Dibenzylamine supplier | CasNO.103-49-1

Name
Dibenzylamine
EINECS 203-117-7
CAS No. 103-49-1
Article Data700
CAS DataBase
Density 1.026 g/cm³
Solubility soluble in alcohol and ether, insoluble in water
Melting Point -26 °C(lit.)
Formula C₁₄H₁₅N
Boiling Point 300 °C at 760 mmHg
Molecular Weight 197.28
Flash Point 143.3 °C
Transport Information UN 2810
Appearance Colorless to light yellow liquid
Safety 26-61-45-36/37/39
Risk Codes 22-36/38-52/53-34
Molecular Structure
Hazard Symbols Xn,Xi,C
Synonyms Dibenzylamine(8CI);(N-Benzylaminomethyl)benzene;Bibenzylamine;DBA;N,N-Dibenzylamine;N-(Phenylmethyl)benzenemethanamine;N-Benzylbenzylamine;NSC 4811;
PSA 12.03000
LogP 3.36730

Synthetic route

: 780-25-6
N-benzylidene benzylamine

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With hydrogen; Ru((R,R)-cyP2N2)HCl In benzene-d6 at 20℃; under 2280.15 Torr; for 4h; Product distribution / selectivity; Alkaline conditions; Cooling with liquid nitrogen;	100%
With hydrogen; Ru((R,R)-cyP2(NH)2)HCl In benzene-d6 at 20℃; under 2280.15 Torr; for 4h; Product distribution / selectivity; Alkaline conditions; Cooling with liquid nitrogen;	100%
With bis(pentamethylcyclopentadienyl)zinc; hydrogen; 1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene In benzene-d6 at 25℃; under 75007.5 Torr; for 72h; Reagent/catalyst; Temperature; Time; Pressure; Inert atmosphere;	100%

: 621-07-8
N,N-dibenzylhydroxylamine

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With indium; ammonium chloride In ethanol for 3.5h; Product distribution; Further Variations:; Reagents; Heating;	100%
With indium(III) chloride; ammonium chloride; zinc In ethanol; water for 3.5h; Catalytic behavior; Reagent/catalyst; Reflux; chemoselective reaction;	100%
With titanium(III) chloride In methanol Ambient temperature;	93%
With hydrogen iodide
With phosphorus trichloride durch Zersetzen des Reaktionsproduktes mit Wasser;

: 27845-50-7
(E)-N-benzylidenebenzylamine

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With calcium hydride; zinc dibromide In tetrahydrofuran at 40℃; for 12h;	100%
With hydrogen; β-cyclodextrin/Pd In water at 25℃; under 15001.2 Torr; for 1h;	100%
With hydrogen; palladium on activated charcoal In tetrahydrofuran at 25℃; under 15001.2 Torr;	92%

: 1485-70-7
N-benzylbenzamide

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With 1,1,3,3-Tetramethyldisiloxane; [((CH3)5C5)IrCl((CH3)2NC6H3C5H4N)]; trityl tetrakis(pentafluorophenyl)borate In 1,1,2,2-tetrachloroethane at 100℃; for 0.5h; Inert atmosphere; Schlenk technique; Glovebox; chemoselective reaction;	100%
With indium(III) bromide; 1,1,3,3-Tetramethyldisiloxane In 5,5-dimethyl-1,3-cyclohexadiene at 140℃; for 3h; Solvent; Temperature; Sealed tube;	91%
With 1,1,3,3-Tetramethyldisiloxane; C25H23N3O2; copper(II) bis(trifluoromethanesulfonate) In toluene at 65℃; for 24h; Inert atmosphere;	90%

: 27046-29-3
N-(4-bromobenzylidene)benzylamine

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With palladium 10% on activated carbon; hydrogen In methanol at 30℃; under 22502.3 Torr;	100%

: 100-52-7
benzaldehyde

: 100-46-9
benzylamine

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With Au0998Ag0002; hydrogen In ethanol at 90℃; under 6080.41 Torr; for 24h; chemoselective reaction;	99%
With butyl triphenylphosphonium tetraborate at 20℃; for 0.166667h;	98%
With benzyltriphenylphosphonium borohydride In methanol at 20℃; for 0.333333h;	98%

: 100-47-0
benzonitrile

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With hydrogen In toluene at 90℃; under 750.075 Torr; for 20h; chemoselective reaction;	99%
With hydrogen In water at 120℃; under 37503.8 Torr; for 24h; chemoselective reaction;	98%
With sodium tetrahydroborate; nickel dichloride In methanol at 20℃; for 4h; Reduction;	96%

: 100-46-9
benzylamine

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With hydrogen In toluene at 60℃; under 7500.75 Torr; for 8h; Autoclave;	99%
With hydrogen at 140℃; under 2250.23 Torr; for 24h; Reagent/catalyst; Pressure; Molecular sieve;	98%
With 5 % Pd/TiO2 at 30℃; for 10h; Catalytic behavior; Inert atmosphere; UV-irradiation;	96%

: 905244-84-0
N,N-dibenzyl-2,4,6-triisopropylbenzenesulfonamide

A: 717-74-8
1,3,5-triisopropyl benzene

B: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With titanium(IV) isopropylate; chloro-trimethyl-silane; magnesium In tetrahydrofuran at 50℃; Inert atmosphere;	A 99% B 93%

: N,N-dibenzyl-4-nitrobenzenesulfonamide

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With potassium carbonate; mercaptoacetic acid In methanol at 0 - 25℃; Inert atmosphere; chemoselective reaction;	99%

: 1587717-84-7
(R)-N,N-dibenzyl-2-methylpropane-2-sulfinamide

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With water; iodine In tetrahydrofuran at 50℃;	99%

: C18H17NO2

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With titanium(IV) isopropylate; chloro-trimethyl-silane; magnesium In tetrahydrofuran at 50℃; for 24h;	99%

: 100-46-9
benzylamine

: 100-51-6
benzyl alcohol

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With 1,2-bis-(diphenylphosphino)ethane; palladium dichloride; lithium hydroxide In neat (no solvent) at 100℃; for 24h;	98%
With C42H44ClN4P2Ru(1+)*Cl(1-); potassium tert-butylate In tert-Amyl alcohol at 120℃; for 24h;	98%
In neat (no solvent) at 145℃; for 24h; Inert atmosphere; Sealed tube;	97%

: 100-46-9
benzylamine

: 10294-56-1
phosphorous acid

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With benzaldehyde; triethylamine	98%

: 23825-35-6
N,N-dibenzylbenzamide

A: 65-85-0
benzoic acid

B: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With 40% potassium fluoride/alumina for 0.0666667h; Microwave irradiation; Neat (no solvent);	A 98% B 95%

: 140-11-4
Benzyl acetate

: 100-46-9
benzylamine

A: 588-46-5
N-(phenylmethyl)acetamide

B: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; sodium acetate In neat (no solvent) at 115℃; for 24h; Inert atmosphere; Glovebox; Green chemistry;	A 98% B 67%

...Expand

: 92-29-5
hydrobenzamide

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With sodium tetrahydroborate In methanol at 20℃; for 2h;	97%
With ethanol; nickel at 100℃; under 73550.8 Torr; Hydrogenation;
With sodium acetate durch elektrolytische Reduktion an einer Blei-Kathode;

: 10479-30-8
N,N-dibenzylacetamide

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With ammonium bromide; ethylenediamine at 80℃; for 10h; Reagent/catalyst; Solvent; Microwave irradiation;	97%
Stage #1: N,N-dibenzylacetamide With Schwartz's reagent In tetrahydrofuran at 20℃; for 0.05h; Inert atmosphere; Stage #2: With water In tetrahydrofuran Inert atmosphere;	94%

: 1285711-92-3
N,N-dibenzyl-3-methyl-2-pyridinamine

A: 6456-92-4
1,3-dimethylpyridin-2(1H)-one

B: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
Stage #1: N,N-dibenzyl-3-methyl-2-pyridinamine With methyl trifluoromethanesulfonate In dichloromethane at 0 - 4℃; Stage #2: With sodium hydroxide In methanol at 50℃; for 6h;	A 86% B 97%

: 14618-33-8
2,2,2-trifluoro-N,N-bis(phenylmethyl)acetamide

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With potassium hydroxide	96%
With ammonium iodide; hydrazine In ethanol at 50℃; for 36h;	96%
With ammonium bromide; ethylenediamine at 50℃; for 3h; Microwave irradiation; Inert atmosphere; neat (no solvent);	86%

: 100-52-7
benzaldehyde

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
Stage #1: benzaldehyde With lithium perchlorate; 1,1,1,3,3,3-hexamethyl-disilazane at 50℃; for 0.5h; Stage #2: With sodium tetrahydroborate In methanol at 20℃; for 2h;	95%
Stage #1: benzaldehyde With titanium(IV) isopropylate; ammonium chloride; triethylamine In ethanol at 20℃; for 6h; Stage #2: With sodium tetrahydroborate In ethanol at 20℃; for 3h; Further stages.;	76%
With ammonium acetate; borohydride exchange resin; triethylamine hydrochloride In ethanol for 0.5h; Ambient temperature;	53%

: 201230-82-2
carbon monoxide

: 766-77-8
Dimethylphenylsilane

: 68452-41-5
N,N-dibenzylpropargylamine

A: 5272-18-4
dimethylphenylsilanol

B: 56-33-7
1,1,3,3-tetramethyl-1,3-diphenyldisiloxane

C: 144776-76-1
2-(dimethylphenyl)silylmethyl-2-propenal

D: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
dodecacarbonyltetrarhodium(0) In benzene at 100℃; under 14710.2 Torr; for 2h; Product distribution; other temperature, other substrates;	A n/a B n/a C 94% D n/a
dodecacarbonyltetrarhodium(0) In benzene at 100℃; under 14710.2 Torr; for 2h;	A n/a B n/a C 94% D n/a

...Expand

: 72210-07-2
N,N-dibenzyl-4-methylbenzenesulfonamide

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With titanium(IV) isopropylate; chloro-trimethyl-silane; magnesium In tetrahydrofuran at 50℃; for 12h; Inert atmosphere;	94%
With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; samarium diiodide In tetrahydrofuran for 8h; Heating;	84%
With sodium hydride In N,N-dimethyl acetamide at 60℃; for 5h; Inert atmosphere;	73%

: 100-39-0
benzyl bromide

: 100-46-9
benzylamine

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With Fe3O4-supported (diisopropylamino)acetamide In dichloromethane at 25℃;	94%
In nitrobenzene at 40℃; Rate constant; Mechanism;
In methanol at 24.84℃; Mechanism; Kinetics; Thermodynamic data; Temperature;
With tetrabutylammomium bromide; sodium hydroxide In water at 15℃; for 4h; Catalytic behavior; Solvent; Reagent/catalyst;	75 %Chromat.
In methanol at 30℃; Kinetics; Temperature;

: 137406-90-7
N-benzylidene<α-(benzotriazol-1-yl)benzyl>amine

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In tetrahydrofuran for 0.5h; Ambient temperature;	94%

: 22014-91-1
3-(dibenzylamino)prop-1-ene

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With aminomethyl resin-supported N-propylbarbituric acid; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 40℃;	93%
With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); diisobutylaluminium hydride In toluene for 1h; Ambient temperature;	82%
Grubbs catalyst first generation In toluene at 110℃; for 3.5h;	77%
Grubbs catalyst first generation In toluene for 3.5h; Heating;	77%

: 100-47-0
benzonitrile

: 100-51-6
benzyl alcohol

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With rhodium(III) chloride hydrate; potassium carbonate; triphenylphosphine at 140℃; for 9h; Inert atmosphere;	93%
With hydrogen; potassium carbonate In acetonitrile under 760.051 Torr; for 30h; Irradiation; Green chemistry; chemoselective reaction;

: 100-46-9
benzylamine

: 100-51-6
benzyl alcohol

A: 780-25-6
N-benzylidene benzylamine

B: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With Ir(PPh3)(PPEP*) In toluene for 24h; Reagent/catalyst; Reflux; Inert atmosphere; Schlenk technique; Glovebox;	A 93% B 6%
With C48H71IrN2P2 In toluene at 135℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique; Glovebox;	A 8% B 92%
With gold-ceria nanoparticle In dodecane at 180℃; for 6h; Autoclave; Inert atmosphere;	A 15% B 84%

...Expand

: 5464-77-7
N,N-dibenzylformamide

: 103-49-1
dibenzylamine

Conditions

Conditions	Yield
With ammonium bromide; ethylenediamine at 80℃; for 10h; Microwave irradiation; Inert atmosphere; neat (no solvent);	93%
With ammonium iodide; hydrazine hydrate In ethanol at 70℃; for 5h; Inert atmosphere; Sealed tube; Microwave irradiation;	92%

: 558-30-5
2-methyl-1,2-epoxypropane

: 103-49-1
dibenzylamine

: 344868-41-3
1-dibenzylamino-2-methyl-propan-2-ol

Conditions

Conditions	Yield
In ethanol at 50℃; for 72h;	100%
With water
With lithium bromide In methanol at 20 - 65℃; for 6h;
With lithium bromide at 20 - 60℃; for 18h;
With lithium bromide at 20 - 60℃; for 18h;

: 106-95-6
allyl bromide

: 103-49-1
dibenzylamine

: 22014-91-1
3-(dibenzylamino)prop-1-ene

Conditions

Conditions	Yield
With potassium carbonate In acetonitrile at 20℃; for 24h;	100%
With potassium carbonate In acetonitrile at 20℃; for 16h;	100%
With sodium perborate In water at 20℃; for 6.5h; Green chemistry;	92%

: 103-80-0
phenylacetyl chloride

: 103-49-1
dibenzylamine

: 102459-18-7
N,N-dibenzyl-2-phenylacetamide

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 20℃; for 14h; Inert atmosphere;	100%
With triethylamine In dichloromethane at 20℃;	60%

: 95-14-7
1,2,3-Benzotriazole

: 653-37-2
perfluorobenzaldehyde

: 103-49-1
dibenzylamine

: 1-(1-benzotriazol-1-yl)-1-dibenzylamino-1-pentafluorophenylmethane

Conditions

Conditions	Yield
In benzene Ambient temperature;	100%

...Expand

: 75-87-6
chloral

: 103-49-1
dibenzylamine

: 5464-77-7
N,N-dibenzylformamide

Conditions

Conditions	Yield
In chloroform at 10 - 15℃; for 12h;	100%

: 5292-43-3
bromoacetic acid tert-butyl ester

: 103-49-1
dibenzylamine

: 94226-56-9
tert-butyl 2-(dibenzylamino)ethanoate

Conditions

Conditions	Yield
In 1,4-dioxane; ethanol for 4h; Heating;	100%
In 1,4-dioxane; ethanol for 8h; Reflux;	94%
In ethanol at 20℃; for 4h;	90%
In 1,4-dioxane; ethanol for 5h; Heating;	89%

: 103-49-1
dibenzylamine

: 5336-53-8
dibenzylnitrosamine

Conditions

Conditions	Yield
With bromine; triethylamine; sodium nitrite; N-benzyl-N,N,N-triethylammonium chloride In dichloromethane; water	100%
With [NO(1+)18-crown-6H(NO3)2(1-)] In dichloromethane at 20℃; for 0.0833333h;	100%
With aluminium trichloride; silica gel; sodium nitrite In dichloromethane at 20℃; for 0.5h; Nitrosation;	99%

: (2S)-N-(2-bromopropionyl)bornane-10,2-sultam

: 103-49-1
dibenzylamine

: (2R)-N-<2-(N',N'-dibenzylamino)propionyl> bornane-10,2-sultam

Conditions

Conditions	Yield
In acetonitrile Heating;	100%

: 167934-71-6
(2R)-N-(2-bromopropionyl)bornane-10,2-sultam

: 103-49-1
dibenzylamine

: (2R)-N-<2-(N',N'-dibenzylamino)propionyl> bornane-10,2-sultam

Conditions

Conditions	Yield
In acetonitrile Heating;	100%

: 27871-49-4
(S)-Methyl lactate

: 103-49-1
dibenzylamine

: 188798-80-3
methyl (R)-2-(N,N-dibenzylamino)propanoate

Conditions

Conditions	Yield
Stage #1: (S)-Methyl lactate With 2,6-dimethylpyridine; trifluoromethylsulfonic anhydride In dichloromethane at 0℃; for 0.25h; Stage #2: dibenzylamine In dichloromethane at 20℃; for 2h;	100%
With 2,6-dimethylpyridine; trifluoromethylsulfonic anhydride 1.) CH2Cl2, 0 deg C, 15 min, 2.) room temperature, 2 h; Yield given. Multistep reaction;

: 31562-43-3
tert-butylsulfinyl chloride

: 103-49-1
dibenzylamine

: N,N-dibenzyltrimethylmethanesulfinamide

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 0℃; for 1h; sulfinylation;	100%
In dichloromethane at 0℃; for 3.33333h;	98%

: 286-20-4
cyclohexene oxide

: 103-49-1
dibenzylamine

: 97807-82-4
trans-(+/-)-2-(dibenzylamino)cyclohexanol

Conditions

Conditions	Yield
With ytterbium(III) triflate In dichloromethane at 20℃;	100%

: 106-89-8
epichlorohydrin

: 103-49-1
dibenzylamine

: 99931-16-5
1-[bis(phenylmethyl)amino]-3-chloro-2-propanol

Conditions

Conditions	Yield
at 90℃; Inert atmosphere;	100%
With calcium(II) trifluoromethanesulfonate In acetonitrile at 20℃; for 5h;	91%
In methanol for 16h;	90%

: 917-92-0
2,2-dimethyl-3-butyne

: 201230-82-2
carbon monoxide

: 103-49-1
dibenzylamine

: 252667-35-9
(E)-4,4-dimethyl-N,N-bis(phenylmethyl)-2-pentenamide

Conditions

Conditions	Yield
Stage #1: 3,3-Dimethylbut-1-yne; carbon monoxide With quinoline; tri(2-furyl)germane; tris(2,4-di-tert-butylphenyl)phosphite; bis(η3-allyl-μ-chloropalladium(II)) In toluene at 20℃; under 760.051 Torr; for 5.5h; Stage #2: dibenzylamine; dmap In toluene at 70℃; for 6h; Further stages.;	100%

...Expand

: 17392-83-5
(R)-Methyl lactate

: 103-49-1
dibenzylamine

: 87281-16-1
2-dibenzylamino-propionic acid methyl ester

Conditions

Conditions	Yield
Stage #1: (R)-Methyl lactate With 2,6-dimethylpyridine; trifluoromethylsulfonic anhydride In dichloromethane at 0℃; for 0.25h; Stage #2: dibenzylamine In dichloromethane at 20℃; for 2h;	100%

: 103-49-1
dibenzylamine

: 274694-17-6
(dibenzylamido)phosphoric dichloride

Conditions

Conditions	Yield
With trichlorophosphate In diethyl ether at 0℃; for 4h;	100%

: 24424-99-5
di-tert-butyl dicarbonate

: 103-49-1
dibenzylamine

: 203866-88-0
dibenzyl-carbamic acid tert-butyl ester

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 0.75h;	100%
With perchloric acid at 30 - 35℃; for 0.166667h;	100%
With guanidine hydrochloride In ethanol at 35 - 40℃; for 0.0166667h;	100%

: 201230-82-2
carbon monoxide

: 3923-51-1
1,1-diphenylprop-2-en-1-ol

: 103-49-1
dibenzylamine

: 4-dibenzylamino-1,1-diphenylbutan-1-ol

Conditions

Conditions	Yield
chloro(1,5-cyclooctadiene)rhodium(I) dimer In 1,4-dioxane; ethanol at 120℃; under 37503 Torr; for 65h;	100%

...Expand

: 78-84-2
isobutyraldehyde

: 103-49-1
dibenzylamine

: 121238-79-7
N,N-dibenzyl-2-methylpropan-1-amine

Conditions

Conditions	Yield
Stage #1: isobutyraldehyde; dibenzylamine With chloro-trimethyl-silane; triethylamine-borane; lithium perchlorate In diethyl ether at 20℃; for 0.333333h; Stage #2: With triethylamine-borane; lithium perchlorate In diethyl ether at 20℃; for 1h;	100%

: 816444-14-1
tert-butyl (RS)-3-benzyl-cyclopent-1-enecarboxylate

: 103-49-1
dibenzylamine

: tert-butyl (1SR,2SR,3RS)-3-benzyl-2-(N,N-dibenzylamino)-cyclopentane-1-carboxylate

Conditions

Conditions	Yield
Stage #1: dibenzylamine With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Stage #2: tert-butyl (RS)-3-benzyl-cyclopent-1-enecarboxylate In tetrahydrofuran; hexane at -78℃; for 3h; Stage #3: With potassium tert-butylate In hexane; tert-butyl alcohol for 3h; Heating;	100%

: 98-61-3
4-iodobenzenesulfonyl chloride

: 103-49-1
dibenzylamine

: 428486-70-8
N,N-dibenzyl-4-iodobenzenesulfonamide

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 80℃; under 6723.1 Torr; for 0.111667h;	100%
With triethylamine In dichloromethane at 20℃; for 16h; Inert atmosphere;	92%
With triethylamine In dichloromethane at 20℃; for 24h; Inert atmosphere;	89%

: 103-49-1
dibenzylamine

: 816444-23-2
tert-butyl (RS)-3-ethylcyclopentene-1-carboxylate

: tert-butyl (1SR,2SR,3RS)-3-ethyl-2-(N,N-dibenzylamino)-cyclopentane-1-carboxylate

Conditions

Conditions	Yield
Stage #1: dibenzylamine With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Stage #2: tert-butyl (RS)-3-ethylcyclopentene-1-carboxylate In tetrahydrofuran; hexane at -78℃; for 3h; Stage #3: With potassium tert-butylate In hexane; tert-butyl alcohol for 3h; Heating;	100%

: 103-49-1
dibenzylamine

: methyl (R)-2'-(((trifluoromethyl)sulfonyl)oxy)-[1,1'-binaphthalene]-2-carboxylate

: (R)-2-N,N-dibenzylcarbamoyl-2'-trifluoromethanesulfonyloxy-1,1'-binaphthyl

Conditions

Conditions	Yield
Stage #1: dibenzylamine With trimethylaluminum In toluene at 20℃; for 1h; Stage #2: 2'-trifluoromethanesulfonyloxy-[1,1']binaphthalenyl-2-carboxylic acid methyl ester In toluene for 3h; Heating; Further stages.;	100%

: 814-68-6
acryloyl chloride

: 103-49-1
dibenzylamine

: 57625-28-2
N,N-dibenzylprop-2-enamide

Conditions

Conditions	Yield
With N-ethyl-N,N-diisopropylamine In tetrahydrofuran at -78 - 20℃; for 1.33333h;	100%
With N-ethyl-N,N-diisopropylamine In tetrahydrofuran at -78 - 20℃; for 1.33333h;	100%
With N-ethyl-N,N-diisopropylamine In tetrahydrofuran at 0℃; for 2h;	83%

: 23056-33-9
2-chloro-4-methyl-5-nitro-pyridine

: 103-49-1
dibenzylamine

: 867034-18-2
2-(dibenzylamino)-5-nitro-4-methylpyridine

Conditions

Conditions	Yield
Stage #1: 2-chloro-4-methyl-5-nitro-pyridine; dibenzylamine With sodium carbonate In toluene for 36h; Heating / reflux; Stage #2: With hydrogenchloride In dichloromethane; water	100%

: 2211-94-1
2,3-epoxypropyl p-methoxyphenyl ether

: 64-17-5
ethanol

: 103-49-1
dibenzylamine

: 1-[bisbenzylamino]-3-(4-methoxyphenoxy)propan-2-ol

Conditions

Conditions	Yield
	100%
	100%

...Expand

Dibenzylamine Specification

The Dibenzylamine, with CAS registry number of 103-49-1, is also known as Benzenemethanamine,N-(phenylmethyl)-. The IUPAC name is N-Benzyl-1-phenylmethanamine. It belongs to product categories of Pharmaceutical Intermediates; Amines; C11 to C38; Nitrogen Compounds. Its EINECS registry number is 203-117-7. In addition, the formula is C₁₄H₁₅N and the molecular weight is 197.28. This chemical is a colorless to light yellow liquid that soluble in alcohol and ether, insoluble in water. Besides, it should be sealed in ventilated, cool place away from fire, heat, oxidants and even acids. This chemical is used as intermediates in organic synthesis and used for determination of cobalt, iron and cyanates.

Physical properties about Dibenzylamine are: (1)ACD/LogP: 3.42; (2)ACD/LogD (pH 5.5): 0.55; (3)ACD/LogD (pH 7.4): 2.05; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 9.98; (6)ACD/KOC (pH 5.5): 2.32; (7)ACD/KOC (pH 7.4): 73.67; (8)#H bond acceptors: 1; (9)#H bond donors: 1; (10)#Freely Rotating Bonds: 4; (11)Index of Refraction: 1.58; (12)Molar Refractivity: 63.88 cm³; (13)Molar Volume: 191.7 cm³; (14)Surface Tension: 40.5 dyne/cm; (15)Density: 1.028 g/cm³; (16)Flash Point: 143.3 °C; (17)Enthalpy of Vaporization: 54 kJ/mol; (18)Boiling Point: 300 °C at 760 mmHg; (19)Vapour Pressure: 0.00115 mmHg at 25 °C.

Preparation of Dibenzylamine: it is prepared by reaction of benzaldehyde with benzylamine. The reaction needs reagent benzyltriphenylphosphonium borohydride and solvent methanol at the temperature of 20 °C for 20 minutes. The yield is about 98%.

Dibenzylamine is prepared by reaction of benzaldehyde with benzylamine.

Uses of Dibenzylamine: it is used to produce dibenzyl-nitroso-amine. The reaction occurs with reagent cross-linked polyvinylpyrrolidone·N₂O₄ and solvent CH₂Cl₂ at 20 °C for 5 minutes. The yield is about 95%.

Dibenzylamine is used to produce dibenzyl-nitroso-amine.

When you are using this chemical, please be cautious about it as the following:
As a chemical, it is irritating to eyes and skin. This chemical is harmful if swallowed and also is harmful to aquatic organisms as it may cause long-term adverse effects in the aquatic environment. What's more, it causes burns. When using it, you should wear suitable protective clothing, gloves and eye/face protection. You must avoid releasing it to the environment. If contact with eyes accidently, you must rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, you should seek medical advice immediately.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: C1=CC=C(C=C1)CNCC2=CC=CC=C2
(2) InChI: InChI=1S/C14H15N/c1-3-7-13(8-4-1)11-15-12-14-9-5-2-6-10-14/h1-10,15H,11-12H2
(3)InChIKey: BWLUMTFWVZZZND-UHFFFAOYSA-N

Product Name

Dibenzylamine

Synthetic route

Dibenzylamine Specification

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