Product Name

  • Name

    alpha-Acetoxytoluene

  • EINECS 205-399-7
  • CAS No. 140-11-4
  • Article Data733
  • CAS DataBase
  • Density 1.055 g/cm3
  • Solubility practically insoluble in water
  • Melting Point -51 °C
  • Formula C9H10O2
  • Boiling Point 213.5 °C at 760 mmHg
  • Molecular Weight 150.177
  • Flash Point 102.2 °C
  • Transport Information
  • Appearance clear colourless liquid
  • Safety 26-37/39
  • Risk Codes 36/37/38
  • Molecular Structure Molecular Structure of 140-11-4 (alpha-Acetoxytoluene)
  • Hazard Symbols IrritantXi
  • Synonyms Acetic acid, phenylmethyl ester;Benzyl acetate (natural);NCI-C06508;Benzylester kyseliny octove [Czech];Phenylmethyl ethanoate;.alpha.-Acetoxytoluene;Acetic acid, benzyl ester;alpha-Acetoxytoluene;Phenylmethyl acetate;Benzyl ethanoate;Natural benzyl acetate;
  • PSA 26.30000
  • LogP 1.74970

Synthetic route

acetic anhydride
108-24-7

acetic anhydride

benzyl alcohol
100-51-6

benzyl alcohol

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
With iodine for 15h; Ambient temperature;100%
With magnesium(II) perchlorate at 20℃; for 0.25h;100%
With nickel dichloride for 0.116667h; microwave irradiation;100%
potassium acetate
127-08-2

potassium acetate

benzyl chloride
100-44-7

benzyl chloride

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
Amberlyst A27 In toluene at 95℃; for 20h;100%
With dicyclohexano-18-crown-6 In acetonitrile at 60℃; for 0.5h; Product distribution; further reagents;85.4%
With zirconium (benzyldiethylammoniomethylphosphonate chloride) phosphate In water; toluene at 88℃; for 15h;82.5%
acetic acid
64-19-7

acetic acid

benzyl alcohol
100-51-6

benzyl alcohol

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
zirconium(IV) oxide In toluene for 1h; Heating; in vapor-phase at 150 deg C;100%
LaY zeolite at 116℃; for 8h; Acetylation;99%
With bismuth(lll) trifluoromethanesulfonate at 20℃; for 0.25h;99%
potassium acetate
127-08-2

potassium acetate

benzyl bromide
100-39-0

benzyl bromide

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
Sucrose-ethyleneoxide adducts In acetonitrile at 20℃; for 8h; Product distribution; further catalysts: PEG, DB18K6; further objects of study: phase-transfer catalysis; further solvents: toluene/H2O;100%
With ammonium salt In neat (no solvent) for 2h; Ambient temperature;99%
With tetradecane; potassium acetate; magnetic nanoparticle-supported crown ether In toluene at 80℃; for 8h;96%
ethyl acetate
141-78-6

ethyl acetate

benzyl alcohol
100-51-6

benzyl alcohol

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
With dilithium tetra(tert-butyl)zincate at 0℃; for 1h; Temperature; Inert atmosphere;100%
With heterogeneous zinc/imidazole catalyst at 90℃; for 1h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Schlenk technique;99%
With C12F18O13Zn4 for 18h; Reflux; Inert atmosphere;98%
acetic acid methyl ester
79-20-9

acetic acid methyl ester

benzyl alcohol
100-51-6

benzyl alcohol

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
With dilithium tetra(tert-butyl)zincate at 0℃; for 1h; Temperature; Inert atmosphere; Molecular sieve;100%
1,3-dicyclohexyl-imidazol-2-ylidene In tetrahydrofuran at 20℃; for 1h;95%
With 4 A molecular sieve; 1,3-di-tBu-2,3-dihydroimidazole carbene-polydimethylsiloxane at 20℃; for 6h;95%
1-ethoxy-2-(trimethylsilyl)vinyl acetate
104293-02-9

1-ethoxy-2-(trimethylsilyl)vinyl acetate

benzyl alcohol
100-51-6

benzyl alcohol

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
In 1,2-dichloro-ethane at 60℃; for 48h;100%
vinyl acetate
108-05-4

vinyl acetate

benzyl alcohol
100-51-6

benzyl alcohol

A

Benzyl acetate
140-11-4

Benzyl acetate

B

acetaldehyde
75-07-0

acetaldehyde

Conditions
ConditionsYield
With 1,3-dicyclohexylimidazolium-2-thiocarboxylate In tetrahydrofuran at 80℃; for 2h; Inert atmosphere;A 100%
B n/a
With lipase from Pseudomonas Cepacia In benzene at 35℃; other ω-substituted-1-alkanols, var. solvents; kinetic parameters of transesterification;
vinyl acetate
108-05-4

vinyl acetate

benzyl alcohol
100-51-6

benzyl alcohol

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
Y5(OiPr)13O at 20℃; for 42h; Acetylation; transesterification;100%
With dilithium tetra(tert-butyl)zincate In tetrahydrofuran at 25℃; for 1h; Reagent/catalyst; Solvent; Time; Temperature; Inert atmosphere;100%
With P(MeNCH2CH2)3N In tetrahydrofuran for 2h; Ambient temperature;99%
Isopropenyl acetate
108-22-5

Isopropenyl acetate

benzyl alcohol
100-51-6

benzyl alcohol

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
Y5(OiPr)13O at 20℃; for 1h; Acetylation; transesterification;100%
With indium(III) perchlorate; lithium perchlorate In ethyl acetate at 20℃; for 0.75h;99%
With iodine at 85 - 90℃; for 0.0833333h;98%
benzoic acid anhydride
93-97-0

benzoic acid anhydride

benzyl alcohol
100-51-6

benzyl alcohol

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
sodium tetracarbonyl cobaltate In toluene for 12h;100%
ammonium acetate
631-61-8

ammonium acetate

benzyl chloride
100-44-7

benzyl chloride

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
In glycerol at 80℃; for 1h; Solvent;100%
In glycerol at 70℃; for 1h;20%
acetyl chloride
75-36-5

acetyl chloride

benzyl alcohol
100-51-6

benzyl alcohol

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
With aluminum oxide at 25℃; for 0.25h;99%
bismuth(III) oxychloride In dichloromethane at 20℃; for 0.0833333h;98%
In dichloromethane 1.) 0 deg C, 2.) room temperature, 1 h;97%
Benzyl bromoacetate
5437-45-6

Benzyl bromoacetate

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
With indium; sodium dodecyl-sulfate at 60℃; for 0.5h;99%
With borohydride exchange resin; nickel diacetate In methanol for 1h; Ambient temperature;98%
With DMBI In tetrahydrofuran for 1h; Heating;94%
benzyloxy-trimethylsilane
14642-79-6

benzyloxy-trimethylsilane

acetyl chloride
75-36-5

acetyl chloride

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
With montmorillonite K-10 In chloroform at 20℃; for 0.3h;99%
benzyl mesylate
55791-06-5

benzyl mesylate

cesium acetate
3396-11-0

cesium acetate

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 25℃; for 24h;98%
acetic anhydride
108-24-7

acetic anhydride

benzyl alcohol
100-51-6

benzyl alcohol

A

Benzyl acetate
140-11-4

Benzyl acetate

B

dimethylglyoxal
431-03-8

dimethylglyoxal

Conditions
ConditionsYield
With cobalt(II) chloride In acetonitrile at 25℃; for 4h;A 98%
B n/a
benzyloxy-trimethylsilane
14642-79-6

benzyloxy-trimethylsilane

acetic anhydride
108-24-7

acetic anhydride

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
at 20℃; for 0.133333h;98%
With polyvinylpolypyrrolidone-bound boron trifluoride In acetonitrile at 20℃; for 2.5h;96%
With alumina supported P2O5 at 20℃; for 0.75h; neat (no solvent);92%
Sulfate; titanium(IV) oxide at 20℃; for 0.133333h;89%
With montmorillonite K-10 for 0.25h; Acetylation; desilylation;88%
tetrahydro-2-(benzyloxy)-2H-pyran
1927-62-4

tetrahydro-2-(benzyloxy)-2H-pyran

acetic acid
64-19-7

acetic acid

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
bismuth(lll) trifluoromethanesulfonate for 0.75h; Heating;98%
K5 for 2h; Heating;95 % Chromat.
Acetyl bromide
506-96-7

Acetyl bromide

benzyl cinnamyl ether
101306-31-4

benzyl cinnamyl ether

A

Benzyl acetate
140-11-4

Benzyl acetate

B

Cinnamyl bromide
4392-24-9

Cinnamyl bromide

Conditions
ConditionsYield
With lithium bromide In dichloromethane at 30 - 35℃; for 6h; Inert atmosphere;A 98%
B n/a
2-bromobenzyl acetate
82466-12-4

2-bromobenzyl acetate

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
With N,N,N,N,N,N-hexamethylphosphoric triamide; samarium diiodide In tetrahydrofuran for 2h; Ambient temperature; Yields of byproduct given;97%
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride In benzene at 90℃; for 48h;
acetic anhydride
108-24-7

acetic anhydride

benzaldehyde
100-52-7

benzaldehyde

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
With 1H-imidazole; zinc In 1,2-dimethoxyethane at 80℃; for 24h;97%
With aluminum oxide; zinc In dichloromethane at 20℃; for 12h; Acetylation; Reductive acetylation;95%
(benzyloxy)(tert-butyl)dimethylsilane
53172-91-1

(benzyloxy)(tert-butyl)dimethylsilane

acetic anhydride
108-24-7

acetic anhydride

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
With pyridine hydrogenfluoride at 20℃; for 2.5h;97%
With iron(III) chloride; 1-butyl-3-methylimidazolium chloride at 20℃; for 0.5h;86%
With boron trifluoride diethyl etherate; sodium iodide In acetonitrile at 0℃; for 1.5h;70%
copper(II) bis(trifluoromethanesulfonate) In dichloromethane at 20℃; for 2.5h;63%
dibenzyl ether
103-50-4

dibenzyl ether

acetic anhydride
108-24-7

acetic anhydride

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
With aminosulfonic acid In acetic acid at 60℃; for 4h;96%
FeCl3-Montmorillonite K-10 at 70℃; for 22h;94%
sulfuric acid In water at 140℃; for 3h; Conversion of starting material;79%
Acetyl bromide
506-96-7

Acetyl bromide

benzyl trityl ether
5333-62-0

benzyl trityl ether

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
In 1,2-dichloro-ethane at 20℃; for 3h;96%
Acetyl bromide
506-96-7

Acetyl bromide

dibenzyl ether
103-50-4

dibenzyl ether

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
With lithium bromide In dichloromethane at 30 - 35℃; for 6h; Inert atmosphere;96%
sodium acetate
127-09-3

sodium acetate

benzyl chloride
100-44-7

benzyl chloride

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
With 1,3-dimethylimidazolinium methanesulfonate at 90℃; for 0.5h;95%
tetrabutyl phosphonium bromide at 150℃; under 20 Torr; g.l.p.t.c.;94%
With polyethylene glycol 400 at 65 - 70℃; for 4.5h;94%
tetrahydro-2-(benzyloxy)-2H-pyran
1927-62-4

tetrahydro-2-(benzyloxy)-2H-pyran

acetic anhydride
108-24-7

acetic anhydride

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
bismuth(lll) trifluoromethanesulfonate In acetonitrile for 0.5h; Heating;95%
With indium(III) triflate In dichloromethane at 0 - 20℃; for 1.16667h;94%
With indium(III) triflate In dichloromethane at 0 - 20℃; Inert atmosphere;93%
benzaldehyde
100-52-7

benzaldehyde

ethyl acetate
141-78-6

ethyl acetate

Benzyl acetate
140-11-4

Benzyl acetate

Conditions
ConditionsYield
With [Zn(BH4)2(nmi)] In diethyl ether at 20℃; for 1h;95%
benzyl chloride
100-44-7

benzyl chloride

1-ethyl-3-methylimidazolium acetate
143314-17-4

1-ethyl-3-methylimidazolium acetate

A

Benzyl acetate
140-11-4

Benzyl acetate

B

1-ethyl-3-methyl-1H-imidazol-3-ium chloride
65039-09-0

1-ethyl-3-methyl-1H-imidazol-3-ium chloride

Conditions
ConditionsYield
at 20℃; for 2h; Inert atmosphere;A 95%
B n/a
Benzyl acetate
140-11-4

Benzyl acetate

benzaldehyde
100-52-7

benzaldehyde

benzyl 3-hydroxy-3-phenylpropanoate

benzyl 3-hydroxy-3-phenylpropanoate

Conditions
ConditionsYield
Stage #1: Benzyl acetate With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78℃; for 0.5h; Inert atmosphere;
Stage #2: benzaldehyde In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere;
100%
With N-ethyl-N,N-diisopropylamine; magnesium iodide In dichloromethane for 20h;46%
Benzyl acetate
140-11-4

Benzyl acetate

tert-butyl (S)-N-tert-butoxycarbonylpyroglutamate
91229-91-3

tert-butyl (S)-N-tert-butoxycarbonylpyroglutamate

(S)-7-benzyl 1-tert-butyl 2-(tert-butoxycarbonyl)-5-oxoheptanedioate
896100-50-8

(S)-7-benzyl 1-tert-butyl 2-(tert-butoxycarbonyl)-5-oxoheptanedioate

Conditions
ConditionsYield
Stage #1: tert-butyl (S)-N-tert-butoxycarbonylpyroglutamate With lithium diisopropyl amide In tetrahydrofuran at -78℃; for 0.583333h;
Stage #2: Benzyl acetate In tetrahydrofuran at -78 - 0℃; for 3.33333h;
100%
methanol
67-56-1

methanol

Benzyl acetate
140-11-4

Benzyl acetate

acetic acid methyl ester
79-20-9

acetic acid methyl ester

Conditions
ConditionsYield
With dilithium tetra(tert-butyl)zincate at 0℃; for 1h; Inert atmosphere;100%
With dilithium tetra(tert-butyl)zincate at 0℃; for 1h; Inert atmosphere; Glovebox; Cooling;61 %Spectr.
Benzyl acetate
140-11-4

Benzyl acetate

A

acetic acid
64-19-7

acetic acid

B

toluene
108-88-3

toluene

Conditions
ConditionsYield
With hydrogen In n-heptane at 160℃; under 750.075 Torr; for 6h; Catalytic behavior;A 96 %Chromat.
B 100%
Benzyl acetate
140-11-4

Benzyl acetate

benzaldehyde
100-52-7

benzaldehyde

(E)-cinnamic acid benzyl ester
103-41-3

(E)-cinnamic acid benzyl ester

Conditions
ConditionsYield
With titanium tetrachloride; triethylamine In dichloromethane at 0 - 25℃; Inert atmosphere; stereoselective reaction;99%
With iodine; magnesium; mercury dichloride Reagens 4: Xylol;
Benzyl acetate
140-11-4

Benzyl acetate

D-α-glutamine
19522-40-8

D-α-glutamine

γ-benzyl isoglutaminate perchlorate
87137-45-9

γ-benzyl isoglutaminate perchlorate

Conditions
ConditionsYield
With perchloric acid for 96h; Ambient temperature;99%
Benzyl acetate
140-11-4

Benzyl acetate

benzyl alcohol
100-51-6

benzyl alcohol

Conditions
ConditionsYield
With [Ru(2-(methylthio)-N-[(pyridin-2-yl)methyl]ethan-1-amine)(triphenylphosphine)Cl2]; potassium tert-butylate; hydrogen In toluene at 80℃; under 30003 Torr; for 3h;99%
With methanol; sodium methylate at 60℃; Reagent/catalyst;99%
With Ximenia american In water at 30℃; for 72h; pH=5; Enzymatic reaction;98%
Benzyl acetate
140-11-4

Benzyl acetate

methyl iodide
74-88-4

methyl iodide

benzyl methyl ether
538-86-3

benzyl methyl ether

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide 1.) 0 deg C, 1 h, 2.) 25 deg C, 24 h;99%
Benzyl acetate
140-11-4

Benzyl acetate

benzaldehyde
100-52-7

benzaldehyde

Conditions
ConditionsYield
With methanol; potassium permanganate In ethyl acetate at 25℃; for 18h;99%
With lithium perchlorate In methanol at 0℃; Inert atmosphere; Sealed tube; Electrochemical reaction; Cooling with ice;80%
Multi-step reaction with 2 steps
1: 180 °C
2: 150 °C
View Scheme
Multi-step reaction with 2 steps
1: lipase B from Candida antarctica immobilized on Immobead 150 / aq. phosphate buffer / 0.33 h / 40 °C / pH 7.4
2: 9-azabicyclo<3.3.1>nonane-N-oxyl; copper(I) bromide; 1-methyl-1H-imidazole / water / 2 h / 20 °C
View Scheme
Multi-step reaction with 2 steps
1: Candida antarctica lipase B; water / 30 °C / pH 6 / Enzymatic reaction
2: thermophilic alcohol dehydrogenase; NAD; butan-1-ol / 30 °C / pH 8 / Enzymatic reaction
View Scheme
Benzyl acetate
140-11-4

Benzyl acetate

phenethylamine
64-04-0

phenethylamine

A

N-benzyl-2-phenylethylamine
3647-71-0

N-benzyl-2-phenylethylamine

B

methyl-N-(benzyl-methyl)-formamide
877-95-2

methyl-N-(benzyl-methyl)-formamide

Conditions
ConditionsYield
With bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; sodium acetate In neat (no solvent) at 115℃; for 24h; Reagent/catalyst; Solvent; Inert atmosphere; Glovebox; Green chemistry;A 69%
B 99%
Benzyl acetate
140-11-4

Benzyl acetate

3-Phenylpropan-1-amine
2038-57-5

3-Phenylpropan-1-amine

A

N-acetyl-3-phenylpropylamine
34059-10-4

N-acetyl-3-phenylpropylamine

B

benzyl-(3-phenyl-propyl)-amine
32861-51-1

benzyl-(3-phenyl-propyl)-amine

Conditions
ConditionsYield
With bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; sodium acetate In neat (no solvent) at 115℃; for 24h; Inert atmosphere; Glovebox; Green chemistry;A 99%
B 66%
Benzyl acetate
140-11-4

Benzyl acetate

2-(3-Fluorophenyl)ethylamine
404-70-6

2-(3-Fluorophenyl)ethylamine

A

N-(3-fluorophenylethyl)benzylamine
1110646-00-8

N-(3-fluorophenylethyl)benzylamine

B

N-<2-(3-fluorophenyl)ethyl>acetamide
125058-99-3

N-<2-(3-fluorophenyl)ethyl>acetamide

Conditions
ConditionsYield
With bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; sodium acetate In neat (no solvent) at 115℃; for 24h; Inert atmosphere; Glovebox; Green chemistry;A 66%
B 99%
Benzyl acetate
140-11-4

Benzyl acetate

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
25015-63-8

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

2-(benzyloxy)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
95843-98-4

2-(benzyloxy)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions
ConditionsYield
With manganese(II) triflate bis-acetonitrile solvate; potassium tert-butylate In benzene-d6 at 20℃; for 3h; Inert atmosphere; Glovebox;99%

Benzyl acetate Chemical Properties


IUPAC Name: Benzyl acetate 
Empirical Formula: C9H10O2
Molecular Weight: 150.1745
Canonical SMILES: CC(=O)OCC1=CC=CC=C1
InChI: InChI=1S/C9H10O2/c1-8(10)11-7-9-5-3-2-4-6-9/h2-6H,7H2,1H3
InChIKey: QUKGYYKBILRGFE-UHFFFAOYSA-N
EINECS: 205-399-7
Product Categories: FINE Chemical & INTERMEDIATES 
Water Solubility: <0.1 g/100 mL at 23 ºC 
Index of Refraction: 1.505
Molar Refractivity: 42.2 cm3
Molar Volume: 142.2 cm3
Surface Tension: 35.9 dyne/cm
Density: 1.055 g/cm3
Flash Point: 102.2 °C
Enthalpy of Vaporization: 44.98 kJ/mol
Boiling Point: 213.5 °C at 760 mmHg
Vapour Pressure: 0.164 mmHg at 25°C 
Appearance: Colorless liquid with an odor of pears.
Melting Point: -51 °C(lit.)
Classification Code of Benzyl acetate (CAS NO.140-11-4): Human Data; Mutation data; Skin / Eye Irritant; Tumor data

Benzyl acetate Uses

 Benzyl acetate (CAS NO.140-11-4) is used widely in perfumery and cosmetics for its aroma and in flavorings to impart apple and pear flavors. Benzyl acetate is commonly used as bait to attract and collect these bees for study. It is also used as a solvent in plastics and resin, cellulose acetate, nitrate, lacquers, oils,  polishes and inks.

Benzyl acetate Production

 Benzyl acetate (CAS NO.140-11-4) is prepared by esterification of benzyl alcohol, by heating with either an excess of acetic anhydride or acetic acid with mineral acids.
       C6H5CH2OH + CH3CO2H → C6H5CH2OCOCH3
The product is purified by treatment with boric acid and distilled to a purityIn excess of 98%.

Benzyl acetate Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
cat LC50 inhalation 245ppm/8H (245ppm)   AMA Archives of Industrial Health. Vol. 21, Pg. 28, 1960.
cat LDLo skin 10gm/kg (10000mg/kg) BEHAVIORAL: TREMOR

BEHAVIORAL: MUSCLE WEAKNESS

GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS
Journal of Pharmacology and Experimental Therapeutics. Vol. 84, Pg. 358, 1945.
guinea pig LD50 oral 2200mg/kg (2200mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 50(7), Pg. 17, 1985.
guinea pig LDLo subcutaneous 3gm/kg (3000mg/kg)   Archiv fuer Gewerbepathologie und Gewerbehygiene. Vol. 5, Pg. 1, 1933.
human TCLo inhalation 50ppm (50ppm) BEHAVIORAL: ANTIPSYCHOTIC

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES

KIDNEY, URETER, AND BLADDER: OTHER CHANGES
"Handbook of Organic Industrial Solvents," 2nd ed., Chicago, National Assoc. of Mutual Casualty Companies, 1961Vol. 2, Pg. 31, 1961.
mouse LCLo inhalation 1300mg/m3/22H (1300mg/m3) BEHAVIORAL: GENERAL ANESTHETIC Archiv fuer Gewerbepathologie und Gewerbehygiene. Vol. 5, Pg. 1, 1933.
mouse LD50 oral 830mg/kg (830mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 50(7), Pg. 17, 1985.
rabbit LD50 oral 2200mg/kg (2200mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 50(7), Pg. 17, 1985.
rabbit LD50 skin > 5gm/kg (5000mg/kg)   Food and Cosmetics Toxicology. Vol. 11, Pg. 875, 1973.
rabbit LDLo subcutaneous 4gm/kg (4000mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD Archiv fuer Gewerbepathologie und Gewerbehygiene. Vol. 5, Pg. 1, 1933.
rat LD50 oral 2490mg/kg (2490mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) Food and Cosmetics Toxicology. Vol. 2, Pg. 327, 1964.

Benzyl acetate Safety Profile

Hazard Codes: IrritantXi
Risk Statements: 36/37/38 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-37/39 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S37/39:Wear suitable gloves and eye/face protection.
RIDADR: 2810
WGK Germany: 1
RTECS: AF5075000

Benzyl acetate Specification

  Benzyl acetate (CAS NO.140-11-4), its Synonyms are Acetic acid, benzyl ester ; Acetic acid, phenylmethyl ester ; Benzyl ethanoate ; Benzylester kyseliny octove ; Phenylmethyl acetate ; Phenylmethyl ethanoate ; alpha-Acetoxytoluene .

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