Chlorotrifluoroethylene supplier

Name
Chlorotrifluoroethylene
EINECS 201-201-8
CAS No. 79-38-9
Article Data93
CAS DataBase
Density 1.411 g/cm³
Solubility 380mg/L at 28℃
Melting Point -158 °C(lit.)
Formula C₂ClF₃
Boiling Point -28 °C
Molecular Weight 116.47
Flash Point -28°C
Transport Information UN 1082
Appearance colorless gas with a faint ethereal odor
Safety 16-38
Risk Codes 12-20/22
Molecular Structure
Hazard Symbols F+,Xn,T,F
Synonyms Ethylene, chlorotrifluoro- (8CI);1-Chloro-1,2,2-trifluoroethene;2-Chloro-1,1,2-trifluoroethylene;CFC 1113;Chlorotrifluoroethene;F 1113;Genetron 1113;Monochlorotrifluoroethylene;R 1113;Trifluoromonochloroethylene;Trifluorovinyl chloride;Trithene;Ethene,chlorotrifluoro- (9CI);
PSA 0.00000
LogP 2.26030

Synthetic route

: 76-13-1
1,1,2-Trichloro-1,2,2-trifluoroethane

: 79-38-9
Chlorotrifluoroethylene

Conditions

Conditions	Yield
With potassium zinc trihydride at 250 - 320℃; under 7500.75 Torr; for 5h; Temperature; Pressure; Inert atmosphere; Large scale;	99.22%
With ammonium chloride; zinc(II) chloride In methanol; water electrochemical process;	90%
With zinc(II) chloride; zinc In ethanol at 50℃; for 3h; Dehalogenation;	75%

: 76-13-1
1,1,2-Trichloro-1,2,2-trifluoroethane

A: 354-23-4
1,2-dichloro-1,2,2-trifluoroethane

B: 79-38-9
Chlorotrifluoroethylene

C: 359-11-5
1,1,2-trifluoroethylene

Conditions

Conditions	Yield
With hydrogen; silica gel; nickel at 450℃; under 760 Torr; Title compound not separated from byproducts;	A n/a B 95.8% C n/a
bismuth(III) chloride; silica gel; palladium at 250℃; Yield given. Yields of byproduct given;
With hydrogen; silica gel; nickel at 450℃; under 760 Torr; Product distribution; other supported Ni catalysts and metal oxides;
bismuth(III) chloride; silica gel; palladium at 250℃; under 760 Torr; Product distribution; other catalysts and modifier; variation of condition: selectivity;

...Expand

: 354-61-0
1,2-dichloro-1,2,2-trifluoro-1-iodoethane

: 79-38-9
Chlorotrifluoroethylene

Conditions

Conditions	Yield
With zinc In dichloromethane; ethyl acetate at 0 - 20℃; for 2h;	93%
With hexaethylphosphoric triamide In benzonitrile ice-salt bath;	92%
With 1,4-dioxane; zinc
With zinc In dichloromethane; acetic anhydride for 3h; Ambient temperature;

: 374-48-1
(2-chloro tetrafluoro ethyl) trichloro silane

: 79-38-9
Chlorotrifluoroethylene

Conditions

Conditions	Yield
In neat (no solvent) byproducts: SiFCl3, SiF2Cl2, SiFCl3; pyrolysis at 220°C, 15 hours;;	90%
In neat (no solvent) byproducts: SiFCl3, SiF2Cl2, SiFCl3; pyrolysis at 220°C, 15 hours;;	90%
at 220℃;

: 662-06-6
(2,2-dichloro trifluoro ethyl) trichloro silane

A: 79-38-9
Chlorotrifluoroethylene

B: 1842-05-3
1,1-dichloro-1,2-difluoroethane

Conditions

Conditions	Yield
With sodium hydroxide; water hydrolysis at 25°C, 30 minutes;;	A 13% B 87%
With NaOH; H2O hydrolysis at 25°C, 30 minutes;;	A 13% B 87%

: 2106-94-7
1-bromo-1,2-dichloro-1,2,2-trifluoro-ethane

: 79-38-9
Chlorotrifluoroethylene

Conditions

Conditions	Yield
With hexaethylphosphoric triamide In benzonitrile other perhalogenated alkanes;	80%
With hexaethylphosphoric triamide In benzonitrile ice-salt bath;	80%

: 354-51-8
1,2-dibromo-1-chloro-1,2,2-trifluoroethane

: 79-38-9
Chlorotrifluoroethylene

Conditions

Conditions	Yield
With hexaethylphosphoric triamide In benzonitrile ice-salt bath;	78%

: 354-61-0
1,2-dichloro-1,2,2-trifluoro-1-iodoethane

: 677-69-0
perfluoroisopropyl iodide

A: 431-89-0
1,1,1,2,3,3,3-Heptafluoropropane

B: 79-38-9
Chlorotrifluoroethylene

C: 354-96-1
perfluoro(2,3-dimethylbutane)

D: 375-45-1
perfluoro-1,2,3,4-tetrachlorobutane

Conditions

Conditions	Yield
With acetic anhydride; zinc In dichloromethane at 40℃;	A n/a B n/a C 47% D 47%

...Expand

: 354-61-0
1,2-dichloro-1,2,2-trifluoro-1-iodoethane

: 677-69-0
perfluoroisopropyl iodide

A: 431-89-0
1,1,1,2,3,3,3-Heptafluoropropane

B: 79-38-9
Chlorotrifluoroethylene

C: 354-96-1
perfluoro(2,3-dimethylbutane)

D: 375-45-1
perfluoro-1,2,3,4-tetrachlorobutane

E: 1173181-83-3
C5Cl2F10

Conditions

Conditions	Yield
With acetic anhydride; zinc In dichloromethane at 40℃;	A n/a B n/a C 27% D 28% E 40%
With acetic anhydride; zinc In dichloromethane at 50℃;	A n/a B n/a C 31% D 32% E 30%

...Expand

: 13709-36-9
xenon difluoride

: 726203-09-4
1-chlorodifluoroethenyldifluoroborane

A: 76-15-3
Chloropentafluoroethane

B: 79-38-9
Chlorotrifluoroethylene

C: 726203-15-2
1-chloro-2,2-difluoroethenylxenon(II) tetrafluoroborate

D: 7637-07-2
boron trifluoride

Conditions

Conditions	Yield
In further solvent(s) soln. of CF2=CClBF2 in 1,1,1,3,3-pentafluoropropane cooled to -65°C and XeF2 added in small portions within 6 min; stirring stopped after2 h; mother liquor decanted; precipitate separated and dried in vacuum at -60°C;	A n/a B n/a C 19% D n/a

...Expand

: 354-23-4
1,2-dichloro-1,2,2-trifluoroethane

: 79-38-9
Chlorotrifluoroethylene

Conditions

Conditions	Yield
at 656.9 - 712.9℃; Thermodynamic data;
With potassium hydroxide at 25 - 50℃;
With sodium hydroxide at 25 - 50℃;

: 812-04-4
1,1-dichloro-1,2,2-trifluoroethane

: 79-38-9
Chlorotrifluoroethylene

Conditions

Conditions	Yield
at 545℃;
at 545℃;
at 570℃;

: 356-18-3, 3832-15-3, 3934-26-7
trans-1,1,2,2,3,4-hexafluoro-3,4-dichlorocyclobutane

: 79-38-9
Chlorotrifluoroethylene

Conditions

Conditions	Yield
at 426 - 514℃; under 30 - 140 Torr; Rate constant; Dissoziation;

: 354-23-4
1,2-dichloro-1,2,2-trifluoroethane

A: 311-81-9
cis-1,2-dichloro-1,2-difluoroethene

B: 79-38-9
Chlorotrifluoroethylene

C: 359-11-5
1,1,2-trifluoroethylene

Conditions

Conditions	Yield
Product distribution; Rate constant; Irradiation; IR laser pulse irradiation;

...Expand

: 75-45-6
Chlorodifluoromethane

A: 116-14-3
polytetrafluoroethylene

B: 116-15-4
perfluoropropylene

C: 75-46-7
trifluoromethan

D: 354-25-6
2-chloro-1,1,2,2-tetrafluoroethane

E: 79-38-9
Chlorotrifluoroethylene

F: 359-11-5
1,1,2-trifluoroethylene

Conditions

Conditions	Yield
for 8.33333E-05h; Product distribution; Heating; varying temperatures;

...Expand

: 75-88-7
1,1,1-trifluoro-2-chloroethane

: 79-38-9
Chlorotrifluoroethylene

Conditions

Conditions	Yield
Irradiation; radiation > 237 nm;

: 431-06-1
1,2-difluoro-1,2-dichloroethene

A: 116-14-3
polytetrafluoroethylene

B: 2268-32-8
trans-1-chloro-2-fluoroethylene

C: 79-38-9
Chlorotrifluoroethylene

D: 1630-77-9
(Z)-1,2-difluoro-ethene

E: 1630-78-0
(E)-1,2-difluoroethene

F: 2837-86-7
cis-1,2-difluoro-1-chloroethene

Conditions

Conditions	Yield
Mechanism; Irradiation;

...Expand

: 354-25-6
2-chloro-1,1,2,2-tetrafluoroethane

A: 116-14-3
polytetrafluoroethylene

B: 116-15-4
perfluoropropylene

C: 79-38-9
Chlorotrifluoroethylene

Conditions

Conditions	Yield
at 681.9℃; Kinetics; Mechanism; other temperatures, He-flow system; Arrhenius equation;

...Expand

: 306-83-2
1,1,1-trifluoro-2,2-dichloroethane

A: 359-10-4
1-Chloro-2,2-difluoroethene

B: 79-38-9
Chlorotrifluoroethylene

C: 375-34-8
1,1,1,4,4,4-hexa-fluoro-2,2,3,3-tetrachlorobutane

D: 359-11-5
1,1,2-trifluoroethylene

E: 2,2,4-Trichloro-1,1,1,3,4,4-hexafluoro-butane

Conditions

Conditions	Yield
With nitric oxide In neat (no solvent) at 23℃; under 1.2 - 23.8 Torr; Quantum yield; Rate constant; Mechanism; Irradiation;

...Expand

: 76-13-1
1,1,2-Trichloro-1,2,2-trifluoroethane

A: 354-23-4
1,2-dichloro-1,2,2-trifluoroethane

B: 79-38-9
Chlorotrifluoroethylene

Conditions

Conditions	Yield
With potassium hydroxide at 25℃; electrolysis; Yield given;
With propane at 475℃; for 0.000833333h; Gas phase;

: 76-13-1
1,1,2-Trichloro-1,2,2-trifluoroethane

A: 34557-54-5
methane

B: 79-38-9
Chlorotrifluoroethylene

C: 359-11-5
1,1,2-trifluoroethylene

Conditions

Conditions	Yield
With hydrogen; nickel(II) oxide; chromium(III) oxide at 400℃; for 0.25h; Mechanism; var. temp. and catalysts;

...Expand

: 76-13-1
1,1,2-Trichloro-1,2,2-trifluoroethane

A: 79-38-9
Chlorotrifluoroethylene

B: 359-11-5
1,1,2-trifluoroethylene

Conditions

Conditions	Yield
With hydrogen; nickel(II) oxide; chromium(III) oxide In gas at 350℃; Product distribution; other catalysts, other temperature;
With hydrogen at 550℃; for 0.000833333h; Gas phase;

: 354-61-0
1,2-dichloro-1,2,2-trifluoro-1-iodoethane

A: 79-38-9
Chlorotrifluoroethylene

B: 375-45-1
perfluoro-1,2,3,4-tetrachlorobutane

C: 56949-85-0
1,2,3,5,6-pentachloro-1,1,2,3,4,4,5,6,6-nonafluoro-hexane

D: 1,2,3,5,7,8-Hexachloro-1,1,2,3,4,4,5,6,6,7,8,8-dodecafluoro-octane

Conditions

Conditions	Yield
With cadmium In acetonitrile for 1h; Ambient temperature;	A 60 % Chromat. B 21 % Chromat. C 10 % Chromat. D 3 % Chromat.

...Expand

: 422-55-9
1-chloro-1,1,2,2,3,3-hexafluoropropane

A: 116-14-3
polytetrafluoroethylene

B: 116-15-4
perfluoropropylene

C: 79-38-9
Chlorotrifluoroethylene

Conditions

Conditions	Yield
at 722.9℃; Kinetics; Mechanism; other temperatures, He-flow system; Arrhenius equation;
In various solvent(s) at 800℃; for 8.61111E-05h; Product distribution; Mechanism; flow pyrolysis, oth. temperature, oth. time;	A 75.54 % Chromat. B 4.14 % Chromat. C 3.58 % Chromat.

...Expand

: 58911-30-1
3-chloro-3-(trifluoromethyl)diazirine

A: 75-88-7
1,1,1-trifluoro-2-chloroethane

B: 79-38-9
Chlorotrifluoroethylene

Conditions

Conditions	Yield
Irradiation;
Irradiation; radiation > 300 nm;

: 421-79-4
1,1,2-Trifluoro-2-chloro-1,2-diiodoethane

: 79-38-9
Chlorotrifluoroethylene

Conditions

Conditions	Yield
With iodine for 288h; Equilibrium constant; Irradiation; various kind of irradiation, variousd times and mole ratio;

: 151-67-7
1,1,1-trifluoro-2-bromo-2-chloroethane

A: 306-83-2
1,1,1-trifluoro-2,2-dichloroethane

B: 124-73-2
1,2-dibromo-1,1,2,2-tetrafluoroethane

C: 79-38-9
Chlorotrifluoroethylene

D: 359-11-5
1,1,2-trifluoroethylene

Conditions

Conditions	Yield
under 7.6 Torr; Product distribution; Irradiation; var. pressure;

...Expand

: 354-23-4
1,2-dichloro-1,2,2-trifluoroethane

aqueous KOH-solution: aqueous KOH-solution

: 79-38-9
Chlorotrifluoroethylene

: 76-13-1
1,1,2-Trichloro-1,2,2-trifluoroethane

hydrogen: hydrogen

nickel /barium phosphate: nickel /barium phosphate

: 79-38-9
Chlorotrifluoroethylene

Conditions

Conditions	Yield
at 450℃;

...Expand

: 79-38-9
Chlorotrifluoroethylene

: 421-79-4
1,1,2-Trifluoro-2-chloro-1,2-diiodoethane

Conditions

Conditions	Yield
With iodine Ambient temperature; Irradiation;	100%
With benzophenone; iodine at -80℃;	95%
With iodine In dichloromethane at 28 - 30℃; for 6h;	42%
With iodine
With iodine at 55℃; Irradiation; Yield given;

: 79-38-9
Chlorotrifluoroethylene

: 123411-35-8
dimethyl 7,12-diiodo-3,8,13,17-tetramethylporphyrin-2,18-dipropionate

: 3,8-Bis(trifluorovinyl)deuteroporphyrin dimethyl ester

Conditions

Conditions	Yield
Stage #1: Chlorotrifluoroethylene With sec.-butyllithium; zinc(II) chloride In diethyl ether; cyclohexane at -60 - 20℃; Metallation; Stage #2: dimethyl 7,12-diiodo-3,8,13,17-tetramethylporphyrin-2,18-dipropionate; tetrakis(triphenylphosphine) palladium(0) In diethyl ether; dichloromethane; cyclohexane at 20℃; for 40h; Coupling reaction; Stage #3: With sulfuric acid In various solvents at 20℃; for 1h; Substitution; Demetallation;	100%

Yield

Stage #1: Chlorotrifluoroethylene With sec.-butyllithium; zinc(II) chloride In diethyl ether; cyclohexane at -60 - 20℃; Metallation;
Stage #2: dimethyl 7,12-diiodo-3,8,13,17-tetramethylporphyrin-2,18-dipropionate; tetrakis(triphenylphosphine) palladium(0) In diethyl ether; dichloromethane; cyclohexane at 20℃; for 40h; Coupling reaction;
Stage #3: With sulfuric acid In various solvents at 20℃; for 1h; Substitution; Demetallation;

100%

: 79-38-9
Chlorotrifluoroethylene

: 150-76-5
4-methoxy-phenol

: 97675-21-3
1-(2-chloro-1,1,2-trifluoroethoxy)-4-methoxybenzene

Conditions

Conditions	Yield
With caesium carbonate In tetrahydrofuran Reagent/catalyst; regiospecific reaction;	99%
With sodium hydride 1.) THF; 2.) reflux; Multistep reaction;

: 76-37-9
2,2,3,3-tetrafluoropropanol

: 79-38-9
Chlorotrifluoroethylene

: 65064-83-7
3-(2-Chloro-1,1,2-trifluoro-ethoxy)-1,1,2,2-tetrafluoro-propane

Conditions

Conditions	Yield
With potassium hydroxide In water at 75 - 85℃; under 3000.3 Torr; Inert atmosphere; Autoclave;	98%
With potassium hydroxide In N,N-dimethyl-formamide

: 79-38-9
Chlorotrifluoroethylene

: 74770-45-9
perfluoro-(2,4,4,7,7,9-hexamethyl-3,8-dioxa-2,5,6,9-tetra-azadec-5-ene)

A: 141520-94-7
perfuoro-(2,9-dimethyl-4,5,7-trichloro-2,9-diazadecane)

B: 684-16-2
Hexafluoroacetone

Conditions

Conditions	Yield
at 140℃; for 1h;	A 31% B 98%
at 140℃; for 1h; Product distribution;	A 31% B 98%

...Expand

: 79-38-9
Chlorotrifluoroethylene

: 2627-86-3
(-)-α-methylbenzylamine

: 96233-01-1
N-α-Methylbenzyl-α-chloro-α-fluoroacetimidyl fluoride

Conditions

Conditions	Yield
In diethyl ether 1.) 1 h, 60 deg C, 2.) 12 h, 20 deg C;	96%

: 56-23-5
tetrachloromethane

: 79-38-9
Chlorotrifluoroethylene

: 2354-06-5
pentachloro-1,2,2-trifluoro-propane

Conditions

Conditions	Yield
With copper dichloride In acetonitrile at 127℃; for 15h;	95%
With aluminium trichloride
With 2-hydroxy-2-phenylacetophenone; CuCl2*4H2O In acetonitrile at 150℃;

: 106-41-2
4-bromo-phenol

: 79-38-9
Chlorotrifluoroethylene

: 403-60-1
1-bromo-4-(2-chloro-1,1,2-trifluoroethoxy)benzene

Conditions

Conditions	Yield
With caesium carbonate In tetrahydrofuran regiospecific reaction;	95%
With potassium hydroxide In acetone at 25℃; for 5h;	51%
With potassium hydroxide; acetone

: 79-38-9
Chlorotrifluoroethylene

: 354-51-8
1,2-dibromo-1-chloro-1,2,2-trifluoroethane

Conditions

Conditions	Yield
With bromine at 0℃;	95%
With benzophenone; bromine at -80℃;	95%
With benzophenone	91%

: 79-38-9
Chlorotrifluoroethylene

: 34837-55-3
Phenylselenyl bromide

: 114953-62-7
1-chloro-2-bromo-1,2,2-trifluoroethyl phenyl selenide

Conditions

Conditions	Yield
In acetonitrile at 60℃; for 15h; in a tube;	95%

: 79-38-9
Chlorotrifluoroethylene

: 2215-63-6
1-benzyl-3-hydroxy-1H-indazole

: 1300727-54-1
1-benzyl-3-(2-chloro-1,1,2-trifluoroethoxy)-1H-indazole

Conditions

Conditions	Yield
Stage #1: 1-benzyl-3-hydroxy-1H-indazole With potassium In N,N-dimethyl-formamide at 20℃; for 4h; Stage #2: Chlorotrifluoroethylene In N,N-dimethyl-formamide at 115℃;	95%

: 79-38-9
Chlorotrifluoroethylene

: 123324-71-0
4-tert-butylphenylboronic acid

: 1-(1,1-dimethylethyl)-4-(1,2,2-trifluoroethenyl)benzene

Conditions

Conditions	Yield
With potassium phosphate; tri-tert-butylphosphonium tetrafluoroborate; bis(dibenzylideneacetone)-palladium(0) In water; N,N-dimethyl-formamide; toluene at 80℃; for 2h; Schlenk technique; Inert atmosphere;	94%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium carbonate In 1,4-dioxane; water at 100℃; for 2h; Suzuki-Miyaura coupling; Inert atmosphere;	87%
With [1,4-bis(diphenylphosphino)butane] palladium(ll) dichloride; cesium fluoride In 1,4-dioxane; water at -196 - 100℃; for 1h; Inert atmosphere;	84%

: 79-38-9
Chlorotrifluoroethylene

: 76-15-3
Chloropentafluoroethane

Conditions

Conditions	Yield
With xenon difluoride; silicon tetrafluoride at 20℃; for 4h; Fluorination;	93%
With sulfur tetrafluoride; lead dioxide at 100℃; for 2h;
With antimony pentafluoride at 95℃; under 500 - 700 Torr;

: 995-25-5
chlorotripropylsilane

: 79-38-9
Chlorotrifluoroethylene

: 93629-26-6
trifluorovinyltripropylsilane

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran; diethyl ether; hexane; pentane 1.) -130 deg C; 2.) up to RT, 3.5 h;	93%

: 79-38-9
Chlorotrifluoroethylene

: 1833-31-4
benzyl(chloro)dimethylsilane

: 93629-28-8
benzyl(trifluorovinyl)dimethylsilane

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran; diethyl ether; hexane; pentane 1.) -130 deg C; 2.) up to RT, 8 h;	93%

: 79-38-9
Chlorotrifluoroethylene

: 1849-36-1
para-nitrobenzenethiol

: 659-27-8
(2-chloro-1,1,2-trifluoroethyl)(4-nitrophenyl)sulfane

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 40℃; under 2660.18 Torr; for 6h; Inert atmosphere;	93%
With potassium hydroxide In ethanol

: 13816-65-4
ClNSF2

: 79-38-9
Chlorotrifluoroethylene

: 30884-99-2
Cl2CFCF2NSF2

Conditions

Conditions	Yield
Irradiation (UV/VIS); irradiation with Philips 500-W SPEC D8 lamp, distance 30-50 cm, 20°C, 40 h;	93%
Irradiation (UV/VIS); irradiation with Philips 500-W SPEC D8 lamp, distance 30-50 cm, 20°C, 40 h;	93%

: 5707-04-0
Phenylselenyl chloride

: 79-38-9
Chlorotrifluoroethylene

: 114953-61-6
1,2-dichloro-1,2,2-trifluoroethyl phenyl selenide

Conditions

Conditions	Yield
In acetonitrile at 60℃; for 15h; in a tube;	92%

: 79-38-9
Chlorotrifluoroethylene

: 758-43-0
N-bromobis(trifluoromethyl)amine

: 4905-97-9
bis(trifluoromethyl)-2-chloro-2-bromotrifluoroethylamine

Conditions

Conditions	Yield
25°C, 24 h, 100°C, 24 h in dark;	92%
25°C, 24 h, 100°C, 24 h in dark;	92%

: 79-38-9
Chlorotrifluoroethylene

: 5285-74-5
4-tolyl thiocyanate

: (2-azido-1-chloro-1,2,2-trifluoroethyl)(p-tolyl)sulfane

Conditions

Conditions	Yield
With copper(l) iodide; sodium azide; 1,10-Phenanthroline In dimethyl sulfoxide; N,N-dimethyl-formamide at 20℃; for 12h; Autoclave; Inert atmosphere;	92%

: 79-38-9
Chlorotrifluoroethylene

: 3-formyl-4-methoxyphenylboronic acid

: 2-methoxy-5-(trifluorovinyl)benzaldehyde

Conditions

Conditions	Yield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium carbonate In 1,4-dioxane; water at -196 - 100℃; for 2h; Inert atmosphere;	92%

: 79-38-9
Chlorotrifluoroethylene

: 76-13-1
1,1,2-Trichloro-1,2,2-trifluoroethane

Conditions

Conditions	Yield
With benzophenone; chlorine at -80℃;	92%

: 872-36-6
vinylene carbonate

: 79-38-9
Chlorotrifluoroethylene

polymer, Mn = 2300 g/mol, PDI = 2.3; monomer(s): chlorotrifluoroethylene; vinylene carbonate: polymer, Mn = 2300 g/mol, PDI = 2.3; monomer(s): chlorotrifluoroethylene; vinylene carbonate

Conditions

Conditions	Yield
With tert-butyl peroxypivalate In ethyl acetate at 80℃; for 4h;	91.6%

: 872-36-6
vinylene carbonate

: 79-38-9
Chlorotrifluoroethylene

polymer, Mn = 4250 g/mol, PDI = 2.3; monomer(s): chlorotrifluoroethylene; vinylene carbonate: polymer, Mn = 4250 g/mol, PDI = 2.3; monomer(s): chlorotrifluoroethylene; vinylene carbonate

Conditions

Conditions	Yield
With tert-butyl peroxypivalate In acetic acid methyl ester at 80℃; for 4h;	91.6%

: 108-05-4
vinyl acetate

: 79-38-9
Chlorotrifluoroethylene

poly[chlorotrifluoroethylene-co-(vinyl acetate)], fluoromonomer in copolymer: 20.5 mol percent (NMR), 25.6 mol percent (elemental analysis), Mw: 282 kg/mol, Mn: 119 kg/mol, PDI: 2.37, Tg: 48 deg C; monomer(s): chlorotrifluoroethylene; vinyl acetate: poly[chlorotrifluoroethylene-co-(vinyl acetate)], fluoromonomer in copolymer: 20.5 mol percent (NMR), 25.6 mol percent (elemental analysis), Mw: 282 kg/mol, Mn: 119 kg/mol, PDI: 2.37, Tg: 48 deg C; monomer(s): chlorotrifluoroethylene; vinyl acetate

Conditions

Conditions	Yield
With Peroxydikohlensaeure-diethylester In carbon dioxide at 45℃; under 150012 - 172514 Torr; for 24h;	91%

: 615-15-6
2-Methyl-1H-benzimidazole

: 79-38-9
Chlorotrifluoroethylene

: 13616-04-1
1-(2-Chloro-1,1,2-trifluoroethyl)-2-methylbenzimidazole

Conditions

Conditions	Yield
With potassium hydroxide In acetone for 1.3h;	90%
With potassium fluoride In acetone for 89h;	62%

Chlorotrifluoroethylene Consensus Reports

Reported in EPA TSCA Inventory.

Chlorotrifluoroethylene Standards and Recommendations

DOT Classification: 2.1; Label: Flammable Gas

Chlorotrifluoroethylene Specification

The IUPAC name of Chlorotrifluoroethylene is 1-chloro-1,2,2-trifluoroethene. With the CAS registry number 79-38-9, it is also named as 1,1,2-Trifluoro-2-chloroethylene. The product's categorie is refrigerant. It is a colorless gas with a faint ethereal odor. And it is shipped as a liquefied gas under its vapor pressure. Additionally, Chlorotrifluoroethylene is highly toxic. And under prolonged exposure to intense heat or fire, the containers may violently rupture and rocket, or the material may polymerize with possible container rupture.

The other characteristics of this product can be summarized as: (1)ACD/LogP: 2.16; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 2.16; (4)ACD/LogD (pH 7.4): 2.16; (5)ACD/BCF (pH 5.5): 25.96; (6)ACD/BCF (pH 7.4): 25.96; (7)ACD/KOC (pH 5.5): 358.05; (8)ACD/KOC (pH 7.4): 358.05; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)Index of Refraction: 1.32; (12)Molar Refractivity: 16.39 cm³; (13)Molar Volume: 82.4 cm³; (14)Polarizability: 6.5×10^-24 cm³; (15)Surface Tension: 13.5 dyne/cm; (16)Enthalpy of Vaporization: 21.99 kJ/mol; (17)Vapour Pressure: 3940 mmHg at 25°C; (18)Exact Mass: 115.964062; (19)MonoIsotopic Mass: 115.964062; (20)Heavy Atom Count: 6; (21)Complexity: 72.9.

Preparation of Chlorotrifluoroethylene: It is derived from the dechlorination of trifluorotrichloroethane. Generally, using zinc powder as dechlorination agent and methanol as solvent. The reaction temperature is 50-150 °C, the reaction pressure is 2.08MPa, and the reaction time is 3-4s. Consumption of raw materials is fixed: trifluorotrichloroethane 1830 kg / t, methanol (> 95%) 1080kg / t, zinc (> 95%) 840kg / t.

Uses of Chlorotrifluoroethylene: It can be polymerised to produce the plastic ECTFE. And it is used as raw material of fluorine plastic, fluorine rubber, refrigerant, CFCs oil and halothane anesthetic. Additionally, it reacts methanol to get (2-chloro-1,1,2-trifluoro-ethyl)-methyl ether. This reaction needs reagent KOH-solution at temperature of -80 °C.

When you are using this chemical, please be cautious about it as the following:
It is extremely flammable, so people should keep it away from sources of ignition. And it is harmful by inhalation and if swallowed. Inhalation causes dizziness, nausea, vomiting; liver and kidney injury may develop after several hours and cause jaundice and necrosis of the kidney. In case of insufficient ventilation, wear suitable respiratory equipment.

People can use the following data to convert to the molecule structure.
1. SMILES:F/C(F)=C(/Cl)F
2. InChI:InChI=1/C2ClF3/c3-1(4)2(5)6
3. InChIKey:UUAGAQFQZIEFAH-UHFFFAOYAH

The following are the toxicity data which has been tested.

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
guinea pig	LC50	inhalation	4300mg/m³/4H (4300mg/m³)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LIVER: OTHER CHANGES KIDNEY, URETER, AND BLADDER: OTHER CHANGES	Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 21(5), Pg. 36, 1977.
mouse	LC50	inhalation	3000ppm/7H (3000ppm)		Acta Biologica et Medica Germanica. Vol. 21, Pg. 377, 1968.
mouse	LD50	intraperitoneal	175mg/kg (175mg/kg)		Acta Biologica et Medica Germanica. Vol. 21, Pg. 377, 1968.
mouse	LD50	oral	268mg/kg (268mg/kg)		Acta Biologica et Medica Germanica. Vol. 21, Pg. 377, 1968.
rat	LC50	inhalation	1000ppm/4H (1000ppm)	LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES GASTROINTESTINAL: OTHER CHANGES	Fluorine Chemistry Reviews. Vol. 1, Pg. 197, 1967.

Product Name

Chlorotrifluoroethylene

Synthetic route

Chlorotrifluoroethylene Consensus Reports

Chlorotrifluoroethylene Standards and Recommendations

Chlorotrifluoroethylene Specification

Related Products

Hot Products