6-Undecanone supplier | CasNO.927-49-1

Name
6-Undecanone
EINECS 213-150-9
CAS No. 927-49-1
Article Data104
CAS DataBase
Density 0.831
Solubility Insoluble

Melting Point 14 - 15 C

Formula C11H22 O

Boiling Point 228 C

Molecular Weight 170.295

Flash Point 88 ºC

Transport Information 160kgs

Appearance colorless to pale yellow liquid

Safety 24/25

Risk Codes R23/25;

Molecular Structure

Hazard Symbols 3 (Packing Group: III) UN NO.

Synonyms Amylketone; Diamyl ketone; Dipentyl ketone; Pentyl ketone

PSA 17.07000

LogP 3.71610

Synthetic route

947-31-9
2,2-dipentyl-[1,3]dioxolane

927-49-1
dipentyl ketone

Conditions

Conditions Yield

With O-phenyl phosphorodichloridate; sodium iodide In benzene for 16h; Heating; 100%

23708-56-7
6-undecanol

927-49-1
dipentyl ketone

Conditions

Conditions Yield

With iodine; potassium carbonate In tert-butyl alcohol at 90℃; for 5h; 99%

With 4-hydroxy-TEMPO benzoate; sodium bromide In dichloromethane; water at 20 - 25℃; NaHCO3-buffered at pH 8.6; electrolysis; 91%

With ruthenium(IV) oxide; tetrabutylammomium bromide; tetra(n-butyl)ammonium hydroxide In water; acetonitrile electrooxidation on Pt electrodes; 87.6%

2,2-Dipentyl-[1,3]dioxane

927-49-1
dipentyl ketone

Conditions

Conditions Yield

With O-phenyl phosphorodichloridate; sodium iodide In benzene for 36h; Heating; 93%

100009-30-1
Trimethyl-(1-pentyl-hexyloxy)-silane

927-49-1
dipentyl ketone

Conditions

Conditions Yield

With potassium fluoride; jones reagent In acetone at 0℃; for 1h; 91%

6-(phenyldimethyl)-6-undecanol

927-49-1
dipentyl ketone

Conditions

Conditions Yield

With jones reagent In diethyl ether 90%

142-62-1
hexanoic acid

927-49-1
dipentyl ketone

Conditions

Conditions Yield

manganese(IV) oxide; aluminum oxide Heating; 87%

With zinc at 300℃;

With cadmium at 270 - 280℃;

13464-19-2
phenyl chlorothioformate

693-25-4
n-pentylmagnesium bromide

927-49-1
dipentyl ketone

Conditions

Conditions Yield

With 1,2-bis(diphenylphosphino)ethane nickel(II) chloride; iron(III)-acetylacetonate In tetrahydrofuran 1) r.t. 2) 0 deg C; a new and mild method for preparation of ketones which provides other symmetrical and unsymmetrical ketones using other Grignard reagents; 87%

1,2-bis(diphenylphosphino)ethane nickel(II) chloride; iron(III)-acetylacetonate In tetrahydrofuran 58 % Chromat.

tert-butyl (2-hydroxy-2-pentylheptyl)(methyl)carbamate

927-49-1
dipentyl ketone

Conditions

Conditions Yield

With 2,4,6-Triisopropylthiophenol; [Ir(2-(2,4-difluorophenyl)-4-(trifluoromethyl)pyridine)2(5,5'-bis(trifluoromethyl)-2,2'-bipyridine)]PF6; tetrabutylphosphonium diphenyl phosphate at 20℃; for 24h; Glovebox; Sealed tube; Irradiation; 87%

693-25-4
n-pentylmagnesium bromide

142-61-0
Hexanoyl chloride

927-49-1
dipentyl ketone

Conditions

Conditions Yield

iron(III)-acetylacetonate In tetrahydrofuran for 0.166667h; Ambient temperature; 82%

27970-82-7
5-hydroxymethyl-6-undecanone

927-49-1
dipentyl ketone

Conditions

Conditions Yield

With fluorous-organic hybrid ether, F-626 at 200℃; for 5h; Inert atmosphere; 79%

tert-butyl (2-hydroxy-2-pentylheptyl)carbamate

927-49-1
dipentyl ketone

Conditions

Conditions Yield

With 2,4,6-Triisopropylthiophenol; [Ir(2-(2,4-difluorophenyl)-4-(trifluoromethyl)pyridine)2(5,5'-bis(trifluoromethyl)-2,2'-bipyridine)]PF6; tetrabutylphosphonium diphenyl phosphate at 20℃; for 24h; Glovebox; Sealed tube; Irradiation; 78%

6-(3-methylbut-2-en-1-yl)undecan-6-ol

927-49-1
dipentyl ketone

Conditions

Conditions Yield

With 2,4,6-Triisopropylthiophenol; [Ir(2-(2,4-difluorophenyl)-4-(trifluoromethyl)pyridine)2(5,5'-bis(trifluoromethyl)-2,2'-bipyridine)]PF6; tetrabutylphosphonium diphenyl phosphate at 20℃; for 24h; Glovebox; Sealed tube; Irradiation; 70%

693-25-4
n-pentylmagnesium bromide

64214-56-8
N-methoxy-N-methyl hexanamide

927-49-1
dipentyl ketone

Conditions

Conditions Yield

In tetrahydrofuran at 0 - 20℃; for 4h; Inert atmosphere; 66%

In tetrahydrofuran at 0 - 20℃; for 4h; Inert atmosphere; 66%

Benzoic acid 1-butyl-2-oxo-heptyl ester

927-49-1
dipentyl ketone

Conditions

Conditions Yield

With 4-methyl-morpholine; 1.3-propanedithiol; tetrabutyl ammonium fluoride In tetrahydrofuran for 3h; Ambient temperature; 62%

628-17-1
amyl iodide

Fe(CO)5

Fe(CO)5

A

927-49-1
dipentyl ketone

B

66-25-1
hexanal

Conditions

Conditions Yield

With tetra-(n-butyl)ammonium iodide; tetraethylammonium tosylate In acetonitrile Ambient temperature; stainless steel plate cathode, Pt anode, 50 mA; A 1%
B 61%

With tetra-(n-butyl)ammonium iodide; tetraethylammonium tosylate In various solvent(s) Ambient temperature; stainless steel plate cathode, Pt anode, 50 mA; A 7%
B 22%

...Expand

627-31-6
1,3-Diiodopropane

6,6-dihydroperoxyundecane

A

927-49-1
dipentyl ketone

B

3,3-dipentyl-[1,2,4,5]tetroxocane

Conditions

Conditions Yield

With silver(l) oxide In ethyl acetate A n/a
B 58%

...Expand

628-17-1
amyl iodide

A

927-49-1
dipentyl ketone

B

66-25-1
hexanal

Conditions

Conditions Yield

In acetonitrile Ambient temperature; electrochemical synthesis: divided cell, Pt plate electrodes, -2.30 V vs Ag/Ag(+), I as supporting electrolyte; A n/a
B 57%

...Expand

102-82-9
tributyl-amine

67-64-1
acetone

A

110-43-0
n-pentyl methyl ketone

B

927-49-1
dipentyl ketone

Conditions

Conditions Yield

With 5%-palladium/activated carbon In toluene at 120℃; for 40h; regioselective reaction; A 9%
B 55%

...Expand

110-43-0
n-pentyl methyl ketone

71-36-3
butan-1-ol

927-49-1
dipentyl ketone

Conditions

Conditions Yield

With potassium hydroxide; 1-dodecene; tris(triphenylphosphine)ruthenium(II) chloride In 1,4-dioxane at 80℃; for 20h; 50%

104-61-0
γ-nonalactone

142-62-1
hexanoic acid

A

927-49-1
dipentyl ketone

B

(9E)-tetradec-9-en-6-one

Conditions

Conditions Yield

pumice; zinc diacetate; manganese(II) acetate at 450℃; A 50%
B 5%

...Expand

699-61-6
1-oxaspiro[4.5]decan-2-one

142-62-1
hexanoic acid

A

927-49-1
dipentyl ketone

B

1-(cyclohex-1-en-1-yl)octan-3-one

Conditions

Conditions Yield

pumice; zinc diacetate; manganese(II) acetate at 450℃; A 50%
B 21%

...Expand

2051-49-2
n-hexanoic anhydride

927-49-1
dipentyl ketone

Conditions

Conditions Yield

With [2,2]bipyridinyl; (1,2-dimethoxyethane)dichloronickel(II); Ir[dF(OMe)ppy]2-(dtbbpy)PF6; 1,8-diazabicyclo[5.4.0]undec-7-ene In 1,4-dioxane at 25℃; for 36h; Sealed tube; Inert atmosphere; Irradiation; 48%

With boron trifluoride Erwaermen mit wss.Natriumacetat-Loesung;

111-14-8
oenanthic acid

142-62-1
hexanoic acid

A

6064-27-3
dodecan-6-one

B

927-49-1
dipentyl ketone

C

462-18-0
tridecan-7-one

Conditions

Conditions Yield

With zirconium(IV) oxide at 450℃; under 760.051 Torr; Inert atmosphere; Flow reactor; A 48%
B 25%
C 22%

With cerium(IV) oxide; water at 450℃; Mechanism; Reagent/catalyst; Flow reactor; A 47%
B 22%
C 24%

...Expand

91153-65-0
C5H11ClMn

72531-43-2
C9H16O4

A

123-66-0
Ethyl hexanoate

B

927-49-1
dipentyl ketone

Conditions

Conditions Yield

In tetrahydrofuran; diethyl ether at -20 - 20℃; A n/a
B 45%

In tetrahydrofuran at -20 - 20℃; A n/a
B 42%

...Expand

91153-65-0
C5H11ClMn

72531-43-2
C9H16O4

927-49-1
dipentyl ketone

Conditions

Conditions Yield

In tetrahydrofuran; diethyl ether at 20℃; Product distribution; other cosolvents and ratios of solvents and organomanganese; 45%

64-17-5
ethanol

67-64-1
acetone

71-36-3
butan-1-ol

A

110-43-0
n-pentyl methyl ketone

B

4485-09-0
nonan-4-one

C

927-49-1
dipentyl ketone

Conditions

Conditions Yield

With Pd supported on Na and Ca basified SiO2 Reagent/catalyst; A 32.3%
B 6.6%
C 42.1%

at 249.84℃; for 2h; Reagent/catalyst; A 12.2%
B 6.3%
C 21.8%

With potassium phosphate; 5%-palladium/activated carbon In toluene at 160℃; for 20h; Product distribution / selectivity; Sealed tube; A 20.7 %Chromat.
B 15.6 %Chromat.
C 31.7 %Chromat.

With potassium phosphate; 5%-palladium/activated carbon In toluene at 145℃; for 10h; Product distribution / selectivity; Sealed tube; A 6.5 %Chromat.
B 23.2 %Chromat.
C 63.7 %Chromat.

With potassium phosphate; 5%-palladium/activated carbon In toluene at 145℃; for 30h; Product distribution / selectivity; Sealed tube; A 28.6 %Chromat.
B 6.4 %Chromat.
C 15.8 %Chromat.

...Expand

64-17-5
ethanol

67-64-1
acetone

71-36-3
butan-1-ol

A

110-43-0
n-pentyl methyl ketone

B

927-49-1
dipentyl ketone

Conditions

Conditions Yield

With Pd supported on Na and Ca basified SiO2 Reagent/catalyst; A 41%
B 22%

With Mg-Al hydrotalcite at 249.84℃; for 2h; Reagent/catalyst; A 6%
B 20%

With potassium phosphate; 5%-palladium/activated carbon In Phthalic acid dibutyl ester at 145℃; for 20h; Product distribution / selectivity; Sealed tube; A 10.3 %Chromat.
B 14.2 %Chromat.

...Expand

111-71-7
heptanal

142-62-1
hexanoic acid

A

6064-27-3
dodecan-6-one

B

927-49-1
dipentyl ketone

C

462-18-0
tridecan-7-one

Conditions

Conditions Yield

With zirconium(IV) oxide at 450℃; under 760.051 Torr; Inert atmosphere; Flow reactor; A 16%
B 40%
C 22%

With cerium(IV) oxide; water at 450℃; Mechanism; Reagent/catalyst; Flow reactor; A 22%
B 40%
C 26%

...Expand

3021-89-4
2-pentyl-2-nonenal

66-25-1
hexanal

A

6064-27-3
dodecan-6-one

B

927-49-1
dipentyl ketone

Conditions

Conditions Yield

With zirconium(IV) oxide; water at 450℃; under 760.051 Torr; for 2h; Inert atmosphere; Calcination; A 6.5%
B 29.7%

...Expand

111-71-7
heptanal

66-25-1
hexanal

A

6064-27-3
dodecan-6-one

B

927-49-1
dipentyl ketone

Conditions

Conditions Yield

With zirconium(IV) oxide; water at 450℃; under 760.051 Torr; for 2h; Inert atmosphere; Calcination; Flow reactor; A 7.8%
B 29.2%

...Expand

927-49-1
dipentyl ketone

109-77-3
malononitrile

13017-59-9
2-(1-pentyl-hexylidene)-malononitrile

Conditions

Conditions Yield

100%

With 5% active carbon-supported ruthenium In ethanol at 78℃; for 18h; 94.7%

With ammonium acetate; acetic acid

927-49-1
dipentyl ketone

124-68-5
2-Amino-2-methyl-1-propanol

174153-09-4
4,4-dimethyl-2,2-dipentyloxazolidine

Conditions

Conditions Yield

With toluene-4-sulfonic acid In toluene Heating; 100%

124-48-1
chlorodibromomethane

927-49-1
dipentyl ketone

258504-49-3
6-(Dibromochloromethyl)undecan-6-ol

Conditions

Conditions Yield

Stage #1: chlorodibromomethane With lithium diisopropyl amide In tetrahydrofuran; hexane at -100℃; for 0.166667h; Metallation;
Stage #2: dipentyl ketone With boron trifluoride diethyl etherate In tetrahydrofuran; diethyl ether; hexane at -90℃; for 4h; Addition; 100%

927-49-1
dipentyl ketone

32504-26-0
6-(hydroxyimino)undecane

Conditions

Conditions Yield

With hydroxylamine hydrochloride; sodium hydrogencarbonate In methanol; water at 20 - 25℃; for 24h; 99%

With pyridine; hydroxylamine hydrochloride In ethanol at 100℃; 99%

With sodium hydroxide; hydroxylamine; tert-butylamine hydrochloride In water; isopropyl alcohol for 2h; Ambient temperature; 89%

With sodium hydroxide; hydroxylamine hydrochloride

With hydroxylamine hydrochloride

927-49-1
dipentyl ketone

cyclodibromodi-μ-methylene<μ-(tetrahydrofuran)>trizinc

cyclodibromodi-μ-methylene<μ-(tetrahydrofuran)>trizinc

17799-46-1
6-Methyleneundecane

Conditions

Conditions Yield

With boron trifluoride diethyl etherate; titanium chloride In tetrahydrofuran at 0 - 20℃; 99%

927-49-1
dipentyl ketone

1066-54-2
trimethylsilylacetylene

928653-17-2
3-pentyl-1-trimethylsilanyl-oct-1-yn-3-ol

Conditions

Conditions Yield

Stage #1: trimethylsilylacetylene With n-butyllithium; N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran; hexane at -78℃; for 2h;
Stage #2: dipentyl ketone In tetrahydrofuran; hexane at -78℃; for 4h; 98%

927-49-1
dipentyl ketone

540-63-6
ethane-1,2-dithiol

103383-69-3
2,2-di-n-pentyl-1,3-dithiolane

Conditions

Conditions Yield

With boron trifluoride diacetate for 0.25h; 97%

With toluene-4-sulfonic acid In benzene Heating;

927-49-1
dipentyl ketone

33788-00-0
6-aminoundecane

Conditions

Conditions Yield

Stage #1: dipentyl ketone With ammonium acetate In methanol at 20℃; for 1.5h; Inert atmosphere;
Stage #2: With sodium cyanoborohydride In methanol for 56h; 96%

With ammonia; hydrogen In methanol at 90℃; under 15001.5 Torr; for 8h; 77%

benzylamine In palladium-carbon 38%

927-49-1
dipentyl ketone

23708-56-7
6-undecanol

Conditions

Conditions Yield

With (triphenylphosphine)copper(I) hydride hexamer; hydrogen; Dimethyl(phenyl)phosphine In tert-butyl alcohol; benzene at 20℃; under 760 Torr; for 12h; Hydrogenation; 95%

With sodium tetrahydroborate In tetrahydrofuran; methanol at 0 - 20℃; for 2h; 93%

With methanol; sodium tetrahydroborate In tetrahydrofuran at 0 - 20℃; for 2h; 93%

927-49-1
dipentyl ketone

603045-12-1
(S)-(but-3-yn-2-yloxy)(tert-butyl)diphenylsilane

674368-39-9
(S)-4-(tert-butyldiphenylsiloxy)-1,1-dipentyl-2-pentyn-1-ol

Conditions

Conditions Yield

Stage #1: (S)-(but-3-yn-2-yloxy)(tert-butyl)diphenylsilane With n-butyllithium; N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran at -78℃; for 2h;
Stage #2: dipentyl ketone In tetrahydrofuran at -78℃; for 4h; 95%

927-49-1
dipentyl ketone

100-97-0
hexamethylenetetramine

1053242-57-1
5,7-dibutyl-1,3-diazatricyclo[3.3.1.13,7]decan-6-one

Conditions

Conditions Yield

With acetic acid In ethanol for 120h; Heating; 95%

With acetic acid In ethanol for 15h; Mannich Aminomethylation; Reflux;

927-49-1
dipentyl ketone

16466-97-0, 13254-27-8
1-propynylmagnesium bromide

C14H26O

Conditions

Conditions Yield

In tetrahydrofuran at 0 - 20℃; Inert atmosphere; 94%

927-49-1
dipentyl ketone

24824-93-9
chloromethyl p-tolyl sulfoxide

159763-19-6
6-[Chloro-(toluene-4-sulfinyl)-methyl]-undecan-6-ol

Conditions

Conditions Yield

With n-butyllithium; diisopropylamine In tetrahydrofuran at -65℃; for 0.416667h; 93%

With lithium diisopropyl amide 1.) THF, -78 deg C, 10 min, 2.) THF, -78 deg C, 10 min.; Yield given. Multistep reaction;

927-49-1
dipentyl ketone

42330-12-1
5-bromo-6-undecanone

Conditions

Conditions Yield

With ammonium cerium (IV) nitrate; sulfuric acid; lithium bromide In acetonitrile at 65 - 70℃; Reagent/catalyst; Concentration; Time; Solvent; 93%

With N-Bromosuccinimide; toluene-4-sulfonic acid In dichloromethane at 0 - 20℃;

927-49-1
dipentyl ketone

2537-48-6
diethyl 1-cyanomethylphosphonate

3-Pentyl-oct-2-enenitrile

Conditions

Conditions Yield

With sodium methylate In methanol at 70℃; for 96h; Inert atmosphere; 92%

With sodium hydride 1.) THF, RT, 20 min, 2.) THF, RT, 72 h; Multistep reaction;

927-49-1
dipentyl ketone

100-52-7
benzaldehyde

A

6111-82-6
(E)-1-phenyl-1-hexene

B

142-62-1
hexanoic acid

Conditions

Conditions Yield

With boron trifluoride diacetate In hexane for 2.5h; Aldol-Grob reaction; Heating; A n/a
B 92%

...Expand

927-49-1
dipentyl ketone

611-99-4
4,4'-Dihydroxybenzophenone

1,1-bis(4-hydroxyphenyl)-2-pentyl-1-heptene

Conditions

Conditions Yield

With titanium tetrachloride; zinc In tetrahydrofuran at 0 - 90℃; for 2h; Inert atmosphere; Darkness; 92%

927-49-1
dipentyl ketone

56-81-5
glycerol

(2,2-dipentyl-1,3-dioxolan-4-yl)methanol

Conditions

Conditions Yield

With toluene-4-sulfonic acid In n-heptane; toluene for 18h; Dean-Stark; Inert atmosphere; Reflux; 92%

109-80-8
1.3-propanedithiol

927-49-1
dipentyl ketone

5849-09-2
2,2-di-n-pentyl-1,3-dithiane

Conditions

Conditions Yield

With boron trifluoride diacetate for 0.5h; 90%

75-52-5
nitromethane

927-49-1
dipentyl ketone

(Z)-6-Nitromethyl-undec-5-ene

Conditions

Conditions Yield

With N,N`-dimethylethylenediamine In benzene for 48h; Heating; 90%

7677-24-9
trimethylsilyl cyanide

927-49-1
dipentyl ketone

135879-93-5
2-trimethylsilyloxy-2-pentyl-heptanenitrile

Conditions

Conditions Yield

With bis(triphenylphosphine)iminium chloride at 25℃; for 4h; Inert atmosphere; Neat (no solvent); 90%

With zinc(II) iodide

927-49-1
dipentyl ketone

21749-63-3
2-(methylamino)benzenethiol

3-Methyl-2,2-dipentyl-2,3-dihydro-benzothiazole

Conditions

Conditions Yield

In ethanol for 24h; Heating; 90%

927-49-1
dipentyl ketone

98-88-4
benzoyl chloride

34581-60-7
5-benzoyl-6-undecanone

Conditions

Conditions Yield

Stage #1: dipentyl ketone With triethyl gallium In hexane; chlorobenzene at 125℃; for 2h;
Stage #2: benzoyl chloride In hexane; chlorobenzene at 20℃; for 0.166667h; 90%

927-49-1
dipentyl ketone

50635-71-7, 50635-72-8, 31350-93-3
1-chloroethyl p-tolyl sulfoxide

6-<1-chloro-1-(p-tolylsulfinyl)ethyl>-6-undecanol

Conditions

Conditions Yield

With n-butyllithium; diisopropylamine In tetrahydrofuran at -65℃; for 0.416667h; 89%

927-49-1
dipentyl ketone

104-15-4
toluene-4-sulfonic acid

6-oxoundecan-5-yl 4-methylbenzenesulfonate

Conditions

Conditions Yield

With potassium peroxymonosulfate; 4-tolyl iodide In water; acetonitrile at 60℃; for 0.5h; Inert atmosphere; 89%

With 3-chloro-benzenecarboperoxoic acid In acetonitrile at 50℃; for 1.5h; Inert atmosphere; 77%

With iodobenzene; 3-chloro-benzenecarboperoxoic acid In acetonitrile at 50℃; for 5h; 67%

6-Undecanone Chemical Properties

IUPAC Name: Undecan-6-one
Synonyms: 6-Hendecanon ; 6-Oxoundecane ; 6-Undecanon ; Amyl ketone ; Amylketone ; Diamylketon ; Pentyl ketone ; Pentylketone
Molecular Structure of 6-Undecanone (CAS NO. 927-49-1) :
Molecular Formula of 6-Undecanone (CAS NO. 927-49-1) : C₁₁H₂₂O
Molecular Weight of 6-Undecanone (CAS NO. 927-49-1) : 170.29
CAS NO : 927-49-1
EINECS : 213-150-9
Density: 0.831
Melting point : 14.6 ºC
Boiling point : 228 ºC
Refractive index: 1.427-1.429
Flash point : 88 ºC
Appearance: clear colorless to slightly yellow liquid

6-Undecanone Toxicity Data With Reference

1.
orl-rat LDLo:1000 mg/kg
    CTOXAO    Clinical Toxicology. 17 (1980),271.

2.
ivn-mus LD50:117 mg/kg
    JPMSAE    Journal of Pharmaceutical Sciences. 67 (1978),566.

6-Undecanone Consensus Reports

Reported in EPA TSCA Inventory.

6-Undecanone Safety Profile

Poison by intravenous route. Moderately toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes. See also KETONES.
Hazard Codes Xi
Safety Statements 24/25
S24/25:Avoid contact with skin and eyes.
WGK Germany 3
RTECS YQ2828000
Hazard Note Irritant

6-Undecanone Standards and Recommendations

DOT Classification:  3; Label: Flammable Liquid

6-Undecanone Specification

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage: Store in a cool, dry place. Keep container closed when not in use.

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Conditions	Yield
With iodine; potassium carbonate In tert-butyl alcohol at 90℃; for 5h;	99%
With 4-hydroxy-TEMPO benzoate; sodium bromide In dichloromethane; water at 20 - 25℃; NaHCO3-buffered at pH 8.6; electrolysis;	91%
With ruthenium(IV) oxide; tetrabutylammomium bromide; tetra(n-butyl)ammonium hydroxide In water; acetonitrile electrooxidation on Pt electrodes;	87.6%

Conditions	Yield
manganese(IV) oxide; aluminum oxide Heating;	87%
With zinc at 300℃;
With cadmium at 270 - 280℃;

Conditions	Yield
With 1,2-bis(diphenylphosphino)ethane nickel(II) chloride; iron(III)-acetylacetonate In tetrahydrofuran 1) r.t. 2) 0 deg C; a new and mild method for preparation of ketones which provides other symmetrical and unsymmetrical ketones using other Grignard reagents;	87%
1,2-bis(diphenylphosphino)ethane nickel(II) chloride; iron(III)-acetylacetonate In tetrahydrofuran	58 % Chromat.

Conditions	Yield
In tetrahydrofuran at 0 - 20℃; for 4h; Inert atmosphere;	66%
In tetrahydrofuran at 0 - 20℃; for 4h; Inert atmosphere;	66%

Conditions	Yield
With tetra-(n-butyl)ammonium iodide; tetraethylammonium tosylate In acetonitrile Ambient temperature; stainless steel plate cathode, Pt anode, 50 mA;	A 1% B 61%
With tetra-(n-butyl)ammonium iodide; tetraethylammonium tosylate In various solvent(s) Ambient temperature; stainless steel plate cathode, Pt anode, 50 mA;	A 7% B 22%

Conditions	Yield
With [2,2]bipyridinyl; (1,2-dimethoxyethane)dichloronickel(II); Ir[dF(OMe)ppy]2-(dtbbpy)PF6; 1,8-diazabicyclo[5.4.0]undec-7-ene In 1,4-dioxane at 25℃; for 36h; Sealed tube; Inert atmosphere; Irradiation;	48%
With boron trifluoride Erwaermen mit wss.Natriumacetat-Loesung;

Conditions	Yield
With zirconium(IV) oxide at 450℃; under 760.051 Torr; Inert atmosphere; Flow reactor;	A 48% B 25% C 22%
With cerium(IV) oxide; water at 450℃; Mechanism; Reagent/catalyst; Flow reactor;	A 47% B 22% C 24%

Conditions	Yield
In tetrahydrofuran; diethyl ether at -20 - 20℃;	A n/a B 45%
In tetrahydrofuran at -20 - 20℃;	A n/a B 42%

Conditions	Yield
With Pd supported on Na and Ca basified SiO2 Reagent/catalyst;	A 32.3% B 6.6% C 42.1%
at 249.84℃; for 2h; Reagent/catalyst;	A 12.2% B 6.3% C 21.8%
With potassium phosphate; 5%-palladium/activated carbon In toluene at 160℃; for 20h; Product distribution / selectivity; Sealed tube;	A 20.7 %Chromat. B 15.6 %Chromat. C 31.7 %Chromat.
With potassium phosphate; 5%-palladium/activated carbon In toluene at 145℃; for 10h; Product distribution / selectivity; Sealed tube;	A 6.5 %Chromat. B 23.2 %Chromat. C 63.7 %Chromat.
With potassium phosphate; 5%-palladium/activated carbon In toluene at 145℃; for 30h; Product distribution / selectivity; Sealed tube;	A 28.6 %Chromat. B 6.4 %Chromat. C 15.8 %Chromat.

Conditions	Yield
With Pd supported on Na and Ca basified SiO2 Reagent/catalyst;	A 41% B 22%
With Mg-Al hydrotalcite at 249.84℃; for 2h; Reagent/catalyst;	A 6% B 20%
With potassium phosphate; 5%-palladium/activated carbon In Phthalic acid dibutyl ester at 145℃; for 20h; Product distribution / selectivity; Sealed tube;	A 10.3 %Chromat. B 14.2 %Chromat.

Conditions	Yield
With zirconium(IV) oxide at 450℃; under 760.051 Torr; Inert atmosphere; Flow reactor;	A 16% B 40% C 22%
With cerium(IV) oxide; water at 450℃; Mechanism; Reagent/catalyst; Flow reactor;	A 22% B 40% C 26%

Conditions	Yield
	100%
With 5% active carbon-supported ruthenium In ethanol at 78℃; for 18h;	94.7%
With ammonium acetate; acetic acid

Conditions	Yield
With hydroxylamine hydrochloride; sodium hydrogencarbonate In methanol; water at 20 - 25℃; for 24h;	99%
With pyridine; hydroxylamine hydrochloride In ethanol at 100℃;	99%
With sodium hydroxide; hydroxylamine; tert-butylamine hydrochloride In water; isopropyl alcohol for 2h; Ambient temperature;	89%
With sodium hydroxide; hydroxylamine hydrochloride
With hydroxylamine hydrochloride

Conditions	Yield
With boron trifluoride diacetate for 0.25h;	97%
With toluene-4-sulfonic acid In benzene Heating;

Conditions	Yield
Stage #1: dipentyl ketone With ammonium acetate In methanol at 20℃; for 1.5h; Inert atmosphere; Stage #2: With sodium cyanoborohydride In methanol for 56h;	96%
With ammonia; hydrogen In methanol at 90℃; under 15001.5 Torr; for 8h;	77%
benzylamine In palladium-carbon	38%

Conditions	Yield
With (triphenylphosphine)copper(I) hydride hexamer; hydrogen; Dimethyl(phenyl)phosphine In tert-butyl alcohol; benzene at 20℃; under 760 Torr; for 12h; Hydrogenation;	95%
With sodium tetrahydroborate In tetrahydrofuran; methanol at 0 - 20℃; for 2h;	93%
With methanol; sodium tetrahydroborate In tetrahydrofuran at 0 - 20℃; for 2h;	93%

Conditions	Yield
With acetic acid In ethanol for 120h; Heating;	95%
With acetic acid In ethanol for 15h; Mannich Aminomethylation; Reflux;

Conditions	Yield
With n-butyllithium; diisopropylamine In tetrahydrofuran at -65℃; for 0.416667h;	93%
With lithium diisopropyl amide 1.) THF, -78 deg C, 10 min, 2.) THF, -78 deg C, 10 min.; Yield given. Multistep reaction;

Conditions	Yield
With ammonium cerium (IV) nitrate; sulfuric acid; lithium bromide In acetonitrile at 65 - 70℃; Reagent/catalyst; Concentration; Time; Solvent;	93%
With N-Bromosuccinimide; toluene-4-sulfonic acid In dichloromethane at 0 - 20℃;

Conditions	Yield
With sodium methylate In methanol at 70℃; for 96h; Inert atmosphere;	92%
With sodium hydride 1.) THF, RT, 20 min, 2.) THF, RT, 72 h; Multistep reaction;

Product Name

6-Undecanone

Synthetic route

6-Undecanone Chemical Properties

6-Undecanone Toxicity Data With Reference

6-Undecanone Consensus Reports

6-Undecanone Safety Profile

6-Undecanone Standards and Recommendations

6-Undecanone Specification

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Conditions	Yield
With bis(triphenylphosphine)iminium chloride at 25℃; for 4h; Inert atmosphere; Neat (no solvent);	90%
With zinc(II) iodide

Conditions	Yield
With potassium peroxymonosulfate; 4-tolyl iodide In water; acetonitrile at 60℃; for 0.5h; Inert atmosphere;	89%
With 3-chloro-benzenecarboperoxoic acid In acetonitrile at 50℃; for 1.5h; Inert atmosphere;	77%
With iodobenzene; 3-chloro-benzenecarboperoxoic acid In acetonitrile at 50℃; for 5h;	67%

1.		orl-rat LDLo:1000 mg/kg		CTOXAO Clinical Toxicology. 17 (1980),271.
2.		ivn-mus LD50:117 mg/kg		JPMSAE Journal of Pharmaceutical Sciences. 67 (1978),566.