N,N-Dimethylpropargylamin
A
N,N-dimethylaminopropane
B
N,N-dimethyl-2-propen-1-amine
Conditions | Yield |
---|---|
With hydrogen; copper-palladium; silica gel In ethanol at 25℃; under 760 Torr; Kinetics; | A n/a B 100% |
Conditions | Yield |
---|---|
With hydrogen; copper-palladium; silica gel In ethanol at 25℃; under 760.051 Torr; | 100% |
With piperazine; hydrogen In ethanol at 80℃; under 4500.45 Torr; for 24h; | 99% |
With piperazine; hydrogen In ethanol at 100℃; under 4500.45 Torr; for 24h; Green chemistry; | |
With hydrogen In ethanol at 100℃; under 4500.45 Torr; for 24h; chemoselective reaction; | 96 %Chromat. |
A
N,N-dimethyl-2-propen-1-amine
Conditions | Yield |
---|---|
With potassium hydroxide In water at 90 - 92℃; for 1.5h; | A 8% B 71% |
Allyl-dimethylcarbamoylmethyl-dimethyl-ammonium; bromide
A
N,N-dimethyl-2-propen-1-amine
B
2-(dimethylamino)-N,N-dimethylacetamide
C
2-Dimethylamino-pent-4-enoic acid dimethylamide
Conditions | Yield |
---|---|
With potassium hydroxide In benzene at 65 - 70℃; for 1h; metallic sodium in DMSO was also used instead of potassium hydroxide; | A n/a B n/a C 70% |
Allyl-(1-methoxycarbonyl-ethyl)-dimethyl-ammonium; bromide
A
N,N-dimethyl-2-propen-1-amine
B
2-Dimethylamino-2-methyl-pent-4-enoic acid methyl ester
C
acrylic acid methyl ester
Conditions | Yield |
---|---|
With sodium methylate In diethyl ether at 30 - 35℃; Yield given; | A n/a B 69% C n/a |
With sodium methylate In diethyl ether at 30 - 35℃; Yields of byproduct given; | A n/a B 69% C n/a |
Conditions | Yield |
---|---|
In water 1) 30 min, 2) reflux, 30 min.; | 62.5% |
In water Ambient temperature; | 51% |
In benzene | 36% |
Conditions | Yield |
---|---|
With formic acid for 8h; Heating; | 58% |
Conditions | Yield |
---|---|
With formaldehyd In water at 100℃; for 12h; | 46% |
Conditions | Yield |
---|---|
copper(l) chloride In water | 30% |
B
N,N-dimethylaminomethylferrocene
C
propene
D
N,N-dimethyl-2-propen-1-amine
Conditions | Yield |
---|---|
With sodium In ammonia | A 30% B 26% C n/a D n/a |
With Na In ammonia NH3 (liquid); | A 30% B 26% C n/a D n/a |
formic acid
allyl-trimethyl-ammonium; hydroxide
A
N,N-dimethyl-2-propen-1-amine
B
Methyl formate
C
3-formyloxy-propene
D
trimethylamine
Conditions | Yield |
---|---|
at 190 - 200℃; |
allyl trimethylammonium bromide
ethanolamine
A
N,N-dimethyl-2-propen-1-amine
B
trimethylamine
Conditions | Yield |
---|---|
at 154℃; Rate constant; |
Conditions | Yield |
---|---|
With ethanol at 150℃; |
Conditions | Yield |
---|---|
With sodium hydroxide | |
Stage #1: dimethyl amine; 3-chloroprop-1-ene In water at 20 - 30℃; Autoclave; Stage #2: With sodium hydroxide In water for 0.333333h; pH=11 - 13; pH-value; Autoclave; |
N-benzyl-N,N-dimethylprop-2-en-1-ylammonium bromide
N,N-dimethyl-2-propen-1-amine
Conditions | Yield |
---|---|
With sodium hydroxide; thiophenol |
N,N-dimethyl-2-propen-1-amine
Conditions | Yield |
---|---|
With potassium hydroxide |
3-(dimethylamino)-1-propyl acetate
A
N,N-dimethyl-2-propen-1-amine
B
acetic acid methyl ester
C
N,N'-dimethyl-1-propenylamine
D
acetic acid
E
dimethyl amine
F
prop-1-yne
Conditions | Yield |
---|---|
at 347.1℃; Mechanism; Kinetics; other temperatures, various pressures, effect of propene inhibitors; Ea, log A; |
Allyl-but-2-inyl-dimethyl-ammonium
A
3-buten-1-yne
B
N,N-dimethyl-2-propen-1-amine
Conditions | Yield |
---|---|
With potassium hydroxide; tert-butylamine at 50℃; Yield given; |
N,N-dimethyl-2-propen-1-amine
Conditions | Yield |
---|---|
bei der Destillation; |
A
N,N-dimethyl-2-propen-1-amine
Conditions | Yield |
---|---|
With potassium hydroxide durch Destillation; |
A
N,N-dimethyl-2-propen-1-amine
B
bisisopropenyl ether
C
dimethyl amine
hexa-N-methyl-N,N'-propanediyl-di-ammonium; dihydroxyide
A
N,N-dimethyl-2-propen-1-amine
B
4-methylpent-4-en-2-one
C
trimethylamine
Conditions | Yield |
---|---|
bei der Destillation; |
3-dimethylamino-2-methyl-N-isopropylpropanamide
3-chloroprop-1-ene
A
N,N-dimethyl-2-propen-1-amine
B
N-isopropylmethacrylamide
Conditions | Yield |
---|---|
In water |
hexadecyl allyl carbonate
diethylamine
A
N,N-dimethyl-2-propen-1-amine
B
1-Hexadecanol
Conditions | Yield |
---|---|
With tri(3-sulfonatophenyl)phosphine trisodium salt; palladium diacetate; pyrographite In n-heptane; water at 20℃; Tsuji-Trost reaction; Inert atmosphere; |
allyl 1-decyl carbonate
diethylamine
A
N,N-dimethyl-2-propen-1-amine
B
1-Decanol
Conditions | Yield |
---|---|
With tri(3-sulfonatophenyl)phosphine trisodium salt; palladium diacetate; pyrographite In n-heptane; water at 20℃; Tsuji-Trost reaction; Inert atmosphere; |
diethylamine
allyl butyl carbonate
A
N,N-dimethyl-2-propen-1-amine
B
butan-1-ol
Conditions | Yield |
---|---|
With tri(3-sulfonatophenyl)phosphine trisodium salt; palladium diacetate; pyrographite In n-heptane; water at 20℃; Tsuji-Trost reaction; Inert atmosphere; |
Conditions | Yield |
---|---|
With tri(3-sulfonatophenyl)phosphine trisodium salt; palladium diacetate; pyrographite In n-heptane; water at 20℃; Tsuji-Trost reaction; Inert atmosphere; |
Conditions | Yield |
---|---|
With tri(3-sulfonatophenyl)phosphine trisodium salt; palladium diacetate; pyrographite In n-heptane; water at 20℃; Tsuji-Trost reaction; Inert atmosphere; |
Conditions | Yield |
---|---|
With hydrogen; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; Rh(acac)2(CO)2 In tetrahydrofuran at 70℃; under 15001.2 Torr; for 68h; | 100% |
N,N-dimethyl-2-propen-1-amine
(E)-1-N,N-dimethylamino-1-propene
Conditions | Yield |
---|---|
With hydridocarbonylbis(triphenylphosphine)rhodium(I) In benzene-d6 at 60℃; for 2h; Inert atmosphere; | 99% |
+ In tetrahydrofuran at 17℃; for 23h; Yield given; | |
With trans-bisdinitrogenbis(1,2-diphenylphosphinoethane)molybdenum(0) In toluene for 2h; Heating; | 100 % Chromat. |
carbonylhydridetris(triphenylphosphine)rhodium(I) In benzene-d6 at 60℃; for 2h; | 100 % Spectr. |
With [(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]-(η4-1,5-cyclooctadiene)rhodium(I) perchlorate In tetrahydrofuran at 40℃; for 23h; Inert atmosphere; | n/a |
Conditions | Yield |
---|---|
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In tetrahydrofuran at 60℃; Inert atmosphere; Sealed tube; | 99% |
N,N-dimethyl-2-propen-1-amine
Triethoxysilane
N,N-dimethyl-3-(triethoxysilyl)-1-propylamine
Conditions | Yield |
---|---|
With platinum-containing olefin organic polymer catalyst at 20℃; for 24h; | 98% |
With (TFAPDI)Co(2-ethylhexanoate)2 In neat (no solvent) at 23℃; for 1h; | 74% |
dicobalt octacarbonyl | |
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex at 80℃; for 20h; Schlenk technique; Inert atmosphere; regioselective reaction; | 94.8 %Spectr. |
With C28H34CoN3O4(1+)*C5H7O2(1-) In tetrahydrofuran at 50℃; for 6h; Sealed tube; |
N,N-dimethyl-2-propen-1-amine
(3aS,6R,7aR)-1-(bromoacetyl)-8,8-dimethylhexahydro-3a,6-methano-2,1-benzothiazole 2,2-dioxide
Conditions | Yield |
---|---|
In tetrahydrofuran at 20℃; for 6h; | 98% |
N,N-dimethyl-2-propen-1-amine
N,N-dimethyl allylamine-borane
Conditions | Yield |
---|---|
In diethyl ether (inert atm.); stirring (1 h, 0°C); MeOH addn., stirring (30 min, room temp.), solvent removal (vac.), trituration (petroleum ether), evpn. (vac.); | 98% |
Conditions | Yield |
---|---|
With C25H30N2NiO In acetonitrile at 25℃; for 1h; | 98% |
With C25H31N2NiO In acetonitrile at 20℃; for 1h; | 98% |
With N-(1-[2,2′-bipyridin-6-yl]ethylidene)-2,4,6-trimethylbenzenamine iron(II) bromide; sodium triethylborohydride In toluene at 20℃; for 24h; Catalytic behavior; Reagent/catalyst; Schlenk technique; Inert atmosphere; | 94% |
dimethylphosphane
N,N-dimethyl-2-propen-1-amine
A
3-(N,N-dimethylamino)-1-(dimethylphosphino)propane
B
1,3-bis(dimethylphosphino)propane
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In diethyl ether at -20℃; for 24h; Product distribution; Mechanism; Irradiation; reactions under var. conditions; | A 97% B n/a |
With 2,2'-azobis(isobutyronitrile) In diethyl ether at -20℃; for 24h; Irradiation; | A 97% B n/a |
2-chloro-4,6-dimethoxy-1 ,3,5-triazine
N,N-dimethyl-2-propen-1-amine
2-(dimethylamino)-4,6-dimethoxy-1,3,5-triazine
Conditions | Yield |
---|---|
In toluene Reflux; | 97% |
N,N-dimethyl-2-propen-1-amine
methyl iodide
N,N,N-trimethylallylammonium iodide
Conditions | Yield |
---|---|
In diethyl ether at 20℃; for 3h; Inert atmosphere; | 97% |
N,N-dimethyl-2-propen-1-amine
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
C11H24BNO2
Conditions | Yield |
---|---|
With C28H30CoNP In benzene-d6 at 20℃; for 0.5h; Inert atmosphere; | 97% |
With [(2,6-(2,4,6-Me3-C6H2-NdCMe)2C5H3N)Fe(N2)]2(μ2-N2) In neat (no solvent) at 25℃; Reagent/catalyst; Inert atmosphere; | |
With (MesPDI)CoMe In neat (no solvent) at 23℃; for 0.25h; Schlenk technique; Inert atmosphere; Glovebox; |
N,N-dimethyl-2-propen-1-amine
3-chloroprop-1-ene
dimethyldiallylammonium chloride
Conditions | Yield |
---|---|
Stage #1: N,N-dimethyl-2-propen-1-amine; 3-chloroprop-1-ene at 30 - 55℃; for 4.5h; Stage #2: With sodium hydroxide pH=11; Temperature; pH-value; | 97% |
Conditions | Yield |
---|---|
In diethyl ether at 0 - 20℃; for 2.25h; Schlenk technique; Inert atmosphere; | 97% |
diazoacetic acid ethyl ester
N,N-dimethyl-2-propen-1-amine
2-(N,N-dimethylamino)-4-pentenoic acid ethyl ester
Conditions | Yield |
---|---|
With 5,10,15,20-tetrakis(pentafluorophenyl)-21H,23H-porphyrin iron(III) chloride In dichloromethane at 20℃; for 0.0166667h; | 96% |
carbonyl(5,10,15,20-tetraphenylporphyrinato)ruthenium(II) In toluene at 50℃; for 5h; | 87% |
hexarhodium hexadecacarbonyl at 60℃; | 82% |
With copper acetylacetonate In benzene at 60℃; for 22h; Inert atmosphere; | 35% |
carbonyl(5,10,15,20-tetraphenylporphyrinato)ruthenium(II) In dichloromethane at 20℃; for 24h; | 100 % Chromat. |
tetraallyltitanate
N,N-dimethyl-2-propen-1-amine
methylphenylsilane
{(CH3)2N(CH2)3Si(C6H5)(CH3)OTi(OC3H5)2O(CH2)3}2Si(CH3)C6H5
Conditions | Yield |
---|---|
dihydrogen hexachloroplatinate byproducts: propene; to a mixt. of titanate and silane (molar ratio 1:4) catalyst was added and heated to 100°C for 2.5 h; unreacted silane was removed at 50-80 °C and 1-2 Torr within 4 h; then titanosiloxane was reacted with excess amine at 50°C, 4 h;; unreacted amine was removed by heating in vac.; elem. anal.;; | 96% |
Conditions | Yield |
---|---|
With 2-chloro-4,6-dimethoxy-1 ,3,5-triazine In toluene Reflux; | 96% |
Conditions | Yield |
---|---|
With C25H30N2NiO In acetonitrile at 25℃; for 1h; | 96% |
With C25H31N2NiO In acetonitrile at 20℃; for 0.5h; | 96% |
trimethoxysilane
N,N-dimethyl-2-propen-1-amine
A
<3-(dimethylamino)propyl>trimethoxysilane
Conditions | Yield |
---|---|
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; ammonium bicarbonate In toluene at 55℃; for 8h; Reagent/catalyst; | A 95.5% B 6.7% |
N,N-dimethyl-2-propen-1-amine
[N-(p-tolylsulfonyl)imino]phenyliodinane
Conditions | Yield |
---|---|
Stage #1: N,N-dimethyl-2-propen-1-amine With 2C15H31BBr3N6(1-)*2Ag(1+) In dichloromethane for 0.0833333h; Inert atmosphere; Glovebox; Stage #2: [N-(p-tolylsulfonyl)imino]phenyliodinane In dichloromethane at 50℃; for 16h; Inert atmosphere; Glovebox; chemoselective reaction; | 95% |
N,N-dimethyl-2-propen-1-amine
1-diazo-2-heptadecanone
Conditions | Yield |
---|---|
chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) In chloroform at 60℃; for 0.25h; | 94% |
N,N-dimethyl-2-propen-1-amine
Conditions | Yield |
---|---|
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In toluene at 90℃; regioselective reaction; | 94% |
N,N-dimethyl-2-propen-1-amine
1-diazopentan-2-one
Conditions | Yield |
---|---|
chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) In chloroform at 60℃; for 0.25h; | 93% |
N,N-dimethyl-2-propen-1-amine
1-diazo-2-tridecanone
Conditions | Yield |
---|---|
chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) In chloroform at 60℃; for 0.25h; | 93% |
N,N-dimethyl-2-propen-1-amine
Conditions | Yield |
---|---|
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In toluene at 90℃; regioselective reaction; | 93% |
N,N-dimethyl-2-propen-1-amine
Triethoxysilane
A
N,N-dimethyl-3-(triethoxysilyl)-1-propylamine
Conditions | Yield |
---|---|
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; ammonium bicarbonate In toluene at 55℃; for 17h; Reagent/catalyst; | A 92.3% B 6.8% |
diazoacetone
N,N-dimethyl-2-propen-1-amine
3-dimethylamino-5-hexen-2-one
Conditions | Yield |
---|---|
chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) In chloroform at 60℃; for 0.25h; | 92% |
N,N-dimethyl-2-propen-1-amine
1-diazo-3-methylbutan-2-one
Conditions | Yield |
---|---|
chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) In chloroform at 60℃; for 0.25h; | 92% |
carbonyl(5,10,15,20-tetraphenylporphyrinato)ruthenium(II) In toluene at 50℃; for 5h; | 85% |
N,N-dimethyl-2-propen-1-amine
(dimethoxy)methylsilane
B
<3-(dimethylamino)propyl>dimethoxymethylsilane
Conditions | Yield |
---|---|
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; ammonium bicarbonate In toluene at 45℃; for 12h; Reagent/catalyst; | A 8% B 91.4% |
The N,N-Dimethylallylamine with CAS registry number of 2155-94-4 is also known as 2-Propen-1-amine, N,N-dimethyl-. The IUPAC name is N,N-Dimethylprop-2-en-1-amine. Its EINECS registry number is 218-458-7. In addition, the formula is C5H11N and the molecular weight is 85.15. What's more, this chemical is a colourless to faintly yellow liquid and it is slightly soluble in water, soluble in benzene, ether, chloroform, carbon tetrachloride and so on.
Physical properties about this chemical are:(1) ACD/LogP: 1.02; (2) # of Rule of 5 Violations: 0; (3) #H bond acceptors: 1; (4) #H bond donors: 0; (5) #Freely Rotating Bonds: 2; (6) Polar Surface Area: Å2; (7) Index of Refraction: 1.419; (8) Molar Refractivity: 28.65 cm3; (9) Molar Volume: 113.4 cm3; (10) Surface Tension: 22 dyne/cm; (11) Density: 0.75 g/cm3; (12) Enthalpy of Vaporization: 30.57 kJ/mol; (13) Boiling Point: 63.5 °C at 760 mmHg; (14) Vapour Pressure: 171 mmHg at 25 °C; (15) Flash Point: 8 °C.
Preparation of N,N-Dimethylallylamine: it is prepared by reaction of dimethylamine with 3-bromo-propene. The reaction needs solvent H2O in condition of refluxing for 30 minutes. The yield is about 62.5 %.
Uses of N,N-Dimethylallylamine: it is used to produce cyclopropylmethyl-dimethyl-amine. The reaction occurs with catalyzer CuCl, solvent CH2Cl2 and other condition of irradiation.
When you are using this chemical, please be cautious about it. As a chemical, it is irritating to eyes, respiratory system and skin and may cause inflammation to the skin or other mucous membranes. It may destroy living tissue if you contact for it is corrosive. Besides, this chemical is highly flammable. It may catch fire when in contact with air, only need brief contact with an ignition source, have a very low flash point or evolve highly flammable gases in contact with water. Therefore, you should keep away from sources of ignition and wear suitable protective clothing, gloves and eye/face protection. In case of contact with eyes, you must rinse immediately with plenty of water and seek medical advice. In addition, if you feel unwell or in case of accident you should seek medical advice immediately.
You can still convert the following datas into molecular structure:
1. SMILES: CN(C)CC=C
2. InChI: InChI=1S/C5H11N/c1-4-5-6(2)3/h4H,1,5H2,2-3H3
3. InChIKey: GBCKRQRXNXQQPW-UHFFFAOYSA-N
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