Hexylamine supplier | CasNO.111-26-2

Name
Hexylamine
EINECS 203-851-8
CAS No. 111-26-2
Article Data229
CAS DataBase
Density 0.766
Solubility 14 g/L (20 ºC)
Melting Point −23 °C(lit.)
Formula C6H15 N
Boiling Point 131-132 °C(lit.)
Molecular Weight 101.192
Flash Point 27 ºC
Transport Information UN 2734
Appearance colourless liquid
Safety A poison by intraperitoneal route. Moderately toxic by ingestion, inhalation, and skin contact. A severe skin and eye irritant. Dangerous fire hazard when exposed to heat or flame; can react with oxidizing materials. To fight fire, use alcohol foam, CO₂, dry chemical. Upon decomposition it emits toxic fumes of NO_x. See also AMINES.
Risk Codes R10;R20/21/22;R35
Molecular Structure
Hazard Symbols
Synonyms Hexylamine(6CI,8CI); 1-Aminohexane; 1-Hexaneamine; 1-Hexylamine; ENT 16554;Mono-n-hexylamine; NSC 2590; n-Hexylamine
PSA 26.02000
LogP 2.22570

Synthetic route

: 646-14-0
1-nitrohexane

: 111-26-2
hexan-1-amine

Conditions

Conditions	Yield
With carbon monoxide; Au/TiO2-VS; water In ethanol at 25℃; under 3800.26 Torr; for 5.5h; Autoclave; chemoselective reaction;	100%
With trichlorosilane; N-ethyl-N,N-diisopropylamine In acetonitrile at 15℃; for 18h;	100%
With 5%-palladium/activated carbon; hydrogen In para-xylene; isopropyl alcohol at 25℃; under 760.051 Torr; Reagent/catalyst; Temperature;	100%

: 628-73-9
hexanenitrile

: 111-26-2
hexan-1-amine

Conditions

Conditions	Yield
With triethylamine alane In tetrahydrofuran for 0.5h; Ambient temperature;	96.5%
With hydrogen; aluminum oxide; silica gel; nickel In methanol; ammonia at 160℃; under 7600 Torr; for 1h;	95%
With palladium; hydrogen In ethanol at 50℃; under 3750.38 Torr; for 24h; Temperature;	90%

: 20320-48-3
N-hexylphthalimide

A: 111-26-2
hexan-1-amine

B: 612-14-6
phthalyl alcohol

Conditions

Conditions	Yield
With C25H19BrMnN2O2P; potassium tert-butylate; hydrogen In tetrahydrofuran at 130℃; under 22502.3 Torr; for 48h; Inert atmosphere; Glovebox; Autoclave; Green chemistry;	A 95% B 90%
With [Ru(PtBuNNHtBu)H(CO)Cl]; potassium tert-butylate; hydrogen In tetrahydrofuran at 110℃; under 15001.5 Torr; for 24h; Autoclave;

: 628-02-4
Caproamide

: 111-26-2
hexan-1-amine

Conditions

Conditions	Yield
With triethylamine alane In tetrahydrofuran for 48h; Ambient temperature;	93%
With hydrogen; hexarhodium hexadecacarbonyl; decacarbonyldirhenium(0) In 1,2-dimethoxyethane; diethylamine at 180℃; under 76000 Torr; for 8h;	76%
With sodium tetrahydroborate; methanesulfonic acid In dimethyl sulfoxide	74%

: 6926-45-0
1-azidohexane

: 111-26-2
hexan-1-amine

Conditions

Conditions	Yield
With formiate d'ammonium; palladium on activated charcoal In methanol Ambient temperature;	93%
With formiate d'ammonium; palladium on activated charcoal In methanol Product distribution; Ambient temperature;	93%
With sodium tetrahydroborate; lithium chloride In tetrahydrofuran at 0 - 35℃; for 0.5h;	90%

: 628-73-9
hexanenitrile

A: 111-26-2
hexan-1-amine

B: 143-16-8
dihexylamine

Conditions

Conditions	Yield
With hydrogen; aluminum oxide; carbon monoxide In cyclohexane at 120℃; under 152000 Torr; for 2.73333h;	A 91% B 9%
With ammonium hydroxide; chloro(1,5-cyclooctadiene)rhodium(I) dimer; hydrogen at 100℃; under 20686.5 Torr; for 24h; Autoclave; Green chemistry; chemoselective reaction;

: 66-25-1
hexanal

: 111-26-2
hexan-1-amine

Conditions

Conditions	Yield
With ammonium formate In toluene at 80℃; for 4h; Reagent/catalyst; Inert atmosphere; chemoselective reaction;	91%
With ammonium hydroxide; ammonium acetate; hydrogen; [Ru(cod)Cl]2; trisodium tris(3-sulfophenyl)phosphine In toluene at 145℃; under 48754.9 Torr; for 10h;	45 % Chromat.
Multi-step reaction with 3 steps 1: 1,4-dioxane / 0.5 h / 60 °C / Inert atmosphere 2: copper(l) iodide; caesium carbonate / 1,4-dioxane / 3.5 h / 110 °C / Inert atmosphere 3: hydrazine hydrate / 1,4-dioxane / 110 °C / Inert atmosphere View Scheme

: 628-73-9
hexanenitrile

A: 111-26-2
hexan-1-amine

B: 143-16-8
dihexylamine

C: 102-86-3
tri-n-hexylamine

Conditions

Conditions	Yield
With hydrogen; Pt/Al2O3 In cyclohexane at 120℃; under 152000 Torr; for 2.66667h;	A 5.6% B 89% C 5.4%
With hydrogen; aluminum oxide; nickel In cyclohexane at 120℃; under 152000 Torr; for 0.416667h; Product distribution; variation of temperature, time, catalyst;	A 57.5% B 41.3% C 1.2%

...Expand

: 207558-25-6
hexylcarbamic acid tert-butyl ester

: 111-26-2
hexan-1-amine

Conditions

Conditions	Yield
With nitric acid In dichloromethane at 0℃; for 1h;	89%

: 20320-48-3
N-hexylphthalimide

: 111-26-2
hexan-1-amine

Conditions

Conditions	Yield
With hydrazine hydrate In 1,4-dioxane at 110℃; Gabriel Amine Synthesis; Inert atmosphere;	84%
With potassium hydroxide; sodium hydroxide at 200 - 280℃; Yield given;

: 6621-59-6
6-bromo-1-hexanenitrile

: 111-26-2
hexan-1-amine

Conditions

Conditions	Yield
With indium(III) chloride; sodium tetrahydroborate In tetrahydrofuran at 25℃; for 4h; Inert atmosphere;	76%

: 142-62-1
hexanoic acid

A: 110-54-3
hexane

B: 111-26-2
hexan-1-amine

C: 143-16-8
dihexylamine

D: 628-02-4
Caproamide

E: 10264-29-6
N-(n-hexyl)hexanamide

Conditions

Conditions	Yield
Stage #1: hexanoic acid With cyclopentyl methyl ether; ammonia at 200℃; under 4500.45 Torr; Sealed tube; Green chemistry; Stage #2: With cyclopentyl methyl ether; ammonia; hydrogen at 200℃; under 42004.2 Torr; for 6.5h; Cooling with ice; Green chemistry;	A n/a B 75% C 13% D n/a E 6%

...Expand

: 646-14-0
1-nitrohexane

A: 111-26-2
hexan-1-amine

B: 90422-09-6
N-hydroxyhexan-1-amine

Conditions

Conditions	Yield
With 5%-palladium/activated carbon; hydrogen In para-xylene; isopropyl alcohol at 25℃; under 760.051 Torr; for 4h; Reagent/catalyst;	A 26% B 72%
With 5%-palladium/activated carbon; hydrogen In isopropyl alcohol at 20℃; under 750.075 Torr; for 2h;	A 6 %Spectr. B 94 %Spectr.

: 16343-08-1
hexylboronic acid

: 111-26-2
hexan-1-amine

Conditions

Conditions	Yield
With N-Bromosuccinimide; CYANAMID; bis-[(trifluoroacetoxy)iodo]benzene In acetonitrile at 20℃; for 2h; chemoselective reaction;	72%
With N-Bromosuccinimide; N-methoxylamine hydrochloride; bis-[(trifluoroacetoxy)iodo]benzene In acetonitrile at 20℃; for 3h;	65%

: 127146-31-0
1-hexyl-dimethylborane

: 111-26-2
hexan-1-amine

Conditions

Conditions	Yield
With ammonium hydroxide; sodium hypochlorite In water 1.) 0 deg C, 5-10 min, 2.) 0 deg C -> room temperature;	67%

: 64-18-6
formic acid

: 646-14-0
1-nitrohexane

A: 111-26-2
hexan-1-amine

B: 2591-78-8
N-hexylformamide

Conditions

Conditions	Yield
With cobalt nanoparticles anchoring on nitrogen doped carbon, pyrolysis at 700 °C In acetonitrile at 110℃; under 750.075 Torr; for 5h; Inert atmosphere; chemoselective reaction;	A n/a B 59.2%

...Expand

: 146303-94-8
hexylmethylphenylborane

A: 111-26-2
hexan-1-amine

B: 62-53-3
aniline

Conditions

Conditions	Yield
With ammonium hydroxide; sodium hypochlorite In diethyl ether at 25℃; for 0.5h;	A 38% B 56%

: 124-04-9
Adipic acid

A: 105-60-2
caprolactam

B: 111-49-9
hexamethylene imine

C: 21920-79-6
6-(azepan-1-yl)hexan-1-amine

D: 111-26-2
hexan-1-amine

E: 110-58-7
1-pentanamine

Conditions

Conditions	Yield
Stage #1: Adipic acid With cyclopentyl methyl ether; ammonia at 200℃; under 4500.45 Torr; Sealed tube; Green chemistry; Stage #2: With cyclopentyl methyl ether; ammonia; hydrogen at 200℃; under 42004.2 Torr; for 6.5h; Cooling with ice; Green chemistry;	A 39% B 53% C 4% D 2% E 2%

...Expand

: 628-62-6
heptanamide

A: 111-26-2
hexan-1-amine

B: 111-14-8
oenanthic acid

Conditions

Conditions	Yield
With sodium hydroxide; sodium persulfate; sodium chloride In water at 85 - 90℃; for 7h;	A 35% B 52%
With sodium hydroxide; sodium persulfate; sodium chloride In water at 85 - 90℃; for 7h;	A 35% B 49%

(n-C6H13)3ZnMgBr: (n-C6H13)3ZnMgBr

: 111-26-2
hexan-1-amine

Conditions

Conditions	Yield
Stage #1: (n-C6H13)3ZnMgBr With O-Methylhydroxylamin In tetrahydrofuran at 20℃; for 3h; Amination; Stage #2: With ammonia; water; ammonium chloride at 20℃; for 2h; Hydrolysis;	50%

: 67-56-1
methanol

: 6926-45-0
1-azidohexane

A: 111-26-2
hexan-1-amine

B: 4385-04-0
N,N-dimethylhexylamine

C: 42870-70-2
N-methylhexan-1-amine hydrochloride

Conditions

Conditions	Yield
Stage #1: methanol; 1-azidohexane With trans-RuCl(phenpyra-Me)(PPh3)2PF6; sodium hydroxide at 125℃; for 5h; Sealed tube; Inert atmosphere; Glovebox; Stage #2: With hydrogenchloride	A 10 %Chromat. B 12 %Chromat. C 42%

...Expand

: 102-86-3
tri-n-hexylamine

A: 111-26-2
hexan-1-amine

B: 143-16-8
dihexylamine

C: 34695-21-1
N-hexylidenehexan-1-amine

Conditions

Conditions	Yield
With dicarbonyl(chloro)(η5-pentaphenylcyclopentadienyl)ruthenium(II); ammonia In tert-Amyl alcohol at 170℃; for 23.5h; Inert atmosphere; Schlenk technique; Autoclave;	A 12% B 8% C 41.5%

...Expand

: 13822-55-4
di(n-hexyl)zinc

(: (

: 111-26-2
hexan-1-amine

Conditions

Conditions	Yield
Stage #1: di(n-hexyl)zinc; ( With O-Methylhydroxylamin In tetrahydrofuran at 20℃; for 3h; Amination; Stage #2: With ammonia; water; ammonium chloride at 20℃; for 2h; Hydrolysis;	35%

: 631-61-8
ammonium acetate

: 111-27-3
hexan-1-ol

A: 592-41-6
1-hexene

B: 111-26-2
hexan-1-amine

C: 142-92-7
1-hexyl acetate

D: 7501-79-3
N-hexylacetamide

E: 66-25-1
hexanal

Conditions

Conditions	Yield
With water at 400℃; for 1h; Product distribution / selectivity;	A 29.4 %Chromat. B 1.9 %Chromat. C 4 %Chromat. D 30.8% E 1.3 %Chromat.
With water at 380 - 420℃; for 0.05 - 1h; Product distribution / selectivity;	A 0.2 - 11.29 %Chromat. B 0.21 - 6.52 %Chromat. C 1.53 - 10.25 %Chromat. D 7.03 - 78.52 %Chromat. E 0.36 - 1.28 %Chromat.

...Expand

: 97308-22-0
N-(t-butyldimetylsilyl)aziridine

(Bu)2CuLi: (Bu)2CuLi

: 111-26-2
hexan-1-amine

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate In tetrahydrofuran	30%

: 10264-29-6
N-(n-hexyl)hexanamide

A: 111-26-2
hexan-1-amine

B: 143-16-8
dihexylamine

C: 111-27-3
hexan-1-ol

Conditions

Conditions	Yield
With ruthenium(1,1,1-tris(di(3,5-dimethylphenyl)phosphinomethyl)ethane)(η4-trimethylenemethane); tris(pentafluorophenyl)borate; hydrogen In tetrahydrofuran at 160℃; under 75007.5 Torr; for 16h;	A 7.6% B 26.03% C 5.4%
With aluminium(III) triflate; ruthenium(1,1,1-tris(di(3,5-dimethylphenyl)phosphinomethyl)ethane)(η4-trimethylenemethane); hydrogen In tetrahydrofuran at 160℃; under 75007.5 Torr; for 16h;	A 5.4% B 19.04% C 13.1%

...Expand

: 143-16-8
dihexylamine

A: 628-73-9
hexanenitrile

B: 111-26-2
hexan-1-amine

C: 102-86-3
tri-n-hexylamine

Conditions

Conditions	Yield
With dicarbonyl(chloro)(η5-pentaphenylcyclopentadienyl)ruthenium(II); ammonia In tert-Amyl alcohol at 170℃; for 23.5h; Inert atmosphere; Schlenk technique; Autoclave;	A 8.5% B 25% C 11%

...Expand

: 124-38-9
carbon dioxide

: 62-53-3
aniline

: 111-26-2
hexan-1-amine

Conditions

Conditions	Yield
With Pd/C; hydrogen In ethanol at 130℃; for 24h;	11%

: 110-89-4
piperidine

: 41495-45-8
1-Pentyl-1-hexylamine

A: 10324-58-0
1-pentylpiperidine

B: 7335-01-5
1-hexylpiperidine

C: 111-26-2
hexan-1-amine

D: 143-16-8
dihexylamine

E: 110-58-7
1-pentanamine

F: 2050-92-2
Di-n-amylamine

Conditions

Conditions	Yield
With hydrogen; sulphidized CoO-MoO3 at 300℃; under 45003.6 Torr; for 1h; Mechanism; Product distribution;	A 5.5% B 8.5% C 4% D 3% E 1% F 2.5%

...Expand

: 111-26-2
hexan-1-amine

: 100-52-7
benzaldehyde

: 19340-96-6
N-benzylidenehexylamine

Conditions

Conditions	Yield
at 20℃; for 2h;	100%
With ethanol; potassium carbonate
With aluminum oxide for 2h; Ambient temperature;

: 111-26-2
hexan-1-amine

: 598-21-0
2-Bromoacetyl bromide

: 5439-32-7
2-bromo-N-hexylethanamide

Conditions

Conditions	Yield
With potassium carbonate In dichloromethane; water at 5 - 20℃; for 4h;	100%
With potassium carbonate In dichloromethane; water at 4 - 20℃; for 4.5h;	100%
With potassium carbonate In dichloromethane; water at 0 - 20℃; for 6.5h;	100%

: 506-68-3
bromocyane

: 111-26-2
hexan-1-amine

: 15784-76-6
n-hexylcyanamide

Conditions

Conditions	Yield
	100%
In tetrahydrofuran; diethyl ether at 0℃; for 3.5h; Inert atmosphere;	80%
With sodium carbonate In tetrahydrofuran at -20 - 0℃;

: 67-56-1
methanol

: 111-26-2
hexan-1-amine

: 4385-04-0
N,N-dimethylhexylamine

Conditions

Conditions	Yield
chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) at 100℃;	100%
With tris(triphenylphosphine)ruthenium(II) chloride at 180℃; for 7h;	88%
With C53H41ClN3OP2Ru(1+)*F6P(1-); sodium methylate at 110℃; for 24h; Inert atmosphere; Glovebox; Schlenk technique; Sealed tube; Green chemistry;	77%

: 111-26-2
hexan-1-amine

: 7677-24-9
trimethylsilyl cyanide

: 87367-65-5
4,4'-[decane-1,10-diylbis(oxy)]dibenzaldehyde

: 145100-47-6
(4-{10-[4-(Cyano-hexylamino-methyl)-phenoxy]-decyloxy}-phenyl)-hexylamino-acetonitrile

Conditions

Conditions	Yield
In dichloromethane for 120h;	100%

...Expand

: 111-26-2
hexan-1-amine

: 64-19-7
acetic acid

: 7501-79-3
N-hexylacetamide

Conditions

Conditions	Yield
triphenylantimony(V) diacetate In pyridine at 100℃; for 10h;	100%
With silica In toluene for 8h; Dean-Stark; Reflux; Green chemistry;	99%
tetraphosphorus decasulfide; triphenyl antimony oxide In benzene at 40℃; for 5h;	90%
With HOBt-6-carboxamidomethyl polystyrene; dicyclohexyl-carbodiimide 1.) CH2Cl2, 25 deg C, 2.) CH2Cl2, 25 deg C, 4 h; Yield given. Multistep reaction;
With Sc(OTf)3 immobilized onto mesoporous at 80℃; for 24h; Product distribution; Further Variations:; Reagents;

: 111-26-2
hexan-1-amine

: 4637-24-5
N,N-dimethyl-formamide dimethyl acetal

: 85599-94-6
N2-n-hexyl-N1,N1-dimethylformamidine

Conditions

Conditions	Yield
at 60℃;	100%

: 111-26-2
hexan-1-amine

: 105-54-4
butanoic acid ethyl ester

: 10264-17-2
N-hexylbutanamide

Conditions

Conditions	Yield
at 40℃; for 1h; lipase SP 382 (from Candida sp.);	100%

: 111-26-2
hexan-1-amine

: 78-92-2, 15892-23-6
iso-butanol

: 20007-05-0
N-(sec-butyl)hexan-1-amine

Conditions

Conditions	Yield
With Zr6O4(OH)4(BDC-NH2)5.7([LIr]BF4)0.3 at 80℃; for 24h; Catalytic behavior; Autoclave; Green chemistry;	100%
dihydridotetrakis(triphenylphosphine)ruthenium In neat (no solvent) at 180℃; for 6h;	52 % Chromat.

: 111-26-2
hexan-1-amine

: 624-31-7
4-tolyl iodide

: 56506-60-6
N-(4-methylphenyl)hexylamine

Conditions

Conditions	Yield
With 2-(2-methyl-1-oxopropyl)cyclohexanone; caesium carbonate; copper(l) iodide In N,N-dimethyl-formamide at 25℃; for 1.5h;	100%
With caesium carbonate; copper(I) bromide In dimethyl sulfoxide at 55℃; for 24h; Ullmann coupling;	87%
With tetra(n-butyl)ammonium hydroxide; copper(l) chloride In water at 80℃; for 24h; Inert atmosphere;	86%

: 111-26-2
hexan-1-amine

: 66046-61-5
2-chloro-3-methyl-1-oxa-3-aza-2-phosphacyclopentane 2-oxide

: 184417-25-2
Hexyl-(3-methyl-2-oxo-2λ5-[1,3,2]oxazaphospholidin-2-yl)-amine

Conditions

Conditions	Yield
With triethylamine In dichloromethane for 17h; Ambient temperature;	100%

: 111-26-2
hexan-1-amine

: 180716-18-1
2-(bromomethyl)-7-(benzyloxy)chroman

: 198986-38-8
(7-Benzyloxy-chroman-2-ylmethyl)-hexyl-amine

Conditions

Conditions	Yield
at 100℃; for 2h;	100%

: 591-50-4
iodobenzene

: 111-26-2
hexan-1-amine

: 4746-32-1
N-hexylaniline

Conditions

Conditions	Yield
With 2-(2-methyl-1-oxopropyl)cyclohexanone; caesium carbonate; copper(l) iodide In N,N-dimethyl-formamide at 25℃; for 1.16667h;	100%
With copper(l) iodide; 1-(5,6,7,8-tetrahydroquinolin-8-yl)ethan-1-one; caesium carbonate In N,N-dimethyl-formamide at 25℃; for 10h; Ullmann condensation; Inert atmosphere;	97%
With caesium carbonate; copper(I) bromide In dimethyl sulfoxide at 55℃; for 24h; Ullmann coupling;	91%

: 917-92-0
2,2-dimethyl-3-butyne

: 111-26-2
hexan-1-amine

: 201230-82-2
carbon monoxide

: (E)-4,4-Dimethyl-pent-2-enoic acid hexylamide

Conditions

Conditions	Yield
Stage #1: 3,3-Dimethylbut-1-yne; carbon monoxide With quinoline; tri(2-furyl)germane; tris(2,4-di-tert-butylphenyl)phosphite; bis(η3-allyl-μ-chloropalladium(II)) In toluene at 20℃; under 760.051 Torr; for 5.5h; Stage #2: hexan-1-amine; dmap In toluene at 70℃; for 6h; Further stages.;	100%

...Expand

: 57-48-7
D-Fructose

: 111-26-2
hexan-1-amine

: 1,2-dideoxy-1,2-di-n-hexylamino-D-(N)-β-glucoside

Conditions

Conditions	Yield
With 4 A molecular sieve; zinc(II) chloride at -20℃; for 48h;	100%

: 111-26-2
hexan-1-amine

: 1145-80-8
N-(benzyloxycarbonyl)-L-serine

: 138739-31-8
((S)-1-Hexylcarbamoyl-2-hydroxy-ethyl)-carbamic acid benzyl ester

Conditions

Conditions	Yield
With benzotriazol-1-ol; N-(3-dimethylaminopropyl)-N-ethylcarbodiimide In N,N-dimethyl-formamide	100%

: 111-26-2
hexan-1-amine

: 696-62-8
para-iodoanisole

: 16664-54-3
N-(n-hexyl)-p-methoxyaniline

Conditions

Conditions	Yield
With 2-(2-methyl-1-oxopropyl)cyclohexanone; caesium carbonate; copper(l) iodide In N,N-dimethyl-formamide at 25℃; for 1.83333h;	100%
With copper(l) iodide; 1-(5,6,7,8-tetrahydroquinolin-8-yl)ethan-1-one; caesium carbonate In N,N-dimethyl-formamide at 25℃; for 12h; Ullmann condensation; Inert atmosphere;	97%
With copper(l) iodide; 1-tetralone oxime; potassium hydroxide In water at 25℃; for 36h; Sealed tube; Inert atmosphere; Green chemistry;	94%

: 111-26-2
hexan-1-amine

: 6068-70-8
triphenylacetyl chloride

: N-hexyl-2,2,2-triphenyl-acetamide

Conditions

Conditions	Yield
With dmap; triethylamine In dichloromethane for 48h;	100%

: 111-26-2
hexan-1-amine

: 1489-69-6
Cyclopropanecarboxaldehyde

: [1-Cyclopropyl-meth-(E)-ylidene]-hexyl-amine

Conditions

Conditions	Yield
With magnesium sulfate In dichloromethane Heating;	100%

: 637-87-6
1-Chloro-4-iodobenzene

: 111-26-2
hexan-1-amine

: 56506-62-8
N-(4-chlorophenyl)-n-hexylamine

Conditions

Conditions	Yield
With 2-(2-methyl-1-oxopropyl)cyclohexanone; caesium carbonate; copper(l) iodide In N,N-dimethyl-formamide at 25℃; for 0.833333h;	100%
With copper(l) iodide; 1-tetralone oxime; potassium hydroxide In water at 25℃; for 18h; Sealed tube; Inert atmosphere; Green chemistry;	92%
With copper(l) iodide; 1-(5,6,7,8-tetrahydroquinolin-8-yl)ethan-1-one; caesium carbonate In N,N-dimethyl-formamide at 25℃; for 12h; Ullmann condensation; Inert atmosphere;	91%

: 111-26-2
hexan-1-amine

: 3058-39-7
4-iodobenzonitrile

: 4-(N-Hexyl)aminobenzonitrile

Conditions

Conditions	Yield
With 2-(2-methyl-1-oxopropyl)cyclohexanone; caesium carbonate; copper(l) iodide In N,N-dimethyl-formamide at 25℃; for 0.666667h;	100%
With copper(l) iodide; 1-(5,6,7,8-tetrahydroquinolin-8-yl)ethan-1-one; caesium carbonate In N,N-dimethyl-formamide at 25℃; for 10h; Ullmann condensation; Inert atmosphere;	95%
With copper(l) iodide; 1-tetralone oxime; potassium hydroxide In water at 25℃; for 18h; Sealed tube; Inert atmosphere; Green chemistry;	95%

: 111-26-2
hexan-1-amine

: 141-97-9
ethyl acetoacetate

: ethyl 4-(N-hexylamino)but-2-enoate

Conditions

Conditions	Yield
With erbium(III) triflate In dichloromethane at 20℃; for 2h;	100%

: 868-84-8
S,S-dimethyl dithiocarbonate

: 111-26-2
hexan-1-amine

: 120904-15-6
S-methyl N-hexylthiocarbamate

Conditions

Conditions	Yield
In water at 20 - 25℃; for 2h;	100%

: 111-26-2
hexan-1-amine

: H2Ti4O9*1.9H2O

: 1.1C6H13NH3(1+)*0.9H(1+)*Ti4O9(2-)*2.4H2O = (C6H13NH3)1.1H0.9Ti4O9*2.4H2O

Conditions

Conditions	Yield
In not given heating to 100°C for 2 days; centrifugation; filtration; washing (ethanol, acetone); drying in vac. for 1 h; chem. anal.; TGA; electron diffraction;	100%
In not given stirring for 6 days at 50°C; centrifugation; filtration; washing (ethanol, acetone); drying in vac. for 1 h; chem. anal.; TGA; electron diffraction;

: 111-26-2
hexan-1-amine

: 1042070-13-2
C16H21NO7

: 1042070-07-4
C19H26N2O5

Conditions

Conditions	Yield
In methanol at 20℃;	100%

: 111-26-2
hexan-1-amine

: 60-12-8
2-phenylethanol

: 10264-30-9
N-hexyl-2-phenylacetamide

Conditions

Conditions	Yield
With cyclooctadiene ruthenium(II) dichloride; potassium tert-butylate; 1,3-diisopropyl-1H-imidazol-3-ium chloride; tricyclopentylphosphonium tetrafluoroborate In toluene for 24h; Inert atmosphere; Reflux;	100%
With dichloro(1,5-cyclooctadiene)ruthenium(II); potassium tert-butylate; 1,3-diisopropyl-1H-imidazol-3-ium chloride; tricyclopentylphosphonium tetrafluoroborate In toluene at 110℃; for 24h; Inert atmosphere;	100%
With pyridine; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; sodium hydride; 1,3-di(propan-2-yl)-1H-imidazol-3-ium bromide In toluene for 36h; Inert atmosphere; Reflux;	98%

: 111-26-2
hexan-1-amine

: 100-51-6
benzyl alcohol

: 25468-44-4
N-benzylhexylamine

Conditions

Conditions	Yield
With Zr6O4(OH)4(BDC-NH2)5.7([LIr]BF4)0.3 at 120℃; for 0.5h; Catalytic behavior; Temperature; Microwave irradiation; Green chemistry;	100%
With lithium hydroxide In neat (no solvent) at 120℃; for 24h; Inert atmosphere;	94%
With palladium nanoparticles embedded in the solid matrix of tetrabutylammonium bromide synthetized in supercritical carbon dioxide at 140℃; Sealed tube; Inert atmosphere; Green chemistry;	88%

: 111-26-2
hexan-1-amine

: 5336-08-3
D-Ribono-1,4-lactone

: 1190205-35-6
N-hexyl-D-ribonamide

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 20℃; for 1h;	100%
In N,N-dimethyl-formamide at 20℃; for 1h;

Hexylamine Chemical Properties

Chemical Name: Hexylamine
IUPAC NAME: Hexan-1-amine
CAS No.: 111-26-2
EINECS: 203-851-8
RTECS: MQ4540000
RTECS Class: Primary Irritant
EC Class: Flammable, Harmful, Corrosive
Molecular Formula: C₆H₁₅N
Molecular Weight: 101.19 g/mol
Melting Point: -23 °C(lit.)
Density: 0.77 g/cm³
Flash Point: 8.9 °C
Boiling Point: 131.8 °C at 760 mmHg
Water Solubility: 14 g/L (20 ºC)
Sensitive: Air Sensitive
Following is the structure of Hexylamine (111-26-2):

Product Categories about are Alkylamines ; Monofunctional & alpha,omega-Bifunctional Alkanes ; Monofunctional Alkanes
The chemical synonymous of are Ethyl-N-butylamine ; Hexylamine ; 1-Amine-N-hexane ; 1-Aminohexane ; 1-Hexylamine ; Amine C6 ; Rarechem Al Bw 0240 ; N-hexylamine

Hexylamine Toxicity Data With Reference

1.	eye-rbt 750 µg/24H SEV	85JCAE Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,434.
2.	skn-rbt 500 mg open SEV	UCDS** Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 11/3 ,1971.
3.	eye-rbt 5 mg MOD	UCDS** Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 11/3 ,1971.
4.	orl-rat LD50:670 mg/kg	AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
5.	ihl-rat LCLo:500 ppm/4H	AEHLAU Archives of Environmental Health. 1 (1960),343.
6.	ipr-mus LDLo:16 mg/kg	CBCCT* “Summary Tables of Biological Tests“ National Research Council Chemical-Biological Coordination Center. 2 (1950),188.
7.	skn-rbt LD50:420 mg/kg	AEHLAU Archives of Environmental Health. 1 (1960),343.

Hexylamine Consensus Reports

Reported in EPA TSCA Inventory.

Hexylamine Safety Profile

A poison by intraperitoneal route. Moderately toxic by ingestion, inhalation, and skin contact. A severe skin and eye irritant. Dangerous fire hazard when exposed to heat or flame; can react with oxidizing materials. To fight fire, use alcohol foam, CO₂, dry chemical. Upon decomposition it emits toxic fumes of NO_x. See also AMINES.
Hazard Note: Irritant/Flammable/Corrosive/Air Sensitive
Hazard Codes:
C: Corrosive
F: Flammable
Xi: Irritant
Risk Statements about Hexylamine (111-26-2):
R10 Flammable.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R35 Causes severe burns.
Safety Statements about Hexylamine (111-26-2):
S16 Keep away from sources of ignition - No smoking.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Attention:
1. Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
2. Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.

Hexylamine Standards and Recommendations

DOT Classification: 8; Label: Corrosive, Flammable Liquid (UN 2734); DOT Class: 3; Label: Flammable Liquid, Corrosive (UN 2733)

Product Name

Hexylamine

Synthetic route

Hexylamine Chemical Properties

Hexylamine Toxicity Data With Reference

Hexylamine Consensus Reports

Hexylamine Safety Profile

Hexylamine Standards and Recommendations

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