Citronellol supplier | CasNO.106-22-9

Name
6-Octen-1-ol,3,7-dimethyl-
EINECS 203-375-0
CAS No. 106-22-9
Article Data270
CAS DataBase
Density 0.845 g/cm³
Solubility slightly soluble in water
Melting Point 77-83 °C(lit.)
Formula C₁₀H₂₀O
Boiling Point 224.499 °C at 760 mmHg
Molecular Weight 156.268
Flash Point 98.333 °C
Transport Information
Appearance colourless liquid
Safety 26-36-24/25
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms 2,3-Dihydrogeraniol;2,6-Dimethyl-2-octen-8-ol;3,7-Dimethyl-6-octen-1-ol;Cephrol;Citronellol 950;Dihydrogeraniol;Rodinol;
PSA 20.23000
LogP 2.75130

Synthetic route

: 106-23-0, 26489-02-1
3,7-dimethyl-oct-6-enal

: 106-22-9
Citronellol

Conditions

Conditions	Yield
With Zn(BH4)2(Ph3P)2 In tetrahydrofuran at 20℃; Reduction;	100%
With hydrogen; aluminum oxide; copper In isopropyl alcohol at 90℃; for 0.75h;	100%
With trimethylamine-N-oxide; sodium formate; C34H44FeN4O4(2+)*2I(1-) In water at 80℃; for 24h; Inert atmosphere; Schlenk technique;	99%

: 106-24-1
Geraniol

: 106-22-9
Citronellol

Conditions

Conditions	Yield
With hydrogen; aluminum oxide; copper In isopropyl alcohol at 90℃; for 12h;	100%
With hydrogen; polymer-supported rhodium catalyst In dichloromethane under 1551.49 Torr; for 10h; Hydrogenation;	96%
With 1,1'-bis(diphenylphosphino)ferrocene; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; Butane-1,4-diol; potassium tert-butylate at 110℃; for 24h; Inert atmosphere;	71%

: 106-25-2
Nerol

: 106-22-9
Citronellol

Conditions

Conditions	Yield
With hydrogen; aluminum oxide; copper In isopropyl alcohol at 90℃; for 12h;	100%
With dichloro(η3:η2:η3-dodeca-2,6,10-triene-1,12-diyl)ruthenium(IV); caesium carbonate; isopropyl alcohol at 82℃; for 23h; Inert atmosphere; chemoselective reaction;	95 %Chromat.

: 96154-40-4
1-(benzyloxy)-3,7-dimethyloct-6-ene

: 106-22-9
Citronellol

Conditions

Conditions	Yield
With hydrogen; benzyl bromide; Pd<*>MCM-48 In methanol under 760.051 Torr; for 0.5h;	99%
With aluminium trichloride; N,N-dimethyl-aniline In dichloromethane for 1.5h; Ambient temperature;	98%
With naphthalene; lithium In tetrahydrofuran; methanol at -78℃; for 40h;	89%

: 2270-60-2
methyl 3,7-dimethyloct-6-enoate

: 106-22-9
Citronellol

Conditions

Conditions	Yield
With [RuCl2((E)-N-(2-(diphenylphosphino)benzyl)-1-(6-((diphenylphosphino)methyl)pyridin-2-yl)methanimine)]; hydrogen; sodium ethanolate at 80℃; under 37503.8 Torr; for 5h; Autoclave;	98%
With lithium aluminium tetrahydride Yield given;

: 1-(3,7-Dimethyl-oct-6-enyloxymethoxy)-4-methoxy-benzene

: 106-22-9
Citronellol

Conditions

Conditions	Yield
With ammonium cerium(IV) nitrate In water; acetonitrile at 0℃; for 0.5h; Product distribution;	98%

: 90243-41-7
2-(3,7-dimethyloct-6-enyloxy)-tetrahydro-2H-pyran

: 106-22-9
Citronellol

Conditions

Conditions	Yield
With SA-3 silica-alumina gel In methanol at 120℃; for 2.16667h;	98%
With SA-3 silica-alumina gel In methanol at 120℃; for 2.16667h; Product distribution; other ethers, var. silica-alumina gels, temp. and time;	98%
With copper dichloride In methanol at 20℃; Hydrolysis;	90%
With CuCl2*2H2O In methanol at 20℃; for 1.25h;	90%
With boron trifluoride diethyl etherate; sodium cyanoborohydride In tetrahydrofuran for 3h; Ambient temperature;	80%

: Acetaldehyde ethyl 3,7-dimethyl-6-octenyl acetal

: 106-22-9
Citronellol

Conditions

Conditions	Yield
With SA-3 silica-alumina gel In methanol at 120℃; for 1.33333h;	98%

: 8-(1-Methoxy-ethoxy)-2,6-dimethyl-oct-2-ene

: 106-22-9
Citronellol

Conditions

Conditions	Yield
With dibromotriphenylphosphorane In dichloromethane at -50℃; for 2h;	97%

: 18419-09-5
(3,7-dimethyloct-6-enyloxy)trimethylsilane

: 106-22-9
Citronellol

Conditions

Conditions	Yield
With SA-3 silica-alumina gel In methanol for 1.16667h; Ambient temperature;	97%
With 18-crown-6 ether In ethanol; water at 45℃; for 3h; Green chemistry;	91%

: 3,7-dimethyl-1-(1-methyl-1-methoxyethoxy)-6-octene

: 106-22-9
Citronellol

Conditions

Conditions	Yield
With SA-2 silica-alumina gel In methanol for 3.16667h; Ambient temperature;	97%

: 106-26-3
cis-3,7-dimethyl-2,6-octadienal

A: 106-22-9
Citronellol

B: 106-23-0, 26489-02-1
3,7-dimethyl-oct-6-enal

Conditions

Conditions	Yield
With acetylacetonato(1,5-cyclooctadiene)rhodium(I); hydrogen; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In toluene at 25℃; under 750.075 Torr; for 0.5h; Catalytic behavior; Temperature; Pressure; Autoclave; chemoselective reaction;	A 3% B 97%
With acetylacetonatodicarbonylrhodium(l); hydrogen; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In neat (no solvent) at 60℃; under 30003 Torr; for 10h; Temperature; Pressure; Autoclave;	A 88 %Spectr. B 12 %Spectr.

: 8-(2-methoxy-ethoxymethoxy)-2,6-dimethyl-oct-2-ene

: 106-22-9
Citronellol

Conditions

Conditions	Yield
With cerium(III) chloride In acetonitrile for 1h; Heating;	96%

: 5392-40-5
(E/Z)-3,7-dimethyl-2,6-octadienal

: 106-22-9
Citronellol

Conditions

Conditions	Yield
With LaNi5 hydride In tetrahydrofuran; methanol for 12h; Ambient temperature;	95%
With LaNi5 hydride In tetrahydrofuran; methanol 1) 0 deg C, 6 h, 2) r.t., 12 h;	95%
With hydrido(triphenylphosphine)copper(I) hexamer In tetrahydrofuran for 24h; Ambient temperature;	90%

: 5392-40-5
(E/Z)-3,7-dimethyl-2,6-octadienal

A: 106-22-9
Citronellol

B: 106-23-0, 26489-02-1
3,7-dimethyl-oct-6-enal

Conditions

Conditions	Yield
With hydrogen; Ni0.88Cr0.12 In cyclohexane at 79.9℃; under 7575.6 Torr; Product distribution; other catalysts, hydrogenation rates, selectivity of catalysts;	A n/a B 92%
With hydrogen; Ni-Gr2 In methanol at 45℃; under 22800 Torr; for 18h;	A 68% B 26%
With hydrogen; sodium carbonate; chromium(III) oxide; nickel In water; isopropyl alcohol at 120℃; under 30400 Torr; Product distribution; other temperature, other solvent, other pressure, other catalysts;	A 0.6 % Chromat. B 97.5 % Chromat.

: 87921-26-4
tert-butyl((3,7-dimethyloct-6-en-1-yl)oxy)dimethylsilane

: 106-22-9
Citronellol

Conditions

Conditions	Yield
With 2,5-bis(perfluorobutyl)-1,4-benzoquinone In water; acetonitrile at 20℃; for 6h;	92%
With oxone In methanol at 20℃; for 15h;	80%
With bismuth(III) chloride; sodium iodide In acetonitrile at 20℃; for 1.5h;	76%

: 106-23-0, 26489-02-1
3,7-dimethyl-oct-6-enal

: 62-53-3
aniline

A: 106-22-9
Citronellol

B: 31043-21-7
N-(3,7-dimethyloct-6-en-1-yl)aniline

Conditions

Conditions	Yield
Stage #1: 3,7-dimethyl-oct-6-enal; aniline at 25℃; for 0.166667h; Stage #2: With sodium tetrahydroborate; boric acid at 25℃; for 0.333333h;	A n/a B 92%

...Expand

: 3,7-dimethyl-1-[tris(trimethylsilyl)silyl]-6-octen-1-ol

: 106-22-9
Citronellol

Conditions

Conditions	Yield
In methanol; dichloromethane desilylation; Photolysis;	91%

: C23H32OSi

: 106-22-9
Citronellol

Conditions

Conditions	Yield
With 18-crown-6 ether In ethanol; water at 45℃; for 2.5h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Green chemistry;	91%

: 8-iodo-3,7-dimethyloct-6-en-1-ol acetate

: 106-22-9
Citronellol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In tetrahydrofuran at -20℃;	90%

: 141-27-5
3,7-dimethyl-2,6-octadienal

: 106-22-9
Citronellol

Conditions

Conditions	Yield
With Ba(BH2S3)2 In tetrahydrofuran at 20℃; for 2.5h;	90%
With hydrogen In isopropyl alcohol at 70℃; under 56255.6 Torr; for 2h; Reagent/catalyst; Autoclave; Glovebox;

: 5392-40-5
(E/Z)-3,7-dimethyl-2,6-octadienal

A: 106-22-9
Citronellol

B: 106-21-8, 59204-02-3
tetrahydrogeraniol

: 15356-70-4
menthol

Conditions

Conditions	Yield
With hydrogen In tert-butyl alcohol at 80℃; under 1500.15 - 15001.5 Torr; for 8h; Autoclave; diastereoselective reaction;	A n/a B n/a C 89%

...Expand

: 5392-40-5
(E/Z)-3,7-dimethyl-2,6-octadienal

A: 106-22-9
Citronellol

B: 624-15-7
geraniol

Conditions

Conditions	Yield
With hydrogen; silver In tetrahydrofuran at 150℃; under 11251.1 Torr; for 72h;	A 10% B 88%
With sodium cyanoborohydride at 20℃; for 0.05h;	A 46% B 54%
With (triphenylphosphine)copper(I) hydride hexamer; hydrogen; Dimethyl(phenyl)phosphine In tert-butyl alcohol; benzene at 20℃; under 25857.4 Torr; for 15h; Hydrogenation; Title compound not separated from byproducts;

: 1754-00-3, 55722-59-3
3,7-dimethyl-3,6-octadienal

A: 106-22-9
Citronellol

B: 624-15-7
geraniol

Conditions

Conditions	Yield
With chlorine[2-(4,5-dihydro-1H-imidazol-2-yl)-6-methoxypyridine](pentamethylcyclopentadienyl)iridium(III) chloride; sodium formate In water at 80℃; for 0.5h; Schlenk technique; chemoselective reaction;	A 88% B n/a

: allyl 3,7-dimethyloct-6-en-1-yl ether

: 106-22-9
Citronellol

Conditions

Conditions	Yield
With samarium diiodide; water; isopropylamine In tetrahydrofuran at 20℃; for 0.0833333h;	87%
With naphthalene; lithium In tetrahydrofuran; methanol at -78℃; for 40h;	86%

: 5392-40-5
(E/Z)-3,7-dimethyl-2,6-octadienal

A: 106-22-9
Citronellol

B: 106-21-8, 59204-02-3
tetrahydrogeraniol

: 15356-70-4
menthol

: 89-79-2, 7786-67-6, 18674-65-2, 20549-46-6, 21290-09-5, 29141-10-4, 50373-36-9, 59905-53-2, 59905-54-3, 96612-21-4, 104870-56-6, 121468-66-4, 122517-60-6, 122517-61-7, 144541-38-8
isopulegol

Conditions

Conditions	Yield
With hydrogen In tert-butyl alcohol at 80℃; under 7500.75 Torr; for 8h; Autoclave; diastereoselective reaction;	A n/a B n/a C 87% D n/a

...Expand

: 41144-01-8
(+/-)-citronellyl tosylate

: 106-22-9
Citronellol

Conditions

Conditions	Yield
With tetraethylammonium perchlorate; triethylamine In dimethyl sulfoxide at 20℃; for 10h; Electrolysis; Green chemistry;	87%

: 110109-86-9
3,7-dimethyl-1-acetoxy-6-p-toluenesulfonyloxy octane

A: 106-22-9
Citronellol

B: 106-21-8, 59204-02-3
tetrahydrogeraniol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In tetrahydrofuran 1.) -10 deg C 2.) RT;	A 6% B 82%

: 106-23-0, 26489-02-1
3,7-dimethyl-oct-6-enal

A: 106-22-9
Citronellol

B: 13887-74-6, 90544-01-7
(3,7-dimethyloctyl)amine

C: 53339-59-6
3,7-dimethyl-6-octenylamine

D: 24381-83-7
3,3',7,7'-tetramethyldi-6-octenylamine

E: (E)-N-(3,7-dimethyloct-6-en-1-ylidene)-3,7-dimethyloct-6-en-1-amine

F: 3,7-dimethyloct-6-en-1-imine

Conditions

Conditions	Yield
With chloro(1,5-cyclooctadiene)rhodium(I) dimer; hydrogen; ammonium hydroxide; 1-methyl-3-decylimidazolium bromide In toluene at 130℃; under 45004.5 Torr; for 6h; Reagent/catalyst; Autoclave;	A 8% B 1% C 81% D n/a E n/a F 8%
With chloro(1,5-cyclooctadiene)rhodium(I) dimer; hydrogen; ammonium hydroxide; 1-octyl-3-methyl-imidazolium bromide In toluene at 130℃; under 45004.5 Torr; for 6h; Autoclave;	A 20% B 2% C 41% D n/a E n/a F 21%

...Expand

: allyl citronellyl carbonate

: 106-22-9
Citronellol

Conditions

Conditions	Yield
With palladium diacetate; sodium azide; trisodium tris(3-sulfophenyl)phosphine In water; acetonitrile at 25℃; for 1h;	80%

: 106-22-9
Citronellol

: 4895-14-1
citronellylbromide

Conditions

Conditions	Yield
With carbon tetrabromide; triphenylphosphine In dichloromethane at 0℃; for 2h;	100%
With 1H-imidazole; iodine In dichloromethane at 20℃; for 0.75h;	93%
With pyridine; bromine; triphenylphosphine In tetrachloromethane; N,N-dimethyl-formamide at 45℃;	89%

: 106-22-9
Citronellol

: 100-39-0
benzyl bromide

: 96154-40-4
1-(benzyloxy)-3,7-dimethyloct-6-ene

Conditions

Conditions	Yield
Stage #1: Citronellol With sodium hydride In tetrahydrofuran at 0℃; for 0.5h; Stage #2: benzyl bromide With sodium iodide In tetrahydrofuran for 5h; Heating;	100%
Stage #1: Citronellol With sodium hydride In tetrahydrofuran; hexane for 2h; Heating; Stage #2: benzyl bromide With tetra-(n-butyl)ammonium iodide In tetrahydrofuran; hexane for 18h; Heating; Further stages.;	58%
With sodium hydride 1.) dimethoxyethane, room temperature, 2 h, 2.) room temperature, 40 h; Yield given. Multistep reaction;

: 106-22-9
Citronellol

: 98-59-9
p-toluenesulfonyl chloride

: 41144-01-8
(+/-)-citronellyl tosylate

Conditions

Conditions	Yield
With pyridine at 0 - 5℃; for 1h;	100%
With potassium hydroxide; potassium carbonate for 0.05h;	93%
With pyridine In chloroform for 0.5h; sonication;	92%

: 106-22-9
Citronellol

: 108-24-7
acetic anhydride

: 150-84-5
citronellyl-acetate

Conditions

Conditions	Yield
With pyridine In dichloromethane at 20℃;	100%
With C12H8N2*2CH4O3S at 60℃; for 3h;	99%
With iodine at 25℃; for 0.0166667h;	98%

: 106-22-9
Citronellol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 87921-26-4
tert-butyl((3,7-dimethyloct-6-en-1-yl)oxy)dimethylsilane

Conditions

Conditions	Yield
With 1H-imidazole In N,N-dimethyl-formamide at 20℃; for 24h;	100%
With dmap; triethylamine	96%
With 1H-imidazole In dichloromethane at 0 - 20℃; for 16h;	90%

: 106-22-9
Citronellol

: 14436-32-9
dec-9-enoic acid

: dec-9-enoate 3,7-dimethyl-oct-6-en-1-yl

Conditions

Conditions	Yield
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 5h; Inert atmosphere;	100%
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 20℃; for 22h; Inert atmosphere;	88%

: 106-22-9
Citronellol

: 107-92-6
butyric acid

: 141-16-2
3,7-dimethyl-6-octenyl butyrate

Conditions

Conditions	Yield
With Candida antarctica lipase B at 50℃; for 4h; Molecular sieve; Ionic liquid; Green chemistry; Enzymatic reaction;	99.9%
In n-heptane at 40℃; for 24h; lipozyme IM 20 (immobilized Mucor miehi lipase);	94.66%
In water at 30℃; for 18h; lipase from Aspergillus niger; Yield given;

: 106-22-9
Citronellol

: 802294-64-0
propionic acid

: 141-14-0
3,7-dimethyl-6-octen-1-ol propanoate

Conditions

Conditions	Yield
With Candida antarctica lipase B at 50℃; for 4h; Molecular sieve; Ionic liquid; Green chemistry; Enzymatic reaction;	99.9%
In water at 30℃; for 18h; lipase from Aspergillus niger; Yield given;

: 106-22-9
Citronellol

: 109-52-4
valeric acid

: β-citronellyl valerate

Conditions

Conditions	Yield
With Candida antarctica lipase B at 50℃; for 4h; Molecular sieve; Ionic liquid; Green chemistry; Enzymatic reaction;	99.9%
In water at 30℃; for 18h; lipase from Aspergillus niger; Yield given;

: 106-22-9
Citronellol

: 64-19-7
acetic acid

: 150-84-5
citronellyl-acetate

Conditions

Conditions	Yield
With Candida antarctica lipase B at 50℃; for 4h; Molecular sieve; Ionic liquid; Green chemistry; Enzymatic reaction;	99.9%
With cetyltrimethylammonium chloride; potassium hexacyanoferrate(III) at 80℃; for 1h;	90%
With molecular sieve at 120℃; for 8h;

: 106-22-9
Citronellol

: 814-68-6
acryloyl chloride

: 45160-93-8
3,7-dimethyloct-6-en-1-yl acrylate

Conditions

Conditions	Yield
With triethylamine at 20℃;	99.5%
With triethylamine In dichloromethane at 0℃; for 3h; Inert atmosphere;	64%

: 106-22-9
Citronellol

: 106-21-8, 59204-02-3
tetrahydrogeraniol

Conditions

Conditions	Yield
With hydrogen; platinum(IV) oxide In ethyl acetate	99%
With hydrogen; palladium on activated charcoal In ethyl acetate at 80℃; under 2585.81 Torr; for 0.0833333h; microwave irradiation;	99%
With hydrogen; palladium on activated charcoal In methanol at 20℃; for 50h;	93%

: 106-22-9
Citronellol

: 106-23-0, 26489-02-1
3,7-dimethyl-oct-6-enal

Conditions

Conditions	Yield
With pyridine chromium peroxide In dichloromethane for 1.25h; Product distribution; Ambient temperature; effect of various chromium(VI) based oxidants;	99%
With pyridine chromium peroxide In dichloromethane for 1.25h; Ambient temperature;	99%
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; 3-[4'-(diacetoxyiodo)phenoxy]-1-propyl-N,N,N-trimethylammonium 4-methylbenzenesulfonate In dichloromethane at 20℃; for 2h;	99%

: 106-22-9
Citronellol

: 124-63-0
methanesulfonyl chloride

: 42602-37-9
(±)-3,7-dimethyloct-6-en-1-yl methanesulfonate

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 0℃; for 3h; Inert atmosphere;	99%
With triethylamine In dichloromethane at 0 - 20℃; for 24.3h;	97%
With triethylamine In dichloromethane at 0 - 20℃; for 16h; Inert atmosphere;	94%

: 106-22-9
Citronellol

: 1564-98-3
6,7-epoxycitronellol

Conditions

Conditions	Yield
With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid In dichloromethane Epoxidation;	98%
With oxygen; cobalt(II) acetate; isobutyraldehyde In dichloromethane at 20℃; for 5h;	98%
With (NMe4)(Co-ortho-phenylenebis(N'-methyloxamidate)2H2OCH3CN; oxygen; pivalaldehyde In fluorobenzene for 2.5h; Ambient temperature;	95%

: 106-22-9
Citronellol

: 75-36-5
acetyl chloride

: 150-84-5
citronellyl-acetate

Conditions

Conditions	Yield
With potassium fluoride on basic alumina In toluene for 1h;	98%

: 106-22-9
Citronellol

: 74-95-3
1,2-dibromomethane

: 321858-86-0
5-(2,2-dimethylcyclopropyl)-3-methylpentan-1-ol

Conditions

Conditions	Yield
Stage #1: Citronellol; 1,2-dibromomethane With triisobutylaluminum at 10 - 20℃; for 0.25h; Stage #2: With iron(III) chloride; triisobutylaluminum at 25℃; for 3h; regioselective reaction;	98%

: 75-77-4
chloro-trimethyl-silane

: 106-22-9
Citronellol

: 18419-09-5
(3,7-dimethyloct-6-enyloxy)trimethylsilane

Conditions

Conditions	Yield
With 1,1,1,3,3,3-hexamethyl-disilazane at 25℃; Inert atmosphere;	98%

: 106-22-9
Citronellol

: 4083-64-1
Tosyl isocyanate

: C18H27NO4S

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; Inert atmosphere;	98%

Citronellol Consensus Reports

Citronellol (106-22-9) is reported in EPA TSCA Inventory.

Citronellol Specification

The Citronellol, with the CAS registry number 106-22-9, is also known as 2,3-Dihydrogeraniol. It belongs to the product categories of Acyclic Monoterpenes; Biochemistry; Terpenes; Alphabetical Listings; C-D; Flavors and Fragrances; Acyclic; Alcohols; Alkenes; Building Blocks; C9 to C10; Chemical Synthesis; Organic Building Blocks; Oxygen Compounds. Its EINECS registry number is 203-375-0. This chemical's molecular formula is C₁₀H₂₀O and molecular weight is 156.27. What's more, both its IUPAC name and systematic name are the same which is called 3,7-Dimethyloct-6-en-1-ol. It should be stored in a cool, dry and well-ventilated place.

Physical properties about Citronellol are: (1)ACD/LogP: 3.382; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 3.38; (4)ACD/LogD (pH 7.4): 3.38; (5)ACD/BCF (pH 5.5): 218.92; (6)ACD/BCF (pH 7.4): 218.92; (7)ACD/KOC (pH 5.5): 1647.35; (8)ACD/KOC (pH 7.4): 1647.35; (9)#H bond acceptors: 1; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 6; (12)Polar Surface Area: 20.23 Å²; (13)Index of Refraction: 1.45; (14)Molar Refractivity: 49.772 cm³; (15)Molar Volume: 184.902 cm³; (16)Polarizability: 19.731×10^-24cm³; (17)Surface Tension: 28.578 dyne/cm; (18)Density: 0.845 g/cm³; (19)Flash Point: 98.333 °C; (20)Enthalpy of Vaporization: 53.601 kJ/mol; (21)Boiling Point: 224.499 °C at 760 mmHg; (22)Vapour Pressure: 0.018 mmHg at 25 °C.

Preparation of Citronellol: this chemical can be prepared by 8-allyloxy-2,6-dimethyl-oct-2-ene. This reaction needs reagents Li, ROMP gel supported naphthalene and solvents tetrahydrofuran, methanol at temperature of -78 °C. The reaction time is 40 hours. The yield is 86 %.

Citronellol can be prepared by 8-allyloxy-2,6-dimethyl-oct-2-ene.

Uses of Citronellol: (1) it is can be used for the production of paint desiccant, dyeing mordant, glass and steel curing accelerator, and invisible ink and so on; (2) it is used to produce other chemicals. For example, it can react with propionic acid methyl ester to get (S)-citronellyl propionate. The reaction occurs with reagent 0.1 M phosphate buffer and other condition of ambient temperature for 96 hours. The yield is 58 %.

Citronellol can react with propionic acid methyl ester to get (S)-citronellyl propionate.

When you are dealing with this chemical, you should be very careful. This chemical may cause inflammation to the skin or other mucous membranes. And it is irritating to eyes, respiratory system and skin. Therefore, you should wear suitable protective clothing and avoid contacting with skin and eyes. In case of contacting with eyes, you should rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1) SMILES: C\C(C)=C\CCC(C)CCO
(2) InChI: InChI=1S/C10H20O/c1-9(2)5-4-6-10(3)7-8-11/h5,10-11H,4,6-8H2,1-3H3
(3) InChIKey: QMVPMAAFGQKVCJ-UHFFFAOYSA-N

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	intramuscular	4gm/kg (4000mg/kg)		Journal of Scientific and Industrial Research, Section C: Biological Sciences. Vol. 21, Pg. 342, 1962.
mouse	LD50	subcutaneous	880mg/kg (880mg/kg)	PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE	Sapporo Igaku Zasshi. Sapporo Medical Journal. Vol. 3, Pg. 73, 1952.
rabbit	LD50	skin	2650mg/kg (2650mg/kg)		Food and Cosmetics Toxicology. Vol. 13, Pg. 757, 1975.
rat	LD50	oral	3450mg/kg (3450mg/kg)		Food and Cosmetics Toxicology. Vol. 13, Pg. 757, 1975.

Product Name

6-Octen-1-ol,3,7-dimethyl-

Synthetic route

Citronellol Consensus Reports

Citronellol Specification

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