Product Name

  • Name

    HYDROXYLAMINE NITRATE

  • EINECS 236-691-2
  • CAS No. 13465-08-2
  • Article Data14
  • CAS DataBase
  • Density 1.09 g/mL at 20 °C
  • Solubility 587g/L at 20℃
  • Melting Point
  • Formula H4N2O4
  • Boiling Point 83 °C at 760 mmHg
  • Molecular Weight 96.0428
  • Flash Point
  • Transport Information
  • Appearance
  • Safety 26-45-36/37/39-35
  • Risk Codes 1-36/37/38-43-48-34-20/21/22
  • Molecular Structure Molecular Structure of 13465-08-2 (HYDROXYLAMINE NITRATE)
  • Hazard Symbols HarmfulXn; IrritantXi; CorrosiveC
  • Synonyms Hydroxylamine, nitrate;HYDROXYLAMINE NITRATE;LGP 1898;Hydroxylamine, nitrate (salt);Hydroxylammonium nitrate;Hydroxylamine,compounds,nitrate (salt);
  • PSA 112.30000
  • LogP 0.21010

Synthetic route

hydroxylamine
7803-49-8

hydroxylamine

hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

Conditions
ConditionsYield
In neat (no solvent) reaction by influence of O3 on undiluted NH2OH;; condensation by cooling in a ether CO2 mixture;;
hydroxyammonium sulfate

hydroxyammonium sulfate

barium nitrite

barium nitrite

hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

barium nitrite

barium nitrite

NH3OH-oxalate
4682-08-0

NH3OH-oxalate

hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

Conditions
ConditionsYield
In not given evapn. of soln. in vac. at lower temp., residue with alcohol absorpted;
In not given evapn. of soln. in vac. at lower temp., residue with alcohol absorpted;
potassium chlorate
3811-04-9

potassium chlorate

hydroxylammonium perchlorate
15588-62-2

hydroxylammonium perchlorate

hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

Conditions
ConditionsYield
In water mixing components solns. (small amount of NH3OH-salt), water removal (distn.) to dryness; no isolation in pure state; IR spectroscopy;
hydroxylamine hydrochloride
5470-11-1

hydroxylamine hydrochloride

silver nitrate

silver nitrate

hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

Conditions
ConditionsYield
With ozone evapn. of soln. over H2SO4;
With ozone evapn. of soln. over H2SO4;
hydroxylammonium chlorate
66857-72-5

hydroxylammonium chlorate

A

hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

B

chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

Conditions
ConditionsYield
In water decompn. in aq. soln.;
perchloryl fluoride
7616-94-6

perchloryl fluoride

hydroxylamine
7803-49-8

hydroxylamine

A

hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

B

hydroxylammonium fluoride
17256-78-9

hydroxylammonium fluoride

Conditions
ConditionsYield
In ethanol -70 to -60°C, storing (120 h), gradual increase of temperature; IR spectroscopy;
hydroxylamine
7803-49-8

hydroxylamine

hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

Conditions
ConditionsYield
With ozone ice cooling in an ether-CO2 mixture;
With ozone ice cooling in an ether-CO2 mixture;
hydroxyammonium sulfate

hydroxyammonium sulfate

barium(II) nitrate

barium(II) nitrate

hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

Conditions
ConditionsYield
In water byproducts: BaSO4; conc. soln. of (NH2OH)2*H2SO4 added to Ba(NO3)2 soln. heated to 60 °C; BaSO4 sepd, by centrifugation;
hydroxylammonium chlorate
66857-72-5

hydroxylammonium chlorate

hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

Conditions
ConditionsYield
slow dehydration of small amt. of comp. to avoid expolosion;
Cyclohexanone oxime
100-64-1

Cyclohexanone oxime

hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

Conditions
ConditionsYield
With nitric acid In ethylbenzene at 40℃; under 1500.15 Torr; for 0.666667h;
acetylhydroxamic acid
546-88-3

acetylhydroxamic acid

A

hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

B

acetic acid
64-19-7

acetic acid

Conditions
ConditionsYield
With europium(III) nitrate hexahydrate; water; nitric acid pH=Ca. 0.28 - Ca. 1.21; Kinetics;
hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

A

nitrogen
7727-37-9

nitrogen

B

water
7732-18-5

water

C

oxygen
80937-33-3

oxygen

D

Nitrogen dioxide
10102-44-0

Nitrogen dioxide

Conditions
ConditionsYield
With catalyst: Pt/Si-doped Al2O3 In water catalytic decompn. of NH3OH(NO3)/H2O energetic liquid at 45°C on Pt supported on Si-doped alumina;
hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

A

nitrogen
7727-37-9

nitrogen

B

water
7732-18-5

water

C

nitrogen(II) oxide
10102-43-9

nitrogen(II) oxide

Conditions
ConditionsYield
With catalyst: Pt/(Al2O3)0.88(SiO2)012 In water byproducts: NO2, N2O, O2; 79% aq. NH3OHNO3 decompd. in increasing temp. mode or at 40°C in const. volume batch reactor; monitored by online analysis by mass spectrometer;
hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

A

water
7732-18-5

water

B

nitric acid
7697-37-2

nitric acid

C

dinitrogen monoxide
10024-97-2

dinitrogen monoxide

Conditions
ConditionsYield
In neat (no solvent) Kinetics; 463 - 523 K, 27.5 MPa;
hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

A

water
7732-18-5

water

B

nitrogen(II) oxide
10102-43-9

nitrogen(II) oxide

C

Nitrogen dioxide
10102-44-0

Nitrogen dioxide

D

dinitrogen monoxide
10024-97-2

dinitrogen monoxide

Conditions
ConditionsYield
In neat (no solvent) Kinetics; between 84.8-120.9°C;
hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

nitric acid
7697-37-2

nitric acid

Conditions
ConditionsYield
In water Kinetics; byproducts: H2O, N2O, N2; aq. soln. of nitrate was heated at 2°C/min;
hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

A

nitric acid
7697-37-2

nitric acid

B

Nitrogen dioxide
10102-44-0

Nitrogen dioxide

C

dinitrogen monoxide
10024-97-2

dinitrogen monoxide

Conditions
ConditionsYield
In solid Ar atmosphere; thermolysis of solid hydroxylammonium nitrate (15-500 psi Ar, heating rate 130 K/s);
With cobalt doped cerium oxide at 120 - 130℃; Thermodynamic data; Reagent/catalyst; Inert atmosphere;
hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

Nitrogen dioxide
10102-44-0

Nitrogen dioxide

Conditions
ConditionsYield
In water decompn. above 110°C;
In water decompn. above 110°C;
hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

sodium nitrite
7632-00-0

sodium nitrite

dinitrogen monoxide
10024-97-2

dinitrogen monoxide

Conditions
ConditionsYield
In not given Kinetics; byproducts: water;
In not given Kinetics; byproducts: water;
potassium cyanate
590-28-3

potassium cyanate

hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

N-hydroxyurea
127-07-1

N-hydroxyurea

Conditions
ConditionsYield
In ethanol; water -15°C;
hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

barium nitrite

barium nitrite

dinitrogen monoxide
10024-97-2

dinitrogen monoxide

Conditions
ConditionsYield
In not given Kinetics; byproducts: water;
In not given Kinetics; byproducts: water;
lithium nitrite
13568-33-7

lithium nitrite

hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

dinitrogen monoxide
10024-97-2

dinitrogen monoxide

Conditions
ConditionsYield
In not given Kinetics; byproducts: water;
In not given Kinetics; byproducts: water;
potassium nitrite
7758-09-0

potassium nitrite

hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

dinitrogen monoxide
10024-97-2

dinitrogen monoxide

Conditions
ConditionsYield
In not given Kinetics; byproducts: water;
In not given Kinetics; byproducts: water;
hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

strontium nitrite

strontium nitrite

dinitrogen monoxide
10024-97-2

dinitrogen monoxide

Conditions
ConditionsYield
In not given Kinetics; byproducts: water;
In not given Kinetics; byproducts: water;
hydroxylamine nitrate
13465-08-2

hydroxylamine nitrate

Nitrite

Nitrite

dinitrogen monoxide
10024-97-2

dinitrogen monoxide

Conditions
ConditionsYield
In not given Kinetics; byproducts: water;
In not given Kinetics; byproducts: water;

Hydroxyazanium nitrate Specification

The Hydroxyazanium nitrate, with CAS registry number 13465-08-2, belongs to the following product categories: (1)Ammonium; (2)Inorganic Salts; (3)Synthetic Reagents. It has the systematic name of hydroxylamine nitrate (1:1). And the chemical formula of this chemical is H4N2O4. What's more, its EINECS is 236-691-2.

Physical properties of Hydroxyazanium nitrate: (1)ACD/LogP: -0.13; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 0; (4)ACD/LogD (pH 7.4): 0; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)#H bond acceptors: 4; (8)#H bond donors: 1; (9)#Freely Rotating Bonds: 0; (10)Polar Surface Area: 55.05 Å2; (11)Enthalpy of Vaporization: 37.72 kJ/mol; (12)Boiling Point: 83 °C at 760 mmHg; (13)Vapour Pressure: 49.8 mmHg at 25°C.

When you are using this chemical, please be cautious about it as the following:
The Hydroxyazanium nitrate is explosive when dry. This chemical irritates to eyes, respiratory system and skin. It is harmful by inhalation and if swallowed. It may cause sensitization by skin contact. And it has danger of serious damage to health by prolonged exposure. When use it, wear suitable protective clothing, gloves and eye/face protection. If contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

You can still convert the following datas into molecular structure:
(1)SMILES: [O-][N+](=O)O.ON
(2)InChI: InChI=1/HNO3.H3NO/c2-1(3)4;1-2/h(H,2,3,4);2H,1H2
(3)InChIKey: NILJXUMQIIUAFY-UHFFFAOYAI
(4)Std. InChI: InChI=1S/HNO3.H3NO/c2-1(3)4;1-2/h(H,2,3,4);2H,1H2
(5)Std. InChIKey: NILJXUMQIIUAFY-UHFFFAOYSA-N

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