Perfluoro-1-iodohexane supplier

Name
Perfluoro-1-iodohexane
EINECS 206-586-6
CAS No. 355-43-1
Article Data24
CAS DataBase
Density 2.05 g/cm³
Solubility insoluble in water
Melting Point -45 °C
Formula C₆F₁₃I
Boiling Point 117.096 °C at 760 mmHg
Molecular Weight 445.95
Flash Point 44.982 °C
Transport Information UN 2810
Appearance liquid
Safety 23-24/25-37/39-26
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms Hexane,tridecafluoro-1-iodo- (7CI,8CI);1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-6-iodohexane;1,1,2,2,3,3,4,4,5,5,6,6,6-Tridecafluoro-1-iodohexane;1-Iodo-1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexane;1-Iodoperfluorohexane;1-Iodotridecafluorohexane;6-Iodoperfluorohexane;Perfluorohexyl iodide;Tridecafluoro-1-iodohexane;Tridecafluoro-6-iodohexane;Tridecafluorohexyl iodide;n-Perfluorohexyl iodide;
PSA 0.00000
LogP 5.11770

Synthetic route

: 116-14-3
polytetrafluoroethylene

: 354-64-3
Pentafluoroethyl iodide

A: 507-63-1
1-iodoheptadecafluorooctane

B: 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

C: 355-43-1
n-perfluorohexyl iodide

D: 423-62-1
1-Iodo-perfluorodecane

Conditions

Conditions	Yield
at 100℃; for 5.13333h; Irradiation; Further byproducts given;	A 44.5% B 5% C 26.9% D 15.8%
at 100℃; for 5h; Irradiation;	A 13.8% B 34.6% C 40.3% D 3.2%
With copper at 90 - 100℃; for 5h; Product distribution; further reaction times, reagent ratio;	A 15.9% B 10.5% C 17.2% D 2.4%
copper at 60 - 140℃; under 22502.3 - 33753.4 Torr; Product distribution / selectivity;

...Expand

: 116-14-3
polytetrafluoroethylene

: 354-64-3
Pentafluoroethyl iodide

A: 507-63-1
1-iodoheptadecafluorooctane

B: 307-60-8
1-iodoperfluorododecane

C: 355-43-1
n-perfluorohexyl iodide

D: 423-62-1
1-Iodo-perfluorodecane

Conditions

Conditions	Yield
at 100℃; Further byproducts given;	A 44.5% B 5.8% C 26.9% D 5.8%
at 100℃; for 5.13333h; Irradiation; Further byproducts given;	A 44.5% B 5.8% C 26.9% D 15.8%
copper at 120℃; under 33753.4 Torr; Product distribution / selectivity;

...Expand

: 116-14-3
polytetrafluoroethylene

: 354-64-3
Pentafluoroethyl iodide

A: 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

B: 355-43-1
n-perfluorohexyl iodide

Conditions

Conditions	Yield
at 100℃; for 2h; Irradiation;	A 36.9% B 5.5%
at 99.9℃; under 300.02 Torr; for 0.333333h; Rate constant; Quantum yield; Thermodynamic data; Irradiation; var. of partial pressures, temp., time, Ea;	A 36.6 % Chromat. B 11.3 % Chromat.

...Expand

: 116-14-3
polytetrafluoroethylene

: 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

A: 507-63-1
1-iodoheptadecafluorooctane

B: 355-43-1
n-perfluorohexyl iodide

Conditions

Conditions	Yield
mit UV Licht.Irradiation;

...Expand

: 116-14-3
polytetrafluoroethylene

: 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

: 355-43-1
n-perfluorohexyl iodide

Conditions

Conditions	Yield
im UV-Licht;
With bis(pentafluoropropionyl)peroxide at 28 - 70℃; for 0.333333h; Concentration; Temperature; Time;

: 4520-08-5
perfluorohexyl radical

: 355-43-1
n-perfluorohexyl iodide

Conditions

Conditions	Yield
With iodine In gas at 286.9 - 426.9℃; under 30 - 300 Torr; Equilibrium constant;

: 116-14-3
polytetrafluoroethylene

: 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

A: 354-64-3
Pentafluoroethyl iodide

B: 355-43-1
n-perfluorohexyl iodide

Conditions

Conditions	Yield
at 29.9℃; under 300.02 Torr; for 6h; Rate constant; Quantum yield; Thermodynamic data; Irradiation; var. of partial pressures, time, Ea;	A 70.9 % Chromat. B 5.8 % Chromat.

...Expand

silver-salt of/the/ tridecafluoroheptanoic acid: silver-salt of/the/ tridecafluoroheptanoic acid

: 355-43-1
n-perfluorohexyl iodide

Conditions

Conditions	Yield
With iodine

: 116-14-3
polytetrafluoroethylene

: 2314-97-8
iodotrifluoromethane

A: 354-64-3
Pentafluoroethyl iodide

B: 754-34-7
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

C: 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

D: 638-79-9
undecafluoro-1-iodopentane

E: 355-43-1
n-perfluorohexyl iodide

F: 335-58-0
perfluoroheptyl iodide

G CF3(CF2)7I, CF3(CF2)8I: CF3(CF2)7I, CF3(CF2)8I

Conditions

Conditions	Yield
In gas Product distribution; Quantum yield; Thermodynamic data; Irradiation; pulsed CO2 laser; release of reaction enthalpy, selectivity depending on pressure and temperature;

...Expand

: 4520-08-5
perfluorohexyl radical

A: 355-43-1
n-perfluorohexyl iodide

B atomic iodine: atomic iodine

Conditions

Conditions	Yield
With iodine In gas at 286.9 - 426.9℃; under 30 - 300 Torr; Equilibrium constant;

F-hexylnickel iodide bis(acetonitrile) complex: F-hexylnickel iodide bis(acetonitrile) complex

A: 355-43-1
n-perfluorohexyl iodide

B: 755-25-9
perfluoro-1-hexene

C: F-dodecene-6

D: (E)-1,1,1,2,2,3,3,4,4,5,6,7,7,8,8,9,9,10,10,11,11,12,12,12-Tetracosafluoro-dodec-5-ene

Conditions

Conditions	Yield
at 100 - 170℃; under 0.1 - 1 Torr; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

...Expand

: 116-14-3
polytetrafluoroethylene

: 354-64-3
Pentafluoroethyl iodide

: 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

A: 507-63-1
1-iodoheptadecafluorooctane

B: 355-43-1
n-perfluorohexyl iodide

Conditions

Conditions	Yield
With diisopropyl peroxydicarbonate at 65 - 77℃; for 2h; Product distribution / selectivity;

...Expand

: 102061-83-6
sodium 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexane-1-sulfinate

: 355-43-1
n-perfluorohexyl iodide

Conditions

Conditions	Yield
With sodium persulfate; iodine In water; dimethyl sulfoxide at 20℃; for 1h;

: 116-14-3
polytetrafluoroethylene

: 354-64-3
Pentafluoroethyl iodide

A: 507-63-1
1-iodoheptadecafluorooctane

B: 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

C: 355-43-1
n-perfluorohexyl iodide

Conditions

Conditions	Yield
copper at 120℃; under 33753.4 Torr; Product distribution / selectivity;

...Expand

: 116-14-3
polytetrafluoroethylene

: 354-64-3
Pentafluoroethyl iodide

A: 507-63-1
1-iodoheptadecafluorooctane

B: 307-60-8
1-iodoperfluorododecane

C: 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

D: 355-43-1
n-perfluorohexyl iodide

E: 423-62-1
1-Iodo-perfluorodecane

Conditions

Conditions	Yield
copper at 120℃; under 14251.4 - 33753.4 Torr; Product distribution / selectivity;

...Expand

: 116-14-3
polytetrafluoroethylene

: 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

A: perfluorotetradecyl iodide

B: 507-63-1
1-iodoheptadecafluorooctane

C: 307-60-8
1-iodoperfluorododecane

D: 355-43-1
n-perfluorohexyl iodide

E: 423-62-1
1-Iodo-perfluorodecane

Conditions

Conditions	Yield
copper at 110℃; under 2850.29 Torr;

...Expand

: 116-14-3
polytetrafluoroethylene

: 32395-49-6
Bis(pentafluoraethyl)-fluorarsan

: 7553-56-2
iodine

A: 507-63-1
1-iodoheptadecafluorooctane

B: 354-64-3
Pentafluoroethyl iodide

C: 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

D: 355-43-1
n-perfluorohexyl iodide

Conditions

Conditions	Yield
220°C, under pressure;
220°C, under pressure;

...Expand

: 116-14-3
polytetrafluoroethylene

: 359-69-3
Tris(pentafluoraethyl)arsan

: 7553-56-2
iodine

A: 507-63-1
1-iodoheptadecafluorooctane

B: 354-64-3
Pentafluoroethyl iodide

C: 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

D: 355-43-1
n-perfluorohexyl iodide

Conditions

Conditions	Yield
220°C, under pressure;
220°C, under pressure;

...Expand

: 883882-15-3
perfluorohexyliodine tetrafluoride

A: 355-42-0
tetradecafluorohexane

B: 355-43-1
n-perfluorohexyl iodide

C: iodine pentafluoride

...Expand

: 116-14-3
polytetrafluoroethylene

: 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

A: 507-63-1
1-iodoheptadecafluorooctane

B: 307-60-8
1-iodoperfluorododecane

C: 355-43-1
n-perfluorohexyl iodide

D: 423-62-1
1-Iodo-perfluorodecane

Conditions

Conditions	Yield
copper Product distribution / selectivity; Reflux;

...Expand

: 507-63-1
1-iodoheptadecafluorooctane

: 354-64-3
Pentafluoroethyl iodide

A: 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

B: 355-43-1
n-perfluorohexyl iodide

Conditions

Conditions	Yield
at 490℃; for 0.00116667h; Product distribution / selectivity;

...Expand

: 1,8-Diiodo-1,1,3,3,4,4,5,5,6,6,8,8-dodecafluorooctane

A: 355-43-1
n-perfluorohexyl iodide

B: 1613640-22-4
1,1,3,3,4,4,5,5,6,6-decafluoro-6-iodo-1-hexene

C: 1613640-23-5
1,1,3,3,4,4,5,5,6,6,8,8-dodecafluoro-1,7-octadiene

Conditions

Conditions	Yield
With tributyl-amine at 48℃; for 1h;

...Expand

: 355-43-1
n-perfluorohexyl iodide

: 100-52-7
benzaldehyde

: 57242-02-1
2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoro-1-phenyl-1-hydroxyheptane

Conditions

Conditions	Yield
Stage #1: n-perfluorohexyl iodide With methylmagnesium bromide In diethyl ether at -78℃; for 2h; Inert atmosphere; Stage #2: benzaldehyde In diethyl ether at -78℃; for 8h; Inert atmosphere;	100%
Stage #1: n-perfluorohexyl iodide With zirconocene dichloride; butyl magnesium bromide In 1,4-dioxane; diethyl ether at -78℃; for 1h; Inert atmosphere; Stage #2: benzaldehyde In 1,4-dioxane; diethyl ether at 20℃; for 1h; Reagent/catalyst; Inert atmosphere; chemoselective reaction;	99%
Stage #1: n-perfluorohexyl iodide With bis(cyclopentadienyl)titanium dichloride; isopropylmagnesium chloride In 1,4-dioxane; diethyl ether at -78 - -50℃; for 2h; Stage #2: benzaldehyde In 1,4-dioxane; diethyl ether at 20℃; for 1h; Reagent/catalyst; Temperature;	99%

: 355-43-1
n-perfluorohexyl iodide

: 107-18-6
allyl alcohol

: 38550-44-6
2-iodo-4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononan-1-ol

Conditions

Conditions	Yield
With mercury(I) iodide; mercury(II) iodide In N,N-dimethyl-formamide at 35℃; for 1.5h;	100%
zinc at 30℃; for 120h; Product distribution; also with various solvents;	95%
With zinc at 30℃; for 120h;	95%

: 872-05-9
1-Decene

: 355-43-1
n-perfluorohexyl iodide

: 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-1-iodohexadecane

Conditions

Conditions	Yield
With 1-(2',2'-diphenylvinyl)pyrrolidine In dichloromethane at 20℃; for 16h; Reagent/catalyst; Irradiation;	100%
With pyrrolidine; Diphenylacetaldehyde In dichloromethane at 20℃; for 16h; Catalytic behavior; Reagent/catalyst; Wavelength; Inert atmosphere; Irradiation;	99%
With rose bengal; sodium thiosulfate In water; acetonitrile at 20℃; for 1h; Reagent/catalyst; Inert atmosphere; Irradiation;	93%

: 75-38-7
Vinylidene fluoride

: 355-43-1
n-perfluorohexyl iodide

: 53826-16-7
1,1,1,2,2,3,3,4,4,5,5,6,6,8,8-pentadecafluoro-8-iodooctane

Conditions

Conditions	Yield
Heating;	100%
at 180℃;

: 355-43-1
n-perfluorohexyl iodide

: 883882-15-3
perfluorohexyliodine tetrafluoride

Conditions

Conditions	Yield
With xenon difluoride; boron trifluoride In various solvent(s) at -5 - 25℃;	100%

: 32660-96-1
(pentamethylcyclopentadienyl)(dicarbonyl)iridium(I)

: 355-43-1
n-perfluorohexyl iodide

: 923582-51-8
Cp(*)Ir(CO)(n-C6F13)I

Conditions

Conditions	Yield
In dichloromethane I(CF2)5CF3 added dropwise to a soln. of Ir complex, stirred for 15 min under N2; solvent-removed, washed (hexane); elem. anal.;	100%

: 867-13-0
diethoxyphosphoryl-acetic acid ethyl ester

: 355-43-1
n-perfluorohexyl iodide

: 583-02-8
ethyl 4-(trifluoromethyl)benzoate

: E-ethyl 4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-3-[p-(tri-fluoromethyl)phenyl]non-2-enoate

Conditions

Conditions	Yield
Stage #1: n-perfluorohexyl iodide; ethyl 4-(trifluoromethyl)benzoate With methyllithium; lithium bromide In diethyl ether at -80℃; for 0.5h; Horner-Wadsworth-Emmons Olefination; Inert atmosphere; Stage #2: With diethylaluminium chloride In diethyl ether at -80℃; for 0.25h; Horner-Wadsworth-Emmons Olefination; Inert atmosphere; Stage #3: diethoxyphosphoryl-acetic acid ethyl ester With triethylamine; lithium bromide In tetrahydrofuran; diethyl ether at 20℃; for 3h; Horner-Wadsworth-Emmons Olefination; Inert atmosphere; stereospecific reaction;	100%

Yield

Stage #1: n-perfluorohexyl iodide; ethyl 4-(trifluoromethyl)benzoate With methyllithium; lithium bromide In diethyl ether at -80℃; for 0.5h; Horner-Wadsworth-Emmons Olefination; Inert atmosphere;
Stage #2: With diethylaluminium chloride In diethyl ether at -80℃; for 0.25h; Horner-Wadsworth-Emmons Olefination; Inert atmosphere;
Stage #3: diethoxyphosphoryl-acetic acid ethyl ester With triethylamine; lithium bromide In tetrahydrofuran; diethyl ether at 20℃; for 3h; Horner-Wadsworth-Emmons Olefination; Inert atmosphere; stereospecific reaction;

100%

...Expand

: 355-43-1
n-perfluorohexyl iodide

: 24932-48-7
1,2-dibromo-4,5-dimethylbenzene

: 1,2-dimethyl-4,5-bis(perfluorohexyl)benzene

Conditions

Conditions	Yield
With copper In dimethyl sulfoxide at 110℃; for 22h; Inert atmosphere; Schlenk technique;	100%
With copper In dimethyl sulfoxide at 110℃; for 22h; Inert atmosphere;	97%

: 355-43-1
n-perfluorohexyl iodide

: 24743-14-4
1-allyl-3-methoxybenzene

: 3-(1H,1H,2H,3H,3H-perfluoro-2-iodononyl)anisole

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0) In hexane at -78 - 20℃; for 36h; Inert atmosphere;	100%

: 7539-12-0
allylsuccinic anhydride

: 355-43-1
n-perfluorohexyl iodide

: 674786-54-0
3-(perfluorohexyl)-2-iodopropyl-2-butane-1,4-dioic acid anhydride

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile) at 70 - 92℃; for 7h;	99.6%

: 355-43-1
n-perfluorohexyl iodide

: prop-2-en-1-yl-2-butane-1,4-dioic acid anhydride

: 674786-56-2
4-(perfluorohexyl)-3-iodo-2-butyl-2-butane-1,4-dioic acid anhydride

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile) at 72 - 84℃; for 6h;	99.4%

: 355-43-1
n-perfluorohexyl iodide

: 121667-04-7
3,4-epoxy-1-tetradecene

: 121666-82-8
(E)-1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-icos-8-en-10-ol

Conditions

Conditions	Yield
With triethyl borane In hexane; benzene at 25℃; for 17h; Product distribution; The reaction of 1,3-diene monoxide with different radical sources in the presence of Et3B provides 4-substituted-2-buten-1-ol in good yield with a novel synthetic route.;	99%
With triethyl borane In hexane; benzene at 25℃; for 17h;	99%

: 355-43-1
n-perfluorohexyl iodide

: 768-56-9
4-Phenyl-1-butene

: (5,5,6,6,7,7,8,8,9,9,10,10,10-tridecafluoro-3-iododecyl)benzene

Conditions

Conditions	Yield
With pyrrolidine; Diphenylacetaldehyde In dichloromethane at 20℃; for 16h; Inert atmosphere; Irradiation;	99%
With sodium triethylborohydride In hexane for 6h; Ambient temperature;	82.8%

: 355-43-1
n-perfluorohexyl iodide

: 20316-77-2
(3aR,5R,6S,6aR)-6-(allyloxy)-5-((R)-2,2-dimethyl[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydrofuro[2,3-d][1,3]dioxole

: (3aR,5R,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-6-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-2-iodo-nonyloxy)-tetrahydro-furo[2,3-d][1,3]dioxole

Conditions

Conditions	Yield
With sodium dithionite; sodium hydrogencarbonate In water; acetonitrile for 0.5h; Ambient temperature;	99%

: 355-43-1
n-perfluorohexyl iodide

: 6,6'-dibromo-2,2'-diacetyloxy-1,1'-binaphthalene

: (R)-6,6'-bis(perfluorohexyl)-2,2'-diacetoxy-1,1'-binaphthyl

Conditions

Conditions	Yield
With [2,2]bipyridinyl; copper In fluorobenzene; dimethyl sulfoxide at 80℃; for 72h;	99%

: 592-41-6
1-hexene

: 355-43-1
n-perfluorohexyl iodide

: 2348-82-5
2-methoxy-1,4-naphthoquinone

: 2-(1-butyl-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-3-methoxy-[1,4]naphthoquinone

Conditions

Conditions	Yield
Stage #1: 1-hexene; n-perfluorohexyl iodide In acetic acid Heating; Stage #2: 2-methoxy-1,4-naphthoquinone With dibenzoyl peroxide In acetic acid Heating;	99%

...Expand

: 355-43-1
n-perfluorohexyl iodide

: 2348-82-5
2-methoxy-1,4-naphthoquinone

: 2-hydroxymethyl-3-tridecafluorohexyl-[1,4]naphthoquinone

Conditions

Conditions	Yield
With dibenzoyl peroxide In acetic acid for 4h; Heating;	99%

: 1693-71-6
tris(allyl)borate

: 355-43-1
n-perfluorohexyl iodide

A: 38550-44-6
2-iodo-4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononan-1-ol

B: 107-18-6
allyl alcohol

Conditions

Conditions	Yield
Stage #1: tris(allyl)borate; n-perfluorohexyl iodide With 2,2'-azobis(isobutyronitrile) at 60 - 70℃; for 3h; Stage #2: With water at 60℃;	A 99% B n/a

...Expand

: 355-43-1
n-perfluorohexyl iodide

: 89343-06-6
tris-iso-propylsilyl acetylene

: 1231687-28-7
(Z)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-iodo-1-triisopropylsilyl-1-octene

Conditions

Conditions	Yield
With zinc In dichloromethane for 2h; Reflux; stereoselective reaction;	99%

: 355-43-1
n-perfluorohexyl iodide

: 97-63-2
methyl methacrylate

: 140834-68-0
Ethyl 2-methyl-4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononanoate

Conditions

Conditions	Yield
With tris-(trimethylsilyl)silane; sodium thiosulfate In dichloromethane; water at 20℃; for 4h; UV-irradiation; Sealed tube;	99%

: 355-43-1
n-perfluorohexyl iodide

: 3376-23-6
N-methyl-α-phenylnitrone

: N-methyl-N-(2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoro-1-phenylheptyl)hydroxylamine

Conditions

Conditions	Yield
With 2,4,6-trimethyl-pyridine; (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate; ascorbic acid In dimethyl sulfoxide at 23 - 25℃; for 2h; Inert atmosphere; Irradiation;	99%

: 355-43-1
n-perfluorohexyl iodide

: 540-37-4
p-aminoiodobenzene

: 139613-90-4
4-(1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexyl)phenylamine

Conditions

Conditions	Yield
With copper In dimethyl sulfoxide at 120℃; for 10h;	98.5%
With copper In dimethyl sulfoxide at 120℃; for 2h;	86%
With copper In dimethyl sulfoxide at 120℃;	84.27%

: 112-41-4
1-dodecene

: 355-43-1
n-perfluorohexyl iodide

: 125081-35-8
1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-8-iodooctadecane

Conditions

Conditions	Yield
With diethylamine; 1,1'-bis-(diphenylphosphino)ferrocene; bis(benzonitrile)palladium(II) dichloride In water at 20℃; for 1h; Kharasch reaction;	98%
With triethyl borane In hexane at 25℃; for 3.5h;	93%
With sodium acetate In neat (no solvent) at 140℃; for 24h; Kharash-Sosnovsky Allylic Oxidation; Green chemistry;	85%

: 355-43-1
n-perfluorohexyl iodide

: 354-88-1
perfluoroethanesulfonic acid

: 78522-66-4
1,1,2,2,2-Pentafluoro-ethanesulfonic acid tridecafluorohexyl ester

Conditions

Conditions	Yield
at 25℃; anodic oxidation;	98%
byproducts: I2; Electrochem. Process; in the acid;	98%
byproducts: I2; Electrochem. Process; in the acid;	98%

: 355-43-1
n-perfluorohexyl iodide

: 115-19-5
2-methyl-but-3-yn-2-ol

: (Z)-5,5,6,6,7,7,8,8,9,9,10,10,10-Tridecafluoro-3-iodo-2-methyl-dec-3-en-2-ol

Conditions

Conditions	Yield
In water for 2h; Ambient temperature; electrocatalysis; carbon fibre cathode, carbon rod anode, sat. KCl electrolyt;	98%

: 355-43-1
n-perfluorohexyl iodide

: (3aR,4S,6S,7S,7aR)-7-Allyloxy-2,2,6-trimethyl-4-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran

: (3aR,4S,6S,7S,7aR)-2,2,6-Trimethyl-4-phenylsulfanyl-7-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-2-iodo-nonyloxy)-tetrahydro-[1,3]dioxolo[4,5-c]pyran

Conditions

Conditions	Yield
With sodium dithionite; sodium hydrogencarbonate In water; acetonitrile for 0.5h; Ambient temperature;	98%

: 355-43-1
n-perfluorohexyl iodide

: 211180-37-9
(2R,4aR,6S,7R,8S,8aR)-7,8-Bis-allyloxy-2-phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxine

: (2R,4aR,6S,7R,8S,8aR)-2-Phenyl-6-phenylsulfanyl-7,8-bis-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-2-iodo-nonyloxy)-hexahydro-pyrano[3,2-d][1,3]dioxine

Conditions

Conditions	Yield
With sodium dithionite; sodium hydrogencarbonate In water; acetonitrile for 0.5h; Ambient temperature;	98%

: 58315-80-3
3,4-di-O-allyl-1,2:5,6-di-O-isopropylidene-D-mannitol

: 355-43-1
n-perfluorohexyl iodide

: 266328-62-5
1,2:5,6-di-O-isopropylidene-3,4-di-O-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-2-iodononyl)-D-mannitol

Conditions

Conditions	Yield
With air; triethyl borane In hexane at 0 - 20℃; for 1.16667h; Addition;	98%

: 605-94-7
2,3-Dimethoxy-5-methyl-1,4-benzoquinone

: 355-43-1
n-perfluorohexyl iodide

: 2,3-dimethoxy-5-methyl-6-tridecafluorohexyl-[1,4]benzoquinone

Conditions

Conditions	Yield
With dibenzoyl peroxide In acetic acid for 4h; Heating;	98%

: 355-43-1
n-perfluorohexyl iodide

: 15451-32-8
1-(3-butenyl)-4-bromobenzene

: 915698-45-2
1-bromo-4-(5,5,6,6,7,7,8,8,9,9,10,10,10-tridecafluoro-3-iododecyl)benzene

Conditions

Conditions	Yield
With sodium metabisulfite; 2,2'-azobis(isobutyronitrile) at 80℃; for 4h;	98%
With sodium metabisulfite; 2,2'-azobis(isobutyronitrile) at 80℃; for 4h;	98%

Perfluoro-1-iodohexane Chemical Properties

MF: C₆F₁₃I
MW: 445.95
BRN: 1802118
Stability: Stable.
EINECS: 206-586-6
Melting Point: -45 °C
Water Solubility: insoluble
Sensitive: Light Sensitive
Defractive index: n20/D 1.329(lit.)
Density: 2.063 g/mL at 25 °C(lit.)
Enthalpy of Vaporization: 34.07 kJ/mol
Boiling Point: 117.1 °C at 760 mmHg
Vapour Pressure: 21.1 mmHg at 25°C
Appearance: Clear very slight yellow liquidFlash Point: 45 °C
IUPAC Name: 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-6-iodohexane
Product Categories: Organic Fluorides ; Fluorous Chemistry ; Fluorous Compounds ; Synthetic Organic Chemistry
Synonyms: 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-6-iodohexane ; 1-Iodotridecafluorohexane ; 1-Iodoperfluorohexane ; Perfluoro-1-iodohexane ; Perfluoro-n-hexyl iodide ; Perfluorohexyl iodide ; 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-6-iodo-hexan ; Hexane, 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-6-iodo-
Following is the molecular structure of Perfluorohexyl iodide (355-43-1):

Perfluoro-1-iodohexane Safety Profile

Explodes in contact with sodium when heated to the boiling point of the iodide. When heated to decomposition it emits toxic fumes of F⁻ and I⁻.
Safety Information
Hazard Codes: Xi
Risk Statements: 36/37/38
36/37/38: Irritating to eyes, respiratory system and skin
Safety Statements: 23-24/25-37/39-26
23: Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)
24/25: Avoid contact with skin and eyes
37/39: Wear suitable gloves and eye/face protection
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
RIDADR: 2810
WGK Germany: 3
F8: Photosensitive.
Hazard Note: Irritant
HazardClass: 6.1(b)
PackingGroup: III
HS Code: 29034700

Perfluoro-1-iodohexane Specification

Handling and Storag: of Perfluorohexyl iodide (355-43-1):
Storage: Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container. Dark room.
Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.

Product Name

Perfluoro-1-iodohexane

Synthetic route

Perfluoro-1-iodohexane Chemical Properties

Perfluoro-1-iodohexane Safety Profile

Perfluoro-1-iodohexane Specification

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