Heptafluoro-1-iodopropane supplier

Name
PERFLUOROPROPYL IODIDE
EINECS 212-045-5
CAS No. 754-34-7
Article Data26
CAS DataBase
Density 2.189 g/cm³
Solubility
Melting Point -95°C
Formula C₃F₇I
Boiling Point 37.9 °C at 760 mmHg
Molecular Weight 295.926
Flash Point 3.4 °C
Transport Information
Appearance light red liquid
Safety 23-24/25
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi;T
Synonyms Propane,heptafluoro-1-iodo- (6CI,7CI,8CI);1,1,1,2,2,3,3-Heptafluoro-3-iodopropane;1,1,2,2,3,3,3-Heptafluoro-1-iodopropane;1-Iodoheptafluoropropane;1-Iodoperfluoropropane;Heptafluoro-1-iodopropane;Heptafluoropropyl iodide;NSC 66409;Perfluoropropyl iodide;R 217I1;n-Heptafluoropropyl iodide;
PSA 0.00000
LogP 3.21180

Synthetic route

: 1349736-92-0
[(η5-pentamethylcyclopentadienyl)2Rh2I(μ-I)2(CH2CH2CF(CF3)2)]

: 1350458-19-3
[(η5-pentamethylcyclopentadienyl)2Rh2(μ-I)2(CH2CH2CF(CF3)2)2]*benzene-d6

: 603-35-0
triphenylphosphine

A: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

B: 1349737-19-4
[(η5-pentamethylcyclopentadienyl)RhI(CH2CH2CF(CF3)2)(PPh3)]

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: CH2CH2; (N2, Schlenk technique); stirring mixt. of rhodium compds. and phosphinederiv. in THF for 5 h; evapn. in vac., chromy. (silica gel, diethyl ether/hexane (1:1)), evapn., elem. anal.;	A n/a B 86%

...Expand

: 678-07-9
heptafluoropropyl-diiodo-phosphine

A: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

B: 756-18-3
bis-heptafluoropropyl-iodo-phosphine

C: 13455-01-1
phosphorous triiodide

Conditions

Conditions	Yield
220°C (48 h);	A 46% B 36% C n/a

...Expand

: 105062-53-1
C3F17IO2Te2

A: 76-19-7
freon-218

B: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

C: 91600-26-9
C3F12OTe

D TeF6: TeF6

Conditions

Conditions	Yield
at 115℃; for 26h;	A n/a B n/a C 30% D n/a

...Expand

: 756-18-3
bis-heptafluoropropyl-iodo-phosphine

A: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

B: 678-07-9
heptafluoropropyl-diiodo-phosphine

Conditions

Conditions	Yield
220°C (48 h);	A 16% B 2%
at 220℃;

: 116-14-3
polytetrafluoroethylene

: 2314-97-8
iodotrifluoromethane

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

Conditions

Conditions	Yield
Irradiation.mit UV-Licht;
photochemische Bildung;

: 116-14-3
polytetrafluoroethylene

: 2314-97-8
iodotrifluoromethane

A: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

B: 638-79-9
undecafluoro-1-iodopentane

Conditions

Conditions	Yield
UV.Irradiation;

...Expand

: 375-18-8
heptafluoro-butyryl iodide

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

Conditions

Conditions	Yield
With iodine at 550 - 600℃; in der Dampfphase;

: 377-51-5
heptafluoro-butyric acid iodoamide

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

Conditions

Conditions	Yield
at 100℃;

: 678-07-9
heptafluoropropyl-diiodo-phosphine

A: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

B: 756-18-3
bis-heptafluoropropyl-iodo-phosphine

Conditions

Conditions	Yield
at 220℃;

: 3794-64-7
silver heptafluorobutyrate

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

Conditions

Conditions	Yield
With iodine at 100℃;
With air; iodine at 150 - 160℃;
With Perfluorotributylamine; iodine at 115℃;

: 3170-79-4
heptafluoropropyl

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

Conditions

Conditions	Yield
With iodine In gas at 560 - 700℃; under 30 - 300 Torr; Equilibrium constant;

: 116-15-4
perfluoropropylene

: 2314-97-8
iodotrifluoromethane

A: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

B: 382-21-8
perfluoroisobutylene

C: 677-69-0
perfluoroisopropyl iodide

D: 1542-18-3
2-trifluoromethyl-perfluoropropyl iodide

E: 4459-18-1
perfluoro-tert-butyl iodide

F: 1,1,1,2-Tetrafluoro-2-iodo-butane

Conditions

Conditions	Yield
at 360℃; Product distribution; nickel reactor; other temperatures, influence of reactor material;

...Expand

: 107432-46-2
Perfluoro(1-propoxyethyl) iodide

A: 354-34-7
trifluoroacetyl fluoride

B: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

Conditions

Conditions	Yield
at 250℃; under 7500.6 Torr; Pyrex tube;

: 80392-00-3
C8H19O2P*C3F7I

A: 76509-66-5
diisopropyl ethylphosphonite

B: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

Conditions

Conditions	Yield
In octane at 19.9℃; Equilibrium constant; other temperatures; ΔH; ΔS; ΔG;

: 80391-99-7
C8H19O2P*C3F7I

A: 20355-93-5
dipropyl ethylphosphonite

B: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

Conditions

Conditions	Yield
In octane at 19.9℃; Equilibrium constant; other temperatures; ΔH; ΔS; ΔG;

: 80392-02-5
C10H23O2P*C3F7I

A: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

B: 24681-02-5
Diisobutoxy-ethylphosphin

Conditions

Conditions	Yield
In octane at 19.9℃; Equilibrium constant; other temperatures; ΔH; ΔS; ΔG;

: 80392-01-4
C10H23O2P*C3F7I

A: 24603-81-4
dibutyl ethylphosphonite

B: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

Conditions

Conditions	Yield
In octane at 19.9℃; Equilibrium constant; other temperatures; ΔH; ΔS; ΔG;

: 26735-60-4
heptafluoropropyl-difluoro-λ3-iodane

: 2170-06-1
1-Phenyl-2-(trimethylsilyl)acetylene

A: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

B: 932-88-7
1-iodo-2-phenylethyne

C: 886-66-8
1,4-diphenyl-1,3-butadiyne

D: 81674-08-0
3,3,4,4,5,5,5-heptafluoro-1-phenyl-1-pentyne

Conditions

Conditions	Yield
With potassium fluoride; 18-crown-6 ether In dichloromethane at 20℃; for 0.5h;

...Expand

: 375-22-4
heptafluorobutyric Acid

: 7553-56-2
iodine

A: 116-15-4
perfluoropropylene

B: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

Conditions

Conditions	Yield
at 260℃; Reaktion des Natrium-Salzes;

...Expand

: 375-18-8
heptafluoro-butyryl iodide

: 7553-56-2
iodine

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

Conditions

Conditions	Yield
at 600℃;

: 3170-79-4
heptafluoropropyl

A: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

B atomic iodine: atomic iodine

Conditions

Conditions	Yield
With iodine In gas at 560 - 700℃; under 30 - 300 Torr; Equilibrium constant;

: 116-14-3
polytetrafluoroethylene

: 2314-97-8
iodotrifluoromethane

A: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

B CF3-n-I: CF3-n-I

Conditions

Conditions	Yield
im UV-Licht.Irradiation;
at 220℃;

...Expand

: 116-14-3
polytetrafluoroethylene

: 2314-97-8
iodotrifluoromethane

A: 354-64-3
Pentafluoroethyl iodide

B: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

C: 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

D: 638-79-9
undecafluoro-1-iodopentane

E: 355-43-1
n-perfluorohexyl iodide

F: 335-58-0
perfluoroheptyl iodide

G CF3(CF2)7I, CF3(CF2)8I: CF3(CF2)7I, CF3(CF2)8I

Conditions

Conditions	Yield
In gas Product distribution; Quantum yield; Thermodynamic data; Irradiation; pulsed CO2 laser; release of reaction enthalpy, selectivity depending on pressure and temperature;

...Expand

: 116-14-3
polytetrafluoroethylene

: 2314-97-8
iodotrifluoromethane

A: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

B: 677-69-0
perfluoroisopropyl iodide

Conditions

Conditions	Yield
With aluminum chlorofluoride at 25 - 30℃; for 16h; Addition; Title compound not separated from byproducts;

...Expand

: 1623-05-8
perfluoro(propyl vinyl ether)

: 1184-76-5
difluorodiiodomethane

A: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

B: 91095-98-6
2,2,3,3-Tetrafluoro-3-iodo-propionyl fluoride

C: 1,3-diiodopentafluoropropyl heptafluoropropyl ether

D: 1,1,2,3,3-pentafluoro-2-heptafluoropropyloxy-1,3-diiodo-propane

Conditions

Conditions	Yield
at 185℃; for 3.5h; Title compound not separated from byproducts;

...Expand

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 5-phenylpentanoic acid-methoxy-methyl-amide

: 1071001-11-0
1,1,1,2,2,3,3-heptafluoro-8-phenyloctan-4-one

Conditions

Conditions	Yield
Stage #1: 1,1,1,2,2,3,3-heptafluoro-3-iodo-propane; 5-phenylpentanoic acid-methoxy-methyl-amide With methyllithium lithium bromide In diethyl ether at -78℃; for 1.5h; Stage #2: With potassium hydrogensulfate In diethyl ether; water pH=5.0;	99%
With methyllithium lithium bromide In diethyl ether at -78℃; for 1.5h; Product distribution / selectivity;	99%

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 2097-18-9
1-vinylsilatrane

: 112330-85-5
1-(2-perfluoropropyl-1-iodoethyl)silatrane

Conditions

Conditions	Yield
In chloroform for 3h; Irradiation;	98.1%
In chloroform for 3h; Irradiation;	98%

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 407-25-0
trifluoroacetic anhydride

: 77758-71-5
heptafluoropropyliodine bis(trifluoroacetate)

Conditions

Conditions	Yield
With dihydrogen peroxide In trifluoroacetic acid for 17h; Ambient temperature;	98%
With dihydrogen peroxide
With dihydrogen peroxide; trifluoroacetic acid

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 118364-67-3
4-methoxycarbonylaminothiophenol

: (4-Heptafluoropropylsulfanyl-phenyl)-carbamic acid methyl ester

Conditions

Conditions	Yield
With triethylamine In acetonitrile at 21 - 22℃; for 0.5h;	98%

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 770-14-9
3,7-dimethylenebicyclo[3.3.1]nonane

: 3-(2,2,3,3,4,4,4-heptafluorobutyl)-7-iodomethyltricyclo[3.3.1.03,7]nonane

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 6h; Irradiation;	98%

: 84692-66-0
CH2CHCH2Ge(O(CH2)2)3N

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 70565-61-6
1-iodogermatrane

Conditions

Conditions	Yield
In dichloromethane Irradiation (UV/VIS); mixt. irradiation (5 min, 20°C, vac.); (1)H-NMR spectroscopy;	97%

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 66-77-3
1-naphthaldehyde

: 62509-75-5
2,2,3,3,4,4,4-heptafluoro-1-(1-naphthyl)-1-hydroxybutane

Conditions

Conditions	Yield
Stage #1: 1,1,1,2,2,3,3-heptafluoro-3-iodo-propane With zirconocene dichloride; butyl magnesium bromide In 1,4-dioxane; diethyl ether at -78℃; for 1h; Inert atmosphere; Stage #2: 1-naphthaldehyde In 1,4-dioxane; diethyl ether at 20℃; for 1h; Inert atmosphere; chemoselective reaction;	97%
Stage #1: 1,1,1,2,2,3,3-heptafluoro-3-iodo-propane With zirconocene dichloride; 1-propylmagnesium chloride In 1,4-dioxane; diethyl ether at -78 - 0℃; for 1h; Stage #2: 1-naphthaldehyde In 1,4-dioxane; diethyl ether at 20℃; for 2h; Reagent/catalyst; Temperature;	97%

: N-methyl-N-(o-tolyl)methacrylamide

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 3-(2,2,3,3,4,4,4-heptafluorobutyl)-1,3,7-trimethylindolin-2-one

Conditions

Conditions	Yield
With ammonium cerium (IV) nitrate; 2,2'-azobis(isobutyronitrile); silver trifluoroacetate; 2-iodo-1-methoxyethane; 2,3-butane diamine; N-fluorobis(benzenesulfon)imide at 90℃; for 5h; Reagent/catalyst;	96.5%
With 2,2'-azobis(isobutyronitrile); di-tert-butyl peroxide In acetonitrile at 105℃; for 12h;	75%

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 4109-84-6
trichlorovinylstannane

: 170308-93-7
bis(perfluoropropyl)vinyltin chloride

Conditions

Conditions	Yield
With isopropylmagnesium chloride In diethyl ether byproducts: i-PrI; Ar-atmosphere; treatment of C3F7I with i-PrMgCl, slow addn. of Sn-compd.(-70°C), stirring at -40°C for 2 h, warming to room temp. overnight; distn. (reduced pressure); elem. anal.;	96%

: 592-41-6
1-hexene

: 6479-18-1
1-methyl-2(1H)-quinoxalinone

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: C18H19F7N2O

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In 1-methyl-pyrrolidin-2-one at 25℃; for 16h; Schlenk technique; Inert atmosphere; Sealed tube; Irradiation;	96%

...Expand

: 107-37-9
allyltrichlorosilane

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: Trichloro-(4,4,5,5,6,6,6-heptafluoro-2-iodo-hexyl)-silane

Conditions

Conditions	Yield
at 25 - 30℃; for 6h; Irradiation;	95%

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 557-20-0
diethylzinc

: 75-05-8
acetonitrile

: Zn(2+)*2CF3CF2CF2(1-)*2CH3CN=Zn(C2F5CF2)2*2CH3CN

Conditions

Conditions	Yield
In hexane byproducts: C2H5I, ZnI2; dry N2 atm.; cooling (-78°C), stirring (-20°C, 3 h), heating (room temp., 15 min); evapn. (vac.); elem. anal.;	95%

...Expand

: 7226-23-5
1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 557-20-0
diethylzinc

: Zn(nC3F7)2(1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone)2

Conditions

Conditions	Yield
In hexane at -60 - -20℃; for 48h; Inert atmosphere;	95%
In hexane; toluene at -35 - -5℃; for 24h; Inert atmosphere;	93%
In hexane; toluene at -41 - -5℃; for 12h; Inert atmosphere;	92%

...Expand

: 111-66-0
oct-1-ene

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 23885-16-7
1,1,1,2,2,3,3-heptafluoro-5-iodoundecane

Conditions

Conditions	Yield
With silver(I) acetate; tin(ll) chloride In methanol Ambient temperature;	94%
With ethanolamine; copper(l) chloride; copper dichloride In tert-butyl alcohol for 24h; Heating;

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

A: 105062-53-1
C3F17IO2Te2

B Cl2, TeF5OH: Cl2, TeF5OH

Conditions

Conditions	Yield
With ClOTeF5 at 25℃; for 72h;	A 94% B n/a

: 4383-22-6
Allylbenzylamine

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 124-38-9
carbon dioxide

: 3-benzyl-5-(2,2,3,3,4,4,4-heptafluorobutyl)oxazolidin-2-one

Conditions

Conditions	Yield
Stage #1: Allylbenzylamine; carbon dioxide With 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine In acetonitrile at 20℃; for 2h; Autoclave; Stage #2: 1,1,1,2,2,3,3-heptafluoro-3-iodo-propane In acetonitrile at 20℃; under 750.075 Torr; for 12h; Autoclave; Irradiation;	94%

...Expand

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 3376-23-6
N-methyl-α-phenylnitrone

: N-(2,2,3,3,4,4,4-heptafluoro-1-phenylbutyl)-N-methylhydroxylamine

Conditions

Conditions	Yield
With 2,4,6-trimethyl-pyridine; (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate; ascorbic acid In dimethyl sulfoxide at 23 - 25℃; for 2h; Inert atmosphere; Irradiation;	94%

: 7440-36-0
antimony

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 756-18-3
bis-heptafluoropropyl-iodo-phosphine

A: 51761-69-4
Tris(heptafluor-n-propyl)phosphan

B: 7790-44-5
antimony triiodide

Conditions

Conditions	Yield
230°C (16 h);	A 93% B n/a
230°C (16 h);	A 93% B n/a

...Expand

: 59645-28-2
1,2-bis(heptafluoropropyl)-1,2-bis(trifluoromethyl)diphosphine

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

A: 20608-32-6
Trifluormethyl-bis(heptafluor-n-propyl)phosphan

B: 51577-24-3
trifluoromethyl(heptafluoro-n-propyl)iodophosphine

Conditions

Conditions	Yield
Irradiation (UV/VIS); 16°C, 1 h;	A 93% B n/a
Irradiation (UV/VIS); 16°C, 1 h;	A 93% B n/a
167°C in dark;

...Expand

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 14243-78-8
Ir(CO)(PPh3)(2,4-pentanedionato)

A: 1118766-38-3
Ir(CO)(PPh3)(2,4-pentanedionato)(CF2CF2CF3)(I)

: Ir(CO)(PPh3)(2,4-pentanedionato)(CF2CF2CF3)(I)

Conditions

Conditions	Yield
In dichloromethane (N2) to soln. Ir complex in CH2Cl2 n-C3F7I was added at 0°C; solvent was removed in vacuo, residue was recrystd. from hexane-ether; elem. anal.;	A n/a B 93%

...Expand

: 7226-23-5
1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 557-20-0
diethylzinc

: C6F14Zn*2C6H12N2O

Conditions

Conditions	Yield
In hexane; toluene at -35 - -5℃; for 24h; Inert atmosphere;	93%

...Expand

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 41795-26-0
benzoic acid hex-5-enyl ester

: (E)-7,7,8,8,9,9,9-heptafluoronon-5-en-1-yl benzoate

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene; tri-(9-anthryl)borane In acetonitrile at 20℃; for 6h; Inert atmosphere; Irradiation;	93%

: 627-27-0
homoalylic alcohol

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 89621-93-2
1H,1H,2H,2H,3H,4H,4H-heptafluoro-3-iodohepta-1-ol

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0) In hexane at 4 - 20℃; for 2h; Inert atmosphere;	92%
With tetrakis(triphenylphosphine) palladium(0) In hexane at 4 - 20℃; for 2h; Inert atmosphere;	92%
tetrakis(triphenylphosphine) palladium(0) In hexane Ambient temperature;	65%
With pyridine; triiron dodecarbonyl at 60℃; for 2h;	85 % Chromat.

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 593-91-9
trimethylbismuthine

A: 2138-73-0
Dimethyl-heptafluorpropyl-wismut

B: 1957-54-6
Methyl-bis-heptafluorpropyl-wismut

Conditions

Conditions	Yield
100°C (12 h);	A 92% B 8%
100°C (12 h);	A 92% B 8%

...Expand

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 1146964-22-8
3,3-diallyl-1,5-dioxa-spiro[5.5]undecane-2,4-dione

: 1146964-23-9
C18H20F7IO4

Conditions

Conditions	Yield
With sodium dithionite; sodium carbonate In water; acetonitrile at 0℃; for 3h;	92%

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: [PtMe2(nBu-1,5-cyclooctadiene)]

: [PtMenC3F7(nBu-1,5-cyclooctadiene)]

Conditions

Conditions	Yield
In dichloromethane at 35℃; for 120h; Darkness;	92%

: 2235-00-9
vinylcaprolactam

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: (E)-1-(3,3,4,4,5,5,5-heptafluoropent-1-en-1-yl)azepan-2-one

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene; tri-(9-anthryl)borane In acetonitrile at 20℃; for 6h; Inert atmosphere; Irradiation;	92%

: 872-05-9
1-Decene

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 1,1,1,2,2,3,3-heptafluoro-5-iodotridecane

Conditions

Conditions	Yield
With pyrrolidine; Diphenylacetaldehyde In dichloromethane at 20℃; for 16h; Inert atmosphere; Irradiation;	92%

: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

: 141-43-5
ethanolamine

: 754-05-2
ethenyltrimethylsilane

: 89608-32-2
(1-iodo-3,3,4,4,5,5,5-heptafluoropentyl)trimethylsilane

Conditions

Conditions	Yield
In ethanol	91%
copper(I) chloride	2%
With iron(III) chloride

...Expand

Heptafluoro-1-iodopropane Specification

The Propane,1,1,1,2,2,3,3-heptafluoro-3-iodo- with CAS registry number of 754-34-7 is also called Perfluoropropyl iodide and n-Heptafluoropropyl iodide. It belongs to categories of Organic Fluorides. Both systematic name and IUPAC name are the same which is called 1,1,1,2,2,3,3-heptafluoro-3-iodopropane. Its EINECS registry number is 212-045-5.

Physical properties about this chemical are: (1) ACD/LogP: 4.31; (2) ACD/LogD (pH 5.5): 4.31; (3) ACD/LogD (pH 7.4): 4.31; (4) ACD/BCF (pH 5.5): 1107.2; (5) ACD/BCF (pH 7.4): 1107.2; (6) ACD/KOC (pH 5.5): 5256.01; (7) ACD/KOC (pH 7.4): 5256.01; (8) #Freely Rotating Bonds: 1; (9) Index of Refraction: 1.361; (10) Molar Refractivity: 29.96 cm³; (11) Molar Volume: 135.1 cm³ ; (12) Polarizability: 11.87×10^-24cm³; (13) Surface Tension: 17.7 dyne/cm; (14) Density: 2.189 g/cm³; (15) Flash Point: 3.4 °C; (16) Enthalpy of Vaporization: 27.09 kJ/mol; (17) Boiling Point: 37.9 °C at 760 mmHg; (18) Vapour Pressure: 478 mmHg at 25°C; (19) Melting Point: -95 °C; (20) Storage temp. : 2-8 °C; (21) Sensitive: Light Sensitive; (22) Stability: Stable. Incompatible with strong oxidizing agents.

Preparation of Propane,1,1,1,2,2,3,3-heptafluoro-3-iodo- : this chemical is prepared by C₃F₁₇IO₂Te₂.

This reaction needs the temperature of 115 °C, and the reaction time is 26 hours. The yield is 30%.

Uses of Propane,1,1,1,2,2,3,3-heptafluoro-3-iodo-: it is used to produce other chemicals. For example, it is used to produce 1H,2H-heptafluoro-1-iodo-pent-1-ene.

This reaction will occur at temperature of 200 °C for 6 hours and other condition of steel cylinder. The yield is 76%.

When you are using this chemical, please be cautious about it as the following:
As a chemical, it is irritating to eyes, respiratory system and skin. Avoid contact with skin and eyes. And do not breathe vapour.

You can still convert the following datas into molecular structure:
(1) SMILES: FC(F)(F)C(F)(F)C(F)(F)ICopyCopied;
(2) InChI: InChI=1/C3F7I/c4-1(5,2(6,7)8)3(9,10)11;
(3) InChIKey: XTGYEAXBNRVNQU-UHFFFAOYAV;
(4) Std. InChI: InChI=1S/C3F7I/c4-1(5,2(6,7)8)3(9,10)11;
(5) Std. InChIKey: XTGYEAXBNRVNQU-UHFFFAOYSA-N

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LC50	inhalation	404gm/m³/2H (404000mg/m³)		"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 76, 1982.

Product Name

PERFLUOROPROPYL IODIDE

Synthetic route

Heptafluoro-1-iodopropane Specification

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