Pentaerythritol triacrylate supplier

Name
Pentaerythritol triacrylate
EINECS 222-540-8
CAS No. 3524-68-3
Article Data8
CAS DataBase
Density 1.179 g/cm³
Solubility insoluble in water
Melting Point 15℃
Formula C₁₄H₁₈O₇
Boiling Point 427.9 ºC at 760 mmHg
Molecular Weight 298.293
Flash Point 153.5 °C
Transport Information UN 3265
Appearance viscous yellow liquid
Safety 39
Risk Codes 36/38-43
Molecular Structure
Hazard Symbols Xi
Synonyms 2-Propenoicacid, 2-(hydroxymethyl)-2-[[(1-oxo-2-propenyl)oxy]methyl]-1,3-propanediyl ester(9CI);Acrylic acid, triester with pentaerythritol (7CI,8CI);Pentaerythritol,triacrylate (8CI);A-TMM 3OHV122;A-TMMA;Agi Syn 2884;Aronix M 30;Aronix M305;Aronix M 306;Gafgard 233;Hipenny;Kayarad PET 30;Light Acrylate PE 3A;Light Ester PE 3A;M 305;NK Ester A-TMN 3LM-N;NK Ester TMM 50T;NewfrontierPET 3;P 300;P 300 (acrylate);PE 3A;PET 30;PETA;PETIA;Pentaerythrityltriacrylate;SR 444;SR 444C;SR 444D;Sartomer 444;Sartomer SR 444;SetaluxUV 2242;Tetramethylolmethane triacrylate;Viscoat 300PETA;2-Propenoic acid,1,1'-[2-(hydroxymethyl)-2-[[(1-oxo-2-propen-1-yl)oxy]methyl]-1,3-propanediyl]ester;
PSA 99.13000
LogP 0.15270

Synthetic route

: 115-77-5
Pentaerythritol

: 79-10-7
acrylic acid

: 3524-68-3
pentaerythritol triacrylate

Conditions

Conditions	Yield
Stage #1: Pentaerythritol; acrylic acid With IR-120 strong acid type ion exchange resin at 100℃; for 0.5h; Stage #2: In benzene at 100℃; for 3h; Temperature;	88%

: 1471-17-6
pentaerythritol triallyl ether

: 3524-68-3
pentaerythritol triacrylate

Conditions

Conditions	Yield
With triethylamine; trichlorophosphate In (2S)-N-methyl-1-phenylpropan-2-amine hydrate

: 115-77-5
Pentaerythritol

: 3121-61-7
2-methoxyethyl acrylate

A: 2,2-bis(hydroxymethyl)-1,3-propanediyl diacrylate

B: 4986-89-4
pentaerythritol tetraacrylate

C: 3524-68-3
pentaerythritol triacrylate

Conditions

Conditions	Yield
With zinc diacetate; oxygen; 4-methoxy-phenol; 1,8-diazabicyclo[5.4.0]undec-7-ene at 105 - 120℃; for 5h; Reagent/catalyst; Inert atmosphere; Overall yield = 48 %;

...Expand

: 115-77-5
Pentaerythritol

: 3121-61-7
2-methoxyethyl acrylate

A: 4986-89-4
pentaerythritol tetraacrylate

B: 3524-68-3
pentaerythritol triacrylate

Conditions

Conditions	Yield
With 1,4-diaza-bicyclo[2.2.2]octane; zinc diacetate; oxygen; 4-methoxy-phenol at 105 - 120℃; under 130 - 760 Torr; for 30h; Inert atmosphere; Overall yield = 96 %;
With 1,4-diaza-bicyclo[2.2.2]octane; zinc diacetate; oxygen; 4-methoxy-phenol at 105 - 120℃; under 130 - 760 Torr; for 30h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Overall yield = 88 %;
With 1,4-diaza-bicyclo[2.2.2]octane; zinc diacetate; oxygen; 4-methoxy-phenol at 105 - 120℃; under 130 - 760 Torr; for 30h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Overall yield = 88 %;

...Expand

: 108-30-5
succinic acid anhydride

: 3524-68-3
pentaerythritol triacrylate

: C19H22O11

Conditions

Conditions	Yield
With triphenylphosphine at 90℃; for 8h;	99.9%

: 542-92-7
cyclopenta-1,3-diene

: 3524-68-3
pentaerythritol triacrylate

: C29H36O7

Conditions

Conditions	Yield
In toluene for 3h; Diels-Alder Cycloaddition; Inert atmosphere; Schlenk technique;	97%

: 3524-68-3
pentaerythritol triacrylate

polymer resin; monomer(s): pentaerythritol triacrylate: polymer resin; monomer(s): pentaerythritol triacrylate

Conditions

Conditions	Yield
With acetic acid butyl ester; hydroxyethyl cellulose; dibenzoyl peroxide In water at 80℃; for 8h; Product distribution; Further Variations:; Reagents;	96.6%

: 3524-68-3
pentaerythritol triacrylate

: 2451-62-9
teroxirone

: C66H81N3O36

Conditions

Conditions	Yield
With 4-methoxy-phenol; triphenylphosphine at 95℃; for 14h;	94.58%

: 19438-60-9
4-methyl-hexahydrophthalic anhydride

: 3524-68-3
pentaerythritol triacrylate

: C22H28O10

Conditions

Conditions	Yield
With 4-methoxy-phenol; triphenylphosphine at 90℃; for 8h;	91.2%

: C29H22O4

: 3524-68-3
pentaerythritol triacrylate

: C57H54O16

Conditions

Conditions	Yield
With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 20h;	85%

: 24801-88-5
3-(triethoxypropyl) isocyanate

: 3524-68-3
pentaerythritol triacrylate

: C24H39NO11Si

Conditions

Conditions	Yield
With dibutyltin dilaurate at 50℃; Reagent/catalyst; Temperature;	82%
With dibutyltin dilaurate at 40℃; for 16h;
With dibutyltin dilaurate; 4-methoxy-phenol at 60℃; for 5h;

: 15396-00-6
3-(trimethoxysilyl)propyl isocyanate

: 3524-68-3
pentaerythritol triacrylate

: C21H33NO11Si

Conditions

Conditions	Yield
With triethylamine at 50℃; Temperature; Reagent/catalyst;	81%
With octyl sulfoxide; pentaerythritol tetraacrylate at 80℃; for 2h;

: 54941-51-4
4,4'-(9-fluorenylidene)-bis-benzoic acid

: 3524-68-3
pentaerythritol triacrylate

: C55H50O16

Conditions

Conditions	Yield
With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 20h;	80%

: 111-19-3
sebacoyl chloride

: 3524-68-3
pentaerythritol triacrylate

: C38H50O16

Conditions

Conditions	Yield
With pyridine In dichloromethane at 26℃; for 2h; Reflux;	73%

: C28H31N2O3(1+)*C24BF20(1-)

: 3524-68-3
pentaerythritol triacrylate

: C42H47N2O9(1+)*C24BF20(1-)

Conditions

Conditions	Yield
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 25℃; for 3h;	21%

: C29H31N2O5(1+)*C24BF20(1-)

: 3524-68-3
pentaerythritol triacrylate

: C57H67N2O14(1+)*C24BF20(1-)

Conditions

Conditions	Yield
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 25℃; for 8h;	18%

: 151-56-4
ethyleneimine

: 3524-68-3
pentaerythritol triacrylate

: 57116-45-7
pentaerythritol tris(3-(1-aziridinyl)propionate)

: 3524-68-3
pentaerythritol triacrylate

polymer; monomer(s): pentaerythritol triacrylate: polymer; monomer(s): pentaerythritol triacrylate

Conditions

Conditions	Yield
With 1-hydroxycyclohexyl phenyl ketone; sodium dodecyl-sulfate In water UV-irradiation;

: 3524-68-3
pentaerythritol triacrylate

poly[pentaerythritol triacrylate], photocured stereolithography; monomer(s): pentaerythritol triacrylate: poly[pentaerythritol triacrylate], photocured stereolithography; monomer(s): pentaerythritol triacrylate

Conditions

Conditions	Yield
With Camphorquinone UV-irradiation;

: 3524-68-3
pentaerythritol triacrylate

: 822-06-0
Hexamethylene diisocyanate

: 77001-81-1
C36H48N2O16

Conditions

Conditions	Yield
dibutyltin dilaurate In methylpentan-2-one, 4- at 70℃; for 4h; Heating / reflux;
With dibutyltin dilaurate at 75℃; for 6h;

: 4098-71-9
isophorone diisocyanate

: 3524-68-3
pentaerythritol triacrylate

: 101162-60-1
C40H54N2O16

Conditions

Conditions	Yield
dibutyltin dilaurate In methylpentan-2-one, 4- at 70℃; for 4h; Heating / reflux;
With dibutyltin dilaurate; 4-methoxy-phenol at 70 - 80℃; for 6h;

: N-propyl-perfluorooctylethylamine

: 3524-68-3
pentaerythritol triacrylate

: 852876-56-3
C27H30F17NO7

Conditions

Conditions	Yield
triethylamine at 50℃; for 3h; Michael Condensation;

: 108-55-4
glutaric anhydride,

: 3524-68-3
pentaerythritol triacrylate

: C19H24O10

Conditions

Conditions	Yield
With 2,6-di-tert-butyl-4-methyl-phenol; sulfuric acid at 20 - 50℃;

: 105-06-6
1,4-Divinylbenzene

: 3524-68-3
pentaerythritol triacrylate

polymer; monomer(s): pentaerythritol triacrylate; 4-divinylbenzene: polymer; monomer(s): pentaerythritol triacrylate; 4-divinylbenzene

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile) In ethanol; toluene at 60℃; for 6h;

: 3524-68-3
pentaerythritol triacrylate

poly(pentaerythritol triacrylate); monomer(s): pentaerythritol triacrylate: poly(pentaerythritol triacrylate); monomer(s): pentaerythritol triacrylate

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile) In ethanol; toluene at 60℃;

: 110-63-4
Butane-1,4-diol

: 109-86-4
2-methoxy-ethanol

: 3779-63-3
(2,4,6-trioxotriazine-1,3,5(2H,4H,6H)-triyl)tris(hexamethylene)isocyanate

: 3977-29-5
2-amino-6-methylpyrimidin-4-ol

: 3524-68-3
pentaerythritol triacrylate

1,4-butanediol; DESMODUR N-100; 2-methoxyethanol; methyl isocytocine; PETA; mixture of, heated: 1,4-butanediol; DESMODUR N-100; 2-methoxyethanol; methyl isocytocine; PETA; mixture of, heated

Conditions

Conditions	Yield
Stage #1: Butane-1,4-diol; (2,4,6-trioxotriazine-1,3,5(2H,4H,6H)-triyl)tris(hexamethylene)isocyanate; dibutyltin dilaurate In ISOPROPYLAMIDE at 40℃; for 0.5h; Stage #2: 2-amino-6-methylpyrimidin-4-ol In ISOPROPYLAMIDE at 40 - 87℃; Stage #3: 2-methoxy-ethanol; pentaerythritol triacrylate With hydroquinone more than 3 stages;

...Expand

: 110-63-4
Butane-1,4-diol

: 3779-63-3
(2,4,6-trioxotriazine-1,3,5(2H,4H,6H)-triyl)tris(hexamethylene)isocyanate

: 3977-29-5
2-amino-6-methylpyrimidin-4-ol

: 3524-68-3
pentaerythritol triacrylate

1,4-butanediol; DESMODUR N-100; methyl isocytocine; PETA; mixture of, heated: 1,4-butanediol; DESMODUR N-100; methyl isocytocine; PETA; mixture of, heated

Conditions

Conditions	Yield
Stage #1: (2,4,6-trioxotriazine-1,3,5(2H,4H,6H)-triyl)tris(hexamethylene)isocyanate; 2-amino-6-methylpyrimidin-4-ol In ISOPROPYLAMIDE at 87 - 90℃; Stage #2: pentaerythritol triacrylate With hydroquinone; dibutyltin dilaurate In ISOPROPYLAMIDE at 40 - 60℃; for 5.5h; Stage #3: Butane-1,4-diol In ISOPROPYLAMIDE at 50℃; for 5.5h;

...Expand

: 3524-68-3
pentaerythritol triacrylate

(hexanediol diacrylate)-co-(hydroxyethyl acrylat)-co-(pentaerythritol triacrylate): (hexanediol diacrylate)-co-(hydroxyethyl acrylat)-co-(pentaerythritol triacrylate)

Conditions

Conditions	Yield
With 2-methyl-1-[4-(methylthio)phenyl]-2-morpholinopropan-1-one In isopropyl alcohol; toluene UV-irradiation;

: 3,5-bis(1,1-dimethylethyl)-4-hydroxy-N-(4-hydroxy-3-methylphenyl)-benzenepropanamide

: 3524-68-3
pentaerythritol triacrylate

: 1001078-10-9
C86H117N3O16

Conditions

Conditions	Yield
Stage #1: 3,5-bis(1,1-dimethylethyl)-4-hydroxy-N-(4-hydroxy-3-methylphenyl)-benzenepropanamide With potassium tert-butylate In tetrahydrofuran Michael Addition; Stage #2: pentaerythritol triacrylate In tetrahydrofuran

: C67H108N6O27

: 3524-68-3
pentaerythritol triacrylate

: C109H162N6O45

Conditions

Conditions	Yield
In acetone for 40 - 50h; Inert atmosphere;

Pentaerythritol triacrylate Chemical Properties

IUPAC Name: [2-(Hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate
Empirical Formula: C₁₄H₁₈O₇
Molecular Weight: 298.2885
EINECS: 222-540-8
Product Categories: Functional Monomer; RAW material for negative PR
storage temp.: 2-8 °C
Sensitive: Hygroscopic
Stability: Stable at room temperature, but potentially explosive at elevated temperatures. Combustible, but may explode if involved in a fire.
Index of Refraction: 1.488
Molar Refractivity: 72.91 cm³
Molar Volume: 252.9 cm³
Surface Tension: 41.5 dyne/cm
Density: 1.179 g/cm³
Flash Point: 153.5 °C
Enthalpy of Vaporization: 78.86 kJ/mol
Boiling Point: 427.9 °C at 760 mmHg
Vapour Pressure: 4.08E-09 mmHg at 25 °C
Appearance: Thick clear yellow liquid.
Classification Code of Pentaerythritol triacrylate (CAS NO.3524-68-3): Mutation data; Reproductive Effect; Skin / Eye Irritant; Tumor data

Pentaerythritol triacrylate Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rabbit	LD50	skin	4mL/kg (4mL/kg)		Toxicology and Applied Pharmacology. Vol. 28, Pg. 313, 1974.
rat	LD50	intraperitoneal	25mg/kg (25mg/kg)	BEHAVIORAL: ATAXIA GASTROINTESTINAL: OTHER CHANGES SKIN AND APPENDAGES (SKIN): HAIR: OTHER	National Technical Information Service. Vol. OTS0555706,
rat	LD50	oral	1830mg/kg (1830mg/kg)	GASTROINTESTINAL: ULCERATION OR BLEEDING FROM SMALL INTESTINE GASTROINTESTINAL: ULCERATION OR BLEEDING FROM LARGE INTESTINE GASTROINTESTINAL: OTHER CHANGES	National Technical Information Service. Vol. OTS0555713,

Pentaerythritol triacrylate Consensus Reports

Reported in EPA TSCA Inventory.

Pentaerythritol triacrylate Safety Profile

Moderately toxic by ingestion and skin contact. Skin and severe eye irritant. Questionable carcinogen with experimental tumorigenic data. Used for radiation-cured adhesives, coatings, inks, textiles, photo resists, and coatings. When heated to decomposition it emits acrid smoke and irritating fumes.
Hazard Codes: Xi
Risk Statements: 36/38-43
R36/38:Irritating to eyes and skin.
R43:May cause sensitization by skin contact.
Safety Statements: 39
S39:Wear eye / face protection.
RIDADR: UN3265
WGK Germany: 1
RTECS: UD3370000
HazardClass: 8
PackingGroup: III

Pentaerythritol triacrylate Specification

Pentaerythritol triacrylate (CAS NO.3524-68-3), its Synonyms are Pentaerythrityl triacrylate ; Acrylic acid, triester with pentaerythritol ; Aronix M 305 ; Gafgard 233 ; Kayarad PET 30 ; Light Acrylate PE 3A ; NK Ester A-TMM 3 ; NK Ester A-TMM 3L ; NK Ester TMM 50T ; 2-(Hydroxymethyl)-2-(((1-oxoallyl)oxy)methyl)-1,3-propanediyl diacrylate ; 2-Propenoic acid, 1,1'-(2-(hydroxymethyl)-2-(((1-oxo-2-propen-1-yl)oxy)methyl)-1,3-propanediyl) ester ; 2-Propenoic acid, 2-(hydroxymethyl)-2-(((1-oxo-2-propenyl)oxy)methyl)-1,3-propanediyl ester .

Product Name

Pentaerythritol triacrylate

Synthetic route

Pentaerythritol triacrylate Chemical Properties

Pentaerythritol triacrylate Toxicity Data With Reference

Pentaerythritol triacrylate Consensus Reports

Pentaerythritol triacrylate Safety Profile

Pentaerythritol triacrylate Specification

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