A
carbonylhydrido[6-(di-tert-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II)
B
potassium formate
Conditions | Yield |
---|---|
With potassium tert-butylate at 25℃; for 0.0833333h; | A 100% B 97 %Spectr. |
Conditions | Yield |
---|---|
With hydrogen In dimethylsulfoxide-d6 at 120℃; under 750.075 Torr; for 1h; | A 98% B 15% |
Conditions | Yield |
---|---|
In water 1 h, 160°C, 20 atm CO-pressure; | 97.8% |
In water 1 h, 160°C, 20 atm CO-pressure; | 97.8% |
in presence of enough water, methanol, ethanol, acetone or ether; |
Conditions | Yield |
---|---|
With water In water byproducts: BaSO4, H2S; 150-160°C under pressure; | 97% |
With H2O In water byproducts: BaSO4, H2S; 150-160°C under pressure; | 97% |
Conditions | Yield |
---|---|
With water In water byproducts: BaSO4; 150-160°C under pressure; | 97% |
With H2O In water byproducts: BaSO4; 150-160°C under pressure; | 97% |
Conditions | Yield |
---|---|
With hydrogen In water at 100℃; under 30003 Torr; for 10h; Temperature; Pressure; Autoclave; | 96.8% |
With nickel; hydrogen In water at 200℃; under 45004.5 Torr; for 2h; Green chemistry; | 92.1% |
With hydrogen; palladium In water with Pd -black,30-60 atm,70-95°C,24 h; | 70% |
Conditions | Yield |
---|---|
With [carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethylamino] ruthenium(II); potassium hydrogencarbonate; potassium hydroxide In water at 150℃; for 20h; Catalytic behavior; Reagent/catalyst; Temperature; Time; Autoclave; Inert atmosphere; | 92% |
With C12H16IrN4O2(1+)*BF4(1-); potassium hydroxide In water at 115℃; for 15h; Catalytic behavior; Reagent/catalyst; Temperature; Schlenk technique; Inert atmosphere; |
Conditions | Yield |
---|---|
A 73.3% B 85.1% | |
A 73.3% B 85.1% | |
With water In water at b.p.;in concd. soln.; |
Conditions | Yield |
---|---|
at 20℃; for 0.25h; Schlenk technique; Inert atmosphere; Glovebox; | A n/a B 85% |
Conditions | Yield |
---|---|
With nickel; hydrogen In water at 200℃; under 45004.5 Torr; for 2h; Green chemistry; | 76.6% |
Conditions | Yield |
---|---|
With palladium In not given 60 atm, 70°C; | 75% |
With Pd black In not given 60 atm, 70°C; | 75% |
With palladium In not given 60 atm, 70°C; | 75% |
In water 4h, 350°C, 380 atm; | 11% |
In water 4h, 350°C, 380 atm; | 11% |
A
potassium formate
B
4-[N-(4'-methoxyphenyl)amino]-5,7-dinitro-2,1,3-benzoxadiazole
Conditions | Yield |
---|---|
With water at 90℃; for 1h; | A n/a B 73% |
Conditions | Yield |
---|---|
With water at 90℃; for 1h; | A 72% B n/a |
Conditions | Yield |
---|---|
With potassium tetrafluoroborate; 1,2,3-trimethylbenzimidazoline In dimethylsulfoxide-d6 at 50℃; under 1794.37 Torr; for 18h; Reagent/catalyst; Solvent; Pressure; Temperature; | 66% |
With potassium fluoride; carbonyl(5,10,15,20-tetraphenylporphyrinato)ruthenium(II); Dimethylphenylsilane In acetonitrile at 60℃; under 760.051 Torr; for 4h; Catalytic behavior; Temperature; Reagent/catalyst; Solvent; | 55% |
With C23H19ClN7ORu(1+)*Cl(1-); hydrogen; potassium hydroxide In tetrahydrofuran; water at 20 - 130℃; under 11400.8 Torr; for 25h; Catalytic behavior; Reagent/catalyst; Autoclave; Schlenk technique; | 5.8% |
triethylsilane
carbon dioxide
A
Triethylsilanol
B
hexaethyl disiloxane
C
potassium formate
Conditions | Yield |
---|---|
With potassium fluoride; dodecacarbonyl-triangulo-triruthenium In water at 80℃; under 5171.62 Torr; for 13h; Inert atmosphere; Autoclave; Green chemistry; | A n/a B n/a C 60% |
Conditions | Yield |
---|---|
With potassium hydroxide at 140℃; under 2585.81 Torr; for 24h; | 55% |
(RS)-alanine N,N-dimethylamide
nitrobenzene
A
potassium formate
B
potassium oxalate
Conditions | Yield |
---|---|
With potassium tert-butylate In tert-butyl alcohol at 50℃; for 44h; anaerobic reaction; | A 20% B n/a C n/a |
carbon dioxide
carbon monoxide
potassium carbonate
A
potassium formate
B
potassium oxalate
C
potassium hydrogencarbonate
Conditions | Yield |
---|---|
In neat (no solvent) High Pressure; 2 h at 380°C; cooling, dissolution in water, addn. of HClO4; HPLC; | A 0% B 1% C 0.8% |
Conditions | Yield |
---|---|
With potassium hydroxide |
Conditions | Yield |
---|---|
With potassium sulfate | |
With potassium sulfate |
Conditions | Yield |
---|---|
With potassium hydroxide at 25℃; Mechanism; carbonyl carbon, carbonyl oxygen and nucleophile oxygen isotope effect; |
Conditions | Yield |
---|---|
With potassium hydroxide; oxygen; sodium anthraquinone-2-sulfonate; dihydrogen peroxide at 19.9℃; under 750.06 Torr; for 48.6111h; Mechanism; Product distribution; Thermodynamic data; different reaction times, O2 concentrations, absence and presence of catalyst; activation energy; | |
With potassium hydroxide; oxygen at 19.9℃; under 750.06 Torr; |
carbon monoxide
potassium formate
Conditions | Yield |
---|---|
With KRu; hydrogen heterogeneous reaction in an UHV/high pressure reactor system; |
Conditions | Yield |
---|---|
With potassium hydroxide; oxygen; sodium anthraquinone-2-sulfonate; dihydrogen peroxide at 29.9℃; under 750.06 Torr; Mechanism; Product distribution; Thermodynamic data; different reaction times, O2 concentrations, absence and presence of catalyst; activation energy; |
lactose
A
D-gulopyranose
B
potassium formate
C
4-deoxy-D-glycero-2,3-hexodiulose
D
potassium O-β-D-galactopyranosyl-(1->3)-D-arabinonate
Conditions | Yield |
---|---|
With potassium hydroxide; oxygen at 19.9℃; under 750.06 Torr; for 48.6111h; |
lactose
A
D-gulopyranose
B
potassium formate
C
potassium O-β-D-galactopyranosyl-(1->3)-D-arabinonate
Conditions | Yield |
---|---|
With potassium hydroxide; oxygen; sodium anthraquinone-2-sulfonate; dihydrogen peroxide at 19.9℃; under 750.06 Torr; for 48.6111h; Mechanism; Rate constant; Product distribution; different reaction times, O2 concentrations, absence and presence of catalyst; | |
With potassium hydroxide; oxygen; sodium anthraquinone-2-sulfonate; dihydrogen peroxide at 19.9℃; under 750.06 Torr; for 48.6111h; Thermodynamic data; different reaction times, O2 concentrations, absence and presence of catalyst; activation energy; |
lactose
A
potassium formate
Conditions | Yield |
---|---|
With potassium hydroxide; oxygen at 29.9℃; under 750.06 Torr; |
Conditions | Yield |
---|---|
at 157 - 180℃; Product distribution; Thermodynamic data; ΔH of the decomposition; |
Conditions | Yield |
---|---|
at 112 - 120℃; Product distribution; Thermodynamic data; ΔH of the decomposition; |
Conditions | Yield |
---|---|
at 115 - 156℃; Product distribution; Thermodynamic data; ΔH of the decomposition; |
4-hydroxybenzaldehyde 4-methylbenzenesulfonate ester
potassium formate
4-carboxyphenyl 4-methylbenzenesulfonate
Conditions | Yield |
---|---|
With [PhCOPd(PtBu3)I]; dtbpf In 2-methyltetrahydrofuran at 80℃; for 18h; Inert atmosphere; | 98% |
With dichloro(1,5-cyclooctadiene)palladium(II); N-Methyldicyclohexylamine; dtbpf; 9-methyl-9H-fluorene-9-carbonyl chloride; bis(dibenzylideneacetone)-palladium(0); tri tert-butylphosphoniumtetrafluoroborate In 1,4-dioxane at 80℃; for 18h; Reagent/catalyst; Inert atmosphere; | 99 %Spectr. |
potassium formate
1-butyl-3-methylimidazolium chloride
1-butyl-3-methylimidazolium formate
Conditions | Yield |
---|---|
In water Green chemistry; | 97.9% |
In water at 25℃; | 90.5% |
In methanol at 20℃; for 24h; |
Conditions | Yield |
---|---|
Silica D22; tetramethlyammonium chloride at 150℃; for 2h; Mechanism; other alkyl halides, other alkali salts, other catalyst; | 97% |
Silica D22; tetramethlyammonium chloride at 150℃; for 2h; | 97% |
Amberlyst A27 In toluene at 95℃; for 15h; Product distribution; other catalysts (ion exchange resins); | 97 % Chromat. |
With Amberlyst A27 In toluene at 95℃; for 20h; | 100.0 % Chromat. |
With graphene oxide-supported quaternary ammonium salt at 80℃; for 8h; |
Conditions | Yield |
---|---|
With [PhCOPd(PtBu3)I]; dtbpf In 2-methyltetrahydrofuran at 80℃; for 18h; Inert atmosphere; | 97% |
Conditions | Yield |
---|---|
With [PhCOPd(PtBu3)I]; dtbpf In diethylene glycol dimethyl ether at 120℃; for 18h; Inert atmosphere; | 97% |
potassium formate
Conditions | Yield |
---|---|
With [PhCOPd(PtBu3)I]; dtbpf In 2-methyltetrahydrofuran at 80℃; for 18h; Inert atmosphere; | 96% |
1-chloro-2,2-difluoroethane
potassium formate
2,2-difluoroethyl formate
Conditions | Yield |
---|---|
at 125℃; for 5.5h; | 96% |
Conditions | Yield |
---|---|
absence of O2, 440-450°C; | 95% |
Conditions | Yield |
---|---|
With Tris(3,6-dioxaheptyl)amine In acetonitrile for 0.25h; Heating; | 95% |
4-iodobenzoic acid ethyl ester
potassium formate
terephthalic acid monoethyl ester
Conditions | Yield |
---|---|
With [PhCOPd(PtBu3)I]; dtbpf In 2-methyltetrahydrofuran at 80℃; for 18h; Inert atmosphere; | 95% |
Stage #1: potassium formate With acetic anhydride; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 20℃; Stage #2: 4-iodobenzoic acid ethyl ester With tris(dibenzylideneacetone)dipalladium (0); lithium chloride In N,N-dimethyl-formamide at 80℃; for 22h; | 81% |
Conditions | Yield |
---|---|
With [PhCOPd(PtBu3)I]; dtbpf In 2-methyltetrahydrofuran at 80℃; for 18h; Inert atmosphere; | 95% |
(2E)-3-(4-bromophenyl)-1-phenylprop-2-en-1-one
potassium formate
4-[(1E)-3-oxo-3-phenylprop-1-en-1-yl]benzoic acid
Conditions | Yield |
---|---|
With [PhCOPd(PtBu3)I]; dtbpf In 2-methyltetrahydrofuran at 80℃; for 18h; Inert atmosphere; | 95% |
Ethyl 4-bromobenzoate
potassium formate
terephthalic acid monoethyl ester
Conditions | Yield |
---|---|
With [PhCOPd(PtBu3)I]; dtbpf In 2-methyltetrahydrofuran at 80℃; for 18h; Inert atmosphere; | 95% |
Conditions | Yield |
---|---|
In methanol for 10h; | 94% |
Conditions | Yield |
---|---|
potassium hydroxide In solid byproducts: H2; 330 °C; with KOH (1:0.05) in N2 atmosphere, the heating rate 6 deg/min; | A 93% B n/a |
in aluminium block at 460-500°C; | A 79% B n/a |
With air In melt 460-500°C, in presence of air; | A 79% B 20% |
Conditions | Yield |
---|---|
With [PhCOPd(PtBu3)I]; dtbpf In diethylene glycol dimethyl ether at 120℃; for 18h; Inert atmosphere; | 93% |
1-bromo-3-chloro-4-fluorobenzene
potassium formate
3-chloro-4-fluorobenzoic acid
Conditions | Yield |
---|---|
With [PhCOPd(PtBu3)I]; dtbpf In 2-methyltetrahydrofuran at 80℃; for 18h; Inert atmosphere; | 93% |
potassium formate
6-bromo-1,4-benzodioxane
2,3-dihydro-1,4-benzodioxin-6-carboxylic acid
Conditions | Yield |
---|---|
With [PhCOPd(PtBu3)I]; dtbpf In 2-methyltetrahydrofuran at 80℃; for 18h; Inert atmosphere; | 93% |
ethyl 4-chlorobenzoate
potassium formate
terephthalic acid monoethyl ester
Conditions | Yield |
---|---|
With [PhCOPd(PtBu3)I]; dtbpf In diethylene glycol dimethyl ether at 120℃; for 18h; Inert atmosphere; | 93% |
Conditions | Yield |
---|---|
With [PhCOPd(PtBu3)I]; dtbpf In 2-methyltetrahydrofuran at 80℃; for 18h; Inert atmosphere; | 92% |
Conditions | Yield |
---|---|
In water at 25℃; | 91.2% |
1-fluoro-3-iodo-5-methylbenzene
potassium formate
3-fluoro-5-methylbenzoic acid
Conditions | Yield |
---|---|
With [PhCOPd(PtBu3)I]; dtbpf In 2-methyltetrahydrofuran at 80℃; for 18h; Inert atmosphere; | 91% |
Conditions | Yield |
---|---|
With [PhCOPd(PtBu3)I]; dtbpf In 2-methyltetrahydrofuran at 80℃; for 18h; Inert atmosphere; | 91% |
The IUPAC name of thisa chemical is potassium formate. With the CAS registry number 590-29-4, it is also named as Formic acid potassium salt. The product's categories are Alphabetical Biological Buffers; Biological Buffers; BioUltra Buffers; Buffer Solutions Protein Structural Analysis; Inorganic Salts; Optimization Reagents Synthetic Reagents; Potassium; X-Ray Crystallography. It is white crystalline solid which should be sealed in the container and stored in dry place.
The other characteristics of this product can be summarized as: (1)ACD/LogP: -0.54; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -2.3; (4)ACD/LogD (pH 7.4): -3.94; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 2; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 0; (12)Enthalpy of Vaporization: 22.69 kJ/mol; (13)Vapour Pressure: 36.5 mmHg at 25°C; (14)Exact Mass: 83.961361; (15)MonoIsotopic Mass: 83.961361; (16)Topological Polar Surface Area: 40.1; (17)Heavy Atom Count: 4; (18)Complexity: 13.5.
Uses of Potassium formate: It is an intermediate in the formate potash process for the production of potassium. It has also been studied as a potential environmentally-friendly deicing salt for use on roads. In addition, it can react with chloroacetonitrile to get formyloxy-acetonitrile. This reaction needs reagent KI and solvent tetrahydrothiophene 1,1-dioxide at temperature of 100 °C. The reaction time is 4.0 hours. The yield is 76%.
When you are using this chemical, please be cautious about it as the following:
It is irritating to eyes, respiratory system and skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If you want to contact this product, you must wear suitable gloves and eye/face protection.
People can use the following data to convert to the molecule structure.
1. SMILES:[K+].[O-]C=O
2. InChI:InChI=1/CH2O2.K/c2-1-3;/h1H,(H,2,3);/q;+1/p-1
3. InChIKey:WFIZEGIEIOHZCP-REWHXWOFAK
The following are the toxicity data which has been tested.
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mouse | LD50 | intravenous | 95mg/kg (95mg/kg) | Zeitschrift fuer Ernaehrungswissenschaft. Vol. 9, Pg. 332, 1969. | |
mouse | LD50 | oral | 5500mg/kg (5500mg/kg) | Zeitschrift fuer Ernaehrungswissenschaft. Vol. 9, Pg. 332, 1969. |
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