Cupric acetate monohydrate supplier

Name
Cupric acetate monohydrate
EINECS 205-553-3
CAS No. 6046-93-1
Article Data33
CAS DataBase
Density 1.882
Solubility 7.2 g/100 mL in cold water, 20 g / 100 mL in hot water, Soluble in alcohol, Slightly soluble in ether and glycerol
Melting Point 115 °C
Formula Cu(C₂H₄O₂)₂^.H₂O
Boiling Point 117.1 °C at 760 mmHg
Molecular Weight 199.651
Flash Point 40 °C
Transport Information UN 9106/3077
Appearance Dark green small crystal with odour of acetic acid
Safety 36/37/39-60-61-36-26
Risk Codes 22-36/37/38-50/53
Molecular Structure
Hazard Symbols Xn; N; Xi
Synonyms Copper(2+) acetate monohydrate;Copper(II) acetatemonohydrate;copper(2+) acetate hydrate (1:2:1);acetic acid, copper(2+) salt, hydrate (2:1:1);
PSA 89.49000
LogP -2.55440

Synthetic route

: 127-09-3
sodium acetate

: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In not given Electrolysis; 20% sodium acetate soln.; Cu anode;;	96.3%
In not given Electrolysis; 20% sodium acetate soln.; Cu electrodes; 2-8V; 50-100°C;;
In not given Electrolysis; 20% sodium acetate soln.; Cu electrodes; 2-8V; 50-100°C;;

: 127-09-3
sodium acetate

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
With acetic acid; sodium chloride Electrolysis;

: 62-54-4
calcium acetate

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
With copper(I) sulfate; copper(II) sulfate

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
With basic verdigris

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

acetic acid: acetic acid

copper turnings: copper turnings

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
With air

water: water

: 20427-59-2
copper hydroxide

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In water Cu(OH)2 treated with aq. soln. of acetic acid;

...Expand

: 64-19-7
acetic acid

: copper(II) oxide

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In acetic acid 2h; excess of concd. acetic acid;;
In acetic acid 2h; excess of concd. acetic acid;;

: 141-78-6
ethyl acetate

: copper(II) oxide

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
in the warm;;
in the warm;;

: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

: copper(II) nitrate

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In ammonia concd. acetic acid in excess; concd. aq. NH3; boiling;;
In ammonia aq. ammonia=NH3; concd. acetic acid in excess; concd. aq. NH3; boiling;;

: 62-54-4
calcium acetate

: 7758-99-8
copper(II) sulfate

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
excess of acetic acid; at 80°C;; evaporation at maximal 66°C or in vacuum;;
excess of acetic acid; at 80°C;; evaporation at maximal 66°C or in vacuum;;

...Expand

: 142-71-2
copper diacetate

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In water density at 15°C <1.10;;
In water density at 15°C <1.10;;
In not given evaporation at 33°C;;

: 7758-99-8
copper(II) sulfate

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In ammonia concd. acetic acid in excess; concd. aq. NH3; boiling;;
In ammonia aq. ammonia=NH3; concd. acetic acid in excess; concd. aq. NH3; boiling;;

: copper(II) carbonate

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In acetic acid prepn. from CuCO3 and acetic acid; recrystd. (H2O);

: 20427-59-2
copper hydroxide

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In acetic acid at ambient temp. or at 40-45°C; 8-10% acetic acid;;
In acetic acid
In acetic acid at ambient temp. or at 40-45°C; 8-10% acetic acid;;
In acetic acid

calcium acetate: calcium acetate

: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In not given Electrolysis; 20% sodium acetate soln.; Cu electrodes; 2-8V; 50-100°C;;
In not given Electrolysis; 20% sodium acetate soln.; Cu electrodes; 2-8V; 50-100°C;;

ammonium acetate: ammonium acetate

: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
With air or O2 In not given several h until formation of heat ends;; precipitation with acetic acid;;
With oxygen In not given at 35-40°C treated 2h each with NH4-acetate soln. and O2-containing gas stream;;
With O2 In not given at 35-40°C treated 2h each with NH4-acetate soln. and O2-containing gas stream;;
With air or O2 In not given several h until formation of heat ends;; precipitation with acetic acid;;

: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

: 75-07-0
acetaldehyde

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
With air or O2; copper dichloride In further solvent(s) warm air or O2 passed in soln.;;
With air or O2; copper dichloride In further solvent(s) warm air or O2 passed in soln.;;

: 64-17-5
ethanol

: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
With air or O2; copper dichloride In ethanol warm air or O2 passed in soln.;;
With air or O2; copper dichloride In ethanol warm air or O2 passed in soln.;;

: 62-54-4
calcium acetate

: 7758-99-8
copper(II) sulfate

A: calcium sulfate

B: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In not given boiling soln.; Fe-free CuSO4;; precipitation on evaporation;;
In not given boiling soln.; Fe-free CuSO4;; precipitation on evaporation;;

...Expand

: 71327-10-1
acetic acid ; acidic copper (II)-acetate

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
in moist atmosphere;;
In water evapn. at 50°C;;
in moist atmosphere;;
In water evapn. at 50°C;;

: 71327-10-1
acetic acid ; acidic copper (II)-acetate

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In neat (no solvent) by air moisture in 15 d;;
In neat (no solvent) by air moisture in 15 d;;

: calcium copper acetate hexahydrate

A: 7732-18-5
water

B: 114460-21-8
calcium acetate hydrate

C: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
at 76.2-78°C at ambient pressure during several hours;;
at 50°C at 6000 atm.;;
at 75°C at 1 atm.;;

...Expand

: [Cu(tris(3,5-dimethylpyrazolyl)methane)(NO2)]

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In dichloromethane Kinetics; solvent-removed, crystd. (CH2Cl2/Et2O);

: (tris(3,5-diethyl-1-pyrazolyl)methane)Cu(NO2)

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In dichloromethane Kinetics; solvent-removed, crystd. (CH2Cl2/Et2O);

: 127-09-3
sodium acetate

: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In not given Electrolysis; 20% sodium acetate soln.; Cu anode;;	96.3%
In not given Electrolysis; 20% sodium acetate soln.; Cu electrodes; 2-8V; 50-100°C;;
In not given Electrolysis; 20% sodium acetate soln.; Cu electrodes; 2-8V; 50-100°C;;

: 127-09-3
sodium acetate

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
With acetic acid; sodium chloride Electrolysis;

: 62-54-4
calcium acetate

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
With copper(I) sulfate; copper(II) sulfate

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
With basic verdigris

: 64-19-7
acetic acid

basic copper carbonate: basic copper carbonate

: 6046-93-1
copper(II) acetate monohydrate

: 64-19-7
acetic acid

copper turnings: copper turnings

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
With air

: 7732-18-5
water

: 20427-59-2
copper hydroxide

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In water Cu(OH)2 treated with aq. soln. of acetic acid;

...Expand

: 64-19-7
acetic acid

: copper(II) oxide

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In acetic acid 2h; excess of concd. acetic acid;;
In acetic acid 2h; excess of concd. acetic acid;;

: 141-78-6
ethyl acetate

: copper(II) oxide

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
in the warm;;
in the warm;;

: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

: copper(II) nitrate

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In ammonia concd. acetic acid in excess; concd. aq. NH3; boiling;;
In ammonia aq. ammonia=NH3; concd. acetic acid in excess; concd. aq. NH3; boiling;;

: 62-54-4
calcium acetate

: 7758-99-8
copper(II) sulfate

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
excess of acetic acid; at 80°C;; evaporation at maximal 66°C or in vacuum;;
excess of acetic acid; at 80°C;; evaporation at maximal 66°C or in vacuum;;

...Expand

: 142-71-2
copper diacetate

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In water density at 15°C <1.10;;
In water density at 15°C <1.10;;
In not given evaporation at 33°C;;

: 7758-99-8
copper(II) sulfate

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In ammonia concd. acetic acid in excess; concd. aq. NH3; boiling;;
In ammonia aq. ammonia=NH3; concd. acetic acid in excess; concd. aq. NH3; boiling;;

: copper(II) carbonate

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In acetic acid prepn. from CuCO3 and acetic acid; recrystd. (H2O);

: 20427-59-2
copper hydroxide

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In acetic acid at ambient temp. or at 40-45°C; 8-10% acetic acid;;
In acetic acid
In acetic acid at ambient temp. or at 40-45°C; 8-10% acetic acid;;
In acetic acid

: 62-54-4
calcium acetate

: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In not given Electrolysis; 20% sodium acetate soln.; Cu electrodes; 2-8V; 50-100°C;;
In not given Electrolysis; 20% sodium acetate soln.; Cu electrodes; 2-8V; 50-100°C;;

: ammonium acetate

: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
With air or O2 In not given several h until formation of heat ends;; precipitation with acetic acid;;
With oxygen In not given at 35-40°C treated 2h each with NH4-acetate soln. and O2-containing gas stream;;
With O2 In not given at 35-40°C treated 2h each with NH4-acetate soln. and O2-containing gas stream;;
With air or O2 In not given several h until formation of heat ends;; precipitation with acetic acid;;

: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

: 75-07-0
acetaldehyde

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
With air or O2; copper dichloride In further solvent(s) warm air or O2 passed in soln.;;
With air or O2; copper dichloride In further solvent(s) warm air or O2 passed in soln.;;

: 64-17-5
ethanol

: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
With air or O2; copper dichloride In ethanol warm air or O2 passed in soln.;;
With air or O2; copper dichloride In ethanol warm air or O2 passed in soln.;;

: 62-54-4
calcium acetate

: 7758-99-8
copper(II) sulfate

A: calcium sulfate

B: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In not given boiling soln.; Fe-free CuSO4;; precipitation on evaporation;;
In not given boiling soln.; Fe-free CuSO4;; precipitation on evaporation;;

...Expand

: 71327-10-1
acetic acid ; acidic copper (II)-acetate

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
in moist atmosphere;;
In water evapn. at 50°C;;
in moist atmosphere;;
In water evapn. at 50°C;;

: 71327-10-1
acetic acid ; acidic copper (II)-acetate

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In neat (no solvent) by air moisture in 15 d;;
In neat (no solvent) by air moisture in 15 d;;

: calcium copper acetate hexahydrate

A: 7732-18-5
water

B: 114460-21-8
calcium acetate hydrate

C: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
at 76.2-78°C at ambient pressure during several hours;;
at 50°C at 6000 atm.;;
at 75°C at 1 atm.;;

...Expand

: [Cu(tris(3,5-dimethylpyrazolyl)methane)(NO2)]

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In dichloromethane Kinetics; solvent-removed, crystd. (CH2Cl2/Et2O);

: (tris(3,5-diethyl-1-pyrazolyl)methane)Cu(NO2)

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In dichloromethane Kinetics; solvent-removed, crystd. (CH2Cl2/Et2O);

: (tris(3,5-diisopropyl-1-pyrazolyl)methane)Cu(NO2)

: 64-19-7
acetic acid

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In dichloromethane Kinetics; solvent-removed, crystd. (CH2Cl2/Et2O);

: C14H23NO4Si

: C28H44CuN2O8Si2

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
In methanol for 3h; Reflux;

: copper(ll) sulfate pentahydrate

: 6046-93-1
copper(II) acetate monohydrate

Conditions

Conditions	Yield
With sodium citrate; sodium hydroxide; ascorbic acid In water for 2h;

: 102942-30-3
Mo(CO)5((C6H5)2PNHCH2CH2NCHC6H4OH)

: 6046-93-1
copper(II) acetate monohydrate

: trans-{Mo(CO)5(Ph2PNHCH2CH2N=CHC6H4-o-O)}2Cu

Conditions

Conditions	Yield
In tetrahydrofuran A mixt. of Cu(OAc)2*H2O and Mo(CO)5(Ph2PNHCH2CH2NCHC6H4OH) in THF was stirred under Ar at ambient temp. for 42 h. The color of the mixt. changed from bright yellow to dark green overnight.; The mixt. was filtered and then the filtrate evapd. to dryness to yield {Mo(CO)5(Ph2PNHCH2CH2NCHC6H4O)}2Cu.;	100%

: 21051-65-0
{copper(II)-(N,N'-disalicylidene-1,3-propanediamine)}

: 6046-93-1
copper(II) acetate monohydrate

: {copper(II)-(N,N'-disalicylidene-1,3-propanediamine-μ-O,O')-(μ-CH3COO)Cu(μ-CH3O)2-Cu(μ-CH3COO)(N,N'-disalicylidene-1,3-propanediamine-μ-O,O')Cu}

Conditions

Conditions	Yield
With N(C2H5)3; CH3OH In methanol byproducts: CH3COOH; N2 bubbled through Cu(CH3COO)2 soln. for 10 min; addn. of (Cu(salpd)) and N(C2H5)3; stirred at 25°C for 36 h; filtration; washed (MeOH/Et2O); dried at 60°C under reduced pressure for 40 min; elem. anal.; IR;	100%

: 127522-45-6
(CO)5Mo(Ph2PNH(CH2)3NCHC6H4-o-OH)

: 6046-93-1
copper(II) acetate monohydrate

: Mo2Cu(2+)*10CO*2(C6H5)2PNH(CH2)3NCHC6H4O(1-)=((CO)5Mo((C6H5)2PNH(CH2)3NCHC6H4O))2Cu

Conditions

Conditions	Yield
In tetrahydrofuran react. under N2; stirring a soln. of Mo-complex and Cu-compd. in THF for 4 days at ambient temp.; evapn. to dryness, recrystn. from CH2Cl2/hexane; elem. anal.;	100%

: 5,10,15,20-tetrakis[(3,5-di-tert-butylphenyl)]porphyrin

: 6046-93-1
copper(II) acetate monohydrate

: 146164-93-4
[5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)

Conditions

Conditions	Yield
In methanol; dichloromethane refluxing a mixt. of porphyrine and copper salt in CH2Cl2 and CH3OH for 1.5 h, cooling; evapn., passing through a plug of silica (CH2Cl2), evapn.;	100%

: ammonium hexafluorophosphate

: 6046-93-1
copper(II) acetate monohydrate

: 147439-49-4
4',4''''-bis(methylsulfanyl)-2,2':6',2'':6'',2''':6''',2'''':6'''',2'''''-sexipyridine

: {Cu2((C5H4N)2(C5H2(CH3S)N)2(C5H3N)2)2}(4+)*4PF6(1-)*3H2O={Cu2((C5H4N)2(C5H2(CH3S)N)2(C5H3N)2)2}{PF6}4*3H2O

Conditions

Conditions	Yield
In methanol addn. of 1.79E-4 mol sexipyridine to a soln. of 1.8E-4 mol Cu(O2CCH3)2*H2O in methanol; stirring for 4 h at room temperature; treating with a satd. methanolic soln. of NH4PF6; pptn.;; collection; washing with methanol; recrystallization from CH3CN/diethyl ether; elem. anal.;;	100%

...Expand

Cupric acetate monohydrate Consensus Reports

Copper and its compounds are on the Community Right-To-Know List.

Cupric acetate monohydrate Specification

The Copper(II) Acetate Monohydrate, with the CAS registry number 6046-93-1 and EINECS registry number 205-553-3, has the systematic name of copper(2+) acetate hydrate (1:2:1). It is a kind of dark green small crystal with odour of acetic acid, and incompatible with oxidizing agents. And the molecular formula of the chemical is Cu(C₂H₄O₂)₂^.H₂O. What's more, it is usually used in the field of Pharmaceutical and printing & dyeing. It is also used as analytical reagent and catalyst in the organic synthesis.

The physical properties of Copper(II) Acetate Monohydrate are as followings: (1)ACD/LogP: -0.29; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -1.07; (4)ACD/LogD (pH 7.4): -2.86; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 2.73; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 2; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 0; (12)Polar Surface Area: 37.3 Å²; (13)Flash Point: 40 °C; (14)Enthalpy of Vaporization: 23.7 kJ/mol; (15)Boiling Point: 117.1 °C at 760 mmHg; (16)Vapour Pressure: 13.9 mmHg at 25°C.

Preparation and uses of Copper(II) Acetate Monohydrate: Dissolve copper sulphate with hot water, and add sodium carbonate solution, and the production is copper carbonate precipitation. Dissolve the precipitation with acetic acid, and after a series of evaporation, concentration, washing and drying, you can get the product.

You should be cautious while dealing with this chemical. It irritates to eyes, respiratory system and skin. It is toxic to aquatic organisms, and may cause long-term adverse effects in the aquatic environment. Therefore, you had better take the following instructions: Wear suitable protective clothing, gloves and eye/face protection, and in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice; This material and/or its container must be disposed of as hazardous waste; Avoid release to the environment. Refer to special instructions safety data sheet.

You can still convert the following datas into molecular structure:
(1)SMILES: [Cu+2].[O-]C(=O)C.[O-]C(=O)C.O
(2)InChI: InChI=1/2C2H4O2.Cu.H2O/c2*1-2(3)4;;/h2*1H3,(H,3,4);;1H2/q;;+2;/p-2
(3)InChIKey: NWFNSTOSIVLCJA-NUQVWONBAK

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mammal (species unspecified)	LD50	intraperitoneal	5mg/kg (5mg/kg)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS GASTROINTESTINAL: NAUSEA OR VOMITING	Journal of Animal Science. Vol. 55, Pg. 337, 1982.
mouse	LDLo	oral	1600mg/kg (1600mg/kg)		Archives of Environmental Contamination and Toxicology. Vol. 14, Pg. 111, 1985.
rat	LD50	oral	710mg/kg (710mg/kg)		American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969.

Product Name

Cupric acetate monohydrate

Synthetic route

Cupric acetate monohydrate Consensus Reports

Cupric acetate monohydrate Specification

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