Conditions | Yield |
---|---|
With cerium(IV) triflate; water at 20℃; for 22h; | 100% |
With Xylaria polymorpha laccase; 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonate) diammonium salt In 1,4-dioxane at 20℃; for 1.83333h; pH=4.5; Green chemistry; Enzymatic reaction; | 96% |
With cobalt(II) acetate; acetic acid; potassium bromide at 120℃; under 15001.5 Torr; for 2.5h; Reagent/catalyst; Temperature; Pressure; Autoclave; | 95% |
Conditions | Yield |
---|---|
With oxygen; perruthenate modified mesoporous silicate MCM-41 In toluene at 80℃; for 1h; Oxidation; | 100% |
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; oxygen; copper(I) bromide dimethylsulfide complex In chlorobenzene at 90℃; for 6h; | 100% |
With iron(III) chloride; 4-acetylamino-2,2,6,6-tetramethyl-1-piperidinoxy; oxygen; sodium nitrite In 1,2-dichloro-ethane at 50℃; under 3000.3 Torr; for 5h; Autoclave; | 99% |
Conditions | Yield |
---|---|
With phosphoric acid In ethanol at 25℃; for 0.25h; Sonication; Green chemistry; | 99% |
With N,N'-dichlorophenobarbital In acetonitrile at 20℃; for 0.233333h; | 96% |
With water; Dess-Martin periodane In dichloromethane at 5℃; for 0.0333333h; | 95% |
Conditions | Yield |
---|---|
With sodium periodate; C53H44As2N2O3Ru In water; ethyl acetate; acetonitrile at 25℃; for 0.5h; | 99% |
With dihydrogen peroxide In water at 100℃; for 4h; | 92% |
With sodium periodate; C31H29Br2N3Ru*CH2Cl2 In water; ethyl acetate; acetonitrile at 25℃; for 0.5h; Inert atmosphere; Schlenk technique; | 92% |
Conditions | Yield |
---|---|
With methanol; potassium permanganate In ethyl acetate at 25℃; for 20h; | 99% |
Conditions | Yield |
---|---|
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; laccasefrom Trametes versicolor; oxygen In water at 30℃; for 24h; pH=4.5; Enzymatic reaction; | 97% |
With sodium periodate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; acetic acid; trifluoroacetic acid In water; acetonitrile for 20h; | 93% |
With cercosporin; oxygen In methanol at 20℃; Schlenk technique; Irradiation; Green chemistry; chemoselective reaction; | 87% |
(4-fluorophenyl)methylene diacetate
4-fluorobenzaldehyde
Conditions | Yield |
---|---|
With indium(III) bromide; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate at 20℃; for 0.416667h; | 97% |
With bovine liver acetone powder In aq. phosphate buffer; acetone at 20℃; for 0.333333h; pH=7.4; Enzymatic reaction; chemoselective reaction; | 97% |
With sodium hydrogen sulfate; PEG-2000 at 70℃; for 0.416667h; | 95% |
4-fluorobenzylic alcohol
di(p-tolyl) sulfoxide
A
di-(p-tolyl)sulfane
B
4-fluorobenzaldehyde
Conditions | Yield |
---|---|
With per-rhenic acid In toluene for 17h; Reflux; | A 97% B 90% |
Conditions | Yield |
---|---|
With tetrabutyl ammonium fluoride In tetrahydrofuran for 0.166667h; Inert atmosphere; Microwave irradiation; | 95% |
With tetrabutyl ammonium fluoride In tetrahydrofuran for 10h; Inert atmosphere; Reflux; chemoselective reaction; | 82.1 %Chromat. |
Multi-step reaction with 2 steps 1: benzene-d6 / 23 °C / Inert atmosphere 2: benzene-d6 / 2 h / 60 °C View Scheme |
Conditions | Yield |
---|---|
With 1,3-bis(2,6-diisopropylphenyl)-2,2-difluoro-2,3-dihydro-1h-imidazole; cesium fluoride In toluene at 80℃; for 3h; Product distribution / selectivity; Sealed vial; | 95% |
With 1,3-bis(2,6-diisopropylphenyl)-2,2-difluoro-2,3-dihydro-1h-imidazole; cesium fluoride In toluene at 23 - 80℃; for 3.5h; Inert atmosphere; | 95 %Spectr. |
4,4'-difluorodeoxybenzoin
aniline
A
4-fluoro-N-phenylbenzamide
B
4-fluorobenzaldehyde
Conditions | Yield |
---|---|
With 1,10-Phenanthroline; copper(II) chloride dihydrate; oxygen In acetonitrile under 760.051 Torr; for 24h; Reflux; | A 95% B 96 %Chromat. |
Conditions | Yield |
---|---|
With (CH3)2NCH2NpSiH2Ph at 110 - 140℃; | 94% |
With dipotassium hydrogenphosphate; fac-tris(2-phenylpyridinato-N,C2')iridium(III); tris-(trimethylsilyl)silane; dimethyl dicarbonate In acetonitrile at 20℃; for 6h; Schlenk technique; Inert atmosphere; Sealed tube; Irradiation; | 89% |
With palladium(II) acetylacetonate; hydrogen; 2,2-dimethylpropanoic anhydride; dicyclohexylphenylphosphine In tetrahydrofuran at 80℃; under 3750.38 Torr; for 20h; Inert atmosphere; | 80% |
2-(4-fluorophenyl)-1,3-dithiolane
4-fluorobenzaldehyde
Conditions | Yield |
---|---|
With 1,3,5-trichloro-2,4,6-triazine; dimethyl sulfoxide In dichloromethane at 20℃; for 3.5h; | 93% |
Conditions | Yield |
---|---|
With dimethyl sulfoxide at 120℃; for 12h; | 93% |
With dimethyl amine at 60℃; for 0.166667h; | 86% |
1-(dibromomethyl)-4-fluorobenzene
dimethyl sulfoxide
4-fluorobenzaldehyde
Conditions | Yield |
---|---|
at 120℃; for 12h; | 93% |
4-fluoro-1-iodobenzene
carbon monoxide
A
fluorobenzene
B
4-fluorobenzaldehyde
Conditions | Yield |
---|---|
With hydrogen; potassium carbonate In 1,4-dioxane at 120 - 140℃; under 30003 Torr; for 20h; Autoclave; | A 7% B 91% |
Conditions | Yield |
---|---|
With (NH4)4[ZnMo6O18(OH)6]; oxygen In water; acetonitrile at 60℃; under 760.051 Torr; for 12h; | 90% |
With water; sodium hydroxide at 20℃; for 0.0833333h; Microwave irradiation; | 88% |
With bismuth(III) nitrate; tetrabutyl ammonium fluoride at 100℃; for 4h; | 87% |
Conditions | Yield |
---|---|
With 1H-imidazole; C17H16ClMnN2O2; tetrabutylammonium periodite In chloroform at 20℃; for 0.416667h; | 90% |
With potassium 12-tungstocobaltate(III) In water; acetonitrile for 0.3h; Microwave irradiation; | 90% |
With 1H-imidazole; [bis(acetoxy)iodo]benzene; Co(AAOPD) In acetonitrile at 20℃; for 5h; | 89% |
α,α-dimethoxy-4-fluorotoluene
4-fluorobenzaldehyde
Conditions | Yield |
---|---|
perchloric acid In methanol; water at 25 - 30℃; for 0.166667h; | 90% |
With water In methanol at 25 - 30℃; for 0.166667h; | 90% |
Conditions | Yield |
---|---|
With dimethyl amine at 60℃; for 0.166667h; | 89% |
With sodium perchlorate; water In acetonitrile at 25℃; Kinetics; | |
Multi-step reaction with 2 steps 1: 94 percent / 14 h / 70 °C 2: H2O / Acid hydrolysis View Scheme |
(±)-2-[(4-fluorobenzyl)oxy]tetrahydropyran
4-fluorobenzaldehyde
Conditions | Yield |
---|---|
With 1-n-butylpyridinium tetrachloroferrate; pyridinium chlorochromate at 50℃; for 0.166667h; | 89% |
With trichloroisocyanuric acid In acetonitrile Reflux; |
Conditions | Yield |
---|---|
With N,N,N,N,-tetramethylethylenediamine; hydrogen; palladium diacetate; propyl di-tert-butylphosphinite In toluene at 100℃; under 3750.38 Torr; for 20h; Inert atmosphere; | 88% |
With 4-methoxy-N'-tetramethylethylenediamine; hydrogen; catacxium A; palladium diacetate In toluene at 100℃; under 3750.3 Torr; for 16h; | 89 % Chromat. |
With N,N,N,N,-tetramethylethylenediamine; hydrogen; catacxium A; palladium diacetate In toluene at 100℃; under 3750.38 Torr; for 16h; | 89 % Chromat. |
With N,N,N,N,-tetramethylethylenediamine; C6H6*C48H78O2P2Pd; hydrogen In toluene at 20 - 100℃; under 3750.38 Torr; Inert atmosphere; Autoclave; | 95 %Chromat. |
With N,N,N,N,-tetramethylethylenediamine; hydrogen; palladium diacetate; catacxium A In toluene at 120℃; under 9000.9 Torr; Flow reactor; Green chemistry; | 86 %Chromat. |
Conditions | Yield |
---|---|
With dichloro [1,1'-bis(diphenylphosphino)propane]palladium(II); 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide at 80℃; under 7500.75 Torr; for 20h; Autoclave; Green chemistry; | 88% |
With rhodium(III) iodide; hydrogen; acetic anhydride; triethylamine; triphenylphosphine In N,N-dimethyl acetamide at 100℃; for 24h; Autoclave; | 84% |
With carbon supported Pd nanoparticles; 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 80℃; under 7500.75 Torr; for 12h; Sealed tube; Green chemistry; | 76% |
Conditions | Yield |
---|---|
With rhodium(III) chloride trihydrate; hydrogen; triethylamine; triphenylphosphine In N,N-dimethyl acetamide at 90℃; under 7500.75 Torr; for 12h; Autoclave; | 88% |
Conditions | Yield |
---|---|
With pyridine; 1,3-bis-(diphenylphosphino)propane; hydrogen; palladium diacetate In dimethyl sulfoxide at 120℃; under 15001.5 Torr; for 0.716667h; Flow reactor; | 87% |
Conditions | Yield |
---|---|
With C25H19(1+)*BF4(1-) In dichloromethane at 20℃; for 1.5h; Reagent/catalyst; Schlenk technique; Inert atmosphere; | A 86% B 22% |
Conditions | Yield |
---|---|
Stage #1: 4-fluorobenzonitrile With diisobutylaluminium hydride In toluene at 0℃; for 0.00555556h; Flow reactor; Stage #2: With water; sodium L-tartrate In toluene at 0℃; chemoselective reaction; | 85% |
With lithium diisobutyl-iso-propoxyaluminium hydride In tetrahydrofuran; hexane at 20℃; for 1h; | 99 %Chromat. |
With lithium diisobutylmorpholinoaluminum hydride In tetrahydrofuran; hexane at 0℃; for 0.5h; | 99 %Chromat. |
4-fluorobenzaldehyde
Conditions | Yield |
---|---|
With methanol; sodium tetrahydroborate; nickel(II) chloride hexahydrate at 20℃; for 1.5h; | 85% |
With eosin Y disodium salt In acetonitrile at 20℃; for 3h; Irradiation; | 50% |
4-fluorobenzaldehyde
4-fluoro-3-nitrobenzaldehyde
Conditions | Yield |
---|---|
With sulfuric acid; nitric acid | 100% |
With sulfuric acid; nitric acid at 20℃; for 3h; | 99% |
With sulfuric acid; nitric acid at -5 - 20℃; for 1h; | 98% |
morpholine
4-fluorobenzaldehyde
(4-fluorophenyl)(morpholino)methane thione
Conditions | Yield |
---|---|
With sulfur In N,N-dimethyl-formamide at 110℃; for 2.5h; | 100% |
With sulfur In neat (no solvent) at 100℃; for 2h; Kindler Reaction; Green chemistry; | 96% |
With sulfur In dimethyl sulfoxide at 20℃; for 6h; | 81% |
With sulfur In N,N-dimethyl-formamide for 0.0333333h; Microwave irradiation; | 80% |
With toluene-4-sulfonic acid; sulfur at 60℃; for 4h; |
Conditions | Yield |
---|---|
With 1-(3-silica-supported propyl)-3-[(3-{[1-(3-silica-supported propyl)-4,5-dihydro-1H-imidazol-3-ium-3-yl]methyl}-2,4,6-trimethylphenyl)methyl]-4,5-dihydro-1H-imidazol-3-ium chloride at 100℃; for 4h; Knoevenagel condensation; | 100% |
With 2C9H3O6(3-)*2C27H18N6*3Ni(2+)*15H2O*5C2H6O In dichloromethane at 60℃; for 2h; Knoevenagel Condensation; Inert atmosphere; | 100% |
With N,N-dimethyl-N-hydroxyethylammonium acetate at 20℃; for 0.0333333h; Knoevenagel Condensation; | 99% |
acetic anhydride
4-fluorobenzaldehyde
(4-fluorophenyl)methylene diacetate
Conditions | Yield |
---|---|
With titanium tetrachloride at 20℃; for 16h; screw-capped vial; Inert atmosphere; neat (no solvent); | 100% |
With indium(III) bromide at 20℃; for 0.333333h; | 98% |
With tetrafluoroboric acid at 20℃; for 0.0333333h; | 98% |
trimethylsilyl cyanide
4-fluorobenzaldehyde
2-(4-fluorophenyl)-2-(trimethylsilyloxy)acetonitrile
Conditions | Yield |
---|---|
With triethylamine at 20℃; for 24h; | 100% |
With C42H50Mg2N4 In benzene-d6 at 25℃; Glovebox; Inert atmosphere; | 99% |
at 100℃; for 6h; Glovebox; | 99% |
potassium cyanide
aniline hydrochloride
4-fluorobenzaldehyde
2-(4-fluorophenyl)-2-(phenylamino) acetonitrile
Conditions | Yield |
---|---|
In ethanol; water 1.) 1 h cooling; 2.) 20 h room temperature; | 100% |
4-fluorobenzaldehyde
4-methoxy-aniline
N-(4-fluorobenzylidene)-4-methoxyaniline
Conditions | Yield |
---|---|
In ethanol for 1h; Sonication; | 100% |
at 90 - 120℃; Irradiation; | 98% |
With magnesium sulfate In dichloromethane for 15h; Ambient temperature; | 86% |
Conditions | Yield |
---|---|
With magnesium sulfate In dichloromethane; water at 24.84℃; for 4h; | 100% |
In diethyl ether for 2h; | 74% |
Conditions | Yield |
---|---|
In benzene at 80℃; for 2h; | 100% |
In neat (no solvent) at 60℃; for 0.0666667h; Microwave irradiation; | 98% |
In diethyl ether Ambient temperature; | 87% |
4-fluorobenzaldehyde
ethyl 2-cyanoacetate
ethyl (E)-2-cyano-3-(4-fluorophenyl)-2-propenoate
Conditions | Yield |
---|---|
With 1-(3-silica-supported propyl)-3-[(3-{[1-(3-silica-supported propyl)-4,5-dihydro-1H-imidazol-3-ium-3-yl]methyl}-2,4,6-trimethylphenyl)methyl]-4,5-dihydro-1H-imidazol-3-ium chloride at 130℃; for 2h; Knoevenagel condensation; | 100% |
With polyacrylonitrile fiber functionalized with N,N-dimethyl-1,3-propanediamine In ethanol for 1.5h; Knoevenagel condensation; Reflux; | 99% |
With N-(propylcarbamoyl)sulfamic acid bonded on silica at 100℃; for 0.25h; | 97% |
Conditions | Yield |
---|---|
With sodium hydroxide In water at 65℃; for 2h; | 100% |
With sodium hydroxide In ethanol; water at 20℃; Claisen-Schmidt Condensation; Inert atmosphere; | 98% |
With sodium hydroxide In water at 4 - 20℃; for 2h; Claisen-Schmidt condensation; Inert atmosphere; | 87% |
4-fluorobenzaldehyde
benzylamine
N-(4-fluorophenylmethylene)-benzylamine
Conditions | Yield |
---|---|
for 6h; Molecular sieve; Reflux; | 100% |
With sodium sulfate In dichloromethane for 1h; Ambient temperature; | 88.6% |
With magnesium sulfate In dichloromethane Molecular sieve; Inert atmosphere; | 58% |
4-fluorobenzaldehyde
2-Methylacetophenone
Conditions | Yield |
---|---|
With sodium ethanolate In ethanol | 100% |
With sodium ethanolate In ethanol for 16h; Ambient temperature; |
Conditions | Yield |
---|---|
With sodium tetrahydroborate In methanol at 20℃; for 1h; | 100% |
With C24H30Cl2NPRuS2; potassium tert-butylate; hydrogen In dichloromethane; toluene at 80℃; under 15001.5 Torr; for 5h; Autoclave; | 100% |
With C55H44O2P4Ru; hydrogen In toluene at 80℃; under 38002.6 Torr; for 18h; Glovebox; Autoclave; | 99% |
4-fluorobenzaldehyde
di[1-hydroxy(4-fluorophenyl)methyl]peroxide
Conditions | Yield |
---|---|
With dihydrogen peroxide for 1h; Ambient temperature; | 100% |
With dihydrogen peroxide In water at 0 - 20℃; | 98% |
cyclohexanone
4-fluorobenzaldehyde
2-(4-fluorobenzylidene)cyclohexanone
Conditions | Yield |
---|---|
sodium hydroxide In water at 90 - 95℃; for 3h; | 100% |
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 120℃; for 4.5h; Substitution; | 100% |
Stage #1: thiophenol With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 0.25h; Stage #2: 4-fluorobenzaldehyde In N,N-dimethyl-formamide at 80℃; for 6h; | 96% |
With potassium carbonate In dimethyl sulfoxide for 1h; Reflux; | 92% |
isovanillin
4-fluorobenzaldehyde
3-(4-formylphenoxy)-4-methoxybenzaldehyde
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide for 18h; Reflux; | 100% |
With potassium carbonate In N,N-dimethyl-formamide at 80℃; Inert atmosphere; | 89% |
With potassium carbonate In N,N-dimethyl-formamide for 4h; Heating; | 80% |
Conditions | Yield |
---|---|
(1S)-1-(9-piperidylfluoren-9-yl)ethanol In hexane; toluene at 0℃; for 4h; Addition; | 100% |
Stage #1: diethylzinc In toluene at 0℃; for 0.5h; Inert atmosphere; Stage #2: 4-fluorobenzaldehyde In toluene at 0℃; for 6h; Inert atmosphere; Stage #3: With ammonium chloride In water; toluene at 0℃; Inert atmosphere; optical yield given as %ee; enantioselective reaction; | 92% |
Stage #1: diethylzinc With (Sa)-1-[2-diphenylhydroxymethyl-6-(trifluoromethyl)phenyl]-2-(1-pyrrolidinomethyl)-1H-pyrrole In hexane at 20℃; for 1h; Inert atmosphere; Stage #2: 4-fluorobenzaldehyde In hexane at 0℃; for 16h; Inert atmosphere; enantioselective reaction; | 91% |
hexamethylene imine
4-fluorobenzaldehyde
4-(hexamethylenimin-1-yl)benzaldehyde
Conditions | Yield |
---|---|
In acetonitrile for 16h; Heating / reflux; | 100% |
With potassium carbonate In dimethyl sulfoxide for 0.25h; ultrasound; | 95% |
With tetrabutylammomium bromide; potassium carbonate In dimethyl sulfoxide at 90℃; for 48h; | 83% |
4-fluorobenzaldehyde
1,2-bis(4-fluorophenyl)-1,2-ethanediol
Conditions | Yield |
---|---|
With (t-BuOK)3FeK; magnesium In tetrahydrofuran at 20℃; for 12h; | 100% |
With aluminium; potassium hydroxide In methanol at 0℃; for 1h; Inert atmosphere; | 100% |
With ZnIn2S4; triethylamine In water; acetonitrile for 0.5h; Sealed tube; Sonication; Irradiation; Inert atmosphere; | 99% |
4-fluorobenzaldehyde
acrylic acid methyl ester
methyl 3-(4-fluorophenyl)-3-hydroxy-2-methylenepropanoate
Conditions | Yield |
---|---|
With 1,4-diaza-bicyclo[2.2.2]octane at 20℃; for 3.5h; Baylis-Hillman reaction; neat (no solvent); | 100% |
With 1,4-diaza-bicyclo[2.2.2]octane; 1-n-butyl-2,3-dimethylimidazolium hexafluorophosphate at 20℃; for 24h; Baylis-Hillman; | 99% |
With 1,4-diaza-bicyclo[2.2.2]octane In methanol at 0℃; for 48h; Baylis-Hillman reaction; | 99% |
Conditions | Yield |
---|---|
With sodium hydroxide; hydroxylamine hydrochloride In ethanol for 3h; | 100% |
With hydroxylamine hydrochloride In tetrahydrofuran; etanol; water at 20℃; for 0.416667h; | 100% |
With hydroxylamine hydrochloride; sodium carbonate In ethanol at 20℃; | 100% |
4-fluorobenzaldehyde
[(4-fluorophenyl)methylidene]hydrazine
Conditions | Yield |
---|---|
With hydrazine hydrate In ethanol for 1h; Reflux; Inert atmosphere; | 100% |
With hydrazine hydrate In methanol at 20℃; for 1h; | 99% |
With hydrazine hydrate In ethanol |
4-fluorobenzaldehyde
allyl alcohol
1-(4-fluorophenyl)-3-buten-1-ol
Conditions | Yield |
---|---|
With indium(III) chloride; indium; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; water at 20℃; for 20h; | 100% |
4-fluorobenzaldehyde
ethyl (triphenylphosphoranylidene)acetate
ethyl 4-fluorocinnamate
Conditions | Yield |
---|---|
In dichloromethane at 20 - 25℃; for 16h; Inert atmosphere; | 100% |
In dichloromethane at 20℃; for 16h; | 98% |
In dichloromethane at 20℃; | 93% |
4-fluorobenzaldehyde
2-(4-(3,4-dichlorophenyl)piperazino)-4-hydroxy-1,6-dihydro-6-oxopyridine-3-carboxylic acid ethyl ester
Conditions | Yield |
---|---|
With piperidine In ethanol for 3h; Heating; | 100% |
4-fluorobenzaldehyde
thiophenol
1-((4-fluorophenyl)(phenylthio)methylthio)benzene
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In toluene at 120℃; for 15h; Inert atmosphere; Schlenk technique; | 100% |
In chloroform at 20℃; | 77% |
With boron trifluoride diethyl etherate In chloroform at 25℃; for 1h; | 75% |
IUPAC Name: 4-Fluorobenzaldehyde
Synonyms of 4-Fluorobenzaldehyde (CAS NO.459-57-4): 4-Fluorbenzolcarbaldehyd ; 4-Fluorobenzaldehyde ; Benzaldehyde, 4-fluoro- ; 4-Fluorobenzaldehyde 99%
Molecular Structure:
Molecular Formula : C7H5FO
Molecular Weight: 124.11
CAS NO: 459-57-4
EINECS : 207-293-6
H bond acceptors: 1
H bond donors: 0
Freely Rotating Bonds: 1
Polar Surface Area: 17.07 Å2
Index of Refraction: 1.539
Molar Refractivity: 32.99 cm3
Molar Volume: 105.3 cm3
Index of Refraction: 1.539
Surface Tension: 36.8 dyne/cm
Density: 1.178 g/cm3
Flash Point: 56.7 °C
Enthalpy of Vaporization: 41.83 kJ/mol
Boiling Point: 182 °C at 760 mmHg
Vapour Pressure: 0.828 mmHg at 25°C
Melting point : -10 ºC
Water solubility: Immiscible.
Sensitive : Air Sensitive
SMILES: O=Cc1ccc(F)cc1
InChI: InChI=1/C7H5FO/c8-7-3-1-6(5-9)2-4-7/h1-5H
InChIKey: UOQXIWFBQSVDPP-UHFFFAOYAW
Std. InChI: InChI=1S/C7H5FO/c8-7-3-1-6(5-9)2-4-7/h1-5H
Std. InChIKey: UOQXIWFBQSVDPP-UHFFFAOYSA-N
Product Categories of of 4-Fluorobenzaldehyde (CAS NO.459-57-4): Fluoro-Aromatics;Benzaldehyde;Fluorobenzene;Adehydes, Acetals & Ketones;Fluorine Compounds;Atorvastatin Calcium;Pharmaceutical Intermediate;Aldehydes;C7;Carbonyl Compounds
4-Fluorobenzaldehyde (CAS NO.459-57-4) is an important intermediates of medicine, dye and pesticide.
With p-Chlorotoluene as raw material, first fluorination by Potassium fluoride to generate Fluorotoluene, and then chlorination of methyl to produce 4-Fluoro-benzylidene dichloride, and then hydrolysis , p-Fluorobenzaldehyde is obtained.
Hazard Codes: Xi,F
Risk Statements: 36/37/38
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36/37/39-27
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S27: Take off immediately all contaminated clothing.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
RIDADR: UN 1989 3/PG 3
WGK: Germany 2
F: 9-23
Hazard Note: Flammable
TSCA: T
HazardClass: 3.2
PackingGroup: III
HS Code: 29130000
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