium carbonate; sodium nitrite In water
Stage #1: 4-dodecylaniline With hydrogenchloride; sodium nitrite In water at 0℃; for 0.5h; Stage #2: phenol With sodium carbonate In water at 0℃; for 1h;

4-Dodecylaniline Chemical Properties

Product Name: 4-Dodecylaniline
The MF of 4-Dodecylaniline (104-42-7) is C₁₈H₃₁N.

The MW of 4-Dodecylaniline (104-42-7) is 261.45.
Synonyms of 4-Dodecylaniline (104-42-7): 4-Dodecylaniline ; p-Dodecylaniline ; 4-Dodecyl-benzenamin ; 4-N-Dodecylamine ; Benzenamine, 4-dodecyl-
Product Categories: Intermediates of Dyes and Pigments;Alkyl;Alkylanilines;Nitrogen Compounds;Organic Building Blocks;Polyamines
EINECS: 203-201-3
Index of Refraction: 1.508
Density: 0.902 g/ml
Flash Point: 162.7 °C
Boiling Point: 364 °C
Melting Point: 35-39 °C(lit.)

4-Dodecylaniline Uses

4-Dodecylaniline (104-42-7) is used for the manufacture of Kapu Lun Huang 3GS, Kapu Lun pink BS, Kapu Lun blue dye BS, etc.

4-Dodecylaniline Safety Profile

Safety information of 4-Dodecylaniline (104-42-7):
Hazard Codes Xn
Risk Statements
22 Harmful if swallowed
Safety Statements
22 Do not breathe dust
24/25 Avoid contact with skin and eyes
WGK Germany 3

Product Name

4-Dodecylaniline

Synthetic route

4-Dodecylaniline Chemical Properties

4-Dodecylaniline Uses

4-Dodecylaniline Safety Profile

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