Conditions | Yield |
---|---|
at 200°C for 6 h; under CO2; | A n/a B 97% |
Conditions | Yield |
---|---|
With hydrogen In neat (no solvent) in a reversed chlorine detonating gas flame;; | A 93% B 7% |
1-bromo-butane
tri(p-tolyl)antimony
A
p-butyltoluene
B
antimony(III) chloride
Conditions | Yield |
---|---|
With aluminium trichloride In carbon disulfide byproducts: Al(OH)3; hydrolysis; | A 80% B n/a |
(2-ClC6H4)2SbCl
A
antimony(III) chloride
B
tris(2-chlorophenyl)stibine dichloride
Conditions | Yield |
---|---|
In acetone byproducts: N2; in cold acetone; | A n/a B 73% |
In acetone byproducts: N2; in cold acetone; | A n/a B 73% |
chloro-trimethyl-silane
B
antimony(III) chloride
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: hexamethyldisilixane; mixture of Sb2O3 and trimethylchlorosilane was stirred at room temp. for1 h; precipitate was filtered off, residue distilled iv vac.; | A n/a B n/a C 69% |
dichlorodimethylaminoborane
antimony(III) fluoride
A
(dimethylamino)difluoroborane
B
antimony(III) chloride
Conditions | Yield |
---|---|
heating at 220°C; | A 45% B n/a |
heating at 220°C; | A 45% B n/a |
Conditions | Yield |
---|---|
In acetone byproducts: N2; in cold acetone; | A n/a B 45% |
In acetone byproducts: N2; in cold acetone; | A n/a B 45% |
acetonitrile
A
bis(diethyldithiocarbamato)nitridorhenium(V)
C
antimony(III) chloride
Conditions | Yield |
---|---|
In acetonitrile reflux for 5 h, with exclusion of moisture; soln. was concd., cooled, crystn. for 12 h, crystals were filtered off, washed with MeCN, elem. anal.; | A n/a B 40% C n/a |
bis(sulfinylamido)tellurane
antimonypentachloride
C
antimony(III) chloride
Conditions | Yield |
---|---|
In dichloromethane byproducts: SO2, N2; stirring mixt. of Te-compd. and SbCl5 (molar ratio 2.1:1.5) in abs. CH2Cl2 at -80°C in a sealed tube (12 h); filtration of pptn. in absence of air and moisture, washing (CH2Cl2), concn. of combined filtrates by removal of solvent in vac. to half of vol., crystn. after few weeks; | A n/a B 1% C n/a |
Conditions | Yield |
---|---|
at 300 - 350℃; |
carbon disulfide
antimonypentachloride
A
tetrachloromethane
B
antimony(III) chloride
triphenylantimony
A
antimony(III) chloride
B
phenylmercury(II) chloride
hydrogenchloride
tris(p-anisyl)antimony
A
antimony(III) chloride
B
methoxybenzene
A
hydrogenchloride
B
para-dichlorobenzene
C
antimony(III) chloride
D
phosphorus trichloride
Conditions | Yield |
---|---|
beim Erhitzen; |
Conditions | Yield |
---|---|
heated with a mixture of NH4Cl and NH4NO3 (3/1 or 5/1);; |
A
ammonium sulfide
B
antimony(III) chloride
Conditions | Yield |
---|---|
boiled in NH4Cl-soln.;; |
Conditions | Yield |
---|---|
byproducts: SO2, SO3; dropping S2O5Cl2 to Sb; |
phosphorus pentachloride
A
antimony(III) chloride
B
diselenium dichloride
C
phosphorus trichloride
Conditions | Yield |
---|---|
In neat (no solvent) react. on heating;; |
phosphonium iodide
antimonypentachloride
A
phosphorus
B
phosphan
C
antimony(III) chloride
D
antimony triiodide
Conditions | Yield |
---|---|
byproducts: HCl; in sealed tube, 100°C; | A n/a B n/a C >99 D n/a |
Conditions | Yield |
---|---|
In neat (no solvent) heating below melting point of AgCl in vacuum;; | |
In neat (no solvent) heating below melting point of AgCl in vacuum;; |
antimony(III) chloride
triphenylantimony
diphenylantimony(III) chloride
Conditions | Yield |
---|---|
In neat (no solvent) for 72h; | 100% |
In neat (no solvent) for 3h; | 100% |
Stage #1: antimony(III) chloride; triphenylantimony at 20℃; for 72h; Inert atmosphere; Stage #2: for 336h; Cooling; | 95% |
Conditions | Yield |
---|---|
In neat (no solvent) for 72h; | 100% |
In neat (no solvent) for 3h; | 100% |
In neat (no solvent) for 3h; Schlenk technique; Inert atmosphere; | 100% |
2-N-(n-butylamino)cyclopentene-1-dithiocarboxylic acid
antimony(III) chloride
antimony(2-butylaminocyclopentenecarbodithioate)3
Conditions | Yield |
---|---|
In benzene addn. of the carbodithioic acid in benzene to SbCl3 in benzene at room temp. and refluxing for about 8 h; filtn., washing with benzene and drying in vacuo at room temp.; elem. anal.; | 100% |
Conditions | Yield |
---|---|
In benzene treatment of the Zr compd. in benzene suspn. with SbCl3 (1 equiv) (25°C); not isolated; detn. by 1H-NMR; | A n/a B 100% |
tetraphosphorus decasulfide
pentan-1-ol
antimony(III) chloride
antimony tris-(O,O-di-n-pentylphosphorodithioate)
Conditions | Yield |
---|---|
In pentan-1-ol byproducts: H2S, HCl; addn. of P4S10 to pentanol under Ar, stirring at room temp. until H2S evolution ceased (20 h), addn. of SbCl3, stirring at room temp. for 3 h (until HCl evolution stopped); filtn., concentrating the volume of the filtrate under vac., elem. anal.; | 100% |
Conditions | Yield |
---|---|
In 1,4-dioxane soln. of reagents in 1,4-dioxane was heated to 50°C under reflux; ppt. was filtered off, washed with 1,4-dioxane and air-dried, then dried over P2O5 under vac.; elem. anal.; | 100% |
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: MgCl2, anthracene, THF; Ar atmosphere, addn. of SbCl3 to stirred suspn. of Mg compound, stirring(room temp., 290 h); filtration, washing (THF, pentane), drying (0.1-0.2 mbar); elem. anal.; | 100% |
Conditions | Yield |
---|---|
In dichloromethane SbCl3 was added to mixt. of corazol and Fe-complex in CH2Cl2, stirred for 25 min, treated with Et2O, left to stand for 10 d at 4-5°C; filtered, washed with Et2O, dried at room temp.; elem. anal.; | 100% |
pyridine
hydrogenchloride
antimony(III) chloride
4-chloro-aniline
Conditions | Yield |
---|---|
Stage #1: 4-chloro-aniline With sulfuric acid In ethanol for 0.25h; Cooling with ice; Stage #2: antimony(III) chloride In ethanol for 0.166667h; Cooling with ice; Stage #3: pyridine; hydrogenchloride Further stages; | 100% |
antimony(III) chloride
1-butyl-3-methylimidazolium chloride
Conditions | Yield |
---|---|
at 120℃; for 4h; Inert atmosphere; | 100% |
antimony(III) chloride
trans-1,2-bis(4-pyridyl)ethylene
Conditions | Yield |
---|---|
In neat (no solvent) for 48h; Inert atmosphere; Sealed tube; | 100% |
Conditions | Yield |
---|---|
In neat (no solvent) for 72h; Inert atmosphere; Sealed tube; | 100% |
O,O-di(2-tolyl)dithiophosphoric acid ammonium salt
antimony(III) chloride
[Sb(S2P(OC6H4Me-o)2)3]
Conditions | Yield |
---|---|
In benzene benzene soln. of SbCl3 and NH4S2P(OC6H4Me-o)2 refluxed for 5 h; filtered; vac. evapn.; crystd. from refrigerated hexane soln. after 2-3 d; elem. anal.; | 99.06% |
Conditions | Yield |
---|---|
In benzene byproducts: NaCl, H2; refluxing of Na and the phenol in THF to a clear and transparent soln., complete removing of THF, drying (reduced pressure), dissolving of the solid in benzene, addn. of SbCl3 in benzene, refluxing (12 h), filtration from pptd. NaCl; removing of excess solvent; elem. anal.; | 99% |
antimony(III) chloride
Tri-m-tolyl-stibane
m-tolylantimony dichloride
Conditions | Yield |
---|---|
In neat (no solvent) Ar atmosphere, stirring (90°C, 2 h), cooling; elem. anal.; | 99% |
antimony(III) tris(O,O′-diisopropyldithiophosphato-S,S′)
antimony(III) chloride
bis(O,O′-diisopropyldithiophosphato-S,S′)antimony(III) chloride
Conditions | Yield |
---|---|
In benzene for 0.3h; Reflux; | 99% |
In benzene stirring and heating for ca 2 h (mol. ratio 1:2); evapn.; elem. anal.; | 86% |
antimony(III) chloride
tri(o-tolyl)antimony
o-tolylantimony dichloride
Conditions | Yield |
---|---|
In neat (no solvent) Ar atmosphere, stirring (90°C, 2 h), cooling; elem. anal.; | 99% |
antimony(III) chloride
2-chloro-1,3-dioxa-4,6-di-t-butylbenzo-2-stibolane
Conditions | Yield |
---|---|
In chloroform-d1 N2, Schlenk tube; mixing stoich. amts. of Sb-compd. and org. compd. solns.; elem. anal.; | 99% |
In toluene for 48h; Reflux; Inert atmosphere; |
zirconocene 1,3-diphosphabicyclo[1.1.0]butane
antimony(III) chloride
ClSbP2(CC(CH3)3)2
Conditions | Yield |
---|---|
In hexane standard Schlenk line and glovebox techniques, Zr-compd. dissolved in n-hexane, reacted with two equiv. SbCl3 at room temp. for 2 h; filtered, stored for 16 h at -15°C; | 99% |
1,5-bis(4-hydroxy-3-methoxybenzaldehyde)carbohydrazone
antimony(III) chloride
Sb((C6H3(OH)(OCH3)CHNNH)2CO)Cl3
Conditions | Yield |
---|---|
In benzene addn. of carbohydrazone to soln. of SbCl3 in dry benzene (molar ratio 1:1), refluxed (110°C bath temp., 12 h); filtered, washed (repeatedly with warm anhydrous alcohol), dried under vac. at 40°C; elem. anal.; | 99% |
Conditions | Yield |
---|---|
In ethylenediamine High Pressure; solvothermal synthesis; Mg, SbCl3, S, ethylenediamine heated in a sealedTeflon-lined stainless steel autoclave at 170°C for 10 d; coolin g to room temp.; filtered off; washed with H2O, EtOH, acetone; elem. anal.; | 99% |
2-naphthalenylmagnesium bromide
antimony(III) chloride
tri(2-naphthyl)stibine
Conditions | Yield |
---|---|
In tetrahydrofuran Inert atmosphere; | 99% |
Conditions | Yield |
---|---|
In acetone at 20℃; for 5h; | 99% |
Conditions | Yield |
---|---|
Stage #1: chlorobenzene With cis-Octadecenoic acid; sodium In toluene at 30 - 40℃; for 2h; Inert atmosphere; Stage #2: antimony(III) chloride In toluene at 110℃; for 3.5h; Solvent; Reagent/catalyst; Temperature; Inert atmosphere; | 98.1% |
Conditions | Yield |
---|---|
In benzene addn. of carbohydrazide to soln. of SbCl3 in dry benzene (molar ratio 1:1), mixt. stirred (40°C, 20 h), cream coloured ppt.; filtered, washed (repeatedly with warm anhydrous alcohol), dried under vac. at 40°C; elem. anal.; | 98% |
bis[[2-hydroxyphenyl]methylene]carbonic dihydrazide
antimony(III) chloride
Sb((C6H4OHCHNNH)2CO)2Cl2(1+)*Cl(1-)={Sb((C6H4OHCHNNH)2CO)2Cl2}Cl
Conditions | Yield |
---|---|
In benzene addn. of carbohydrazone to soln. of SbCl3 in dry benzene (molar ratio 2:1), colour change from white to pale yellow at room temp., refluxed (110°C bath temp., 12 h); filtered, washed (repeatedly with warm anhydrous alcohol), dried under vac. at 40°C; elem. anal.; | 98% |
antimony(III) chloride
Thiocarbohydrazide
trichloro-thiocarbohydrazide-antimony
Conditions | Yield |
---|---|
In benzene ligand soln. added to SbCl3 soln. in molar ratio 1/1, refluxed for 10 h; filtered, washed with anhyd. alc., dried (vac.) at 35°C; elem. anal.; | 98% |
antimony(III) chloride
trichloro-(1,5-bis(2-hydroxybenzaldehyde)thiocarbohydrazene)-antimony
Conditions | Yield |
---|---|
In benzene ligand soln. added to SbCl3 soln. in molar ratio 1/1, refluxed for 10 h; filtered, washed with anhyd. alc., dried (vac.) at 35°C; elem. anal.; | 98% |
chlorobis(trimethylsilyl)methane
antimony(III) chloride
tris(bis(trimethylsilyl)methyl)antimony
Conditions | Yield |
---|---|
With Li In tetrahydrofuran; diethyl ether soln. of ligand in THF was added with stirring to Li in Et2O for 1 h, stirred for 24 h with reflux, filtered, added at room temp. to SbCl3 in Et2O, stirred for 16 h at room temp. under Ar; solvent was removed under reduced pressure, extd. with petroleum ether, solvent was removed, sublimated at 110°C/6E-3 mbar; | 98% |
antimony(III) tris(O,O-di-n-propyl phosphorodithioate)
antimony(III) chloride
dichloroantimony(III) di(n-propyl)dithiophosphate
Conditions | Yield |
---|---|
In benzene stirring and heating for ca 2 h (mol. ratio 2:1); evapn.; elem. anal.; | 98% |
Chemical Name: Antimony trichloride
IUPAC NAME: trichlorostibane
CAS No.: 10025-91-9
EINECS: 233-047-2
RTECS: CC4900000
Molecular Formula: Cl3Sb
Molecular Weight: 228.12 g/mol
Melting Point: 73.4 °C(lit.)
Density: 3,14 g/cm3
Flash Point: 223.5°C
Boiling Point: 223 °C
WGK Germany: 2
Sensitive: Moisture Sensitive
ANTIMONY(III) CHLORIDE (10025-91-9) is a colorless crystalline solid and shipped as a solid or liquid solution.It is decomposed slowly by water to hydrochloric acid and antimony oxychloride.and it is soluble in hydrochloric acid but insoluble in water. ANTIMONY(III) CHLORIDE (10025-91-9) is corrosive to metals and tissue. Following is the structure:
The chemical synonymous of ANTIMONY(III) CHLORIDE (10025-91-9) are Alferrlc ; Aluminoferric ; antimoine(trichlorured’) ; antimoine(trichlorured’)(french) ; antimonio(triclorurodi) ; Antimontrichlorid ; Antimony butter ; antimonybutter
ANTIMONY(III) CHLORIDE (10025-91-9) is used as analytical reagent, catalyst and in organic synthesis,It can used as mordant for dyeing and printing and fabric flame retardants, inorganic and organic chlorination catalyst and for the coating of steel to make bronze.In addition,it is the raw material of antimony salt. and also used in medicine or used as a preservative.
Product Categories about ANTIMONY(III) CHLORIDE (10025-91-9) are Industrial/Fine Chemicals ; Inorganics ; AAS CRMs ; AAS ; AASSpectroscopy ; Application CRMs ; Spectroscopy
1. | dnr-bcs 10 mmol/L | MUREAV Mutation Research. 77 (1980),109. | ||
2. | ihl-hmn TDLo:73 mg/kg:PUL | BJIMAG British Journal of Industrial Medicine. 23 (1966),318. | ||
3. | orl-rat LD50:525 mg/kg | MarJV# Personal Communication from Josef V. Marhold, VUOS, 539-18, Pardubice, Czechoslovakia, to the Editor of RTECS, Cincinnati, OH, March 29, 1977 29MAR77 . | ||
4. | ipr-mus LD50:13 mg/kg | 85GMAT Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,23. | ||
5. | orl-gpg LD50:574 mg/kg | HYSAAV Hygiene and Sanitation: English Translation of Gigiena Sanitariya. 29 (12)(1964),16. |
Reported in EPA TSCA Inventory. Antimony and its compounds are on the Community Right-To-Know List.
Moderately toxic by ingestion. Human pulmonary system effects by inhalation. Corrosive by vigorous reaction with moisture, generating heat and hydrogen chloride gas (a strong irritant), which can cause pulmonary edema when inhaled. Systemic effects can be caused by the antimony. See also ANTIMONY COMPOUNDS. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits very toxic fumes of chlorine and antimony. It can react violently with aluminum, potassium, sodium.
Hazard Codes:
C: Corrosive
N: Dangerous for the environment
Xi: Irritant
Risk Statements about ANTIMONY(III) CHLORIDE (10025-91-9):
R34 Causes burns.
R36/37/38: Irritating to eyes, respiratory system and skin.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements about ANTIMONY(III) CHLORIDE (10025-91-9):
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 Wear suitable protective clothing.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S61 Avoid release to the environment. Refer to special instructions / safety data sheets.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
Health Hazard: TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire Hazard: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.
OSHA PEL: TWA 500 µg(Sb)/m3
ACGIH TLV: TWA 0.5 mg(Sb)/m3
NIOSH REL: (Antimony) TWA 0.5 mg(Sb)/m3
DOT Classification: 8; Label: Corrosive
1. Storage: Store in a cool, dry place. Store in a tightly closed container. Keep under a nitrogen blanket.
2. Handling: Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Do not allow contact with water. Use only in a chemical fume hood.
3. Personal Protection: Eyes: Wear chemical splash goggles.Skin: Wear appropriate protective gloves to prevent skin exposure.Clothing: Wear appropriate protective clothing to prevent skin exposure.Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
4. Fire Fighting: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Not flammable, but reacts with most metals to form flammable hydrogen gas. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products. Reacts violently with water.Extinguishing Media: Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER!
5. Reactivity Profile: Acidic salts, such as ANTIMONY TRICHLORIDE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.
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